##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_2
_audit_creation_method     'SHELXL-2019/3'
_chemical_name_systematic
;
Bromido(pyrrolidine-κN)gold(I)
bis(pyrrolidine-κN)gold(I) bromide
;
_chemical_name_common     ?
_chemical_formula_moiety     'C4 H9 Au Br N, C8 H18 Au N2 +, Br -'
_chemical_formula_sum     'C12 H27 Au2 Br2 N3'
_chemical_formula_iupac     '[Au Br (C4 H9 N)], [Au (C4 H9 N)2] Br'
_chemical_formula_weight     767.12
_chemical_melting_point     ?
_space_group_crystal_system     orthorhombic
_space_group_name_H-M_alt     'P b c a'
_space_group_name_Hall     '-P 2ac 2ab'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x+1/2, -y, z+1/2'
    '-x, y+1/2, -z+1/2'
    'x+1/2, -y+1/2, -z'
    '-x, -y, -z'
    'x-1/2, y, -z-1/2'
    'x, -y-1/2, z-1/2'
    '-x-1/2, y-1/2, z'
_cell_length_a     14.8040(11)
_cell_length_b     12.4631(6)
_cell_length_c     19.4486(8)
_cell_angle_alpha     90
_cell_angle_beta     90
_cell_angle_gamma     90
_cell_volume     3588.3(3)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     7080
_cell_measurement_theta_min     2.5070
_cell_measurement_theta_max     29.3130
_cell_measurement_temperature     100(2)
_exptl_crystal_description     plate
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.08
_exptl_crystal_size_mid     0.08
_exptl_crystal_size_min     0.01
_exptl_crystal_density_diffrn     2.840
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     2784
_exptl_absorpt_coefficient_mu     20.782
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlisPro; Agilent, 2014)
;
_exptl_absorpt_correction_T_min     0.2872
_exptl_absorpt_correction_T_max     0.8191
_diffrn_ambient_temperature     100(2)
_diffrn_source     'fine-focus sealed tube'
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_measurement_device_type     'Oxford Diffraction Xcalibur, Eos'
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     16.1419
_diffrn_reflns_number     129826
_diffrn_reflns_av_R_equivalents     0.1428
_diffrn_reflns_av_unetI/netI     0.0374
_diffrn_reflns_theta_min     2.094
_diffrn_reflns_theta_max     28.282
_diffrn_reflns_theta_full     28.000
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -19
_diffrn_reflns_limit_h_max     19
_diffrn_reflns_limit_k_min     -16
_diffrn_reflns_limit_k_max     16
_diffrn_reflns_limit_l_min     -25
_diffrn_reflns_limit_l_max     25
_refine_special_details     ?
_reflns_number_total     4461
_reflns_number_gt     3055
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0820
_refine_ls_R_factor_gt     0.0512
_refine_ls_wR_factor_gt     0.1161
_refine_ls_wR_factor_ref     0.1298
_refine_ls_goodness_of_fit_ref     1.031
_refine_ls_restrained_S_all     1.028
_refine_ls_number_reflns     4461
_refine_ls_number_parameters     193
_refine_ls_number_restraints     90
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
             'w=1/[σ²(Fo²)+(0.0601P)²+57.3562P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     7.824
_refine_diff_density_min     -2.447
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Br' 'Br' -0.2901 2.4595
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlisPro, Version 1.171.36.28 (Agilent, 2014)
;
_computing_cell_refinement
;
CrysAlisPro, Version 1.171.36.28 (Agilent, 2014)
;
_computing_data_reduction
;
CrysAlisPro, Version 1.171.36.28 (Agilent, 2014)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2018/3 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
Siemens XP (Siemens, 1994)
;
_computing_publication_material
;
SHELXL2018/3 (Sheldrick, 2015)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au1 0.22755(3) 0.62223(3) 0.35070(2) 0.01738(12) Uani d 1 . .
    Au Au2 0.24402(3) 0.37177(3) 0.36733(2) 0.02106(13) Uani d 1 . .
    Br Br1 0.24081(9) 0.62289(10) 0.47285(6) 0.0319(3) Uani d 1 . .
    Br Br2 0.47574(7) 0.62096(9) 0.29066(7) 0.0265(3) Uani d 1 . .
    N N11 0.2072(6) 0.6225(7) 0.2457(5) 0.0198(18) Uani d 1 . .
    H H01 0.154(5) 0.613(8) 0.238(5) 0.00(3) Uiso d 1 . .
    C C12 0.2422(9) 0.7142(9) 0.2053(6) 0.024(3) Uani d 1 . .
    H H12A 0.306033 0.728819 0.217289 0.029 Uiso calc 1 . .
    H H12B 0.206137 0.779540 0.214322 0.029 Uiso calc 1 . .
    C C13 0.2342(13) 0.6814(11) 0.1315(7) 0.051(4) Uani d 1 . .
    H H13A 0.285701 0.709593 0.104528 0.061 Uiso calc 1 . .
    H H13B 0.177388 0.709107 0.111426 0.061 Uiso calc 1 . .
    C C14 0.2346(11) 0.5599(10) 0.1315(7) 0.042(4) Uani d 1 . .
    H H14A 0.178228 0.531639 0.110969 0.051 Uiso calc 1 . .
    H H14B 0.286700 0.532125 0.105008 0.051 Uiso calc 1 . .
    C C15 0.2417(10) 0.5284(9) 0.2057(7) 0.030(4) Uani d 1 . .
    H H15A 0.204779 0.463819 0.215090 0.036 Uiso calc 1 . .
    H H15B 0.305281 0.512831 0.218052 0.036 Uiso calc 1 . .
    N N21 0.3785(7) 0.3993(7) 0.3701(5) 0.026(2) Uani d 1 . .
    H H02 0.396(7) 0.459(7) 0.359(6) 0.01(3) Uiso d 1 . .
    C C22 0.4148(9) 0.3975(12) 0.4418(6) 0.040(3) Uani d 1 . .
    H H22A 0.397647 0.330468 0.465778 0.047 Uiso calc 1 . .
    H H22B 0.392387 0.459598 0.468609 0.047 Uiso calc 1 . .
    C C23 0.5151(9) 0.4038(11) 0.4319(8) 0.046(4) Uani d 1 . .
    H H23A 0.547490 0.373081 0.471874 0.055 Uiso calc 1 . .
    H H23B 0.534842 0.479034 0.425349 0.055 Uiso calc 1 . .
    C C24 0.5321(8) 0.3377(11) 0.3674(8) 0.046(4) Uani d 1 . .
    H H24A 0.575759 0.374322 0.336788 0.056 Uiso calc 1 . .
    H H24B 0.556329 0.266040 0.379409 0.056 Uiso calc 1 . .
    C C25 0.4417(8) 0.3276(11) 0.3330(7) 0.038(3) Uani d 1 . .
    H H25A 0.446156 0.348998 0.284058 0.046 Uiso calc 1 . .
    H H25B 0.420235 0.252415 0.335148 0.046 Uiso calc 1 . .
    N N31 0.1091(8) 0.3412(8) 0.3728(6) 0.033(2) Uani d 1 . .
    H H03 0.105(11) 0.278(7) 0.362(8) 0.05(5) Uiso d 1 . .
    C C32 0.0779(10) 0.3300(13) 0.4453(7) 0.050(3) Uani d 1 . .
    H H32A 0.094769 0.259062 0.464201 0.060 Uiso calc 0.64(2) A 1
    H H32B 0.104374 0.386778 0.474678 0.060 Uiso calc 0.64(2) A 1
    H H32C 0.028784 0.276281 0.448143 0.060 Uiso calc 0.36(2) A 2
    H H32D 0.128372 0.305867 0.474869 0.060 Uiso calc 0.36(2) A 2
    C C33 -0.0217(12) 0.341(2) 0.4413(11) 0.051(6) Uani d 0.64(2) A 1
    H H33A -0.044827 0.379924 0.482176 0.061 Uiso calc 0.64(2) A 1
    H H33B -0.050730 0.269918 0.439248 0.061 Uiso calc 0.64(2) A 1
    C C34 -0.0420(11) 0.404(2) 0.3768(13) 0.058(8) Uani d 0.64(2) A 1
    H H34A -0.083197 0.363328 0.346441 0.070 Uiso calc 0.64(2) A 1
    H H34B -0.070657 0.473716 0.388309 0.070 Uiso calc 0.64(2) A 1
    C C35 0.0453(8) 0.4212(10) 0.3433(7) 0.032(3) Uani d 1 . .
    H H35A 0.067222 0.494943 0.352072 0.039 Uiso calc 0.64(2) A 1
    H H35B 0.039676 0.410829 0.293019 0.039 Uiso calc 0.64(2) A 1
    H H35C -0.006657 0.384712 0.321348 0.039 Uiso calc 0.36(2) A 2
    H H35D 0.075975 0.466200 0.308490 0.039 Uiso calc 0.36(2) A 2
    C C33' 0.045(4) 0.435(3) 0.4683(12) 0.072(17) Uiso d 0.36(2) A 2
    H H33C 0.094119 0.476047 0.490651 0.087 Uiso calc 0.36(2) A 2
    H H33D -0.005492 0.426470 0.501145 0.087 Uiso calc 0.36(2) A 2
    C C34' 0.014(2) 0.488(2) 0.4031(12) 0.035(10) Uiso d 0.36(2) A 2
    H H34C -0.052331 0.494791 0.402725 0.042 Uiso calc 0.36(2) A 2
    H H34D 0.040500 0.561337 0.399837 0.042 Uiso calc 0.36(2) A 2
_geom_special_details     ?
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au1 N11 . 2.065(9) y
    Au1 Br1 . 2.3837(12) y
    Au1 Au2 . 3.1476(6) y
    Au1 Au2 8_665 3.1551(6) y
    Au2 N21 . 2.021(11) y
    Au2 N31 . 2.036(12) y
    N11 C12 . 1.480(12) ?
    N11 C15 . 1.497(12) ?
    N11 H01 . 0.81(7) ?
    C12 C13 . 1.496(16) ?
    C12 H12A . 0.9900 ?
    C12 H12B . 0.9900 ?
    C13 C14 . 1.514(17) ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C14 C15 . 1.500(16) ?
    C14 H14A . 0.9900 ?
    C14 H14B . 0.9900 ?
    C15 H15A . 0.9900 ?
    C15 H15B . 0.9900 ?
    N21 C25 . 1.481(13) ?
    N21 C22 . 1.496(12) ?
    N21 H02 . 0.81(7) ?
    C22 C23 . 1.500(15) ?
    C22 H22A . 0.9900 ?
    C22 H22B . 0.9900 ?
    C23 C24 . 1.523(17) ?
    C23 H23A . 0.9900 ?
    C23 H23B . 0.9900 ?
    C24 C25 . 1.501(15) ?
    C24 H24A . 0.9900 ?
    C24 H24B . 0.9900 ?
    C25 H25A . 0.9900 ?
    C25 H25B . 0.9900 ?
    N31 C35 . 1.488(13) ?
    N31 C32 . 1.490(14) ?
    N31 H03 . 0.81(7) ?
    C32 C33' . 1.460(19) ?
    C32 C33 . 1.483(17) ?
    C32 H32A . 0.9900 ?
    C32 H32B . 0.9900 ?
    C32 H32C . 0.9900 ?
    C32 H32D . 0.9900 ?
    C33 C34 . 1.508(19) ?
    C33 H33A . 0.9900 ?
    C33 H33B . 0.9900 ?
    C34 C35 . 1.463(17) ?
    C34 H34A . 0.9900 ?
    C34 H34B . 0.9900 ?
    C35 C34' . 1.504(18) ?
    C35 H35A . 0.9900 ?
    C35 H35B . 0.9900 ?
    C35 H35C . 0.9900 ?
    C35 H35D . 0.9900 ?
    C33' C34' . 1.51(2) ?
    C33' H33C . 0.9900 ?
    C33' H33D . 0.9900 ?
    C34' H34C . 0.9900 ?
    C34' H34D . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N11 Au1 Br1 . . 176.3(3) y
    N11 Au1 Au2 . . 96.6(2) ?
    Br1 Au1 Au2 . . 83.95(3) ?
    N11 Au1 Au2 . 8_665 96.8(2) ?
    Br1 Au1 Au2 . 8_665 83.31(3) ?
    Au2 Au1 Au2 . 8_665 163.074(19) y
    N21 Au2 N31 . . 175.4(4) y
    N21 Au2 Au1 . . 84.9(2) ?
    N31 Au2 Au1 . . 96.6(3) ?
    N21 Au2 Au1 . 8_655 92.2(2) ?
    N31 Au2 Au1 . 8_655 87.2(3) ?
    Au1 Au2 Au1 . 8_655 167.78(2) y
    C12 N11 C15 . . 102.1(8) ?
    C12 N11 Au1 . . 118.3(7) ?
    C15 N11 Au1 . . 117.5(7) ?
    C12 N11 H01 . . 111(7) ?
    C15 N11 H01 . . 97(7) ?
    Au1 N11 H01 . . 109(8) ?
    N11 C12 C13 . . 105.7(9) ?
    N11 C12 H12A . . 110.6 ?
    C13 C12 H12A . . 110.6 ?
    N11 C12 H12B . . 110.6 ?
    C13 C12 H12B . . 110.6 ?
    H12A C12 H12B . . 108.7 ?
    C12 C13 C14 . . 105.9(11) ?
    C12 C13 H13A . . 110.6 ?
    C14 C13 H13A . . 110.6 ?
    C12 C13 H13B . . 110.6 ?
    C14 C13 H13B . . 110.6 ?
    H13A C13 H13B . . 108.7 ?
    C15 C14 C13 . . 105.2(10) ?
    C15 C14 H14A . . 110.7 ?
    C13 C14 H14A . . 110.7 ?
    C15 C14 H14B . . 110.7 ?
    C13 C14 H14B . . 110.7 ?
    H14A C14 H14B . . 108.8 ?
    N11 C15 C14 . . 105.7(9) ?
    N11 C15 H15A . . 110.6 ?
    C14 C15 H15A . . 110.6 ?
    N11 C15 H15B . . 110.6 ?
    C14 C15 H15B . . 110.6 ?
    H15A C15 H15B . . 108.7 ?
    C25 N21 C22 . . 102.6(9) ?
    C25 N21 Au2 . . 120.5(7) ?
    C22 N21 Au2 . . 112.1(8) ?
    C25 N21 H02 . . 103(8) ?
    C22 N21 H02 . . 98(8) ?
    Au2 N21 H02 . . 117(8) ?
    N21 C22 C23 . . 103.6(10) ?
    N21 C22 H22A . . 111.0 ?
    C23 C22 H22A . . 111.0 ?
    N21 C22 H22B . . 111.0 ?
    C23 C22 H22B . . 111.0 ?
    H22A C22 H22B . . 109.0 ?
    C22 C23 C24 . . 103.9(10) ?
    C22 C23 H23A . . 111.0 ?
    C24 C23 H23A . . 111.0 ?
    C22 C23 H23B . . 111.0 ?
    C24 C23 H23B . . 111.0 ?
    H23A C23 H23B . . 109.0 ?
    C25 C24 C23 . . 105.4(10) ?
    C25 C24 H24A . . 110.7 ?
    C23 C24 H24A . . 110.7 ?
    C25 C24 H24B . . 110.7 ?
    C23 C24 H24B . . 110.7 ?
    H24A C24 H24B . . 108.8 ?
    N21 C25 C24 . . 107.2(9) ?
    N21 C25 H25A . . 110.3 ?
    C24 C25 H25A . . 110.3 ?
    N21 C25 H25B . . 110.3 ?
    C24 C25 H25B . . 110.3 ?
    H25A C25 H25B . . 108.5 ?
    C35 N31 C32 . . 103.3(9) ?
    C35 N31 Au2 . . 118.5(8) ?
    C32 N31 Au2 . . 111.8(9) ?
    C35 N31 H03 . . 119(10) ?
    C32 N31 H03 . . 98(10) ?
    Au2 N31 H03 . . 104(10) ?
    C33' C32 N31 . . 108.0(14) ?
    C33 C32 N31 . . 104.4(11) ?
    C33 C32 H32A . . 110.9 ?
    N31 C32 H32A . . 110.9 ?
    C33 C32 H32B . . 110.9 ?
    N31 C32 H32B . . 110.9 ?
    H32A C32 H32B . . 108.9 ?
    C33' C32 H32C . . 110.1 ?
    N31 C32 H32C . . 110.1 ?
    C33' C32 H32D . . 110.1 ?
    N31 C32 H32D . . 110.1 ?
    H32C C32 H32D . . 108.4 ?
    C32 C33 C34 . . 107.0(13) ?
    C32 C33 H33A . . 110.3 ?
    C34 C33 H33A . . 110.3 ?
    C32 C33 H33B . . 110.3 ?
    C34 C33 H33B . . 110.3 ?
    H33A C33 H33B . . 108.6 ?
    C35 C34 C33 . . 105.6(12) ?
    C35 C34 H34A . . 110.6 ?
    C33 C34 H34A . . 110.6 ?
    C35 C34 H34B . . 110.6 ?
    C33 C34 H34B . . 110.6 ?
    H34A C34 H34B . . 108.7 ?
    C34 C35 N31 . . 107.0(11) ?
    N31 C35 C34' . . 105.6(12) ?
    C34 C35 H35A . . 110.3 ?
    N31 C35 H35A . . 110.3 ?
    C34 C35 H35B . . 110.3 ?
    N31 C35 H35B . . 110.3 ?
    H35A C35 H35B . . 108.6 ?
    N31 C35 H35C . . 110.6 ?
    C34' C35 H35C . . 110.6 ?
    N31 C35 H35D . . 110.6 ?
    C34' C35 H35D . . 110.6 ?
    H35C C35 H35D . . 108.8 ?
    C32 C33' C34' . . 103.8(15) ?
    C32 C33' H33C . . 111.0 ?
    C34' C33' H33C . . 111.0 ?
    C32 C33' H33D . . 111.0 ?
    C34' C33' H33D . . 111.0 ?
    H33C C33' H33D . . 109.0 ?
    C35 C34' C33' . . 108.1(14) ?
    C35 C34' H34C . . 110.1 ?
    C33' C34' H34C . . 110.1 ?
    C35 C34' H34D . . 110.1 ?
    C33' C34' H34D . . 110.1 ?
    H34C C34' H34D . . 108.4 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    N11 Au1 Au2 N21 . . . . 100.5(4) ?
    Br1 Au1 Au2 N21 . . . . -83.2(3) y
    Au2 Au1 Au2 N21 8_665 . . . -41.9(3) ?
    N11 Au1 Au2 N31 . . . . -83.9(4) ?
    Br1 Au1 Au2 N31 . . . . 92.4(3) y
    Au2 Au1 Au2 N31 8_665 . . . 133.7(3) ?
    N11 Au1 Au2 Au1 . . . 8_655 23.8(3) ?
    Br1 Au1 Au2 Au1 . . . 8_655 -159.83(9) ?
    Au2 Au1 Au2 Au1 8_665 . . 8_655 -118.48(12) ?
    Au2 Au1 N11 C12 . . . . -147.6(8) ?
    Au2 Au1 N11 C12 8_665 . . . 22.1(8) ?
    Au2 Au1 N11 C15 . . . . -24.3(8) ?
    Au2 Au1 N11 C15 8_665 . . . 145.4(8) ?
    C15 N11 C12 C13 . . . . 38.1(13) ?
    Au1 N11 C12 C13 . . . . 168.8(9) ?
    N11 C12 C13 C14 . . . . -24.3(17) ?
    C12 C13 C14 C15 . . . . 0.7(19) ?
    C12 N11 C15 C14 . . . . -37.7(13) ?
    Au1 N11 C15 C14 . . . . -169.0(9) ?
    C13 C14 C15 N11 . . . . 22.9(17) ?
    Au1 Au2 N21 C25 . . . . -138.4(9) ?
    Au1 Au2 N21 C25 8_655 . . . 29.7(9) ?
    Au1 Au2 N21 C22 . . . . 100.7(7) ?
    Au1 Au2 N21 C22 8_655 . . . -91.2(7) ?
    C25 N21 C22 C23 . . . . 41.7(13) ?
    Au2 N21 C22 C23 . . . . 172.4(8) ?
    N21 C22 C23 C24 . . . . -36.5(14) ?
    C22 C23 C24 C25 . . . . 17.2(16) ?
    C22 N21 C25 C24 . . . . -31.0(14) ?
    Au2 N21 C25 C24 . . . . -156.3(9) ?
    C23 C24 C25 N21 . . . . 8.6(16) ?
    Au1 Au2 N31 C35 . . . . 22.3(9) ?
    Au1 Au2 N31 C35 8_655 . . . -146.0(9) ?
    Au1 Au2 N31 C32 . . . . -97.7(8) ?
    Au1 Au2 N31 C32 8_655 . . . 94.0(8) ?
    C35 N31 C32 C33' . . . . -35(2) ?
    Au2 N31 C32 C33' . . . . 94(2) ?
    C35 N31 C32 C33 . . . . 34.9(16) ?
    Au2 N31 C32 C33 . . . . 163.4(13) ?
    N31 C32 C33 C34 . . . . -24(2) ?
    C32 C33 C34 C35 . . . . 4(3) ?
    C33 C34 C35 N31 . . . . 19(3) ?
    C32 N31 C35 C34 . . . . -33.4(18) ?
    Au2 N31 C35 C34 . . . . -157.7(15) ?
    C32 N31 C35 C34' . . . . 27.0(19) ?
    Au2 N31 C35 C34' . . . . -97.3(18) ?
    N31 C32 C33' C34' . . . . 28(4) ?
    N31 C35 C34' C33' . . . . -11(4) ?
    C32 C33' C34' C35 . . . . -10(4) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N11 H01 Br2 6_556 0.81(7) 2.70(7) 3.498(9) 169(9) y
    N21 H02 Br2 . 0.81(7) 2.69(8) 3.477(10) 162(11) y
    C22 H22B Br1 . 0.99 3.03 3.859(13) 142.0 ?
    N31 H03 Br2 8_655 0.81(7) 2.68(10) 3.416(12) 151(14) y
    C32 H32A Br1 8_655 0.99 2.97 3.763(14) 137.6 ?
    C33 H33A Br1 5_566 0.99 3.03 3.675(18) 123.9 ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.287
_shelx_estimated_absorpt_T_max     0.819
data_3
_audit_creation_method     'SHELXL-2018/3'
_chemical_name_systematic
;
Trichlorido(piperidine-κN)gold(III)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C5 H11 Au Cl3 N'
_chemical_formula_sum     'C5 H11 Au Cl3 N'
_chemical_formula_iupac     '[Au Cl3 (C5 H11 N)]'
_chemical_formula_weight     388.46
_chemical_melting_point     ?
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/c'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     8.47646(16)
_cell_length_b     6.57436(11)
_cell_length_c     16.9961(3)
_cell_angle_alpha     90
_cell_angle_beta     93.5133(16)
_cell_angle_gamma     90
_cell_volume     945.36(3)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     13188
_cell_measurement_theta_min     2.3960
_cell_measurement_theta_max     30.6850
_cell_measurement_temperature     100(2)
_exptl_crystal_description     irregular
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.17
_exptl_crystal_size_mid     0.17
_exptl_crystal_size_min     0.15
_exptl_crystal_density_diffrn     2.729
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     712
_exptl_absorpt_coefficient_mu     16.340
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlisPro; Agilent, 2014)
;
_exptl_absorpt_correction_T_min     0.68875
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100(2)
_diffrn_source     'Enhance (Mo) X-ray Source'
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_measurement_device_type     'Oxford Diffraction Xcalibur, Eos'
_diffrn_measurement_method     'ω scan'
_diffrn_detector_area_resol_mean     16.1419
_diffrn_reflns_number     24604
_diffrn_reflns_av_R_equivalents     0.0374
_diffrn_reflns_av_unetI/netI     0.0225
_diffrn_reflns_theta_min     2.401
_diffrn_reflns_theta_max     31.093
_diffrn_reflns_theta_full     30.000
_diffrn_measured_fraction_theta_max     0.936
_diffrn_measured_fraction_theta_full     0.992
_diffrn_reflns_limit_h_min     -12
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -9
_diffrn_reflns_limit_k_max     9
_diffrn_reflns_limit_l_min     -23
_diffrn_reflns_limit_l_max     24
_refine_special_details     ?
_reflns_number_total     2853
_reflns_number_gt     2690
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0187
_refine_ls_R_factor_gt     0.0165
_refine_ls_wR_factor_gt     0.0292
_refine_ls_wR_factor_ref     0.0296
_refine_ls_goodness_of_fit_ref     1.132
_refine_ls_restrained_S_all     1.132
_refine_ls_number_reflns     2853
_refine_ls_number_parameters     96
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0085P)²+0.3159P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.003
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.923
_refine_diff_density_min     -0.800
_refine_ls_extinction_method
;
SHELXL2018/3 (Sheldrick, 2015)
;
_refine_ls_extinction_coef     0.00109(7)
_refine_ls_extinction_expression
                                  'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_cell_refinement
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_data_reduction
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2018/3 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
Siemens XP (Siemens, 1994)
;
_computing_publication_material
;
SHELXL2018/3 (Sheldrick, 2015)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au1 0.50340(2) 0.60493(2) 0.86802(2) 0.00923(4) Uani d 1 . .
    Cl Cl1 0.28810(7) 0.81001(9) 0.87943(4) 0.01663(12) Uani d 1 . .
    Cl Cl2 0.62533(7) 0.74686(9) 0.97772(3) 0.01580(12) Uani d 1 . .
    Cl Cl3 0.38860(7) 0.46665(9) 0.75544(3) 0.01487(12) Uani d 1 . .
    N N11 0.6977(2) 0.4215(3) 0.85214(12) 0.0099(4) Uani d 1 . .
    H H01 0.659(3) 0.348(4) 0.8139(18) 0.023(8) Uiso d 1 . .
    C C12 0.7391(3) 0.2837(4) 0.92065(15) 0.0162(5) Uani d 1 . .
    H H12A 0.647301 0.196029 0.930291 0.019 Uiso calc 1 . .
    H H12B 0.763017 0.366729 0.968501 0.019 Uiso calc 1 . .
    C C13 0.8809(3) 0.1509(4) 0.90554(16) 0.0169(5) Uani d 1 . .
    H H13A 0.851842 0.054401 0.862344 0.020 Uiso calc 1 . .
    H H13B 0.910481 0.070664 0.953489 0.020 Uiso calc 1 . .
    C C14 1.0226(3) 0.2774(4) 0.88339(15) 0.0190(6) Uani d 1 . .
    H H14A 1.059299 0.364332 0.928430 0.023 Uiso calc 1 . .
    H H14B 1.110477 0.186397 0.870636 0.023 Uiso calc 1 . .
    C C15 0.9751(3) 0.4096(4) 0.81249(16) 0.0174(5) Uani d 1 . .
    H H15A 0.946403 0.321752 0.766522 0.021 Uiso calc 1 . .
    H H15B 1.065906 0.495127 0.799304 0.021 Uiso calc 1 . .
    C C16 0.8357(3) 0.5454(4) 0.82901(15) 0.0145(5) Uani d 1 . .
    H H16A 0.867252 0.641410 0.872008 0.017 Uiso calc 1 . .
    H H16B 0.804704 0.625874 0.781317 0.017 Uiso calc 1 . .
_geom_special_details
;
 Non-bonded contacts:
    3.7100 (0.0006)  Au1 - Cl2_$2
    3.3365 (0.0006)  Au1 - Cl3_$5
    3.8344 (0.0008)  Cl1 - Cl2_$6
    3.8204 (0.0009)  Cl1 - Cl3_$5
    3.8344 (0.0008)  Cl2 - Cl1_$6
    3.9775 (0.0012)  Cl2 - Cl2_$2
    3.8204 (0.0009)  Cl3 - Cl1_$1
    3.8012 (0.0006)  Cl3 - Cl3_$1
    3.8012 (0.0006)  Cl3 - Cl3_$5
   112.26 ( 0.02)  Au1 - Cl1 - Cl2_$6
    60.17 ( 0.02)  Au1 - Cl1 - Cl3_$5
   152.87 ( 0.03)  Au1 - Cl2 - Cl1_$6
    66.44 ( 0.02)  Au1 - Cl2 - Cl2_$2
   109.01 ( 0.02)  Au1 - Cl3 - Cl1_$1
   101.40 ( 0.03)  Au1 - Cl3 - Cl3_$1
    60.57 ( 0.02)  Au1 - Cl3 - Cl3_$5
   133.79 ( 0.02)  Au1 - Cl3 - Au1_$1
 Operators for generating equivalent atoms:
 $1   -x+1, y-1/2, -z+3/2
 $2   -x+1, -y+1, -z+2
 $5   -x+1, y+1/2, -z+3/2
 $6   -x+1, -y+2, -z+2
 Dihedral angle
    -8.35 ( 2.02)  H01 - N11 - Au1 - Cl3
 Least-squares planes (x,y,z in crystal coordinates) and deviations from them
 (* indicates atom used to define plane)
 - 3.7482 (0.0032) x -  4.6421 (0.0018) y +  9.8430 (0.0029) z =  3.8214
 (0.0031)
 *  0.0275 (0.0005)  Au1
 * -0.0055 (0.0007)  N11
 * -0.0051 (0.0006)  Cl1
 * -0.0085 (0.0005)  Cl2
 * -0.0083 (0.0005)  Cl3
 Rms deviation of fitted atoms =   0.0138
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au1 N11 . 2.0718(19) y
    Au1 Cl2 . 2.2757(6) y
    Au1 Cl3 . 2.2817(6) y
    Au1 Cl1 . 2.2868(6) y
    N11 C16 . 1.498(3) ?
    N11 C12 . 1.500(3) ?
    C12 C13 . 1.520(3) ?
    C13 C14 . 1.527(4) ?
    C14 C15 . 1.520(4) ?
    C15 C16 . 1.520(3) ?
    N11 H01 . 0.86(3) ?
    C12 H12A . 0.9900 ?
    C12 H12B . 0.9900 ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C14 H14A . 0.9900 ?
    C14 H14B . 0.9900 ?
    C15 H15A . 0.9900 ?
    C15 H15B . 0.9900 ?
    C16 H16A . 0.9900 ?
    C16 H16B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N11 Au1 Cl2 . . 91.19(6) y
    N11 Au1 Cl3 . . 87.73(6) y
    Cl2 Au1 Cl3 . . 177.91(2) y
    N11 Au1 Cl1 . . 177.36(6) y
    Cl2 Au1 Cl1 . . 90.77(2) y
    Cl3 Au1 Cl1 . . 90.25(2) y
    C16 N11 C12 . . 112.49(19) y
    C16 N11 Au1 . . 110.96(14) ?
    C12 N11 Au1 . . 113.61(15) ?
    N11 C12 C13 . . 111.5(2) ?
    C12 C13 C14 . . 111.8(2) ?
    C15 C14 C13 . . 109.4(2) ?
    C14 C15 C16 . . 111.1(2) ?
    N11 C16 C15 . . 110.96(19) ?
    C16 N11 H01 . . 112(2) ?
    C12 N11 H01 . . 108(2) ?
    Au1 N11 H01 . . 99(2) ?
    N11 C12 H12A . . 109.3 ?
    C13 C12 H12A . . 109.3 ?
    N11 C12 H12B . . 109.3 ?
    C13 C12 H12B . . 109.3 ?
    H12A C12 H12B . . 108.0 ?
    C12 C13 H13A . . 109.3 ?
    C14 C13 H13A . . 109.3 ?
    C12 C13 H13B . . 109.3 ?
    C14 C13 H13B . . 109.3 ?
    H13A C13 H13B . . 107.9 ?
    C15 C14 H14A . . 109.8 ?
    C13 C14 H14A . . 109.8 ?
    C15 C14 H14B . . 109.8 ?
    C13 C14 H14B . . 109.8 ?
    H14A C14 H14B . . 108.2 ?
    C14 C15 H15A . . 109.4 ?
    C16 C15 H15A . . 109.4 ?
    C14 C15 H15B . . 109.4 ?
    C16 C15 H15B . . 109.4 ?
    H15A C15 H15B . . 108.0 ?
    N11 C16 H16A . . 109.4 ?
    C15 C16 H16A . . 109.4 ?
    N11 C16 H16B . . 109.4 ?
    C15 C16 H16B . . 109.4 ?
    H16A C16 H16B . . 108.0 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C16 N11 C12 C13 . . . . -53.6(3) ?
    Au1 N11 C12 C13 . . . . 179.30(16) y
    N11 C12 C13 C14 . . . . 54.2(3) ?
    C12 C13 C14 C15 . . . . -55.8(3) ?
    C13 C14 C15 C16 . . . . 57.1(3) ?
    C12 N11 C16 C15 . . . . 54.9(3) ?
    Au1 N11 C16 C15 . . . . -176.54(17) y
    C14 C15 C16 N11 . . . . -57.0(3) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N11 H01 Cl3 . 0.86(3) 2.57(3) 3.021(2) 114(2) yes
    N11 H01 Cl3 2_646 0.86(3) 2.79(3) 3.558(2) 150(3) yes
    C12 H12B Cl1 3_667 0.99 2.89 3.475(3) 118.6 ?
    C14 H14B Cl1 1_645 0.99 2.90 3.812(3) 154.3 ?
    C12 H12A Cl2 3_667 0.99 2.89 3.636(3) 132.5 ?
    C13 H13A Cl3 2_646 0.99 2.83 3.661(3) 142.3 ?
    C15 H15B Cl3 1_655 0.99 2.88 3.713(3) 141.7 ?
    C16 H16B Cl3 2_656 0.99 2.82 3.607(2) 136.6 ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.168
_shelx_estimated_absorpt_T_max     0.193
data_4
_audit_creation_method     'SHELXL-2018/3'
_chemical_name_systematic
;
Bis(piperidinium) tetrachloridoaurate(III) chloride
;
_chemical_name_common     ?
_chemical_formula_moiety     '2(C5 H12 N +), Au Cl4 -, Cl -'
_chemical_formula_sum     'C10 H24 Au Cl5 N2'
_chemical_formula_iupac     '(C5 H12 N)2 [Au Cl4] Cl'
_chemical_formula_weight     546.53
_chemical_melting_point     ?
_chemical_absolute_configuration     .
_space_group_crystal_system     orthorhombic
_space_group_name_H-M_alt     'I b a 2'
_space_group_name_Hall     'I 2 -2c'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, z'
    'x+1/2, -y+1/2, z'
    '-x+1/2, y+1/2, z'
    'x+1/2, y+1/2, z+1/2'
    '-x+1/2, -y+1/2, z+1/2'
    'x+1, -y+1, z+1/2'
    '-x+1, y+1, z+1/2'
_cell_length_a     19.4014(15)
_cell_length_b     9.7612(6)
_cell_length_c     19.1922(11)
_cell_angle_alpha     90
_cell_angle_beta     90
_cell_angle_gamma     90
_cell_volume     3634.6(4)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     2523
_cell_measurement_theta_min     2.9690
_cell_measurement_theta_max     24.5140
_cell_measurement_temperature     100(2)
_exptl_crystal_description     plate
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.10
_exptl_crystal_size_mid     0.05
_exptl_crystal_size_min     0.03
_exptl_crystal_density_diffrn     1.998
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     2096
_exptl_absorpt_coefficient_mu     8.817
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlisPro; Agilent, 2014)
;
_exptl_absorpt_correction_T_min     0.71802
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100(2)
_diffrn_source     'Enhance (Mo) X-ray Source'
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_measurement_device_type     'Oxford Diffraction Xcalibur, Eos'
_diffrn_measurement_method     'ω scan'
_diffrn_detector_area_resol_mean     16.1419
_diffrn_reflns_number     19554
_diffrn_reflns_av_R_equivalents     0.0746
_diffrn_reflns_av_unetI/netI     0.0750
_diffrn_reflns_theta_min     2.336
_diffrn_reflns_theta_max     28.266
_diffrn_reflns_theta_full     28.000
_diffrn_measured_fraction_theta_max     0.977
_diffrn_measured_fraction_theta_full     0.984
_diffrn_reflns_limit_h_min     -24
_diffrn_reflns_limit_h_max     25
_diffrn_reflns_limit_k_min     -12
_diffrn_reflns_limit_k_max     12
_diffrn_reflns_limit_l_min     -25
_diffrn_reflns_limit_l_max     24
_refine_special_details     ?
_reflns_number_total     4242
_reflns_number_gt     2632
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0864
_refine_ls_R_factor_gt     0.0414
_refine_ls_wR_factor_gt     0.0572
_refine_ls_wR_factor_ref     0.0674
_refine_ls_goodness_of_fit_ref     1.021
_refine_ls_restrained_S_all     1.019
_refine_ls_number_reflns     4242
_refine_ls_number_parameters     105
_refine_ls_number_restraints     59
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                      'w=1/[σ²(Fo²)+(0.0131P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.837
_refine_diff_density_min     -0.862
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
_refine_ls_abs_structure_details
;
 Refined as an inversion twin
;
_refine_ls_abs_structure_Flack     0.45(3)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_cell_refinement
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_data_reduction
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2018/3 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
Siemens XP (Siemens, 1994)
;
_computing_publication_material
;
SHELXL2018/3 (Sheldrick, 2015)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au1 0.15024(2) 0.74808(5) 0.5000(4) 0.01752(11) Uani d 1 . .
    Cl Cl1 0.23809(15) 0.9043(3) 0.5022(7) 0.0293(7) Uani d 1 . .
    Cl Cl2 0.1479(5) 0.7502(5) 0.3813(3) 0.041(4) Uani d 1 . .
    Cl Cl3 0.06697(15) 0.5852(3) 0.5004(8) 0.0363(8) Uani d 1 . .
    Cl Cl4 0.1459(5) 0.7478(6) 0.6189(2) 0.041(4) Uani d 1 . .
    Cl Cl5 0.500000 0.500000 0.7497(9) 0.0209(8) Uani d 1 . .
    Cl Cl6 0.500000 0.500000 0.4997(9) 0.0212(8) Uani d 1 . .
    N N11 0.4450(6) 0.6793(10) 0.6243(7) 0.019(3) Uiso d 1 . .
    H H11A 0.470289 0.655584 0.586253 0.023 Uiso calc 1 . .
    H H11B 0.463181 0.635613 0.661943 0.023 Uiso calc 1 . .
    C C12 0.3724(9) 0.6341(16) 0.6143(9) 0.041(5) Uiso d 1 . .
    H H12A 0.371230 0.533700 0.606908 0.049 Uiso calc 1 . .
    H H12B 0.353076 0.678608 0.572227 0.049 Uiso calc 1 . .
    C C13 0.3277(9) 0.6715(13) 0.6786(9) 0.032(5) Uiso d 1 . .
    H H13A 0.279477 0.641926 0.670841 0.038 Uiso calc 1 . .
    H H13B 0.345430 0.623615 0.720410 0.038 Uiso calc 1 . .
    C C14 0.3301(7) 0.8260(12) 0.6901(9) 0.014(4) Uiso d 1 . .
    H H14A 0.307256 0.873104 0.650700 0.017 Uiso calc 1 . .
    H H14B 0.304874 0.849496 0.733331 0.017 Uiso calc 1 . .
    C C15 0.4040(8) 0.8740(15) 0.6958(8) 0.028(4) Uiso d 1 . .
    H H15A 0.424040 0.837655 0.739549 0.033 Uiso calc 1 . .
    H H15B 0.404483 0.975256 0.698961 0.033 Uiso calc 1 . .
    C C16 0.4494(7) 0.8302(12) 0.6350(8) 0.026(4) Uiso d 1 . .
    H H16A 0.434476 0.878041 0.592151 0.031 Uiso calc 1 . .
    H H16B 0.497850 0.856231 0.644571 0.031 Uiso calc 1 . .
    N N21 0.4104(6) 0.6232(10) 0.3780(7) 0.024(3) Uiso d 1 . .
    H H22A 0.428402 0.583084 0.339287 0.028 Uiso calc 1 . .
    H H22B 0.422809 0.571487 0.415422 0.028 Uiso calc 1 . .
    C C22 0.3351(7) 0.6233(14) 0.3724(9) 0.035(4) Uiso d 1 . .
    H H23A 0.314692 0.657301 0.416377 0.042 Uiso calc 1 . .
    H H23B 0.318457 0.528585 0.364636 0.042 Uiso calc 1 . .
    C C23 0.3127(10) 0.7123(14) 0.3134(9) 0.052(6) Uiso d 1 . .
    H H24A 0.261699 0.715798 0.312386 0.062 Uiso calc 1 . .
    H H24B 0.328482 0.671209 0.269046 0.062 Uiso calc 1 . .
    C C24 0.3408(8) 0.8578(14) 0.3190(11) 0.037(5) Uiso d 1 . .
    H H25A 0.327245 0.910784 0.277207 0.045 Uiso calc 1 . .
    H H25B 0.320773 0.903412 0.360378 0.045 Uiso calc 1 . .
    C C25 0.4187(8) 0.8560(14) 0.3252(9) 0.033(4) Uiso d 1 . .
    H H26A 0.435924 0.949881 0.334072 0.040 Uiso calc 1 . .
    H H26B 0.439282 0.823089 0.281000 0.040 Uiso calc 1 . .
    C C26 0.4402(8) 0.7603(14) 0.3857(8) 0.036(4) Uiso d 1 . .
    H H21A 0.491080 0.753018 0.386922 0.043 Uiso calc 1 . .
    H H21B 0.424817 0.800577 0.430385 0.043 Uiso calc 1 . .
_geom_special_details
;
 Non-bonded contacts:
    3.9947 (0.0026)  Au1 - Cl1_$1
    3.8135 (0.0004)  Au1 - Cl6_$4
    3.0850 (0.0053)  Cl3 - Cl3_$5
   164.57 ( 0.12)  Au1 - Cl1_$1 - Au1_$1
   168.05 ( 0.18)  Cl3 - Cl3_$5 - Au1_$5
 Operators for generating equivalent atoms:
 $1   -x+1/2, y-1/2, z
 $4   x-1/2, -y+3/2, z
 $5   -x, -y+1, z
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au1 Cl3 . 2.267(3) y
    Au1 Cl2 . 2.278(13) y
    Au1 Cl4 . 2.284(11) y
    Au1 Cl1 . 2.287(3) y
    N11 C12 . 1.489(15) ?
    N11 C16 . 1.490(13) ?
    C12 C13 . 1.553(16) ?
    C13 C14 . 1.525(14) ?
    C14 C15 . 1.514(15) ?
    C15 C16 . 1.523(14) ?
    N21 C22 . 1.465(14) ?
    N21 C26 . 1.466(13) ?
    C22 C23 . 1.491(15) ?
    C23 C24 . 1.526(15) ?
    C24 C25 . 1.517(15) ?
    C25 C26 . 1.547(14) ?
    N11 H11A . 0.9100 ?
    N11 H11B . 0.9100 ?
    C12 H12A . 0.9900 ?
    C12 H12B . 0.9900 ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C14 H14A . 0.9900 ?
    C14 H14B . 0.9900 ?
    C15 H15A . 0.9900 ?
    C15 H15B . 0.9900 ?
    C16 H16A . 0.9900 ?
    C16 H16B . 0.9900 ?
    N21 H22A . 0.9100 ?
    N21 H22B . 0.9100 ?
    C22 H23A . 0.9900 ?
    C22 H23B . 0.9900 ?
    C23 H24A . 0.9900 ?
    C23 H24B . 0.9900 ?
    C24 H25A . 0.9900 ?
    C24 H25B . 0.9900 ?
    C25 H26A . 0.9900 ?
    C25 H26B . 0.9900 ?
    C26 H21A . 0.9900 ?
    C26 H21B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    Cl3 Au1 Cl2 . . 89.8(4) y
    Cl3 Au1 Cl4 . . 88.2(4) y
    Cl2 Au1 Cl4 . . 176.70(12) y
    Cl3 Au1 Cl1 . . 177.0(3) y
    Cl2 Au1 Cl1 . . 91.6(3) y
    Cl4 Au1 Cl1 . . 90.6(4) y
    C12 N11 C16 . . 111.5(11) ?
    N11 C12 C13 . . 110.8(12) ?
    C14 C13 C12 . . 109.3(11) ?
    C15 C14 C13 . . 110.2(12) ?
    C14 C15 C16 . . 113.9(11) ?
    N11 C16 C15 . . 110.5(10) ?
    C22 N21 C26 . . 113.6(10) ?
    N21 C22 C23 . . 110.3(12) ?
    C22 C23 C24 . . 112.7(12) ?
    C25 C24 C23 . . 110.6(12) ?
    C24 C25 C26 . . 109.5(12) ?
    N21 C26 C25 . . 111.7(11) ?
    C12 N11 H11A . . 109.3 ?
    C16 N11 H11A . . 109.3 ?
    C12 N11 H11B . . 109.3 ?
    C16 N11 H11B . . 109.3 ?
    H11A N11 H11B . . 108.0 ?
    N11 C12 H12A . . 109.5 ?
    C13 C12 H12A . . 109.5 ?
    N11 C12 H12B . . 109.5 ?
    C13 C12 H12B . . 109.5 ?
    H12A C12 H12B . . 108.1 ?
    C14 C13 H13A . . 109.8 ?
    C12 C13 H13A . . 109.8 ?
    C14 C13 H13B . . 109.8 ?
    C12 C13 H13B . . 109.8 ?
    H13A C13 H13B . . 108.3 ?
    C15 C14 H14A . . 109.6 ?
    C13 C14 H14A . . 109.6 ?
    C15 C14 H14B . . 109.6 ?
    C13 C14 H14B . . 109.6 ?
    H14A C14 H14B . . 108.1 ?
    C14 C15 H15A . . 108.8 ?
    C16 C15 H15A . . 108.8 ?
    C14 C15 H15B . . 108.8 ?
    C16 C15 H15B . . 108.8 ?
    H15A C15 H15B . . 107.7 ?
    N11 C16 H16A . . 109.6 ?
    C15 C16 H16A . . 109.6 ?
    N11 C16 H16B . . 109.6 ?
    C15 C16 H16B . . 109.6 ?
    H16A C16 H16B . . 108.1 ?
    C22 N21 H22A . . 108.8 ?
    C26 N21 H22A . . 108.8 ?
    C22 N21 H22B . . 108.8 ?
    C26 N21 H22B . . 108.8 ?
    H22A N21 H22B . . 107.7 ?
    N21 C22 H23A . . 109.6 ?
    C23 C22 H23A . . 109.6 ?
    N21 C22 H23B . . 109.6 ?
    C23 C22 H23B . . 109.6 ?
    H23A C22 H23B . . 108.1 ?
    C22 C23 H24A . . 109.1 ?
    C24 C23 H24A . . 109.1 ?
    C22 C23 H24B . . 109.1 ?
    C24 C23 H24B . . 109.1 ?
    H24A C23 H24B . . 107.8 ?
    C25 C24 H25A . . 109.5 ?
    C23 C24 H25A . . 109.5 ?
    C25 C24 H25B . . 109.5 ?
    C23 C24 H25B . . 109.5 ?
    H25A C24 H25B . . 108.1 ?
    C24 C25 H26A . . 109.8 ?
    C26 C25 H26A . . 109.8 ?
    C24 C25 H26B . . 109.8 ?
    C26 C25 H26B . . 109.8 ?
    H26A C25 H26B . . 108.2 ?
    N21 C26 H21A . . 109.3 ?
    C25 C26 H21A . . 109.3 ?
    N21 C26 H21B . . 109.3 ?
    C25 C26 H21B . . 109.3 ?
    H21A C26 H21B . . 107.9 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C16 N11 C12 C13 . . . . -59.6(17) ?
    N11 C12 C13 C14 . . . . 58.7(17) ?
    C12 C13 C14 C15 . . . . -54.6(17) ?
    C13 C14 C15 C16 . . . . 53.4(16) ?
    C12 N11 C16 C15 . . . . 55.6(16) ?
    C14 C15 C16 N11 . . . . -53.2(16) ?
    C26 N21 C22 C23 . . . . 56.0(16) ?
    N21 C22 C23 C24 . . . . -55.1(18) ?
    C22 C23 C24 C25 . . . . 55(2) ?
    C23 C24 C25 C26 . . . . -53.1(18) ?
    C22 N21 C26 C25 . . . . -56.3(16) ?
    C24 C25 C26 N21 . . . . 54.1(16) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N11 H11A Cl6 . 0.91 2.32 3.150(16) 150.9 yes
    N11 H11B Cl5 . 0.91 2.26 3.161(16) 171.6 yes
    C12 H12A Cl4 4_545 0.99 2.82 3.788(17) 166.0 ?
    C13 H13A Cl4 . 0.99 2.96 3.78(2) 140.8 ?
    C16 H16A Cl3 4 0.99 2.68 3.601(16) 154.8 yes
    N21 H22B Cl6 . 0.91 2.31 3.150(15) 153.0 yes
    N21 H22A Cl5 7_454 0.91 2.35 3.246(17) 166.3 yes
    C22 H23B Cl2 4_545 0.99 2.81 3.661(14) 144.0 ?
    C23 H24A Cl2 . 0.99 2.60 3.47(2) 147.6 yes
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.473
_shelx_estimated_absorpt_T_max     0.778
data_6
_audit_creation_method     'SHELXL-2018/3'
_chemical_name_systematic
;
Bis(pyrrolidinium) tetrabromidoaurate(III) bromide
;
_chemical_name_common     ?
_chemical_formula_moiety     '2(C4 H10 N +), Au Br4 -, Br -'
_chemical_formula_sum     'C8 H20 Au Br5 N2'
_chemical_formula_iupac     '(C4 H10 N)2 [Au Br4] Br'
_chemical_formula_weight     740.78
_chemical_melting_point     ?
_space_group_crystal_system     orthorhombic
_space_group_name_H-M_alt     'I b a m'
_space_group_name_Hall     '-I 2 2c'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, z'
    'x, -y, -z+1/2'
    '-x, y, -z+1/2'
    'x+1/2, y+1/2, z+1/2'
    '-x+1/2, -y+1/2, z+1/2'
    'x+1/2, -y+1/2, -z+1'
    '-x+1/2, y+1/2, -z+1'
    '-x, -y, -z'
    'x, y, -z'
    '-x, y, z-1/2'
    'x, -y, z-1/2'
    '-x+1/2, -y+1/2, -z+1/2'
    'x+1/2, y+1/2, -z+1/2'
    '-x+1/2, y+1/2, z'
    'x+1/2, -y+1/2, z'
_cell_length_a     19.1275(7)
_cell_length_b     9.4396(13)
_cell_length_c     18.9259(17)
_cell_angle_alpha     90
_cell_angle_beta     90
_cell_angle_gamma     90
_cell_volume     3417.2(6)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     6924
_cell_measurement_theta_min     2.4020
_cell_measurement_theta_max     30.3070
_cell_measurement_temperature     100(2)
_exptl_crystal_description     plate
_exptl_crystal_colour     red
_exptl_crystal_size_max     0.15
_exptl_crystal_size_mid     0.12
_exptl_crystal_size_min     0.03
_exptl_crystal_density_diffrn     2.880
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     2688
_exptl_absorpt_coefficient_mu     20.284
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlisPro; Agilent, 2014)
;
_exptl_absorpt_correction_T_min     0.17666
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100(2)
_diffrn_source     'Enhance (Mo) X-ray Source'
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Oxford Diffraction Xcalibur, Eos'
_diffrn_measurement_method     'ω scan'
_diffrn_detector_area_resol_mean     16.1419
_diffrn_reflns_number     35669
_diffrn_reflns_av_R_equivalents     0.0850
_diffrn_reflns_av_unetI/netI     0.0422
_diffrn_reflns_theta_min     2.129
_diffrn_reflns_theta_max     30.969
_diffrn_reflns_theta_full     30.000
_diffrn_measured_fraction_theta_max     0.959
_diffrn_measured_fraction_theta_full     0.997
_diffrn_reflns_limit_h_min     -27
_diffrn_reflns_limit_h_max     27
_diffrn_reflns_limit_k_min     -12
_diffrn_reflns_limit_k_max     13
_diffrn_reflns_limit_l_min     -27
_diffrn_reflns_limit_l_max     26
_refine_special_details     ?
_reflns_number_total     2689
_reflns_number_gt     2205
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0504
_refine_ls_R_factor_gt     0.0340
_refine_ls_wR_factor_gt     0.0608
_refine_ls_wR_factor_ref     0.0652
_refine_ls_goodness_of_fit_ref     1.077
_refine_ls_restrained_S_all     1.077
_refine_ls_number_reflns     2689
_refine_ls_number_parameters     88
_refine_ls_number_restraints     1
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
             'w=1/[σ²(Fo²)+(0.0204P)²+17.1013P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     2.214
_refine_diff_density_min     -1.240
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Br' 'Br' -0.2901 2.4595
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_cell_refinement
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_data_reduction
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2018/3 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
Siemens XP (Siemens, 1994)
;
_computing_publication_material
;
SHELXL2018/3 (Sheldrick, 2015)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au1 0.14803(2) 0.71040(3) 0.000000 0.01444(7) Uani d 1 . .
    Br Br1 0.14858(2) 0.71441(5) 0.12839(3) 0.02063(12) Uani d 1 . .
    Br Br2 0.22029(4) 0.49747(8) 0.000000 0.02791(18) Uani d 1 . .
    Br Br3 0.07792(3) 0.92257(7) 0.000000 0.02033(15) Uani d 1 . .
    Br Br4 0.000000 0.500000 0.000000 0.01607(19) Uani d 1 . .
    Br Br5 0.000000 0.500000 0.250000 0.0268(2) Uani d 1 . .
    N N11 0.0999(2) 0.3577(5) 0.1304(3) 0.0271(10) Uani d 1 . .
    H H01 0.069(3) 0.423(6) 0.161(3) 0.05(2) Uiso d 1 . .
    H H02 0.101(3) 0.392(7) 0.079(2) 0.05(2) Uiso d 1 . .
    C C12 0.0578(3) 0.2271(5) 0.1206(3) 0.0299(13) Uani d 1 . .
    H H12A 0.064538 0.187577 0.072666 0.036 Uiso calc 1 . .
    H H12B 0.007466 0.246555 0.127932 0.036 Uiso calc 1 . .
    C C13 0.0852(3) 0.1262(5) 0.1763(3) 0.0248(11) Uani d 1 . .
    H H13A 0.076595 0.026327 0.162891 0.030 Uiso calc 1 . .
    H H13B 0.063519 0.144850 0.222896 0.030 Uiso calc 1 . .
    C C14 0.1628(3) 0.1595(5) 0.1772(3) 0.0280(13) Uani d 1 . .
    H H14A 0.187067 0.112565 0.137389 0.034 Uiso calc 1 . .
    H H14B 0.184447 0.128375 0.222131 0.034 Uiso calc 1 . .
    C C15 0.1659(3) 0.3205(6) 0.1699(4) 0.0316(14) Uani d 1 . .
    H H15A 0.166824 0.366671 0.216800 0.038 Uiso calc 1 . .
    H H15B 0.207800 0.349832 0.142885 0.038 Uiso calc 1 . .
_geom_special_details
;
 Au...Br and Br...Br contacts:
    3.6997 (0.0008)  Au1 - Br2_$5
    3.4585 (0.0003)  Au1 - Br4
    3.6997 (0.0008)  Br2 - Au1_$3
    3.3201 (0.0013)  Br3 - Br3_$6
    3.4585 (0.0003)  Br4 - Au1_$7
   171.61 ( 0.03)  Au1 - Br2 - Au1_$3
   149.92 ( 0.04)  Au1 - Br3 - Br3_$6
 Operators for generating equivalent atoms:
 $3   -x+1/2, y-1/2, z
 $4   x, y-1, z
 $5   -x+1/2, y+1/2, z
 $6   -x, -y+2, -z
 $7   -x, -y+1, -z
 $8   x, y, -z
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au1 Br3 . 2.4102(7) y
    Au1 Br1 . 2.4303(5) y
    Au1 Br1 10 2.4303(5) ?
    Au1 Br2 . 2.4393(8) y
    N11 C12 . 1.484(7) ?
    N11 C15 . 1.508(7) ?
    N11 H01 . 1.03(4) ?
    N11 H02 . 1.02(4) ?
    C12 C13 . 1.514(7) ?
    C12 H12A . 0.9900 ?
    C12 H12B . 0.9900 ?
    C13 C14 . 1.517(7) ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C14 C15 . 1.527(7) ?
    C14 H14A . 0.9900 ?
    C14 H14B . 0.9900 ?
    C15 H15A . 0.9900 ?
    C15 H15B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    Br3 Au1 Br1 . . 89.399(13) y
    Br3 Au1 Br1 . 10 89.399(13) ?
    Br1 Au1 Br1 . 10 178.15(3) y
    Br3 Au1 Br2 . . 179.29(3) y
    Br1 Au1 Br2 . . 90.592(13) y
    Br1 Au1 Br2 10 . 90.593(13) ?
    C12 N11 C15 . . 108.8(4) ?
    C12 N11 H01 . . 105(4) ?
    C15 N11 H01 . . 110(4) ?
    C12 N11 H02 . . 99(4) ?
    C15 N11 H02 . . 122(4) ?
    H01 N11 H02 . . 111(5) ?
    N11 C12 C13 . . 104.4(4) ?
    N11 C12 H12A . . 110.9 ?
    C13 C12 H12A . . 110.9 ?
    N11 C12 H12B . . 110.9 ?
    C13 C12 H12B . . 110.9 ?
    H12A C12 H12B . . 108.9 ?
    C12 C13 C14 . . 102.5(4) ?
    C12 C13 H13A . . 111.3 ?
    C14 C13 H13A . . 111.3 ?
    C12 C13 H13B . . 111.3 ?
    C14 C13 H13B . . 111.3 ?
    H13A C13 H13B . . 109.2 ?
    C13 C14 C15 . . 104.1(4) ?
    C13 C14 H14A . . 110.9 ?
    C15 C14 H14A . . 110.9 ?
    C13 C14 H14B . . 110.9 ?
    C15 C14 H14B . . 110.9 ?
    H14A C14 H14B . . 109.0 ?
    N11 C15 C14 . . 104.2(4) ?
    N11 C15 H15A . . 110.9 ?
    C14 C15 H15A . . 110.9 ?
    N11 C15 H15B . . 110.9 ?
    C14 C15 H15B . . 110.9 ?
    H15A C15 H15B . . 108.9 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C15 N11 C12 C13 . . . . 20.1(6) ?
    N11 C12 C13 C14 . . . . -36.7(6) ?
    C12 C13 C14 C15 . . . . 39.7(6) ?
    C12 N11 C15 C14 . . . . 4.5(6) ?
    C13 C14 C15 N11 . . . . -27.3(6) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N11 H01 Br5 . 1.03(4) 2.26(5) 3.253(5) 161(5) yes
    N11 H02 Br2 . 1.02(4) 2.90(6) 3.624(5) 128(5) yes
    N11 H02 Br4 . 1.02(4) 2.65(6) 3.398(5) 130(5) yes
    C12 H12B Br1 2_565 0.99 3.01 3.989(6) 171.3 ?
    C15 H15A Br1 3_565 0.99 3.05 3.847(7) 138.6 ?
    C15 H15B Br1 15_545 0.99 3.04 3.770(5) 131.3 ?
    C15 H15B Br2 . 0.99 3.05 3.769(6) 130.4 ?
    C12 H12A Br3 1_545 0.99 2.87 3.691(6) 141.3 y
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.151
_shelx_estimated_absorpt_T_max     0.581
data_7
_audit_creation_method     'SHELXL-2018/3'
_chemical_name_systematic
;
Tribromido(piperidine-κN)gold(III) dichloromethane monosolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C5 H11 Au Br3 N, C H2 Cl2'
_chemical_formula_sum     'C6 H13 Au Br3 Cl2 N'
_chemical_formula_iupac     '[Au Br3 (C5 H11 N)], C H2 Cl2'
_chemical_formula_weight     606.77
_chemical_melting_point     ?
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/c'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     7.3473(3)
_cell_length_b     22.0860(8)
_cell_length_c     8.5066(3)
_cell_angle_alpha     90
_cell_angle_beta     96.423(3)
_cell_angle_gamma     90
_cell_volume     1371.71(9)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     8200
_cell_measurement_theta_min     2.6540
_cell_measurement_theta_max     30.7580
_cell_measurement_temperature     100(2)
_exptl_crystal_description     block
_exptl_crystal_colour     red
_exptl_crystal_size_max     0.15
_exptl_crystal_size_mid     0.12
_exptl_crystal_size_min     0.10
_exptl_crystal_density_diffrn     2.938
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1096
_exptl_absorpt_coefficient_mu     19.815
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlisPro; Agilent, 2014)
;
_exptl_absorpt_correction_T_min     0.57357
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100(2)
_diffrn_source     'Enhance (Mo) X-ray Source'
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_measurement_device_type     'Oxford Diffraction Xcalibur, Eos'
_diffrn_measurement_method     'ω scan'
_diffrn_detector_area_resol_mean     16.1419
_diffrn_reflns_number     36043
_diffrn_reflns_av_R_equivalents     0.0430
_diffrn_reflns_av_unetI/netI     0.0266
_diffrn_reflns_theta_min     2.580
_diffrn_reflns_theta_max     30.927
_diffrn_reflns_theta_full     30.000
_diffrn_measured_fraction_theta_max     0.951
_diffrn_measured_fraction_theta_full     0.989
_diffrn_reflns_limit_h_min     -10
_diffrn_reflns_limit_h_max     10
_diffrn_reflns_limit_k_min     -31
_diffrn_reflns_limit_k_max     31
_diffrn_reflns_limit_l_min     -12
_diffrn_reflns_limit_l_max     11
_refine_special_details     ?
_reflns_number_total     4139
_reflns_number_gt     3658
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0317
_refine_ls_R_factor_gt     0.0242
_refine_ls_wR_factor_gt     0.0373
_refine_ls_wR_factor_ref     0.0385
_refine_ls_goodness_of_fit_ref     1.150
_refine_ls_restrained_S_all     1.150
_refine_ls_number_reflns     4139
_refine_ls_number_parameters     123
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0061P)²+2.1369P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.839
_refine_diff_density_min     -0.833
_refine_ls_extinction_method
;
SHELXL2018/3 (Sheldrick 2015)
;
_refine_ls_extinction_coef     0.00041(2)
_refine_ls_extinction_expression
                                  'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Br' 'Br' -0.2901 2.4595
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_cell_refinement
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_data_reduction
;
CrysAlisPro, Version 1.171.37.35 (Agilent, 2014)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2018/3 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
Siemens XP (Siemens, 1994)
;
_computing_publication_material
;
SHELXL2018/3 (Sheldrick, 2015)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au1 0.51277(2) 0.24454(2) 0.25555(2) 0.00781(4) Uani d 1 . .
    Br Br1 0.52418(4) 0.35307(2) 0.21990(4) 0.01219(7) Uani d 1 . .
    Br Br2 0.79078(4) 0.24741(2) 0.43841(4) 0.01246(7) Uani d 1 . .
    Br Br3 0.24299(4) 0.24137(2) 0.06300(4) 0.01363(7) Uani d 1 . .
    N N11 0.5152(4) 0.15094(13) 0.2928(3) 0.0105(6) Uani d 1 . .
    H H01 0.564(5) 0.1462(17) 0.388(4) 0.010(9) Uiso d 1 . .
    C C12 0.3327(5) 0.12067(16) 0.2919(4) 0.0166(7) Uani d 1 . .
    H H12A 0.262660 0.125337 0.186272 0.020 Uiso calc 1 . .
    H H12B 0.262625 0.140485 0.370457 0.020 Uiso calc 1 . .
    C C13 0.3548(5) 0.05401(17) 0.3310(4) 0.0206(8) Uani d 1 . .
    H H13A 0.232656 0.034650 0.324584 0.025 Uiso calc 1 . .
    H H13B 0.414508 0.049313 0.440558 0.025 Uiso calc 1 . .
    C C14 0.4697(5) 0.02288(17) 0.2170(4) 0.0219(8) Uani d 1 . .
    H H14A 0.488269 -0.020115 0.247579 0.026 Uiso calc 1 . .
    H H14B 0.404673 0.024218 0.108612 0.026 Uiso calc 1 . .
    C C15 0.6531(5) 0.05400(17) 0.2194(4) 0.0212(8) Uani d 1 . .
    H H15A 0.724300 0.034610 0.141007 0.025 Uiso calc 1 . .
    H H15B 0.722566 0.049134 0.325312 0.025 Uiso calc 1 . .
    C C16 0.6307(5) 0.12090(16) 0.1816(4) 0.0158(7) Uani d 1 . .
    H H16A 0.752587 0.140470 0.189969 0.019 Uiso calc 1 . .
    H H16B 0.572596 0.125882 0.071625 0.019 Uiso calc 1 . .
    C C1 0.0245(5) 0.37793(17) 0.2600(4) 0.0185(7) Uani d 1 . .
    H H1A 0.145117 0.357439 0.273057 0.022 Uiso calc 1 . .
    H H1B -0.071860 0.346408 0.252639 0.022 Uiso calc 1 . .
    Cl Cl1 0.00338(15) 0.42462(5) 0.42603(12) 0.0294(2) Uani d 1 . .
    Cl Cl2 0.00380(16) 0.42122(5) 0.08506(12) 0.0327(2) Uani d 1 . .
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_22
    _atom_site_aniso_U_33
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_23
    Au1 0.00905(6) 0.00586(6) 0.00833(6) -0.00023(5) 0.00018(4) 0.00005(5)
    Br1 0.01637(16) 0.00648(16) 0.01348(16) 0.00051(12) 0.00062(12) 0.00047(12)
    Br2 0.01135(14) 0.01168(17) 0.01346(15) -0.00178(12) -0.00249(11)
                                                                     0.00151(12)
    Br3 0.01223(15) 0.01432(18) 0.01331(15) -0.00090(13) -0.00310(12)
                                                                     0.00090(13)
    N11 0.0165(14) 0.0063(14) 0.0080(13) 0.0013(11) -0.0018(11) -0.0003(10)
    C12 0.0186(18) 0.0109(18) 0.0216(18) -0.0050(14) 0.0082(14) -0.0023(14)
    C13 0.032(2) 0.0105(19) 0.0203(18) -0.0055(15) 0.0068(16) -0.0003(15)
    C14 0.038(2) 0.0085(18) 0.0198(19) 0.0001(16) 0.0037(17) -0.0009(14)
    C15 0.031(2) 0.0091(19) 0.0233(19) 0.0028(15) 0.0042(16) -0.0017(15)
    C16 0.0212(18) 0.0104(18) 0.0162(17) 0.0036(14) 0.0038(14) 0.0002(14)
    C1 0.0178(18) 0.0147(18) 0.0239(19) 0.0012(14) 0.0061(15) 0.0030(15)
    Cl1 0.0363(6) 0.0285(6) 0.0232(5) 0.0024(4) 0.0023(4) -0.0021(4)
    Cl2 0.0477(7) 0.0282(6) 0.0239(5) 0.0064(5) 0.0118(5) 0.0081(4)
_geom_special_details
;
 Non-bonded contacts:
    3.5658 (0.0004)  Au1 - Br2_$3
    3.4678 (0.0004)  Au1 - Br3_$1
    3.5658 (0.0004)  Br2 - Au1_$1
    3.3817 (0.0004)  Br2 - Br3_$5
    3.4678 (0.0004)  Br3 - Au1_$3
    3.3817 (0.0004)  Br3 - Br2_$6
    3.5618 (0.0021)  Cl1 - Cl1_$7
    88.50 ( 0.01)  Au1 - Br2 - Au1_$1
   158.46 ( 0.01)  Au1 - Br2 - Br3_$5
    90.79 ( 0.01)  Au1 - Br3 - Au1_$3
   155.37 ( 0.01)  Au1 - Br3 - Br2_$6
   146.38 ( 0.13)  C1 - Cl1 - Cl1_$7
Operators for generating equivalent atoms:
 $1   x, -y+1/2, z+1/2
 $3   x, -y+1/2, z-1/2
 $5   x+1, -y+1/2, z+1/2
 $6   x-1, -y+1/2, z-1/2
 $7   -x, -y+1, -z+1
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au1 N11 . 2.091(3) y
    Au1 Br1 . 2.4187(4) y
    Au1 Br2 . 2.4260(3) y
    Au1 Br3 . 2.4270(3) y
    N11 C16 . 1.495(4) y
    N11 C12 . 1.497(4) y
    C12 C13 . 1.514(5) ?
    C13 C14 . 1.520(5) ?
    C14 C15 . 1.511(5) ?
    C15 C16 . 1.517(5) ?
    C1 Cl2 . 1.761(4) ?
    C1 Cl1 . 1.769(4) ?
    N11 H01 . 0.85(4) ?
    C12 H12A . 0.9900 ?
    C12 H12B . 0.9900 ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C14 H14A . 0.9900 ?
    C14 H14B . 0.9900 ?
    C15 H15A . 0.9900 ?
    C15 H15B . 0.9900 ?
    C16 H16A . 0.9900 ?
    C16 H16B . 0.9900 ?
    C1 H1A . 0.9900 ?
    C1 H1B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N11 Au1 Br1 . . 177.24(8) y
    N11 Au1 Br2 . . 86.35(8) y
    Br1 Au1 Br2 . . 90.913(12) y
    N11 Au1 Br3 . . 93.80(8) y
    Br1 Au1 Br3 . . 88.920(12) y
    Br2 Au1 Br3 . . 177.454(13) y
    C16 N11 C12 . . 111.7(3) y
    C16 N11 Au1 . . 109.8(2) ?
    C12 N11 Au1 . . 116.6(2) ?
    N11 C12 C13 . . 111.1(3) ?
    C12 C13 C14 . . 110.7(3) ?
    C15 C14 C13 . . 110.1(3) ?
    C14 C15 C16 . . 111.4(3) ?
    N11 C16 C15 . . 110.7(3) ?
    Cl2 C1 Cl1 . . 110.5(2) ?
    C16 N11 H01 . . 110(2) ?
    C12 N11 H01 . . 104(2) ?
    Au1 N11 H01 . . 105(3) ?
    N11 C12 H12A . . 109.4 ?
    C13 C12 H12A . . 109.4 ?
    N11 C12 H12B . . 109.4 ?
    C13 C12 H12B . . 109.4 ?
    H12A C12 H12B . . 108.0 ?
    C12 C13 H13A . . 109.5 ?
    C14 C13 H13A . . 109.5 ?
    C12 C13 H13B . . 109.5 ?
    C14 C13 H13B . . 109.5 ?
    H13A C13 H13B . . 108.1 ?
    C15 C14 H14A . . 109.6 ?
    C13 C14 H14A . . 109.6 ?
    C15 C14 H14B . . 109.6 ?
    C13 C14 H14B . . 109.6 ?
    H14A C14 H14B . . 108.2 ?
    C14 C15 H15A . . 109.4 ?
    C16 C15 H15A . . 109.4 ?
    C14 C15 H15B . . 109.4 ?
    C16 C15 H15B . . 109.4 ?
    H15A C15 H15B . . 108.0 ?
    N11 C16 H16A . . 109.5 ?
    C15 C16 H16A . . 109.5 ?
    N11 C16 H16B . . 109.5 ?
    C15 C16 H16B . . 109.5 ?
    H16A C16 H16B . . 108.1 ?
    Cl2 C1 H1A . . 109.5 ?
    Cl1 C1 H1A . . 109.5 ?
    Cl2 C1 H1B . . 109.5 ?
    Cl1 C1 H1B . . 109.5 ?
    H1A C1 H1B . . 108.1 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C16 N11 C12 C13 . . . . 56.4(4) ?
    Au1 N11 C12 C13 . . . . -176.2(2) y
    N11 C12 C13 C14 . . . . -56.4(4) ?
    C12 C13 C14 C15 . . . . 56.3(4) ?
    C13 C14 C15 C16 . . . . -56.3(4) ?
    C12 N11 C16 C15 . . . . -55.8(4) ?
    Au1 N11 C16 C15 . . . . 173.2(2) y
    C14 C15 C16 N11 . . . . 56.0(4) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N11 H01 Br1 4_566 0.85(4) 2.87(4) 3.627(3) 148(3) yes
    C14 H14A Br1 2_645 0.99 2.82 3.788(4) 167.0 yes
    C16 H16B Br1 4_565 0.99 3.01 3.960(3) 161.3 ?
    C1 H1B Br1 1_455 0.99 2.95 3.695(4) 132.5 ?
    C1 H1B Br2 1_455 0.99 2.94 3.761(4) 140.8 ?
    C12 H12A Cl1 4_565 0.99 2.97 3.855(4) 149.8 ?
    C15 H15B Cl2 4_666 0.99 2.93 3.849(4) 155.7 ?
    C1 H1A Br1 . 0.99 2.87 3.765(4) 150.3 yes
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.155
_shelx_estimated_absorpt_T_max     0.242
data_global
_journal_date_recd_electronic     2023-07-18
_journal_date_accepted     2023-09-27
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2023
_journal_volume     79
_journal_issue     11
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     GM
_journal_paper_doi     10.1107/S205698902300854X
_journal_coeditor_code     YZ2040
_publ_contact_author_name
;
Peter G. Jones
;
_publ_contact_author_address
;
Institut für Anorganische und Analytische Chemie
     Technische Universität Braunschweig
     Hagenring 30
     D-38106 Braunschweig
     Germany
;
_publ_contact_author_email     'p.jones@tu-braunschweig.de'
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;
Crystal structures of five halido gold complexes involving piperidine or
pyrrolidine as ligands or (protonated) as cations
;
_publ_section_title_footnote
;
Gold complexes with amine ligands, Part 12. Part 11: Döring & Jones
[(2018b).  Naturforsch. B, 73, 975--978].
;
loop_
    _publ_author_name
    _publ_author_address
    'Döring, Cindy'
;
Institut für Anorganische und Analytische Chemie
Technische Universität Braunschweig
Hagenring 30
D-38106 Braunschweig
Germany
;
    'Jones, Peter G.'
;
Institut für Anorganische und Analytische Chemie
Technische Universität Braunschweig
Hagenring 30
D-38106 Braunschweig
Germany
;
_publ_section_synopsis
;
The structures of five gold complexes involving piperidine or pyrrolidine,
whether as neutral ligands or protonated counter-cations, are presented.
;
