##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section C. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section C, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_1b
_audit_creation_method
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_chemical_name_systematic
;
Dichloridobis[tris(pyridin-2-yl)amine-κ²N,N']ruthenium(II)
dichloromethane disolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C30 H24 Cl2 N8 Ru, 2(C H2 Cl2)'
_chemical_formula_sum     'C32 H28 Cl6 N8 Ru'
_chemical_formula_iupac     '[Ru Cl2 (C15 H12 N4)2], 2C H2 Cl2'
_chemical_formula_weight     838.39
_chemical_melting_point     ?
_space_group_crystal_system     triclinic
_space_group_name_H-M_alt     'P -1'
_space_group_name_Hall     '-P 1'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     11.2435(7)
_cell_length_b     11.4038(7)
_cell_length_c     13.6340(7)
_cell_angle_alpha     74.278(5)
_cell_angle_beta     75.995(5)
_cell_angle_gamma     84.642(5)
_cell_volume     1631.99(17)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     15256
_cell_measurement_theta_min     2.7860
_cell_measurement_theta_max     30.4630
_cell_measurement_temperature     93(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     orange
_exptl_crystal_size_max     0.37
_exptl_crystal_size_mid     0.29
_exptl_crystal_size_min     0.2
_exptl_crystal_density_diffrn     1.706
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     844
_exptl_absorpt_coefficient_mu     1.011
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2019)
;
_exptl_absorpt_correction_T_min     0.92578
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     93.15
_diffrn_source     ?
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_measurement_device_type     'Rigaku Mercury275R CCD'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     6.8
_diffrn_reflns_number     34353
_diffrn_reflns_av_R_equivalents     0.0927
_diffrn_reflns_av_unetI/netI     0.1041
_diffrn_reflns_theta_min     2.672
_diffrn_reflns_theta_max     30.502
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.992
_diffrn_measured_fraction_theta_full     0.998
_diffrn_reflns_limit_h_min     -15
_diffrn_reflns_limit_h_max     16
_diffrn_reflns_limit_k_min     -16
_diffrn_reflns_limit_k_max     16
_diffrn_reflns_limit_l_min     -19
_diffrn_reflns_limit_l_max     19
_refine_special_details     ?
_reflns_number_total     9877
_reflns_number_gt     6726
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.1097
_refine_ls_R_factor_gt     0.0606
_refine_ls_wR_factor_gt     0.0951
_refine_ls_wR_factor_ref     0.1079
_refine_ls_goodness_of_fit_ref     1.028
_refine_ls_restrained_S_all     1.028
_refine_ls_number_reflns     9877
_refine_ls_number_parameters     424
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0266P)²+3.9087P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.974
_refine_diff_density_min     -0.757
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ru' 'Ru' -1.2594 0.8363
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2019)
;
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2019)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2019)
;
_computing_structure_solution
;
SHELXT2014 (Sheldrick, 2015a)
;
_computing_structure_refinement
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ru Ru1 0.76400(3) 0.73839(3) 0.50380(2) 0.01125(8) Uani d 1 . .
    Cl Cl1 0.96002(8) 0.71921(8) 0.38718(7) 0.01494(18) Uani d 1 . .
    Cl Cl2 0.66580(8) 0.80970(8) 0.35919(7) 0.01553(19) Uani d 1 . .
    Cl Cl3 1.14367(11) 0.95770(11) 0.88069(9) 0.0323(3) Uani d 1 . .
    Cl Cl4 0.89342(11) 0.99325(10) 0.85424(9) 0.0312(3) Uani d 1 . .
    Cl Cl5 1.37129(11) 1.34020(11) 0.86258(9) 0.0361(3) Uani d 1 . .
    Cl Cl6 1.10635(11) 1.32412(11) 0.92797(9) 0.0358(3) Uani d 1 . .
    N N1 0.8092(3) 0.9115(3) 0.4951(2) 0.0123(6) Uani d 1 . .
    N N2 0.8448(3) 0.6834(3) 0.6271(2) 0.0123(6) Uani d 1 . .
    N N3 0.6383(3) 1.0142(3) 0.7273(3) 0.0257(8) Uani d 1 . .
    N N4 0.7763(3) 0.8649(3) 0.6766(2) 0.0127(6) Uani d 1 . .
    N N5 0.5991(3) 0.7491(3) 0.6038(2) 0.0122(6) Uani d 1 . .
    N N6 0.7166(3) 0.5678(3) 0.5075(2) 0.0123(6) Uani d 1 . .
    N N7 0.6217(3) 0.5179(3) 0.8553(3) 0.0220(7) Uani d 1 . .
    N N8 0.6141(3) 0.5413(3) 0.6825(2) 0.0140(6) Uani d 1 . .
    C C1 0.8431(3) 0.9909(3) 0.4010(3) 0.0158(8) Uani d 1 . .
    H H1 0.841044 0.966068 0.340388 0.019 Uiso calc 1 . .
    C C2 0.8801(3) 1.1051(3) 0.3888(3) 0.0162(8) Uani d 1 . .
    H H2 0.899673 1.159809 0.321172 0.019 Uiso calc 1 . .
    C C3 0.8888(3) 1.1405(3) 0.4754(3) 0.0179(8) Uani d 1 . .
    H H3 0.916364 1.219205 0.468523 0.021 Uiso calc 1 . .
    C C4 0.8571(3) 1.0602(3) 0.5717(3) 0.0146(7) Uani d 1 . .
    H H4 0.863908 1.081662 0.632727 0.017 Uiso calc 1 . .
    C C5 0.8150(3) 0.9472(3) 0.5787(3) 0.0129(7) Uani d 1 . .
    C C6 0.5434(4) 1.0466(4) 0.7950(4) 0.0316(11) Uani d 1 . .
    H H6 0.512007 1.128064 0.778063 0.038 Uiso calc 1 . .
    C C7 0.4882(4) 0.9701(5) 0.8872(4) 0.0311(11) Uani d 1 . .
    H H7 0.420620 0.997012 0.933752 0.037 Uiso calc 1 . .
    C C8 0.5344(4) 0.8523(4) 0.9101(3) 0.0277(10) Uani d 1 . .
    H H8 0.498303 0.796129 0.973571 0.033 Uiso calc 1 . .
    C C9 0.6313(4) 0.8157(3) 0.8427(3) 0.0176(8) Uani d 1 . .
    H H9 0.664006 0.734654 0.858153 0.021 Uiso calc 1 . .
    C C10 0.6803(3) 0.8989(3) 0.7520(3) 0.0156(8) Uani d 1 . .
    C C11 0.9096(3) 0.5772(3) 0.6425(3) 0.0146(7) Uani d 1 . .
    H H11 0.921410 0.531855 0.591715 0.017 Uiso calc 1 . .
    C C12 0.9591(3) 0.5317(3) 0.7280(3) 0.0161(8) Uani d 1 . .
    H H12 1.001666 0.454927 0.737285 0.019 Uiso calc 1 . .
    C C13 0.9465(3) 0.5987(3) 0.8004(3) 0.0175(8) Uani d 1 . .
    H H13 0.979346 0.568807 0.860782 0.021 Uiso calc 1 . .
    C C14 0.8857(3) 0.7091(3) 0.7833(3) 0.0158(8) Uani d 1 . .
    H H14 0.877527 0.757892 0.831152 0.019 Uiso calc 1 . .
    C C15 0.8363(3) 0.7496(3) 0.6970(3) 0.0137(7) Uani d 1 . .
    C C16 0.7464(3) 0.5277(3) 0.4209(3) 0.0144(7) Uani d 1 . .
    H H16 0.797867 0.575801 0.360192 0.017 Uiso calc 1 . .
    C C17 0.7062(3) 0.4205(3) 0.4161(3) 0.0176(8) Uani d 1 . .
    H H17 0.733441 0.392770 0.354419 0.021 Uiso calc 1 . .
    C C18 0.6264(3) 0.3535(3) 0.5008(3) 0.0184(8) Uani d 1 . .
    H H18 0.595363 0.280010 0.498074 0.022 Uiso calc 1 . .
    C C19 0.5921(3) 0.3942(3) 0.5895(3) 0.0170(8) Uani d 1 . .
    H H19 0.535170 0.350752 0.648962 0.020 Uiso calc 1 . .
    C C20 0.6420(3) 0.5000(3) 0.5910(3) 0.0128(7) Uani d 1 . .
    C C21 0.6584(4) 0.4546(4) 0.9414(3) 0.0267(10) Uani d 1 . .
    H H21 0.639614 0.487612 1.000517 0.032 Uiso calc 1 . .
    C C22 0.7203(4) 0.3469(4) 0.9493(3) 0.0298(10) Uani d 1 . .
    H H22 0.745311 0.305038 1.011724 0.036 Uiso calc 1 . .
    C C23 0.7458(4) 0.2998(4) 0.8640(4) 0.0311(11) Uani d 1 . .
    H H23 0.788795 0.223605 0.867265 0.037 Uiso calc 1 . .
    C C24 0.7103(4) 0.3607(3) 0.7744(3) 0.0226(9) Uani d 1 . .
    H H24 0.727817 0.328566 0.714851 0.027 Uiso calc 1 . .
    C C25 0.6479(3) 0.4713(3) 0.7736(3) 0.0146(7) Uani d 1 . .
    C C26 0.5354(3) 0.8562(3) 0.5945(3) 0.0149(7) Uani d 1 . .
    H H26 0.567244 0.923808 0.538769 0.018 Uiso calc 1 . .
    C C27 0.4275(3) 0.8713(3) 0.6615(3) 0.0147(7) Uani d 1 . .
    H H27 0.386480 0.948849 0.654234 0.018 Uiso calc 1 . .
    C C28 0.3784(3) 0.7724(4) 0.7402(3) 0.0169(8) Uani d 1 . .
    H H28 0.302883 0.780619 0.787888 0.020 Uiso calc 1 . .
    C C29 0.4402(3) 0.6625(3) 0.7484(3) 0.0165(8) Uani d 1 . .
    H H29 0.407755 0.592811 0.801363 0.020 Uiso calc 1 . .
    C C30 0.5503(3) 0.6541(3) 0.6789(3) 0.0134(7) Uani d 1 . .
    C C31 1.0237(4) 1.0647(4) 0.8564(3) 0.0245(9) Uani d 1 . .
    H H31A 1.002534 1.109425 0.911565 0.029 Uiso calc 1 . .
    H H31B 1.051384 1.124580 0.788381 0.029 Uiso calc 1 . .
    C C32 1.2459(4) 1.2483(4) 0.8893(4) 0.0278(10) Uani d 1 . .
    H H32A 1.254901 1.174403 0.945609 0.033 Uiso calc 1 . .
    H H32B 1.244774 1.221948 0.826080 0.033 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ru1 Cl1 . 2.4157(9) ?
    Ru1 Cl2 . 2.4051(9) ?
    Ru1 N1 . 2.050(3) ?
    Ru1 N2 . 2.027(3) ?
    Ru1 N5 . 2.033(3) ?
    Ru1 N6 . 2.049(3) ?
    Cl3 C31 . 1.763(4) ?
    Cl4 C31 . 1.752(4) ?
    Cl5 C32 . 1.744(4) ?
    Cl6 C32 . 1.755(4) ?
    N1 C1 . 1.345(5) ?
    N1 C5 . 1.327(4) ?
    N2 C11 . 1.346(5) ?
    N2 C15 . 1.348(4) ?
    N3 C6 . 1.327(6) ?
    N3 C10 . 1.337(5) ?
    N4 C5 . 1.403(5) ?
    N4 C10 . 1.406(5) ?
    N4 C15 . 1.410(5) ?
    N5 C26 . 1.348(5) ?
    N5 C30 . 1.327(5) ?
    N6 C16 . 1.336(4) ?
    N6 C20 . 1.335(5) ?
    N7 C21 . 1.338(5) ?
    N7 C25 . 1.320(5) ?
    N8 C20 . 1.406(4) ?
    N8 C25 . 1.399(5) ?
    N8 C30 . 1.408(5) ?
    C1 H1 . 0.9500 ?
    C1 C2 . 1.359(5) ?
    C2 H2 . 0.9500 ?
    C2 C3 . 1.374(5) ?
    C3 H3 . 0.9500 ?
    C3 C4 . 1.368(5) ?
    C4 H4 . 0.9500 ?
    C4 C5 . 1.386(5) ?
    C6 H6 . 0.9500 ?
    C6 C7 . 1.362(7) ?
    C7 H7 . 0.9500 ?
    C7 C8 . 1.376(6) ?
    C8 H8 . 0.9500 ?
    C8 C9 . 1.358(6) ?
    C9 H9 . 0.9500 ?
    C9 C10 . 1.365(5) ?
    C11 H11 . 0.9500 ?
    C11 C12 . 1.367(5) ?
    C12 H12 . 0.9500 ?
    C12 C13 . 1.378(5) ?
    C13 H13 . 0.9500 ?
    C13 C14 . 1.366(5) ?
    C14 H14 . 0.9500 ?
    C14 C15 . 1.370(5) ?
    C16 H16 . 0.9500 ?
    C16 C17 . 1.365(5) ?
    C17 H17 . 0.9500 ?
    C17 C18 . 1.368(5) ?
    C18 H18 . 0.9500 ?
    C18 C19 . 1.369(5) ?
    C19 H19 . 0.9500 ?
    C19 C20 . 1.384(5) ?
    C21 H21 . 0.9500 ?
    C21 C22 . 1.345(6) ?
    C22 H22 . 0.9500 ?
    C22 C23 . 1.367(6) ?
    C23 H23 . 0.9500 ?
    C23 C24 . 1.363(6) ?
    C24 H24 . 0.9500 ?
    C24 C25 . 1.384(5) ?
    C26 H26 . 0.9500 ?
    C26 C27 . 1.359(5) ?
    C27 H27 . 0.9500 ?
    C27 C28 . 1.379(5) ?
    C28 H28 . 0.9500 ?
    C28 C29 . 1.366(5) ?
    C29 H29 . 0.9500 ?
    C29 C30 . 1.378(5) ?
    C31 H31A . 0.9900 ?
    C31 H31B . 0.9900 ?
    C32 H32A . 0.9900 ?
    C32 H32B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    Cl2 Ru1 Cl1 . . 91.45(3) ?
    N1 Ru1 Cl1 . . 88.02(8) ?
    N1 Ru1 Cl2 . . 92.07(9) ?
    N2 Ru1 Cl1 . . 89.57(9) ?
    N2 Ru1 Cl2 . . 178.12(9) ?
    N2 Ru1 N1 . . 86.39(12) ?
    N2 Ru1 N5 . . 89.74(12) ?
    N2 Ru1 N6 . . 95.74(11) ?
    N5 Ru1 Cl1 . . 178.31(9) ?
    N5 Ru1 Cl2 . . 89.28(9) ?
    N5 Ru1 N1 . . 93.48(12) ?
    N5 Ru1 N6 . . 86.78(12) ?
    N6 Ru1 Cl1 . . 91.76(9) ?
    N6 Ru1 Cl2 . . 85.81(8) ?
    N6 Ru1 N1 . . 177.86(12) ?
    C1 N1 Ru1 . . 119.7(2) ?
    C5 N1 Ru1 . . 122.6(2) ?
    C5 N1 C1 . . 117.5(3) ?
    C11 N2 Ru1 . . 120.5(2) ?
    C11 N2 C15 . . 117.2(3) ?
    C15 N2 Ru1 . . 122.4(2) ?
    C6 N3 C10 . . 117.1(4) ?
    C5 N4 C10 . . 119.8(3) ?
    C5 N4 C15 . . 118.7(3) ?
    C10 N4 C15 . . 121.6(3) ?
    C26 N5 Ru1 . . 119.6(2) ?
    C30 N5 Ru1 . . 122.6(2) ?
    C30 N5 C26 . . 117.8(3) ?
    C16 N6 Ru1 . . 120.4(2) ?
    C20 N6 Ru1 . . 121.6(2) ?
    C20 N6 C16 . . 117.5(3) ?
    C25 N7 C21 . . 117.7(4) ?
    C20 N8 C30 . . 117.5(3) ?
    C25 N8 C20 . . 120.7(3) ?
    C25 N8 C30 . . 121.8(3) ?
    N1 C1 H1 . . 118.5 ?
    N1 C1 C2 . . 123.0(3) ?
    C2 C1 H1 . . 118.5 ?
    C1 C2 H2 . . 120.4 ?
    C1 C2 C3 . . 119.1(4) ?
    C3 C2 H2 . . 120.4 ?
    C2 C3 H3 . . 120.6 ?
    C4 C3 C2 . . 118.8(3) ?
    C4 C3 H3 . . 120.6 ?
    C3 C4 H4 . . 120.5 ?
    C3 C4 C5 . . 118.9(3) ?
    C5 C4 H4 . . 120.5 ?
    N1 C5 N4 . . 117.1(3) ?
    N1 C5 C4 . . 122.5(3) ?
    C4 C5 N4 . . 120.4(3) ?
    N3 C6 H6 . . 118.0 ?
    N3 C6 C7 . . 124.0(4) ?
    C7 C6 H6 . . 118.0 ?
    C6 C7 H7 . . 121.4 ?
    C6 C7 C8 . . 117.2(4) ?
    C8 C7 H7 . . 121.4 ?
    C7 C8 H8 . . 119.7 ?
    C9 C8 C7 . . 120.5(4) ?
    C9 C8 H8 . . 119.7 ?
    C8 C9 H9 . . 121.0 ?
    C8 C9 C10 . . 118.0(4) ?
    C10 C9 H9 . . 121.0 ?
    N3 C10 N4 . . 116.1(3) ?
    N3 C10 C9 . . 123.2(4) ?
    C9 C10 N4 . . 120.7(3) ?
    N2 C11 H11 . . 118.5 ?
    N2 C11 C12 . . 123.0(3) ?
    C12 C11 H11 . . 118.5 ?
    C11 C12 H12 . . 120.5 ?
    C11 C12 C13 . . 119.1(4) ?
    C13 C12 H12 . . 120.5 ?
    C12 C13 H13 . . 120.8 ?
    C14 C13 C12 . . 118.4(3) ?
    C14 C13 H13 . . 120.8 ?
    C13 C14 H14 . . 120.0 ?
    C13 C14 C15 . . 120.0(3) ?
    C15 C14 H14 . . 120.0 ?
    N2 C15 N4 . . 117.1(3) ?
    N2 C15 C14 . . 122.2(3) ?
    C14 C15 N4 . . 120.7(3) ?
    N6 C16 H16 . . 118.6 ?
    N6 C16 C17 . . 122.8(4) ?
    C17 C16 H16 . . 118.6 ?
    C16 C17 H17 . . 120.3 ?
    C16 C17 C18 . . 119.4(4) ?
    C18 C17 H17 . . 120.3 ?
    C17 C18 H18 . . 120.6 ?
    C17 C18 C19 . . 118.7(3) ?
    C19 C18 H18 . . 120.6 ?
    C18 C19 H19 . . 120.6 ?
    C18 C19 C20 . . 118.7(4) ?
    C20 C19 H19 . . 120.6 ?
    N6 C20 N8 . . 116.9(3) ?
    N6 C20 C19 . . 122.6(3) ?
    C19 C20 N8 . . 120.4(3) ?
    N7 C21 H21 . . 118.1 ?
    N7 C21 C22 . . 123.8(4) ?
    C22 C21 H21 . . 118.1 ?
    C21 C22 H22 . . 121.2 ?
    C21 C22 C23 . . 117.5(4) ?
    C23 C22 H22 . . 121.2 ?
    C22 C23 H23 . . 119.5 ?
    C24 C23 C22 . . 120.9(4) ?
    C24 C23 H23 . . 119.5 ?
    C23 C24 H24 . . 121.3 ?
    C23 C24 C25 . . 117.3(4) ?
    C25 C24 H24 . . 121.3 ?
    N7 C25 N8 . . 117.1(3) ?
    N7 C25 C24 . . 122.7(4) ?
    C24 C25 N8 . . 120.2(3) ?
    N5 C26 H26 . . 118.6 ?
    N5 C26 C27 . . 122.7(4) ?
    C27 C26 H26 . . 118.6 ?
    C26 C27 H27 . . 120.5 ?
    C26 C27 C28 . . 119.0(3) ?
    C28 C27 H27 . . 120.5 ?
    C27 C28 H28 . . 120.6 ?
    C29 C28 C27 . . 118.8(4) ?
    C29 C28 H28 . . 120.6 ?
    C28 C29 H29 . . 120.4 ?
    C28 C29 C30 . . 119.2(4) ?
    C30 C29 H29 . . 120.4 ?
    N5 C30 N8 . . 116.8(3) ?
    N5 C30 C29 . . 122.5(3) ?
    C29 C30 N8 . . 120.6(3) ?
    Cl3 C31 H31A . . 109.4 ?
    Cl3 C31 H31B . . 109.4 ?
    Cl4 C31 Cl3 . . 111.2(2) ?
    Cl4 C31 H31A . . 109.4 ?
    Cl4 C31 H31B . . 109.4 ?
    H31A C31 H31B . . 108.0 ?
    Cl5 C32 Cl6 . . 112.2(2) ?
    Cl5 C32 H32A . . 109.2 ?
    Cl5 C32 H32B . . 109.2 ?
    Cl6 C32 H32A . . 109.2 ?
    Cl6 C32 H32B . . 109.2 ?
    H32A C32 H32B . . 107.9 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Ru1 N1 C1 C2 . . . . -176.7(3) ?
    Ru1 N1 C5 N4 . . . . -6.5(4) ?
    Ru1 N1 C5 C4 . . . . 173.5(3) ?
    Ru1 N2 C11 C12 . . . . -175.5(3) ?
    Ru1 N2 C15 N4 . . . . -4.9(4) ?
    Ru1 N2 C15 C14 . . . . 176.5(3) ?
    Ru1 N5 C26 C27 . . . . -176.9(3) ?
    Ru1 N5 C30 N8 . . . . -4.2(4) ?
    Ru1 N5 C30 C29 . . . . 178.0(3) ?
    Ru1 N6 C16 C17 . . . . -172.9(3) ?
    Ru1 N6 C20 N8 . . . . -10.5(4) ?
    Ru1 N6 C20 C19 . . . . 168.8(3) ?
    N1 C1 C2 C3 . . . . 2.9(6) ?
    N2 C11 C12 C13 . . . . -2.3(5) ?
    N3 C6 C7 C8 . . . . -0.4(7) ?
    N5 C26 C27 C28 . . . . -2.4(5) ?
    N6 C16 C17 C18 . . . . 3.8(6) ?
    N7 C21 C22 C23 . . . . -0.6(7) ?
    C1 N1 C5 N4 . . . . 178.3(3) ?
    C1 N1 C5 C4 . . . . -1.7(5) ?
    C1 C2 C3 C4 . . . . -1.5(6) ?
    C2 C3 C4 C5 . . . . -1.3(5) ?
    C3 C4 C5 N1 . . . . 3.0(5) ?
    C3 C4 C5 N4 . . . . -177.0(3) ?
    C5 N1 C1 C2 . . . . -1.3(5) ?
    C5 N4 C10 N3 . . . . -5.4(5) ?
    C5 N4 C10 C9 . . . . 172.0(3) ?
    C5 N4 C15 N2 . . . . -52.7(4) ?
    C5 N4 C15 C14 . . . . 125.9(4) ?
    C6 N3 C10 N4 . . . . 176.5(3) ?
    C6 N3 C10 C9 . . . . -0.8(6) ?
    C6 C7 C8 C9 . . . . 0.2(6) ?
    C7 C8 C9 C10 . . . . -0.3(6) ?
    C8 C9 C10 N3 . . . . 0.7(6) ?
    C8 C9 C10 N4 . . . . -176.6(3) ?
    C10 N3 C6 C7 . . . . 0.7(6) ?
    C10 N4 C5 N1 . . . . -121.4(4) ?
    C10 N4 C5 C4 . . . . 58.6(5) ?
    C10 N4 C15 N2 . . . . 127.9(3) ?
    C10 N4 C15 C14 . . . . -53.5(5) ?
    C11 N2 C15 N4 . . . . 175.4(3) ?
    C11 N2 C15 C14 . . . . -3.2(5) ?
    C11 C12 C13 C14 . . . . -0.6(5) ?
    C12 C13 C14 C15 . . . . 1.5(6) ?
    C13 C14 C15 N2 . . . . 0.4(6) ?
    C13 C14 C15 N4 . . . . -178.2(3) ?
    C15 N2 C11 C12 . . . . 4.2(5) ?
    C15 N4 C5 N1 . . . . 59.2(4) ?
    C15 N4 C5 C4 . . . . -120.8(4) ?
    C15 N4 C10 N3 . . . . 174.0(3) ?
    C15 N4 C10 C9 . . . . -8.6(5) ?
    C16 N6 C20 N8 . . . . 178.2(3) ?
    C16 N6 C20 C19 . . . . -2.5(5) ?
    C16 C17 C18 C19 . . . . -2.0(6) ?
    C17 C18 C19 C20 . . . . -1.7(6) ?
    C18 C19 C20 N6 . . . . 4.1(6) ?
    C18 C19 C20 N8 . . . . -176.6(3) ?
    C20 N6 C16 C17 . . . . -1.5(5) ?
    C20 N8 C25 N7 . . . . 178.0(3) ?
    C20 N8 C25 C24 . . . . 0.6(5) ?
    C20 N8 C30 N5 . . . . -54.5(4) ?
    C20 N8 C30 C29 . . . . 123.2(4) ?
    C21 N7 C25 N8 . . . . -177.0(3) ?
    C21 N7 C25 C24 . . . . 0.3(6) ?
    C21 C22 C23 C24 . . . . 0.5(7) ?
    C22 C23 C24 C25 . . . . 0.0(6) ?
    C23 C24 C25 N7 . . . . -0.4(6) ?
    C23 C24 C25 N8 . . . . 176.9(4) ?
    C25 N7 C21 C22 . . . . 0.2(6) ?
    C25 N8 C20 N6 . . . . -117.6(4) ?
    C25 N8 C20 C19 . . . . 63.0(5) ?
    C25 N8 C30 N5 . . . . 126.2(4) ?
    C25 N8 C30 C29 . . . . -56.1(5) ?
    C26 N5 C30 N8 . . . . 175.6(3) ?
    C26 N5 C30 C29 . . . . -2.1(5) ?
    C26 C27 C28 C29 . . . . 0.2(5) ?
    C27 C28 C29 C30 . . . . 0.8(5) ?
    C28 C29 C30 N5 . . . . 0.1(5) ?
    C28 C29 C30 N8 . . . . -177.6(3) ?
    C30 N5 C26 C27 . . . . 3.3(5) ?
    C30 N8 C20 N6 . . . . 63.1(4) ?
    C30 N8 C20 C19 . . . . -116.3(4) ?
    C30 N8 C25 N7 . . . . -2.7(5) ?
    C30 N8 C25 C24 . . . . 179.8(3) ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.706
_shelx_estimated_absorpt_T_max     0.823
data_2b
_audit_creation_method
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_chemical_name_systematic
;\
Chlorido[tris(pyridin-2-yl)amine-κ²N,N'][tris(pyridin-2-\
yl)amine-κ³N,N',N'']ruthenium(II)
hexafluoridoantimonate chloroform monosolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C30 H24 Cl N8 Ru +, F6 Sb -, C H Cl3'
_chemical_formula_sum     'C31 H25 Cl4 F6 N8 Ru Sb'
_chemical_formula_iupac     '[Ru Cl (C15 H12 N4)2] [Sb F6], C H Cl3'
_chemical_formula_weight     988.21
_chemical_melting_point     ?
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 1 21/n 1'
_space_group_name_Hall     '-P 2yn'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     8.3209(3)
_cell_length_b     27.3213(10)
_cell_length_c     15.7839(6)
_cell_angle_alpha     90
_cell_angle_beta     99.554(4)
_cell_angle_gamma     90
_cell_volume     3538.5(2)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     8950
_cell_measurement_theta_min     3.3270
_cell_measurement_theta_max     30.3910
_cell_measurement_temperature     93(2)
_exptl_crystal_description     Needle
_exptl_crystal_colour     Yellow
_exptl_crystal_size_max     0.2
_exptl_crystal_size_mid     0.04
_exptl_crystal_size_min     0.01
_exptl_crystal_density_diffrn     1.855
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1936
_exptl_absorpt_coefficient_mu     1.561
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2019)
;
_exptl_absorpt_correction_T_min     0.78296
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     93.15
_diffrn_source     ?
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_measurement_device_type     'Dectris Pilatus 3R'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     5.8
_diffrn_reflns_number     32718
_diffrn_reflns_av_R_equivalents     0.0669
_diffrn_reflns_av_unetI/netI     0.0704
_diffrn_reflns_theta_min     2.711
_diffrn_reflns_theta_max     28.282
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.988
_diffrn_measured_fraction_theta_full     0.996
_diffrn_reflns_limit_h_min     -10
_diffrn_reflns_limit_h_max     11
_diffrn_reflns_limit_k_min     -36
_diffrn_reflns_limit_k_max     36
_diffrn_reflns_limit_l_min     -21
_diffrn_reflns_limit_l_max     21
_refine_special_details     ?
_reflns_number_total     8658
_reflns_number_gt     6339
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0829
_refine_ls_R_factor_gt     0.0481
_refine_ls_wR_factor_gt     0.0739
_refine_ls_wR_factor_ref     0.0812
_refine_ls_goodness_of_fit_ref     1.081
_refine_ls_restrained_S_all     1.081
_refine_ls_number_reflns     8658
_refine_ls_number_parameters     460
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0259P)²+4.6355P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.981
_refine_diff_density_min     -1.306
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'F' 'F' 0.0171 0.0103
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ru' 'Ru' -1.2594 0.8363
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Sb' 'Sb' -0.5866 1.5461
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2019)
;
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2019)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2019)
;
_computing_structure_solution
;
olex2.solve (Bourhis et al.,  2015)
;
_computing_structure_refinement
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Sb Sb1 0.69166(3) 0.62728(2) -0.05383(2) 0.01521(7) Uani d 1 . .
    F F1 0.6827(4) 0.59602(10) 0.05068(15) 0.0327(7) Uani d 1 . .
    F F2 0.5627(3) 0.67836(9) -0.02234(18) 0.0328(7) Uani d 1 . .
    F F3 0.8788(3) 0.66146(10) -0.00166(16) 0.0287(6) Uani d 1 . .
    F F4 0.8247(3) 0.57702(10) -0.08400(18) 0.0355(7) Uani d 1 . .
    F F5 0.5049(3) 0.59389(11) -0.10526(17) 0.0349(7) Uani d 1 . .
    F F6 0.7015(4) 0.65920(12) -0.15811(16) 0.0418(8) Uani d 1 . .
    Ru Ru1 0.58927(4) 0.60754(2) 0.30593(2) 0.00852(7) Uani d 1 . .
    Cl Cl1 0.77395(11) 0.59764(3) 0.44096(5) 0.01372(19) Uani d 1 . .
    N N2 0.7417(4) 0.56320(12) 0.24889(19) 0.0107(6) Uani d 1 . .
    N N3 0.4391(4) 0.60839(12) 0.18936(19) 0.0115(6) Uani d 1 . .
    N N1 0.4703(4) 0.54419(11) 0.32919(19) 0.0113(7) Uani d 1 . .
    N N4 0.4977(4) 0.52254(12) 0.18626(18) 0.0115(7) Uani d 1 . .
    N N5 0.7063(4) 0.67232(12) 0.28082(19) 0.0115(7) Uani d 1 . .
    N N6 0.4277(4) 0.65211(12) 0.35747(19) 0.0117(7) Uani d 1 . .
    N N8 0.6459(4) 0.70582(12) 0.40989(19) 0.0123(7) Uani d 1 . .
    N N7 0.8885(4) 0.72276(13) 0.5000(2) 0.0177(7) Uani d 1 . .
    C C6 0.9055(5) 0.56764(15) 0.2601(2) 0.0141(8) Uani d 1 . .
    H H6 0.957103 0.592094 0.297909 0.017 Uiso calc 1 . .
    C C7 0.9997(5) 0.53763(15) 0.2181(3) 0.0185(9) Uani d 1 . .
    H H7 1.114568 0.541992 0.226651 0.022 Uiso calc 1 . .
    C C8 0.9284(5) 0.50120(15) 0.1636(2) 0.0185(9) Uani d 1 . .
    H H8 0.992479 0.480445 0.134202 0.022 Uiso calc 1 . .
    C C9 0.7597(5) 0.49589(15) 0.1530(2) 0.0152(8) Uani d 1 . .
    H H9 0.706172 0.470935 0.117000 0.018 Uiso calc 1 . .
    C C10 0.6719(5) 0.52755(14) 0.1958(2) 0.0118(8) Uani d 1 . .
    C C11 0.3591(5) 0.64812(15) 0.1527(2) 0.0162(8) Uani d 1 . .
    H H11 0.378994 0.678958 0.180210 0.019 Uiso calc 1 . .
    C C12 0.2496(5) 0.64568(16) 0.0766(2) 0.0186(9) Uani d 1 . .
    H H12 0.195487 0.674313 0.052487 0.022 Uiso calc 1 . .
    C C13 0.2198(5) 0.60054(17) 0.0360(3) 0.0218(10) Uani d 1 . .
    H H13 0.143533 0.597921 -0.015685 0.026 Uiso calc 1 . .
    C C14 0.3023(5) 0.55957(16) 0.0716(2) 0.0158(8) Uani d 1 . .
    H H14 0.284818 0.528513 0.044608 0.019 Uiso calc 1 . .
    C C15 0.4114(5) 0.56490(15) 0.1478(2) 0.0127(8) Uani d 1 . .
    C C1 0.4138(5) 0.53416(15) 0.4028(2) 0.0146(8) Uani d 1 . .
    H H1 0.427994 0.557844 0.447456 0.017 Uiso calc 1 . .
    C C2 0.3361(5) 0.49068(16) 0.4153(3) 0.0181(9) Uani d 1 . .
    H H2 0.295013 0.485214 0.467210 0.022 Uiso calc 1 . .
    C C3 0.3185(5) 0.45529(15) 0.3522(3) 0.0177(9) Uani d 1 . .
    H H3 0.269121 0.424770 0.360926 0.021 Uiso calc 1 . .
    C C4 0.3740(5) 0.46486(15) 0.2756(2) 0.0171(9) Uani d 1 . .
    H H4 0.362905 0.441262 0.230780 0.021 Uiso calc 1 . .
    C C5 0.4461(4) 0.50989(14) 0.2664(2) 0.0118(8) Uani d 1 . .
    C C16 0.7696(5) 0.67804(15) 0.2075(2) 0.0142(8) Uani d 1 . .
    H H16 0.755458 0.652306 0.166493 0.017 Uiso calc 1 . .
    C C17 0.8538(5) 0.71946(16) 0.1895(2) 0.0176(9) Uani d 1 . .
    H H17 0.898884 0.721472 0.138081 0.021 Uiso calc 1 . .
    C C18 0.8713(5) 0.75793(16) 0.2476(3) 0.0188(9) Uani d 1 . .
    H H18 0.928272 0.786806 0.236878 0.023 Uiso calc 1 . .
    C C19 0.8034(5) 0.75320(15) 0.3218(2) 0.0152(8) Uani d 1 . .
    H H19 0.811851 0.779197 0.362252 0.018 Uiso calc 1 . .
    C C20 0.7234(4) 0.71047(14) 0.3365(2) 0.0113(8) Uani d 1 . .
    C C21 0.2662(5) 0.64252(15) 0.3464(2) 0.0162(8) Uani d 1 . .
    H H21 0.228360 0.612872 0.318558 0.019 Uiso calc 1 . .
    C C22 0.1540(5) 0.67308(16) 0.3730(3) 0.0192(9) Uani d 1 . .
    H H22 0.042697 0.663737 0.366764 0.023 Uiso calc 1 . .
    C C23 0.2053(5) 0.71796(16) 0.4093(3) 0.0188(9) Uani d 1 . .
    H H23 0.129180 0.740390 0.426053 0.023 Uiso calc 1 . .
    C C24 0.3687(5) 0.72921(15) 0.4203(2) 0.0163(9) Uani d 1 . .
    H H24 0.407285 0.759756 0.444306 0.020 Uiso calc 1 . .
    C C25 0.4759(5) 0.69520(14) 0.3959(2) 0.0120(8) Uani d 1 . .
    C C26 0.9761(5) 0.72691(16) 0.5791(3) 0.0207(9) Uani d 1 . .
    H H26 1.087385 0.736011 0.583817 0.025 Uiso calc 1 . .
    C C27 0.9150(6) 0.71882(17) 0.6538(3) 0.0244(10) Uani d 1 . .
    H H27 0.982144 0.721872 0.708417 0.029 Uiso calc 1 . .
    C C28 0.7517(6) 0.70605(17) 0.6463(3) 0.0249(10) Uani d 1 . .
    H H28 0.705096 0.700071 0.696331 0.030 Uiso calc 1 . .
    C C29 0.6573(5) 0.70206(16) 0.5659(2) 0.0200(9) Uani d 1 . .
    H H29 0.545079 0.693674 0.559312 0.024 Uiso calc 1 . .
    C C30 0.7328(5) 0.71082(14) 0.4946(2) 0.0119(8) Uani d 1 . .
    Cl Cl2 1.1042(2) 0.60896(5) 0.71672(8) 0.0461(4) Uani d 1 . .
    Cl Cl3 1.30678(17) 0.62246(5) 0.58615(9) 0.0424(3) Uani d 1 . .
    Cl Cl4 1.14129(16) 0.53000(4) 0.59932(7) 0.0312(3) Uani d 1 . .
    C C31 1.1291(6) 0.59395(18) 0.6109(3) 0.0276(11) Uani d 1 . .
    H H31 1.032515 0.606278 0.570191 0.033 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Sb1 F1 . 1.870(2) ?
    Sb1 F2 . 1.877(3) ?
    Sb1 F3 . 1.884(2) ?
    Sb1 F4 . 1.874(3) ?
    Sb1 F5 . 1.867(3) ?
    Sb1 F6 . 1.876(3) ?
    Ru1 Cl1 . 2.4269(9) ?
    Ru1 N2 . 2.065(3) ?
    Ru1 N3 . 2.046(3) ?
    Ru1 N1 . 2.057(3) ?
    Ru1 N5 . 2.090(3) ?
    Ru1 N6 . 2.077(3) ?
    N2 C6 . 1.350(5) ?
    N2 C10 . 1.351(5) ?
    N3 C11 . 1.352(5) ?
    N3 C15 . 1.358(5) ?
    N1 C1 . 1.351(5) ?
    N1 C5 . 1.354(5) ?
    N4 C10 . 1.439(5) ?
    N4 C15 . 1.442(5) ?
    N4 C5 . 1.444(5) ?
    N5 C16 . 1.357(5) ?
    N5 C20 . 1.355(5) ?
    N6 C21 . 1.352(5) ?
    N6 C25 . 1.354(5) ?
    N8 C20 . 1.423(5) ?
    N8 C25 . 1.425(5) ?
    N8 C30 . 1.417(5) ?
    N7 C26 . 1.341(5) ?
    N7 C30 . 1.325(5) ?
    C6 H6 . 0.9500 ?
    C6 C7 . 1.378(6) ?
    C7 H7 . 0.9500 ?
    C7 C8 . 1.384(6) ?
    C8 H8 . 0.9500 ?
    C8 C9 . 1.393(6) ?
    C9 H9 . 0.9500 ?
    C9 C10 . 1.379(5) ?
    C11 H11 . 0.9500 ?
    C11 C12 . 1.383(5) ?
    C12 H12 . 0.9500 ?
    C12 C13 . 1.393(6) ?
    C13 H13 . 0.9500 ?
    C13 C14 . 1.383(6) ?
    C14 H14 . 0.9500 ?
    C14 C15 . 1.389(5) ?
    C1 H1 . 0.9500 ?
    C1 C2 . 1.382(6) ?
    C2 H2 . 0.9500 ?
    C2 C3 . 1.379(6) ?
    C3 H3 . 0.9500 ?
    C3 C4 . 1.388(6) ?
    C4 H4 . 0.9500 ?
    C4 C5 . 1.387(6) ?
    C16 H16 . 0.9500 ?
    C16 C17 . 1.385(6) ?
    C17 H17 . 0.9500 ?
    C17 C18 . 1.387(6) ?
    C18 H18 . 0.9500 ?
    C18 C19 . 1.388(6) ?
    C19 H19 . 0.9500 ?
    C19 C20 . 1.382(5) ?
    C21 H21 . 0.9500 ?
    C21 C22 . 1.369(6) ?
    C22 H22 . 0.9500 ?
    C22 C23 . 1.390(6) ?
    C23 H23 . 0.9500 ?
    C23 C24 . 1.376(6) ?
    C24 H24 . 0.9500 ?
    C24 C25 . 1.387(5) ?
    C26 H26 . 0.9500 ?
    C26 C27 . 1.377(6) ?
    C27 H27 . 0.9500 ?
    C27 C28 . 1.389(7) ?
    C28 H28 . 0.9500 ?
    C28 C29 . 1.382(6) ?
    C29 H29 . 0.9500 ?
    C29 C30 . 1.398(5) ?
    Cl2 C31 . 1.765(5) ?
    Cl3 C31 . 1.771(5) ?
    Cl4 C31 . 1.761(5) ?
    C31 H31 . 1.0000 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    F1 Sb1 F2 . . 89.87(12) ?
    F1 Sb1 F3 . . 89.53(12) ?
    F1 Sb1 F4 . . 90.06(13) ?
    F1 Sb1 F6 . . 179.44(13) ?
    F2 Sb1 F3 . . 89.04(12) ?
    F4 Sb1 F2 . . 178.69(13) ?
    F4 Sb1 F3 . . 89.66(12) ?
    F4 Sb1 F6 . . 90.24(14) ?
    F5 Sb1 F1 . . 90.47(13) ?
    F5 Sb1 F2 . . 90.42(13) ?
    F5 Sb1 F3 . . 179.46(13) ?
    F5 Sb1 F4 . . 90.88(13) ?
    F5 Sb1 F6 . . 90.00(13) ?
    F6 Sb1 F2 . . 89.82(13) ?
    F6 Sb1 F3 . . 89.99(13) ?
    N2 Ru1 Cl1 . . 88.41(9) ?
    N2 Ru1 N5 . . 94.29(12) ?
    N2 Ru1 N6 . . 177.10(12) ?
    N3 Ru1 Cl1 . . 173.96(10) ?
    N3 Ru1 N2 . . 86.69(12) ?
    N3 Ru1 N1 . . 85.98(12) ?
    N3 Ru1 N5 . . 93.11(12) ?
    N3 Ru1 N6 . . 90.41(12) ?
    N1 Ru1 Cl1 . . 90.16(9) ?
    N1 Ru1 N2 . . 86.14(12) ?
    N1 Ru1 N5 . . 178.97(12) ?
    N1 Ru1 N6 . . 93.53(13) ?
    N5 Ru1 Cl1 . . 90.79(8) ?
    N6 Ru1 Cl1 . . 94.47(8) ?
    N6 Ru1 N5 . . 85.99(13) ?
    C6 N2 Ru1 . . 124.7(3) ?
    C6 N2 C10 . . 117.8(3) ?
    C10 N2 Ru1 . . 117.5(3) ?
    C11 N3 Ru1 . . 125.3(3) ?
    C11 N3 C15 . . 117.6(3) ?
    C15 N3 Ru1 . . 117.0(3) ?
    C1 N1 Ru1 . . 124.8(3) ?
    C1 N1 C5 . . 117.2(3) ?
    C5 N1 Ru1 . . 118.0(3) ?
    C10 N4 C15 . . 113.0(3) ?
    C10 N4 C5 . . 111.8(3) ?
    C15 N4 C5 . . 111.2(3) ?
    C16 N5 Ru1 . . 121.2(3) ?
    C20 N5 Ru1 . . 122.0(2) ?
    C20 N5 C16 . . 116.7(3) ?
    C21 N6 Ru1 . . 122.0(3) ?
    C21 N6 C25 . . 116.1(3) ?
    C25 N6 Ru1 . . 121.5(3) ?
    C20 N8 C25 . . 117.7(3) ?
    C30 N8 C20 . . 122.1(3) ?
    C30 N8 C25 . . 120.3(3) ?
    C30 N7 C26 . . 117.0(4) ?
    N2 C6 H6 . . 119.1 ?
    N2 C6 C7 . . 121.8(4) ?
    C7 C6 H6 . . 119.1 ?
    C6 C7 H7 . . 119.8 ?
    C6 C7 C8 . . 120.5(4) ?
    C8 C7 H7 . . 119.8 ?
    C7 C8 H8 . . 121.0 ?
    C7 C8 C9 . . 118.0(4) ?
    C9 C8 H8 . . 121.0 ?
    C8 C9 H9 . . 120.6 ?
    C10 C9 C8 . . 118.8(4) ?
    C10 C9 H9 . . 120.6 ?
    N2 C10 N4 . . 117.1(3) ?
    N2 C10 C9 . . 123.2(4) ?
    C9 C10 N4 . . 119.7(3) ?
    N3 C11 H11 . . 118.7 ?
    N3 C11 C12 . . 122.7(4) ?
    C12 C11 H11 . . 118.7 ?
    C11 C12 H12 . . 120.6 ?
    C11 C12 C13 . . 118.9(4) ?
    C13 C12 H12 . . 120.6 ?
    C12 C13 H13 . . 120.3 ?
    C14 C13 C12 . . 119.4(4) ?
    C14 C13 H13 . . 120.3 ?
    C13 C14 H14 . . 120.8 ?
    C13 C14 C15 . . 118.4(4) ?
    C15 C14 H14 . . 120.8 ?
    N3 C15 N4 . . 117.8(3) ?
    N3 C15 C14 . . 122.9(4) ?
    C14 C15 N4 . . 119.2(3) ?
    N1 C1 H1 . . 118.8 ?
    N1 C1 C2 . . 122.4(4) ?
    C2 C1 H1 . . 118.8 ?
    C1 C2 H2 . . 120.2 ?
    C3 C2 C1 . . 119.6(4) ?
    C3 C2 H2 . . 120.2 ?
    C2 C3 H3 . . 120.4 ?
    C2 C3 C4 . . 119.1(4) ?
    C4 C3 H3 . . 120.4 ?
    C3 C4 H4 . . 121.0 ?
    C5 C4 C3 . . 118.0(4) ?
    C5 C4 H4 . . 121.0 ?
    N1 C5 N4 . . 116.5(3) ?
    N1 C5 C4 . . 123.5(3) ?
    C4 C5 N4 . . 120.0(3) ?
    N5 C16 H16 . . 118.3 ?
    N5 C16 C17 . . 123.4(4) ?
    C17 C16 H16 . . 118.3 ?
    C16 C17 H17 . . 120.5 ?
    C16 C17 C18 . . 119.0(4) ?
    C18 C17 H17 . . 120.5 ?
    C17 C18 H18 . . 120.8 ?
    C17 C18 C19 . . 118.4(4) ?
    C19 C18 H18 . . 120.8 ?
    C18 C19 H19 . . 120.2 ?
    C20 C19 C18 . . 119.6(4) ?
    C20 C19 H19 . . 120.2 ?
    N5 C20 N8 . . 116.5(3) ?
    N5 C20 C19 . . 122.9(4) ?
    C19 C20 N8 . . 120.5(3) ?
    N6 C21 H21 . . 118.1 ?
    N6 C21 C22 . . 123.8(4) ?
    C22 C21 H21 . . 118.1 ?
    C21 C22 H22 . . 120.5 ?
    C21 C22 C23 . . 119.1(4) ?
    C23 C22 H22 . . 120.5 ?
    C22 C23 H23 . . 120.7 ?
    C24 C23 C22 . . 118.6(4) ?
    C24 C23 H23 . . 120.7 ?
    C23 C24 H24 . . 120.6 ?
    C23 C24 C25 . . 118.9(4) ?
    C25 C24 H24 . . 120.6 ?
    N6 C25 N8 . . 117.3(3) ?
    N6 C25 C24 . . 123.4(4) ?
    C24 C25 N8 . . 119.2(3) ?
    N7 C26 H26 . . 117.9 ?
    N7 C26 C27 . . 124.3(4) ?
    C27 C26 H26 . . 117.9 ?
    C26 C27 H27 . . 121.2 ?
    C26 C27 C28 . . 117.5(4) ?
    C28 C27 H27 . . 121.2 ?
    C27 C28 H28 . . 120.1 ?
    C29 C28 C27 . . 119.8(4) ?
    C29 C28 H28 . . 120.1 ?
    C28 C29 H29 . . 121.2 ?
    C28 C29 C30 . . 117.6(4) ?
    C30 C29 H29 . . 121.2 ?
    N7 C30 N8 . . 115.1(3) ?
    N7 C30 C29 . . 123.8(3) ?
    C29 C30 N8 . . 121.0(3) ?
    Cl2 C31 Cl3 . . 109.9(3) ?
    Cl2 C31 H31 . . 108.8 ?
    Cl3 C31 H31 . . 108.8 ?
    Cl4 C31 Cl2 . . 110.3(3) ?
    Cl4 C31 Cl3 . . 110.4(3) ?
    Cl4 C31 H31 . . 108.8 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Ru1 N2 C6 C7 . . . . -178.1(3) ?
    Ru1 N2 C10 N4 . . . . -2.2(4) ?
    Ru1 N2 C10 C9 . . . . 179.2(3) ?
    Ru1 N3 C11 C12 . . . . -175.0(3) ?
    Ru1 N3 C15 N4 . . . . -3.9(4) ?
    Ru1 N3 C15 C14 . . . . 174.8(3) ?
    Ru1 N1 C1 C2 . . . . -179.3(3) ?
    Ru1 N1 C5 N4 . . . . -3.8(4) ?
    Ru1 N1 C5 C4 . . . . 177.1(3) ?
    Ru1 N5 C16 C17 . . . . -177.4(3) ?
    Ru1 N5 C20 N8 . . . . -5.0(4) ?
    Ru1 N5 C20 C19 . . . . 178.6(3) ?
    Ru1 N6 C21 C22 . . . . -174.3(3) ?
    Ru1 N6 C25 N8 . . . . -8.2(5) ?
    Ru1 N6 C25 C24 . . . . 170.7(3) ?
    N2 C6 C7 C8 . . . . -1.0(6) ?
    N3 C11 C12 C13 . . . . 0.1(6) ?
    N1 C1 C2 C3 . . . . 1.8(6) ?
    N5 C16 C17 C18 . . . . -1.9(6) ?
    N6 C21 C22 C23 . . . . 3.8(6) ?
    N7 C26 C27 C28 . . . . -0.7(7) ?
    C6 N2 C10 N4 . . . . 178.5(3) ?
    C6 N2 C10 C9 . . . . -0.1(5) ?
    C6 C7 C8 C9 . . . . -0.2(6) ?
    C7 C8 C9 C10 . . . . 1.2(6) ?
    C8 C9 C10 N2 . . . . -1.1(6) ?
    C8 C9 C10 N4 . . . . -179.6(3) ?
    C10 N2 C6 C7 . . . . 1.1(6) ?
    C10 N4 C15 N3 . . . . -60.3(4) ?
    C10 N4 C15 C14 . . . . 120.9(4) ?
    C10 N4 C5 N1 . . . . 66.4(4) ?
    C10 N4 C5 C4 . . . . -114.5(4) ?
    C11 N3 C15 N4 . . . . 179.4(3) ?
    C11 N3 C15 C14 . . . . -1.9(6) ?
    C11 C12 C13 C14 . . . . -1.2(6) ?
    C12 C13 C14 C15 . . . . 0.8(6) ?
    C13 C14 C15 N3 . . . . 0.8(6) ?
    C13 C14 C15 N4 . . . . 179.6(4) ?
    C15 N3 C11 C12 . . . . 1.4(6) ?
    C15 N4 C10 N2 . . . . 63.7(4) ?
    C15 N4 C10 C9 . . . . -117.6(4) ?
    C15 N4 C5 N1 . . . . -60.9(4) ?
    C15 N4 C5 C4 . . . . 118.2(4) ?
    C1 N1 C5 N4 . . . . 176.1(3) ?
    C1 N1 C5 C4 . . . . -3.0(5) ?
    C1 C2 C3 C4 . . . . -2.4(6) ?
    C2 C3 C4 C5 . . . . 0.4(6) ?
    C3 C4 C5 N1 . . . . 2.4(6) ?
    C3 C4 C5 N4 . . . . -176.7(3) ?
    C5 N1 C1 C2 . . . . 0.8(6) ?
    C5 N4 C10 N2 . . . . -62.6(4) ?
    C5 N4 C10 C9 . . . . 116.0(4) ?
    C5 N4 C15 N3 . . . . 66.4(4) ?
    C5 N4 C15 C14 . . . . -112.4(4) ?
    C16 N5 C20 N8 . . . . 175.2(3) ?
    C16 N5 C20 C19 . . . . -1.2(5) ?
    C16 C17 C18 C19 . . . . 0.1(6) ?
    C17 C18 C19 C20 . . . . 1.1(6) ?
    C18 C19 C20 N5 . . . . -0.5(6) ?
    C18 C19 C20 N8 . . . . -176.8(3) ?
    C20 N5 C16 C17 . . . . 2.4(5) ?
    C20 N8 C25 N6 . . . . 62.8(5) ?
    C20 N8 C25 C24 . . . . -116.1(4) ?
    C20 N8 C30 N7 . . . . 3.6(5) ?
    C20 N8 C30 C29 . . . . -174.6(4) ?
    C21 N6 C25 N8 . . . . 178.8(3) ?
    C21 N6 C25 C24 . . . . -2.4(6) ?
    C21 C22 C23 C24 . . . . -2.6(6) ?
    C22 C23 C24 C25 . . . . -0.8(6) ?
    C23 C24 C25 N6 . . . . 3.4(6) ?
    C23 C24 C25 N8 . . . . -177.8(4) ?
    C25 N6 C21 C22 . . . . -1.3(6) ?
    C25 N8 C20 N5 . . . . -54.6(5) ?
    C25 N8 C20 C19 . . . . 121.9(4) ?
    C25 N8 C30 N7 . . . . -177.2(4) ?
    C25 N8 C30 C29 . . . . 4.6(6) ?
    C26 N7 C30 N8 . . . . -178.7(4) ?
    C26 N7 C30 C29 . . . . -0.6(6) ?
    C26 C27 C28 C29 . . . . -0.2(7) ?
    C27 C28 C29 C30 . . . . 0.6(7) ?
    C28 C29 C30 N8 . . . . 177.8(4) ?
    C28 C29 C30 N7 . . . . -0.2(7) ?
    C30 N8 C20 N5 . . . . 124.6(4) ?
    C30 N8 C20 C19 . . . . -58.9(5) ?
    C30 N8 C25 N6 . . . . -116.4(4) ?
    C30 N8 C25 C24 . . . . 64.7(5) ?
    C30 N7 C26 C27 . . . . 1.1(7) ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     0.745
_shelx_estimated_absorpt_T_max     0.985
data_global
_journal_data_validation_number     ?
_journal_date_recd_electronic     2023-08-10
_journal_date_accepted     2023-10-26
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2023
_journal_volume     79
_journal_issue     12
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     FA
_journal_paper_doi     10.1107/S2053229623009415
_journal_coeditor_code     DG3046
_publ_contact_author_name
;
Jack Faller
;
_publ_contact_author_address
;
Department of Chemistry
Yale University
PO Box 208107
New Haven
Connecticut 06520-8107
USA
;
_publ_contact_author_email     'jack.faller@yale.edu'
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;
Studies of κ²- and κ³-tripyridylamine complexes of ruthenium and
π-stacking by pyridyls
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Jack Faller' .
;
Department of Chemistry
Yale University
PO Box 208107
New Haven
Connecticut 06520-8107
USA
;
    'Kevin J. Chase' .
;
Department of Chemistry
Yale University
PO Box 208107
New Haven
Connecticut 06520-8107
USA
;
    'Jonathan Parr' .
;
Department of Chemistry
Yale University
PO Box 208107
New Haven
Connecticut 06520-8107
USA
;
    'Brandon Mercado' .
;
Department of Chemistry
Yale University
PO Box 208107
New Haven
Connecticut 06520-8107
USA
;
_publ_section_synopsis
;
The propensity for the central amine N atom in tris(pyridin-2-yl)amine [or
(2-py)₃N] to remain sp²-hydridized allows the isolation of
complexes containing either κ²- or κ³-(2-py)₃N, or both, as in
[RuCl{κ²-(2-py)₃N}{κ³-(2-py)₃N}][SbF₆].
;
