##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     'SHELXL-2018/3'
_chemical_name_systematic
;
[(Sₚ)-(2-Phenylferrocenyl)methyl]trimethylammonium iodide
dichloromethane monosolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C20 H24 Fe N +, I -, C H2 Cl2'
_chemical_formula_sum     'C21 H26 Cl2 Fe I N'
_chemical_formula_iupac     '[Fe (C5 H5) (C15 H19 N)] I, C H2 Cl2'
_chemical_formula_weight     546.08
_chemical_melting_point     ?
_chemical_absolute_configuration     rmad
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21'
_space_group_name_Hall     'P 2yb'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z'
_cell_length_a     10.7919(7)
_cell_length_b     10.2128(5)
_cell_length_c     11.2941(7)
_cell_angle_alpha     90
_cell_angle_beta     113.031(3)
_cell_angle_gamma     90
_cell_volume     1145.57(12)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     9989
_cell_measurement_theta_min     2.80
_cell_measurement_theta_max     28.28
_cell_measurement_temperature     110(2)
_exptl_crystal_description     stick
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.300
_exptl_crystal_size_mid     0.100
_exptl_crystal_size_min     0.100
_exptl_crystal_density_diffrn     1.583
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     544
_exptl_absorpt_coefficient_mu     2.244
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(SADABS; Krause et al.,  2015)
;
_exptl_absorpt_correction_T_min     0.5195
_exptl_absorpt_correction_T_max     0.7457
_diffrn_ambient_temperature     110(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'micro-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII CCD'
_diffrn_measurement_method     'φ and ω scans'
_diffrn_reflns_number     58547
_diffrn_reflns_av_R_equivalents     0.0518
_diffrn_reflns_av_unetI/netI     0.0218
_diffrn_reflns_theta_min     2.051
_diffrn_reflns_theta_max     30.531
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.998
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -15
_diffrn_reflns_limit_h_max     15
_diffrn_reflns_limit_k_min     -14
_diffrn_reflns_limit_k_max     14
_diffrn_reflns_limit_l_min     -16
_diffrn_reflns_limit_l_max     16
_refine_special_details     ?
_reflns_number_total     6993
_reflns_number_gt     6822
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0334
_refine_ls_R_factor_gt     0.0326
_refine_ls_wR_factor_gt     0.0911
_refine_ls_wR_factor_ref     0.0920
_refine_ls_goodness_of_fit_ref     1.063
_refine_ls_restrained_S_all     1.063
_refine_ls_number_reflns     6993
_refine_ls_number_parameters     247
_refine_ls_number_restraints     1
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0507P)²+0.9038P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.496
_refine_diff_density_min     -0.685
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
_refine_ls_abs_structure_details
;
Flack x determined using 3144 quotients
[(I⁺)-(I⁻)]/[(I⁺)+(I⁻)]
(Parsons et al.,  2013)
;
_refine_ls_abs_structure_Flack     0.018(6)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Fe' 'Fe' 0.3463 0.8444
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'I' 'I' -0.4742 1.8119
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
APEX2 (Bruker, 2015)
;
_computing_cell_refinement
;
SAINT (Bruker, 2015)
;
_computing_data_reduction
;
SAINT (Bruker, 2015)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_computing_structure_refinement
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_molecular_graphics
;
ORTEPIII (Burnett & Johnson, 1996), ORTEP-3 for Windows (Farrugia,
2012)
and Mercury (Macrae et al.,  2020)
;
_computing_publication_material
;
SHELXL2018 (Sheldrick, 2015b)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Fe Fe1 0.94060(5) 0.53142(6) 0.79508(5) 0.02716(11) Uani d 1 . .
    I I1 0.22433(3) 0.13532(3) 0.79999(3) 0.04532(10) Uani d 1 . .
    N N1 0.5997(3) 0.3408(3) 0.8610(3) 0.0281(6) Uani d 1 . .
    C C1 0.7697(3) 0.4388(3) 0.7817(3) 0.0243(6) Uani d 1 . .
    C C2 0.7375(3) 0.5512(4) 0.6967(3) 0.0248(6) Uani d 1 . .
    C C3 0.8016(4) 0.5304(5) 0.6083(4) 0.0323(7) Uani d 1 . .
    H H3 0.797426 0.587679 0.540618 0.039 Uiso calc 1 . .
    C C4 0.8728(4) 0.4085(5) 0.6395(4) 0.0361(8) Uani d 1 . .
    H H4 0.924513 0.371724 0.596435 0.043 Uiso calc 1 . .
    C C5 0.8532(4) 0.3521(4) 0.7450(4) 0.0316(7) Uani d 1 . .
    H H5 0.888964 0.270870 0.784766 0.038 Uiso calc 1 . .
    C C6 1.0323(5) 0.6035(7) 0.9762(5) 0.0588(18) Uani d 1 . .
    H H6 0.996901 0.602449 1.041048 0.071 Uiso calc 1 . .
    C C7 1.1125(5) 0.5035(6) 0.9540(6) 0.0546(14) Uani d 1 . .
    H H7 1.139685 0.424007 1.000841 0.065 Uiso calc 1 . .
    C C8 1.1439(4) 0.5440(6) 0.8501(6) 0.0482(11) Uani d 1 . .
    H H8 1.196503 0.496477 0.814202 0.058 Uiso calc 1 . .
    C C9 1.0835(5) 0.6679(6) 0.8081(6) 0.0517(13) Uani d 1 . .
    H H9 1.088663 0.717959 0.739283 0.062 Uiso calc 1 . .
    C C10 1.0143(5) 0.7038(6) 0.8864(7) 0.0542(14) Uani d 1 . .
    H H10 0.964387 0.782051 0.879465 0.065 Uiso calc 1 . .
    C C11 0.7314(3) 0.4163(4) 0.8937(3) 0.0262(6) Uani d 1 . .
    H H11A 0.723121 0.502191 0.930581 0.031 Uiso calc 1 . .
    H H11B 0.804794 0.367396 0.960681 0.031 Uiso calc 1 . .
    C C12 0.4841(4) 0.4146(5) 0.7671(6) 0.0463(11) Uani d 1 . .
    H H12A 0.496041 0.423269 0.685738 0.069 Uiso calc 1 . .
    H H12B 0.479920 0.501808 0.801502 0.069 Uiso calc 1 . .
    H H12C 0.400292 0.367326 0.752068 0.069 Uiso calc 1 . .
    C C13 0.6057(5) 0.2094(4) 0.8064(5) 0.0389(9) Uani d 1 . .
    H H13A 0.518810 0.165131 0.783295 0.058 Uiso calc 1 . .
    H H13B 0.676498 0.156995 0.870448 0.058 Uiso calc 1 . .
    H H13C 0.625814 0.219443 0.729424 0.058 Uiso calc 1 . .
    C C14 0.5803(6) 0.3216(6) 0.9844(5) 0.0501(13) Uani d 1 . .
    H H14A 0.494379 0.277179 0.966431 0.075 Uiso calc 1 . .
    H H14B 0.579953 0.406942 1.023851 0.075 Uiso calc 1 . .
    H H14C 0.654042 0.268085 1.043360 0.075 Uiso calc 1 . .
    C C21 0.6496(4) 0.6618(3) 0.6930(3) 0.0279(7) Uani d 1 . .
    C C22 0.5483(5) 0.6960(5) 0.5744(4) 0.0425(10) Uani d 1 . .
    H H22 0.539718 0.649794 0.498588 0.051 Uiso calc 1 . .
    C C23 0.4595(6) 0.7987(7) 0.5682(6) 0.0594(16) Uani d 1 . .
    H H23 0.390870 0.820909 0.487518 0.071 Uiso calc 1 . .
    C C24 0.4694(5) 0.8671(5) 0.6747(6) 0.0469(11) Uani d 1 . .
    H H24 0.408025 0.935960 0.668760 0.056 Uiso calc 1 . .
    C C25 0.5712(5) 0.8348(5) 0.7930(5) 0.0372(8) Uani d 1 . .
    H H25 0.579600 0.882142 0.868150 0.045 Uiso calc 1 . .
    C C26 0.6603(4) 0.7334(4) 0.8012(4) 0.0308(7) Uani d 1 . .
    H H26 0.729624 0.712896 0.882019 0.037 Uiso calc 1 . .
    C C30A 0.1255(9) 0.5103(11) 0.4280(8) 0.086(3) Uani d 0.5 A 1
    H H30C 0.160640 0.586709 0.485441 0.103 Uiso calc 0.5 A 1
    H H30A 0.029108 0.526078 0.374882 0.103 Uiso calc 0.5 A 1
    Cl Cl1A 0.2146(3) 0.4929(2) 0.3278(2) 0.0790(6) Uani d 0.5 A 1
    Cl Cl2B 0.1425(3) 0.3690(3) 0.5204(3) 0.0674(8) Uani d 0.6 A 1
    C C30B 0.1255(9) 0.5103(11) 0.4280(8) 0.086(3) Uani d 0.5 B 2
    H H30D 0.032076 0.537089 0.374507 0.103 Uiso calc 0.5 B 2
    H H30B 0.121215 0.423883 0.465898 0.103 Uiso calc 0.5 B 2
    Cl Cl1B 0.2146(3) 0.4929(2) 0.3278(2) 0.0790(6) Uani d 0.5 B 2
    Cl Cl2C 0.1919(5) 0.6201(4) 0.5491(4) 0.0680(11) Uani d 0.4 B 2
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Fe1 C1 . 2.025(3) ?
    Fe1 C6 . 2.030(5) ?
    Fe1 C7 . 2.034(5) ?
    Fe1 C8 . 2.037(4) ?
    Fe1 C5 . 2.037(4) ?
    Fe1 C10 . 2.038(5) ?
    Fe1 C9 . 2.041(5) ?
    Fe1 C2 . 2.043(3) ?
    Fe1 C4 . 2.048(4) ?
    Fe1 C3 . 2.055(4) ?
    N1 C12 . 1.488(6) ?
    N1 C13 . 1.489(5) ?
    N1 C14 . 1.500(6) ?
    N1 C11 . 1.529(5) ?
    C1 C5 . 1.435(5) ?
    C1 C2 . 1.449(5) ?
    C1 C11 . 1.495(5) ?
    C2 C3 . 1.435(5) ?
    C2 C21 . 1.465(5) ?
    C3 C4 . 1.433(7) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.412(6) ?
    C4 H4 . 0.9500 ?
    C5 H5 . 0.9500 ?
    C6 C10 . 1.400(10) ?
    C6 C7 . 1.422(10) ?
    C6 H6 . 0.9500 ?
    C7 C8 . 1.406(9) ?
    C7 H7 . 0.9500 ?
    C8 C9 . 1.418(9) ?
    C8 H8 . 0.9500 ?
    C9 C10 . 1.411(9) ?
    C9 H9 . 0.9500 ?
    C10 H10 . 0.9500 ?
    C11 H11A . 0.9900 ?
    C11 H11B . 0.9900 ?
    C12 H12A . 0.9800 ?
    C12 H12B . 0.9800 ?
    C12 H12C . 0.9800 ?
    C13 H13A . 0.9800 ?
    C13 H13B . 0.9800 ?
    C13 H13C . 0.9800 ?
    C14 H14A . 0.9800 ?
    C14 H14B . 0.9800 ?
    C14 H14C . 0.9800 ?
    C21 C26 . 1.390(5) ?
    C21 C22 . 1.402(5) ?
    C22 C23 . 1.404(7) ?
    C22 H22 . 0.9500 ?
    C23 C24 . 1.359(9) ?
    C23 H23 . 0.9500 ?
    C24 C25 . 1.398(8) ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.391(6) ?
    C25 H25 . 0.9500 ?
    C26 H26 . 0.9500 ?
    C30A Cl2B . 1.748(11) ?
    C30A Cl1A . 1.758(8) ?
    C30A H30C . 0.9900 ?
    C30A H30A . 0.9900 ?
    C30B Cl2C . 1.695(11) ?
    C30B Cl1B . 1.758(8) ?
    C30B H30D . 0.9900 ?
    C30B H30B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C1 Fe1 C6 . . 108.39(19) ?
    C1 Fe1 C7 . . 119.30(19) ?
    C6 Fe1 C7 . . 41.0(3) ?
    C1 Fe1 C8 . . 153.2(2) ?
    C6 Fe1 C8 . . 68.1(2) ?
    C7 Fe1 C8 . . 40.4(2) ?
    C1 Fe1 C5 . . 41.37(15) ?
    C6 Fe1 C5 . . 126.6(2) ?
    C7 Fe1 C5 . . 106.4(2) ?
    C8 Fe1 C5 . . 117.9(2) ?
    C1 Fe1 C10 . . 127.2(2) ?
    C6 Fe1 C10 . . 40.3(3) ?
    C7 Fe1 C10 . . 68.5(3) ?
    C8 Fe1 C10 . . 68.3(2) ?
    C5 Fe1 C10 . . 164.6(2) ?
    C1 Fe1 C9 . . 164.8(2) ?
    C6 Fe1 C9 . . 67.8(3) ?
    C7 Fe1 C9 . . 68.3(2) ?
    C8 Fe1 C9 . . 40.7(2) ?
    C5 Fe1 C9 . . 152.8(2) ?
    C10 Fe1 C9 . . 40.5(3) ?
    C1 Fe1 C2 . . 41.75(14) ?
    C6 Fe1 C2 . . 120.6(2) ?
    C7 Fe1 C2 . . 155.2(2) ?
    C8 Fe1 C2 . . 163.3(2) ?
    C5 Fe1 C2 . . 69.89(15) ?
    C10 Fe1 C2 . . 108.24(19) ?
    C9 Fe1 C2 . . 126.2(2) ?
    C1 Fe1 C4 . . 68.89(16) ?
    C6 Fe1 C4 . . 163.1(3) ?
    C7 Fe1 C4 . . 124.6(2) ?
    C8 Fe1 C4 . . 106.3(2) ?
    C5 Fe1 C4 . . 40.44(18) ?
    C10 Fe1 C4 . . 154.4(3) ?
    C9 Fe1 C4 . . 119.1(2) ?
    C2 Fe1 C4 . . 69.31(16) ?
    C1 Fe1 C3 . . 69.09(15) ?
    C6 Fe1 C3 . . 155.3(2) ?
    C7 Fe1 C3 . . 162.3(2) ?
    C8 Fe1 C3 . . 125.5(2) ?
    C5 Fe1 C3 . . 68.75(18) ?
    C10 Fe1 C3 . . 120.5(2) ?
    C9 Fe1 C3 . . 107.8(2) ?
    C2 Fe1 C3 . . 40.99(14) ?
    C4 Fe1 C3 . . 40.88(19) ?
    C12 N1 C13 . . 108.7(4) ?
    C12 N1 C14 . . 110.2(4) ?
    C13 N1 C14 . . 108.1(4) ?
    C12 N1 C11 . . 110.9(3) ?
    C13 N1 C11 . . 111.6(3) ?
    C14 N1 C11 . . 107.2(3) ?
    C5 C1 C2 . . 108.2(3) ?
    C5 C1 C11 . . 124.2(3) ?
    C2 C1 C11 . . 127.5(3) ?
    C5 C1 Fe1 . . 69.8(2) ?
    C2 C1 Fe1 . . 69.78(19) ?
    C11 C1 Fe1 . . 123.7(2) ?
    C3 C2 C1 . . 106.7(3) ?
    C3 C2 C21 . . 125.2(3) ?
    C1 C2 C21 . . 127.9(3) ?
    C3 C2 Fe1 . . 70.0(2) ?
    C1 C2 Fe1 . . 68.47(19) ?
    C21 C2 Fe1 . . 129.6(3) ?
    C4 C3 C2 . . 108.4(4) ?
    C4 C3 Fe1 . . 69.3(2) ?
    C2 C3 Fe1 . . 69.0(2) ?
    C4 C3 H3 . . 125.8 ?
    C2 C3 H3 . . 125.8 ?
    Fe1 C3 H3 . . 127.5 ?
    C5 C4 C3 . . 108.6(3) ?
    C5 C4 Fe1 . . 69.4(2) ?
    C3 C4 Fe1 . . 69.8(2) ?
    C5 C4 H4 . . 125.7 ?
    C3 C4 H4 . . 125.7 ?
    Fe1 C4 H4 . . 126.7 ?
    C4 C5 C1 . . 108.1(4) ?
    C4 C5 Fe1 . . 70.2(2) ?
    C1 C5 Fe1 . . 68.9(2) ?
    C4 C5 H5 . . 126.0 ?
    C1 C5 H5 . . 126.0 ?
    Fe1 C5 H5 . . 126.5 ?
    C10 C6 C7 . . 108.7(5) ?
    C10 C6 Fe1 . . 70.2(3) ?
    C7 C6 Fe1 . . 69.7(3) ?
    C10 C6 H6 . . 125.7 ?
    C7 C6 H6 . . 125.7 ?
    Fe1 C6 H6 . . 126.0 ?
    C8 C7 C6 . . 107.3(5) ?
    C8 C7 Fe1 . . 69.9(3) ?
    C6 C7 Fe1 . . 69.3(3) ?
    C8 C7 H7 . . 126.4 ?
    C6 C7 H7 . . 126.4 ?
    Fe1 C7 H7 . . 126.0 ?
    C7 C8 C9 . . 108.2(5) ?
    C7 C8 Fe1 . . 69.7(3) ?
    C9 C8 Fe1 . . 69.8(3) ?
    C7 C8 H8 . . 125.9 ?
    C9 C8 H8 . . 125.9 ?
    Fe1 C8 H8 . . 126.2 ?
    C10 C9 C8 . . 108.0(5) ?
    C10 C9 Fe1 . . 69.7(3) ?
    C8 C9 Fe1 . . 69.5(3) ?
    C10 C9 H9 . . 126.0 ?
    C8 C9 H9 . . 126.0 ?
    Fe1 C9 H9 . . 126.4 ?
    C6 C10 C9 . . 107.8(5) ?
    C6 C10 Fe1 . . 69.6(3) ?
    C9 C10 Fe1 . . 69.9(3) ?
    C6 C10 H10 . . 126.1 ?
    C9 C10 H10 . . 126.1 ?
    Fe1 C10 H10 . . 126.1 ?
    C1 C11 N1 . . 114.3(3) ?
    C1 C11 H11A . . 108.7 ?
    N1 C11 H11A . . 108.7 ?
    C1 C11 H11B . . 108.7 ?
    N1 C11 H11B . . 108.7 ?
    H11A C11 H11B . . 107.6 ?
    N1 C12 H12A . . 109.5 ?
    N1 C12 H12B . . 109.5 ?
    H12A C12 H12B . . 109.5 ?
    N1 C12 H12C . . 109.5 ?
    H12A C12 H12C . . 109.5 ?
    H12B C12 H12C . . 109.5 ?
    N1 C13 H13A . . 109.5 ?
    N1 C13 H13B . . 109.5 ?
    H13A C13 H13B . . 109.5 ?
    N1 C13 H13C . . 109.5 ?
    H13A C13 H13C . . 109.5 ?
    H13B C13 H13C . . 109.5 ?
    N1 C14 H14A . . 109.5 ?
    N1 C14 H14B . . 109.5 ?
    H14A C14 H14B . . 109.5 ?
    N1 C14 H14C . . 109.5 ?
    H14A C14 H14C . . 109.5 ?
    H14B C14 H14C . . 109.5 ?
    C26 C21 C22 . . 118.3(4) ?
    C26 C21 C2 . . 123.4(3) ?
    C22 C21 C2 . . 118.3(4) ?
    C21 C22 C23 . . 119.8(4) ?
    C21 C22 H22 . . 120.1 ?
    C23 C22 H22 . . 120.1 ?
    C24 C23 C22 . . 121.6(5) ?
    C24 C23 H23 . . 119.2 ?
    C22 C23 H23 . . 119.2 ?
    C23 C24 C25 . . 119.0(4) ?
    C23 C24 H24 . . 120.5 ?
    C25 C24 H24 . . 120.5 ?
    C26 C25 C24 . . 120.3(4) ?
    C26 C25 H25 . . 119.9 ?
    C24 C25 H25 . . 119.9 ?
    C21 C26 C25 . . 121.1(4) ?
    C21 C26 H26 . . 119.5 ?
    C25 C26 H26 . . 119.5 ?
    Cl2B C30A Cl1A . . 110.2(5) ?
    Cl2B C30A H30C . . 109.6 ?
    Cl1A C30A H30C . . 109.6 ?
    Cl2B C30A H30A . . 109.6 ?
    Cl1A C30A H30A . . 109.6 ?
    H30C C30A H30A . . 108.1 ?
    Cl2C C30B Cl1B . . 114.9(7) ?
    Cl2C C30B H30D . . 113.2 ?
    Cl1B C30B H30D . . 109.6 ?
    Cl2C C30B H30B . . 108.5 ?
    Cl1B C30B H30B . . 108.5 ?
    H30D C30B H30B . . 101.0 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    N1 C11 C1 C2 . . . . 92.4(4) ?
    N1 C11 C1 C5 . . . . -91.2(4) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    C11 H11A I1 2_657 0.99 3.17 3.988(4) 140.4 yes
    C12 H12C I1 . 0.98 3.21 4.117(5) 154.3 yes
    C12 H12B Cl2C . 0.98 3.51 3.787(7) 98.9 yes
    C13 H13A I1 . 0.98 3.27 4.158(5) 151.4 yes
    C14 H14A I1 . 0.98 3.14 4.057(5) 156.9 yes
    C14 H14B I1 2_657 0.98 3.25 4.077(5) 143.0 yes
    C30A H30A I1 2_556 1.00 2.89 3.867(7) 165.8 yes
    C13 H13B CT2 2_747 0.98 2.98 3.901(6) 157.7 yes
    C23 H23 CT1 2_656 0.95 2.69 3.600(7) 160.4 yes
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.553
_shelx_estimated_absorpt_T_max     0.807
data_global
_journal_date_recd_electronic     2022-01-24
_journal_date_accepted     2022-06-07
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2022
_journal_volume     78
_journal_issue      7
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     GM
_journal_paper_doi     10.1107/S2056989022006053
_journal_coeditor_code     DJ2043
_publ_contact_author_name     'Jean-Claude Daran'
_publ_contact_author_address
;
CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse,
UPS, INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
;
_publ_contact_author_email     'jean-claude.daran@lcc-toulouse.fr'
_publ_contact_author_fax     ' + 33 5 61 55 30 03'
_publ_contact_author_phone     '+ 33 5 61 33 31 74'
_publ_section_title
;
Synthesis and crystal structure of
[(Sₚ)-(2-phenylferrocenyl)methyl]trimethylammonium iodide
dichloromethane monosolvate
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_address
    'Lachguar, Abdelhak'
;
CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse,
UPS,INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
IUT A Paul Sabatier, de Chimie, Avenue Georges Pompidou, CS 20258, F-81104
Castres Cedex, France
;
    'Deydier, Eric'
;
CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse,
UPS,INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
IUT A Paul Sabatier, de Chimie, Avenue Georges Pompidou, CS 20258, F-81104
Castres Cedex, France
;
    'Labande, Agnès'
;
CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse,
UPS,INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
;
    'Manoury, Eric'
;
CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse,
UPS,INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
;
    'Poli, Rinaldo'
;
CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse,
UPS,INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
;
    'Daran, Jean-Claude'
;
CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse,
UPS,INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
;
_publ_section_synopsis
;
The packing of the title disubstituted ferrocene derivative is stabilized by
weak C---H...X (X = I, Cl), C---H...π(Cp) and
C---Cl...π(phenyl) interactions, building a three-dimensional network. The
cation has planar chirality with Sₚ(Fc) absolute configuration. The
structure of the title compound is compared with related disubstituted
(tri\\u000173methyl\\u000173ammonio)\\u000173methyl ferrocenes.
;
