##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section C. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section C, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     'SHELXL-2014/7'
_database_code_depnum_ccdc_archive     'CCDC 1898827'
_chemical_name_systematic
;
Bis[μ-(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f]\
[1,3,2]dioxaphosphepin-6-yl)oxy]-1:2κ²P:\
O;\
1:2κ²O:P-bis{[6-([1,1'-biphenyl]-2-yloxy)-4,8-di-tert-\
butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine-\
κP]carbonylrhodium} toluene tatrasolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C114 H130 O22 P4 Rh2, 4(C7 H8)'
_chemical_formula_sum     'C142 H162 O22 P4 Rh2'
_chemical_formula_iupac
                        '[Rh2 (C22 H28 O5 P1)2 (C34 H37 O5 P1)2 (C O)2], 4C7 H8'
_chemical_formula_weight     2550.41
_chemical_melting_point     ?
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/n'
_space_group_name_Hall     '-P 2yn'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     13.4100(5)
_cell_length_b     15.5455(5)
_cell_length_c     31.1570(11)
_cell_angle_alpha     90
_cell_angle_beta     98.7430(14)
_cell_angle_gamma     90
_cell_volume     6419.7(4)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     9938
_cell_measurement_theta_min     2.28
_cell_measurement_theta_max     30.28
_cell_measurement_temperature     150(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.414
_exptl_crystal_size_mid     0.336
_exptl_crystal_size_min     0.324
_exptl_crystal_density_diffrn     1.319
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     2680
_exptl_absorpt_coefficient_mu     0.376
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2014)
;
_exptl_absorpt_correction_T_min     0.86
_exptl_absorpt_correction_T_max     0.89
_diffrn_ambient_temperature     150(2)
_diffrn_source     'fine-focus sealed tube'
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_measurement_device_type     'Bruker APEXII CCD'
_diffrn_measurement_method     'φ and ω scans'
_diffrn_detector_area_resol_mean     8.3333
_diffrn_reflns_number     140325
_diffrn_reflns_av_R_equivalents     0.0398
_diffrn_reflns_av_unetI/netI     0.0231
_diffrn_reflns_theta_min     1.578
_diffrn_reflns_theta_max     28.000
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -17
_diffrn_reflns_limit_h_max     17
_diffrn_reflns_limit_k_min     -20
_diffrn_reflns_limit_k_max     20
_diffrn_reflns_limit_l_min     -41
_diffrn_reflns_limit_l_max     41
_refine_special_details     ?
_reflns_number_total     15481
_reflns_number_gt     13358
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0425
_refine_ls_R_factor_gt     0.0353
_refine_ls_wR_factor_gt     0.0870
_refine_ls_wR_factor_ref     0.0929
_refine_ls_goodness_of_fit_ref     1.031
_refine_ls_restrained_S_all     1.031
_refine_ls_number_reflns     15481
_refine_ls_number_parameters     760
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0453P)²+5.3591P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.807
_refine_diff_density_min     -0.395
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Rh' 'Rh' -1.1178 0.9187
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
APEX2 (Bruker, 2014)
;
_computing_cell_refinement
;
SAINT (Bruker, 2013)
;
_computing_data_reduction
;
SAINT (Bruker, 2013)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
XP in SHELXTL (Sheldrick, 2008)
;
_computing_publication_material     ?
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C1 -0.05877(14) 1.10380(12) 0.15205(6) 0.0222(3) Uani d 1 . .
    C C2 0.00322(15) 1.14899(13) 0.12855(6) 0.0274(4) Uani d 1 . .
    H H2 0.0414 1.1195 0.1098 0.033 Uiso calc 1 . .
    C C3 0.00930(18) 1.23754(14) 0.13250(7) 0.0342(5) Uani d 1 . .
    H H3 0.0526 1.2690 0.1167 0.041 Uiso calc 1 . .
    C C4 -0.04732(19) 1.28050(14) 0.15927(7) 0.0387(5) Uani d 1 . .
    H H4 -0.0437 1.3414 0.1618 0.046 Uiso calc 1 . .
    C C5 -0.10935(17) 1.23413(13) 0.18239(7) 0.0343(5) Uani d 1 . .
    H H5 -0.1486 1.2640 0.2005 0.041 Uiso calc 1 . .
    C C6 -0.11587(14) 1.14461(12) 0.17978(6) 0.0255(4) Uani d 1 . .
    C C7 -0.17942(15) 1.09749(13) 0.20697(6) 0.0273(4) Uani d 1 . .
    C C8 -0.28188(16) 1.11705(15) 0.20360(7) 0.0346(5) Uani d 1 . .
    H H8 -0.3115 1.1573 0.1825 0.042 Uiso calc 1 . .
    C C9 -0.34058(17) 1.07785(17) 0.23096(8) 0.0427(6) Uani d 1 . .
    H H9 -0.4104 1.0913 0.2284 0.051 Uiso calc 1 . .
    C C10 -0.29892(18) 1.01997(17) 0.26169(8) 0.0435(6) Uani d 1 . .
    H H10 -0.3397 0.9937 0.2804 0.052 Uiso calc 1 . .
    C C11 -0.19711(18) 0.99962(15) 0.26553(8) 0.0390(5) Uani d 1 . .
    H H11 -0.1681 0.9597 0.2869 0.047 Uiso calc 1 . .
    C C12 -0.13792(16) 1.03784(14) 0.23793(7) 0.0307(4) Uani d 1 . .
    H H12 -0.0686 1.0231 0.2402 0.037 Uiso calc 1 . .
    C C13 -0.03331(13) 0.84098(11) 0.19468(5) 0.0199(3) Uani d 1 . .
    C C14 -0.12566(14) 0.81619(12) 0.20717(6) 0.0227(4) Uani d 1 . .
    C C15 -0.12299(14) 0.79805(13) 0.25087(6) 0.0263(4) Uani d 1 . .
    H H15 -0.1840 0.7824 0.2609 0.032 Uiso calc 1 . .
    C C16 -0.03476(15) 0.80181(13) 0.28062(6) 0.0258(4) Uani d 1 . .
    C C17 0.05601(14) 0.81946(12) 0.26674(6) 0.0240(4) Uani d 1 . .
    H H17 0.1171 0.8184 0.2867 0.029 Uiso calc 1 . .
    C C18 0.05714(13) 0.83903(11) 0.22290(6) 0.0208(3) Uani d 1 . .
    C C19 0.15755(13) 0.84937(12) 0.20853(5) 0.0212(3) Uani d 1 . .
    C C20 0.23197(14) 0.78886(13) 0.22332(6) 0.0252(4) Uani d 1 . .
    H H20 0.2171 0.7417 0.2407 0.030 Uiso calc 1 . .
    C C21 0.32743(15) 0.79833(14) 0.21237(6) 0.0288(4) Uani d 1 . .
    C C22 0.35060(14) 0.87008(14) 0.18910(6) 0.0285(4) Uani d 1 . .
    H H22 0.4176 0.8766 0.1832 0.034 Uiso calc 1 . .
    C C23 0.28013(14) 0.93226(12) 0.17423(6) 0.0242(4) Uani d 1 . .
    C C24 0.18141(13) 0.91769(12) 0.18293(6) 0.0208(3) Uani d 1 . .
    C C25 -0.22374(14) 0.80187(13) 0.17502(6) 0.0259(4) Uani d 1 . .
    C C26 -0.20636(17) 0.72748(15) 0.14487(8) 0.0385(5) Uani d 1 . .
    H H26A -0.2689 0.7156 0.1251 0.058 Uiso calc 1 . .
    H H26B -0.1860 0.6761 0.1622 0.058 Uiso calc 1 . .
    H H26C -0.1530 0.7431 0.1280 0.058 Uiso calc 1 . .
    C C27 -0.25697(16) 0.88192(14) 0.14816(7) 0.0340(5) Uani d 1 . .
    H H27A -0.2625 0.9306 0.1676 0.051 Uiso calc 1 . .
    H H27B -0.3226 0.8712 0.1304 0.051 Uiso calc 1 . .
    H H27C -0.2071 0.8952 0.1292 0.051 Uiso calc 1 . .
    C C28 -0.31157(16) 0.77680(18) 0.19899(7) 0.0414(6) Uani d 1 . .
    H H28A -0.3218 0.8221 0.2198 0.062 Uiso calc 1 . .
    H H28B -0.2957 0.7225 0.2145 0.062 Uiso calc 1 . .
    H H28C -0.3732 0.7698 0.1779 0.062 Uiso calc 1 . .
    C C29 0.03783(16) 0.79999(15) 0.35515(6) 0.0334(5) Uani d 1 . .
    H H29A 0.0934 0.7618 0.3506 0.050 Uiso calc 1 . .
    H H29B 0.0190 0.7890 0.3838 0.050 Uiso calc 1 . .
    H H29C 0.0593 0.8600 0.3534 0.050 Uiso calc 1 . .
    C C30 0.38639(18) 0.67199(17) 0.25083(9) 0.0474(6) Uani d 1 . .
    H H30A 0.3739 0.6951 0.2788 0.071 Uiso calc 1 . .
    H H30B 0.4455 0.6341 0.2555 0.071 Uiso calc 1 . .
    H H30C 0.3273 0.6393 0.2374 0.071 Uiso calc 1 . .
    C C31 0.31189(15) 1.01366(14) 0.15168(7) 0.0305(4) Uani d 1 . .
    C C32 0.26525(17) 1.01554(16) 0.10375(7) 0.0386(5) Uani d 1 . .
    H H32A 0.1917 1.0199 0.1013 0.058 Uiso calc 1 . .
    H H32B 0.2829 0.9626 0.0896 0.058 Uiso calc 1 . .
    H H32C 0.2913 1.0653 0.0896 0.058 Uiso calc 1 . .
    C C33 0.28132(19) 1.09348(15) 0.17499(8) 0.0433(6) Uani d 1 . .
    H H33A 0.3148 1.0929 0.2052 0.065 Uiso calc 1 . .
    H H33B 0.2080 1.0937 0.1743 0.065 Uiso calc 1 . .
    H H33C 0.3016 1.1451 0.1605 0.065 Uiso calc 1 . .
    C C34 0.42695(17) 1.01700(18) 0.15328(9) 0.0468(6) Uani d 1 . .
    H H34A 0.4459 1.0720 0.1414 0.070 Uiso calc 1 . .
    H H34B 0.4484 0.9697 0.1360 0.070 Uiso calc 1 . .
    H H34C 0.4600 1.0114 0.1834 0.070 Uiso calc 1 . .
    C C35 -0.01994(13) 0.74019(11) -0.00710(5) 0.0190(3) Uani d 1 . .
    C C36 -0.10642(13) 0.71434(11) 0.01005(6) 0.0211(3) Uani d 1 . .
    C C37 -0.09665(14) 0.64049(12) 0.03547(6) 0.0242(4) Uani d 1 . .
    H H37 -0.1521 0.6226 0.0490 0.029 Uiso calc 1 . .
    C C38 -0.00846(15) 0.59184(12) 0.04181(6) 0.0234(4) Uani d 1 . .
    C C39 0.07087(14) 0.61313(11) 0.02026(6) 0.0216(3) Uani d 1 . .
    H H39 0.1287 0.5772 0.0224 0.026 Uiso calc 1 . .
    C C40 0.06490(13) 0.68827(11) -0.00473(6) 0.0191(3) Uani d 1 . .
    C C41 0.14602(13) 0.70671(11) -0.03120(6) 0.0195(3) Uani d 1 . .
    C C42 0.17301(14) 0.64030(11) -0.05760(6) 0.0222(3) Uani d 1 . .
    H H42 0.1406 0.5859 -0.0581 0.027 Uiso calc 1 . .
    C C43 0.24729(14) 0.65520(12) -0.08274(6) 0.0243(4) Uani d 1 . .
    C C44 0.29977(14) 0.73246(12) -0.07929(6) 0.0243(4) Uani d 1 . .
    H H44 0.3529 0.7402 -0.0959 0.029 Uiso calc 1 . .
    C C45 0.27748(13) 0.79902(11) -0.05244(6) 0.0202(3) Uani d 1 . .
    C C46 0.19454(13) 0.78558(11) -0.03043(5) 0.0186(3) Uani d 1 . .
    C C47 -0.20971(14) 0.75849(13) -0.00268(6) 0.0255(4) Uani d 1 . .
    C C48 -0.23840(16) 0.75233(15) -0.05224(7) 0.0329(4) Uani d 1 . .
    H H48A -0.3043 0.7795 -0.0611 0.049 Uiso calc 1 . .
    H H48B -0.2418 0.6917 -0.0610 0.049 Uiso calc 1 . .
    H H48C -0.1874 0.7819 -0.0663 0.049 Uiso calc 1 . .
    C C49 -0.20901(16) 0.85279(14) 0.01137(8) 0.0351(5) Uani d 1 . .
    H H49A -0.1854 0.8568 0.0426 0.053 Uiso calc 1 . .
    H H49B -0.2774 0.8763 0.0048 0.053 Uiso calc 1 . .
    H H49C -0.1638 0.8856 -0.0044 0.053 Uiso calc 1 . .
    C C50 -0.29270(16) 0.71236(17) 0.01750(8) 0.0392(5) Uani d 1 . .
    H H50A -0.2764 0.7144 0.0492 0.059 Uiso calc 1 . .
    H H50B -0.2971 0.6523 0.0079 0.059 Uiso calc 1 . .
    H H50C -0.3575 0.7410 0.0083 0.059 Uiso calc 1 . .
    C C51 0.07793(17) 0.46875(13) 0.07478(7) 0.0328(4) Uani d 1 . .
    H H51A 0.0858 0.4419 0.0470 0.049 Uiso calc 1 . .
    H H51B 0.0699 0.4239 0.0961 0.049 Uiso calc 1 . .
    H H51C 0.1379 0.5033 0.0852 0.049 Uiso calc 1 . .
    C C52 0.22870(18) 0.51538(14) -0.11391(8) 0.0390(5) Uani d 1 . .
    H H52A 0.2455 0.4870 -0.0857 0.059 Uiso calc 1 . .
    H H52B 0.2532 0.4804 -0.1363 0.059 Uiso calc 1 . .
    H H52C 0.1553 0.5219 -0.1209 0.059 Uiso calc 1 . .
    C C53 0.34312(14) 0.88047(12) -0.04674(6) 0.0244(4) Uani d 1 . .
    C C54 0.43790(16) 0.87090(14) -0.06847(8) 0.0349(5) Uani d 1 . .
    H H54A 0.4765 0.8206 -0.0565 0.052 Uiso calc 1 . .
    H H54B 0.4797 0.9226 -0.0630 0.052 Uiso calc 1 . .
    H H54C 0.4180 0.8634 -0.0998 0.052 Uiso calc 1 . .
    C C55 0.28377(16) 0.95709(13) -0.06802(8) 0.0367(5) Uani d 1 . .
    H H55A 0.2640 0.9457 -0.0991 0.055 Uiso calc 1 . .
    H H55B 0.3260 1.0088 -0.0642 0.055 Uiso calc 1 . .
    H H55C 0.2232 0.9659 -0.0545 0.055 Uiso calc 1 . .
    C C56 0.37997(18) 0.89737(17) 0.00145(7) 0.0413(5) Uani d 1 . .
    H H56A 0.3218 0.9059 0.0166 0.062 Uiso calc 1 . .
    H H56B 0.4223 0.9490 0.0046 0.062 Uiso calc 1 . .
    H H56C 0.4194 0.8480 0.0141 0.062 Uiso calc 1 . .
    C C57 0.10115(15) 0.83262(12) 0.08053(6) 0.0259(4) Uani d 1 . .
    C C58 0.43179(16) 0.65168(12) 0.08541(7) 0.0611(8) Uani d 1 . .
    C C59 0.50365(15) 0.59332(16) 0.10454(7) 0.0776(11) Uani d 1 . .
    H H59 0.5499 0.6096 0.1294 0.093 Uiso calc 1 . .
    C C60 0.50780(16) 0.51116(14) 0.08730(9) 0.0863(12) Uani d 1 . .
    H H60 0.5569 0.4713 0.1004 0.104 Uiso calc 1 . .
    C C61 0.4401(2) 0.48734(13) 0.05094(10) 0.0995(14) Uani d 1 . .
    H H61 0.4429 0.4312 0.0392 0.119 Uiso calc 1 . .
    C C62 0.3682(2) 0.54570(17) 0.03182(8) 0.1091(16) Uani d 1 . .
    H H62 0.3219 0.5294 0.0070 0.131 Uiso calc 1 . .
    C C63 0.36407(16) 0.62787(15) 0.04905(7) 0.0756(10) Uani d 1 . .
    H H63 0.3150 0.6678 0.0360 0.091 Uiso calc 1 . .
    C C64 0.4267(3) 0.7386(3) 0.10370(13) 0.0878(11) Uani d 1 . .
    H H64A 0.4834 0.7730 0.0968 0.132 Uiso calc 1 . .
    H H64B 0.4302 0.7346 0.1353 0.132 Uiso calc 1 . .
    H H64C 0.3630 0.7659 0.0912 0.132 Uiso calc 1 . .
    C C65 0.21479(11) 0.53242(11) 0.17671(5) 0.0518(7) Uani d 1 . .
    C C66 0.17226(11) 0.60699(10) 0.15723(5) 0.0410(5) Uani d 1 . .
    H H66 0.2077 0.6395 0.1386 0.049 Uiso calc 1 . .
    C C67 0.07787(11) 0.63405(9) 0.16505(5) 0.0401(5) Uani d 1 . .
    H H67 0.0488 0.6850 0.1517 0.048 Uiso calc 1 . .
    C C68 0.02601(10) 0.58654(12) 0.19234(6) 0.0534(7) Uani d 1 . .
    H H68 -0.0385 0.6050 0.1977 0.064 Uiso calc 1 . .
    C C69 0.06854(13) 0.51197(11) 0.21182(6) 0.0584(7) Uani d 1 . .
    H H69 0.0331 0.4795 0.2305 0.070 Uiso calc 1 . .
    C C70 0.16293(14) 0.48491(9) 0.20400(5) 0.0539(7) Uani d 1 . .
    H H70 0.1920 0.4339 0.2173 0.065 Uiso calc 1 . .
    C C71 0.3155(3) 0.5033(3) 0.16757(13) 0.1101(18) Uani d 1 . .
    H H71A 0.3065 0.4573 0.1458 0.165 Uiso calc 1 . .
    H H71B 0.3554 0.4818 0.1944 0.165 Uiso calc 1 . .
    H H71C 0.3507 0.5518 0.1565 0.165 Uiso calc 1 . .
    O O1 -0.07102(9) 1.01463(8) 0.14786(4) 0.0223(3) Uani d 1 . .
    O O2 -0.02939(9) 0.85920(8) 0.15060(4) 0.0199(2) Uani d 1 . .
    O O3 0.10367(9) 0.97617(8) 0.16894(4) 0.0214(3) Uani d 1 . .
    O O4 -0.04594(11) 0.78438(11) 0.32282(4) 0.0363(4) Uani d 1 . .
    O O5 0.40458(11) 0.74111(11) 0.22297(5) 0.0396(4) Uani d 1 . .
    O O6 -0.01933(9) 0.81766(7) -0.02991(4) 0.0185(2) Uani d 1 . .
    O O7 0.16567(9) 0.84936(8) -0.00312(4) 0.0191(2) Uani d 1 . .
    O O8 0.04755(9) 0.96021(8) -0.04265(4) 0.0205(2) Uani d 1 . .
    O O9 -0.00905(11) 0.52279(9) 0.06893(4) 0.0284(3) Uani d 1 . .
    O O10 0.27510(11) 0.59780(9) -0.11224(5) 0.0327(3) Uani d 1 . .
    O O11 0.14861(13) 0.77373(10) 0.09226(5) 0.0397(4) Uani d 1 . .
    P P1 0.00872(3) 0.94829(3) 0.13333(2) 0.01749(9) Uani d 1 . .
    P P2 0.05519(3) 0.89371(3) -0.00705(2) 0.01635(9) Uani d 1 . .
    Rh Rh1 0.03018(2) 0.92806(2) 0.06248(2) 0.01662(4) Uani d 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 C2 . 1.381(3) ?
    C1 C6 . 1.392(3) ?
    C1 O1 . 1.400(2) ?
    C2 C3 . 1.383(3) ?
    C2 H2 . 0.9500 ?
    C3 C4 . 1.382(3) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.383(3) ?
    C4 H4 . 0.9500 ?
    C5 C6 . 1.396(3) ?
    C5 H5 . 0.9500 ?
    C6 C7 . 1.483(3) ?
    C7 C12 . 1.392(3) ?
    C7 C8 . 1.395(3) ?
    C8 C9 . 1.386(3) ?
    C8 H8 . 0.9500 ?
    C9 C10 . 1.370(4) ?
    C9 H9 . 0.9500 ?
    C10 C11 . 1.389(3) ?
    C10 H10 . 0.9500 ?
    C11 C12 . 1.389(3) ?
    C11 H11 . 0.9500 ?
    C12 H12 . 0.9500 ?
    C13 C18 . 1.386(3) ?
    C13 C14 . 1.407(2) ?
    C13 O2 . 1.411(2) ?
    C14 C15 . 1.386(3) ?
    C14 C25 . 1.543(3) ?
    C15 C16 . 1.389(3) ?
    C15 H15 . 0.9500 ?
    C16 O4 . 1.373(2) ?
    C16 C17 . 1.380(3) ?
    C17 C18 . 1.402(2) ?
    C17 H17 . 0.9500 ?
    C18 C19 . 1.491(2) ?
    C19 C24 . 1.395(2) ?
    C19 C20 . 1.398(3) ?
    C20 C21 . 1.382(3) ?
    C20 H20 . 0.9500 ?
    C21 O5 . 1.366(2) ?
    C21 C22 . 1.391(3) ?
    C22 C23 . 1.382(3) ?
    C22 H22 . 0.9500 ?
    C23 C24 . 1.409(2) ?
    C23 C31 . 1.539(3) ?
    C24 O3 . 1.402(2) ?
    C25 C27 . 1.528(3) ?
    C25 C26 . 1.530(3) ?
    C25 C28 . 1.538(3) ?
    C26 H26A . 0.9800 ?
    C26 H26B . 0.9800 ?
    C26 H26C . 0.9800 ?
    C27 H27A . 0.9800 ?
    C27 H27B . 0.9800 ?
    C27 H27C . 0.9800 ?
    C28 H28A . 0.9800 ?
    C28 H28B . 0.9800 ?
    C28 H28C . 0.9800 ?
    C29 O4 . 1.411(2) ?
    C29 H29A . 0.9800 ?
    C29 H29B . 0.9800 ?
    C29 H29C . 0.9800 ?
    C30 O5 . 1.425(3) ?
    C30 H30A . 0.9800 ?
    C30 H30B . 0.9800 ?
    C30 H30C . 0.9800 ?
    C31 C33 . 1.525(3) ?
    C31 C32 . 1.529(3) ?
    C31 C34 . 1.537(3) ?
    C32 H32A . 0.9800 ?
    C32 H32B . 0.9800 ?
    C32 H32C . 0.9800 ?
    C33 H33A . 0.9800 ?
    C33 H33B . 0.9800 ?
    C33 H33C . 0.9800 ?
    C34 H34A . 0.9800 ?
    C34 H34B . 0.9800 ?
    C34 H34C . 0.9800 ?
    C35 C40 . 1.388(2) ?
    C35 O6 . 1.399(2) ?
    C35 C36 . 1.407(2) ?
    C36 C37 . 1.390(3) ?
    C36 C47 . 1.543(3) ?
    C37 C38 . 1.392(3) ?
    C37 H37 . 0.9500 ?
    C38 O9 . 1.367(2) ?
    C38 C39 . 1.382(2) ?
    C39 C40 . 1.399(2) ?
    C39 H39 . 0.9500 ?
    C40 C41 . 1.489(2) ?
    C41 C46 . 1.387(2) ?
    C41 C42 . 1.401(2) ?
    C42 C43 . 1.377(2) ?
    C42 H42 . 0.9500 ?
    C43 O10 . 1.373(2) ?
    C43 C44 . 1.388(3) ?
    C44 C45 . 1.391(2) ?
    C44 H44 . 0.9500 ?
    C45 C46 . 1.408(2) ?
    C45 C53 . 1.537(2) ?
    C46 O7 . 1.399(2) ?
    C47 C49 . 1.529(3) ?
    C47 C48 . 1.536(3) ?
    C47 C50 . 1.537(3) ?
    C48 H48A . 0.9800 ?
    C48 H48B . 0.9800 ?
    C48 H48C . 0.9800 ?
    C49 H49A . 0.9800 ?
    C49 H49B . 0.9800 ?
    C49 H49C . 0.9800 ?
    C50 H50A . 0.9800 ?
    C50 H50B . 0.9800 ?
    C50 H50C . 0.9800 ?
    C51 O9 . 1.427(3) ?
    C51 H51A . 0.9800 ?
    C51 H51B . 0.9800 ?
    C51 H51C . 0.9800 ?
    C52 O10 . 1.422(2) ?
    C52 H52A . 0.9800 ?
    C52 H52B . 0.9800 ?
    C52 H52C . 0.9800 ?
    C53 C55 . 1.527(3) ?
    C53 C56 . 1.531(3) ?
    C53 C54 . 1.535(3) ?
    C54 H54A . 0.9800 ?
    C54 H54B . 0.9800 ?
    C54 H54C . 0.9800 ?
    C55 H55A . 0.9800 ?
    C55 H55B . 0.9800 ?
    C55 H55C . 0.9800 ?
    C56 H56A . 0.9800 ?
    C56 H56B . 0.9800 ?
    C56 H56C . 0.9800 ?
    C57 O11 . 1.143(2) ?
    C57 Rh1 . 1.8057(19) ?
    C58 C59 . 1.3900 ?
    C58 C63 . 1.3900 ?
    C58 C64 . 1.472(4) ?
    C59 C60 . 1.3900 ?
    C59 H59 . 0.9500 ?
    C60 C61 . 1.3900 ?
    C60 H60 . 0.9500 ?
    C61 C62 . 1.3900 ?
    C61 H61 . 0.9500 ?
    C62 C63 . 1.3900 ?
    C62 H62 . 0.9500 ?
    C63 H63 . 0.9500 ?
    C64 H64A . 0.9800 ?
    C64 H64B . 0.9800 ?
    C64 H64C . 0.9800 ?
    C65 C66 . 1.3900 ?
    C65 C70 . 1.3900 ?
    C65 C71 . 1.492(3) ?
    C66 C67 . 1.3900 ?
    C66 H66 . 0.9500 ?
    C67 C68 . 1.3900 ?
    C67 H67 . 0.9500 ?
    C68 C69 . 1.3900 ?
    C68 H68 . 0.9500 ?
    C69 C70 . 1.3900 ?
    C69 H69 . 0.9500 ?
    C70 H70 . 0.9500 ?
    C71 H71A . 0.9800 ?
    C71 H71B . 0.9800 ?
    C71 H71C . 0.9800 ?
    O1 P1 . 1.5999(13) ?
    O2 P1 . 1.5976(12) ?
    O3 P1 . 1.6157(13) ?
    O6 P2 . 1.6393(13) ?
    O7 P2 . 1.6217(12) ?
    O8 P2 . 1.5081(12) ?
    O8 Rh1 3_575 2.0710(12) ?
    P1 Rh1 . 2.2906(4) ?
    P2 Rh1 . 2.3049(4) ?
    Rh1 O8 3_575 2.0711(12) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C2 C1 C6 . . 122.00(17) ?
    C2 C1 O1 . . 121.74(16) ?
    C6 C1 O1 . . 116.20(16) ?
    C1 C2 C3 . . 119.42(18) ?
    C1 C2 H2 . . 120.3 ?
    C3 C2 H2 . . 120.3 ?
    C4 C3 C2 . . 120.3(2) ?
    C4 C3 H3 . . 119.9 ?
    C2 C3 H3 . . 119.9 ?
    C3 C4 C5 . . 119.4(2) ?
    C3 C4 H4 . . 120.3 ?
    C5 C4 H4 . . 120.3 ?
    C4 C5 C6 . . 121.78(19) ?
    C4 C5 H5 . . 119.1 ?
    C6 C5 H5 . . 119.1 ?
    C1 C6 C5 . . 117.08(18) ?
    C1 C6 C7 . . 123.20(17) ?
    C5 C6 C7 . . 119.70(17) ?
    C12 C7 C8 . . 118.9(2) ?
    C12 C7 C6 . . 121.40(17) ?
    C8 C7 C6 . . 119.61(19) ?
    C9 C8 C7 . . 120.2(2) ?
    C9 C8 H8 . . 119.9 ?
    C7 C8 H8 . . 119.9 ?
    C10 C9 C8 . . 120.6(2) ?
    C10 C9 H9 . . 119.7 ?
    C8 C9 H9 . . 119.7 ?
    C9 C10 C11 . . 120.1(2) ?
    C9 C10 H10 . . 120.0 ?
    C11 C10 H10 . . 120.0 ?
    C10 C11 C12 . . 119.7(2) ?
    C10 C11 H11 . . 120.1 ?
    C12 C11 H11 . . 120.1 ?
    C11 C12 C7 . . 120.5(2) ?
    C11 C12 H12 . . 119.7 ?
    C7 C12 H12 . . 119.7 ?
    C18 C13 C14 . . 122.73(16) ?
    C18 C13 O2 . . 117.61(15) ?
    C14 C13 O2 . . 119.25(15) ?
    C15 C14 C13 . . 115.79(17) ?
    C15 C14 C25 . . 120.03(16) ?
    C13 C14 C25 . . 123.99(16) ?
    C14 C15 C16 . . 122.64(17) ?
    C14 C15 H15 . . 118.7 ?
    C16 C15 H15 . . 118.7 ?
    O4 C16 C17 . . 124.70(17) ?
    O4 C16 C15 . . 115.14(16) ?
    C17 C16 C15 . . 120.13(17) ?
    C16 C17 C18 . . 119.28(17) ?
    C16 C17 H17 . . 120.4 ?
    C18 C17 H17 . . 120.4 ?
    C13 C18 C17 . . 119.01(16) ?
    C13 C18 C19 . . 123.40(15) ?
    C17 C18 C19 . . 117.38(16) ?
    C24 C19 C20 . . 119.12(16) ?
    C24 C19 C18 . . 123.38(16) ?
    C20 C19 C18 . . 117.44(16) ?
    C21 C20 C19 . . 119.26(18) ?
    C21 C20 H20 . . 120.4 ?
    C19 C20 H20 . . 120.4 ?
    O5 C21 C20 . . 124.53(19) ?
    O5 C21 C22 . . 115.29(18) ?
    C20 C21 C22 . . 120.19(18) ?
    C23 C22 C21 . . 122.70(17) ?
    C23 C22 H22 . . 118.7 ?
    C21 C22 H22 . . 118.7 ?
    C22 C23 C24 . . 115.96(17) ?
    C22 C23 C31 . . 120.39(17) ?
    C24 C23 C31 . . 123.59(17) ?
    C19 C24 O3 . . 116.57(15) ?
    C19 C24 C23 . . 122.43(17) ?
    O3 C24 C23 . . 120.80(16) ?
    C27 C25 C26 . . 109.77(17) ?
    C27 C25 C28 . . 106.94(17) ?
    C26 C25 C28 . . 107.82(18) ?
    C27 C25 C14 . . 112.75(16) ?
    C26 C25 C14 . . 108.25(16) ?
    C28 C25 C14 . . 111.19(16) ?
    C25 C26 H26A . . 109.5 ?
    C25 C26 H26B . . 109.5 ?
    H26A C26 H26B . . 109.5 ?
    C25 C26 H26C . . 109.5 ?
    H26A C26 H26C . . 109.5 ?
    H26B C26 H26C . . 109.5 ?
    C25 C27 H27A . . 109.5 ?
    C25 C27 H27B . . 109.5 ?
    H27A C27 H27B . . 109.5 ?
    C25 C27 H27C . . 109.5 ?
    H27A C27 H27C . . 109.5 ?
    H27B C27 H27C . . 109.5 ?
    C25 C28 H28A . . 109.5 ?
    C25 C28 H28B . . 109.5 ?
    H28A C28 H28B . . 109.5 ?
    C25 C28 H28C . . 109.5 ?
    H28A C28 H28C . . 109.5 ?
    H28B C28 H28C . . 109.5 ?
    O4 C29 H29A . . 109.5 ?
    O4 C29 H29B . . 109.5 ?
    H29A C29 H29B . . 109.5 ?
    O4 C29 H29C . . 109.5 ?
    H29A C29 H29C . . 109.5 ?
    H29B C29 H29C . . 109.5 ?
    O5 C30 H30A . . 109.5 ?
    O5 C30 H30B . . 109.5 ?
    H30A C30 H30B . . 109.5 ?
    O5 C30 H30C . . 109.5 ?
    H30A C30 H30C . . 109.5 ?
    H30B C30 H30C . . 109.5 ?
    C33 C31 C32 . . 110.5(2) ?
    C33 C31 C34 . . 107.35(19) ?
    C32 C31 C34 . . 106.89(17) ?
    C33 C31 C23 . . 109.79(17) ?
    C32 C31 C23 . . 111.18(17) ?
    C34 C31 C23 . . 111.05(18) ?
    C31 C32 H32A . . 109.5 ?
    C31 C32 H32B . . 109.5 ?
    H32A C32 H32B . . 109.5 ?
    C31 C32 H32C . . 109.5 ?
    H32A C32 H32C . . 109.5 ?
    H32B C32 H32C . . 109.5 ?
    C31 C33 H33A . . 109.5 ?
    C31 C33 H33B . . 109.5 ?
    H33A C33 H33B . . 109.5 ?
    C31 C33 H33C . . 109.5 ?
    H33A C33 H33C . . 109.5 ?
    H33B C33 H33C . . 109.5 ?
    C31 C34 H34A . . 109.5 ?
    C31 C34 H34B . . 109.5 ?
    H34A C34 H34B . . 109.5 ?
    C31 C34 H34C . . 109.5 ?
    H34A C34 H34C . . 109.5 ?
    H34B C34 H34C . . 109.5 ?
    C40 C35 O6 . . 117.37(15) ?
    C40 C35 C36 . . 122.00(16) ?
    O6 C35 C36 . . 120.50(15) ?
    C37 C36 C35 . . 116.15(16) ?
    C37 C36 C47 . . 121.14(16) ?
    C35 C36 C47 . . 122.34(16) ?
    C36 C37 C38 . . 122.28(17) ?
    C36 C37 H37 . . 118.9 ?
    C38 C37 H37 . . 118.9 ?
    O9 C38 C39 . . 124.45(17) ?
    O9 C38 C37 . . 115.45(16) ?
    C39 C38 C37 . . 120.06(17) ?
    C38 C39 C40 . . 119.16(17) ?
    C38 C39 H39 . . 120.4 ?
    C40 C39 H39 . . 120.4 ?
    C35 C40 C39 . . 119.49(16) ?
    C35 C40 C41 . . 121.36(15) ?
    C39 C40 C41 . . 118.95(15) ?
    C46 C41 C42 . . 119.95(15) ?
    C46 C41 C40 . . 122.74(15) ?
    C42 C41 C40 . . 117.31(16) ?
    C43 C42 C41 . . 118.93(17) ?
    C43 C42 H42 . . 120.5 ?
    C41 C42 H42 . . 120.5 ?
    O10 C43 C42 . . 124.42(17) ?
    O10 C43 C44 . . 115.35(16) ?
    C42 C43 C44 . . 120.23(17) ?
    C43 C44 C45 . . 122.50(16) ?
    C43 C44 H44 . . 118.7 ?
    C45 C44 H44 . . 118.7 ?
    C44 C45 C46 . . 116.12(16) ?
    C44 C45 C53 . . 120.70(15) ?
    C46 C45 C53 . . 123.15(15) ?
    C41 C46 O7 . . 117.70(14) ?
    C41 C46 C45 . . 121.73(15) ?
    O7 C46 C45 . . 120.21(15) ?
    C49 C47 C48 . . 109.71(17) ?
    C49 C47 C50 . . 107.67(17) ?
    C48 C47 C50 . . 107.21(17) ?
    C49 C47 C36 . . 112.74(16) ?
    C48 C47 C36 . . 107.97(15) ?
    C50 C47 C36 . . 111.41(16) ?
    C47 C48 H48A . . 109.5 ?
    C47 C48 H48B . . 109.5 ?
    H48A C48 H48B . . 109.5 ?
    C47 C48 H48C . . 109.5 ?
    H48A C48 H48C . . 109.5 ?
    H48B C48 H48C . . 109.5 ?
    C47 C49 H49A . . 109.5 ?
    C47 C49 H49B . . 109.5 ?
    H49A C49 H49B . . 109.5 ?
    C47 C49 H49C . . 109.5 ?
    H49A C49 H49C . . 109.5 ?
    H49B C49 H49C . . 109.5 ?
    C47 C50 H50A . . 109.5 ?
    C47 C50 H50B . . 109.5 ?
    H50A C50 H50B . . 109.5 ?
    C47 C50 H50C . . 109.5 ?
    H50A C50 H50C . . 109.5 ?
    H50B C50 H50C . . 109.5 ?
    O9 C51 H51A . . 109.5 ?
    O9 C51 H51B . . 109.5 ?
    H51A C51 H51B . . 109.5 ?
    O9 C51 H51C . . 109.5 ?
    H51A C51 H51C . . 109.5 ?
    H51B C51 H51C . . 109.5 ?
    O10 C52 H52A . . 109.5 ?
    O10 C52 H52B . . 109.5 ?
    H52A C52 H52B . . 109.5 ?
    O10 C52 H52C . . 109.5 ?
    H52A C52 H52C . . 109.5 ?
    H52B C52 H52C . . 109.5 ?
    C55 C53 C56 . . 111.18(18) ?
    C55 C53 C54 . . 107.22(16) ?
    C56 C53 C54 . . 106.48(17) ?
    C55 C53 C45 . . 109.93(16) ?
    C56 C53 C45 . . 110.40(16) ?
    C54 C53 C45 . . 111.55(15) ?
    C53 C54 H54A . . 109.5 ?
    C53 C54 H54B . . 109.5 ?
    H54A C54 H54B . . 109.5 ?
    C53 C54 H54C . . 109.5 ?
    H54A C54 H54C . . 109.5 ?
    H54B C54 H54C . . 109.5 ?
    C53 C55 H55A . . 109.5 ?
    C53 C55 H55B . . 109.5 ?
    H55A C55 H55B . . 109.5 ?
    C53 C55 H55C . . 109.5 ?
    H55A C55 H55C . . 109.5 ?
    H55B C55 H55C . . 109.5 ?
    C53 C56 H56A . . 109.5 ?
    C53 C56 H56B . . 109.5 ?
    H56A C56 H56B . . 109.5 ?
    C53 C56 H56C . . 109.5 ?
    H56A C56 H56C . . 109.5 ?
    H56B C56 H56C . . 109.5 ?
    O11 C57 Rh1 . . 177.9(2) ?
    C59 C58 C63 . . 120.0 ?
    C59 C58 C64 . . 120.2(2) ?
    C63 C58 C64 . . 119.8(2) ?
    C60 C59 C58 . . 120.0 ?
    C60 C59 H59 . . 120.0 ?
    C58 C59 H59 . . 120.0 ?
    C59 C60 C61 . . 120.0 ?
    C59 C60 H60 . . 120.0 ?
    C61 C60 H60 . . 120.0 ?
    C62 C61 C60 . . 120.0 ?
    C62 C61 H61 . . 120.0 ?
    C60 C61 H61 . . 120.0 ?
    C61 C62 C63 . . 120.0 ?
    C61 C62 H62 . . 120.0 ?
    C63 C62 H62 . . 120.0 ?
    C62 C63 C58 . . 120.0 ?
    C62 C63 H63 . . 120.0 ?
    C58 C63 H63 . . 120.0 ?
    C58 C64 H64A . . 109.5 ?
    C58 C64 H64B . . 109.5 ?
    H64A C64 H64B . . 109.5 ?
    C58 C64 H64C . . 109.5 ?
    H64A C64 H64C . . 109.5 ?
    H64B C64 H64C . . 109.5 ?
    C66 C65 C70 . . 120.0 ?
    C66 C65 C71 . . 119.52(19) ?
    C70 C65 C71 . . 120.47(19) ?
    C65 C66 C67 . . 120.0 ?
    C65 C66 H66 . . 120.0 ?
    C67 C66 H66 . . 120.0 ?
    C68 C67 C66 . . 120.0 ?
    C68 C67 H67 . . 120.0 ?
    C66 C67 H67 . . 120.0 ?
    C69 C68 C67 . . 120.0 ?
    C69 C68 H68 . . 120.0 ?
    C67 C68 H68 . . 120.0 ?
    C68 C69 C70 . . 120.0 ?
    C68 C69 H69 . . 120.0 ?
    C70 C69 H69 . . 120.0 ?
    C69 C70 C65 . . 120.0 ?
    C69 C70 H70 . . 120.0 ?
    C65 C70 H70 . . 120.0 ?
    C65 C71 H71A . . 109.5 ?
    C65 C71 H71B . . 109.5 ?
    H71A C71 H71B . . 109.5 ?
    C65 C71 H71C . . 109.5 ?
    H71A C71 H71C . . 109.5 ?
    H71B C71 H71C . . 109.5 ?
    C1 O1 P1 . . 126.22(11) ?
    C13 O2 P1 . . 124.26(11) ?
    C24 O3 P1 . . 120.71(11) ?
    C16 O4 C29 . . 117.31(15) ?
    C21 O5 C30 . . 116.40(17) ?
    C35 O6 P2 . . 116.77(10) ?
    C46 O7 P2 . . 126.12(11) ?
    P2 O8 Rh1 . 3_575 140.28(7) ?
    C38 O9 C51 . . 117.38(15) ?
    C43 O10 C52 . . 116.63(15) ?
    O2 P1 O1 . . 101.63(7) ?
    O2 P1 O3 . . 105.08(7) ?
    O1 P1 O3 . . 97.10(7) ?
    O2 P1 Rh1 . . 107.40(5) ?
    O1 P1 Rh1 . . 123.27(5) ?
    O3 P1 Rh1 . . 119.82(5) ?
    O8 P2 O7 . . 107.83(7) ?
    O8 P2 O6 . . 101.89(7) ?
    O7 P2 O6 . . 102.46(6) ?
    O8 P2 Rh1 . . 121.95(5) ?
    O7 P2 Rh1 . . 106.81(5) ?
    O6 P2 Rh1 . . 114.16(5) ?
    C57 Rh1 O8 . 3_575 178.25(7) ?
    C57 Rh1 P1 . . 87.14(6) ?
    O8 Rh1 P1 3_575 . 92.36(3) ?
    C57 Rh1 P2 . . 87.55(6) ?
    O8 Rh1 P2 3_575 . 93.00(3) ?
    P1 Rh1 P2 . . 174.350(16) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C6 C1 C2 C3 . . . . 0.0(3) ?
    O1 C1 C2 C3 . . . . 177.22(18) ?
    C1 C2 C3 C4 . . . . -0.9(3) ?
    C2 C3 C4 C5 . . . . 0.6(3) ?
    C3 C4 C5 C6 . . . . 0.6(4) ?
    C2 C1 C6 C5 . . . . 1.1(3) ?
    O1 C1 C6 C5 . . . . -176.24(17) ?
    C2 C1 C6 C7 . . . . -177.06(18) ?
    O1 C1 C6 C7 . . . . 5.6(3) ?
    C4 C5 C6 C1 . . . . -1.4(3) ?
    C4 C5 C6 C7 . . . . 176.8(2) ?
    C1 C6 C7 C12 . . . . 59.9(3) ?
    C5 C6 C7 C12 . . . . -118.2(2) ?
    C1 C6 C7 C8 . . . . -124.3(2) ?
    C5 C6 C7 C8 . . . . 57.5(3) ?
    C12 C7 C8 C9 . . . . 0.4(3) ?
    C6 C7 C8 C9 . . . . -175.45(19) ?
    C7 C8 C9 C10 . . . . 0.3(3) ?
    C8 C9 C10 C11 . . . . -0.4(4) ?
    C9 C10 C11 C12 . . . . -0.4(3) ?
    C10 C11 C12 C7 . . . . 1.1(3) ?
    C8 C7 C12 C11 . . . . -1.2(3) ?
    C6 C7 C12 C11 . . . . 174.64(19) ?
    C18 C13 C14 C15 . . . . 6.5(3) ?
    O2 C13 C14 C15 . . . . 178.99(16) ?
    C18 C13 C14 C25 . . . . -168.51(17) ?
    O2 C13 C14 C25 . . . . 3.9(3) ?
    C13 C14 C15 C16 . . . . -1.5(3) ?
    C25 C14 C15 C16 . . . . 173.73(18) ?
    C14 C15 C16 O4 . . . . 178.17(18) ?
    C14 C15 C16 C17 . . . . -3.7(3) ?
    O4 C16 C17 C18 . . . . -177.94(18) ?
    C15 C16 C17 C18 . . . . 4.1(3) ?
    C14 C13 C18 C17 . . . . -6.2(3) ?
    O2 C13 C18 C17 . . . . -178.77(16) ?
    C14 C13 C18 C19 . . . . 168.40(17) ?
    O2 C13 C18 C19 . . . . -4.2(3) ?
    C16 C17 C18 C13 . . . . 0.6(3) ?
    C16 C17 C18 C19 . . . . -174.28(17) ?
    C13 C18 C19 C24 . . . . 52.2(3) ?
    C17 C18 C19 C24 . . . . -133.16(19) ?
    C13 C18 C19 C20 . . . . -130.61(19) ?
    C17 C18 C19 C20 . . . . 44.1(2) ?
    C24 C19 C20 C21 . . . . 0.3(3) ?
    C18 C19 C20 C21 . . . . -177.09(17) ?
    C19 C20 C21 O5 . . . . -176.43(18) ?
    C19 C20 C21 C22 . . . . 3.8(3) ?
    O5 C21 C22 C23 . . . . 177.17(18) ?
    C20 C21 C22 C23 . . . . -3.0(3) ?
    C21 C22 C23 C24 . . . . -1.8(3) ?
    C21 C22 C23 C31 . . . . 175.35(18) ?
    C20 C19 C24 O3 . . . . 179.79(15) ?
    C18 C19 C24 O3 . . . . -3.0(2) ?
    C20 C19 C24 C23 . . . . -5.4(3) ?
    C18 C19 C24 C23 . . . . 171.83(17) ?
    C22 C23 C24 C19 . . . . 6.0(3) ?
    C31 C23 C24 C19 . . . . -171.03(17) ?
    C22 C23 C24 O3 . . . . -179.34(16) ?
    C31 C23 C24 O3 . . . . 3.6(3) ?
    C15 C14 C25 C27 . . . . 126.3(2) ?
    C13 C14 C25 C27 . . . . -58.9(2) ?
    C15 C14 C25 C26 . . . . -112.1(2) ?
    C13 C14 C25 C26 . . . . 62.7(2) ?
    C15 C14 C25 C28 . . . . 6.2(3) ?
    C13 C14 C25 C28 . . . . -178.99(19) ?
    C22 C23 C31 C33 . . . . -124.4(2) ?
    C24 C23 C31 C33 . . . . 52.6(3) ?
    C22 C23 C31 C32 . . . . 113.1(2) ?
    C24 C23 C31 C32 . . . . -70.0(2) ?
    C22 C23 C31 C34 . . . . -5.8(3) ?
    C24 C23 C31 C34 . . . . 171.14(19) ?
    C40 C35 C36 C37 . . . . 9.9(3) ?
    O6 C35 C36 C37 . . . . -174.39(15) ?
    C40 C35 C36 C47 . . . . -163.16(17) ?
    O6 C35 C36 C47 . . . . 12.5(3) ?
    C35 C36 C37 C38 . . . . -3.4(3) ?
    C47 C36 C37 C38 . . . . 169.73(17) ?
    C36 C37 C38 O9 . . . . 177.68(16) ?
    C36 C37 C38 C39 . . . . -4.3(3) ?
    O9 C38 C39 C40 . . . . -176.40(16) ?
    C37 C38 C39 C40 . . . . 5.8(3) ?
    O6 C35 C40 C39 . . . . 175.53(15) ?
    C36 C35 C40 C39 . . . . -8.6(3) ?
    O6 C35 C40 C41 . . . . -9.8(2) ?
    C36 C35 C40 C41 . . . . 166.06(16) ?
    C38 C39 C40 C35 . . . . 0.5(3) ?
    C38 C39 C40 C41 . . . . -174.31(16) ?
    C35 C40 C41 C46 . . . . 54.6(2) ?
    C39 C40 C41 C46 . . . . -130.68(18) ?
    C35 C40 C41 C42 . . . . -125.56(18) ?
    C39 C40 C41 C42 . . . . 49.2(2) ?
    C46 C41 C42 C43 . . . . -0.6(3) ?
    C40 C41 C42 C43 . . . . 179.59(17) ?
    C41 C42 C43 O10 . . . . -174.92(18) ?
    C41 C42 C43 C44 . . . . 5.0(3) ?
    O10 C43 C44 C45 . . . . 176.86(17) ?
    C42 C43 C44 C45 . . . . -3.1(3) ?
    C43 C44 C45 C46 . . . . -3.3(3) ?
    C43 C44 C45 C53 . . . . 174.90(18) ?
    C42 C41 C46 O7 . . . . -179.21(15) ?
    C40 C41 C46 O7 . . . . 0.6(2) ?
    C42 C41 C46 C45 . . . . -6.1(3) ?
    C40 C41 C46 C45 . . . . 173.78(16) ?
    C44 C45 C46 C41 . . . . 7.8(3) ?
    C53 C45 C46 C41 . . . . -170.31(17) ?
    C44 C45 C46 O7 . . . . -179.22(15) ?
    C53 C45 C46 O7 . . . . 2.7(3) ?
    C37 C36 C47 C49 . . . . 123.2(2) ?
    C35 C36 C47 C49 . . . . -64.0(2) ?
    C37 C36 C47 C48 . . . . -115.40(19) ?
    C35 C36 C47 C48 . . . . 57.3(2) ?
    C37 C36 C47 C50 . . . . 2.1(2) ?
    C35 C36 C47 C50 . . . . 174.80(18) ?
    C44 C45 C53 C55 . . . . 111.1(2) ?
    C46 C45 C53 C55 . . . . -70.9(2) ?
    C44 C45 C53 C56 . . . . -125.9(2) ?
    C46 C45 C53 C56 . . . . 52.1(2) ?
    C44 C45 C53 C54 . . . . -7.7(3) ?
    C46 C45 C53 C54 . . . . 170.29(18) ?
    C63 C58 C59 C60 . . . . 0.0 ?
    C64 C58 C59 C60 . . . . 179.6(3) ?
    C58 C59 C60 C61 . . . . 0.0 ?
    C59 C60 C61 C62 . . . . 0.0 ?
    C60 C61 C62 C63 . . . . 0.0 ?
    C61 C62 C63 C58 . . . . 0.0 ?
    C59 C58 C63 C62 . . . . 0.0 ?
    C64 C58 C63 C62 . . . . -179.6(3) ?
    C70 C65 C66 C67 . . . . 0.0 ?
    C71 C65 C66 C67 . . . . 179.1(3) ?
    C65 C66 C67 C68 . . . . 0.0 ?
    C66 C67 C68 C69 . . . . 0.0 ?
    C67 C68 C69 C70 . . . . 0.0 ?
    C68 C69 C70 C65 . . . . 0.0 ?
    C66 C65 C70 C69 . . . . 0.0 ?
    C71 C65 C70 C69 . . . . -179.1(3) ?
    C2 C1 O1 P1 . . . . 26.3(2) ?
    C6 C1 O1 P1 . . . . -156.39(14) ?
    C18 C13 O2 P1 . . . . -63.9(2) ?
    C14 C13 O2 P1 . . . . 123.26(15) ?
    C19 C24 O3 P1 . . . . -69.83(18) ?
    C23 C24 O3 P1 . . . . 115.23(16) ?
    C17 C16 O4 C29 . . . . 11.4(3) ?
    C15 C16 O4 C29 . . . . -170.62(19) ?
    C20 C21 O5 C30 . . . . -6.4(3) ?
    C22 C21 O5 C30 . . . . 173.3(2) ?
    C40 C35 O6 P2 . . . . -71.52(17) ?
    C36 C35 O6 P2 . . . . 112.59(15) ?
    C41 C46 O7 P2 . . . . -63.4(2) ?
    C45 C46 O7 P2 . . . . 123.33(15) ?
    C39 C38 O9 C51 . . . . -0.8(3) ?
    C37 C38 O9 C51 . . . . 177.12(17) ?
    C42 C43 O10 C52 . . . . -5.2(3) ?
    C44 C43 O10 C52 . . . . 174.89(19) ?
    C13 O2 P1 O1 . . . . -61.60(14) ?
    C13 O2 P1 O3 . . . . 39.12(14) ?
    C13 O2 P1 Rh1 . . . . 167.75(12) ?
    C1 O1 P1 O2 . . . . 160.96(13) ?
    C1 O1 P1 O3 . . . . 53.90(14) ?
    C1 O1 P1 Rh1 . . . . -79.02(14) ?
    C24 O3 P1 O2 . . . . 49.52(13) ?
    C24 O3 P1 O1 . . . . 153.65(12) ?
    C24 O3 P1 Rh1 . . . . -71.24(13) ?
    Rh1 O8 P2 O7 3_575 . . . -156.08(11) ?
    Rh1 O8 P2 O6 3_575 . . . 96.51(12) ?
    Rh1 O8 P2 Rh1 3_575 . . . -32.11(15) ?
    C46 O7 P2 O8 . . . . -78.92(14) ?
    C46 O7 P2 O6 . . . . 28.10(14) ?
    C46 O7 P2 Rh1 . . . . 148.40(12) ?
    C35 O6 P2 O8 . . . . 172.30(11) ?
    C35 O6 P2 O7 . . . . 60.77(12) ?
    C35 O6 P2 Rh1 . . . . -54.30(12) ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
data_global
_journal_date_recd_electronic     2018-12-03
_journal_date_accepted     2019-02-22
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2019
_journal_volume     75
_journal_issue      4
_journal_page_first     398
_journal_page_last     401
_journal_paper_category     FA
_journal_paper_doi     10.1107/S2053229619002730
_journal_coeditor_code     QF3023
_publ_contact_author_name     'Selent, Detlef'
_publ_contact_author_address
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
_publ_contact_author_email     detlef.selent@catalysis.de
_publ_contact_author_fax     '+49(381)1281-5000'
_publ_contact_author_phone     '+49(381)1281-169'
_publ_section_title
;
A dinuclear phosphite rhodium(I) complex obtained by syngas treatment of a
Rh/hydroxy phosphonite olefin hydroformylation precatalyst
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Selent, Detlef' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Str. 29a
18059 Rostock
Germany
;
    'Spannenberg, Anke' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Kubis, Christoph' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Börner, Armin' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
_publ_section_synopsis
;
The crystal structure of a rhodium complex containing fragments and
rearrangement products of a hydroxy phosphonite is described.
;
