##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
_journal_date_recd_electronic     2017-03-09
_journal_date_accepted     2017-03-17
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2017
_journal_volume     73
_journal_issue      4
_journal_page_first     573
_journal_page_last     578
_journal_paper_category     GM
_journal_paper_doi     10.1107/S2056989017004285
_journal_coeditor_code     RZ5208
_publ_contact_author_name     'Luc Van Meervelt'
_publ_contact_author_address
;
Department of Chemistry
KU Leuven
Biomolecular Architecture, Celestijnenlaan 200F
Leuven (Heverlee)
B-3001
Belgium
;
_publ_contact_author_email     luc.vanmeervelt@kuleuven.be
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;
Crystal structures of two platinum(II) complexes containing ethyl
eugenoxyacetate and 2-aminopyridine
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Le Thi Hong, Hai' .
;
Department of Chemistry
Hanoi National University of Education
136 Xuan Thuy
Cau Giay
Hanoi
Vietnam
;
    'Nguyen Thu, Thao' .
;
Department of Chemistry
Hanoi National University of Education
136 Xuan Thuy
Cau Giay
Hanoi
Vietnam
;
    'Nguyen, Hien' .
;
Department of Chemistry
Hanoi National University of Education
136 Xuan Thuy
Cau Giay
Hanoi
Vietnam
;
    'Van Meervelt, Luc' .
;
Department of Chemistry
KU Leuven
Biomolecular Architecture, Celestijnenlaan 200F
Leuven (Heverlee)
B-3001
Belgium
;
_publ_section_synopsis
;
The synthesis and crystal structures of two platinum(II) complexes containing
one or two Cl atoms, an eugenol derivative and 2-aminopyridine as ligand are
described. The central PtII atom displays a distorted square-planar
coordination.
;
_chemical_name_systematic
;\
trans-(2-Aminopyridine-κN)dichlorido{4-ethoxycarbonylmethoxy-\
3-methoxy-1-[(2,3-η)-prop-2-en-1-yl]benzene}platinum(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C19 H24 Cl2 N2 O4 Pt'
_chemical_formula_sum     'C19 H24 Cl2 N2 O4 Pt'
_chemical_formula_iupac     '[Pt Cl2 (C5 H6 N2) (C14 H18 O4)]'
_chemical_formula_weight     610.39
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     triclinic
_space_group_name_H-M_alt     'P -1'
_space_group_name_Hall     '-P 1'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     8.3187(3)
_cell_length_b     11.4119(3)
_cell_length_c     12.1012(4)
_cell_angle_alpha     70.437(3)
_cell_angle_beta     73.688(3)
_cell_angle_gamma     87.038(2)
_cell_volume     1037.76(6)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     13838
_cell_measurement_theta_min     2.7030
_cell_measurement_theta_max     28.9750
_cell_measurement_temperature     100.01(10)
_exptl_crystal_description     block
_exptl_crystal_colour     orange
_exptl_crystal_size_max     0.3
_exptl_crystal_size_mid     0.3
_exptl_crystal_size_min     0.15
_exptl_crystal_density_diffrn     1.953
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     592
_exptl_absorpt_coefficient_mu     7.046
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku Oxford Diffraction, 2015)
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
_exptl_absorpt_correction_T_min     0.40577
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100.01(10)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     mirror
_diffrn_measurement_device_type
      'Agilent SuperNova diffractometer (single source at offset, Eos detector)'
_diffrn_measurement_device     'four-circle diffractometer'
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     15.9631
_diffrn_reflns_number     21329
_diffrn_reflns_av_R_equivalents     0.0516
_diffrn_reflns_theta_min     2.554
_diffrn_reflns_theta_max     26.369
_diffrn_reflns_theta_full     26.000
_diffrn_measured_fraction_theta_max     0.999
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -10
_diffrn_reflns_limit_h_max     10
_diffrn_reflns_limit_k_min     -14
_diffrn_reflns_limit_k_max     14
_diffrn_reflns_limit_l_min     -15
_diffrn_reflns_limit_l_max     15
_refine_special_details     ?
_reflns_number_total     4241
_reflns_number_gt     4006
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0309
_refine_ls_R_factor_gt     0.0287
_refine_ls_wR_factor_gt     0.0631
_refine_ls_wR_factor_ref     0.0646
_refine_ls_goodness_of_fit_ref     1.040
_refine_ls_restrained_S_all     1.047
_refine_ls_number_reflns     4241
_refine_ls_number_parameters     265
_refine_ls_number_restraints     26
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0193P)²+4.6851P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.409
_refine_diff_density_min     -2.245
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
_computing_cell_refinement
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Pt Pt1 0.11518(2) 0.08277(2) 0.62392(2) 0.02167(7) Uani d 1 . .
    N N2 -0.0430(4) 0.0375(3) 0.7993(3) 0.0155(7) Uani d 1 . .
    C C3 -0.0741(5) 0.1198(4) 0.8603(4) 0.0146(8) Uani d 1 . .
    C C4 -0.1797(5) 0.0846(4) 0.9812(4) 0.0170(8) Uani d 1 . .
    H H4 -0.2041 0.1432 1.0232 0.020 Uiso calc 1 . .
    C C5 -0.2465(5) -0.0343(4) 1.0371(4) 0.0205(9) Uani d 1 . .
    H H5 -0.3167 -0.0591 1.1187 0.025 Uiso calc 1 . .
    C C6 -0.2119(6) -0.1198(4) 0.9745(4) 0.0208(9) Uani d 1 . .
    H H6 -0.2573 -0.2030 1.0124 0.025 Uiso calc 1 . .
    C C7 -0.1108(5) -0.0804(4) 0.8570(4) 0.0175(9) Uani d 1 . .
    H H7 -0.0870 -0.1380 0.8139 0.021 Uiso calc 1 . .
    N N8 -0.0004(4) 0.2351(3) 0.8045(3) 0.0174(7) Uani d 1 . .
    H H8A 0.0666 0.2556 0.7296 0.021 Uiso calc 1 . .
    H H8B -0.0193 0.2898 0.8429 0.021 Uiso calc 1 . .
    Cl Cl9 -0.0885(2) 0.20013(13) 0.55243(12) 0.0524(5) Uani d 1 . .
    Cl Cl10 0.30457(16) -0.05058(16) 0.70053(13) 0.0431(4) Uani d 1 . .
    C C11 0.2551(6) 0.0923(4) 0.4411(4) 0.0277(11) Uani d 1 . .
    H H11A 0.1965 0.1311 0.3822 0.033 Uiso calc 0.614(14) A 1
    H H11B 0.2525 0.0041 0.4747 0.033 Uiso calc 0.614(14) A 1
    H H11C 0.3564 0.0494 0.4378 0.033 Uiso calc 0.386(14) A 2
    H H11D 0.1567 0.0527 0.4423 0.033 Uiso calc 0.386(14) A 2
    C C12A 0.3491(9) 0.1682(6) 0.4797(6) 0.023(2) Uani d 0.614(14) A 1
    H H12A 0.4508 0.1263 0.5000 0.028 Uiso calc 0.614(14) A 1
    C C12B 0.2510(13) 0.2166(8) 0.4441(9) 0.017(3) Uani d 0.386(14) A 2
    H H12B 0.1698 0.2651 0.4012 0.020 Uiso calc 0.386(14) A 2
    C C13 0.3685(9) 0.2936(6) 0.4434(6) 0.063(2) Uani d 1 . .
    H H13A 0.2955 0.3289 0.3893 0.075 Uiso calc 0.614(14) A 1
    H H13B 0.4857 0.3167 0.3923 0.075 Uiso calc 0.614(14) A 1
    H H13C 0.3991 0.3586 0.3616 0.075 Uiso calc 0.386(14) A 2
    H H13D 0.4693 0.2450 0.4510 0.075 Uiso calc 0.386(14) A 2
    C C14 0.3340(7) 0.3596(5) 0.5366(4) 0.0345(13) Uani d 1 . .
    C C15 0.4254(6) 0.3359(4) 0.6219(4) 0.0270(11) Uani d 1 . .
    H H15 0.5109 0.2775 0.6217 0.032 Uiso calc 1 . .
    C C16 0.3922(5) 0.3972(4) 0.7070(4) 0.0175(9) Uani d 1 . .
    C C17 0.2668(5) 0.4837(4) 0.7075(4) 0.0170(8) Uani d 1 . .
    C C18 0.1784(6) 0.5086(4) 0.6213(4) 0.0243(10) Uani d 1 . .
    H H18 0.0940 0.5679 0.6201 0.029 Uiso calc 1 . .
    C C19 0.2133(7) 0.4467(5) 0.5364(4) 0.0315(12) Uani d 1 . .
    H H19 0.1527 0.4649 0.4773 0.038 Uiso calc 1 . .
    O O20 0.4752(4) 0.3819(3) 0.7940(3) 0.0220(7) Uani d 1 . .
    C C21 0.6142(6) 0.3034(5) 0.7900(5) 0.0313(12) Uani d 1 . .
    H H21A 0.6947 0.3334 0.7087 0.047 Uiso calc 1 . .
    H H21B 0.5748 0.2180 0.8068 0.047 Uiso calc 1 . .
    H H21C 0.6687 0.3047 0.8516 0.047 Uiso calc 1 . .
    O O22 0.2431(4) 0.5390(3) 0.7957(3) 0.0178(6) Uani d 1 . .
    C C23 0.1152(5) 0.6250(4) 0.8002(4) 0.0187(9) Uani d 1 . .
    H H23A 0.1245 0.6827 0.7165 0.022 Uiso calc 1 . .
    H H23B 0.1309 0.6750 0.8497 0.022 Uiso calc 1 . .
    C C24 -0.0586(5) 0.5614(4) 0.8548(4) 0.0163(8) Uani d 1 . .
    O O25 -0.0878(4) 0.4502(3) 0.9044(3) 0.0201(6) Uani d 1 . .
    O O26 -0.1749(3) 0.6460(3) 0.8437(3) 0.0170(6) Uani d 1 . .
    C C27 -0.3490(5) 0.5976(4) 0.9030(4) 0.0188(9) Uani d 1 . .
    H H27A -0.3670 0.5590 0.9923 0.023 Uiso calc 1 . .
    H H27B -0.3737 0.5333 0.8710 0.023 Uiso calc 1 . .
    C C28 -0.4627(5) 0.7039(4) 0.8770(4) 0.0192(9) Uani d 1 . .
    H H28A -0.4425 0.7425 0.7885 0.029 Uiso calc 1 . .
    H H28B -0.4399 0.7657 0.9113 0.029 Uiso calc 1 . .
    H H28C -0.5798 0.6727 0.9143 0.029 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Pt1 N2 . 2.066(3) ?
    Pt1 Cl9 . 2.2860(14) ?
    Pt1 Cl10 . 2.2990(14) ?
    Pt1 C11 . 2.161(4) ?
    Pt1 C12A . 2.221(7) ?
    Pt1 C12B . 2.217(10) ?
    N2 C3 . 1.352(5) ?
    N2 C7 . 1.358(5) ?
    C3 C4 . 1.412(6) ?
    C3 N8 . 1.348(5) ?
    C4 H4 . 0.9500 ?
    C4 C5 . 1.364(6) ?
    C5 H5 . 0.9500 ?
    C5 C6 . 1.397(6) ?
    C6 H6 . 0.9500 ?
    C6 C7 . 1.367(6) ?
    C7 H7 . 0.9500 ?
    N8 H8A . 0.8800 ?
    N8 H8B . 0.8800 ?
    C11 H11A . 0.9500 ?
    C11 H11B . 0.9500 ?
    C11 H11C . 0.9500 ?
    C11 H11D . 0.9500 ?
    C11 C12A . 1.458(8) ?
    C11 C12B . 1.429(9) ?
    C12A H12A . 1.0000 ?
    C12A C13 . 1.353(9) ?
    C12B H12B . 1.0000 ?
    C12B C13 . 1.344(9) ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C13 H13C . 0.9900 ?
    C13 H13D . 0.9900 ?
    C13 C14 . 1.513(7) ?
    C14 C15 . 1.395(8) ?
    C14 C19 . 1.376(8) ?
    C15 H15 . 0.9500 ?
    C15 C16 . 1.389(6) ?
    C16 C17 . 1.399(6) ?
    C16 O20 . 1.375(5) ?
    C17 C18 . 1.386(6) ?
    C17 O22 . 1.377(5) ?
    C18 H18 . 0.9500 ?
    C18 C19 . 1.391(7) ?
    C19 H19 . 0.9500 ?
    O20 C21 . 1.426(5) ?
    C21 H21A . 0.9800 ?
    C21 H21B . 0.9800 ?
    C21 H21C . 0.9800 ?
    O22 C23 . 1.413(5) ?
    C23 H23A . 0.9900 ?
    C23 H23B . 0.9900 ?
    C23 C24 . 1.518(6) ?
    C24 O25 . 1.211(5) ?
    C24 O26 . 1.333(5) ?
    O26 C27 . 1.467(5) ?
    C27 H27A . 0.9900 ?
    C27 H27B . 0.9900 ?
    C27 C28 . 1.502(6) ?
    C28 H28A . 0.9800 ?
    C28 H28B . 0.9800 ?
    C28 H28C . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N2 Pt1 Cl9 . . 89.18(10) ?
    N2 Pt1 Cl10 . . 88.85(10) ?
    N2 Pt1 C11 . . 167.04(16) ?
    N2 Pt1 C12A . . 153.0(2) ?
    N2 Pt1 C12B . . 153.2(3) ?
    Cl9 Pt1 Cl10 . . 174.90(6) ?
    C11 Pt1 Cl9 . . 91.10(15) ?
    C11 Pt1 Cl10 . . 89.77(15) ?
    C11 Pt1 C12A . . 38.8(2) ?
    C11 Pt1 C12B . . 38.1(2) ?
    C12A Pt1 Cl9 . . 103.0(2) ?
    C12A Pt1 Cl10 . . 80.8(2) ?
    C12B Pt1 Cl9 . . 75.1(3) ?
    C12B Pt1 Cl10 . . 108.4(3) ?
    C3 N2 Pt1 . . 122.0(3) ?
    C3 N2 C7 . . 119.1(4) ?
    C7 N2 Pt1 . . 118.9(3) ?
    N2 C3 C4 . . 120.4(4) ?
    N8 C3 N2 . . 118.8(4) ?
    N8 C3 C4 . . 120.8(4) ?
    C3 C4 H4 . . 120.3 ?
    C5 C4 C3 . . 119.4(4) ?
    C5 C4 H4 . . 120.3 ?
    C4 C5 H5 . . 119.9 ?
    C4 C5 C6 . . 120.1(4) ?
    C6 C5 H5 . . 119.9 ?
    C5 C6 H6 . . 120.9 ?
    C7 C6 C5 . . 118.1(4) ?
    C7 C6 H6 . . 120.9 ?
    N2 C7 C6 . . 122.9(4) ?
    N2 C7 H7 . . 118.5 ?
    C6 C7 H7 . . 118.5 ?
    C3 N8 H8A . . 120.0 ?
    C3 N8 H8B . . 120.0 ?
    H8A N8 H8B . . 120.0 ?
    Pt1 C11 H11A . . 112.8 ?
    Pt1 C11 H11B . . 84.7 ?
    Pt1 C11 H11C . . 113.4 ?
    Pt1 C11 H11D . . 83.9 ?
    H11A C11 H11B . . 120.0 ?
    H11C C11 H11D . . 120.0 ?
    C12A C11 Pt1 . . 72.8(3) ?
    C12A C11 H11A . . 120.0 ?
    C12A C11 H11B . . 120.0 ?
    C12B C11 Pt1 . . 73.1(4) ?
    C12B C11 H11C . . 120.0 ?
    C12B C11 H11D . . 120.0 ?
    Pt1 C12A H12A . . 111.8 ?
    C11 C12A Pt1 . . 68.3(3) ?
    C11 C12A H12A . . 111.8 ?
    C13 C12A Pt1 . . 116.3(5) ?
    C13 C12A C11 . . 129.2(6) ?
    C13 C12A H12A . . 111.8 ?
    Pt1 C12B H12B . . 110.3 ?
    C11 C12B Pt1 . . 68.8(4) ?
    C11 C12B H12B . . 110.3 ?
    C13 C12B Pt1 . . 116.9(6) ?
    C13 C12B C11 . . 132.6(8) ?
    C13 C12B H12B . . 110.3 ?
    C12A C13 H13A . . 107.2 ?
    C12A C13 H13B . . 107.2 ?
    C12A C13 C14 . . 120.4(6) ?
    C12B C13 H13C . . 107.2 ?
    C12B C13 H13D . . 107.2 ?
    C12B C13 C14 . . 120.7(6) ?
    H13A C13 H13B . . 106.8 ?
    H13C C13 H13D . . 106.8 ?
    C14 C13 H13A . . 107.2 ?
    C14 C13 H13B . . 107.2 ?
    C14 C13 H13C . . 107.2 ?
    C14 C13 H13D . . 107.2 ?
    C15 C14 C13 . . 121.1(6) ?
    C19 C14 C13 . . 119.9(6) ?
    C19 C14 C15 . . 119.0(5) ?
    C14 C15 H15 . . 119.8 ?
    C16 C15 C14 . . 120.5(5) ?
    C16 C15 H15 . . 119.8 ?
    C15 C16 C17 . . 120.0(4) ?
    O20 C16 C15 . . 125.3(4) ?
    O20 C16 C17 . . 114.6(4) ?
    C18 C17 C16 . . 119.3(4) ?
    O22 C17 C16 . . 115.6(4) ?
    O22 C17 C18 . . 125.1(4) ?
    C17 C18 H18 . . 120.0 ?
    C17 C18 C19 . . 120.0(5) ?
    C19 C18 H18 . . 120.0 ?
    C14 C19 C18 . . 121.2(5) ?
    C14 C19 H19 . . 119.4 ?
    C18 C19 H19 . . 119.4 ?
    C16 O20 C21 . . 116.7(4) ?
    O20 C21 H21A . . 109.5 ?
    O20 C21 H21B . . 109.5 ?
    O20 C21 H21C . . 109.5 ?
    H21A C21 H21B . . 109.5 ?
    H21A C21 H21C . . 109.5 ?
    H21B C21 H21C . . 109.5 ?
    C17 O22 C23 . . 117.0(3) ?
    O22 C23 H23A . . 109.2 ?
    O22 C23 H23B . . 109.2 ?
    O22 C23 C24 . . 112.2(3) ?
    H23A C23 H23B . . 107.9 ?
    C24 C23 H23A . . 109.2 ?
    C24 C23 H23B . . 109.2 ?
    O25 C24 C23 . . 125.1(4) ?
    O25 C24 O26 . . 124.8(4) ?
    O26 C24 C23 . . 110.1(3) ?
    C24 O26 C27 . . 115.6(3) ?
    O26 C27 H27A . . 110.0 ?
    O26 C27 H27B . . 110.0 ?
    O26 C27 C28 . . 108.4(3) ?
    H27A C27 H27B . . 108.4 ?
    C28 C27 H27A . . 110.0 ?
    C28 C27 H27B . . 110.0 ?
    C27 C28 H28A . . 109.5 ?
    C27 C28 H28B . . 109.5 ?
    C27 C28 H28C . . 109.5 ?
    H28A C28 H28B . . 109.5 ?
    H28A C28 H28C . . 109.5 ?
    H28B C28 H28C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Pt1 N2 C3 C4 . . . . -178.4(3) ?
    Pt1 N2 C3 N8 . . . . 0.5(5) ?
    Pt1 N2 C7 C6 . . . . 177.6(3) ?
    Pt1 C11 C12A C13 . . . . -106.9(7) ?
    Pt1 C11 C12B C13 . . . . 107.7(11) ?
    Pt1 C12A C13 C14 . . . . 46.1(8) ?
    Pt1 C12B C13 C14 . . . . -44.9(10) ?
    N2 C3 C4 C5 . . . . 1.8(6) ?
    C3 N2 C7 C6 . . . . 1.0(6) ?
    C3 C4 C5 C6 . . . . -0.7(6) ?
    C4 C5 C6 C7 . . . . -0.2(6) ?
    C5 C6 C7 N2 . . . . 0.1(7) ?
    C7 N2 C3 C4 . . . . -1.9(6) ?
    C7 N2 C3 N8 . . . . 177.0(4) ?
    N8 C3 C4 C5 . . . . -177.1(4) ?
    C11 C12A C13 C14 . . . . 128.7(7) ?
    C11 C12B C13 C14 . . . . -130.1(10) ?
    C12A C13 C14 C15 . . . . 61.2(8) ?
    C12A C13 C14 C19 . . . . -120.3(7) ?
    C12B C13 C14 C15 . . . . 116.1(8) ?
    C12B C13 C14 C19 . . . . -65.4(9) ?
    C13 C14 C15 C16 . . . . -180.0(4) ?
    C13 C14 C19 C18 . . . . 179.8(4) ?
    C14 C15 C16 C17 . . . . -0.2(6) ?
    C14 C15 C16 O20 . . . . -179.4(4) ?
    C15 C14 C19 C18 . . . . -1.7(7) ?
    C15 C16 C17 C18 . . . . -0.9(6) ?
    C15 C16 C17 O22 . . . . 179.7(4) ?
    C15 C16 O20 C21 . . . . 4.8(6) ?
    C16 C17 C18 C19 . . . . 0.8(6) ?
    C16 C17 O22 C23 . . . . -178.8(4) ?
    C17 C16 O20 C21 . . . . -174.4(4) ?
    C17 C18 C19 C14 . . . . 0.5(7) ?
    C17 O22 C23 C24 . . . . 74.6(5) ?
    C18 C17 O22 C23 . . . . 1.9(6) ?
    C19 C14 C15 C16 . . . . 1.5(7) ?
    O20 C16 C17 C18 . . . . 178.4(4) ?
    O20 C16 C17 O22 . . . . -1.0(5) ?
    O22 C17 C18 C19 . . . . -179.9(4) ?
    O22 C23 C24 O25 . . . . 9.5(6) ?
    O22 C23 C24 O26 . . . . -172.5(3) ?
    C23 C24 O26 C27 . . . . -174.6(3) ?
    C24 O26 C27 C28 . . . . -177.6(3) ?
    O25 C24 O26 C27 . . . . 3.5(6) ?
loop_
    _geom_hbond_atom_site_label_d
    _geom_hbond_atom_site_label_h
    _geom_hbond_atom_site_label_a
    _geom_hbond_site_symmetry_d
    _geom_hbond_site_symmetry_h
    _geom_hbond_site_symmetry_a
    _geom_hbond_distance_dh
    _geom_hbond_distance_ha
    _geom_hbond_distance_da
    _geom_hbond_angle_dha
    _geom_hbond_publ_flag
    N8 H8B O25 1_555 1_555 1_555 0.88 2.19 3.054(5) 167 yes
    C7 H7 O26 1_555 1_555 1_545 0.95 2.49 3.258(6) 138 yes
    C18 H18 Cl9 1_555 1_555 2_566 0.95 2.78 3.460(5) 130 yes
    N8 H8A '<i>Cg</i>1' 1_555 1_555 1_555 0.88 2.53 3.166(4) 129 yes
data_II
_audit_creation_method
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
_journal_date_recd_electronic     2017-03-09
_journal_date_accepted     2017-03-17
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2017
_journal_volume     73
_journal_issue      4
_journal_page_first     573
_journal_page_last     578
_journal_paper_category     GM
_journal_paper_doi     10.1107/S2056989017004285
_journal_coeditor_code     RZ5208
_chemical_name_systematic
;\
(2-Aminopyridine-κN)chlorido{5-ethoxycarbonylmethoxy-\
4-methoxy-1-[(2,3-η)-prop-2-en-1-yl]phenyl-κC¹}platinum(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C19 H23 Cl N2 O4 Pt'
_chemical_formula_sum     'C19 H23 Cl N2 O4 Pt'
_chemical_formula_iupac     '[Pt (C14 H17 O4) Cl (C5 H6 N2)]'
_chemical_formula_weight     573.93
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/c'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     15.1198(5)
_cell_length_b     10.0855(2)
_cell_length_c     14.1855(4)
_cell_angle_alpha     90
_cell_angle_beta     117.329(4)
_cell_angle_gamma     90
_cell_volume     1921.72(11)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     14326
_cell_measurement_theta_min     3.2230
_cell_measurement_theta_max     29.1110
_cell_measurement_temperature     100.01(10)
_exptl_crystal_description     block
_exptl_crystal_colour     white
_exptl_crystal_size_max     0.3
_exptl_crystal_size_mid     0.3
_exptl_crystal_size_min     0.2
_exptl_crystal_density_diffrn     1.984
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1112
_exptl_absorpt_coefficient_mu     7.468
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku Oxford Diffraction, 2015)
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
_exptl_absorpt_correction_T_min     0.31352
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100.01(10)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     mirror
_diffrn_measurement_device_type
      'Agilent SuperNova diffractometer (single source at offset, Eos detector)'
_diffrn_measurement_device     'four-circle diffractometer'
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     15.9631
_diffrn_reflns_number     20268
_diffrn_reflns_av_R_equivalents     0.0334
_diffrn_reflns_theta_min     2.523
_diffrn_reflns_theta_max     26.342
_diffrn_reflns_theta_full     25.214
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -18
_diffrn_reflns_limit_h_max     18
_diffrn_reflns_limit_k_min     -12
_diffrn_reflns_limit_k_max     12
_diffrn_reflns_limit_l_min     -17
_diffrn_reflns_limit_l_max     17
_refine_special_details     ?
_reflns_number_total     3928
_reflns_number_gt     3715
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0178
_refine_ls_R_factor_gt     0.0162
_refine_ls_wR_factor_gt     0.0375
_refine_ls_wR_factor_ref     0.0382
_refine_ls_goodness_of_fit_ref     1.059
_refine_ls_restrained_S_all     1.059
_refine_ls_number_reflns     3928
_refine_ls_number_parameters     246
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0159P)²+1.3858P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.691
_refine_diff_density_min     -1.035
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
_computing_cell_refinement
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
_computing_structure_solution
;
SUPERFLIP (Palatinus & Chapuis, 2007)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Pt Pt1 0.10189(2) 0.16233(2) 0.26543(2) 0.00950(4) Uani d 1 . .
    N N2 -0.03286(15) 0.2169(2) 0.12855(16) 0.0120(4) Uani d 1 . .
    C C3 -0.10502(19) 0.1243(3) 0.0838(2) 0.0152(5) Uani d 1 . .
    H H3 -0.0934 0.0380 0.1141 0.018 Uiso calc 1 . .
    C C4 -0.1940(2) 0.1495(3) -0.0030(2) 0.0184(6) Uani d 1 . .
    H H4 -0.2437 0.0828 -0.0320 0.022 Uiso calc 1 . .
    C C5 -0.2097(2) 0.2756(3) -0.0476(2) 0.0185(6) Uani d 1 . .
    H H5 -0.2705 0.2958 -0.1084 0.022 Uiso calc 1 . .
    C C6 -0.1378(2) 0.3701(3) -0.0039(2) 0.0172(6) Uani d 1 . .
    H H6 -0.1479 0.4561 -0.0344 0.021 Uiso calc 1 . .
    C C7 -0.0487(2) 0.3395(2) 0.0864(2) 0.0131(5) Uani d 1 . .
    N N8 0.02411(16) 0.4301(2) 0.13082(18) 0.0190(5) Uani d 1 . .
    H H8A 0.0804 0.4087 0.1861 0.023 Uiso calc 1 . .
    H H8B 0.0154 0.5109 0.1046 0.023 Uiso calc 1 . .
    C C9 0.1753(2) 0.1410(3) 0.1694(2) 0.0165(6) Uani d 1 . .
    H H9A 0.2434 0.1627 0.2122 0.020 Uiso calc 1 . .
    H H9B 0.1320 0.2033 0.1191 0.020 Uiso calc 1 . .
    C C10 0.13895(19) 0.0178(3) 0.18011(19) 0.0141(5) Uani d 1 . .
    H H10 0.0818 -0.0176 0.1146 0.017 Uiso calc 1 . .
    C C11 0.20439(19) -0.0853(3) 0.25867(19) 0.0140(5) Uani d 1 . .
    H H11A 0.1626 -0.1585 0.2626 0.017 Uiso calc 1 . .
    H H11B 0.2511 -0.1227 0.2345 0.017 Uiso calc 1 . .
    C C12 0.26227(18) -0.0239(2) 0.36696(18) 0.0106(5) Uani d 1 . .
    C C13 0.22571(18) 0.0934(2) 0.38748(19) 0.0105(5) Uani d 1 . .
    C C14 0.27648(18) 0.1489(2) 0.48888(19) 0.0102(5) Uani d 1 . .
    H H14 0.2536 0.2298 0.5043 0.012 Uiso calc 1 . .
    C C15 0.35958(18) 0.0873(2) 0.56683(18) 0.0104(5) Uani d 1 . .
    C C16 0.39390(17) -0.0322(2) 0.54590(18) 0.0099(5) Uani d 1 . .
    C C17 0.34544(18) -0.0865(2) 0.44517(19) 0.0105(5) Uani d 1 . .
    H H17 0.3691 -0.1666 0.4295 0.013 Uiso calc 1 . .
    O O18 0.47426(13) -0.08947(17) 0.62958(13) 0.0129(4) Uani d 1 . .
    C C19 0.52470(19) -0.1911(3) 0.6034(2) 0.0148(5) Uani d 1 . .
    H H19A 0.5461 -0.1566 0.5526 0.022 Uiso calc 1 . .
    H H19B 0.4797 -0.2664 0.5719 0.022 Uiso calc 1 . .
    H H19C 0.5831 -0.2202 0.6679 0.022 Uiso calc 1 . .
    O O20 0.40683(13) 0.14275(17) 0.66777(13) 0.0113(4) Uani d 1 . .
    C C21 0.50526(18) 0.1854(2) 0.6969(2) 0.0124(5) Uani d 1 . .
    H H21A 0.5375 0.1211 0.6697 0.015 Uiso calc 1 . .
    H H21B 0.5436 0.1867 0.7752 0.015 Uiso calc 1 . .
    C C22 0.50842(19) 0.3214(3) 0.65427(19) 0.0135(5) Uani d 1 . .
    O O23 0.43843(14) 0.39064(19) 0.60292(15) 0.0208(4) Uani d 1 . .
    O O24 0.60368(13) 0.35149(17) 0.68185(14) 0.0140(4) Uani d 1 . .
    C C25 0.6206(2) 0.4778(3) 0.6433(2) 0.0177(6) Uani d 1 . .
    H H25A 0.5806 0.5482 0.6543 0.021 Uiso calc 1 . .
    H H25B 0.6007 0.4719 0.5665 0.021 Uiso calc 1 . .
    C C26 0.7291(2) 0.5093(3) 0.7039(2) 0.0240(6) Uani d 1 . .
    H H26A 0.7436 0.5898 0.6749 0.036 Uiso calc 1 . .
    H H26B 0.7681 0.4353 0.6978 0.036 Uiso calc 1 . .
    H H26C 0.7466 0.5234 0.7788 0.036 Uiso calc 1 . .
    Cl Cl27 0.04241(4) 0.25459(6) 0.37522(5) 0.01518(13) Uani d 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Pt1 N2 . 2.143(2) ?
    Pt1 C9 . 2.127(3) ?
    Pt1 C10 . 2.127(2) ?
    Pt1 C13 . 2.003(2) ?
    Pt1 Cl27 . 2.3209(6) ?
    N2 C3 . 1.353(3) ?
    N2 C7 . 1.346(3) ?
    C3 H3 . 0.9500 ?
    C3 C4 . 1.367(4) ?
    C4 H4 . 0.9500 ?
    C4 C5 . 1.392(4) ?
    C5 H5 . 0.9500 ?
    C5 C6 . 1.363(4) ?
    C6 H6 . 0.9500 ?
    C6 C7 . 1.402(4) ?
    C7 N8 . 1.345(3) ?
    N8 H8A . 0.8800 ?
    N8 H8B . 0.8800 ?
    C9 H9A . 0.9500 ?
    C9 H9B . 0.9500 ?
    C9 C10 . 1.395(4) ?
    C10 H10 . 1.0000 ?
    C10 C11 . 1.514(3) ?
    C11 H11A . 0.9900 ?
    C11 H11B . 0.9900 ?
    C11 C12 . 1.509(3) ?
    C12 C13 . 1.391(4) ?
    C12 C17 . 1.389(3) ?
    C13 C14 . 1.399(3) ?
    C14 H14 . 0.9500 ?
    C14 C15 . 1.382(3) ?
    C15 C16 . 1.397(4) ?
    C15 O20 . 1.391(3) ?
    C16 C17 . 1.385(3) ?
    C16 O18 . 1.376(3) ?
    C17 H17 . 0.9500 ?
    O18 C19 . 1.425(3) ?
    C19 H19A . 0.9800 ?
    C19 H19B . 0.9800 ?
    C19 H19C . 0.9800 ?
    O20 C21 . 1.416(3) ?
    C21 H21A . 0.9900 ?
    C21 H21B . 0.9900 ?
    C21 C22 . 1.509(4) ?
    C22 O23 . 1.196(3) ?
    C22 O24 . 1.343(3) ?
    O24 C25 . 1.454(3) ?
    C25 H25A . 0.9900 ?
    C25 H25B . 0.9900 ?
    C25 C26 . 1.495(4) ?
    C26 H26A . 0.9800 ?
    C26 H26B . 0.9800 ?
    C26 H26C . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N2 Pt1 Cl27 . . 90.28(6) ?
    C9 Pt1 N2 . . 90.24(9) ?
    C9 Pt1 C10 . . 38.29(10) ?
    C9 Pt1 Cl27 . . 161.33(7) ?
    C10 Pt1 N2 . . 92.85(9) ?
    C10 Pt1 Cl27 . . 160.20(7) ?
    C13 Pt1 N2 . . 174.40(9) ?
    C13 Pt1 C9 . . 87.89(10) ?
    C13 Pt1 C10 . . 82.42(10) ?
    C13 Pt1 Cl27 . . 93.18(7) ?
    C3 N2 Pt1 . . 118.29(17) ?
    C7 N2 Pt1 . . 122.69(17) ?
    C7 N2 C3 . . 119.0(2) ?
    N2 C3 H3 . . 118.6 ?
    N2 C3 C4 . . 122.8(3) ?
    C4 C3 H3 . . 118.6 ?
    C3 C4 H4 . . 120.9 ?
    C3 C4 C5 . . 118.1(3) ?
    C5 C4 H4 . . 120.9 ?
    C4 C5 H5 . . 120.1 ?
    C6 C5 C4 . . 119.9(2) ?
    C6 C5 H5 . . 120.1 ?
    C5 C6 H6 . . 120.2 ?
    C5 C6 C7 . . 119.6(3) ?
    C7 C6 H6 . . 120.2 ?
    N2 C7 C6 . . 120.6(2) ?
    N8 C7 N2 . . 118.4(2) ?
    N8 C7 C6 . . 121.0(2) ?
    C7 N8 H8A . . 120.0 ?
    C7 N8 H8B . . 120.0 ?
    H8A N8 H8B . . 120.0 ?
    Pt1 C9 H9A . . 107.3 ?
    Pt1 C9 H9B . . 91.7 ?
    H9A C9 H9B . . 120.0 ?
    C10 C9 Pt1 . . 70.86(15) ?
    C10 C9 H9A . . 120.0 ?
    C10 C9 H9B . . 120.0 ?
    Pt1 C10 H10 . . 115.6 ?
    C9 C10 Pt1 . . 70.85(15) ?
    C9 C10 H10 . . 115.6 ?
    C9 C10 C11 . . 122.4(2) ?
    C11 C10 Pt1 . . 107.81(16) ?
    C11 C10 H10 . . 115.6 ?
    C10 C11 H11A . . 109.6 ?
    C10 C11 H11B . . 109.6 ?
    H11A C11 H11B . . 108.1 ?
    C12 C11 C10 . . 110.2(2) ?
    C12 C11 H11A . . 109.6 ?
    C12 C11 H11B . . 109.6 ?
    C13 C12 C11 . . 117.5(2) ?
    C17 C12 C11 . . 121.0(2) ?
    C17 C12 C13 . . 121.3(2) ?
    C12 C13 Pt1 . . 114.69(17) ?
    C12 C13 C14 . . 118.2(2) ?
    C14 C13 Pt1 . . 127.13(19) ?
    C13 C14 H14 . . 119.6 ?
    C15 C14 C13 . . 120.7(2) ?
    C15 C14 H14 . . 119.6 ?
    C14 C15 C16 . . 120.5(2) ?
    C14 C15 O20 . . 119.5(2) ?
    O20 C15 C16 . . 120.0(2) ?
    C17 C16 C15 . . 119.2(2) ?
    O18 C16 C15 . . 116.5(2) ?
    O18 C16 C17 . . 124.3(2) ?
    C12 C17 H17 . . 120.0 ?
    C16 C17 C12 . . 120.0(2) ?
    C16 C17 H17 . . 120.0 ?
    C16 O18 C19 . . 116.32(19) ?
    O18 C19 H19A . . 109.5 ?
    O18 C19 H19B . . 109.5 ?
    O18 C19 H19C . . 109.5 ?
    H19A C19 H19B . . 109.5 ?
    H19A C19 H19C . . 109.5 ?
    H19B C19 H19C . . 109.5 ?
    C15 O20 C21 . . 113.37(19) ?
    O20 C21 H21A . . 109.1 ?
    O20 C21 H21B . . 109.1 ?
    O20 C21 C22 . . 112.4(2) ?
    H21A C21 H21B . . 107.9 ?
    C22 C21 H21A . . 109.1 ?
    C22 C21 H21B . . 109.1 ?
    O23 C22 C21 . . 126.4(2) ?
    O23 C22 O24 . . 125.2(2) ?
    O24 C22 C21 . . 108.4(2) ?
    C22 O24 C25 . . 116.0(2) ?
    O24 C25 H25A . . 110.1 ?
    O24 C25 H25B . . 110.1 ?
    O24 C25 C26 . . 107.8(2) ?
    H25A C25 H25B . . 108.5 ?
    C26 C25 H25A . . 110.1 ?
    C26 C25 H25B . . 110.1 ?
    C25 C26 H26A . . 109.5 ?
    C25 C26 H26B . . 109.5 ?
    C25 C26 H26C . . 109.5 ?
    H26A C26 H26B . . 109.5 ?
    H26A C26 H26C . . 109.5 ?
    H26B C26 H26C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Pt1 N2 C3 C4 . . . . 179.4(2) ?
    Pt1 N2 C7 C6 . . . . 179.41(18) ?
    Pt1 N2 C7 N8 . . . . 1.5(3) ?
    Pt1 C9 C10 C11 . . . . -99.4(2) ?
    Pt1 C10 C11 C12 . . . . -28.5(2) ?
    Pt1 C13 C14 C15 . . . . 177.68(18) ?
    N2 C3 C4 C5 . . . . 1.0(4) ?
    C3 N2 C7 C6 . . . . -1.3(4) ?
    C3 N2 C7 N8 . . . . -179.2(2) ?
    C3 C4 C5 C6 . . . . -0.7(4) ?
    C4 C5 C6 C7 . . . . -0.5(4) ?
    C5 C6 C7 N2 . . . . 1.5(4) ?
    C5 C6 C7 N8 . . . . 179.4(3) ?
    C7 N2 C3 C4 . . . . 0.0(4) ?
    C9 C10 C11 C12 . . . . 49.7(3) ?
    C10 C11 C12 C13 . . . . 21.0(3) ?
    C10 C11 C12 C17 . . . . -162.9(2) ?
    C11 C12 C13 Pt1 . . . . -1.4(3) ?
    C11 C12 C13 C14 . . . . 177.6(2) ?
    C11 C12 C17 C16 . . . . -176.2(2) ?
    C12 C13 C14 C15 . . . . -1.2(4) ?
    C13 C12 C17 C16 . . . . -0.2(4) ?
    C13 C14 C15 C16 . . . . -0.5(4) ?
    C13 C14 C15 O20 . . . . -178.1(2) ?
    C14 C15 C16 C17 . . . . 1.9(4) ?
    C14 C15 C16 O18 . . . . -177.0(2) ?
    C14 C15 O20 C21 . . . . -115.9(2) ?
    C15 C16 C17 C12 . . . . -1.5(4) ?
    C15 C16 O18 C19 . . . . -164.7(2) ?
    C15 O20 C21 C22 . . . . 83.1(3) ?
    C16 C15 O20 C21 . . . . 66.4(3) ?
    C17 C12 C13 Pt1 . . . . -177.47(19) ?
    C17 C12 C13 C14 . . . . 1.5(4) ?
    C17 C16 O18 C19 . . . . 16.5(3) ?
    O18 C16 C17 C12 . . . . 177.3(2) ?
    O20 C15 C16 C17 . . . . 179.5(2) ?
    O20 C15 C16 O18 . . . . 0.6(3) ?
    O20 C21 C22 O23 . . . . 1.2(4) ?
    O20 C21 C22 O24 . . . . -177.57(19) ?
    C21 C22 O24 C25 . . . . 177.5(2) ?
    C22 O24 C25 C26 . . . . 165.5(2) ?
    O23 C22 O24 C25 . . . . -1.3(4) ?
loop_
    _geom_hbond_atom_site_label_d
    _geom_hbond_atom_site_label_h
    _geom_hbond_atom_site_label_a
    _geom_hbond_site_symmetry_d
    _geom_hbond_site_symmetry_h
    _geom_hbond_site_symmetry_a
    _geom_hbond_distance_dh
    _geom_hbond_distance_ha
    _geom_hbond_distance_da
    _geom_hbond_angle_dha
    _geom_hbond_publ_flag
    C17 H17 O24 1_555 1_555 3_656 0.95 2.60 3.501(3) 159 yes
    C25 H25B O23 1_555 1_555 3_666 0.99 2.60 3.449(3) 144 yes
    N8 H8B Cl27 1_555 1_555 2_555 0.88 2.67 3.413(2) 143 yes
    C19 H19A '<i>Cg</i>2' 1_555 1_555 3_656 0.98 2.63 3.476(3) 145 yes
