##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_database_code_depnum_ccdc_archive 'CCDC 1060013'
_audit_creation_method     SHELXL-2014/6
_chemical_name_systematic
;
Bis[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver(I)
chloride tetrahydrofuran monosolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C54 H72 Ag N4 +, Cl -, C4 H8 O'
_chemical_formula_sum     'C58 H80 Ag Cl N4 O'
_chemical_formula_iupac     '[Ag (C27 H36 N2)2] Cl, C4 H8 O'
_chemical_formula_weight     992.58
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/n'
_space_group_name_Hall     '-P 2yn'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     11.9302(3)
_cell_length_b     18.3390(5)
_cell_length_c     26.0144(6)
_cell_angle_alpha     90
_cell_angle_beta     103.068(2)
_cell_angle_gamma     90
_cell_volume     5544.2(2)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     115747
_cell_measurement_theta_min     2.0
_cell_measurement_theta_max     30.3
_cell_measurement_temperature     173(2)
_exptl_crystal_description     block
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.310
_exptl_crystal_size_mid     0.270
_exptl_crystal_size_min     0.260
_exptl_crystal_density_diffrn     1.189
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     2112
_exptl_absorpt_coefficient_mu     0.452
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(X-AREA; Stoe & Cie, 2001)
;
_shelx_estimated_absorpt_T_min     0.873
_shelx_estimated_absorpt_T_max     0.892
_exptl_absorpt_correction_T_min     0.571
_exptl_absorpt_correction_T_max     1.000
_diffrn_ambient_temperature     173(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     'plane graphite'
_diffrn_measurement_device_type     'Stoe IPDS 2'
_diffrn_measurement_device     '2-circle goniometer'
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     111561
_diffrn_reflns_av_R_equivalents     0.0751
_diffrn_reflns_theta_min     2.075
_diffrn_reflns_theta_max     30.067
_diffrn_reflns_theta_full     25.000
_diffrn_measured_fraction_theta_max     0.981
_diffrn_measured_fraction_theta_full     0.998
_diffrn_reflns_limit_h_min     -16
_diffrn_reflns_limit_h_max     16
_diffrn_reflns_limit_k_min     -25
_diffrn_reflns_limit_k_max     25
_diffrn_reflns_limit_l_min     -36
_diffrn_reflns_limit_l_max     36
_refine_special_details     ?
_reflns_number_total     15949
_reflns_number_gt     13800
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0561
_refine_ls_R_factor_gt     0.0479
_refine_ls_wR_factor_gt     0.1147
_refine_ls_wR_factor_ref     0.1208
_refine_ls_goodness_of_fit_ref     1.049
_refine_ls_restrained_S_all     1.078
_refine_ls_number_reflns     15949
_refine_ls_number_parameters     651
_refine_ls_number_restraints     75
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0596P)²+3.8737P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.030
_refine_diff_density_min     -1.373
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ag' 'Ag' -0.8971 1.1015
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
X-AREA (Stoe & Cie, 2001)
;
_computing_cell_refinement
;
X-AREA (Stoe & Cie, 2001)
;
_computing_data_reduction
;
X-RED32 (Stoe & Cie, 2001)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
XP (Sheldrick, 2008)
;
_computing_publication_material
;
SHELXL2014 (Sheldrick, 2015), PLATON (Spek, 2009) and
publCIF (Westrip, 2010)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Cl Cl1 -0.25283(7) 0.79025(8) 0.41564(3) 0.0832(3) Uani d 1 . .
    Ag Ag1 0.32700(2) 0.73977(2) 0.61445(2) 0.02859(5) Uani d 1 . .
    N N1 0.10444(15) 0.66141(9) 0.55242(7) 0.0324(3) Uani d 1 . .
    N N2 0.09066(15) 0.77562(9) 0.53662(7) 0.0318(3) Uani d 1 . .
    C C1 0.16299(17) 0.72485(11) 0.56468(7) 0.0295(4) Uani d 1 . .
    C C2 -0.00005(19) 0.67258(12) 0.51718(8) 0.0366(4) Uani d 1 . .
    H H2 -0.0549 0.6362 0.5028 0.044 Uiso calc 1 . .
    C C3 -0.00911(19) 0.74443(12) 0.50725(9) 0.0365(4) Uani d 1 . .
    H H3 -0.0714 0.7689 0.4846 0.044 Uiso calc 1 . .
    C C11 0.14323(19) 0.58950(11) 0.57077(8) 0.0339(4) Uani d 1 . .
    C C12 0.11632(19) 0.56315(12) 0.61711(9) 0.0376(4) Uani d 1 . .
    C C13 0.1487(2) 0.49169(14) 0.63150(11) 0.0472(5) Uani d 1 . .
    H H13 0.1342 0.4726 0.6633 0.057 Uiso calc 1 . .
    C C14 0.2013(3) 0.44784(14) 0.60066(12) 0.0512(6) Uani d 1 . .
    H H14 0.2208 0.3989 0.6109 0.061 Uiso calc 1 . .
    C C15 0.2255(2) 0.47539(13) 0.55510(11) 0.0472(5) Uani d 1 . .
    H H15 0.2613 0.4449 0.5340 0.057 Uiso calc 1 . .
    C C16 0.1985(2) 0.54696(12) 0.53932(9) 0.0397(5) Uani d 1 . .
    C C17 0.0557(2) 0.61055(14) 0.65057(9) 0.0418(5) Uani d 1 . .
    H H17 0.0084 0.6472 0.6266 0.050 Uiso calc 1 . .
    C C18 0.2273(3) 0.57670(15) 0.48954(10) 0.0484(6) Uani d 1 . .
    H H18 0.2044 0.6292 0.4862 0.058 Uiso calc 1 . .
    C C21 0.11102(17) 0.85337(11) 0.53718(8) 0.0315(4) Uani d 1 . .
    C C22 0.16141(18) 0.88315(12) 0.49827(8) 0.0355(4) Uani d 1 . .
    C C23 0.1789(2) 0.95834(13) 0.49946(10) 0.0414(5) Uani d 1 . .
    H H23 0.2142 0.9802 0.4740 0.050 Uiso calc 1 . .
    C C24 0.1459(2) 1.00192(12) 0.53687(10) 0.0421(5) Uani d 1 . .
    H H24 0.1595 1.0530 0.5372 0.051 Uiso calc 1 . .
    C C25 0.0930(2) 0.97107(12) 0.57377(9) 0.0389(4) Uani d 1 . .
    H H25 0.0694 1.0015 0.5989 0.047 Uiso calc 1 . .
    C C26 0.07386(18) 0.89620(11) 0.57481(8) 0.0342(4) Uani d 1 . .
    C C27 0.1978(2) 0.83601(14) 0.45695(9) 0.0421(5) Uani d 1 . .
    H H27 0.1554 0.7887 0.4552 0.050 Uiso calc 1 . .
    C C28 0.0168(2) 0.86275(13) 0.61588(9) 0.0408(5) Uani d 1 . .
    H H28 -0.0058 0.8116 0.6047 0.049 Uiso calc 1 . .
    N N3 0.53162(16) 0.72843(10) 0.71425(7) 0.0346(4) Uani d 1 . .
    N N4 0.57794(15) 0.79569(11) 0.65566(7) 0.0350(4) Uani d 1 . .
    C C4 0.48997(17) 0.75476(11) 0.66489(8) 0.0292(3) Uani d 1 . .
    C C5 0.6422(2) 0.75307(16) 0.73539(10) 0.0474(6) Uani d 1 . .
    H H5 0.6884 0.7420 0.7693 0.057 Uiso calc 1 . .
    C C6 0.6713(2) 0.79563(16) 0.69851(10) 0.0476(6) Uani d 1 . .
    H H6 0.7420 0.8208 0.7012 0.057 Uiso calc 1 . .
    C C31 0.47404(19) 0.67686(12) 0.74141(8) 0.0346(4) Uani d 1 . .
    C C32 0.4827(2) 0.60301(13) 0.72966(9) 0.0421(5) Uani d 1 . .
    C C33 0.4296(3) 0.55367(14) 0.75715(11) 0.0501(6) Uani d 1 . .
    H H33 0.4320 0.5030 0.7498 0.060 Uiso calc 1 . .
    C C34 0.3733(2) 0.57756(15) 0.79501(10) 0.0492(6) Uani d 1 . .
    H H34 0.3372 0.5431 0.8133 0.059 Uiso calc 1 . .
    C C35 0.3688(2) 0.65110(14) 0.80671(9) 0.0444(5) Uani d 1 . .
    H H35 0.3312 0.6664 0.8334 0.053 Uiso calc 1 . .
    C C36 0.4192(2) 0.70272(12) 0.77967(8) 0.0377(4) Uani d 1 . .
    C C37 0.5505(3) 0.57671(16) 0.69008(12) 0.0538(6) Uani d 1 . .
    H H37 0.5788 0.6208 0.6743 0.065 Uiso calc 1 . .
    C C38 0.4136(2) 0.78324(14) 0.79234(10) 0.0451(5) Uani d 1 . .
    H H38 0.4406 0.8116 0.7646 0.054 Uiso calc 1 . .
    C C41 0.58009(17) 0.83616(12) 0.60799(8) 0.0333(4) Uani d 1 . .
    C C42 0.61299(18) 0.79945(13) 0.56671(9) 0.0370(4) Uani d 1 . .
    C C43 0.6249(2) 0.84112(15) 0.52329(9) 0.0428(5) Uani d 1 . .
    H H43 0.6468 0.8182 0.4943 0.051 Uiso calc 1 . .
    C C44 0.6050(2) 0.91521(15) 0.52225(10) 0.0477(6) Uani d 1 . .
    H H44 0.6150 0.9430 0.4928 0.057 Uiso calc 1 . .
    C C45 0.5707(2) 0.94981(14) 0.56344(10) 0.0465(5) Uani d 1 . .
    H H45 0.5560 1.0008 0.5615 0.056 Uiso calc 1 . .
    C C46 0.55756(19) 0.91082(13) 0.60776(9) 0.0389(4) Uani d 1 . .
    C C47 0.6370(2) 0.71821(15) 0.56861(11) 0.0470(5) Uani d 1 . .
    H H47 0.5884 0.6948 0.5906 0.056 Uiso calc 1 . .
    C C48 0.5198(2) 0.94851(15) 0.65304(11) 0.0484(5) Uani d 1 . .
    H H48 0.5085 0.9087 0.6776 0.058 Uiso calc 0.447(17) A 1
    H H48' 0.5559 0.9219 0.6862 0.058 Uiso calc 0.553(17) A 2
    C C171 0.1420(3) 0.65204(18) 0.69207(12) 0.0595(7) Uani d 1 . .
    H H17A 0.1009 0.6820 0.7130 0.089 Uiso calc 1 . .
    H H17B 0.1920 0.6174 0.7152 0.089 Uiso calc 1 . .
    H H17C 0.1888 0.6835 0.6748 0.089 Uiso calc 1 . .
    C C172 -0.0252(3) 0.5682(2) 0.67752(13) 0.0685(9) Uani d 1 . .
    H H17D -0.0812 0.5412 0.6509 0.103 Uiso calc 1 . .
    H H17E 0.0196 0.5338 0.7030 0.103 Uiso calc 1 . .
    H H17F -0.0658 0.6022 0.6959 0.103 Uiso calc 1 . .
    C C181 0.1623(4) 0.5374(3) 0.44116(13) 0.0885(13) Uani d 1 . .
    H H18A 0.0795 0.5405 0.4395 0.133 Uiso calc 1 . .
    H H18B 0.1791 0.5600 0.4096 0.133 Uiso calc 1 . .
    H H18C 0.1858 0.4861 0.4429 0.133 Uiso calc 1 . .
    C C271 0.1680(3) 0.87042(18) 0.40178(11) 0.0579(7) Uani d 1 . .
    H H27A 0.1931 0.8380 0.3766 0.087 Uiso calc 1 . .
    H H27B 0.0846 0.8778 0.3908 0.087 Uiso calc 1 . .
    H H27C 0.2072 0.9175 0.4026 0.087 Uiso calc 1 . .
    C C272 0.3262(3) 0.8194(2) 0.47309(13) 0.0701(9) Uani d 1 . .
    H H27D 0.3483 0.7890 0.4461 0.105 Uiso calc 1 . .
    H H27E 0.3697 0.8652 0.4767 0.105 Uiso calc 1 . .
    H H27F 0.3430 0.7935 0.5069 0.105 Uiso calc 1 . .
    C C281 0.1018(3) 0.85940(17) 0.66940(10) 0.0547(7) Uani d 1 . .
    H H28A 0.0640 0.8378 0.6955 0.082 Uiso calc 1 . .
    H H28B 0.1681 0.8295 0.6665 0.082 Uiso calc 1 . .
    H H28C 0.1278 0.9088 0.6806 0.082 Uiso calc 1 . .
    C C381 0.4926(3) 0.80103(19) 0.84580(14) 0.0658(8) Uani d 1 . .
    H H38A 0.4875 0.8532 0.8531 0.099 Uiso calc 1 . .
    H H38B 0.4687 0.7727 0.8735 0.099 Uiso calc 1 . .
    H H38C 0.5721 0.7886 0.8451 0.099 Uiso calc 1 . .
    C C382 0.2906(2) 0.80671(16) 0.79172(11) 0.0521(6) Uani d 1 . .
    H H38D 0.2895 0.8588 0.8000 0.078 Uiso calc 1 . .
    H H38E 0.2415 0.7977 0.7567 0.078 Uiso calc 1 . .
    H H38F 0.2618 0.7787 0.8181 0.078 Uiso calc 1 . .
    C C471 0.7617(3) 0.7022(2) 0.5937(2) 0.0959(15) Uani d 1 . .
    H H47A 0.7746 0.6494 0.5944 0.144 Uiso calc 1 . .
    H H47B 0.8112 0.7257 0.5732 0.144 Uiso calc 1 . .
    H H47C 0.7803 0.7212 0.6299 0.144 Uiso calc 1 . .
    C C472 0.6065(4) 0.6833(2) 0.51324(15) 0.0744(10) Uani d 1 . .
    H H47D 0.5257 0.6935 0.4967 0.112 Uiso calc 1 . .
    H H47E 0.6559 0.7039 0.4915 0.112 Uiso calc 1 . .
    H H47F 0.6184 0.6305 0.5164 0.112 Uiso calc 1 . .
    C C282 -0.0920(3) 0.90368(19) 0.62077(14) 0.0614(7) Uani d 1 . .
    H H28D -0.1255 0.8801 0.6476 0.092 Uiso calc 1 . .
    H H28E -0.0723 0.9543 0.6311 0.092 Uiso calc 1 . .
    H H28F -0.1478 0.9028 0.5867 0.092 Uiso calc 1 . .
    C C372 0.4758(3) 0.5337(2) 0.64546(13) 0.0747(10) Uani d 1 . .
    H H37A 0.5222 0.5178 0.6209 0.112 Uiso calc 1 . .
    H H37B 0.4443 0.4909 0.6599 0.112 Uiso calc 1 . .
    H H37C 0.4126 0.5645 0.6267 0.112 Uiso calc 1 . .
    C C371 0.6557(3) 0.5331(2) 0.71798(18) 0.0836(12) Uani d 1 . .
    H H37D 0.7019 0.5625 0.7465 0.125 Uiso calc 1 . .
    H H37E 0.6306 0.4884 0.7327 0.125 Uiso calc 1 . .
    H H37F 0.7021 0.5204 0.6926 0.125 Uiso calc 1 . .
    C C182 0.3550(4) 0.5721(4) 0.49240(18) 0.130(3) Uani d 1 . .
    H H18D 0.3970 0.5978 0.5240 0.195 Uiso calc 1 . .
    H H18E 0.3788 0.5209 0.4942 0.195 Uiso calc 1 . .
    H H18F 0.3721 0.5948 0.4609 0.195 Uiso calc 1 . .
    C C481 0.4036(10) 0.9851(11) 0.6354(4) 0.082(4) Uani d 0.447(17) A 1
    H H48A 0.3478 0.9501 0.6159 0.123 Uiso calc 0.447(17) A 1
    H H48B 0.3774 1.0023 0.6665 0.123 Uiso calc 0.447(17) A 1
    H H48C 0.4102 1.0267 0.6126 0.123 Uiso calc 0.447(17) A 1
    C C482 0.6139(10) 0.9942(9) 0.6833(6) 0.086(5) Uani d 0.447(17) A 1
    H H48D 0.5884 1.0182 0.7123 0.130 Uiso calc 0.447(17) A 1
    H H48E 0.6810 0.9636 0.6976 0.130 Uiso calc 0.447(17) A 1
    H H48F 0.6348 1.0313 0.6600 0.130 Uiso calc 0.447(17) A 1
    C C483 0.3931(7) 0.9449(6) 0.6467(4) 0.070(2) Uani d 0.553(17) A 2
    H H48G 0.3716 0.9696 0.6765 0.104 Uiso calc 0.553(17) A 2
    H H48H 0.3553 0.9689 0.6137 0.104 Uiso calc 0.553(17) A 2
    H H48I 0.3689 0.8937 0.6458 0.104 Uiso calc 0.553(17) A 2
    C C484 0.5609(11) 1.0302(5) 0.6600(4) 0.077(3) Uani d 0.553(17) A 2
    H H48J 0.6446 1.0323 0.6642 0.116 Uiso calc 0.553(17) A 2
    H H48K 0.5234 1.0583 0.6288 0.116 Uiso calc 0.553(17) A 2
    H H48L 0.5403 1.0508 0.6914 0.116 Uiso calc 0.553(17) A 2
    O O71 0.8401(3) 0.7674(2) 0.84592(17) 0.0709(14) Uani d 0.589(6) B 1
    C C72 0.9183(7) 0.7094(4) 0.8373(3) 0.081(2) Uani d 0.589(6) B 1
    H H72A 0.9685 0.6941 0.8712 0.097 Uiso calc 0.589(6) B 1
    H H72B 0.8739 0.6665 0.8208 0.097 Uiso calc 0.589(6) B 1
    C C73 0.9877(7) 0.7388(4) 0.8023(3) 0.0728(18) Uani d 0.589(6) B 1
    H H73A 0.9638 0.7172 0.7666 0.087 Uiso calc 0.589(6) B 1
    H H73B 1.0703 0.7281 0.8164 0.087 Uiso calc 0.589(6) B 1
    C C74 0.9636(9) 0.8317(5) 0.7999(4) 0.099(3) Uani d 0.589(6) B 1
    H H74A 1.0309 0.8617 0.7969 0.119 Uiso calc 0.589(6) B 1
    H H74B 0.8927 0.8473 0.7745 0.119 Uiso calc 0.589(6) B 1
    C C75 0.9500(11) 0.8200(7) 0.8552(5) 0.150(5) Uani d 0.589(6) B 1
    H H75A 0.9353 0.8665 0.8718 0.180 Uiso calc 0.589(6) B 1
    H H75B 1.0187 0.7962 0.8773 0.180 Uiso calc 0.589(6) B 1
    O O71' 0.9421(7) 0.7754(4) 0.7663(2) 0.084(2) Uani d 0.411(6) B 2
    C C72' 0.9671(10) 0.7119(6) 0.8015(4) 0.077(3) Uani d 0.411(6) B 2
    H H72C 1.0503 0.7004 0.8087 0.092 Uiso calc 0.411(6) B 2
    H H72D 0.9240 0.6689 0.7844 0.092 Uiso calc 0.411(6) B 2
    C C73' 0.9325(10) 0.7283(5) 0.8529(4) 0.075(3) Uani d 0.411(6) B 2
    H H73C 0.9966 0.7197 0.8838 0.090 Uiso calc 0.411(6) B 2
    H H73D 0.8645 0.6996 0.8565 0.090 Uiso calc 0.411(6) B 2
    C C74' 0.8976(9) 0.8296(5) 0.8429(4) 0.072(2) Uani d 0.411(6) B 2
    H H74C 0.8248 0.8412 0.8174 0.087 Uiso calc 0.411(6) B 2
    H H74D 0.9084 0.8590 0.8756 0.087 Uiso calc 0.411(6) B 2
    C C75' 1.0046(8) 0.8220(5) 0.8193(4) 0.075(3) Uani d 0.411(6) B 2
    H H75C 1.0672 0.7942 0.8426 0.089 Uiso calc 0.411(6) B 2
    H H75D 1.0340 0.8698 0.8105 0.089 Uiso calc 0.411(6) B 2
_geom_special_details
;
All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 C4 . 2.103(2) ?
    Ag1 C1 . 2.1058(19) ?
    N1 C1 . 1.357(2) ?
    N1 C2 . 1.385(3) ?
    N1 C11 . 1.443(3) ?
    N2 C1 . 1.364(3) ?
    N2 C3 . 1.384(3) ?
    N2 C21 . 1.446(3) ?
    C2 C3 . 1.342(3) ?
    C2 H2 . 0.9500 ?
    C3 H3 . 0.9500 ?
    C11 C16 . 1.399(3) ?
    C11 C12 . 1.402(3) ?
    C12 C13 . 1.393(3) ?
    C12 C17 . 1.524(3) ?
    C13 C14 . 1.383(4) ?
    C13 H13 . 0.9500 ?
    C14 C15 . 1.378(4) ?
    C14 H14 . 0.9500 ?
    C15 C16 . 1.391(3) ?
    C15 H15 . 0.9500 ?
    C16 C18 . 1.514(3) ?
    C17 C171 . 1.517(4) ?
    C17 C172 . 1.527(4) ?
    C17 H17 . 1.0000 ?
    C18 C181 . 1.504(4) ?
    C18 C182 . 1.511(5) ?
    C18 H18 . 1.0000 ?
    C21 C22 . 1.400(3) ?
    C21 C26 . 1.403(3) ?
    C22 C23 . 1.394(3) ?
    C22 C27 . 1.517(3) ?
    C23 C24 . 1.384(4) ?
    C23 H23 . 0.9500 ?
    C24 C25 . 1.383(3) ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.393(3) ?
    C25 H25 . 0.9500 ?
    C26 C28 . 1.520(3) ?
    C27 C272 . 1.525(4) ?
    C27 C271 . 1.534(4) ?
    C27 H27 . 1.0000 ?
    C28 C281 . 1.527(4) ?
    C28 C282 . 1.528(4) ?
    C28 H28 . 1.0000 ?
    N3 C4 . 1.356(2) ?
    N3 C5 . 1.386(3) ?
    N3 C31 . 1.444(3) ?
    N4 C4 . 1.355(3) ?
    N4 C6 . 1.387(3) ?
    N4 C41 . 1.451(2) ?
    C5 C6 . 1.342(3) ?
    C5 H5 . 0.9500 ?
    C6 H6 . 0.9500 ?
    C31 C36 . 1.392(3) ?
    C31 C32 . 1.397(3) ?
    C32 C33 . 1.392(3) ?
    C32 C37 . 1.525(4) ?
    C33 C34 . 1.383(4) ?
    C33 H33 . 0.9500 ?
    C34 C35 . 1.386(4) ?
    C34 H34 . 0.9500 ?
    C35 C36 . 1.394(3) ?
    C35 H35 . 0.9500 ?
    C36 C38 . 1.518(3) ?
    C37 C372 . 1.515(5) ?
    C37 C371 . 1.526(5) ?
    C37 H37 . 1.0000 ?
    C38 C382 . 1.526(4) ?
    C38 C381 . 1.529(4) ?
    C38 H38 . 1.0000 ?
    C41 C46 . 1.395(3) ?
    C41 C42 . 1.397(3) ?
    C42 C43 . 1.397(3) ?
    C42 C47 . 1.516(4) ?
    C43 C44 . 1.378(4) ?
    C43 H43 . 0.9500 ?
    C44 C45 . 1.384(4) ?
    C44 H44 . 0.9500 ?
    C45 C46 . 1.395(3) ?
    C45 H45 . 0.9500 ?
    C46 C48 . 1.519(3) ?
    C47 C471 . 1.512(4) ?
    C47 C472 . 1.543(4) ?
    C47 H47 . 1.0000 ?
    C48 C482 . 1.478(9) ?
    C48 C483 . 1.484(8) ?
    C48 C481 . 1.516(10) ?
    C48 C484 . 1.574(7) ?
    C48 H48 . 1.0000 ?
    C48 H48' . 1.0000 ?
    C171 H17A . 0.9800 ?
    C171 H17B . 0.9800 ?
    C171 H17C . 0.9800 ?
    C172 H17D . 0.9800 ?
    C172 H17E . 0.9800 ?
    C172 H17F . 0.9800 ?
    C181 H18A . 0.9800 ?
    C181 H18B . 0.9800 ?
    C181 H18C . 0.9800 ?
    C271 H27A . 0.9800 ?
    C271 H27B . 0.9800 ?
    C271 H27C . 0.9800 ?
    C272 H27D . 0.9800 ?
    C272 H27E . 0.9800 ?
    C272 H27F . 0.9800 ?
    C281 H28A . 0.9800 ?
    C281 H28B . 0.9800 ?
    C281 H28C . 0.9800 ?
    C381 H38A . 0.9800 ?
    C381 H38B . 0.9800 ?
    C381 H38C . 0.9800 ?
    C382 H38D . 0.9800 ?
    C382 H38E . 0.9800 ?
    C382 H38F . 0.9800 ?
    C471 H47A . 0.9800 ?
    C471 H47B . 0.9800 ?
    C471 H47C . 0.9800 ?
    C472 H47D . 0.9800 ?
    C472 H47E . 0.9800 ?
    C472 H47F . 0.9800 ?
    C282 H28D . 0.9800 ?
    C282 H28E . 0.9800 ?
    C282 H28F . 0.9800 ?
    C372 H37A . 0.9800 ?
    C372 H37B . 0.9800 ?
    C372 H37C . 0.9800 ?
    C371 H37D . 0.9800 ?
    C371 H37E . 0.9800 ?
    C371 H37F . 0.9800 ?
    C182 H18D . 0.9800 ?
    C182 H18E . 0.9800 ?
    C182 H18F . 0.9800 ?
    C481 H48A . 0.9800 ?
    C481 H48B . 0.9800 ?
    C481 H48C . 0.9800 ?
    C482 H48D . 0.9800 ?
    C482 H48E . 0.9800 ?
    C482 H48F . 0.9800 ?
    C483 H48G . 0.9800 ?
    C483 H48H . 0.9800 ?
    C483 H48I . 0.9800 ?
    C484 H48J . 0.9800 ?
    C484 H48K . 0.9800 ?
    C484 H48L . 0.9800 ?
    O71 C72 . 1.465(8) ?
    O71 C75 . 1.602(11) ?
    C72 C73 . 1.464(9) ?
    C72 H72A . 0.9900 ?
    C72 H72B . 0.9900 ?
    C73 C74 . 1.727(11) ?
    C73 H73A . 0.9900 ?
    C73 H73B . 0.9900 ?
    C74 C75 . 1.499(11) ?
    C74 H74A . 0.9900 ?
    C74 H74B . 0.9900 ?
    C75 H75A . 0.9900 ?
    C75 H75B . 0.9900 ?
    O71' C72' . 1.472(11) ?
    O71' C75' . 1.651(10) ?
    C72' C73' . 1.515(11) ?
    C72' H72C . 0.9900 ?
    C72' H72D . 0.9900 ?
    C73' C74' . 1.908(12) ?
    C73' H73C . 0.9900 ?
    C73' H73D . 0.9900 ?
    C74' C75' . 1.543(11) ?
    C74' H74C . 0.9900 ?
    C74' H74D . 0.9900 ?
    C75' H75C . 0.9900 ?
    C75' H75D . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C4 Ag1 C1 . . 179.36(7) ?
    C1 N1 C2 . . 111.53(17) ?
    C1 N1 C11 . . 126.59(17) ?
    C2 N1 C11 . . 121.83(17) ?
    C1 N2 C3 . . 111.98(17) ?
    C1 N2 C21 . . 125.69(17) ?
    C3 N2 C21 . . 122.31(17) ?
    N1 C1 N2 . . 103.28(16) ?
    N1 C1 Ag1 . . 127.82(14) ?
    N2 C1 Ag1 . . 128.90(14) ?
    C3 C2 N1 . . 107.07(18) ?
    C3 C2 H2 . . 126.5 ?
    N1 C2 H2 . . 126.5 ?
    C2 C3 N2 . . 106.12(19) ?
    C2 C3 H3 . . 126.9 ?
    N2 C3 H3 . . 126.9 ?
    C16 C11 C12 . . 122.7(2) ?
    C16 C11 N1 . . 118.33(19) ?
    C12 C11 N1 . . 118.76(19) ?
    C13 C12 C11 . . 116.9(2) ?
    C13 C12 C17 . . 121.4(2) ?
    C11 C12 C17 . . 121.7(2) ?
    C14 C13 C12 . . 121.7(2) ?
    C14 C13 H13 . . 119.2 ?
    C12 C13 H13 . . 119.2 ?
    C15 C14 C13 . . 119.8(2) ?
    C15 C14 H14 . . 120.1 ?
    C13 C14 H14 . . 120.1 ?
    C14 C15 C16 . . 121.4(2) ?
    C14 C15 H15 . . 119.3 ?
    C16 C15 H15 . . 119.3 ?
    C15 C16 C11 . . 117.5(2) ?
    C15 C16 C18 . . 120.7(2) ?
    C11 C16 C18 . . 121.8(2) ?
    C171 C17 C12 . . 111.0(2) ?
    C171 C17 C172 . . 109.0(2) ?
    C12 C17 C172 . . 113.7(2) ?
    C171 C17 H17 . . 107.6 ?
    C12 C17 H17 . . 107.6 ?
    C172 C17 H17 . . 107.6 ?
    C181 C18 C182 . . 109.8(3) ?
    C181 C18 C16 . . 111.7(2) ?
    C182 C18 C16 . . 111.0(3) ?
    C181 C18 H18 . . 108.1 ?
    C182 C18 H18 . . 108.1 ?
    C16 C18 H18 . . 108.1 ?
    C22 C21 C26 . . 122.77(19) ?
    C22 C21 N2 . . 118.44(19) ?
    C26 C21 N2 . . 118.69(18) ?
    C23 C22 C21 . . 117.2(2) ?
    C23 C22 C27 . . 120.9(2) ?
    C21 C22 C27 . . 121.88(19) ?
    C24 C23 C22 . . 121.5(2) ?
    C24 C23 H23 . . 119.3 ?
    C22 C23 H23 . . 119.3 ?
    C25 C24 C23 . . 119.9(2) ?
    C25 C24 H24 . . 120.0 ?
    C23 C24 H24 . . 120.0 ?
    C24 C25 C26 . . 121.3(2) ?
    C24 C25 H25 . . 119.4 ?
    C26 C25 H25 . . 119.4 ?
    C25 C26 C21 . . 117.3(2) ?
    C25 C26 C28 . . 120.9(2) ?
    C21 C26 C28 . . 121.81(19) ?
    C22 C27 C272 . . 110.4(2) ?
    C22 C27 C271 . . 112.7(2) ?
    C272 C27 C271 . . 110.2(2) ?
    C22 C27 H27 . . 107.8 ?
    C272 C27 H27 . . 107.8 ?
    C271 C27 H27 . . 107.8 ?
    C26 C28 C281 . . 110.2(2) ?
    C26 C28 C282 . . 112.6(2) ?
    C281 C28 C282 . . 110.2(2) ?
    C26 C28 H28 . . 107.9 ?
    C281 C28 H28 . . 107.9 ?
    C282 C28 H28 . . 107.9 ?
    C4 N3 C5 . . 111.83(18) ?
    C4 N3 C31 . . 125.68(18) ?
    C5 N3 C31 . . 122.35(18) ?
    C4 N4 C6 . . 111.76(17) ?
    C4 N4 C41 . . 126.80(17) ?
    C6 N4 C41 . . 121.44(18) ?
    N4 C4 N3 . . 103.43(17) ?
    N4 C4 Ag1 . . 127.26(14) ?
    N3 C4 Ag1 . . 129.28(14) ?
    C6 C5 N3 . . 106.4(2) ?
    C6 C5 H5 . . 126.8 ?
    N3 C5 H5 . . 126.8 ?
    C5 C6 N4 . . 106.5(2) ?
    C5 C6 H6 . . 126.7 ?
    N4 C6 H6 . . 126.7 ?
    C36 C31 C32 . . 123.8(2) ?
    C36 C31 N3 . . 118.6(2) ?
    C32 C31 N3 . . 117.5(2) ?
    C33 C32 C31 . . 116.9(2) ?
    C33 C32 C37 . . 121.0(2) ?
    C31 C32 C37 . . 122.1(2) ?
    C34 C33 C32 . . 120.7(2) ?
    C34 C33 H33 . . 119.6 ?
    C32 C33 H33 . . 119.6 ?
    C33 C34 C35 . . 120.9(2) ?
    C33 C34 H34 . . 119.6 ?
    C35 C34 H34 . . 119.6 ?
    C34 C35 C36 . . 120.5(2) ?
    C34 C35 H35 . . 119.7 ?
    C36 C35 H35 . . 119.7 ?
    C31 C36 C35 . . 117.1(2) ?
    C31 C36 C38 . . 122.5(2) ?
    C35 C36 C38 . . 120.4(2) ?
    C372 C37 C32 . . 111.8(3) ?
    C372 C37 C371 . . 111.7(3) ?
    C32 C37 C371 . . 110.5(3) ?
    C372 C37 H37 . . 107.6 ?
    C32 C37 H37 . . 107.6 ?
    C371 C37 H37 . . 107.5 ?
    C36 C38 C382 . . 111.2(2) ?
    C36 C38 C381 . . 110.9(2) ?
    C382 C38 C381 . . 110.1(2) ?
    C36 C38 H38 . . 108.2 ?
    C382 C38 H38 . . 108.2 ?
    C381 C38 H38 . . 108.2 ?
    C46 C41 C42 . . 123.9(2) ?
    C46 C41 N4 . . 117.73(19) ?
    C42 C41 N4 . . 118.2(2) ?
    C41 C42 C43 . . 117.1(2) ?
    C41 C42 C47 . . 122.2(2) ?
    C43 C42 C47 . . 120.7(2) ?
    C44 C43 C42 . . 120.4(2) ?
    C44 C43 H43 . . 119.8 ?
    C42 C43 H43 . . 119.8 ?
    C43 C44 C45 . . 121.1(2) ?
    C43 C44 H44 . . 119.5 ?
    C45 C44 H44 . . 119.5 ?
    C44 C45 C46 . . 120.9(2) ?
    C44 C45 H45 . . 119.6 ?
    C46 C45 H45 . . 119.6 ?
    C41 C46 C45 . . 116.7(2) ?
    C41 C46 C48 . . 122.3(2) ?
    C45 C46 C48 . . 121.1(2) ?
    C471 C47 C42 . . 111.4(3) ?
    C471 C47 C472 . . 109.0(3) ?
    C42 C47 C472 . . 112.0(2) ?
    C471 C47 H47 . . 108.1 ?
    C42 C47 H47 . . 108.1 ?
    C472 C47 H47 . . 108.1 ?
    C482 C48 C46 . . 110.4(4) ?
    C483 C48 C46 . . 111.5(4) ?
    C482 C48 C481 . . 116.3(7) ?
    C46 C48 C481 . . 112.3(4) ?
    C483 C48 C484 . . 109.8(5) ?
    C46 C48 C484 . . 112.5(4) ?
    C482 C48 H48 . . 105.7 ?
    C46 C48 H48 . . 105.7 ?
    C481 C48 H48 . . 105.7 ?
    C483 C48 H48' . . 107.6 ?
    C46 C48 H48' . . 107.6 ?
    C484 C48 H48' . . 107.6 ?
    C17 C171 H17A . . 109.5 ?
    C17 C171 H17B . . 109.5 ?
    H17A C171 H17B . . 109.5 ?
    C17 C171 H17C . . 109.5 ?
    H17A C171 H17C . . 109.5 ?
    H17B C171 H17C . . 109.5 ?
    C17 C172 H17D . . 109.5 ?
    C17 C172 H17E . . 109.5 ?
    H17D C172 H17E . . 109.5 ?
    C17 C172 H17F . . 109.5 ?
    H17D C172 H17F . . 109.5 ?
    H17E C172 H17F . . 109.5 ?
    C18 C181 H18A . . 109.5 ?
    C18 C181 H18B . . 109.5 ?
    H18A C181 H18B . . 109.5 ?
    C18 C181 H18C . . 109.5 ?
    H18A C181 H18C . . 109.5 ?
    H18B C181 H18C . . 109.5 ?
    C27 C271 H27A . . 109.5 ?
    C27 C271 H27B . . 109.5 ?
    H27A C271 H27B . . 109.5 ?
    C27 C271 H27C . . 109.5 ?
    H27A C271 H27C . . 109.5 ?
    H27B C271 H27C . . 109.5 ?
    C27 C272 H27D . . 109.5 ?
    C27 C272 H27E . . 109.5 ?
    H27D C272 H27E . . 109.5 ?
    C27 C272 H27F . . 109.5 ?
    H27D C272 H27F . . 109.5 ?
    H27E C272 H27F . . 109.5 ?
    C28 C281 H28A . . 109.5 ?
    C28 C281 H28B . . 109.5 ?
    H28A C281 H28B . . 109.5 ?
    C28 C281 H28C . . 109.5 ?
    H28A C281 H28C . . 109.5 ?
    H28B C281 H28C . . 109.5 ?
    C38 C381 H38A . . 109.5 ?
    C38 C381 H38B . . 109.5 ?
    H38A C381 H38B . . 109.5 ?
    C38 C381 H38C . . 109.5 ?
    H38A C381 H38C . . 109.5 ?
    H38B C381 H38C . . 109.5 ?
    C38 C382 H38D . . 109.5 ?
    C38 C382 H38E . . 109.5 ?
    H38D C382 H38E . . 109.5 ?
    C38 C382 H38F . . 109.5 ?
    H38D C382 H38F . . 109.5 ?
    H38E C382 H38F . . 109.5 ?
    C47 C471 H47A . . 109.5 ?
    C47 C471 H47B . . 109.5 ?
    H47A C471 H47B . . 109.5 ?
    C47 C471 H47C . . 109.5 ?
    H47A C471 H47C . . 109.5 ?
    H47B C471 H47C . . 109.5 ?
    C47 C472 H47D . . 109.5 ?
    C47 C472 H47E . . 109.5 ?
    H47D C472 H47E . . 109.5 ?
    C47 C472 H47F . . 109.5 ?
    H47D C472 H47F . . 109.5 ?
    H47E C472 H47F . . 109.5 ?
    C28 C282 H28D . . 109.5 ?
    C28 C282 H28E . . 109.5 ?
    H28D C282 H28E . . 109.5 ?
    C28 C282 H28F . . 109.5 ?
    H28D C282 H28F . . 109.5 ?
    H28E C282 H28F . . 109.5 ?
    C37 C372 H37A . . 109.5 ?
    C37 C372 H37B . . 109.5 ?
    H37A C372 H37B . . 109.5 ?
    C37 C372 H37C . . 109.5 ?
    H37A C372 H37C . . 109.5 ?
    H37B C372 H37C . . 109.5 ?
    C37 C371 H37D . . 109.5 ?
    C37 C371 H37E . . 109.5 ?
    H37D C371 H37E . . 109.5 ?
    C37 C371 H37F . . 109.5 ?
    H37D C371 H37F . . 109.5 ?
    H37E C371 H37F . . 109.5 ?
    C18 C182 H18D . . 109.5 ?
    C18 C182 H18E . . 109.5 ?
    H18D C182 H18E . . 109.5 ?
    C18 C182 H18F . . 109.5 ?
    H18D C182 H18F . . 109.5 ?
    H18E C182 H18F . . 109.5 ?
    C48 C481 H48A . . 109.5 ?
    C48 C481 H48B . . 109.5 ?
    H48A C481 H48B . . 109.5 ?
    C48 C481 H48C . . 109.5 ?
    H48A C481 H48C . . 109.5 ?
    H48B C481 H48C . . 109.5 ?
    C48 C482 H48D . . 109.5 ?
    C48 C482 H48E . . 109.5 ?
    H48D C482 H48E . . 109.5 ?
    C48 C482 H48F . . 109.5 ?
    H48D C482 H48F . . 109.5 ?
    H48E C482 H48F . . 109.5 ?
    C48 C483 H48G . . 109.5 ?
    C48 C483 H48H . . 109.5 ?
    H48G C483 H48H . . 109.5 ?
    C48 C483 H48I . . 109.5 ?
    H48G C483 H48I . . 109.5 ?
    H48H C483 H48I . . 109.5 ?
    C48 C484 H48J . . 109.5 ?
    C48 C484 H48K . . 109.5 ?
    H48J C484 H48K . . 109.5 ?
    C48 C484 H48L . . 109.5 ?
    H48J C484 H48L . . 109.5 ?
    H48K C484 H48L . . 109.5 ?
    C72 O71 C75 . . 86.1(6) ?
    C73 C72 O71 . . 107.3(6) ?
    C73 C72 H72A . . 110.2 ?
    O71 C72 H72A . . 110.2 ?
    C73 C72 H72B . . 110.2 ?
    O71 C72 H72B . . 110.2 ?
    H72A C72 H72B . . 108.5 ?
    C72 C73 C74 . . 105.8(6) ?
    C72 C73 H73A . . 110.6 ?
    C74 C73 H73A . . 110.6 ?
    C72 C73 H73B . . 110.6 ?
    C74 C73 H73B . . 110.6 ?
    H73A C73 H73B . . 108.7 ?
    C75 C74 C73 . . 82.9(7) ?
    C75 C74 H74A . . 114.8 ?
    C73 C74 H74A . . 114.8 ?
    C75 C74 H74B . . 114.8 ?
    C73 C74 H74B . . 114.8 ?
    H74A C74 H74B . . 111.9 ?
    C74 C75 O71 . . 101.8(8) ?
    C74 C75 H75A . . 111.4 ?
    O71 C75 H75A . . 111.4 ?
    C74 C75 H75B . . 111.4 ?
    O71 C75 H75B . . 111.4 ?
    H75A C75 H75B . . 109.3 ?
    C72' O71' C75' . . 84.2(6) ?
    O71' C72' C73' . . 109.5(8) ?
    O71' C72' H72C . . 109.8 ?
    C73' C72' H72C . . 109.8 ?
    O71' C72' H72D . . 109.8 ?
    C73' C72' H72D . . 109.8 ?
    H72C C72' H72D . . 108.2 ?
    C72' C73' C74' . . 99.8(6) ?
    C72' C73' H73C . . 111.8 ?
    C74' C73' H73C . . 111.8 ?
    C72' C73' H73D . . 111.8 ?
    C74' C73' H73D . . 111.8 ?
    H73C C73' H73D . . 109.5 ?
    C75' C74' C73' . . 77.9(5) ?
    C75' C74' H74C . . 115.6 ?
    C73' C74' H74C . . 115.6 ?
    C75' C74' H74D . . 115.6 ?
    C73' C74' H74D . . 115.6 ?
    H74C C74' H74D . . 112.6 ?
    C74' C75' O71' . . 97.0(7) ?
    C74' C75' H75C . . 112.4 ?
    O71' C75' H75C . . 112.4 ?
    C74' C75' H75D . . 112.4 ?
    O71' C75' H75D . . 112.4 ?
    H75C C75' H75D . . 109.9 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C2 N1 C1 N2 . . . . 1.0(2) ?
    C11 N1 C1 N2 . . . . 178.67(19) ?
    C2 N1 C1 Ag1 . . . . -178.36(15) ?
    C11 N1 C1 Ag1 . . . . -0.6(3) ?
    C3 N2 C1 N1 . . . . -0.8(2) ?
    C21 N2 C1 N1 . . . . 177.90(19) ?
    C3 N2 C1 Ag1 . . . . 178.49(16) ?
    C21 N2 C1 Ag1 . . . . -2.8(3) ?
    C1 N1 C2 C3 . . . . -0.8(3) ?
    C11 N1 C2 C3 . . . . -178.6(2) ?
    N1 C2 C3 N2 . . . . 0.2(3) ?
    C1 N2 C3 C2 . . . . 0.4(3) ?
    C21 N2 C3 C2 . . . . -178.4(2) ?
    C1 N1 C11 C16 . . . . -93.8(3) ?
    C2 N1 C11 C16 . . . . 83.7(3) ?
    C1 N1 C11 C12 . . . . 91.0(3) ?
    C2 N1 C11 C12 . . . . -91.5(2) ?
    C16 C11 C12 C13 . . . . 0.8(3) ?
    N1 C11 C12 C13 . . . . 175.8(2) ?
    C16 C11 C12 C17 . . . . -179.8(2) ?
    N1 C11 C12 C17 . . . . -4.8(3) ?
    C11 C12 C13 C14 . . . . -2.1(4) ?
    C17 C12 C13 C14 . . . . 178.5(2) ?
    C12 C13 C14 C15 . . . . 1.6(4) ?
    C13 C14 C15 C16 . . . . 0.4(4) ?
    C14 C15 C16 C11 . . . . -1.6(4) ?
    C14 C15 C16 C18 . . . . 179.1(3) ?
    C12 C11 C16 C15 . . . . 1.0(3) ?
    N1 C11 C16 C15 . . . . -174.0(2) ?
    C12 C11 C16 C18 . . . . -179.7(2) ?
    N1 C11 C16 C18 . . . . 5.3(3) ?
    C13 C12 C17 C171 . . . . 89.4(3) ?
    C11 C12 C17 C171 . . . . -90.0(3) ?
    C13 C12 C17 C172 . . . . -34.1(3) ?
    C11 C12 C17 C172 . . . . 146.6(3) ?
    C15 C16 C18 C181 . . . . 63.9(4) ?
    C11 C16 C18 C181 . . . . -115.4(3) ?
    C15 C16 C18 C182 . . . . -59.0(4) ?
    C11 C16 C18 C182 . . . . 121.7(4) ?
    C1 N2 C21 C22 . . . . 94.2(2) ?
    C3 N2 C21 C22 . . . . -87.2(3) ?
    C1 N2 C21 C26 . . . . -89.2(3) ?
    C3 N2 C21 C26 . . . . 89.4(2) ?
    C26 C21 C22 C23 . . . . 2.9(3) ?
    N2 C21 C22 C23 . . . . 179.34(19) ?
    C26 C21 C22 C27 . . . . -178.2(2) ?
    N2 C21 C22 C27 . . . . -1.7(3) ?
    C21 C22 C23 C24 . . . . -1.2(3) ?
    C27 C22 C23 C24 . . . . 179.9(2) ?
    C22 C23 C24 C25 . . . . -0.8(4) ?
    C23 C24 C25 C26 . . . . 1.2(4) ?
    C24 C25 C26 C21 . . . . 0.4(3) ?
    C24 C25 C26 C28 . . . . 179.4(2) ?
    C22 C21 C26 C25 . . . . -2.5(3) ?
    N2 C21 C26 C25 . . . . -178.97(18) ?
    C22 C21 C26 C28 . . . . 178.5(2) ?
    N2 C21 C26 C28 . . . . 2.1(3) ?
    C23 C22 C27 C272 . . . . 81.1(3) ?
    C21 C22 C27 C272 . . . . -97.8(3) ?
    C23 C22 C27 C271 . . . . -42.6(3) ?
    C21 C22 C27 C271 . . . . 138.5(2) ?
    C25 C26 C28 C281 . . . . -75.7(3) ?
    C21 C26 C28 C281 . . . . 103.2(2) ?
    C25 C26 C28 C282 . . . . 47.8(3) ?
    C21 C26 C28 C282 . . . . -133.3(2) ?
    C6 N4 C4 N3 . . . . -0.8(3) ?
    C41 N4 C4 N3 . . . . 179.4(2) ?
    C6 N4 C4 Ag1 . . . . 177.48(18) ?
    C41 N4 C4 Ag1 . . . . -2.3(3) ?
    C5 N3 C4 N4 . . . . 0.7(3) ?
    C31 N3 C4 N4 . . . . -175.1(2) ?
    C5 N3 C4 Ag1 . . . . -177.59(18) ?
    C31 N3 C4 Ag1 . . . . 6.6(3) ?
    C4 N3 C5 C6 . . . . -0.3(3) ?
    C31 N3 C5 C6 . . . . 175.7(2) ?
    N3 C5 C6 N4 . . . . -0.2(3) ?
    C4 N4 C6 C5 . . . . 0.7(3) ?
    C41 N4 C6 C5 . . . . -179.5(2) ?
    C4 N3 C31 C36 . . . . -101.7(3) ?
    C5 N3 C31 C36 . . . . 82.9(3) ?
    C4 N3 C31 C32 . . . . 81.9(3) ?
    C5 N3 C31 C32 . . . . -93.5(3) ?
    C36 C31 C32 C33 . . . . 2.1(4) ?
    N3 C31 C32 C33 . . . . 178.2(2) ?
    C36 C31 C32 C37 . . . . -175.8(2) ?
    N3 C31 C32 C37 . . . . 0.4(3) ?
    C31 C32 C33 C34 . . . . -1.3(4) ?
    C37 C32 C33 C34 . . . . 176.6(3) ?
    C32 C33 C34 C35 . . . . -0.3(4) ?
    C33 C34 C35 C36 . . . . 1.3(4) ?
    C32 C31 C36 C35 . . . . -1.1(3) ?
    N3 C31 C36 C35 . . . . -177.3(2) ?
    C32 C31 C36 C38 . . . . 178.6(2) ?
    N3 C31 C36 C38 . . . . 2.5(3) ?
    C34 C35 C36 C31 . . . . -0.6(4) ?
    C34 C35 C36 C38 . . . . 179.6(2) ?
    C33 C32 C37 C372 . . . . 60.4(4) ?
    C31 C32 C37 C372 . . . . -121.9(3) ?
    C33 C32 C37 C371 . . . . -64.6(4) ?
    C31 C32 C37 C371 . . . . 113.1(3) ?
    C31 C36 C38 C382 . . . . 129.5(2) ?
    C35 C36 C38 C382 . . . . -50.7(3) ?
    C31 C36 C38 C381 . . . . -107.6(3) ?
    C35 C36 C38 C381 . . . . 72.1(3) ?
    C4 N4 C41 C46 . . . . 98.9(3) ?
    C6 N4 C41 C46 . . . . -80.9(3) ?
    C4 N4 C41 C42 . . . . -85.9(3) ?
    C6 N4 C41 C42 . . . . 94.3(3) ?
    C46 C41 C42 C43 . . . . 0.8(3) ?
    N4 C41 C42 C43 . . . . -174.10(19) ?
    C46 C41 C42 C47 . . . . 179.8(2) ?
    N4 C41 C42 C47 . . . . 4.9(3) ?
    C41 C42 C43 C44 . . . . 0.3(3) ?
    C47 C42 C43 C44 . . . . -178.7(2) ?
    C42 C43 C44 C45 . . . . -1.3(4) ?
    C43 C44 C45 C46 . . . . 1.3(4) ?
    C42 C41 C46 C45 . . . . -0.8(3) ?
    N4 C41 C46 C45 . . . . 174.13(19) ?
    C42 C41 C46 C48 . . . . 178.9(2) ?
    N4 C41 C46 C48 . . . . -6.2(3) ?
    C44 C45 C46 C41 . . . . -0.3(3) ?
    C44 C45 C46 C48 . . . . -179.9(2) ?
    C41 C42 C47 C471 . . . . -89.0(3) ?
    C43 C42 C47 C471 . . . . 89.9(3) ?
    C41 C42 C47 C472 . . . . 148.6(2) ?
    C43 C42 C47 C472 . . . . -32.4(3) ?
    C41 C46 C48 C482 . . . . 108.1(9) ?
    C45 C46 C48 C482 . . . . -72.3(9) ?
    C41 C46 C48 C483 . . . . -86.4(6) ?
    C45 C46 C48 C483 . . . . 93.2(6) ?
    C41 C46 C48 C481 . . . . -120.4(9) ?
    C45 C46 C48 C481 . . . . 59.2(9) ?
    C41 C46 C48 C484 . . . . 149.7(6) ?
    C45 C46 C48 C484 . . . . -30.6(6) ?
    C75 O71 C72 C73 . . . . -45.6(8) ?
    O71 C72 C73 C74 . . . . 12.0(9) ?
    C72 C73 C74 C75 . . . . 31.5(9) ?
    C73 C74 C75 O71 . . . . -63.1(8) ?
    C72 O71 C75 C74 . . . . 75.7(9) ?
    C75' O71' C72' C73' . . . . 46.5(9) ?
    O71' C72' C73' C74' . . . . -8.2(11) ?
    C73' C74' C75' O71' . . . . 70.7(6) ?
    C72' O71' C75' C74' . . . . -84.5(7) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C5 H5 O71 . 0.95 2.42 3.292(5) 153
    C3 H3 Cl1 . 0.95 2.51 3.422(2) 161
    C35 H35 Cl1 4_676 0.95 2.68 3.627(3) 174
    C43 H43 Cl1 1_655 0.95 2.64 3.562(2) 163
    C171 H17B Cg1 . 0.98 2.81 3.532(4) 131
    C372 H37C Cg2 . 0.98 2.94 3.613(4) 126
    C481 H48A Cg3 . 0.98 2.98 3.840(12) 147
_shelxl_version_number     2014/6
data_Global
_journal_date_recd_electronic     2015-04-07
_journal_date_accepted     2015-04-16
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2015
_journal_volume     71
_journal_issue      5
_journal_page_first     544
_journal_page_last     546
_journal_paper_category     GM
_journal_paper_doi     10.1107/S2056989015007525
_journal_coeditor_code     SU5115
_publ_contact_author_name     'Michael Bolte'
_publ_contact_author_address
;
Institut für Anorganische Chemie, Goethe-Universität Frankfurt,
Max-von-Laue-Strasse 7, 60438 Frankfurt/Main, Germany
;
_publ_contact_author_email     'bolte@chemie.uni-frankfurt.de'
_publ_contact_author_fax     '49-69-79829239'
_publ_contact_author_phone     '49-69-79829136'
_publ_section_title
;
Crystal structure of
bis[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver(I)
chloride tetrahydrofuran monosolvate
;
loop_
    _publ_author_name
    _publ_author_address
    'Sänger, Inge'
;
Institut für Anorganische Chemie, Goethe-Universität Frankfurt,
Max-von-Laue-Strasse 7, 60438 Frankfurt/Main, Germany
;
    'Lerner, Hans-Wolfram'
;
Institut für Anorganische Chemie, Goethe-Universität Frankfurt,
Max-von-Laue-Strasse 7, 60438 Frankfurt/Main, Germany
;
    'Bolte, Michael'
;
Institut für Anorganische Chemie, Goethe-Universität Frankfurt,
Max-von-Laue-Strasse 7, 60438 Frankfurt/Main, Germany
;
_publ_section_synopsis
;
In the title compound, the silver atom is coordinated by two
1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene ligands, with the imidazole
rings inclined to one another by 46.69 (13)°. In the crystal, molecules are
linked by trifurcated C---H...(Cl,Cl,Cl) hydrogen bonds, forming
two-dimensional networks parallel to (010).
;
