##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_database_code_depnum_ccdc_archive 'CCDC 1039507'
_audit_creation_method     SHELXL-2014/6
_chemical_name_systematic
;\
catena-Poly[[tris(μ-2,4,6-trimethylbenzoato-\
κ²O:O')dizinc]-μ-2,4,6-trimethylbenzoato-\
κ²O:O']
;
_chemical_name_common     'zinc mesitycarboxylate'
_chemical_formula_moiety     'C40 H44 O8 Zn2'
_chemical_formula_sum     'C40 H44 O8 Zn2'
_chemical_formula_iupac     '[Zn2 (C10 H11 O2)4]'
_chemical_formula_weight     783.49
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/c'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     12.0578(12)
_cell_length_b     14.5824(15)
_cell_length_c     22.275(2)
_cell_angle_alpha     90
_cell_angle_beta     102.3600(10)
_cell_angle_gamma     90
_cell_volume     3825.9(7)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     1351
_cell_measurement_theta_min     2.67
_cell_measurement_theta_max     27.54
_cell_measurement_temperature     120(2)
_exptl_crystal_description     'block'
_exptl_crystal_colour     'pale yellow'
_exptl_crystal_size_max     0.200
_exptl_crystal_size_mid     0.100
_exptl_crystal_size_min     0.050
_exptl_crystal_density_diffrn     1.360
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1632
_exptl_absorpt_coefficient_mu     1.303
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2007)
;
_shelx_estimated_absorpt_T_min     0.781
_shelx_estimated_absorpt_T_max     0.938
_exptl_absorpt_correction_T_min     0.855
_exptl_absorpt_correction_T_max     0.937
_diffrn_ambient_temperature     120(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII CCD'
_diffrn_measurement_method     'φ and ω scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     21404
_diffrn_reflns_av_R_equivalents     0.0264
_diffrn_reflns_theta_min     1.681
_diffrn_reflns_theta_max     28.541
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.910
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -15
_diffrn_reflns_limit_h_max     15
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     16
_diffrn_reflns_limit_l_min     -29
_diffrn_reflns_limit_l_max     28
_refine_special_details     ?
_reflns_number_total     8867
_reflns_number_gt     7157
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0482
_refine_ls_R_factor_gt     0.0344
_refine_ls_wR_factor_gt     0.0737
_refine_ls_wR_factor_ref     0.0796
_refine_ls_goodness_of_fit_ref     1.009
_refine_ls_restrained_S_all     1.009
_refine_ls_number_reflns     8867
_refine_ls_number_parameters     463
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0200P)²+5.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.784
_refine_diff_density_min     -0.390
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Zn' 'Zn' 0.2839 1.4301
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
APEX2 (Bruker, 2007)
;
_computing_cell_refinement
;
SAINT (Bruker, 2007)
;
_computing_data_reduction
;
SAINT (Bruker, 2007)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2008)
;
_computing_molecular_graphics
;
ORTEP-3 for Windows (Farrugia, 2012)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Zn Zn1 -0.01963(2) -0.09027(2) 0.23624(2) 0.02038(7) Uani d 1 . .
    Zn Zn2 0.03822(2) 0.10799(2) 0.18232(2) 0.02097(7) Uani d 1 . .
    O O1 0.06415(15) -0.02033(12) 0.30507(7) 0.0356(4) Uani d 1 . .
    O O2 0.13211(15) 0.10089(12) 0.26440(8) 0.0350(4) Uani d 1 . .
    O O3 0.07929(15) 0.01158(11) 0.13049(8) 0.0333(4) Uani d 1 . .
    O O4 0.07284(14) -0.12268(11) 0.17787(7) 0.0282(4) Uani d 1 . .
    O O5 0.09977(13) 0.21646(10) 0.14961(7) 0.0229(3) Uani d 1 . .
    O O6 0.04628(12) 0.29611(10) 0.22260(7) 0.0228(3) Uani d 1 . .
    O O7 -0.12449(13) 0.10862(11) 0.17198(8) 0.0286(4) Uani d 1 . .
    O O8 -0.16060(13) -0.03770(11) 0.19109(7) 0.0276(3) Uani d 1 . .
    C C1 0.12488(19) 0.04947(16) 0.30840(10) 0.0242(5) Uani d 1 . .
    C C2 0.19581(19) 0.07447(16) 0.36990(10) 0.0256(5) Uani d 1 . .
    C C3 0.15013(19) 0.13166(16) 0.40868(10) 0.0267(5) Uani d 1 . .
    C C4 0.0311(2) 0.16725(19) 0.38925(12) 0.0380(6) Uani d 1 . .
    H H4A 0.0053 0.1902 0.4253 0.057 Uiso calc 1 . .
    H H4B -0.0191 0.1176 0.3702 0.057 Uiso calc 1 . .
    H H4C 0.0293 0.2172 0.3596 0.057 Uiso calc 1 . .
    C C5 0.2184(2) 0.15481(17) 0.46520(11) 0.0305(5) Uani d 1 . .
    H H5 0.1881 0.1928 0.4924 0.037 Uiso calc 1 . .
    C C6 0.3292(2) 0.12416(18) 0.48299(11) 0.0332(5) Uani d 1 . .
    C C7 0.4023(2) 0.1525(2) 0.54398(12) 0.0455(7) Uani d 1 . .
    H H7A 0.4707 0.1142 0.5530 0.068 Uiso calc 1 . .
    H H7B 0.3596 0.1446 0.5764 0.068 Uiso calc 1 . .
    H H7C 0.4241 0.2170 0.5421 0.068 Uiso calc 1 . .
    C C8 0.3712(2) 0.0667(2) 0.44354(12) 0.0409(6) Uani d 1 . .
    H H8 0.4467 0.0444 0.4556 0.049 Uiso calc 1 . .
    C C9 0.3057(2) 0.0407(2) 0.38663(11) 0.0368(6) Uani d 1 . .
    C C10 0.3514(3) -0.0230(3) 0.34406(14) 0.0597(10) Uani d 1 . .
    H H10A 0.3071 -0.0798 0.3387 0.090 Uiso calc 1 . .
    H H10B 0.4312 -0.0371 0.3618 0.090 Uiso calc 1 . .
    H H10C 0.3456 0.0068 0.3041 0.090 Uiso calc 1 . .
    C C11 0.09609(17) -0.07343(15) 0.13581(9) 0.0208(4) Uani d 1 . .
    C C12 0.14756(18) -0.11860(14) 0.08808(10) 0.0214(4) Uani d 1 . .
    C C13 0.26351(19) -0.13914(16) 0.10146(11) 0.0270(5) Uani d 1 . .
    C C14 0.3086(2) -0.18030(17) 0.05554(12) 0.0340(6) Uani d 1 . .
    H H14 0.3873 -0.1945 0.0638 0.041 Uiso calc 1 . .
    C C15 0.2426(2) -0.20120(17) -0.00179(12) 0.0343(6) Uani d 1 . .
    C C16 0.1284(2) -0.17891(16) -0.01349(11) 0.0295(5) Uani d 1 . .
    H H16 0.0825 -0.1924 -0.0527 0.035 Uiso calc 1 . .
    C C17 0.07876(19) -0.13739(15) 0.03051(10) 0.0232(4) Uani d 1 . .
    C C18 -0.04636(19) -0.11609(17) 0.01647(11) 0.0293(5) Uani d 1 . .
    H H18A -0.0809 -0.1380 -0.0249 0.044 Uiso calc 1 . .
    H H18B -0.0573 -0.0497 0.0186 0.044 Uiso calc 1 . .
    H H18C -0.0822 -0.1467 0.0466 0.044 Uiso calc 1 . .
    C C19 0.2929(3) -0.2497(2) -0.04983(14) 0.0524(8) Uani d 1 . .
    H H19A 0.3047 -0.3146 -0.0389 0.079 Uiso calc 1 . .
    H H19B 0.3658 -0.2214 -0.0518 0.079 Uiso calc 1 . .
    H H19C 0.2408 -0.2445 -0.0900 0.079 Uiso calc 1 . .
    C C20 0.3372(2) -0.11762(19) 0.16336(12) 0.0372(6) Uani d 1 . .
    H H20A 0.4102 -0.1493 0.1677 0.056 Uiso calc 1 . .
    H H20B 0.2993 -0.1382 0.1957 0.056 Uiso calc 1 . .
    H H20C 0.3502 -0.0513 0.1670 0.056 Uiso calc 1 . .
    C C21 0.10079(17) 0.28918(14) 0.18022(9) 0.0193(4) Uani d 1 . .
    C C22 0.17023(19) 0.36796(15) 0.16578(10) 0.0228(4) Uani d 1 . .
    C C23 0.2758(2) 0.38501(16) 0.20402(11) 0.0283(5) Uani d 1 . .
    C C24 0.3370(2) 0.46119(19) 0.19157(13) 0.0400(6) Uani d 1 . .
    H H24 0.4082 0.4744 0.2178 0.048 Uiso calc 1 . .
    C C25 0.2967(3) 0.51814(19) 0.14191(15) 0.0460(7) Uani d 1 . .
    C C26 0.1934(3) 0.49777(18) 0.10388(13) 0.0434(7) Uani d 1 . .
    H H26 0.1659 0.5359 0.0693 0.052 Uiso calc 1 . .
    C C27 0.1280(2) 0.42316(16) 0.11443(11) 0.0311(5) Uani d 1 . .
    C C28 0.0159(2) 0.40370(19) 0.07240(11) 0.0394(6) Uani d 1 . .
    H H28A -0.0106 0.4586 0.0482 0.059 Uiso calc 1 . .
    H H28B -0.0395 0.3865 0.0968 0.059 Uiso calc 1 . .
    H H28C 0.0245 0.3532 0.0447 0.059 Uiso calc 1 . .
    C C29 0.3633(4) 0.6017(2) 0.1296(2) 0.0733(12) Uani d 1 . .
    H H29A 0.4307 0.6087 0.1627 0.110 Uiso calc 1 . .
    H H29B 0.3155 0.6564 0.1276 0.110 Uiso calc 1 . .
    H H29C 0.3868 0.5939 0.0904 0.110 Uiso calc 1 . .
    C C30 0.3245(2) 0.32251(19) 0.25705(12) 0.0350(6) Uani d 1 . .
    H H30A 0.2625 0.2951 0.2731 0.053 Uiso calc 1 . .
    H H30B 0.3737 0.3579 0.2896 0.053 Uiso calc 1 . .
    H H30C 0.3689 0.2739 0.2429 0.053 Uiso calc 1 . .
    C C31 -0.19067(18) 0.04227(16) 0.17330(10) 0.0235(4) Uani d 1 . .
    C C32 -0.31529(19) 0.06039(16) 0.15257(11) 0.0259(5) Uani d 1 . .
    C C33 -0.3641(2) 0.13265(18) 0.17911(12) 0.0345(6) Uani d 1 . .
    C C34 -0.2952(3) 0.1926(2) 0.22803(14) 0.0510(8) Uani d 1 . .
    H H34A -0.2465 0.1543 0.2590 0.077 Uiso calc 1 . .
    H H34B -0.3463 0.2288 0.2475 0.077 Uiso calc 1 . .
    H H34C -0.2479 0.2340 0.2095 0.077 Uiso calc 1 . .
    C C35 -0.4808(2) 0.14777(19) 0.15916(13) 0.0421(7) Uani d 1 . .
    H H35 -0.5151 0.1957 0.1777 0.051 Uiso calc 1 . .
    C C36 -0.5479(2) 0.09607(19) 0.11378(14) 0.0404(7) Uani d 1 . .
    C C37 -0.6736(2) 0.1147(2) 0.09255(18) 0.0588(9) Uani d 1 . .
    H H37A -0.6870 0.1497 0.0541 0.088 Uiso calc 1 . .
    H H37B -0.7005 0.1501 0.1240 0.088 Uiso calc 1 . .
    H H37C -0.7148 0.0564 0.0857 0.088 Uiso calc 1 . .
    C C38 -0.4969(2) 0.02634(18) 0.08789(13) 0.0378(6) Uani d 1 . .
    H H38 -0.5418 -0.0094 0.0561 0.045 Uiso calc 1 . .
    C C39 -0.38183(19) 0.00636(17) 0.10665(11) 0.0298(5) Uani d 1 . .
    C C40 -0.3316(2) -0.07034(19) 0.07582(12) 0.0392(6) Uani d 1 . .
    H H40A -0.3901 -0.0960 0.0427 0.059 Uiso calc 1 . .
    H H40B -0.3032 -0.1183 0.1060 0.059 Uiso calc 1 . .
    H H40C -0.2689 -0.0466 0.0588 0.059 Uiso calc 1 . .
_geom_special_details
;
All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Zn1 O1 . 1.9361(16) y
    Zn1 O8 . 1.9382(15) y
    Zn1 O4 . 1.9436(15) y
    Zn1 O6 2_545 1.9532(15) y
    Zn2 O7 . 1.9258(16) y
    Zn2 O2 . 1.9363(16) y
    Zn2 O3 . 1.9492(16) y
    Zn2 O5 . 1.9532(15) y
    O1 C1 . 1.247(3) ?
    O2 C1 . 1.252(3) ?
    O3 C11 . 1.258(3) ?
    O4 C11 . 1.259(3) ?
    O5 C21 . 1.259(2) ?
    O6 C21 . 1.265(2) ?
    O6 Zn1 2 1.9532(15) ?
    O7 C31 . 1.259(3) ?
    O8 C31 . 1.260(3) ?
    C1 C2 . 1.497(3) ?
    C2 C9 . 1.387(3) ?
    C2 C3 . 1.396(3) ?
    C3 C5 . 1.391(3) ?
    C3 C4 . 1.500(3) ?
    C4 H4A . 0.9800 ?
    C4 H4B . 0.9800 ?
    C4 H4C . 0.9800 ?
    C5 C6 . 1.384(3) ?
    C5 H5 . 0.9500 ?
    C6 C8 . 1.386(4) ?
    C6 C7 . 1.510(3) ?
    C7 H7A . 0.9800 ?
    C7 H7B . 0.9800 ?
    C7 H7C . 0.9800 ?
    C8 C9 . 1.395(4) ?
    C8 H8 . 0.9500 ?
    C9 C10 . 1.513(4) ?
    C10 H10A . 0.9800 ?
    C10 H10B . 0.9800 ?
    C10 H10C . 0.9800 ?
    C11 C12 . 1.494(3) ?
    C12 C17 . 1.397(3) ?
    C12 C13 . 1.398(3) ?
    C13 C14 . 1.393(3) ?
    C13 C20 . 1.505(3) ?
    C14 C15 . 1.386(4) ?
    C14 H14 . 0.9500 ?
    C15 C16 . 1.384(3) ?
    C15 C19 . 1.514(3) ?
    C16 C17 . 1.391(3) ?
    C16 H16 . 0.9500 ?
    C17 C18 . 1.506(3) ?
    C18 H18A . 0.9800 ?
    C18 H18B . 0.9800 ?
    C18 H18C . 0.9800 ?
    C19 H19A . 0.9800 ?
    C19 H19B . 0.9800 ?
    C19 H19C . 0.9800 ?
    C20 H20A . 0.9800 ?
    C20 H20B . 0.9800 ?
    C20 H20C . 0.9800 ?
    C21 C22 . 1.497(3) ?
    C22 C23 . 1.394(3) ?
    C22 C27 . 1.402(3) ?
    C23 C24 . 1.394(3) ?
    C23 C30 . 1.508(3) ?
    C24 C25 . 1.385(4) ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.381(4) ?
    C25 C29 . 1.517(4) ?
    C26 C27 . 1.393(4) ?
    C26 H26 . 0.9500 ?
    C27 C28 . 1.497(4) ?
    C28 H28A . 0.9800 ?
    C28 H28B . 0.9800 ?
    C28 H28C . 0.9800 ?
    C29 H29A . 0.9800 ?
    C29 H29B . 0.9800 ?
    C29 H29C . 0.9800 ?
    C30 H30A . 0.9800 ?
    C30 H30B . 0.9800 ?
    C30 H30C . 0.9800 ?
    C31 C32 . 1.498(3) ?
    C32 C33 . 1.398(3) ?
    C32 C39 . 1.400(3) ?
    C33 C35 . 1.400(4) ?
    C33 C34 . 1.501(4) ?
    C34 H34A . 0.9800 ?
    C34 H34B . 0.9800 ?
    C34 H34C . 0.9800 ?
    C35 C36 . 1.377(4) ?
    C35 H35 . 0.9500 ?
    C36 C38 . 1.378(4) ?
    C36 C37 . 1.512(4) ?
    C37 H37A . 0.9800 ?
    C37 H37B . 0.9800 ?
    C37 H37C . 0.9800 ?
    C38 C39 . 1.391(3) ?
    C38 H38 . 0.9500 ?
    C39 C40 . 1.506(3) ?
    C40 H40A . 0.9800 ?
    C40 H40B . 0.9800 ?
    C40 H40C . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Zn1 O8 . . 116.97(8) ?
    O1 Zn1 O4 . . 112.40(7) ?
    O8 Zn1 O4 . . 108.30(7) ?
    O1 Zn1 O6 . 2_545 100.69(7) ?
    O8 Zn1 O6 . 2_545 111.41(6) ?
    O4 Zn1 O6 . 2_545 106.46(6) ?
    O7 Zn2 O2 . . 119.20(7) ?
    O7 Zn2 O3 . . 108.31(7) ?
    O2 Zn2 O3 . . 110.45(8) ?
    O7 Zn2 O5 . . 114.23(7) ?
    O2 Zn2 O5 . . 101.74(7) ?
    O3 Zn2 O5 . . 101.43(6) ?
    C1 O1 Zn1 . . 132.64(15) ?
    C1 O2 Zn2 . . 130.29(15) ?
    C11 O3 Zn2 . . 135.35(15) ?
    C11 O4 Zn1 . . 127.61(15) ?
    C21 O5 Zn2 . . 116.12(13) ?
    C21 O6 Zn1 . 2 125.61(14) ?
    C31 O7 Zn2 . . 128.93(15) ?
    C31 O8 Zn1 . . 133.69(15) ?
    O1 C1 O2 . . 125.5(2) ?
    O1 C1 C2 . . 117.8(2) ?
    O2 C1 C2 . . 116.7(2) ?
    C9 C2 C3 . . 121.8(2) ?
    C9 C2 C1 . . 119.0(2) ?
    C3 C2 C1 . . 119.2(2) ?
    C5 C3 C2 . . 118.0(2) ?
    C5 C3 C4 . . 121.5(2) ?
    C2 C3 C4 . . 120.5(2) ?
    C3 C4 H4A . . 109.5 ?
    C3 C4 H4B . . 109.5 ?
    H4A C4 H4B . . 109.5 ?
    C3 C4 H4C . . 109.5 ?
    H4A C4 H4C . . 109.5 ?
    H4B C4 H4C . . 109.5 ?
    C6 C5 C3 . . 122.0(2) ?
    C6 C5 H5 . . 119.0 ?
    C3 C5 H5 . . 119.0 ?
    C5 C6 C8 . . 118.4(2) ?
    C5 C6 C7 . . 120.7(2) ?
    C8 C6 C7 . . 120.9(2) ?
    C6 C7 H7A . . 109.5 ?
    C6 C7 H7B . . 109.5 ?
    H7A C7 H7B . . 109.5 ?
    C6 C7 H7C . . 109.5 ?
    H7A C7 H7C . . 109.5 ?
    H7B C7 H7C . . 109.5 ?
    C6 C8 C9 . . 121.8(2) ?
    C6 C8 H8 . . 119.1 ?
    C9 C8 H8 . . 119.1 ?
    C2 C9 C8 . . 118.1(2) ?
    C2 C9 C10 . . 120.3(2) ?
    C8 C9 C10 . . 121.6(2) ?
    C9 C10 H10A . . 109.5 ?
    C9 C10 H10B . . 109.5 ?
    H10A C10 H10B . . 109.5 ?
    C9 C10 H10C . . 109.5 ?
    H10A C10 H10C . . 109.5 ?
    H10B C10 H10C . . 109.5 ?
    O3 C11 O4 . . 125.1(2) ?
    O3 C11 C12 . . 116.79(18) ?
    O4 C11 C12 . . 118.08(19) ?
    C17 C12 C13 . . 121.6(2) ?
    C17 C12 C11 . . 118.95(19) ?
    C13 C12 C11 . . 119.4(2) ?
    C14 C13 C12 . . 117.7(2) ?
    C14 C13 C20 . . 121.1(2) ?
    C12 C13 C20 . . 121.2(2) ?
    C15 C14 C13 . . 122.3(2) ?
    C15 C14 H14 . . 118.9 ?
    C13 C14 H14 . . 118.9 ?
    C16 C15 C14 . . 118.3(2) ?
    C16 C15 C19 . . 120.6(3) ?
    C14 C15 C19 . . 121.1(2) ?
    C15 C16 C17 . . 122.0(2) ?
    C15 C16 H16 . . 119.0 ?
    C17 C16 H16 . . 119.0 ?
    C16 C17 C12 . . 118.1(2) ?
    C16 C17 C18 . . 120.4(2) ?
    C12 C17 C18 . . 121.44(19) ?
    C17 C18 H18A . . 109.5 ?
    C17 C18 H18B . . 109.5 ?
    H18A C18 H18B . . 109.5 ?
    C17 C18 H18C . . 109.5 ?
    H18A C18 H18C . . 109.5 ?
    H18B C18 H18C . . 109.5 ?
    C15 C19 H19A . . 109.5 ?
    C15 C19 H19B . . 109.5 ?
    H19A C19 H19B . . 109.5 ?
    C15 C19 H19C . . 109.5 ?
    H19A C19 H19C . . 109.5 ?
    H19B C19 H19C . . 109.5 ?
    C13 C20 H20A . . 109.5 ?
    C13 C20 H20B . . 109.5 ?
    H20A C20 H20B . . 109.5 ?
    C13 C20 H20C . . 109.5 ?
    H20A C20 H20C . . 109.5 ?
    H20B C20 H20C . . 109.5 ?
    O5 C21 O6 . . 121.68(19) ?
    O5 C21 C22 . . 118.11(18) ?
    O6 C21 C22 . . 120.21(18) ?
    C23 C22 C27 . . 121.4(2) ?
    C23 C22 C21 . . 119.0(2) ?
    C27 C22 C21 . . 119.6(2) ?
    C24 C23 C22 . . 118.3(2) ?
    C24 C23 C30 . . 120.3(2) ?
    C22 C23 C30 . . 121.5(2) ?
    C25 C24 C23 . . 121.8(3) ?
    C25 C24 H24 . . 119.1 ?
    C23 C24 H24 . . 119.1 ?
    C26 C25 C24 . . 118.5(2) ?
    C26 C25 C29 . . 120.3(3) ?
    C24 C25 C29 . . 121.2(3) ?
    C25 C26 C27 . . 122.3(3) ?
    C25 C26 H26 . . 118.9 ?
    C27 C26 H26 . . 118.9 ?
    C26 C27 C22 . . 117.8(2) ?
    C26 C27 C28 . . 120.7(2) ?
    C22 C27 C28 . . 121.5(2) ?
    C27 C28 H28A . . 109.5 ?
    C27 C28 H28B . . 109.5 ?
    H28A C28 H28B . . 109.5 ?
    C27 C28 H28C . . 109.5 ?
    H28A C28 H28C . . 109.5 ?
    H28B C28 H28C . . 109.5 ?
    C25 C29 H29A . . 109.5 ?
    C25 C29 H29B . . 109.5 ?
    H29A C29 H29B . . 109.5 ?
    C25 C29 H29C . . 109.5 ?
    H29A C29 H29C . . 109.5 ?
    H29B C29 H29C . . 109.5 ?
    C23 C30 H30A . . 109.5 ?
    C23 C30 H30B . . 109.5 ?
    H30A C30 H30B . . 109.5 ?
    C23 C30 H30C . . 109.5 ?
    H30A C30 H30C . . 109.5 ?
    H30B C30 H30C . . 109.5 ?
    O7 C31 O8 . . 125.3(2) ?
    O7 C31 C32 . . 117.2(2) ?
    O8 C31 C32 . . 117.5(2) ?
    C33 C32 C39 . . 120.4(2) ?
    C33 C32 C31 . . 119.2(2) ?
    C39 C32 C31 . . 120.4(2) ?
    C32 C33 C35 . . 118.0(3) ?
    C32 C33 C34 . . 121.9(2) ?
    C35 C33 C34 . . 120.1(2) ?
    C33 C34 H34A . . 109.5 ?
    C33 C34 H34B . . 109.5 ?
    H34A C34 H34B . . 109.5 ?
    C33 C34 H34C . . 109.5 ?
    H34A C34 H34C . . 109.5 ?
    H34B C34 H34C . . 109.5 ?
    C36 C35 C33 . . 122.7(2) ?
    C36 C35 H35 . . 118.7 ?
    C33 C35 H35 . . 118.7 ?
    C35 C36 C38 . . 117.8(2) ?
    C35 C36 C37 . . 121.6(3) ?
    C38 C36 C37 . . 120.6(3) ?
    C36 C37 H37A . . 109.5 ?
    C36 C37 H37B . . 109.5 ?
    H37A C37 H37B . . 109.5 ?
    C36 C37 H37C . . 109.5 ?
    H37A C37 H37C . . 109.5 ?
    H37B C37 H37C . . 109.5 ?
    C36 C38 C39 . . 122.4(3) ?
    C36 C38 H38 . . 118.8 ?
    C39 C38 H38 . . 118.8 ?
    C38 C39 C32 . . 118.7(2) ?
    C38 C39 C40 . . 119.4(2) ?
    C32 C39 C40 . . 121.9(2) ?
    C39 C40 H40A . . 109.5 ?
    C39 C40 H40B . . 109.5 ?
    H40A C40 H40B . . 109.5 ?
    C39 C40 H40C . . 109.5 ?
    H40A C40 H40C . . 109.5 ?
    H40B C40 H40C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Zn1 O1 C1 O2 . . . . 11.9(4) ?
    Zn1 O1 C1 C2 . . . . -167.94(16) ?
    Zn2 O2 C1 O1 . . . . 12.8(4) ?
    Zn2 O2 C1 C2 . . . . -167.40(16) ?
    O1 C1 C2 C9 . . . . 91.1(3) ?
    O2 C1 C2 C9 . . . . -88.7(3) ?
    O1 C1 C2 C3 . . . . -89.4(3) ?
    O2 C1 C2 C3 . . . . 90.8(3) ?
    C9 C2 C3 C5 . . . . 0.3(4) ?
    C1 C2 C3 C5 . . . . -179.1(2) ?
    C9 C2 C3 C4 . . . . 179.9(2) ?
    C1 C2 C3 C4 . . . . 0.4(3) ?
    C2 C3 C5 C6 . . . . 1.1(4) ?
    C4 C3 C5 C6 . . . . -178.4(2) ?
    C3 C5 C6 C8 . . . . -1.8(4) ?
    C3 C5 C6 C7 . . . . 178.4(2) ?
    C5 C6 C8 C9 . . . . 1.1(4) ?
    C7 C6 C8 C9 . . . . -179.1(3) ?
    C3 C2 C9 C8 . . . . -1.0(4) ?
    C1 C2 C9 C8 . . . . 178.5(2) ?
    C3 C2 C9 C10 . . . . 178.5(3) ?
    C1 C2 C9 C10 . . . . -2.0(4) ?
    C6 C8 C9 C2 . . . . 0.3(4) ?
    C6 C8 C9 C10 . . . . -179.2(3) ?
    Zn2 O3 C11 O4 . . . . 11.1(4) ?
    Zn2 O3 C11 C12 . . . . -169.00(16) ?
    Zn1 O4 C11 O3 . . . . 12.8(3) ?
    Zn1 O4 C11 C12 . . . . -167.06(14) ?
    O3 C11 C12 C17 . . . . -77.9(3) ?
    O4 C11 C12 C17 . . . . 102.0(2) ?
    O3 C11 C12 C13 . . . . 100.6(2) ?
    O4 C11 C12 C13 . . . . -79.5(3) ?
    C17 C12 C13 C14 . . . . -0.8(3) ?
    C11 C12 C13 C14 . . . . -179.3(2) ?
    C17 C12 C13 C20 . . . . 179.3(2) ?
    C11 C12 C13 C20 . . . . 0.8(3) ?
    C12 C13 C14 C15 . . . . -0.2(4) ?
    C20 C13 C14 C15 . . . . 179.7(2) ?
    C13 C14 C15 C16 . . . . 0.9(4) ?
    C13 C14 C15 C19 . . . . -177.3(2) ?
    C14 C15 C16 C17 . . . . -0.6(4) ?
    C19 C15 C16 C17 . . . . 177.6(2) ?
    C15 C16 C17 C12 . . . . -0.3(3) ?
    C15 C16 C17 C18 . . . . -178.7(2) ?
    C13 C12 C17 C16 . . . . 1.1(3) ?
    C11 C12 C17 C16 . . . . 179.6(2) ?
    C13 C12 C17 C18 . . . . 179.4(2) ?
    C11 C12 C17 C18 . . . . -2.1(3) ?
    Zn2 O5 C21 O6 . . . . -12.9(3) ?
    Zn2 O5 C21 C22 . . . . 166.21(14) ?
    Zn1 O6 C21 O5 2 . . . -168.98(14) ?
    Zn1 O6 C21 C22 2 . . . 11.9(3) ?
    O5 C21 C22 C23 . . . . -101.5(2) ?
    O6 C21 C22 C23 . . . . 77.6(3) ?
    O5 C21 C22 C27 . . . . 78.7(3) ?
    O6 C21 C22 C27 . . . . -102.2(2) ?
    C27 C22 C23 C24 . . . . 2.8(3) ?
    C21 C22 C23 C24 . . . . -177.0(2) ?
    C27 C22 C23 C30 . . . . -176.3(2) ?
    C21 C22 C23 C30 . . . . 3.9(3) ?
    C22 C23 C24 C25 . . . . -1.5(4) ?
    C30 C23 C24 C25 . . . . 177.6(2) ?
    C23 C24 C25 C26 . . . . -0.4(4) ?
    C23 C24 C25 C29 . . . . 179.0(3) ?
    C24 C25 C26 C27 . . . . 1.1(4) ?
    C29 C25 C26 C27 . . . . -178.3(3) ?
    C25 C26 C27 C22 . . . . 0.1(4) ?
    C25 C26 C27 C28 . . . . 179.5(2) ?
    C23 C22 C27 C26 . . . . -2.1(3) ?
    C21 C22 C27 C26 . . . . 177.7(2) ?
    C23 C22 C27 C28 . . . . 178.5(2) ?
    C21 C22 C27 C28 . . . . -1.7(3) ?
    Zn2 O7 C31 O8 . . . . 11.4(3) ?
    Zn2 O7 C31 C32 . . . . -169.20(15) ?
    Zn1 O8 C31 O7 . . . . 13.8(3) ?
    Zn1 O8 C31 C32 . . . . -165.51(15) ?
    O7 C31 C32 C33 . . . . -53.1(3) ?
    O8 C31 C32 C33 . . . . 126.3(2) ?
    O7 C31 C32 C39 . . . . 126.1(2) ?
    O8 C31 C32 C39 . . . . -54.5(3) ?
    C39 C32 C33 C35 . . . . 1.1(3) ?
    C31 C32 C33 C35 . . . . -179.6(2) ?
    C39 C32 C33 C34 . . . . -179.4(2) ?
    C31 C32 C33 C34 . . . . -0.2(4) ?
    C32 C33 C35 C36 . . . . -1.7(4) ?
    C34 C33 C35 C36 . . . . 178.9(3) ?
    C33 C35 C36 C38 . . . . 0.6(4) ?
    C33 C35 C36 C37 . . . . -179.2(3) ?
    C35 C36 C38 C39 . . . . 0.9(4) ?
    C37 C36 C38 C39 . . . . -179.2(2) ?
    C36 C38 C39 C32 . . . . -1.4(4) ?
    C36 C38 C39 C40 . . . . -179.4(2) ?
    C33 C32 C39 C38 . . . . 0.3(3) ?
    C31 C32 C39 C38 . . . . -178.9(2) ?
    C33 C32 C39 C40 . . . . 178.3(2) ?
    C31 C32 C39 C40 . . . . -0.9(3) ?
_shelxl_version_number     2014/6
data_New_Global_Publ_Block
_journal_date_recd_electronic     2014-11-11
_journal_date_accepted     2014-12-16
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2015
_journal_volume     71
_journal_issue      1
_journal_page_first     m14
_journal_page_last     m15
_journal_paper_category     HM
_journal_paper_doi     10.1107/S2056989014027418
_journal_coeditor_code     NK2228
_publ_contact_author_name     'Tatsuya Nabeshima'
_publ_contact_author_address
;
Graduate School of Pure and Applied Sciences,
Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki 305-8571, Japan
;
_publ_contact_author_email     'nabesima@chem.tsukuba.ac.jp'
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;\
Crystal structure of the one-dimensional metal--organic polymer
catena-poly[[tris(μ-2,4,6-trimethylbenzoato-κ²O:O')\
dizinc]-μ-2,4,6-trimethylbenzoato-κ²O:O']
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Yamamura, Masaki' .
;
Graduate School of Pure and Applied Sciences,
Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba, 1-1-1,
Tennodai, Tsukuba, Ibaraki 305-8571,
Japan
;
    'Nabeshima, Tatsuya' .
;
Graduate School of Pure and Applied Sciences,
Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba, 1-1-1,
Tennodai, Tsukuba, Ibaraki 305-8571,
Japan
;
_publ_section_synopsis     .
