##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     'SHELXL-2014/7'
_chemical_name_systematic
;\
{O-Ethyl
N-(4-nitrophenyl)thiocarbamato-κS}(tri-4-tolylphosphane-\
κP)gold(I)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C30 H30 Au N2 O3 P S'
_chemical_formula_sum     'C30 H30 Au N2 O3 P S'
_chemical_formula_iupac     '[Au (C9 H9 N2 O3 S) (C21 H21 P)]'
_chemical_formula_weight     726.55
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/c'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     9.8815(6)
_cell_length_b     14.0448(9)
_cell_length_c     21.2332(13)
_cell_angle_alpha     90
_cell_angle_beta     99.924(2)
_cell_angle_gamma     90
_cell_volume     2902.7(3)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     7098
_cell_measurement_theta_min     2.429
_cell_measurement_theta_max     28.221
_cell_measurement_temperature     223(2)
_exptl_crystal_description     block
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.270
_exptl_crystal_size_mid     0.120
_exptl_crystal_size_min     0.110
_exptl_crystal_density_diffrn     1.663
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1432
_exptl_absorpt_coefficient_mu     5.229
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2000)
;
_shelx_estimated_absorpt_T_min     0.333
_shelx_estimated_absorpt_T_max     0.597
_exptl_absorpt_correction_T_min     0.421
_exptl_absorpt_correction_T_max     1
_diffrn_ambient_temperature     223(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker AXS SMART CCD'
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     23909
_diffrn_reflns_av_R_equivalents     0.0399
_diffrn_reflns_theta_min     1.947
_diffrn_reflns_theta_max     29.971
_diffrn_reflns_theta_full     25.240
_diffrn_measured_fraction_theta_max     0.998
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -10
_diffrn_reflns_limit_h_max     13
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     19
_diffrn_reflns_limit_l_min     -29
_diffrn_reflns_limit_l_max     19
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     0
_refine_special_details
;
;
_reflns_number_total     8412
_reflns_number_gt     6748
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0429
_refine_ls_R_factor_gt     0.0307
_refine_ls_wR_factor_gt     0.0724
_refine_ls_wR_factor_ref     0.0780
_refine_ls_goodness_of_fit_ref     0.947
_refine_ls_restrained_S_all     0.947
_refine_ls_number_reflns     8412
_refine_ls_number_parameters     347
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                      'w=1/[σ²(Fo²)+(0.0423P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.002
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.159
_refine_diff_density_min     -0.784
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
SMART (Bruker, 2000)
;
_computing_cell_refinement
;
SAINT (Bruker, 2000)
;
_computing_data_reduction
;
SAINT (Bruker, 2000)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014/7 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
ORTEP-3 for Windows (Farrugia, 2012),  DIAMOND (Brandenburg,
2006)
and QMol (Gans & Shalloway, 2001)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au 0.12283(2) 0.07759(2) 0.34429(2) 0.03271(5) Uani d 1 . .
    S S1 0.18283(10) -0.03609(6) 0.42279(4) 0.03903(18) Uani d 1 . .
    P P1 0.06779(8) 0.19705(6) 0.27309(4) 0.03035(16) Uani d 1 . .
    O O1 0.1276(2) 0.12051(16) 0.47896(10) 0.0395(5) Uani d 1 . .
    O O2 0.6243(3) -0.3434(2) 0.61518(16) 0.0661(8) Uani d 1 . .
    O O3 0.4384(3) -0.3994(2) 0.63774(18) 0.0711(9) Uani d 1 . .
    N N1 0.2402(3) 0.0118(2) 0.54778(13) 0.0419(7) Uani d 1 . .
    N N2 0.5036(3) -0.3355(2) 0.61897(15) 0.0451(7) Uani d 1 . .
    C C1 0.1877(3) 0.0344(2) 0.49148(15) 0.0343(6) Uani d 1 . .
    C C2 0.3048(4) -0.0766(2) 0.56273(15) 0.0368(7) Uani d 1 . .
    C C3 0.2308(4) -0.1524(3) 0.58156(18) 0.0461(8) Uani d 1 . .
    H H3 0.1361 -0.1459 0.5815 0.055 Uiso calc 1 . .
    C C4 0.2960(4) -0.2371(3) 0.60035(19) 0.0473(9) Uani d 1 . .
    H H4 0.2462 -0.2887 0.6129 0.057 Uiso calc 1 . .
    C C5 0.4348(3) -0.2452(2) 0.60053(15) 0.0356(7) Uani d 1 . .
    C C6 0.5105(3) -0.1700(3) 0.58361(17) 0.0422(8) Uani d 1 . .
    H H6 0.6056 -0.1763 0.5848 0.051 Uiso calc 1 . .
    C C7 0.4448(4) -0.0855(2) 0.56491(19) 0.0449(8) Uani d 1 . .
    H H7 0.4956 -0.0335 0.5536 0.054 Uiso calc 1 . .
    C C8 0.1369(4) 0.1857(3) 0.53290(17) 0.0505(10) Uani d 1 . .
    H H8A 0.1311 0.1498 0.5719 0.061 Uiso calc 1 . .
    H H8B 0.0599 0.2307 0.5254 0.061 Uiso calc 1 . .
    C C9 0.2709(5) 0.2398(3) 0.5413(2) 0.0596(11) Uani d 1 . .
    H H9A 0.3469 0.1951 0.5477 0.089 Uiso calc 1 . .
    H H9B 0.2776 0.2812 0.5783 0.089 Uiso calc 1 . .
    H H9C 0.2744 0.2777 0.5035 0.089 Uiso calc 1 . .
    C C10 -0.0001(3) 0.2979(2) 0.31120(14) 0.0312(6) Uani d 1 . .
    C C11 0.0534(4) 0.3172(3) 0.37427(16) 0.0419(8) Uani d 1 . .
    H H11 0.1214 0.2772 0.3967 0.050 Uiso calc 1 . .
    C C12 0.0079(4) 0.3948(3) 0.40474(17) 0.0483(9) Uani d 1 . .
    H H12 0.0464 0.4074 0.4476 0.058 Uiso calc 1 . .
    C C13 -0.0930(4) 0.4540(3) 0.37347(17) 0.0416(8) Uani d 1 . .
    C C14 -0.1455(4) 0.4348(2) 0.31043(18) 0.0457(8) Uani d 1 . .
    H H14 -0.2145 0.4742 0.2882 0.055 Uiso calc 1 . .
    C C15 -0.0986(4) 0.3585(2) 0.27939(16) 0.0410(7) Uani d 1 . .
    H H15 -0.1342 0.3476 0.2360 0.049 Uiso calc 1 . .
    C C16 -0.1475(5) 0.5364(3) 0.4073(2) 0.0593(11) Uani d 1 . .
    H H16A -0.2063 0.5125 0.4359 0.089 Uiso calc 1 . .
    H H16B -0.2001 0.5785 0.3760 0.089 Uiso calc 1 . .
    H H16C -0.0713 0.5713 0.4317 0.089 Uiso calc 1 . .
    C C17 0.2135(3) 0.2461(2) 0.24238(14) 0.0326(6) Uani d 1 . .
    C C18 0.2127(4) 0.3395(3) 0.22013(16) 0.0411(7) Uani d 1 . .
    H H18 0.1349 0.3781 0.2203 0.049 Uiso calc 1 . .
    C C19 0.3248(4) 0.3757(3) 0.19790(17) 0.0475(9) Uani d 1 . .
    H H19 0.3227 0.4387 0.1827 0.057 Uiso calc 1 . .
    C C20 0.4419(4) 0.3201(3) 0.19754(17) 0.0509(9) Uani d 1 . .
    C C21 0.4425(4) 0.2289(3) 0.21997(18) 0.0529(10) Uani d 1 . .
    H H21 0.5205 0.1907 0.2198 0.063 Uiso calc 1 . .
    C C22 0.3299(3) 0.1914(3) 0.24308(16) 0.0428(8) Uani d 1 . .
    H H22 0.3332 0.1289 0.2591 0.051 Uiso calc 1 . .
    C C23 0.5626(4) 0.3616(4) 0.1716(2) 0.0784(15) Uani d 1 . .
    H H23A 0.6203 0.3104 0.1608 0.118 Uiso calc 1 . .
    H H23B 0.6156 0.4021 0.2038 0.118 Uiso calc 1 . .
    H H23C 0.5292 0.3989 0.1337 0.118 Uiso calc 1 . .
    C C24 -0.0624(3) 0.1663(2) 0.20533(14) 0.0314(6) Uani d 1 . .
    C C25 -0.0789(4) 0.2143(3) 0.14741(15) 0.0403(7) Uani d 1 . .
    H H25 -0.0181 0.2635 0.1413 0.048 Uiso calc 1 . .
    C C26 -0.1852(4) 0.1897(3) 0.09838(17) 0.0477(9) Uani d 1 . .
    H H26 -0.1966 0.2236 0.0597 0.057 Uiso calc 1 . .
    C C27 -0.2745(4) 0.1164(3) 0.10531(17) 0.0447(8) Uani d 1 . .
    C C28 -0.2578(4) 0.0687(3) 0.1635(2) 0.0516(10) Uani d 1 . .
    H H28 -0.3182 0.0190 0.1693 0.062 Uiso calc 1 . .
    C C29 -0.1533(4) 0.0933(2) 0.21300(17) 0.0416(8) Uani d 1 . .
    H H29 -0.1438 0.0605 0.2521 0.050 Uiso calc 1 . .
    C C30 -0.3886(6) 0.0899(3) 0.0519(2) 0.0748(15) Uani d 1 . .
    H H30A -0.4521 0.1428 0.0430 0.112 Uiso calc 1 . .
    H H30B -0.4370 0.0348 0.0644 0.112 Uiso calc 1 . .
    H H30C -0.3506 0.0749 0.0139 0.112 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au P1 . 2.2611(8) y
    Au S1 . 2.3105(8) y
    S1 C1 . 1.756(3) y
    P1 C10 . 1.816(3) ?
    P1 C24 . 1.809(3) ?
    P1 C17 . 1.815(3) ?
    O1 C1 . 1.354(4) ?
    O1 C8 . 1.457(4) ?
    O2 N2 . 1.215(4) ?
    O3 N2 . 1.211(4) ?
    N1 C1 . 1.259(4) y
    N1 C2 . 1.407(4) ?
    N2 C5 . 1.460(4) ?
    C2 C7 . 1.381(5) ?
    C2 C3 . 1.389(5) ?
    C3 C4 . 1.379(5) ?
    C3 H3 . 0.9400 ?
    C4 C5 . 1.375(5) ?
    C4 H4 . 0.9400 ?
    C5 C6 . 1.377(5) ?
    C6 C7 . 1.379(5) ?
    C6 H6 . 0.9400 ?
    C7 H7 . 0.9400 ?
    C8 C9 . 1.510(6) ?
    C8 H8A . 0.9800 ?
    C8 H8B . 0.9800 ?
    C9 H9A . 0.9700 ?
    C9 H9B . 0.9700 ?
    C9 H9C . 0.9700 ?
    C10 C11 . 1.379(4) ?
    C10 C15 . 1.378(4) ?
    C11 C12 . 1.382(5) ?
    C11 H11 . 0.9400 ?
    C12 C13 . 1.378(6) ?
    C12 H12 . 0.9400 ?
    C13 C14 . 1.377(5) ?
    C13 C16 . 1.510(5) ?
    C14 C15 . 1.380(5) ?
    C14 H14 . 0.9400 ?
    C15 H15 . 0.9400 ?
    C16 H16A . 0.9700 ?
    C16 H16B . 0.9700 ?
    C16 H16C . 0.9700 ?
    C17 C22 . 1.382(5) ?
    C17 C18 . 1.395(5) ?
    C18 C19 . 1.374(5) ?
    C18 H18 . 0.9400 ?
    C19 C20 . 1.397(6) ?
    C19 H19 . 0.9400 ?
    C20 C21 . 1.366(6) ?
    C20 C23 . 1.514(5) ?
    C21 C22 . 1.395(5) ?
    C21 H21 . 0.9400 ?
    C22 H22 . 0.9400 ?
    C23 H23A . 0.9700 ?
    C23 H23B . 0.9700 ?
    C23 H23C . 0.9700 ?
    C24 C29 . 1.391(5) ?
    C24 C25 . 1.387(4) ?
    C25 C26 . 1.389(5) ?
    C25 H25 . 0.9400 ?
    C26 C27 . 1.379(5) ?
    C26 H26 . 0.9400 ?
    C27 C28 . 1.391(5) ?
    C27 C30 . 1.502(5) ?
    C28 C29 . 1.384(5) ?
    C28 H28 . 0.9400 ?
    C29 H29 . 0.9400 ?
    C30 H30A . 0.9700 ?
    C30 H30B . 0.9700 ?
    C30 H30C . 0.9700 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    P1 Au S1 . . 175.80(3) y
    C1 S1 Au . . 100.18(11) y
    C10 P1 C24 . . 105.90(14) ?
    C10 P1 C17 . . 103.93(14) ?
    C24 P1 C17 . . 107.71(14) ?
    C10 P1 Au . . 110.22(10) ?
    C24 P1 Au . . 114.24(10) ?
    C17 P1 Au . . 114.04(10) ?
    C1 O1 C8 . . 116.2(2) ?
    C1 N1 C2 . . 122.2(3) ?
    O3 N2 O2 . . 122.5(3) ?
    O3 N2 C5 . . 118.8(3) ?
    O2 N2 C5 . . 118.6(3) ?
    N1 C1 O1 . . 120.4(3) ?
    N1 C1 S1 . . 126.5(3) ?
    O1 C1 S1 . . 113.1(2) ?
    C7 C2 N1 . . 120.0(3) ?
    C7 C2 C3 . . 119.7(3) ?
    N1 C2 C3 . . 120.0(3) ?
    C4 C3 C2 . . 120.1(3) ?
    C4 C3 H3 . . 120.0 ?
    C2 C3 H3 . . 120.0 ?
    C3 C4 C5 . . 119.2(3) ?
    C3 C4 H4 . . 120.4 ?
    C5 C4 H4 . . 120.4 ?
    C6 C5 C4 . . 121.5(3) ?
    C6 C5 N2 . . 119.1(3) ?
    C4 C5 N2 . . 119.4(3) ?
    C5 C6 C7 . . 119.0(3) ?
    C5 C6 H6 . . 120.5 ?
    C7 C6 H6 . . 120.5 ?
    C6 C7 C2 . . 120.4(3) ?
    C6 C7 H7 . . 119.8 ?
    C2 C7 H7 . . 119.8 ?
    O1 C8 C9 . . 110.2(3) ?
    O1 C8 H8A . . 109.6 ?
    C9 C8 H8A . . 109.6 ?
    O1 C8 H8B . . 109.6 ?
    C9 C8 H8B . . 109.6 ?
    H8A C8 H8B . . 108.1 ?
    C8 C9 H9A . . 109.5 ?
    C8 C9 H9B . . 109.5 ?
    H9A C9 H9B . . 109.5 ?
    C8 C9 H9C . . 109.5 ?
    H9A C9 H9C . . 109.5 ?
    H9B C9 H9C . . 109.5 ?
    C11 C10 C15 . . 118.3(3) ?
    C11 C10 P1 . . 118.5(2) ?
    C15 C10 P1 . . 123.1(2) ?
    C12 C11 C10 . . 120.5(3) ?
    C12 C11 H11 . . 119.7 ?
    C10 C11 H11 . . 119.7 ?
    C13 C12 C11 . . 121.2(3) ?
    C13 C12 H12 . . 119.4 ?
    C11 C12 H12 . . 119.4 ?
    C12 C13 C14 . . 118.0(3) ?
    C12 C13 C16 . . 121.4(3) ?
    C14 C13 C16 . . 120.5(4) ?
    C15 C14 C13 . . 121.0(3) ?
    C15 C14 H14 . . 119.5 ?
    C13 C14 H14 . . 119.5 ?
    C14 C15 C10 . . 120.8(3) ?
    C14 C15 H15 . . 119.6 ?
    C10 C15 H15 . . 119.6 ?
    C13 C16 H16A . . 109.5 ?
    C13 C16 H16B . . 109.5 ?
    H16A C16 H16B . . 109.5 ?
    C13 C16 H16C . . 109.5 ?
    H16A C16 H16C . . 109.5 ?
    H16B C16 H16C . . 109.5 ?
    C22 C17 C18 . . 118.9(3) ?
    C22 C17 P1 . . 119.7(3) ?
    C18 C17 P1 . . 121.3(2) ?
    C17 C18 C19 . . 120.4(3) ?
    C17 C18 H18 . . 119.8 ?
    C19 C18 H18 . . 119.8 ?
    C18 C19 C20 . . 120.9(4) ?
    C18 C19 H19 . . 119.6 ?
    C20 C19 H19 . . 119.6 ?
    C21 C20 C19 . . 118.4(3) ?
    C21 C20 C23 . . 122.1(4) ?
    C19 C20 C23 . . 119.5(4) ?
    C20 C21 C22 . . 121.4(4) ?
    C20 C21 H21 . . 119.3 ?
    C22 C21 H21 . . 119.3 ?
    C17 C22 C21 . . 119.9(4) ?
    C17 C22 H22 . . 120.0 ?
    C21 C22 H22 . . 120.0 ?
    C20 C23 H23A . . 109.5 ?
    C20 C23 H23B . . 109.5 ?
    H23A C23 H23B . . 109.5 ?
    C20 C23 H23C . . 109.5 ?
    H23A C23 H23C . . 109.5 ?
    H23B C23 H23C . . 109.5 ?
    C29 C24 C25 . . 118.8(3) ?
    C29 C24 P1 . . 117.9(2) ?
    C25 C24 P1 . . 123.2(2) ?
    C26 C25 C24 . . 120.1(3) ?
    C26 C25 H25 . . 119.9 ?
    C24 C25 H25 . . 119.9 ?
    C27 C26 C25 . . 121.4(3) ?
    C27 C26 H26 . . 119.3 ?
    C25 C26 H26 . . 119.3 ?
    C26 C27 C28 . . 118.3(3) ?
    C26 C27 C30 . . 121.0(4) ?
    C28 C27 C30 . . 120.6(4) ?
    C29 C28 C27 . . 120.9(3) ?
    C29 C28 H28 . . 119.6 ?
    C27 C28 H28 . . 119.6 ?
    C28 C29 C24 . . 120.5(3) ?
    C28 C29 H29 . . 119.8 ?
    C24 C29 H29 . . 119.8 ?
    C27 C30 H30A . . 109.5 ?
    C27 C30 H30B . . 109.5 ?
    H30A C30 H30B . . 109.5 ?
    C27 C30 H30C . . 109.5 ?
    H30A C30 H30C . . 109.5 ?
    H30B C30 H30C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C2 N1 C1 O1 . . . . -179.4(3) ?
    C2 N1 C1 S1 . . . . 0.4(5) ?
    C8 O1 C1 N1 . . . . 4.3(5) ?
    C8 O1 C1 S1 . . . . -175.5(3) ?
    Au S1 C1 N1 . . . . -165.6(3) ?
    Au S1 C1 O1 . . . . 14.2(2) ?
    C1 N1 C2 C7 . . . . 92.7(4) ?
    C1 N1 C2 C3 . . . . -93.8(4) ?
    C7 C2 C3 C4 . . . . -2.1(6) ?
    N1 C2 C3 C4 . . . . -175.6(3) ?
    C2 C3 C4 C5 . . . . 0.4(6) ?
    C3 C4 C5 C6 . . . . 1.3(6) ?
    C3 C4 C5 N2 . . . . -178.6(3) ?
    O3 N2 C5 C6 . . . . 175.3(4) ?
    O2 N2 C5 C6 . . . . -4.3(5) ?
    O3 N2 C5 C4 . . . . -4.8(5) ?
    O2 N2 C5 C4 . . . . 175.6(4) ?
    C4 C5 C6 C7 . . . . -1.3(5) ?
    N2 C5 C6 C7 . . . . 178.6(3) ?
    C5 C6 C7 C2 . . . . -0.5(6) ?
    N1 C2 C7 C6 . . . . 175.7(3) ?
    C3 C2 C7 C6 . . . . 2.2(6) ?
    C1 O1 C8 C9 . . . . 85.1(4) ?
    C24 P1 C10 C11 . . . . 159.0(3) ?
    C17 P1 C10 C11 . . . . -87.6(3) ?
    Au P1 C10 C11 . . . . 35.0(3) ?
    C24 P1 C10 C15 . . . . -23.7(3) ?
    C17 P1 C10 C15 . . . . 89.6(3) ?
    Au P1 C10 C15 . . . . -147.8(3) ?
    C15 C10 C11 C12 . . . . 0.7(5) ?
    P1 C10 C11 C12 . . . . 178.1(3) ?
    C10 C11 C12 C13 . . . . 0.9(6) ?
    C11 C12 C13 C14 . . . . -1.2(6) ?
    C11 C12 C13 C16 . . . . 177.3(4) ?
    C12 C13 C14 C15 . . . . -0.1(6) ?
    C16 C13 C14 C15 . . . . -178.6(4) ?
    C13 C14 C15 C10 . . . . 1.7(6) ?
    C11 C10 C15 C14 . . . . -2.0(5) ?
    P1 C10 C15 C14 . . . . -179.3(3) ?
    C10 P1 C17 C22 . . . . 143.8(3) ?
    C24 P1 C17 C22 . . . . -104.1(3) ?
    Au P1 C17 C22 . . . . 23.8(3) ?
    C10 P1 C17 C18 . . . . -33.7(3) ?
    C24 P1 C17 C18 . . . . 78.3(3) ?
    Au P1 C17 C18 . . . . -153.8(2) ?
    C22 C17 C18 C19 . . . . 1.5(5) ?
    P1 C17 C18 C19 . . . . 179.1(3) ?
    C17 C18 C19 C20 . . . . -0.5(5) ?
    C18 C19 C20 C21 . . . . -0.2(6) ?
    C18 C19 C20 C23 . . . . 178.9(4) ?
    C19 C20 C21 C22 . . . . -0.2(6) ?
    C23 C20 C21 C22 . . . . -179.3(4) ?
    C18 C17 C22 C21 . . . . -1.9(5) ?
    P1 C17 C22 C21 . . . . -179.5(3) ?
    C20 C21 C22 C17 . . . . 1.3(6) ?
    C10 P1 C24 C29 . . . . -96.7(3) ?
    C17 P1 C24 C29 . . . . 152.6(3) ?
    Au P1 C24 C29 . . . . 24.8(3) ?
    C10 P1 C24 C25 . . . . 80.7(3) ?
    C17 P1 C24 C25 . . . . -30.0(3) ?
    Au P1 C24 C25 . . . . -157.8(3) ?
    C29 C24 C25 C26 . . . . 0.4(5) ?
    P1 C24 C25 C26 . . . . -177.0(3) ?
    C24 C25 C26 C27 . . . . -1.4(6) ?
    C25 C26 C27 C28 . . . . 1.5(6) ?
    C25 C26 C27 C30 . . . . -179.6(4) ?
    C26 C27 C28 C29 . . . . -0.7(6) ?
    C30 C27 C28 C29 . . . . -179.5(4) ?
    C27 C28 C29 C24 . . . . -0.3(6) ?
    C25 C24 C29 C28 . . . . 0.5(5) ?
    P1 C24 C29 C28 . . . . 177.9(3) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C4 H4 Cg1 3_556 0.94 2.64 3.528(4) 157
    N2 O2 Cg2 3_656 1.215(4) 3.547(4) 83.1(2) 3.608(3)
    N2 O3 Cg2 3_656 1.211(4) 3.833(4) 70.2(2) 3.608(3)
data_global
_journal_date_recd_electronic     2017-09-06
_journal_date_accepted     2017-09-07
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2017
_journal_volume     73
_journal_issue     10
_journal_page_first     1465
_journal_page_last     1471
_journal_paper_category     GM
_journal_paper_doi     10.1107/S2056989017012865
_journal_coeditor_code     HB7703
loop_
    _publ_contact_author_name
    _publ_contact_author_address
    _publ_contact_author_email
    'Edward R. T. Tiekink'
;
Research Centre for Crystalline Materials,
School of Science and Technology,
Sunway University,
No.5 Jalan Universiti,
47500 Bandar Sunway,
Selangor Darul Ehsan, Malaysia
;
 edwardt@sunway.edu.my
_publ_contact_author_fax     ' +60 3 7491 8633 '
_publ_contact_author_phone     ' +60 3 7491 7173 '
_publ_section_title
;\
New monoclinic form of {O-Ethyl
N-(4-nitrophenyl)thiocarbamato-κS}(tri-4-tolylphosphane-\
κP)gold(I): crystal structure and Hirshfeld surface analysis
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Kuan, Fong Sheen' .
;
Department of Chemistry,
National University of Singapore, Singapore 117543
;
    ' Jotani, Mukesh M. '
;
Additional correspondence author, e-mail: mmjotani@rediffmail.com.
;
;
Department of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad,
Gujarat 380001, India
;
    'Tiekink, Edward R. T.' .
;
Research Centre for Crystalline Materials,
School of Science and Technology,
Sunway University, 47500 Bandar Sunway,
Selangor Darul Ehsan, Malaysia
;
_publ_section_synopsis
;
A linear SP coordination geometry for the gold atom is found in the title
structure, which also features a short intramolecular Au...O interaction, in
contrast to a Au...π interaction found in the first polymorph.
;
