##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_database_code_depnum_ccdc_archive 'CCDC 1483066'
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_journal_date_recd_electronic     2016-05-24
_journal_date_accepted     2016-06-01
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2016
_journal_volume     72
_journal_issue      7
_journal_page_first     912
_journal_page_last     917
_journal_paper_category     GM
_journal_paper_doi     10.1107/S2056989016008872
_journal_coeditor_code     RZ5189
_publ_contact_author_name     'Luc Van Meervelt'
_publ_contact_author_address
;
KU Leuven - University of Leuven
Department of Chemistry,
Celestijnenlaan 200F - bus 2404,
B-3001 Heverlee
Belgium
;
_publ_contact_author_email     'luc.vanmeervelt@kuleuven.be'
_publ_contact_author_fax     ?
_publ_contact_author_phone     '32-16327609'
_publ_section_title
;
Crystal structures of organoplatinum complexes containing alkyleugenoxyacetate
and p-chloroaniline
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Le Thi Hong, Hai' .
;
Chemistry Department
Hanoi National University of Education
136 - Xuan Thuy - Cau Giay
Hanoi
Vietnam
;
    'Dao Thi Bich, Diep' .
;
Chemistry Department
Hanoi National University of Education
136 - Xuan Thuy - Cau Giay
Hanoi
Vietnam
;
    'Nguyen Bich, Ngan' .
;
Chemistry Department
Hanoi National University of Education
136 - Xuan Thuy - Cau Giay
Hanoi
Vietnam
;
    'Van Meervelt, Luc' .
;
KU Leuven - University of Leuven
Department of Chemistry,
Celestijnenlaan 200F - bus 2404,
B-3001 Heverlee
Belgium
;
_publ_section_synopsis
;
In the title trans-dichloridoplatinum(II) complexes, the central PtII
atom is further coordinated to the p-chloroaniline N atom and ethylenic
double bond of alkyleugenoxyacetate.
;
_chemical_name_systematic
;\
trans-Dichlorido(4-chloroaniline-κN){3-methoxy-4-\
methoxycarbonylmethoxy-1-[(2,3-η)-prop-2-en-1-yl]benzene}platinum(II)
0.1-hydrate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C19 H22 Cl3 N O4 Pt, 0.1(H2 O)'
_chemical_formula_sum     'C19 H22.2 Cl3 N O4.1 Pt'
_chemical_formula_iupac     '[Pt Cl2 (C6 H6 Cl N) (C13 H16 O4)], 0.1H2 O'
_chemical_formula_weight     631.61
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'C 2/c'
_space_group_name_Hall     '-C 2yc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y, -z+1/2'
    'x+1/2, y+1/2, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y, z-1/2'
    '-x+1/2, -y+1/2, -z'
    'x+1/2, -y+1/2, z-1/2'
_cell_length_a     13.8322(6)
_cell_length_b     15.0753(4)
_cell_length_c     21.0367(9)
_cell_angle_alpha     90
_cell_angle_beta     106.683(5)
_cell_angle_gamma     90
_cell_volume     4202.0(3)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     22209
_cell_measurement_theta_min     3.2570
_cell_measurement_theta_max     28.6090
_cell_measurement_temperature     100.0
_exptl_crystal_description     block
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.2
_exptl_crystal_size_mid     0.1
_exptl_crystal_size_min     0.1
_exptl_crystal_density_diffrn     1.997
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     2440.0
_exptl_absorpt_coefficient_mu     7.086
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Agilent, 2012)
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
_exptl_absorpt_correction_T_min     0.71501
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100.0
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     mirror
_diffrn_measurement_device_type
;
Agilent SuperNova diffractometer (single source at offset, Eos
detector)
;
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     15.9631
_diffrn_reflns_number     44052
_diffrn_reflns_av_R_equivalents     0.0318
_diffrn_reflns_theta_min     2.885
_diffrn_reflns_theta_max     26.369
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.997
_diffrn_measured_fraction_theta_full     0.997
_diffrn_reflns_limit_h_min     -17
_diffrn_reflns_limit_h_max     17
_diffrn_reflns_limit_k_min     -18
_diffrn_reflns_limit_k_max     18
_diffrn_reflns_limit_l_min     -26
_diffrn_reflns_limit_l_max     26
_refine_special_details     ?
_reflns_number_total     4295
_reflns_number_gt     4033
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0351
_refine_ls_R_factor_gt     0.0324
_refine_ls_wR_factor_gt     0.0629
_refine_ls_wR_factor_ref     0.0639
_refine_ls_goodness_of_fit_ref     1.216
_refine_ls_restrained_S_all     1.199
_refine_ls_number_reflns     4295
_refine_ls_number_parameters     315
_refine_ls_number_restraints     291
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                          'w=1/[σ²(Fo²)+46.5817P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.280
_refine_diff_density_min     -0.917
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Agilent, 2012)
;
_computing_cell_refinement
;
CrysAlis PRO (Agilent, 2012)
;
_computing_data_reduction
;
CrysAlis PRO (Agilent, 2012)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Pt Pt1A 0.75061(14) 0.49179(7) 0.82720(10) 0.0213(2) Uani d 0.679(8) A 1
    Pt Pt1B 0.7676(3) 0.4904(2) 0.8417(2) 0.0349(6) Uani d 0.321(8) A 2
    N N2 0.8940(3) 0.5396(3) 0.8235(2) 0.0369(10) Uani d 1 . .
    H H2AA 0.9427 0.4996 0.8432 0.044 Uiso calc 0.679(8) A 1
    H H2AB 0.8938 0.5459 0.7805 0.044 Uiso calc 0.679(8) A 1
    H H2BC 0.9465 0.5015 0.8389 0.044 Uiso calc 0.321(8) A 2
    H H2BD 0.8835 0.5469 0.7791 0.044 Uiso calc 0.321(8) A 2
    C C3 0.9164(4) 0.6242(3) 0.8573(3) 0.0328(11) Uani d 1 . .
    C C4 0.9600(5) 0.6278(4) 0.9245(3) 0.0457(14) Uani d 1 . .
    H H4 0.9792 0.5743 0.9487 0.055 Uiso calc 1 . .
    C C5 0.9763(5) 0.7077(4) 0.9572(3) 0.0491(15) Uani d 1 . .
    H H5 1.0047 0.7096 1.0040 0.059 Uiso calc 1 . .
    C C6 0.9509(4) 0.7856(4) 0.9213(3) 0.0390(12) Uani d 1 . .
    C C7 0.9087(4) 0.7838(4) 0.8539(3) 0.0327(11) Uani d 1 . .
    H H7 0.8915 0.8374 0.8295 0.039 Uiso calc 1 . .
    C C8 0.8913(4) 0.7023(3) 0.8218(3) 0.0303(11) Uani d 1 . .
    H H8 0.8621 0.7002 0.7751 0.036 Uiso calc 1 . .
    Cl Cl9 0.97029(14) 0.88741(11) 0.96197(8) 0.0557(4) Uani d 1 . .
    Cl Cl10 0.8612(7) 0.4286(5) 0.9395(3) 0.0395(16) Uani d 0.321(8) A 2
    Cl Cl11 0.6918(4) 0.5297(5) 0.7175(2) 0.0425(11) Uani d 0.679(8) A 1
    Cl Cl12 0.8205(3) 0.4484(2) 0.93519(14) 0.0337(6) Uani d 0.679(8) A 1
    Cl Cl13 0.6770(6) 0.5272(9) 0.7318(4) 0.036(2) Uani d 0.321(8) A 2
    C C14 0.6190(7) 0.4194(5) 0.8275(4) 0.0265(19) Uani d 0.679(8) A 1
    H H14A 0.6296 0.3818 0.8652 0.032 Uiso calc 0.679(8) A 1
    H H14B 0.6241 0.3962 0.7867 0.032 Uiso calc 0.679(8) A 1
    C C15 0.5959(5) 0.5080(4) 0.8322(3) 0.0213(15) Uani d 0.679(8) A 1
    H H15 0.5489 0.5324 0.7905 0.026 Uiso calc 0.679(8) A 1
    C C16 0.5856(7) 0.5525(4) 0.8945(4) 0.0271(18) Uani d 0.679(8) A 1
    H H16A 0.6411 0.5339 0.9335 0.032 Uiso calc 0.679(8) A 1
    H H16B 0.5205 0.5363 0.9022 0.032 Uiso calc 0.679(8) A 1
    C C17 0.6445(18) 0.4012(12) 0.8481(11) 0.041(5) Uani d 0.321(8) A 2
    H H17A 0.5949 0.3889 0.8073 0.050 Uiso calc 0.321(8) A 2
    H H17B 0.6967 0.3596 0.8662 0.050 Uiso calc 0.321(8) A 2
    C C18 0.6407(13) 0.4798(11) 0.8811(10) 0.046(4) Uani d 0.321(8) A 2
    H H18 0.6633 0.4711 0.9302 0.055 Uiso calc 0.321(8) A 2
    C C19 0.5657(13) 0.5548(7) 0.8620(10) 0.042(4) Uani d 0.321(8) A 2
    H H19A 0.5071 0.5376 0.8774 0.051 Uiso calc 0.321(8) A 2
    H H19B 0.5416 0.5552 0.8129 0.051 Uiso calc 0.321(8) A 2
    C C20 0.5902(4) 0.6522(4) 0.8837(3) 0.0424(13) Uani d 1 . .
    C C21 0.5064(4) 0.7011(3) 0.8465(3) 0.0339(11) Uani d 1 . .
    H H21 0.4456 0.6712 0.8242 0.041 Uiso calc 1 . .
    C C22 0.5118(4) 0.7926(3) 0.8422(2) 0.0282(10) Uani d 1 . .
    C C23 0.6008(4) 0.8361(3) 0.8764(3) 0.0313(11) Uani d 1 . .
    C C24 0.6828(4) 0.7872(4) 0.9122(3) 0.0395(12) Uani d 1 . .
    H H24 0.7435 0.8167 0.9352 0.047 Uiso calc 1 . .
    C C25 0.6774(4) 0.6956(4) 0.9150(3) 0.0440(13) Uani d 1 . .
    H H25 0.7349 0.6627 0.9389 0.053 Uiso calc 1 . .
    O O26 0.4355(3) 0.8454(2) 0.80566(18) 0.0324(8) Uani d 1 . .
    C C27 0.3460(4) 0.8027(4) 0.7673(3) 0.0343(12) Uani d 1 . .
    H H27A 0.3117 0.7750 0.7970 0.051 Uiso calc 1 . .
    H H27B 0.3635 0.7571 0.7393 0.051 Uiso calc 1 . .
    H H27C 0.3012 0.8465 0.7393 0.051 Uiso calc 1 . .
    O O28 0.5993(3) 0.9267(2) 0.86886(19) 0.0372(9) Uani d 1 . .
    C C29 0.6894(5) 0.9716(4) 0.9030(3) 0.0446(14) Uani d 1 . .
    H H29A 0.7479 0.9457 0.8914 0.054 Uiso calc 1 . .
    H H29B 0.7014 0.9667 0.9515 0.054 Uiso calc 1 . .
    C C30 0.6754(5) 1.0688(4) 0.8813(3) 0.0480(14) Uani d 1 . .
    O O31 0.6176(4) 1.0965(3) 0.8301(3) 0.0582(12) Uani d 1 . .
    O O32 0.7487(5) 1.1132(3) 0.9246(2) 0.0740(16) Uani d 1 . .
    C C33 0.7493(9) 1.2074(5) 0.9135(5) 0.102(3) Uani d 1 . .
    H H33A 0.7428 1.2188 0.8666 0.154 Uiso calc 1 . .
    H H33B 0.8128 1.2327 0.9410 0.154 Uiso calc 1 . .
    H H33C 0.6926 1.2349 0.9253 0.154 Uiso calc 1 . .
    O O34 1.0000 0.5000 0.7500 0.10(2) Uani d 0.100(10)
                                                      . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Pt1A N2 . 2.132(5) ?
    Pt1A Cl11 . 2.288(4) ?
    Pt1A Cl12 . 2.294(3) ?
    Pt1A C14 . 2.124(9) ?
    Pt1A C15 . 2.187(6) ?
    Pt1B N2 . 2.033(6) ?
    Pt1B Cl10 . 2.291(5) ?
    Pt1B Cl13 . 2.357(7) ?
    Pt1B C17 . 2.20(2) ?
    Pt1B C18 . 2.151(18) ?
    N2 H2AA . 0.9100 ?
    N2 H2AB . 0.9100 ?
    N2 H2BC . 0.9100 ?
    N2 H2BD . 0.9100 ?
    N2 C3 . 1.450(7) ?
    C3 C4 . 1.370(8) ?
    C3 C8 . 1.384(7) ?
    C4 H4 . 0.9500 ?
    C4 C5 . 1.374(9) ?
    C5 H5 . 0.9500 ?
    C5 C6 . 1.386(8) ?
    C6 C7 . 1.370(8) ?
    C6 Cl9 . 1.741(6) ?
    C7 H7 . 0.9500 ?
    C7 C8 . 1.389(7) ?
    C8 H8 . 0.9500 ?
    C14 H14A . 0.9500 ?
    C14 H14B . 0.9500 ?
    C14 C15 . 1.383(9) ?
    C15 H15 . 1.0000 ?
    C15 C16 . 1.514(8) ?
    C16 H16A . 0.9900 ?
    C16 H16B . 0.9900 ?
    C16 C20 . 1.523(8) ?
    C17 H17A . 0.9500 ?
    C17 H17B . 0.9500 ?
    C17 C18 . 1.381(12) ?
    C18 H18 . 1.0000 ?
    C18 C19 . 1.508(11) ?
    C19 H19A . 0.9900 ?
    C19 H19B . 0.9900 ?
    C19 C20 . 1.546(11) ?
    C20 C21 . 1.407(8) ?
    C20 C25 . 1.364(9) ?
    C21 H21 . 0.9500 ?
    C21 C22 . 1.386(7) ?
    C22 C23 . 1.398(7) ?
    C22 O26 . 1.369(6) ?
    C23 C24 . 1.381(8) ?
    C23 O28 . 1.374(6) ?
    C24 H24 . 0.9500 ?
    C24 C25 . 1.385(8) ?
    C25 H25 . 0.9500 ?
    O26 C27 . 1.422(6) ?
    C27 H27A . 0.9800 ?
    C27 H27B . 0.9800 ?
    C27 H27C . 0.9800 ?
    O28 C29 . 1.419(7) ?
    C29 H29A . 0.9900 ?
    C29 H29B . 0.9900 ?
    C29 C30 . 1.530(9) ?
    C30 O31 . 1.218(8) ?
    C30 O32 . 1.332(8) ?
    O32 C33 . 1.440(9) ?
    C33 H33A . 0.9800 ?
    C33 H33B . 0.9800 ?
    C33 H33C . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N2 Pt1A Cl11 . . 86.8(2) ?
    N2 Pt1A Cl12 . . 90.03(16) ?
    N2 Pt1A C15 . . 153.8(2) ?
    Cl11 Pt1A Cl12 . . 175.35(16) ?
    C14 Pt1A N2 . . 168.7(2) ?
    C14 Pt1A Cl11 . . 94.3(3) ?
    C14 Pt1A Cl12 . . 88.2(3) ?
    C14 Pt1A C15 . . 37.4(3) ?
    C15 Pt1A Cl11 . . 87.2(2) ?
    C15 Pt1A Cl12 . . 97.1(2) ?
    N2 Pt1B Cl10 . . 91.2(2) ?
    N2 Pt1B Cl13 . . 88.5(3) ?
    N2 Pt1B C17 . . 162.7(5) ?
    N2 Pt1B C18 . . 160.0(5) ?
    Cl10 Pt1B Cl13 . . 168.6(4) ?
    C17 Pt1B Cl10 . . 86.8(6) ?
    C17 Pt1B Cl13 . . 90.1(6) ?
    C18 Pt1B Cl10 . . 86.4(6) ?
    C18 Pt1B Cl13 . . 97.6(6) ?
    C18 Pt1B C17 . . 36.9(4) ?
    Pt1A N2 H2AA . . 109.5 ?
    Pt1A N2 H2AB . . 109.5 ?
    Pt1B N2 H2BC . . 110.2 ?
    Pt1B N2 H2BD . . 110.2 ?
    H2AA N2 H2AB . . 108.1 ?
    H2BC N2 H2BD . . 108.5 ?
    C3 N2 Pt1A . . 110.5(3) ?
    C3 N2 Pt1B . . 107.7(3) ?
    C3 N2 H2AA . . 109.5 ?
    C3 N2 H2AB . . 109.5 ?
    C3 N2 H2BC . . 110.2 ?
    C3 N2 H2BD . . 110.2 ?
    C4 C3 N2 . . 120.5(5) ?
    C4 C3 C8 . . 119.5(5) ?
    C8 C3 N2 . . 120.0(5) ?
    C3 C4 H4 . . 119.6 ?
    C3 C4 C5 . . 120.8(6) ?
    C5 C4 H4 . . 119.6 ?
    C4 C5 H5 . . 120.3 ?
    C4 C5 C6 . . 119.3(6) ?
    C6 C5 H5 . . 120.3 ?
    C5 C6 Cl9 . . 119.9(5) ?
    C7 C6 C5 . . 121.0(6) ?
    C7 C6 Cl9 . . 119.1(4) ?
    C6 C7 H7 . . 120.6 ?
    C6 C7 C8 . . 118.9(5) ?
    C8 C7 H7 . . 120.6 ?
    C3 C8 C7 . . 120.5(5) ?
    C3 C8 H8 . . 119.7 ?
    C7 C8 H8 . . 119.7 ?
    Pt1A C14 H14A . . 112.4 ?
    Pt1A C14 H14B . . 84.2 ?
    H14A C14 H14B . . 120.0 ?
    C15 C14 Pt1A . . 73.8(4) ?
    C15 C14 H14A . . 120.0 ?
    C15 C14 H14B . . 120.0 ?
    Pt1A C15 H15 . . 113.4 ?
    C14 C15 Pt1A . . 68.9(5) ?
    C14 C15 H15 . . 113.4 ?
    C14 C15 C16 . . 124.8(6) ?
    C16 C15 Pt1A . . 115.3(5) ?
    C16 C15 H15 . . 113.4 ?
    C15 C16 H16A . . 110.4 ?
    C15 C16 H16B . . 110.4 ?
    C15 C16 C20 . . 106.8(5) ?
    H16A C16 H16B . . 108.6 ?
    C20 C16 H16A . . 110.4 ?
    C20 C16 H16B . . 110.4 ?
    Pt1B C17 H17A . . 115.8 ?
    Pt1B C17 H17B . . 85.2 ?
    H17A C17 H17B . . 120.0 ?
    C18 C17 Pt1B . . 69.4(12) ?
    C18 C17 H17A . . 120.0 ?
    C18 C17 H17B . . 120.0 ?
    Pt1B C18 H18 . . 111.2 ?
    C17 C18 Pt1B . . 73.6(13) ?
    C17 C18 H18 . . 111.2 ?
    C17 C18 C19 . . 129.1(17) ?
    C19 C18 Pt1B . . 114.6(12) ?
    C19 C18 H18 . . 111.2 ?
    C18 C19 H19A . . 106.4 ?
    C18 C19 H19B . . 106.4 ?
    C18 C19 C20 . . 123.8(13) ?
    H19A C19 H19B . . 106.4 ?
    C20 C19 H19A . . 106.4 ?
    C20 C19 H19B . . 106.4 ?
    C21 C20 C16 . . 122.4(6) ?
    C21 C20 C19 . . 104.9(8) ?
    C25 C20 C16 . . 118.1(6) ?
    C25 C20 C19 . . 133.4(8) ?
    C25 C20 C21 . . 119.3(5) ?
    C20 C21 H21 . . 119.8 ?
    C22 C21 C20 . . 120.4(5) ?
    C22 C21 H21 . . 119.8 ?
    C21 C22 C23 . . 119.3(5) ?
    O26 C22 C21 . . 124.6(5) ?
    O26 C22 C23 . . 116.1(4) ?
    C24 C23 C22 . . 119.7(5) ?
    O28 C23 C22 . . 115.1(5) ?
    O28 C23 C24 . . 125.2(5) ?
    C23 C24 H24 . . 119.7 ?
    C23 C24 C25 . . 120.6(6) ?
    C25 C24 H24 . . 119.7 ?
    C20 C25 C24 . . 120.7(6) ?
    C20 C25 H25 . . 119.7 ?
    C24 C25 H25 . . 119.7 ?
    C22 O26 C27 . . 117.5(4) ?
    O26 C27 H27A . . 109.5 ?
    O26 C27 H27B . . 109.5 ?
    O26 C27 H27C . . 109.5 ?
    H27A C27 H27B . . 109.5 ?
    H27A C27 H27C . . 109.5 ?
    H27B C27 H27C . . 109.5 ?
    C23 O28 C29 . . 115.7(4) ?
    O28 C29 H29A . . 110.4 ?
    O28 C29 H29B . . 110.4 ?
    O28 C29 C30 . . 106.8(5) ?
    H29A C29 H29B . . 108.6 ?
    C30 C29 H29A . . 110.4 ?
    C30 C29 H29B . . 110.4 ?
    O31 C30 C29 . . 125.9(6) ?
    O31 C30 O32 . . 127.7(6) ?
    O32 C30 C29 . . 105.7(6) ?
    C30 O32 C33 . . 115.0(7) ?
    O32 C33 H33A . . 109.5 ?
    O32 C33 H33B . . 109.5 ?
    O32 C33 H33C . . 109.5 ?
    H33A C33 H33B . . 109.5 ?
    H33A C33 H33C . . 109.5 ?
    H33B C33 H33C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Pt1A N2 C3 C4 . . . . 85.5(5) ?
    Pt1A N2 C3 C8 . . . . -92.9(5) ?
    Pt1A C14 C15 C16 . . . . -106.8(7) ?
    Pt1A C15 C16 C20 . . . . 83.1(6) ?
    Pt1B N2 C3 C4 . . . . 76.9(6) ?
    Pt1B N2 C3 C8 . . . . -101.5(5) ?
    Pt1B C17 C18 C19 . . . . 109(2) ?
    Pt1B C18 C19 C20 . . . . -65(2) ?
    N2 C3 C4 C5 . . . . -176.4(5) ?
    N2 C3 C8 C7 . . . . 177.4(5) ?
    C3 C4 C5 C6 . . . . -1.9(10) ?
    C4 C3 C8 C7 . . . . -1.0(8) ?
    C4 C5 C6 C7 . . . . 0.9(9) ?
    C4 C5 C6 Cl9 . . . . 179.6(5) ?
    C5 C6 C7 C8 . . . . 0.1(8) ?
    C6 C7 C8 C3 . . . . 0.0(8) ?
    C8 C3 C4 C5 . . . . 2.0(9) ?
    Cl9 C6 C7 C8 . . . . -178.7(4) ?
    C14 C15 C16 C20 . . . . 164.0(7) ?
    C15 C16 C20 C21 . . . . 80.3(8) ?
    C15 C16 C20 C25 . . . . -104.0(7) ?
    C16 C20 C21 C22 . . . . 175.0(5) ?
    C16 C20 C25 C24 . . . . -173.7(6) ?
    C17 C18 C19 C20 . . . . -153(2) ?
    C18 C19 C20 C21 . . . . 170.4(16) ?
    C18 C19 C20 C25 . . . . 9(3) ?
    C19 C20 C21 C22 . . . . -165.6(9) ?
    C19 C20 C25 C24 . . . . 161.9(12) ?
    C20 C21 C22 C23 . . . . -1.4(8) ?
    C20 C21 C22 O26 . . . . 177.9(5) ?
    C21 C20 C25 C24 . . . . 2.1(9) ?
    C21 C22 C23 C24 . . . . 1.9(7) ?
    C21 C22 C23 O28 . . . . 179.7(4) ?
    C21 C22 O26 C27 . . . . -2.8(7) ?
    C22 C23 C24 C25 . . . . -0.5(8) ?
    C22 C23 O28 C29 . . . . -179.6(5) ?
    C23 C22 O26 C27 . . . . 176.5(4) ?
    C23 C24 C25 C20 . . . . -1.6(9) ?
    C23 O28 C29 C30 . . . . 173.5(4) ?
    C24 C23 O28 C29 . . . . -2.0(8) ?
    C25 C20 C21 C22 . . . . -0.6(8) ?
    O26 C22 C23 C24 . . . . -177.4(5) ?
    O26 C22 C23 O28 . . . . 0.3(6) ?
    O28 C23 C24 C25 . . . . -178.0(5) ?
    O28 C29 C30 O31 . . . . -23.3(9) ?
    O28 C29 C30 O32 . . . . 165.6(5) ?
    C29 C30 O32 C33 . . . . -179.7(6) ?
    O31 C30 O32 C33 . . . . 9.4(11) ?
loop_
    _geom_hbond_atom_site_label_d
    _geom_hbond_atom_site_label_h
    _geom_hbond_atom_site_label_a
    _geom_hbond_site_symmetry_d
    _geom_hbond_site_symmetry_h
    _geom_hbond_site_symmetry_a
    _geom_hbond_distance_dh
    _geom_hbond_distance_ha
    _geom_hbond_distance_da
    _geom_hbond_angle_dha
    _geom_hbond_publ_flag
    N2 H2AA O26 1_555 1_555 3_545 0.91 2.45 3.027(5) 122 y
    N2 H2AA O28 1_555 1_555 3_545 0.91 2.35 3.212(6) 158 y
    N2 H2AB O31 1_555 1_555 4_646 0.91 2.41 3.302(3) 167 y
    C16 H16A Cl12 1_555 1_555 1_555 0.99 2.79 3.487(10) 128 y
    C16 H16B Cl9 1_555 1_555 3_445 0.99 2.76 3.472(8) 129 y
    C21 H21 Cl11 1_555 1_555 2_656 0.95 2.82 3.726(8) 159 y
    C29 H29B Cl12 1_555 1_555 7_667 0.99 2.80 3.651(7) 145 y
    C27 H27B Cg1 1_555 1_555 2_656 0.98 2.72 3.523(6) 139 y
data_II
_database_code_depnum_ccdc_archive 'CCDC 1483067'
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_journal_date_recd_electronic     2016-05-24
_journal_date_accepted     2016-06-01
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2016
_journal_volume     72
_journal_issue      7
_journal_page_first     912
_journal_page_last     917
_journal_paper_category     GM
_journal_paper_doi     10.1107/S2056989016008872
_journal_coeditor_code     RZ5189
_chemical_name_systematic
;\
trans-Dichlorido(4-chloroaniline-κN){4-ethoxycarbonylmethoxy-\
3-methoxy-1-[(2,3-η)-prop-2-en-1-yl]benzene}platinum(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C20 H24 Cl3 N O4 Pt'
_chemical_formula_sum     'C20 H24 Cl3 N O4 Pt'
_chemical_formula_iupac     '[Pt Cl2 (C6 H6 Cl N) (C14 H18 O4)]'
_chemical_formula_weight     643.84
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     triclinic
_space_group_name_H-M_alt     'P -1'
_space_group_name_Hall     '-P 1'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     9.9093(3)
_cell_length_b     10.0102(3)
_cell_length_c     11.1414(4)
_cell_angle_alpha     97.302(3)
_cell_angle_beta     99.706(3)
_cell_angle_gamma     92.572(2)
_cell_volume     1078.01(6)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     10730
_cell_measurement_theta_min     3.2010
_cell_measurement_theta_max     28.9660
_cell_measurement_temperature     100.0
_exptl_crystal_description     block
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.3
_exptl_crystal_size_mid     0.3
_exptl_crystal_size_min     0.15
_exptl_crystal_density_diffrn     1.984
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     624
_exptl_absorpt_coefficient_mu     6.907
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Agilent, 2012)
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
_exptl_absorpt_correction_T_min     0.54705
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     100.0
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     mirror
_diffrn_measurement_device_type
;
Agilent SuperNova diffractometer (single source at offset, Eos detector)
;
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     15.9631
_diffrn_reflns_number     22329
_diffrn_reflns_av_R_equivalents     0.0444
_diffrn_reflns_theta_min     2.831
_diffrn_reflns_theta_max     26.371
_diffrn_reflns_theta_full     25.000
_diffrn_measured_fraction_theta_max     0.995
_diffrn_measured_fraction_theta_full     0.995
_diffrn_reflns_limit_h_min     -12
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -12
_diffrn_reflns_limit_k_max     12
_diffrn_reflns_limit_l_min     -13
_diffrn_reflns_limit_l_max     13
_refine_special_details     ?
_reflns_number_total     4378
_reflns_number_gt     4177
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0288
_refine_ls_R_factor_gt     0.0264
_refine_ls_wR_factor_gt     0.0555
_refine_ls_wR_factor_ref     0.0565
_refine_ls_goodness_of_fit_ref     1.199
_refine_ls_restrained_S_all     1.168
_refine_ls_number_reflns     4378
_refine_ls_number_parameters     292
_refine_ls_number_restraints     264
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0056P)²+3.1214P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.966
_refine_diff_density_min     -0.963
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Agilent, 2012)
;
_computing_cell_refinement
;
CrysAlis PRO (Agilent, 2012)
;
_computing_data_reduction
;
CrysAlis PRO (Agilent, 2012)
;
_computing_structure_solution
;
olex2.solve (Bourhis et al.,  2015)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Pt Pt1A 0.69549(11) 0.29586(10) 0.25083(7) 0.01218(14) Uani d 0.872(6) A 1
    Pt Pt1B 0.6572(11) 0.2618(9) 0.2299(6) 0.0263(11) Uani d 0.128(6) A 2
    N N2 0.6352(4) 0.3773(4) 0.4142(3) 0.0175(7) Uani d 1 . .
    H H2AA 0.6687 0.4649 0.4346 0.021 Uiso calc 0.872(6) A 1
    H H2AB 0.5420 0.3754 0.4033 0.021 Uiso calc 0.872(6) A 1
    H H2BC 0.6834 0.4588 0.4258 0.021 Uiso calc 0.128(6) A 2
    H H2BD 0.5454 0.3921 0.4147 0.021 Uiso calc 0.128(6) A 2
    C C3 0.6861(4) 0.3007(4) 0.5131(4) 0.0172(9) Uani d 1 . .
    C C4 0.8223(4) 0.3217(4) 0.5704(4) 0.0191(9) Uani d 1 . .
    H H4 0.8815 0.3854 0.5446 0.023 Uiso calc 1 . .
    C C5 0.8722(4) 0.2504(4) 0.6650(4) 0.0194(9) Uani d 1 . .
    H H5 0.9653 0.2646 0.7049 0.023 Uiso calc 1 . .
    C C6 0.7836(4) 0.1577(4) 0.7002(4) 0.0182(9) Uani d 1 . .
    C C7 0.6483(4) 0.1340(4) 0.6433(4) 0.0191(9) Uani d 1 . .
    H H7 0.5897 0.0692 0.6685 0.023 Uiso calc 1 . .
    C C8 0.5994(4) 0.2062(4) 0.5490(4) 0.0199(9) Uani d 1 . .
    H H8 0.5065 0.1912 0.5088 0.024 Uiso calc 1 . .
    Cl Cl9 0.84620(12) 0.06618(11) 0.81957(10) 0.0252(2) Uani d 1 . .
    Cl Cl10 0.88980(15) 0.4404(2) 0.30141(16) 0.0170(4) Uani d 0.872(6) A 1
    Cl Cl11 0.4916(2) 0.1647(2) 0.20164(18) 0.0173(4) Uani d 0.872(6) A 1
    Cl Cl12 0.8689(13) 0.377(2) 0.2675(13) 0.037(3) Uani d 0.128(6) A 2
    Cl Cl13 0.4387(19) 0.1586(18) 0.1984(16) 0.034(3) Uani d 0.128(6) A 2
    C C14 0.7274(5) 0.2580(5) 0.0645(4) 0.0236(10) Uani d 1 . .
    H H14A 0.6473 0.2280 0.0057 0.028 Uiso calc 1 A .
    H H14B 0.7579 0.3509 0.0794 0.028 Uiso calc 1 A .
    C C15 0.8002(5) 0.1655(5) 0.1289(4) 0.0242(10) Uani d 1 . .
    H H15 0.9021 0.1839 0.1437 0.029 Uiso calc 0.872(6) A 1
    H H15A 0.9000 0.1894 0.1608 0.029 Uiso calc 0.128(6) A 2
    C C16 0.7539(5) 0.0195(4) 0.1067(4) 0.0245(10) Uani d 1 . .
    H H16A 0.8108 -0.0272 0.0517 0.029 Uiso calc 1 . .
    H H16B 0.6582 0.0106 0.0616 0.029 Uiso calc 1 . .
    C C17 0.7586(5) -0.0551(4) 0.2180(4) 0.0186(9) Uani d 1 . .
    C C18 0.6816(4) -0.1797(4) 0.1979(4) 0.0187(9) Uani d 1 . .
    H H18 0.6308 -0.2117 0.1184 0.022 Uiso calc 1 . .
    C C19 0.6787(4) -0.2565(4) 0.2923(4) 0.0161(8) Uani d 1 . .
    C C20 0.7528(4) -0.2097(4) 0.4101(4) 0.0143(8) Uani d 1 . .
    C C21 0.8282(4) -0.0865(4) 0.4312(4) 0.0174(9) Uani d 1 . .
    H H21 0.8780 -0.0536 0.5108 0.021 Uiso calc 1 . .
    C C22 0.8303(4) -0.0106(4) 0.3335(4) 0.0196(9) Uani d 1 . .
    H H22 0.8827 0.0736 0.3480 0.023 Uiso calc 1 . .
    O O23 0.6053(3) -0.3770(3) 0.2818(3) 0.0183(6) Uani d 1 . .
    C C24 0.5250(5) -0.4260(4) 0.1644(4) 0.0241(10) Uani d 1 . .
    H H24A 0.5845 -0.4341 0.1023 0.036 Uiso calc 1 . .
    H H24B 0.4549 -0.3629 0.1430 0.036 Uiso calc 1 . .
    H H24C 0.4805 -0.5147 0.1672 0.036 Uiso calc 1 . .
    O O25 0.7390(3) -0.2930(3) 0.4975(3) 0.0168(6) Uani d 1 . .
    C C26 0.8067(4) -0.2464(4) 0.6172(4) 0.0183(9) Uani d 1 . .
    H H26A 0.7842 -0.1526 0.6418 0.022 Uiso calc 1 . .
    H H26B 0.9072 -0.2473 0.6214 0.022 Uiso calc 1 . .
    C C27 0.7604(4) -0.3380(4) 0.7025(4) 0.0157(8) Uani d 1 . .
    O O28 0.6689(3) -0.4258(3) 0.6725(3) 0.0176(6) Uani d 1 . .
    O O29 0.8362(3) -0.3074(3) 0.8142(3) 0.0180(6) Uani d 1 . .
    C C30 0.8025(5) -0.3861(5) 0.9070(4) 0.0212(10) Uani d 1 . .
    H H30A 0.8025 -0.4837 0.8776 0.025 Uiso calc 1 . .
    H H30B 0.7103 -0.3668 0.9249 0.025 Uiso calc 1 . .
    C C31 0.9091(4) -0.3475(4) 1.0205(4) 0.0200(9) Uani d 1 . .
    H H31A 0.9993 -0.3714 1.0028 0.030 Uiso calc 1 . .
    H H31B 0.8865 -0.3960 1.0864 0.030 Uiso calc 1 . .
    H H31C 0.9112 -0.2501 1.0465 0.030 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Pt1A N2 . 2.089(4) ?
    Pt1A Cl10 . 2.3011(14) ?
    Pt1A Cl11 . 2.3050(15) ?
    Pt1A C14 . 2.142(5) ?
    Pt1A C15 . 2.184(5) ?
    Pt1B N2 . 2.273(8) ?
    Pt1B Cl12 . 2.297(12) ?
    Pt1B Cl13 . 2.309(14) ?
    Pt1B C14 . 2.073(6) ?
    Pt1B C15 . 2.142(6) ?
    N2 H2AA . 0.9100 ?
    N2 H2AB . 0.9100 ?
    N2 H2BC . 0.9100 ?
    N2 H2BD . 0.9100 ?
    N2 C3 . 1.455(5) ?
    C3 C4 . 1.387(6) ?
    C3 C8 . 1.390(6) ?
    C4 H4 . 0.9500 ?
    C4 C5 . 1.383(6) ?
    C5 H5 . 0.9500 ?
    C5 C6 . 1.387(6) ?
    C6 C7 . 1.379(6) ?
    C6 Cl9 . 1.754(4) ?
    C7 H7 . 0.9500 ?
    C7 C8 . 1.384(6) ?
    C8 H8 . 0.9500 ?
    C14 H14A . 0.9500 ?
    C14 H14B . 0.9500 ?
    C14 C15 . 1.396(6) ?
    C15 H15 . 1.0000 ?
    C15 H15A . 1.0000 ?
    C15 C16 . 1.489(6) ?
    C16 H16A . 0.9900 ?
    C16 H16B . 0.9900 ?
    C16 C17 . 1.522(6) ?
    C17 C18 . 1.406(6) ?
    C17 C22 . 1.371(6) ?
    C18 H18 . 0.9500 ?
    C18 C19 . 1.382(6) ?
    C19 C20 . 1.403(6) ?
    C19 O23 . 1.362(5) ?
    C20 C21 . 1.385(6) ?
    C20 O25 . 1.380(5) ?
    C21 H21 . 0.9500 ?
    C21 C22 . 1.406(6) ?
    C22 H22 . 0.9500 ?
    O23 C24 . 1.427(5) ?
    C24 H24A . 0.9800 ?
    C24 H24B . 0.9800 ?
    C24 H24C . 0.9800 ?
    O25 C26 . 1.399(5) ?
    C26 H26A . 0.9900 ?
    C26 H26B . 0.9900 ?
    C26 C27 . 1.512(5) ?
    C27 O28 . 1.207(5) ?
    C27 O29 . 1.332(5) ?
    O29 C30 . 1.449(5) ?
    C30 H30A . 0.9900 ?
    C30 H30B . 0.9900 ?
    C30 C31 . 1.501(6) ?
    C31 H31A . 0.9800 ?
    C31 H31B . 0.9800 ?
    C31 H31C . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N2 Pt1A Cl10 . . 88.86(10) ?
    N2 Pt1A Cl11 . . 88.77(11) ?
    N2 Pt1A C14 . . 163.99(15) ?
    N2 Pt1A C15 . . 158.31(16) ?
    Cl10 Pt1A Cl11 . . 175.82(7) ?
    C14 Pt1A Cl10 . . 90.53(14) ?
    C14 Pt1A Cl11 . . 90.80(15) ?
    C14 Pt1A C15 . . 37.62(17) ?
    C15 Pt1A Cl10 . . 89.13(14) ?
    C15 Pt1A Cl11 . . 94.33(15) ?
    N2 Pt1B Cl12 . . 83.8(4) ?
    N2 Pt1B Cl13 . . 93.1(5) ?
    Cl12 Pt1B Cl13 . . 176.1(6) ?
    C14 Pt1B N2 . . 149.1(6) ?
    C14 Pt1B Cl12 . . 71.8(5) ?
    C14 Pt1B Cl13 . . 110.3(7) ?
    C14 Pt1B C15 . . 38.62(18) ?
    C15 Pt1B N2 . . 143.8(6) ?
    C15 Pt1B Cl12 . . 67.1(6) ?
    C15 Pt1B Cl13 . . 116.7(7) ?
    Pt1A N2 H2AA . . 109.6 ?
    Pt1A N2 H2AB . . 109.6 ?
    Pt1B N2 H2BC . . 109.6 ?
    Pt1B N2 H2BD . . 109.6 ?
    H2AA N2 H2AB . . 108.1 ?
    H2BC N2 H2BD . . 108.2 ?
    C3 N2 Pt1A . . 110.4(3) ?
    C3 N2 Pt1B . . 110.1(3) ?
    C3 N2 H2AA . . 109.6 ?
    C3 N2 H2AB . . 109.6 ?
    C3 N2 H2BC . . 109.6 ?
    C3 N2 H2BD . . 109.6 ?
    C4 C3 N2 . . 119.5(4) ?
    C4 C3 C8 . . 120.2(4) ?
    C8 C3 N2 . . 120.4(4) ?
    C3 C4 H4 . . 119.9 ?
    C5 C4 C3 . . 120.3(4) ?
    C5 C4 H4 . . 119.9 ?
    C4 C5 H5 . . 120.7 ?
    C4 C5 C6 . . 118.6(4) ?
    C6 C5 H5 . . 120.7 ?
    C5 C6 Cl9 . . 118.9(3) ?
    C7 C6 C5 . . 122.1(4) ?
    C7 C6 Cl9 . . 119.0(3) ?
    C6 C7 H7 . . 120.6 ?
    C6 C7 C8 . . 118.7(4) ?
    C8 C7 H7 . . 120.6 ?
    C3 C8 H8 . . 119.9 ?
    C7 C8 C3 . . 120.1(4) ?
    C7 C8 H8 . . 119.9 ?
    Pt1A C14 H14A . . 115.0 ?
    Pt1A C14 H14B . . 82.6 ?
    H14A C14 H14B . . 120.0 ?
    C15 C14 Pt1A . . 72.9(3) ?
    C15 C14 Pt1B . . 73.4(3) ?
    C15 C14 H14A . . 120.0 ?
    C15 C14 H14B . . 120.0 ?
    Pt1A C15 H15 . . 114.2 ?
    Pt1B C15 H15A . . 117.2 ?
    C14 C15 Pt1A . . 69.5(3) ?
    C14 C15 Pt1B . . 68.0(3) ?
    C14 C15 H15 . . 114.2 ?
    C14 C15 H15A . . 117.2 ?
    C14 C15 C16 . . 120.7(4) ?
    C16 C15 Pt1A . . 116.5(3) ?
    C16 C15 Pt1B . . 105.3(4) ?
    C16 C15 H15 . . 114.2 ?
    C16 C15 H15A . . 117.2 ?
    C15 C16 H16A . . 107.9 ?
    C15 C16 H16B . . 107.9 ?
    C15 C16 C17 . . 117.8(4) ?
    H16A C16 H16B . . 107.2 ?
    C17 C16 H16A . . 107.9 ?
    C17 C16 H16B . . 107.9 ?
    C18 C17 C16 . . 115.9(4) ?
    C22 C17 C16 . . 125.5(4) ?
    C22 C17 C18 . . 118.6(4) ?
    C17 C18 H18 . . 119.6 ?
    C19 C18 C17 . . 120.8(4) ?
    C19 C18 H18 . . 119.6 ?
    C18 C19 C20 . . 119.9(4) ?
    O23 C19 C18 . . 124.8(4) ?
    O23 C19 C20 . . 115.2(3) ?
    C21 C20 C19 . . 119.7(4) ?
    O25 C20 C19 . . 114.7(3) ?
    O25 C20 C21 . . 125.6(4) ?
    C20 C21 H21 . . 120.3 ?
    C20 C21 C22 . . 119.4(4) ?
    C22 C21 H21 . . 120.3 ?
    C17 C22 C21 . . 121.5(4) ?
    C17 C22 H22 . . 119.2 ?
    C21 C22 H22 . . 119.2 ?
    C19 O23 C24 . . 117.0(3) ?
    O23 C24 H24A . . 109.5 ?
    O23 C24 H24B . . 109.5 ?
    O23 C24 H24C . . 109.5 ?
    H24A C24 H24B . . 109.5 ?
    H24A C24 H24C . . 109.5 ?
    H24B C24 H24C . . 109.5 ?
    C20 O25 C26 . . 116.1(3) ?
    O25 C26 H26A . . 110.0 ?
    O25 C26 H26B . . 110.0 ?
    O25 C26 C27 . . 108.3(3) ?
    H26A C26 H26B . . 108.4 ?
    C27 C26 H26A . . 110.0 ?
    C27 C26 H26B . . 110.0 ?
    O28 C27 C26 . . 124.6(4) ?
    O28 C27 O29 . . 125.8(4) ?
    O29 C27 C26 . . 109.7(3) ?
    C27 O29 C30 . . 116.1(3) ?
    O29 C30 H30A . . 110.2 ?
    O29 C30 H30B . . 110.2 ?
    O29 C30 C31 . . 107.6(3) ?
    H30A C30 H30B . . 108.5 ?
    C31 C30 H30A . . 110.2 ?
    C31 C30 H30B . . 110.2 ?
    C30 C31 H31A . . 109.5 ?
    C30 C31 H31B . . 109.5 ?
    C30 C31 H31C . . 109.5 ?
    H31A C31 H31B . . 109.5 ?
    H31A C31 H31C . . 109.5 ?
    H31B C31 H31C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Pt1A N2 C3 C4 . . . . 78.3(4) ?
    Pt1A N2 C3 C8 . . . . -101.0(4) ?
    Pt1A C14 C15 C16 . . . . 109.4(4) ?
    Pt1A C15 C16 C17 . . . . -56.7(5) ?
    Pt1B N2 C3 C4 . . . . 91.5(5) ?
    Pt1B N2 C3 C8 . . . . -87.8(5) ?
    Pt1B C14 C15 C16 . . . . 95.3(6) ?
    Pt1B C15 C16 C17 . . . . -64.4(5) ?
    N2 C3 C4 C5 . . . . 179.7(4) ?
    N2 C3 C8 C7 . . . . -179.8(4) ?
    C3 C4 C5 C6 . . . . 0.3(7) ?
    C4 C3 C8 C7 . . . . 0.9(7) ?
    C4 C5 C6 C7 . . . . 0.6(7) ?
    C4 C5 C6 Cl9 . . . . 179.7(3) ?
    C5 C6 C7 C8 . . . . -0.7(7) ?
    C6 C7 C8 C3 . . . . 0.0(7) ?
    C8 C3 C4 C5 . . . . -1.0(7) ?
    Cl9 C6 C7 C8 . . . . -179.8(3) ?
    C14 C15 C16 C17 . . . . -137.6(5) ?
    C15 C16 C17 C18 . . . . 163.5(4) ?
    C15 C16 C17 C22 . . . . -16.3(7) ?
    C16 C17 C18 C19 . . . . 179.8(4) ?
    C16 C17 C22 C21 . . . . 179.8(4) ?
    C17 C18 C19 C20 . . . . 0.3(6) ?
    C17 C18 C19 O23 . . . . 178.8(4) ?
    C18 C17 C22 C21 . . . . 0.0(7) ?
    C18 C19 C20 C21 . . . . 0.2(6) ?
    C18 C19 C20 O25 . . . . 178.3(4) ?
    C18 C19 O23 C24 . . . . -0.5(6) ?
    C19 C20 C21 C22 . . . . -0.6(6) ?
    C19 C20 O25 C26 . . . . -177.2(3) ?
    C20 C19 O23 C24 . . . . 178.1(4) ?
    C20 C21 C22 C17 . . . . 0.5(7) ?
    C20 O25 C26 C27 . . . . 170.4(3) ?
    C21 C20 O25 C26 . . . . 0.7(6) ?
    C22 C17 C18 C19 . . . . -0.4(6) ?
    O23 C19 C20 C21 . . . . -178.5(4) ?
    O23 C19 C20 O25 . . . . -0.4(5) ?
    O25 C20 C21 C22 . . . . -178.4(4) ?
    O25 C26 C27 O28 . . . . -7.9(6) ?
    O25 C26 C27 O29 . . . . 171.8(3) ?
    C26 C27 O29 C30 . . . . 179.3(3) ?
    C27 O29 C30 C31 . . . . 173.4(4) ?
    O28 C27 O29 C30 . . . . -1.1(6) ?
loop_
    _geom_hbond_atom_site_label_d
    _geom_hbond_atom_site_label_h
    _geom_hbond_atom_site_label_a
    _geom_hbond_site_symmetry_d
    _geom_hbond_site_symmetry_h
    _geom_hbond_site_symmetry_a
    _geom_hbond_distance_dh
    _geom_hbond_distance_ha
    _geom_hbond_distance_da
    _geom_hbond_angle_dha
    _geom_hbond_publ_flag
    N2 H2AA O23 1_555 1_555 1_565 0.91 2.49 3.025(5) 118 y
    N2 H2AA O25 1_555 1_555 1_565 0.91 2.47 3.377(5) 174 y
    N2 H2AB O28 1_555 1_555 2_656 0.91 2.22 3.085(5) 158 y
    C26 H26A Cl9 1_555 1_555 1_555 0.99 2.73 3.581(4) 144 y
