##############################################################################
#                                                                            #
# This CIF contains the data for a data article accepted for                 #
# publication in IUCrData. It conforms to the requirements of                #
# Notes for Authors for IUCrData, and has been                               #
# peer reviewed under the auspices of IUCrData.                              #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the data    # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     'SHELXL-2014/7'
_chemical_name_systematic
;\
3-(4-Methoxyphenyl)-4-methyl-N-[4-(4-methylphenyl)-1,3-thiazol-\
2-yl]benzamide
;
_chemical_name_common     ?
_chemical_formula_moiety     'C25 H22 N2 O2 S'
_chemical_formula_sum     'C25 H22 N2 O2 S'
_chemical_formula_iupac     'C25 H22 N2 O2 S'
_chemical_formula_weight     414.50
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/c'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     9.7840(10)
_cell_length_b     10.2910(10)
_cell_length_c     21.58(2)
_cell_angle_alpha     90
_cell_angle_beta     99.528(11)
_cell_angle_gamma     90
_cell_volume     2143(2)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     5988
_cell_measurement_theta_min     3.3
_cell_measurement_theta_max     26.9
_cell_measurement_temperature     296(2)
_exptl_crystal_description     Block
_exptl_crystal_colour     Yellow
_exptl_crystal_size_max     0.22
_exptl_crystal_size_mid     0.20
_exptl_crystal_size_min     0.18
_exptl_crystal_density_diffrn     1.285
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     872
_exptl_absorpt_coefficient_mu     0.175
_exptl_absorpt_correction_type     none
_exptl_absorpt_process_details     ?
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
_exptl_absorpt_correction_T_min     ?
_exptl_absorpt_correction_T_max     ?
_diffrn_ambient_temperature     296(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_measurement_device_type     'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_method     'ω and φ scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     7733
_diffrn_reflns_av_R_equivalents     0.0499
_diffrn_reflns_theta_min     3.076
_diffrn_reflns_theta_max     27.415
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.970
_diffrn_measured_fraction_theta_full     0.987
_diffrn_reflns_limit_h_min     -8
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -13
_diffrn_reflns_limit_k_max     7
_diffrn_reflns_limit_l_min     -27
_diffrn_reflns_limit_l_max     27
_refine_special_details
;
All H atoms were found in a difference map, but refined as riding on
their parent atom with Uiso(H) = 1.2Ueq(C,N) or
Uiso(H) = 1.5Ueq(Cmethyl).
;
_reflns_number_total     4741
_reflns_number_gt     3399
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0789
_refine_ls_R_factor_gt     0.0570
_refine_ls_wR_factor_gt     0.1562
_refine_ls_wR_factor_ref     0.1783
_refine_ls_goodness_of_fit_ref     1.060
_refine_ls_restrained_S_all     1.060
_refine_ls_number_reflns     4741
_refine_ls_number_parameters     273
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0938P)²+0.3624P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.283
_refine_diff_density_min     -0.264
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
SMART (Bruker, 2002)
;
_computing_cell_refinement
;
SAINT (Bruker, 2002)
;
_computing_data_reduction
;
SAINT (Bruker, 2002)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
ORTEP-3 for Windows (Farrugia, 2012) and PLATON (Spek, 2009)
;
_computing_publication_material
;
SHELXL2014 (Sheldrick, 2015) and PLATON (Spek, 2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    S S1 0.15473(6) 0.72428(6) 0.08785(3) 0.0600(2) Uani d 1 . .
    O O1 0.32225(19) 0.7510(2) 0.00108(9) 0.0804(6) Uani d 1 . .
    O O2 0.67000(17) 0.99059(14) -0.32054(6) 0.0536(4) Uani d 1 . .
    N N1 0.31758(17) 0.60345(16) 0.17559(7) 0.0438(4) Uani d 1 . .
    N N2 0.42415(19) 0.64619(18) 0.08819(7) 0.0490(4) Uani d 1 . .
    H H2 0.4980 0.6085 0.1069 0.059 Uiso calc 1 . .
    C C1 0.3007(2) 0.5388(2) 0.30297(9) 0.0450(5) Uani d 1 . .
    H H1 0.3865 0.5414 0.2898 0.054 Uiso calc 1 . .
    C C2 0.2926(2) 0.4998(2) 0.36389(10) 0.0488(5) Uani d 1 . .
    H H2A 0.3733 0.4759 0.3906 0.059 Uiso calc 1 . .
    C C3 0.1669(2) 0.4955(2) 0.38611(11) 0.0508(5) Uani d 1 . .
    C C4 0.0493(2) 0.5281(3) 0.34400(12) 0.0626(6) Uani d 1 . .
    H H4 -0.0367 0.5235 0.3569 0.075 Uiso calc 1 . .
    C C5 0.0560(2) 0.5675(2) 0.28275(12) 0.0596(6) Uani d 1 . .
    H H5 -0.0251 0.5897 0.2559 0.072 Uiso calc 1 . .
    C C6 0.1821(2) 0.57396(19) 0.26133(9) 0.0424(4) Uani d 1 . .
    C C7 0.1594(3) 0.4598(3) 0.45323(12) 0.0701(7) Uani d 1 . .
    H H7A 0.0667 0.4334 0.4564 0.105 Uiso calc 1 . .
    H H7B 0.1845 0.5337 0.4798 0.105 Uiso calc 1 . .
    H H7C 0.2222 0.3896 0.4662 0.105 Uiso calc 1 . .
    C C8 0.1929(2) 0.62106(19) 0.19730(10) 0.0436(4) Uani d 1 . .
    C C9 0.0947(2) 0.6840(2) 0.15596(11) 0.0578(6) Uani d 1 . .
    H H9 0.0061 0.7029 0.1636 0.069 Uiso calc 1 . .
    C C10 0.3109(2) 0.6522(2) 0.11926(9) 0.0447(5) Uani d 1 . .
    C C11 0.4253(2) 0.6969(2) 0.02931(10) 0.0527(5) Uani d 1 . .
    C C12 0.5550(2) 0.6842(2) 0.00231(9) 0.0470(5) Uani d 1 . .
    C C13 0.6709(2) 0.6125(2) 0.02920(10) 0.0537(5) Uani d 1 . .
    H H13 0.6709 0.5695 0.0671 0.064 Uiso calc 1 . .
    C C14 0.7854(2) 0.6052(2) -0.00029(10) 0.0547(6) Uani d 1 . .
    H H14 0.8614 0.5568 0.0184 0.066 Uiso calc 1 . .
    C C15 0.7917(2) 0.6682(2) -0.05762(9) 0.0480(5) Uani d 1 . .
    C C16 0.6745(2) 0.74095(19) -0.08500(9) 0.0431(5) Uani d 1 . .
    C C17 0.5605(2) 0.7478(2) -0.05473(9) 0.0463(5) Uani d 1 . .
    H H17 0.4844 0.7967 -0.0730 0.056 Uiso calc 1 . .
    C C18 0.9212(2) 0.6606(3) -0.08627(11) 0.0611(6) Uani d 1 . .
    H H18A 0.9968 0.6316 -0.0552 0.092 Uiso calc 1 . .
    H H18B 0.9421 0.7449 -0.1012 0.092 Uiso calc 1 . .
    H H18C 0.9075 0.6004 -0.1207 0.092 Uiso calc 1 . .
    C C19 0.6722(2) 0.81014(19) -0.14646(9) 0.0417(4) Uani d 1 . .
    C C20 0.67264(19) 0.94456(19) -0.14980(8) 0.0413(4) Uani d 1 . .
    H H20 0.6735 0.9929 -0.1133 0.050 Uiso calc 1 . .
    C C21 0.6718(2) 1.00913(19) -0.20683(9) 0.0420(4) Uani d 1 . .
    H H21 0.6725 1.0995 -0.2082 0.050 Uiso calc 1 . .
    C C22 0.6699(2) 0.93737(19) -0.26148(8) 0.0416(4) Uani d 1 . .
    C C23 0.6675(2) 0.8030(2) -0.25930(9) 0.0513(5) Uani d 1 . .
    H H23 0.6651 0.7547 -0.2959 0.062 Uiso calc 1 . .
    C C24 0.6687(3) 0.7411(2) -0.20230(10) 0.0537(6) Uani d 1 . .
    H H24 0.6670 0.6507 -0.2012 0.064 Uiso calc 1 . .
    C C25 0.7070(3) 1.1241(2) -0.32305(11) 0.0667(7) Uani d 1 . .
    H H25A 0.7034 1.1498 -0.3661 0.100 Uiso calc 1 . .
    H H25B 0.6432 1.1760 -0.3042 0.100 Uiso calc 1 . .
    H H25C 0.7992 1.1366 -0.3005 0.100 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    S1 C9 . 1.721(3) ?
    S1 C10 . 1.732(2) ?
    O1 C11 . 1.223(3) ?
    O2 C22 . 1.387(2) ?
    O2 C25 . 1.424(3) ?
    N1 C10 . 1.307(3) ?
    N1 C8 . 1.389(3) ?
    N2 C11 . 1.375(3) ?
    N2 C10 . 1.388(3) ?
    N2 H2 . 0.8600 ?
    C1 C2 . 1.389(3) ?
    C1 C6 . 1.393(3) ?
    C1 H1 . 0.9300 ?
    C2 C3 . 1.392(3) ?
    C2 H2A . 0.9300 ?
    C3 C4 . 1.384(3) ?
    C3 C7 . 1.508(3) ?
    C4 C5 . 1.394(4) ?
    C4 H4 . 0.9300 ?
    C5 C6 . 1.389(3) ?
    C5 H5 . 0.9300 ?
    C6 C8 . 1.484(3) ?
    C7 H7A . 0.9600 ?
    C7 H7B . 0.9600 ?
    C7 H7C . 0.9600 ?
    C8 C9 . 1.362(3) ?
    C9 H9 . 0.9300 ?
    C11 C12 . 1.487(3) ?
    C12 C13 . 1.396(3) ?
    C12 C17 . 1.403(3) ?
    C13 C14 . 1.379(3) ?
    C13 H13 . 0.9300 ?
    C14 C15 . 1.407(3) ?
    C14 H14 . 0.9300 ?
    C15 C16 . 1.414(3) ?
    C15 C18 . 1.501(3) ?
    C16 C17 . 1.385(3) ?
    C16 C19 . 1.502(3) ?
    C17 H17 . 0.9300 ?
    C18 H18A . 0.9600 ?
    C18 H18B . 0.9600 ?
    C18 H18C . 0.9600 ?
    C19 C20 . 1.385(3) ?
    C19 C24 . 1.395(3) ?
    C20 C21 . 1.398(3) ?
    C20 H20 . 0.9300 ?
    C21 C22 . 1.389(3) ?
    C21 H21 . 0.9300 ?
    C22 C23 . 1.384(3) ?
    C23 C24 . 1.384(3) ?
    C23 H23 . 0.9300 ?
    C24 H24 . 0.9300 ?
    C25 H25A . 0.9600 ?
    C25 H25B . 0.9600 ?
    C25 H25C . 0.9600 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C9 S1 C10 . . 88.06(11) ?
    C22 O2 C25 . . 117.04(16) ?
    C10 N1 C8 . . 110.62(17) ?
    C11 N2 C10 . . 123.95(18) ?
    C11 N2 H2 . . 118.0 ?
    C10 N2 H2 . . 118.0 ?
    C2 C1 C6 . . 120.91(19) ?
    C2 C1 H1 . . 119.5 ?
    C6 C1 H1 . . 119.5 ?
    C1 C2 C3 . . 121.8(2) ?
    C1 C2 H2A . . 119.1 ?
    C3 C2 H2A . . 119.1 ?
    C4 C3 C2 . . 116.9(2) ?
    C4 C3 C7 . . 121.5(2) ?
    C2 C3 C7 . . 121.7(2) ?
    C3 C4 C5 . . 121.9(2) ?
    C3 C4 H4 . . 119.1 ?
    C5 C4 H4 . . 119.1 ?
    C6 C5 C4 . . 120.9(2) ?
    C6 C5 H5 . . 119.6 ?
    C4 C5 H5 . . 119.6 ?
    C5 C6 C1 . . 117.6(2) ?
    C5 C6 C8 . . 121.95(19) ?
    C1 C6 C8 . . 120.38(18) ?
    C3 C7 H7A . . 109.5 ?
    C3 C7 H7B . . 109.5 ?
    H7A C7 H7B . . 109.5 ?
    C3 C7 H7C . . 109.5 ?
    H7A C7 H7C . . 109.5 ?
    H7B C7 H7C . . 109.5 ?
    C9 C8 N1 . . 113.87(19) ?
    C9 C8 C6 . . 127.9(2) ?
    N1 C8 C6 . . 118.23(17) ?
    C8 C9 S1 . . 111.76(18) ?
    C8 C9 H9 . . 124.1 ?
    S1 C9 H9 . . 124.1 ?
    N1 C10 N2 . . 120.73(18) ?
    N1 C10 S1 . . 115.69(16) ?
    N2 C10 S1 . . 123.58(15) ?
    O1 C11 N2 . . 120.1(2) ?
    O1 C11 C12 . . 122.10(19) ?
    N2 C11 C12 . . 117.83(18) ?
    C13 C12 C17 . . 117.7(2) ?
    C13 C12 C11 . . 124.79(19) ?
    C17 C12 C11 . . 117.51(18) ?
    C14 C13 C12 . . 120.19(19) ?
    C14 C13 H13 . . 119.9 ?
    C12 C13 H13 . . 119.9 ?
    C13 C14 C15 . . 122.5(2) ?
    C13 C14 H14 . . 118.7 ?
    C15 C14 H14 . . 118.7 ?
    C14 C15 C16 . . 117.4(2) ?
    C14 C15 C18 . . 120.07(19) ?
    C16 C15 C18 . . 122.44(19) ?
    C17 C16 C15 . . 119.38(18) ?
    C17 C16 C19 . . 119.78(17) ?
    C15 C16 C19 . . 120.83(18) ?
    C16 C17 C12 . . 122.73(19) ?
    C16 C17 H17 . . 118.6 ?
    C12 C17 H17 . . 118.6 ?
    C15 C18 H18A . . 109.5 ?
    C15 C18 H18B . . 109.5 ?
    H18A C18 H18B . . 109.5 ?
    C15 C18 H18C . . 109.5 ?
    H18A C18 H18C . . 109.5 ?
    H18B C18 H18C . . 109.5 ?
    C20 C19 C24 . . 117.65(17) ?
    C20 C19 C16 . . 121.30(17) ?
    C24 C19 C16 . . 121.05(18) ?
    C19 C20 C21 . . 121.39(17) ?
    C19 C20 H20 . . 119.3 ?
    C21 C20 H20 . . 119.3 ?
    C22 C21 C20 . . 119.49(18) ?
    C22 C21 H21 . . 120.3 ?
    C20 C21 H21 . . 120.3 ?
    C23 C22 O2 . . 115.35(17) ?
    C23 C22 C21 . . 120.02(17) ?
    O2 C22 C21 . . 124.63(18) ?
    C24 C23 C22 . . 119.52(18) ?
    C24 C23 H23 . . 120.2 ?
    C22 C23 H23 . . 120.2 ?
    C23 C24 C19 . . 121.90(19) ?
    C23 C24 H24 . . 119.0 ?
    C19 C24 H24 . . 119.0 ?
    O2 C25 H25A . . 109.5 ?
    O2 C25 H25B . . 109.5 ?
    H25A C25 H25B . . 109.5 ?
    O2 C25 H25C . . 109.5 ?
    H25A C25 H25C . . 109.5 ?
    H25B C25 H25C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C6 C1 C2 C3 . . . . -0.7(3) ?
    C1 C2 C3 C4 . . . . 2.0(3) ?
    C1 C2 C3 C7 . . . . -176.8(2) ?
    C2 C3 C4 C5 . . . . -2.0(4) ?
    C7 C3 C4 C5 . . . . 176.7(2) ?
    C3 C4 C5 C6 . . . . 0.8(4) ?
    C4 C5 C6 C1 . . . . 0.5(4) ?
    C4 C5 C6 C8 . . . . -177.3(2) ?
    C2 C1 C6 C5 . . . . -0.6(3) ?
    C2 C1 C6 C8 . . . . 177.27(18) ?
    C10 N1 C8 C9 . . . . -0.2(3) ?
    C10 N1 C8 C6 . . . . -178.77(17) ?
    C5 C6 C8 C9 . . . . 12.7(3) ?
    C1 C6 C8 C9 . . . . -165.1(2) ?
    C5 C6 C8 N1 . . . . -168.9(2) ?
    C1 C6 C8 N1 . . . . 13.3(3) ?
    N1 C8 C9 S1 . . . . -0.1(2) ?
    C6 C8 C9 S1 . . . . 178.31(16) ?
    C10 S1 C9 C8 . . . . 0.28(18) ?
    C8 N1 C10 N2 . . . . 179.78(17) ?
    C8 N1 C10 S1 . . . . 0.4(2) ?
    C11 N2 C10 N1 . . . . -179.10(19) ?
    C11 N2 C10 S1 . . . . 0.2(3) ?
    C9 S1 C10 N1 . . . . -0.40(18) ?
    C9 S1 C10 N2 . . . . -179.77(19) ?
    C10 N2 C11 O1 . . . . -0.1(4) ?
    C10 N2 C11 C12 . . . . 179.34(19) ?
    O1 C11 C12 C13 . . . . -173.2(2) ?
    N2 C11 C12 C13 . . . . 7.3(3) ?
    O1 C11 C12 C17 . . . . 6.0(3) ?
    N2 C11 C12 C17 . . . . -173.44(19) ?
    C17 C12 C13 C14 . . . . -0.4(3) ?
    C11 C12 C13 C14 . . . . 178.9(2) ?
    C12 C13 C14 C15 . . . . 0.1(4) ?
    C13 C14 C15 C16 . . . . 0.0(3) ?
    C13 C14 C15 C18 . . . . 177.8(2) ?
    C14 C15 C16 C17 . . . . 0.3(3) ?
    C18 C15 C16 C17 . . . . -177.5(2) ?
    C14 C15 C16 C19 . . . . -179.44(19) ?
    C18 C15 C16 C19 . . . . 2.8(3) ?
    C15 C16 C17 C12 . . . . -0.6(3) ?
    C19 C16 C17 C12 . . . . 179.12(18) ?
    C13 C12 C17 C16 . . . . 0.7(3) ?
    C11 C12 C17 C16 . . . . -178.67(19) ?
    C17 C16 C19 C20 . . . . 68.2(3) ?
    C15 C16 C19 C20 . . . . -112.0(2) ?
    C17 C16 C19 C24 . . . . -111.3(2) ?
    C15 C16 C19 C24 . . . . 68.4(3) ?
    C24 C19 C20 C21 . . . . -1.0(3) ?
    C16 C19 C20 C21 . . . . 179.41(17) ?
    C19 C20 C21 C22 . . . . 0.3(3) ?
    C25 O2 C22 C23 . . . . -164.7(2) ?
    C25 O2 C22 C21 . . . . 15.3(3) ?
    C20 C21 C22 C23 . . . . 0.6(3) ?
    C20 C21 C22 O2 . . . . -179.45(18) ?
    O2 C22 C23 C24 . . . . 179.3(2) ?
    C21 C22 C23 C24 . . . . -0.7(3) ?
    C22 C23 C24 C19 . . . . 0.0(4) ?
    C20 C19 C24 C23 . . . . 0.9(3) ?
    C16 C19 C24 C23 . . . . -179.5(2) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    N2 H2 O2 4_576 0.86 2.33 3.175(2) 166
    C7 H7B O1 4_576 0.96 2.59 3.452(3) 149
    C13 H13 O2 4_576 0.93 2.50 3.413(4) 166
    C7 H7C Cg 2_645 0.96 2.67 3.592(5) 149
data_global
_journal_date_recd_electronic     2017-05-11
_journal_date_accepted     2017-05-15
_journal_name_full     'IUCrData'
_journal_year     2017
_journal_volume     2
_journal_issue      5
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     HO
_journal_paper_doi     10.1107/S2414314617007210
_journal_coeditor_code     BT4049
_publ_contact_author_name     'Dr. S. Kabilan'
_publ_contact_author_address
;
Drug Discovery Lab
Department of Chemistry
Annamalai University
Annamalainagar
Chidambaram 608 002
India
;
_publ_contact_author_email     profskabilan@gmail.com
_publ_contact_author_fax     '91-4144-238282'
_publ_contact_author_phone     '91-4144-238282'
_publ_section_title
;\
3-(4-Methoxyphenyl)-4-methyl-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]\
benzamide
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'K. Archana' .
;     Drug Discovery Lab
      Department of Chemistry
      Annamalai University
      Annamalainagar
      Chidambaram 608 002
      India
;
    'K. Saravanan' .
;     Drug Discovery Lab
      Department of Chemistry
      Annamalai University
      Annamalainagar
      Chidambaram 608 002
      India
;
    'K. Lakshmithendral' .
;     Drug Discovery Lab
      Department of Chemistry
      Annamalai University
      Annamalainagar
      Chidambaram 608 002
      India
;
    'S. Kabilan' .
;     Drug Discovery Lab
      Department of Chemistry
      Annamalai University
      Annamalainagar
      Chidambaram 608 002
      India
;
    'S. Selvanayagam'
;
Additional correspondence author, e-mail: s_selvanayagam@rediffmail.com.
;
;     PG & Research Department of Physics
      Government Arts College
      Melur 625 106
      India
;
_publ_section_synopsis
;
The molecules of the title compound are linked via strong N---H...O
hydrogen bonds, which form C(11) chains along the c-axis
direction.
;
