##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section C. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section C, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_1
_database_code_depnum_ccdc_archive 'CCDC 1876889'
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_chemical_name_systematic
;\
Bis{N-[(6-bromopyridin-2-yl)methylidene]-2-[6-ethylamino-3-\
(ethyliminiumyl)-2,7-dimethyl-3H-xanthen-9-yl]benzene-1-\
carbohydrazonate}cobalt(II) bis(perchlorate)--dichloromethane --methanol
(1/1/2)
;
_chemical_name_common
;\
Bis(6-bromopyridine-2-carbaldehyde rhodamine 6G hydrazone)cobalt(II)
bis(perchlorate)--dichloromethane--methanol (1/1/2)
;
_chemical_formula_moiety
                     'C64 H60 Br2 Co N10 O4 2+, 2(Cl O4 -), C H2 Cl2, 2(C H4 O)'
_chemical_formula_sum     'C67 H70 Br2 Cl4 Co N10 O14'
_chemical_formula_iupac
                         '[Co (C32 H30 Br1 N5 O2)2] (Cl O4)2, C H2 Cl2, 2C H4 O'
_chemical_formula_weight     1599.88
_chemical_melting_point     ?
_space_group_crystal_system     triclinic
_space_group_name_H-M_alt     'P -1'
_space_group_name_Hall     '-P 1'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     13.2358(5)
_cell_length_b     16.3228(5)
_cell_length_c     17.8925(5)
_cell_angle_alpha     95.741(2)
_cell_angle_beta     107.412(3)
_cell_angle_gamma     105.197(3)
_cell_volume     3492.0(2)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     11414
_cell_measurement_theta_min     4.2140
_cell_measurement_theta_max     76.2280
_cell_measurement_temperature     100.00(11)
_exptl_crystal_description     block
_exptl_crystal_colour     'clear orange'
_exptl_crystal_size_max     0.3
_exptl_crystal_size_mid     0.2
_exptl_crystal_size_min     0.1
_exptl_crystal_density_diffrn     1.522
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1638
_exptl_absorpt_coefficient_mu     5.270
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2017)
;
_exptl_absorpt_correction_T_min     0.49981
_exptl_absorpt_correction_T_max     1.00000
_exptl_special_details     ?
_diffrn_ambient_temperature     100.00(11)
_diffrn_source     'micro-focus sealed X-ray tube'
_diffrn_radiation_type     CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_monochromator     mirror
_diffrn_measurement_device_type
       'Rigaku OD SuperNova Dual source diffractometer with an AtlasS2 detector'
_diffrn_measurement_device     'four-circle diffractometer'
_diffrn_measurement_method     'ω scans'
_diffrn_detector     'CCD plate'
_diffrn_detector_area_resol_mean     5.2137
_diffrn_reflns_number     25181
_diffrn_reflns_av_R_equivalents     0.0489
_diffrn_reflns_av_unetI/netI     0.0645
_diffrn_reflns_theta_min     3.495
_diffrn_reflns_theta_max     76.715
_diffrn_reflns_theta_full     67.684
_diffrn_measured_fraction_theta_max     0.966
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -13
_diffrn_reflns_limit_h_max     16
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     20
_diffrn_reflns_limit_l_min     -18
_diffrn_reflns_limit_l_max     22
_diffrn_radiation_probe     x-ray
_refine_special_details     ?
_reflns_number_total     14225
_reflns_number_gt     12089
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0764
_refine_ls_R_factor_gt     0.0666
_refine_ls_wR_factor_gt     0.1807
_refine_ls_wR_factor_ref     0.1925
_refine_ls_goodness_of_fit_ref     1.032
_refine_ls_restrained_S_all     1.038
_refine_ls_number_reflns     14225
_refine_ls_number_parameters     895
_refine_ls_number_restraints     12
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.1212P)²+3.4690P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.780
_refine_diff_density_min     -1.141
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0181 0.0091
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Br' 'Br' -0.6763 1.2805
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.3639 0.7018
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Co' 'Co' -2.3653 3.6143
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0311 0.0180
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0492 0.0322
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015b)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009) and
DIAMOND (Brandenburg, 2005)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Br Br2 0.14066(4) 0.57606(3) 0.51810(2) 0.02860(12) Uani d 1 . .
    Br Br1 0.51541(4) 0.53924(3) 0.59296(4) 0.04488(16) Uani d 1 . .
    Co Co1 0.26263(5) 0.41997(4) 0.61822(3) 0.01808(14) Uani d 1 . .
    Cl Cl2 -0.21369(12) 0.28710(8) 0.08614(6) 0.0439(3) Uani d 1 . .
    Cl Cl1 0.73900(10) -0.10611(8) 0.73138(8) 0.0442(3) Uani d 1 . .
    Cl Cl3 0.69813(14) 0.38377(10) 0.65157(13) 0.0707(5) Uani d 1 . .
    Cl Cl4 0.63309(18) 0.22925(14) 0.52976(13) 0.0800(5) Uani d 1 . .
    O O1 0.1241(2) 0.31703(17) 0.60352(15) 0.0237(5) Uani d 1 . .
    O O2 0.3755(2) 0.39020(17) 0.70893(15) 0.0239(5) Uani d 1 . .
    O O3 0.1278(2) 0.08515(17) 0.47006(15) 0.0233(5) Uani d 1 . .
    O O4 0.4141(2) 0.54204(17) 0.92365(16) 0.0270(6) Uani d 1 . .
    N N2 0.1840(3) 0.4661(2) 0.68726(17) 0.0202(6) Uani d 1 . .
    N N5 0.3182(3) 0.3346(2) 0.56242(18) 0.0208(6) Uani d 1 . .
    N N4 0.2023(3) 0.4303(2) 0.49141(17) 0.0210(6) Uani d 1 . .
    N N1 0.3657(3) 0.5546(2) 0.66741(18) 0.0215(6) Uani d 1 . .
    N N6 0.3823(3) 0.2922(2) 0.60836(18) 0.0232(6) Uani d 1 . .
    N N3 0.0930(3) 0.4102(2) 0.69559(18) 0.0210(6) Uani d 1 . .
    O O14 -0.1518(4) 0.3107(3) 0.1706(2) 0.0553(11) Uani d 1 . .
    N N8 0.3628(3) -0.0082(2) 0.6749(2) 0.0275(7) Uani d 1 . .
    H H8 0.3872 -0.0094 0.7250 0.033 Uiso calc 1 . .
    O O10 0.8443(3) -0.0422(2) 0.7537(3) 0.0472(9) Uani d 1 . .
    N N10 0.0722(3) 0.3576(2) 0.9200(2) 0.0332(8) Uani d 1 . .
    H H10 0.0324 0.3054 0.9161 0.040 Uiso calc 1 . .
    C C7 0.0720(3) 0.3330(2) 0.6495(2) 0.0202(7) Uani d 1 . .
    C C14 0.0303(3) 0.1482(2) 0.5732(2) 0.0205(7) Uani d 1 . .
    C C39 0.4063(3) 0.3281(2) 0.6847(2) 0.0212(7) Uani d 1 . .
    C C5 0.3284(3) 0.5946(2) 0.7194(2) 0.0213(7) Uani d 1 . .
    C C8 -0.0170(3) 0.2604(2) 0.6570(2) 0.0204(7) Uani d 1 . .
    N N7 -0.0881(4) 0.1730(3) 0.2503(2) 0.0365(8) Uani d 1 . .
    H H7 -0.1443 0.1909 0.2306 0.044 Uiso calc 1 . .
    C C58 0.3711(3) 0.3889(2) 0.8758(2) 0.0226(7) Uani d 1 . .
    C C46 0.4673(3) 0.4035(2) 0.8561(2) 0.0224(7) Uani d 1 . .
    C C13 -0.0304(3) 0.1744(2) 0.6250(2) 0.0195(6) Uani d 1 . .
    C C21 0.1636(3) 0.0805(2) 0.5488(2) 0.0218(7) Uani d 1 . .
    C C6 0.2283(3) 0.5429(2) 0.7303(2) 0.0220(7) Uani d 1 . .
    H H6 0.1981 0.5638 0.7660 0.026 Uiso calc 1 . .
    C C26 0.1168(3) 0.1125(2) 0.6023(2) 0.0197(6) Uani d 1 . .
    O O5 -0.0996(4) 0.2136(3) 0.9305(3) 0.0642(13) Uani d 1 . .
    H H5 -0.1299 0.2327 0.9589 0.096 Uiso calc 1 . .
    C C47 0.5392(3) 0.4900(2) 0.8710(2) 0.0243(7) Uani d 1 . .
    N N9 0.7355(4) 0.7490(3) 0.9192(3) 0.0417(9) Uani d 1 . .
    H H9 0.7969 0.7599 0.9093 0.050 Uiso calc 1 . .
    C C15 -0.0069(3) 0.1513(2) 0.4911(2) 0.0205(7) Uani d 1 . .
    C C54 0.2454(4) 0.4517(3) 0.9208(2) 0.0269(7) Uani d 1 . .
    H H54 0.2303 0.5006 0.9402 0.032 Uiso calc 1 . .
    C C37 0.2100(3) 0.3622(2) 0.4443(2) 0.0239(7) Uani d 1 . .
    C C53 0.3423(3) 0.4600(2) 0.9064(2) 0.0227(7) Uani d 1 . .
    C C45 0.5034(3) 0.3304(2) 0.8281(2) 0.0222(7) Uani d 1 . .
    C C24 0.2464(3) 0.0694(2) 0.7086(2) 0.0237(7) Uani d 1 . .
    C C23 0.2871(3) 0.0333(2) 0.6512(2) 0.0243(7) Uani d 1 . .
    C C19 0.0173(3) 0.1239(2) 0.3608(2) 0.0261(7) Uani d 1 . .
    H H19 0.0527 0.1017 0.3297 0.031 Uiso calc 1 . .
    C C40 0.4754(3) 0.2929(2) 0.7474(2) 0.0220(7) Uani d 1 . .
    C C4 0.3850(3) 0.6792(2) 0.7605(2) 0.0241(7) Uani d 1 . .
    H H4 0.3596 0.7047 0.7971 0.029 Uiso calc 1 . .
    C C57 0.2915(3) 0.3055(2) 0.8630(2) 0.0222(7) Uani d 1 . .
    H H57 0.3068 0.2569 0.8435 0.027 Uiso calc 1 . .
    C C52 0.5097(3) 0.5573(2) 0.9060(2) 0.0246(7) Uani d 1 . .
    C C25 0.1639(3) 0.1063(2) 0.6836(2) 0.0225(7) Uani d 1 . .
    H H25 0.1372 0.1284 0.7211 0.027 Uiso calc 1 . .
    C C38 0.2785(3) 0.3121(2) 0.4858(2) 0.0224(7) Uani d 1 . .
    H H38 0.2924 0.2670 0.4585 0.027 Uiso calc 1 . .
    C C33 0.1418(3) 0.4765(2) 0.4546(2) 0.0237(7) Uani d 1 . .
    C C20 0.0448(3) 0.1200(2) 0.4409(2) 0.0226(7) Uani d 1 . .
    C C1 0.4583(3) 0.5992(3) 0.6582(2) 0.0273(8) Uani d 1 . .
    O O6 0.4925(5) -0.0476(4) 0.8219(3) 0.0765(17) Uani d 1 . .
    H H6A 0.5493 -0.0229 0.8134 0.115 Uiso calc 1 . .
    C C55 0.1677(3) 0.3692(3) 0.9066(2) 0.0258(7) Uani d 1 . .
    C C17 -0.1218(3) 0.1917(2) 0.3751(2) 0.0246(7) Uani d 1 . .
    C C9 -0.0847(3) 0.2773(3) 0.6991(2) 0.0256(7) Uani d 1 . .
    H H9A -0.0762 0.3342 0.7197 0.031 Uiso calc 1 . .
    C C22 0.2452(3) 0.0411(2) 0.5707(2) 0.0231(7) Uani d 1 . .
    H H22 0.2723 0.0199 0.5331 0.028 Uiso calc 1 . .
    C C56 0.1952(3) 0.2945(2) 0.8782(2) 0.0242(7) Uani d 1 . .
    C C36 0.1561(3) 0.3417(3) 0.3621(2) 0.0286(8) Uani d 1 . .
    H H36 0.1644 0.2962 0.3313 0.034 Uiso calc 1 . .
    C C18 -0.0641(3) 0.1615(3) 0.3272(2) 0.0269(8) Uani d 1 . .
    C C48 0.6363(3) 0.5138(3) 0.8508(2) 0.0281(8) Uani d 1 . .
    H H48 0.6577 0.4708 0.8273 0.034 Uiso calc 1 . .
    C C16 -0.0924(3) 0.1862(2) 0.4540(2) 0.0230(7) Uani d 1 . .
    H H16 -0.1300 0.2062 0.4846 0.028 Uiso calc 1 . .
    C C2 0.5189(4) 0.6850(3) 0.6944(3) 0.0326(9) Uani d 1 . .
    H H2 0.5824 0.7137 0.6841 0.039 Uiso calc 1 . .
    C C3 0.4797(4) 0.7252(3) 0.7466(2) 0.0304(8) Uani d 1 . .
    H H3 0.5165 0.7826 0.7721 0.036 Uiso calc 1 . .
    C C27 -0.2118(3) 0.2303(3) 0.3381(2) 0.0294(8) Uani d 1 . .
    H H27A -0.1810 0.2805 0.3189 0.044 Uiso calc 1 . .
    H H27B -0.2426 0.2466 0.3774 0.044 Uiso calc 1 . .
    H H27C -0.2693 0.1884 0.2944 0.044 Uiso calc 1 . .
    C C44 0.5696(3) 0.2985(3) 0.8875(2) 0.0291(8) Uani d 1 . .
    H H44 0.5881 0.3227 0.9410 0.035 Uiso calc 1 . .
    C C62 0.1129(3) 0.2068(3) 0.8657(2) 0.0268(7) Uani d 1 . .
    H H62A 0.0467 0.2010 0.8220 0.040 Uiso calc 1 . .
    H H62B 0.0946 0.2005 0.9133 0.040 Uiso calc 1 . .
    H H62C 0.1450 0.1628 0.8540 0.040 Uiso calc 1 . .
    C C41 0.5132(3) 0.2244(2) 0.7280(2) 0.0247(7) Uani d 1 . .
    H H41 0.4940 0.1991 0.6747 0.030 Uiso calc 1 . .
    C C10 -0.1647(3) 0.2105(3) 0.7108(3) 0.0285(8) Uani d 1 . .
    H H10A -0.2098 0.2227 0.7387 0.034 Uiso calc 1 . .
    C C12 -0.1101(3) 0.1073(2) 0.6385(2) 0.0249(7) Uani d 1 . .
    H H12 -0.1183 0.0501 0.6189 0.030 Uiso calc 1 . .
    C C49 0.7005(4) 0.5989(3) 0.8646(3) 0.0326(9) Uani d 1 . .
    C C34 0.0815(3) 0.4596(3) 0.3733(2) 0.0283(8) Uani d 1 . .
    H H34 0.0377 0.4932 0.3514 0.034 Uiso calc 1 . .
    C C50 0.6698(4) 0.6643(3) 0.9032(3) 0.0334(9) Uani d 1 . .
    O O11 -0.2185(5) 0.2024(3) 0.0560(3) 0.0781(17) Uani d 1 . .
    C C35 0.0897(4) 0.3902(3) 0.3264(2) 0.0303(8) Uani d 1 . .
    H H35 0.0512 0.3763 0.2717 0.036 Uiso calc 1 . .
    C C30 0.2965(3) 0.0646(3) 0.7946(2) 0.0293(8) Uani d 1 . .
    H H30A 0.2830 0.0051 0.7998 0.044 Uiso calc 1 . .
    H H30B 0.2632 0.0925 0.8261 0.044 Uiso calc 1 . .
    H H30C 0.3752 0.0933 0.8127 0.044 Uiso calc 1 . .
    C C51 0.5744(4) 0.6433(3) 0.9234(2) 0.0301(8) Uani d 1 . .
    H H51 0.5541 0.6861 0.9483 0.036 Uiso calc 1 . .
    C C11 -0.1768(3) 0.1253(3) 0.6806(2) 0.0274(8) Uani d 1 . .
    H H11 -0.2297 0.0802 0.6887 0.033 Uiso calc 1 . .
    C C43 0.6079(4) 0.2310(3) 0.8671(3) 0.0319(8) Uani d 1 . .
    H H43 0.6528 0.2108 0.9068 0.038 Uiso calc 1 . .
    C C42 0.5789(4) 0.1936(3) 0.7871(3) 0.0312(8) Uani d 1 . .
    H H42 0.6038 0.1478 0.7735 0.037 Uiso calc 1 . .
    O O8 0.7534(4) -0.1792(3) 0.7687(3) 0.0751(16) Uani d 1 . .
    C C31 0.4071(4) -0.0513(3) 0.6229(3) 0.0317(8) Uani d 1 . .
    H H31A 0.3478 -0.0795 0.5727 0.038 Uiso calc 1 . .
    H H31B 0.4329 -0.0958 0.6475 0.038 Uiso calc 1 . .
    O O7 0.6661(4) -0.0731(5) 0.7615(4) 0.0877(19) Uani d 1 . .
    O O9 0.6895(7) -0.1313(5) 0.6492(4) 0.105(2) Uani d 1 . .
    O O12 -0.1699(6) 0.3437(5) 0.0432(3) 0.101(2) Uani d 1 . .
    C C63 0.0299(4) 0.4276(3) 0.9409(3) 0.0372(10) Uani d 1 . .
    H H63A 0.0911 0.4748 0.9781 0.045 Uiso calc 1 . .
    H H63B -0.0232 0.4069 0.9675 0.045 Uiso calc 1 . .
    C C32 0.5024(4) 0.0098(3) 0.6060(3) 0.0412(10) Uani d 1 . .
    H H32A 0.5296 -0.0225 0.5729 0.062 Uiso calc 1 . .
    H H32B 0.5613 0.0384 0.6554 0.062 Uiso calc 1 . .
    H H32C 0.4765 0.0522 0.5790 0.062 Uiso calc 1 . .
    O O13 -0.3258(5) 0.2876(5) 0.0733(3) 0.0926(19) Uani d 1 . .
    C C28 -0.0253(4) 0.1569(3) 0.1985(3) 0.0385(10) Uani d 1 . .
    H H28A 0.0510 0.1651 0.2312 0.046 Uiso calc 1 . .
    H H28B -0.0244 0.1988 0.1637 0.046 Uiso calc 1 . .
    C C59 0.8007(4) 0.6235(3) 0.8398(3) 0.0448(11) Uani d 1 . .
    H H59A 0.8662 0.6473 0.8864 0.067 Uiso calc 1 . .
    H H59B 0.7944 0.6659 0.8066 0.067 Uiso calc 1 . .
    H H59C 0.8061 0.5732 0.8105 0.067 Uiso calc 1 . .
    C C60 0.7063(5) 0.8204(3) 0.9519(3) 0.0476(13) Uani d 1 . .
    H H60A 0.6966 0.8120 1.0025 0.057 Uiso calc 1 . .
    H H60B 0.6366 0.8230 0.9157 0.057 Uiso calc 1 . .
    C C65 -0.1473(5) 0.1242(3) 0.9075(4) 0.0483(12) Uani d 1 . .
    H H65A -0.1200 0.1029 0.8679 0.072 Uiso calc 1 . .
    H H65B -0.2267 0.1104 0.8855 0.072 Uiso calc 1 . .
    H H65C -0.1280 0.0978 0.9531 0.072 Uiso calc 1 . .
    C C64 -0.0253(5) 0.4606(4) 0.8692(3) 0.0523(14) Uani d 1 . .
    H H64A -0.0927 0.4167 0.8362 0.078 Uiso calc 1 . .
    H H64B 0.0240 0.4748 0.8393 0.078 Uiso calc 1 . .
    H H64C -0.0426 0.5113 0.8863 0.078 Uiso calc 1 . .
    C C29 -0.0738(5) 0.0671(4) 0.1483(3) 0.0512(13) Uani d 1 . .
    H H29A -0.0347 0.0616 0.1116 0.077 Uiso calc 1 . .
    H H29B -0.1511 0.0570 0.1189 0.077 Uiso calc 1 . .
    H H29C -0.0665 0.0255 0.1822 0.077 Uiso calc 1 . .
    C C61 0.7981(6) 0.9050(3) 0.9641(4) 0.0630(19) Uani d 1 . .
    H H61A 0.8041 0.9149 0.9135 0.095 Uiso calc 1 . .
    H H61B 0.8675 0.9012 0.9982 0.095 Uiso calc 1 . .
    H H61C 0.7802 0.9519 0.9885 0.095 Uiso calc 1 . .
    C C67 0.6052(6) 0.3245(6) 0.5564(5) 0.071(2) Uani d 1 . .
    H H67A 0.5295 0.3104 0.5569 0.086 Uiso calc 1 . .
    H H67B 0.6110 0.3602 0.5167 0.086 Uiso calc 1 . .
    C C66 0.5106(9) -0.0302(8) 0.9036(5) 0.099(3) Uani d 1 . .
    H H66A 0.4760 0.0122 0.9147 0.149 Uiso calc 1 . .
    H H66B 0.5891 -0.0084 0.9324 0.149 Uiso calc 1 . .
    H H66C 0.4791 -0.0824 0.9199 0.149 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Br2 C33 . 1.894(4) ?
    Br1 C1 . 1.892(4) ?
    Co1 O1 . 2.064(3) ?
    Co1 O2 . 2.047(3) ?
    Co1 N2 . 2.042(3) ?
    Co1 N5 . 2.044(3) ?
    Co1 N4 . 2.208(3) ?
    Co1 N1 . 2.188(3) ?
    Cl2 O14 . 1.442(3) ?
    Cl2 O11 . 1.411(4) ?
    Cl2 O12 . 1.381(6) ?
    Cl2 O13 . 1.435(5) ?
    Cl1 O10 . 1.418(4) ?
    Cl1 O8 . 1.452(4) ?
    Cl1 O7 . 1.428(6) ?
    Cl1 O9 . 1.386(6) ?
    Cl3 C67 . 1.773(9) ?
    Cl4 C67 . 1.743(9) ?
    O1 C7 . 1.269(5) ?
    O2 C39 . 1.271(5) ?
    O3 C21 . 1.363(4) ?
    O3 C20 . 1.359(5) ?
    O4 C53 . 1.366(5) ?
    O4 C52 . 1.361(5) ?
    N2 N3 . 1.366(4) ?
    N2 C6 . 1.288(5) ?
    N5 N6 . 1.370(5) ?
    N5 C38 . 1.288(5) ?
    N4 C37 . 1.370(5) ?
    N4 C33 . 1.322(5) ?
    N1 C5 . 1.362(5) ?
    N1 C1 . 1.318(5) ?
    N6 C39 . 1.339(5) ?
    N3 C7 . 1.347(5) ?
    N8 C23 . 1.342(5) ?
    N8 C31 . 1.456(5) ?
    N10 C55 . 1.326(6) ?
    N10 C63 . 1.460(5) ?
    C7 C8 . 1.486(5) ?
    C14 C13 . 1.494(5) ?
    C14 C26 . 1.407(5) ?
    C14 C15 . 1.414(5) ?
    C39 C40 . 1.489(5) ?
    C5 C6 . 1.453(5) ?
    C5 C4 . 1.390(5) ?
    C8 C13 . 1.407(5) ?
    C8 C9 . 1.392(5) ?
    N7 C18 . 1.361(5) ?
    N7 C28 . 1.465(6) ?
    C58 C46 . 1.389(5) ?
    C58 C53 . 1.421(5) ?
    C58 C57 . 1.434(5) ?
    C46 C47 . 1.427(5) ?
    C46 C45 . 1.491(5) ?
    C13 C12 . 1.403(5) ?
    C21 C26 . 1.412(5) ?
    C21 C22 . 1.376(5) ?
    C26 C25 . 1.426(5) ?
    O5 C65 . 1.392(6) ?
    C47 C52 . 1.410(6) ?
    C47 C48 . 1.407(6) ?
    N9 C50 . 1.374(5) ?
    N9 C60 . 1.445(7) ?
    C15 C20 . 1.413(5) ?
    C15 C16 . 1.418(5) ?
    C54 C53 . 1.358(6) ?
    C54 C55 . 1.409(6) ?
    C37 C38 . 1.467(6) ?
    C37 C36 . 1.389(5) ?
    C45 C40 . 1.409(5) ?
    C45 C44 . 1.401(5) ?
    C24 C23 . 1.437(5) ?
    C24 C25 . 1.366(6) ?
    C24 C30 . 1.501(5) ?
    C23 C22 . 1.412(5) ?
    C19 C20 . 1.382(5) ?
    C19 C18 . 1.389(6) ?
    C40 C41 . 1.392(5) ?
    C4 C3 . 1.389(6) ?
    C57 C56 . 1.352(5) ?
    C52 C51 . 1.387(5) ?
    C33 C34 . 1.392(5) ?
    C1 C2 . 1.393(6) ?
    O6 C66 . 1.395(10) ?
    C55 C56 . 1.447(5) ?
    C17 C18 . 1.437(6) ?
    C17 C16 . 1.367(5) ?
    C17 C27 . 1.503(5) ?
    C9 C10 . 1.387(5) ?
    C56 C62 . 1.503(5) ?
    C36 C35 . 1.392(6) ?
    C48 C49 . 1.378(6) ?
    C2 C3 . 1.384(6) ?
    C44 C43 . 1.387(6) ?
    C41 C42 . 1.384(6) ?
    C10 C11 . 1.391(6) ?
    C12 C11 . 1.387(6) ?
    C49 C50 . 1.426(7) ?
    C49 C59 . 1.491(7) ?
    C34 C35 . 1.388(6) ?
    C50 C51 . 1.384(7) ?
    C43 C42 . 1.394(6) ?
    C31 C32 . 1.518(7) ?
    C63 C64 . 1.502(8) ?
    C28 C29 . 1.505(7) ?
    C60 C61 . 1.526(7) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Co1 N4 . . 92.23(11) ?
    O1 Co1 N1 . . 151.55(11) ?
    O2 Co1 O1 . . 98.93(11) ?
    O2 Co1 N4 . . 148.65(12) ?
    O2 Co1 N1 . . 85.63(11) ?
    N2 Co1 O1 . . 75.66(11) ?
    N2 Co1 O2 . . 96.19(11) ?
    N2 Co1 N5 . . 159.47(13) ?
    N2 Co1 N4 . . 114.99(12) ?
    N2 Co1 N1 . . 75.94(12) ?
    N5 Co1 O1 . . 87.08(12) ?
    N5 Co1 O2 . . 75.30(12) ?
    N5 Co1 N4 . . 76.13(12) ?
    N5 Co1 N1 . . 121.05(12) ?
    N1 Co1 N4 . . 98.30(11) ?
    O11 Cl2 O14 . . 110.2(2) ?
    O11 Cl2 O13 . . 107.5(4) ?
    O12 Cl2 O14 . . 112.8(3) ?
    O12 Cl2 O11 . . 109.5(4) ?
    O12 Cl2 O13 . . 107.6(5) ?
    O13 Cl2 O14 . . 109.1(3) ?
    O10 Cl1 O8 . . 108.4(2) ?
    O10 Cl1 O7 . . 109.8(3) ?
    O7 Cl1 O8 . . 107.0(4) ?
    O9 Cl1 O10 . . 112.1(4) ?
    O9 Cl1 O8 . . 111.4(4) ?
    O9 Cl1 O7 . . 107.9(4) ?
    C7 O1 Co1 . . 111.8(2) ?
    C39 O2 Co1 . . 112.3(2) ?
    C20 O3 C21 . . 120.4(3) ?
    C52 O4 C53 . . 120.3(3) ?
    N3 N2 Co1 . . 118.6(2) ?
    C6 N2 Co1 . . 120.2(3) ?
    C6 N2 N3 . . 120.6(3) ?
    N6 N5 Co1 . . 118.3(2) ?
    C38 N5 Co1 . . 119.4(3) ?
    C38 N5 N6 . . 121.4(3) ?
    C37 N4 Co1 . . 110.1(2) ?
    C33 N4 Co1 . . 131.5(3) ?
    C33 N4 C37 . . 116.5(3) ?
    C5 N1 Co1 . . 112.1(2) ?
    C1 N1 Co1 . . 130.6(3) ?
    C1 N1 C5 . . 117.2(3) ?
    C39 N6 N5 . . 107.0(3) ?
    C7 N3 N2 . . 107.5(3) ?
    C23 N8 C31 . . 125.3(3) ?
    C55 N10 C63 . . 124.4(4) ?
    O1 C7 N3 . . 125.9(3) ?
    O1 C7 C8 . . 118.2(3) ?
    N3 C7 C8 . . 115.8(3) ?
    C26 C14 C13 . . 121.5(3) ?
    C26 C14 C15 . . 118.8(3) ?
    C15 C14 C13 . . 119.4(3) ?
    O2 C39 N6 . . 125.8(3) ?
    O2 C39 C40 . . 116.6(3) ?
    N6 C39 C40 . . 117.7(3) ?
    N1 C5 C6 . . 115.9(3) ?
    N1 C5 C4 . . 121.6(3) ?
    C4 C5 C6 . . 122.5(3) ?
    C13 C8 C7 . . 120.5(3) ?
    C9 C8 C7 . . 119.7(3) ?
    C9 C8 C13 . . 119.7(3) ?
    C18 N7 C28 . . 124.7(4) ?
    C46 C58 C53 . . 120.0(3) ?
    C46 C58 C57 . . 124.6(3) ?
    C53 C58 C57 . . 115.3(3) ?
    C58 C46 C47 . . 119.2(4) ?
    C58 C46 C45 . . 121.4(3) ?
    C47 C46 C45 . . 119.1(3) ?
    C8 C13 C14 . . 124.8(3) ?
    C12 C13 C14 . . 116.4(3) ?
    C12 C13 C8 . . 118.7(3) ?
    O3 C21 C26 . . 121.2(3) ?
    O3 C21 C22 . . 115.1(3) ?
    C22 C21 C26 . . 123.7(3) ?
    N2 C6 C5 . . 115.6(3) ?
    C14 C26 C21 . . 119.2(3) ?
    C14 C26 C25 . . 124.9(3) ?
    C21 C26 C25 . . 115.8(3) ?
    C52 C47 C46 . . 118.3(4) ?
    C48 C47 C46 . . 124.7(4) ?
    C48 C47 C52 . . 117.0(4) ?
    C50 N9 C60 . . 123.1(5) ?
    C14 C15 C16 . . 124.7(3) ?
    C20 C15 C14 . . 119.4(3) ?
    C20 C15 C16 . . 115.9(3) ?
    C53 C54 C55 . . 120.1(4) ?
    N4 C37 C38 . . 116.0(3) ?
    N4 C37 C36 . . 122.2(4) ?
    C36 C37 C38 . . 121.9(4) ?
    O4 C53 C58 . . 120.2(4) ?
    C54 C53 O4 . . 116.2(3) ?
    C54 C53 C58 . . 123.5(4) ?
    C40 C45 C46 . . 124.4(3) ?
    C44 C45 C46 . . 116.4(3) ?
    C44 C45 C40 . . 119.2(4) ?
    C23 C24 C30 . . 118.4(3) ?
    C25 C24 C23 . . 119.5(3) ?
    C25 C24 C30 . . 122.1(4) ?
    N8 C23 C24 . . 119.5(3) ?
    N8 C23 C22 . . 121.3(4) ?
    C22 C23 C24 . . 119.2(4) ?
    C20 C19 C18 . . 119.1(4) ?
    C45 C40 C39 . . 118.8(3) ?
    C41 C40 C39 . . 121.6(3) ?
    C41 C40 C45 . . 119.6(3) ?
    C3 C4 C5 . . 119.4(4) ?
    C56 C57 C58 . . 122.9(3) ?
    O4 C52 C47 . . 121.8(3) ?
    O4 C52 C51 . . 115.5(4) ?
    C51 C52 C47 . . 122.7(4) ?
    C24 C25 C26 . . 122.7(3) ?
    N5 C38 C37 . . 115.6(3) ?
    N4 C33 Br2 . . 116.7(3) ?
    N4 C33 C34 . . 125.7(4) ?
    C34 C33 Br2 . . 117.5(3) ?
    O3 C20 C15 . . 120.9(3) ?
    O3 C20 C19 . . 115.7(3) ?
    C19 C20 C15 . . 123.3(4) ?
    N1 C1 Br1 . . 116.5(3) ?
    N1 C1 C2 . . 125.6(4) ?
    C2 C1 Br1 . . 117.9(3) ?
    N10 C55 C54 . . 122.4(4) ?
    N10 C55 C56 . . 119.2(4) ?
    C54 C55 C56 . . 118.4(4) ?
    C18 C17 C27 . . 119.6(3) ?
    C16 C17 C18 . . 119.3(4) ?
    C16 C17 C27 . . 121.1(4) ?
    C10 C9 C8 . . 121.1(4) ?
    C21 C22 C23 . . 119.0(3) ?
    C57 C56 C55 . . 119.8(4) ?
    C57 C56 C62 . . 122.5(3) ?
    C55 C56 C62 . . 117.7(4) ?
    C37 C36 C35 . . 119.2(4) ?
    N7 C18 C19 . . 121.3(4) ?
    N7 C18 C17 . . 119.0(4) ?
    C19 C18 C17 . . 119.7(3) ?
    C49 C48 C47 . . 122.0(4) ?
    C17 C16 C15 . . 122.6(4) ?
    C3 C2 C1 . . 116.6(4) ?
    C2 C3 C4 . . 119.5(4) ?
    C43 C44 C45 . . 120.5(4) ?
    C42 C41 C40 . . 120.7(4) ?
    C9 C10 C11 . . 119.5(4) ?
    C11 C12 C13 . . 120.9(4) ?
    C48 C49 C50 . . 118.9(4) ?
    C48 C49 C59 . . 121.4(4) ?
    C50 C49 C59 . . 119.7(4) ?
    C35 C34 C33 . . 117.0(4) ?
    N9 C50 C49 . . 119.1(4) ?
    N9 C50 C51 . . 120.3(4) ?
    C51 C50 C49 . . 120.6(4) ?
    C34 C35 C36 . . 119.3(4) ?
    C50 C51 C52 . . 118.8(4) ?
    C12 C11 C10 . . 120.2(4) ?
    C44 C43 C42 . . 120.0(4) ?
    C41 C42 C43 . . 120.0(4) ?
    N8 C31 C32 . . 113.3(4) ?
    N10 C63 C64 . . 112.4(4) ?
    N7 C28 C29 . . 112.5(4) ?
    N9 C60 C61 . . 109.7(6) ?
    Cl4 C67 Cl3 . . 112.0(4) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    Br2 C33 C34 C35 . . . . 175.3(3) ?
    Br1 C1 C2 C3 . . . . -175.2(3) ?
    Co1 O1 C7 N3 . . . . 8.0(5) ?
    Co1 O1 C7 C8 . . . . -169.0(2) ?
    Co1 O2 C39 N6 . . . . 8.9(5) ?
    Co1 O2 C39 C40 . . . . -171.4(2) ?
    Co1 N2 N3 C7 . . . . -3.2(4) ?
    Co1 N2 C6 C5 . . . . 6.0(4) ?
    Co1 N5 N6 C39 . . . . -8.4(4) ?
    Co1 N5 C38 C37 . . . . 10.3(4) ?
    Co1 N4 C37 C38 . . . . -14.3(4) ?
    Co1 N4 C37 C36 . . . . 165.6(3) ?
    Co1 N4 C33 Br2 . . . . 22.2(4) ?
    Co1 N4 C33 C34 . . . . -159.5(3) ?
    Co1 N1 C5 C6 . . . . -1.8(4) ?
    Co1 N1 C5 C4 . . . . 176.8(3) ?
    Co1 N1 C1 Br1 . . . . -0.7(5) ?
    Co1 N1 C1 C2 . . . . -178.3(3) ?
    O1 C7 C8 C13 . . . . 10.5(5) ?
    O1 C7 C8 C9 . . . . -172.3(3) ?
    O2 C39 C40 C45 . . . . -0.8(5) ?
    O2 C39 C40 C41 . . . . 179.5(3) ?
    O3 C21 C26 C14 . . . . 1.3(5) ?
    O3 C21 C26 C25 . . . . -178.1(3) ?
    O3 C21 C22 C23 . . . . -179.9(3) ?
    O4 C52 C51 C50 . . . . -176.5(3) ?
    N2 N3 C7 O1 . . . . -3.5(5) ?
    N2 N3 C7 C8 . . . . 173.6(3) ?
    N5 N6 C39 O2 . . . . -0.6(5) ?
    N5 N6 C39 C40 . . . . 179.7(3) ?
    N4 C37 C38 N5 . . . . 4.0(5) ?
    N4 C37 C36 C35 . . . . -1.7(6) ?
    N4 C33 C34 C35 . . . . -2.9(6) ?
    N1 C5 C6 N2 . . . . -2.4(5) ?
    N1 C5 C4 C3 . . . . 2.2(6) ?
    N1 C1 C2 C3 . . . . 2.3(7) ?
    N6 N5 C38 C37 . . . . 179.1(3) ?
    N6 C39 C40 C45 . . . . 178.9(3) ?
    N6 C39 C40 C41 . . . . -0.8(5) ?
    N3 N2 C6 C5 . . . . 176.6(3) ?
    N3 C7 C8 C13 . . . . -166.8(3) ?
    N3 C7 C8 C9 . . . . 10.4(5) ?
    N8 C23 C22 C21 . . . . 176.8(4) ?
    N10 C55 C56 C57 . . . . 178.9(4) ?
    N10 C55 C56 C62 . . . . -0.3(5) ?
    C7 C8 C13 C14 . . . . -8.1(5) ?
    C7 C8 C13 C12 . . . . 175.4(3) ?
    C7 C8 C9 C10 . . . . -176.5(3) ?
    C14 C13 C12 C11 . . . . -175.0(3) ?
    C14 C26 C25 C24 . . . . 178.6(3) ?
    C14 C15 C20 O3 . . . . 1.5(5) ?
    C14 C15 C20 C19 . . . . -177.1(3) ?
    C14 C15 C16 C17 . . . . 176.7(3) ?
    C39 C40 C41 C42 . . . . 178.9(4) ?
    C5 N1 C1 Br1 . . . . 174.7(3) ?
    C5 N1 C1 C2 . . . . -2.8(6) ?
    C5 C4 C3 C2 . . . . -2.7(6) ?
    C8 C13 C12 C11 . . . . 1.8(5) ?
    C8 C9 C10 C11 . . . . 0.6(6) ?
    C58 C46 C47 C52 . . . . 0.5(5) ?
    C58 C46 C47 C48 . . . . -177.1(4) ?
    C58 C46 C45 C40 . . . . 92.8(5) ?
    C58 C46 C45 C44 . . . . -87.3(4) ?
    C58 C57 C56 C55 . . . . 1.7(6) ?
    C58 C57 C56 C62 . . . . -179.1(3) ?
    C46 C58 C53 O4 . . . . -6.2(5) ?
    C46 C58 C53 C54 . . . . 174.4(3) ?
    C46 C58 C57 C56 . . . . -175.6(4) ?
    C46 C47 C52 O4 . . . . -1.7(5) ?
    C46 C47 C52 C51 . . . . 179.5(3) ?
    C46 C47 C48 C49 . . . . 178.0(4) ?
    C46 C45 C40 C39 . . . . 0.7(5) ?
    C46 C45 C40 C41 . . . . -179.6(3) ?
    C46 C45 C44 C43 . . . . -179.5(4) ?
    C13 C14 C26 C21 . . . . 173.4(3) ?
    C13 C14 C26 C25 . . . . -7.3(5) ?
    C13 C14 C15 C20 . . . . -174.9(3) ?
    C13 C14 C15 C16 . . . . 6.8(5) ?
    C13 C8 C9 C10 . . . . 0.7(6) ?
    C13 C12 C11 C10 . . . . -0.6(6) ?
    C21 O3 C20 C15 . . . . -0.6(5) ?
    C21 O3 C20 C19 . . . . 178.1(3) ?
    C21 C26 C25 C24 . . . . -2.1(5) ?
    C6 N2 N3 C7 . . . . -174.0(3) ?
    C6 C5 C4 C3 . . . . -179.4(4) ?
    C26 C14 C13 C8 . . . . 106.2(4) ?
    C26 C14 C13 C12 . . . . -77.2(4) ?
    C26 C14 C15 C20 . . . . -1.0(5) ?
    C26 C14 C15 C16 . . . . -179.4(3) ?
    C26 C21 C22 C23 . . . . -1.4(6) ?
    C47 C46 C45 C40 . . . . -94.0(4) ?
    C47 C46 C45 C44 . . . . 85.9(4) ?
    C47 C52 C51 C50 . . . . 2.3(6) ?
    C47 C48 C49 C50 . . . . 2.2(6) ?
    C47 C48 C49 C59 . . . . -177.5(4) ?
    N9 C50 C51 C52 . . . . 179.7(4) ?
    C15 C14 C13 C8 . . . . -80.1(4) ?
    C15 C14 C13 C12 . . . . 96.5(4) ?
    C15 C14 C26 C21 . . . . -0.3(5) ?
    C15 C14 C26 C25 . . . . 178.9(3) ?
    C54 C55 C56 C57 . . . . -2.7(5) ?
    C54 C55 C56 C62 . . . . 178.1(3) ?
    C37 N4 C33 Br2 . . . . -175.0(3) ?
    C37 N4 C33 C34 . . . . 3.2(5) ?
    C37 C36 C35 C34 . . . . 2.0(6) ?
    C53 O4 C52 C47 . . . . -1.1(5) ?
    C53 O4 C52 C51 . . . . 177.7(3) ?
    C53 C58 C46 C47 . . . . 3.3(5) ?
    C53 C58 C46 C45 . . . . 176.5(3) ?
    C53 C58 C57 C56 . . . . 0.5(5) ?
    C53 C54 C55 N10 . . . . 179.7(4) ?
    C53 C54 C55 C56 . . . . 1.4(5) ?
    C45 C46 C47 C52 . . . . -172.9(3) ?
    C45 C46 C47 C48 . . . . 9.5(5) ?
    C45 C40 C41 C42 . . . . -0.8(6) ?
    C45 C44 C43 C42 . . . . -1.1(7) ?
    C24 C23 C22 C21 . . . . -2.2(5) ?
    C23 N8 C31 C32 . . . . 83.4(5) ?
    C23 C24 C25 C26 . . . . -1.3(6) ?
    C40 C45 C44 C43 . . . . 0.4(6) ?
    C40 C41 C42 C43 . . . . 0.1(6) ?
    C4 C5 C6 N2 . . . . 179.0(3) ?
    C57 C58 C46 C47 . . . . 179.3(3) ?
    C57 C58 C46 C45 . . . . -7.5(5) ?
    C57 C58 C53 O4 . . . . 177.5(3) ?
    C57 C58 C53 C54 . . . . -1.9(5) ?
    C52 O4 C53 C58 . . . . 5.1(5) ?
    C52 O4 C53 C54 . . . . -175.5(3) ?
    C52 C47 C48 C49 . . . . 0.4(5) ?
    C25 C24 C23 N8 . . . . -175.5(4) ?
    C25 C24 C23 C22 . . . . 3.5(5) ?
    C38 N5 N6 C39 . . . . -177.3(3) ?
    C38 C37 C36 C35 . . . . 178.1(4) ?
    C33 N4 C37 C38 . . . . 179.3(3) ?
    C33 N4 C37 C36 . . . . -0.8(5) ?
    C33 C34 C35 C36 . . . . 0.1(6) ?
    C20 O3 C21 C26 . . . . -0.8(5) ?
    C20 O3 C21 C22 . . . . 177.7(3) ?
    C20 C15 C16 C17 . . . . -1.7(5) ?
    C20 C19 C18 N7 . . . . 174.9(4) ?
    C20 C19 C18 C17 . . . . -3.1(6) ?
    C1 N1 C5 C6 . . . . -178.0(3) ?
    C1 N1 C5 C4 . . . . 0.5(5) ?
    C1 C2 C3 C4 . . . . 0.6(6) ?
    C55 N10 C63 C64 . . . . 80.8(6) ?
    C55 C54 C53 O4 . . . . -178.5(3) ?
    C55 C54 C53 C58 . . . . 1.0(6) ?
    C9 C8 C13 C14 . . . . 174.7(3) ?
    C9 C8 C13 C12 . . . . -1.8(5) ?
    C9 C10 C11 C12 . . . . -0.6(6) ?
    C22 C21 C26 C14 . . . . -177.1(3) ?
    C22 C21 C26 C25 . . . . 3.5(5) ?
    C36 C37 C38 N5 . . . . -175.9(4) ?
    C18 N7 C28 C29 . . . . 93.5(6) ?
    C18 C19 C20 O3 . . . . -177.7(3) ?
    C18 C19 C20 C15 . . . . 1.0(6) ?
    C18 C17 C16 C15 . . . . -0.3(6) ?
    C48 C47 C52 O4 . . . . 176.1(3) ?
    C48 C47 C52 C51 . . . . -2.7(5) ?
    C48 C49 C50 N9 . . . . 178.1(4) ?
    C48 C49 C50 C51 . . . . -2.6(6) ?
    C16 C15 C20 O3 . . . . 180.0(3) ?
    C16 C15 C20 C19 . . . . 1.4(5) ?
    C16 C17 C18 N7 . . . . -175.2(4) ?
    C16 C17 C18 C19 . . . . 2.8(6) ?
    C27 C17 C18 N7 . . . . 3.6(6) ?
    C27 C17 C18 C19 . . . . -178.4(4) ?
    C27 C17 C16 C15 . . . . -179.1(3) ?
    C44 C45 C40 C39 . . . . -179.2(3) ?
    C44 C45 C40 C41 . . . . 0.5(5) ?
    C44 C43 C42 C41 . . . . 0.8(7) ?
    C49 C50 C51 C52 . . . . 0.4(6) ?
    C50 N9 C60 C61 . . . . 178.7(4) ?
    C30 C24 C23 N8 . . . . 4.2(5) ?
    C30 C24 C23 C22 . . . . -176.7(3) ?
    C30 C24 C25 C26 . . . . 179.0(3) ?
    C31 N8 C23 C24 . . . . 176.9(4) ?
    C31 N8 C23 C22 . . . . -2.2(6) ?
    C63 N10 C55 C54 . . . . 8.0(7) ?
    C63 N10 C55 C56 . . . . -173.7(4) ?
    C28 N7 C18 C19 . . . . -7.1(7) ?
    C28 N7 C18 C17 . . . . 170.9(4) ?
    C59 C49 C50 N9 . . . . -2.2(6) ?
    C59 C49 C50 C51 . . . . 177.1(4) ?
    C60 N9 C50 C49 . . . . 174.6(4) ?
    C60 N9 C50 C51 . . . . -4.6(7) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    N8 H8 O6 . 0.86 2.14 2.913(5) 150.0
    N10 H10 O5 . 0.86 2.08 2.877(5) 153.1
    N7 H7 O14 . 0.86 2.33 2.951(5) 129.0
    C6 H6 O14 2_566 0.93 2.54 3.373(5) 148.7
    O5 H5 O11 1_556 0.82 2.39 3.098(8) 144.6
    O5 H5 O12 1_556 0.82 2.50 3.277(9) 157.8
    C19 H19 O10 2_656 0.93 2.58 3.509(6) 178.6
    C4 H4 O13 2_566 0.93 2.49 3.323(6) 149.6
    O6 H6A O7 . 0.82 2.30 2.919(7) 132.5
    C2 H2 O8 1_565 0.93 2.41 3.107(6) 131.5
    C44 H44 O13 1_656 0.93 2.50 3.239(6) 137.0
    C12 H12 O3 2_556 0.93 2.54 3.438(5) 162.1
    C28 H28A O8 2_656 0.97 2.54 3.382(7) 145.5
    C67 H67A N6 . 0.97 2.36 3.281(7) 159.0
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
data_2
_database_code_depnum_ccdc_archive 'CCDC 1876890'
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_chemical_name_systematic
;\
Bis{N-[(6-bromopyridin-2-yl)methylidene]-2-[6-ethylamino-3-\
(ethyliminiumyl)-2,7-dimethyl-3H-xanthen-9-yl]benzene-1-\
carbohydrazonate}cobalt(II) bis(tetrafluoridoborate)--dichloromethane--methanol
(1/1/2)
;
_chemical_name_common
;\
Bis(6-bromopyridine-2-carbaldehyde rhodamine 6G hydrazone)cobalt(II)
bis(tetrafluoridoborate)--dichloromethane--methanol (1/1/2)
;
_chemical_formula_moiety
                      'C64 H60 Br2 Co N10 O4 2+, 2(B F4 -), C H2 Cl2, 2(C H4 O)'
_chemical_formula_sum     'C67 H70 B2 Br2 Cl2 Co F8 N10 O6'
_chemical_formula_iupac
                          '[Co (C32 H30 Br1 N5 O2)2] (B F4)2, C H2 Cl2, 2C H4 O'
_chemical_formula_weight     1574.60
_chemical_melting_point     ?
_space_group_crystal_system     triclinic
_space_group_name_H-M_alt     'P -1'
_space_group_name_Hall     '-P 1'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     13.1820(3)
_cell_length_b     16.2426(3)
_cell_length_c     17.7898(3)
_cell_angle_alpha     95.8495(14)
_cell_angle_beta     107.3297(16)
_cell_angle_gamma     104.7128(16)
_cell_volume     3451.18(11)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     12867
_cell_measurement_theta_min     4.2500
_cell_measurement_theta_max     75.9860
_cell_measurement_temperature     99.98(15)
_exptl_crystal_description     block
_exptl_crystal_colour     'clear orange'
_exptl_crystal_size_max     0.3
_exptl_crystal_size_mid     0.2
_exptl_crystal_size_min     0.2
_exptl_crystal_density_diffrn     1.515
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1606
_exptl_absorpt_coefficient_mu     4.704
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2017)
;
_exptl_absorpt_correction_T_min     0.60726
_exptl_absorpt_correction_T_max     1.00000
_diffrn_ambient_temperature     99.98(15)
_diffrn_source     'micro-focus sealed X-ray tube'
_diffrn_radiation_type     CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_monochromator     mirror
_diffrn_measurement_device_type
       'Rigaku OD SuperNova Dual source diffractometer with an AtlasS2 detector'
_diffrn_measurement_device     'four-circle diffractometer'
_diffrn_measurement_method     'ω scans'
_diffrn_detector     'CCD plate'
_diffrn_detector_area_resol_mean     5.2137
_diffrn_reflns_number     24331
_diffrn_reflns_av_R_equivalents     0.0318
_diffrn_reflns_av_unetI/netI     0.0450
_diffrn_reflns_theta_min     3.511
_diffrn_reflns_theta_max     69.999
_diffrn_reflns_theta_full     67.684
_diffrn_measured_fraction_theta_max     0.999
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -16
_diffrn_reflns_limit_h_max     16
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     19
_diffrn_reflns_limit_l_min     -21
_diffrn_reflns_limit_l_max     15
_diffrn_radiation_probe     x-ray
_refine_special_details     ?
_reflns_number_total     13070
_reflns_number_gt     11725
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0548
_refine_ls_R_factor_gt     0.0494
_refine_ls_wR_factor_gt     0.1320
_refine_ls_wR_factor_ref     0.1368
_refine_ls_goodness_of_fit_ref     1.027
_refine_ls_restrained_S_all     1.027
_refine_ls_number_reflns     13070
_refine_ls_number_parameters     923
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0767P)²+4.2094P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.429
_refine_diff_density_min     -1.158
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0181 0.0091
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'B' 'B' 0.0090 0.0039
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Br' 'Br' -0.6763 1.2805
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.3639 0.7018
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Co' 'Co' -2.3653 3.6143
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'F' 'F' 0.0727 0.0534
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0311 0.0180
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0492 0.0322
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015b)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009) and
DIAMOND (Brandenburg, 2005)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Co Co1 0.73545(4) 0.58067(3) 0.37985(3) 0.01313(11) Uani d 1 . .
    Br Br1 0.48426(3) 0.45907(3) 0.40664(3) 0.03829(12) Uani d 1 . .
    Br Br2 0.85935(3) 0.42392(2) 0.48070(2) 0.02339(9) Uani d 1 . .
    N N1 0.6343(2) 0.44558(16) 0.33073(15) 0.0168(5) Uani d 1 . .
    N N2 0.8155(2) 0.53433(16) 0.31085(15) 0.0153(5) Uani d 1 . .
    N N3 0.9064(2) 0.59119(16) 0.30256(15) 0.0166(5) Uani d 1 . .
    N N4 0.7953(2) 0.57032(16) 0.50743(15) 0.0161(5) Uani d 1 . .
    N N5 0.6786(2) 0.66609(16) 0.43614(15) 0.0155(5) Uani d 1 . .
    N N6 0.6139(2) 0.70897(16) 0.38973(15) 0.0173(5) Uani d 1 . .
    N N7 1.0850(2) 0.82666(19) 0.74955(16) 0.0249(6) Uani d 1 . .
    H H7 1.1424 0.8075 0.7690 0.030 Uiso calc 1 . .
    N N8 0.6301(2) 1.01007(18) 0.32443(17) 0.0228(5) Uani d 1 . .
    H H8 0.6047 1.0112 0.2730 0.027 Uiso calc 1 . .
    N N9 0.2679(3) 0.25194(19) 0.08203(19) 0.0338(7) Uani d 1 . .
    H H9 0.2053 0.2412 0.0928 0.041 Uiso calc 1 . .
    N N10 0.9315(3) 0.64350(19) 0.0824(2) 0.0318(7) Uani d 1 . .
    H H10 0.9736 0.6970 0.0885 0.038 Uiso calc 1 . .
    O O1 0.87392(18) 0.68391(13) 0.39508(13) 0.0191(4) Uani d 1 . .
    O O2 0.62230(18) 0.61089(13) 0.28928(12) 0.0190(4) Uani d 1 . .
    O O3 0.86477(17) 0.91361(14) 0.52946(12) 0.0183(4) Uani d 1 . .
    O O4 0.58811(19) 0.45861(14) 0.07600(13) 0.0214(4) Uani d 1 . .
    O O5 1.1013(3) 0.7886(2) 0.0707(2) 0.0549(9) Uani d 1 . .
    H H5 1.0953 0.7707 0.0231 0.082 Uiso calc 1 . .
    O O6 0.4953(3) 1.0432(3) 0.17580(18) 0.0603(10) Uani d 1 . .
    H H6A 0.4329 1.0381 0.1810 0.090 Uiso calc 1 . .
    Cl Cl1 0.36095(14) 0.76760(11) 0.46623(10) 0.0779(4) Uani d 1 . .
    Cl Cl2 0.29729(11) 0.61450(8) 0.34169(10) 0.0656(4) Uani d 1 . .
    B B1 1.2065(5) 0.7122(3) 0.9092(3) 0.0460(13) Uani d 1 . .
    B B2 0.2630(4) 1.1135(3) 0.2669(3) 0.0324(9) Uani d 1 . .
    F F1 1.1762(9) 0.6530(7) 0.9523(5) 0.094(4) Uani d 0.561(17) A 1
    F F2 1.3297(7) 0.7245(9) 0.9283(4) 0.068(3) Uani d 0.561(17) A 1
    F F4 1.2026(10) 0.7880(7) 0.9469(4) 0.061(3) Uani d 0.561(17) A 1
    F F1A 1.1179(19) 0.6930(9) 0.9397(10) 0.134(8) Uani d 0.439(17) A 2
    F F2A 1.2650(15) 0.6640(8) 0.9285(6) 0.096(8) Uani d 0.439(17) A 2
    F F4A 1.2445(9) 0.7998(8) 0.9261(9) 0.072(3) Uani d 0.439(17) A 2
    F F3 1.1547(3) 0.6923(2) 0.82789(14) 0.0566(8) Uani d 1 . .
    F F5 0.3106(3) 1.1425(2) 0.34795(17) 0.0718(9) Uani d 1 . .
    F F6 0.3382(2) 1.0840(2) 0.23837(18) 0.0538(7) Uani d 1 . .
    F F7 0.24318(19) 1.18239(15) 0.23005(17) 0.0469(6) Uani d 1 . .
    F F8 0.16478(19) 1.04844(14) 0.24758(16) 0.0408(5) Uani d 1 . .
    C C1 0.5421(3) 0.3996(2) 0.34021(19) 0.0222(6) Uani d 1 . .
    C C2 0.4842(3) 0.3137(2) 0.3045(2) 0.0273(7) Uani d 1 . .
    H H2 0.4200 0.2837 0.3156 0.033 Uiso calc 1 . .
    C C3 0.5238(3) 0.2738(2) 0.25222(19) 0.0245(7) Uani d 1 . .
    H H3 0.4874 0.2148 0.2267 0.029 Uiso calc 1 . .
    C C4 0.6172(3) 0.3204(2) 0.23702(18) 0.0204(6) Uani d 1 . .
    H H4 0.6434 0.2946 0.1992 0.024 Uiso calc 1 . .
    C C5 0.6718(2) 0.40552(19) 0.27804(17) 0.0165(6) Uani d 1 . .
    C C6 0.7730(2) 0.45778(19) 0.26759(18) 0.0177(6) Uani d 1 . .
    H H6 0.8049 0.4366 0.2313 0.021 Uiso calc 1 . .
    C C7 0.9262(2) 0.66784(19) 0.34841(17) 0.0155(5) Uani d 1 . .
    C C8 1.0149(2) 0.74102(19) 0.34113(17) 0.0161(6) Uani d 1 . .
    C C9 1.0830(3) 0.7251(2) 0.29835(19) 0.0205(6) Uani d 1 . .
    H H9A 1.0754 0.6669 0.2771 0.025 Uiso calc 1 . .
    C C10 1.1619(3) 0.7923(2) 0.2861(2) 0.0242(7) Uani d 1 . .
    H H10A 1.2084 0.7801 0.2574 0.029 Uiso calc 1 . .
    C C11 1.1721(3) 0.8775(2) 0.3161(2) 0.0229(6) Uani d 1 . .
    H H11 1.2249 0.9239 0.3072 0.027 Uiso calc 1 . .
    C C12 1.1048(3) 0.8947(2) 0.35911(19) 0.0195(6) Uani d 1 . .
    H H12 1.1119 0.9532 0.3790 0.023 Uiso calc 1 . .
    C C13 1.0272(2) 0.82761(19) 0.37357(17) 0.0152(5) Uani d 1 . .
    C C14 0.9654(2) 0.85261(18) 0.42578(18) 0.0155(6) Uani d 1 . .
    C C15 0.8784(2) 0.88856(18) 0.39709(18) 0.0160(6) Uani d 1 . .
    C C16 0.8314(2) 0.89565(19) 0.31525(18) 0.0181(6) Uani d 1 . .
    H H16 0.8592 0.8735 0.2766 0.022 Uiso calc 1 . .
    C C17 0.7485(2) 0.93274(19) 0.29041(18) 0.0185(6) Uani d 1 . .
    C C18 0.7067(2) 0.96827(19) 0.34835(19) 0.0190(6) Uani d 1 . .
    C C19 0.7476(3) 0.9589(2) 0.42864(19) 0.0195(6) Uani d 1 . .
    H H19 0.7183 0.9793 0.4671 0.023 Uiso calc 1 . .
    C C20 0.8302(2) 0.92008(18) 0.45077(17) 0.0161(6) Uani d 1 . .
    C C21 0.9497(2) 0.87930(18) 0.55859(18) 0.0165(6) Uani d 1 . .
    C C22 0.9763(3) 0.8749(2) 0.63867(19) 0.0197(6) Uani d 1 . .
    H H22 0.9384 0.8965 0.6702 0.024 Uiso calc 1 . .
    C C23 1.0602(3) 0.8380(2) 0.67307(18) 0.0199(6) Uani d 1 . .
    C C24 1.1198(2) 0.80925(19) 0.62430(19) 0.0184(6) Uani d 1 . .
    C C25 1.0904(2) 0.81530(19) 0.54580(18) 0.0176(6) Uani d 1 . .
    H H25 1.1298 0.7958 0.5144 0.021 Uiso calc 1 . .
    C C26 1.0028(2) 0.84963(18) 0.50824(18) 0.0162(6) Uani d 1 . .
    C C27 0.6992(3) 0.9388(2) 0.20430(19) 0.0247(7) Uani d 1 . .
    H H27A 0.6194 0.9074 0.1845 0.037 Uiso calc 1 . .
    H H27B 0.7362 0.9131 0.1721 0.037 Uiso calc 1 . .
    H H27C 0.7097 0.9998 0.2000 0.037 Uiso calc 1 . .
    C C28 0.5860(3) 1.0536(2) 0.3772(2) 0.0274(7) Uani d 1 . .
    H H28A 0.5623 1.1010 0.3534 0.033 Uiso calc 1 . .
    H H28B 0.6460 1.0799 0.4294 0.033 Uiso calc 1 . .
    C C29 0.4883(3) 0.9934(3) 0.3916(2) 0.0370(8) Uani d 1 . .
    H H29A 0.4279 0.9679 0.3403 0.055 Uiso calc 1 . .
    H H29B 0.4622 1.0261 0.4273 0.055 Uiso calc 1 . .
    H H29C 0.5116 0.9471 0.4165 0.055 Uiso calc 1 . .
    C C30 1.2107(3) 0.7709(2) 0.66154(19) 0.0237(6) Uani d 1 . .
    H H30A 1.1791 0.7175 0.6785 0.036 Uiso calc 1 . .
    H H30B 1.2667 0.8126 0.7083 0.036 Uiso calc 1 . .
    H H30C 1.2456 0.7576 0.6222 0.036 Uiso calc 1 . .
    C C31 1.0241(3) 0.8437(2) 0.8027(2) 0.0274(7) Uani d 1 . .
    H H31A 1.0276 0.8029 0.8405 0.033 Uiso calc 1 . .
    H H31B 0.9449 0.8327 0.7703 0.033 Uiso calc 1 . .
    C C32 1.0702(3) 0.9362(3) 0.8502(2) 0.0417(10) Uani d 1 . .
    H H32A 1.0659 0.9768 0.8130 0.063 Uiso calc 1 . .
    H H32B 1.1481 0.9469 0.8835 0.063 Uiso calc 1 . .
    H H32C 1.0264 0.9444 0.8846 0.063 Uiso calc 1 . .
    C C33 0.8567(2) 0.5230(2) 0.54457(18) 0.0187(6) Uani d 1 . .
    C C34 0.9168(3) 0.5409(2) 0.62615(19) 0.0227(6) Uani d 1 . .
    H H34 0.9621 0.5066 0.6490 0.027 Uiso calc 1 . .
    C C35 0.9084(3) 0.6107(2) 0.67284(19) 0.0248(7) Uani d 1 . .
    H H35 0.9486 0.6255 0.7288 0.030 Uiso calc 1 . .
    C C36 0.8404(3) 0.6590(2) 0.63714(19) 0.0219(6) Uani d 1 . .
    H H36 0.8310 0.7054 0.6688 0.026 Uiso calc 1 . .
    C C37 0.7867(2) 0.63832(19) 0.55459(18) 0.0176(6) Uani d 1 . .
    C C38 0.7173(2) 0.68845(19) 0.51310(18) 0.0180(6) Uani d 1 . .
    H H38 0.7020 0.7343 0.5410 0.022 Uiso calc 1 . .
    C C39 0.5910(2) 0.67350(18) 0.31311(18) 0.0167(6) Uani d 1 . .
    C C40 0.5215(2) 0.70879(19) 0.24975(18) 0.0168(6) Uani d 1 . .
    C C41 0.4829(3) 0.7775(2) 0.26929(19) 0.0207(6) Uani d 1 . .
    H H41 0.5020 0.8033 0.3239 0.025 Uiso calc 1 . .
    C C42 0.4165(3) 0.8085(2) 0.2092(2) 0.0250(7) Uani d 1 . .
    H H42 0.3900 0.8552 0.2228 0.030 Uiso calc 1 . .
    C C43 0.3891(3) 0.7710(2) 0.1291(2) 0.0269(7) Uani d 1 . .
    H H43 0.3439 0.7923 0.0881 0.032 Uiso calc 1 . .
    C C44 0.4273(3) 0.7030(2) 0.1089(2) 0.0238(6) Uani d 1 . .
    H H44 0.4081 0.6775 0.0541 0.029 Uiso calc 1 . .
    C C45 0.4940(2) 0.67149(19) 0.16883(18) 0.0175(6) Uani d 1 . .
    C C46 0.5309(2) 0.59787(19) 0.14141(17) 0.0176(6) Uani d 1 . .
    C C47 0.6287(2) 0.61252(19) 0.12226(17) 0.0175(6) Uani d 1 . .
    C C48 0.7065(3) 0.69576(19) 0.13478(17) 0.0174(6) Uani d 1 . .
    H H48 0.6891 0.7454 0.1537 0.021 Uiso calc 1 . .
    C C49 0.8046(3) 0.7073(2) 0.12085(18) 0.0194(6) Uani d 1 . .
    C C50 0.8330(3) 0.6318(2) 0.09377(19) 0.0223(6) Uani d 1 . .
    C C51 0.7569(3) 0.5487(2) 0.07965(18) 0.0220(6) Uani d 1 . .
    H H51 0.7740 0.4986 0.0612 0.026 Uiso calc 1 . .
    C C52 0.6584(3) 0.54092(19) 0.09271(17) 0.0192(6) Uani d 1 . .
    C C53 0.4918(3) 0.4434(2) 0.09308(17) 0.0199(6) Uani d 1 . .
    C C54 0.4281(3) 0.3575(2) 0.07636(18) 0.0224(6) Uani d 1 . .
    H H54 0.4499 0.3138 0.0511 0.027 Uiso calc 1 . .
    C C55 0.3322(3) 0.3356(2) 0.09668(19) 0.0261(7) Uani d 1 . .
    C C56 0.3003(3) 0.4027(2) 0.1351(2) 0.0262(7) Uani d 1 . .
    C C57 0.3634(3) 0.4871(2) 0.14754(19) 0.0224(6) Uani d 1 . .
    H H57 0.3404 0.5312 0.1708 0.027 Uiso calc 1 . .
    C C58 0.4612(3) 0.5114(2) 0.12723(18) 0.0193(6) Uani d 1 . .
    C C59 0.8856(3) 0.7957(2) 0.13296(19) 0.0213(6) Uani d 1 . .
    H H59A 0.8517 0.8404 0.1448 0.032 Uiso calc 1 . .
    H H59B 0.9042 0.8021 0.0841 0.032 Uiso calc 1 . .
    H H59C 0.9535 0.8021 0.1779 0.032 Uiso calc 1 . .
    C C60 0.9727(4) 0.5729(3) 0.0605(3) 0.0443(10) Uani d 1 . .
    H H60A 1.0280 0.5938 0.0340 0.053 Uiso calc 1 . .
    H H60B 0.9102 0.5255 0.0217 0.053 Uiso calc 1 . .
    C C61 1.0244(5) 0.5392(4) 0.1303(3) 0.0655(15) Uani d 1 . .
    H H61A 1.0292 0.4816 0.1126 0.098 Uiso calc 1 . .
    H H61B 0.9792 0.5349 0.1655 0.098 Uiso calc 1 . .
    H H61C 1.0993 0.5785 0.1596 0.098 Uiso calc 1 . .
    C C62 0.1995(3) 0.3777(3) 0.1602(3) 0.0380(9) Uani d 1 . .
    H H62A 0.1909 0.4297 0.1876 0.057 Uiso calc 1 . .
    H H62B 0.2083 0.3368 0.1966 0.057 Uiso calc 1 . .
    H H62C 0.1333 0.3505 0.1126 0.057 Uiso calc 1 . .
    C C63 0.2975(4) 0.1796(2) 0.0496(2) 0.0368(9) Uani d 1 . .
    H H63A 0.3696 0.1777 0.0863 0.044 Uiso calc 1 . .
    H H63B 0.3060 0.1873 -0.0029 0.044 Uiso calc 1 . .
    C C64 0.2081(4) 0.0951(3) 0.0392(3) 0.0481(12) Uani d 1 . .
    H H64A 0.1362 0.0980 0.0046 0.072 Uiso calc 1 . .
    H H64B 0.2032 0.0858 0.0917 0.072 Uiso calc 1 . .
    H H64C 0.2271 0.0470 0.0146 0.072 Uiso calc 1 . .
    C C65 1.1436(4) 0.8792(3) 0.0891(3) 0.0434(10) Uani d 1 . .
    H H65A 1.1092 0.9032 0.0431 0.065 Uiso calc 1 . .
    H H65B 1.2244 0.8965 0.1013 0.065 Uiso calc 1 . .
    H H65C 1.1266 0.9014 0.1358 0.065 Uiso calc 1 . .
    C C66 0.4824(7) 1.0272(5) 0.0938(3) 0.086(2) Uani d 1 . .
    H H66A 0.4045 0.9954 0.0628 0.128 Uiso calc 1 . .
    H H66B 0.5304 0.9927 0.0852 0.128 Uiso calc 1 . .
    H H66C 0.5032 1.0825 0.0764 0.128 Uiso calc 1 . .
    C C67 0.3882(5) 0.6714(4) 0.4391(4) 0.0669(16) Uani d 1 . .
    H H67A 0.3794 0.6339 0.4787 0.080 Uiso calc 1 . .
    H H67B 0.4662 0.6848 0.4401 0.080 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Co1 N1 . 2.187(3) ?
    Co1 N2 . 2.043(2) ?
    Co1 N4 . 2.209(2) ?
    Co1 N5 . 2.045(2) ?
    Co1 O1 . 2.068(2) ?
    Co1 O2 . 2.040(2) ?
    Br1 C1 . 1.894(3) ?
    Br2 C33 . 1.887(3) ?
    N1 C1 . 1.323(4) ?
    N1 C5 . 1.364(4) ?
    N2 N3 . 1.371(3) ?
    N2 C6 . 1.283(4) ?
    N3 C7 . 1.336(4) ?
    N4 C33 . 1.335(4) ?
    N4 C37 . 1.367(4) ?
    N5 N6 . 1.376(4) ?
    N5 C38 . 1.286(4) ?
    N6 C39 . 1.337(4) ?
    N7 H7 . 0.8800 ?
    N7 C23 . 1.345(4) ?
    N7 C31 . 1.458(4) ?
    N8 H8 . 0.8800 ?
    N8 C18 . 1.347(4) ?
    N8 C28 . 1.455(4) ?
    N9 H9 . 0.8800 ?
    N9 C55 . 1.358(4) ?
    N9 C63 . 1.447(5) ?
    N10 H10 . 0.8800 ?
    N10 C50 . 1.343(4) ?
    N10 C60 . 1.454(4) ?
    O1 C7 . 1.273(4) ?
    O2 C39 . 1.270(4) ?
    O3 C20 . 1.361(4) ?
    O3 C21 . 1.365(4) ?
    O4 C52 . 1.364(4) ?
    O4 C53 . 1.360(4) ?
    O5 H5 . 0.8400 ?
    O5 C65 . 1.401(5) ?
    O6 H6A . 0.8400 ?
    O6 C66 . 1.405(6) ?
    Cl1 C67 . 1.743(6) ?
    Cl2 C67 . 1.779(7) ?
    B1 F1 . 1.344(9) ?
    B1 F2 . 1.512(9) ?
    B1 F4 . 1.360(8) ?
    B1 F1A . 1.407(14) ?
    B1 F2A . 1.236(9) ?
    B1 F4A . 1.353(13) ?
    B1 F3 . 1.367(5) ?
    B2 F5 . 1.366(6) ?
    B2 F6 . 1.401(5) ?
    B2 F7 . 1.395(5) ?
    B2 F8 . 1.370(5) ?
    C1 C2 . 1.387(5) ?
    C2 H2 . 0.9500 ?
    C2 C3 . 1.377(5) ?
    C3 H3 . 0.9500 ?
    C3 C4 . 1.389(5) ?
    C4 H4 . 0.9500 ?
    C4 C5 . 1.392(4) ?
    C5 C6 . 1.462(4) ?
    C6 H6 . 0.9500 ?
    C7 C8 . 1.487(4) ?
    C8 C9 . 1.393(4) ?
    C8 C13 . 1.414(4) ?
    C9 H9A . 0.9500 ?
    C9 C10 . 1.388(4) ?
    C10 H10A . 0.9500 ?
    C10 C11 . 1.389(5) ?
    C11 H11 . 0.9500 ?
    C11 C12 . 1.392(4) ?
    C12 H12 . 0.9500 ?
    C12 C13 . 1.396(4) ?
    C13 C14 . 1.494(4) ?
    C14 C15 . 1.404(4) ?
    C14 C26 . 1.412(4) ?
    C15 C16 . 1.432(4) ?
    C15 C20 . 1.416(4) ?
    C16 H16 . 0.9500 ?
    C16 C17 . 1.361(4) ?
    C17 C18 . 1.441(4) ?
    C17 C27 . 1.500(4) ?
    C18 C19 . 1.407(4) ?
    C19 H19 . 0.9500 ?
    C19 C20 . 1.372(4) ?
    C21 C22 . 1.376(4) ?
    C21 C26 . 1.407(4) ?
    C22 H22 . 0.9500 ?
    C22 C23 . 1.401(4) ?
    C23 C24 . 1.448(4) ?
    C24 C25 . 1.355(4) ?
    C24 C30 . 1.501(4) ?
    C25 H25 . 0.9500 ?
    C25 C26 . 1.426(4) ?
    C27 H27A . 0.9800 ?
    C27 H27B . 0.9800 ?
    C27 H27C . 0.9800 ?
    C28 H28A . 0.9900 ?
    C28 H28B . 0.9900 ?
    C28 C29 . 1.512(5) ?
    C29 H29A . 0.9800 ?
    C29 H29B . 0.9800 ?
    C29 H29C . 0.9800 ?
    C30 H30A . 0.9800 ?
    C30 H30B . 0.9800 ?
    C30 H30C . 0.9800 ?
    C31 H31A . 0.9900 ?
    C31 H31B . 0.9900 ?
    C31 C32 . 1.521(5) ?
    C32 H32A . 0.9800 ?
    C32 H32B . 0.9800 ?
    C32 H32C . 0.9800 ?
    C33 C34 . 1.390(4) ?
    C34 H34 . 0.9500 ?
    C34 C35 . 1.383(5) ?
    C35 H35 . 0.9500 ?
    C35 C36 . 1.393(5) ?
    C36 H36 . 0.9500 ?
    C36 C37 . 1.389(4) ?
    C37 C38 . 1.463(4) ?
    C38 H38 . 0.9500 ?
    C39 C40 . 1.491(4) ?
    C40 C41 . 1.393(4) ?
    C40 C45 . 1.404(4) ?
    C41 H41 . 0.9500 ?
    C41 C42 . 1.393(5) ?
    C42 H42 . 0.9500 ?
    C42 C43 . 1.391(5) ?
    C43 H43 . 0.9500 ?
    C43 C44 . 1.384(5) ?
    C44 H44 . 0.9500 ?
    C44 C45 . 1.397(4) ?
    C45 C46 . 1.491(4) ?
    C46 C47 . 1.399(4) ?
    C46 C58 . 1.420(4) ?
    C47 C48 . 1.424(4) ?
    C47 C52 . 1.418(4) ?
    C48 H48 . 0.9500 ?
    C48 C49 . 1.359(4) ?
    C49 C50 . 1.447(4) ?
    C49 C59 . 1.506(4) ?
    C50 C51 . 1.409(5) ?
    C51 H51 . 0.9500 ?
    C51 C52 . 1.363(5) ?
    C53 C54 . 1.383(4) ?
    C53 C58 . 1.409(4) ?
    C54 H54 . 0.9500 ?
    C54 C55 . 1.387(5) ?
    C55 C56 . 1.444(5) ?
    C56 C57 . 1.367(5) ?
    C56 C62 . 1.499(5) ?
    C57 H57 . 0.9500 ?
    C57 C58 . 1.414(5) ?
    C59 H59A . 0.9800 ?
    C59 H59B . 0.9800 ?
    C59 H59C . 0.9800 ?
    C60 H60A . 0.9900 ?
    C60 H60B . 0.9900 ?
    C60 C61 . 1.458(7) ?
    C61 H61A . 0.9800 ?
    C61 H61B . 0.9800 ?
    C61 H61C . 0.9800 ?
    C62 H62A . 0.9800 ?
    C62 H62B . 0.9800 ?
    C62 H62C . 0.9800 ?
    C63 H63A . 0.9900 ?
    C63 H63B . 0.9900 ?
    C63 C64 . 1.518(5) ?
    C64 H64A . 0.9800 ?
    C64 H64B . 0.9800 ?
    C64 H64C . 0.9800 ?
    C65 H65A . 0.9800 ?
    C65 H65B . 0.9800 ?
    C65 H65C . 0.9800 ?
    C66 H66A . 0.9800 ?
    C66 H66B . 0.9800 ?
    C66 H66C . 0.9800 ?
    C67 H67A . 0.9900 ?
    C67 H67B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N1 Co1 N4 . . 98.15(9) ?
    N2 Co1 N1 . . 75.81(10) ?
    N2 Co1 N4 . . 114.92(10) ?
    N2 Co1 N5 . . 159.69(10) ?
    N2 Co1 O1 . . 75.69(9) ?
    N5 Co1 N1 . . 121.20(10) ?
    N5 Co1 N4 . . 75.84(10) ?
    N5 Co1 O1 . . 87.12(9) ?
    O1 Co1 N1 . . 151.44(9) ?
    O1 Co1 N4 . . 92.07(9) ?
    O2 Co1 N1 . . 86.02(9) ?
    O2 Co1 N2 . . 96.67(9) ?
    O2 Co1 N4 . . 148.25(9) ?
    O2 Co1 N5 . . 75.17(9) ?
    O2 Co1 O1 . . 99.14(9) ?
    C1 N1 Co1 . . 131.1(2) ?
    C1 N1 C5 . . 116.5(3) ?
    C5 N1 Co1 . . 112.28(19) ?
    N3 N2 Co1 . . 118.11(18) ?
    C6 N2 Co1 . . 120.6(2) ?
    C6 N2 N3 . . 120.5(2) ?
    C7 N3 N2 . . 107.9(2) ?
    C33 N4 Co1 . . 131.2(2) ?
    C33 N4 C37 . . 116.9(3) ?
    C37 N4 Co1 . . 110.16(19) ?
    N6 N5 Co1 . . 118.14(18) ?
    C38 N5 Co1 . . 119.7(2) ?
    C38 N5 N6 . . 121.2(3) ?
    C39 N6 N5 . . 107.0(2) ?
    C23 N7 H7 . . 117.5 ?
    C23 N7 C31 . . 125.0(3) ?
    C31 N7 H7 . . 117.5 ?
    C18 N8 H8 . . 117.5 ?
    C18 N8 C28 . . 124.9(3) ?
    C28 N8 H8 . . 117.5 ?
    C55 N9 H9 . . 118.5 ?
    C55 N9 C63 . . 123.0(3) ?
    C63 N9 H9 . . 118.5 ?
    C50 N10 H10 . . 118.1 ?
    C50 N10 C60 . . 123.8(3) ?
    C60 N10 H10 . . 118.1 ?
    C7 O1 Co1 . . 111.58(18) ?
    C39 O2 Co1 . . 112.79(18) ?
    C20 O3 C21 . . 120.3(2) ?
    C53 O4 C52 . . 120.2(2) ?
    C65 O5 H5 . . 109.5 ?
    C66 O6 H6A . . 109.5 ?
    F1 B1 F2 . . 103.6(6) ?
    F1 B1 F4 . . 105.1(7) ?
    F1 B1 F3 . . 117.8(6) ?
    F4 B1 F2 . . 103.8(6) ?
    F4 B1 F3 . . 115.6(5) ?
    F2A B1 F1A . . 110.0(10) ?
    F2A B1 F4A . . 124.6(10) ?
    F2A B1 F3 . . 108.8(5) ?
    F4A B1 F1A . . 103.7(8) ?
    F4A B1 F3 . . 104.1(7) ?
    F3 B1 F2 . . 109.4(4) ?
    F3 B1 F1A . . 103.7(10) ?
    F5 B2 F6 . . 108.7(4) ?
    F5 B2 F7 . . 109.3(4) ?
    F5 B2 F8 . . 111.6(4) ?
    F7 B2 F6 . . 107.7(3) ?
    F8 B2 F6 . . 110.1(3) ?
    F8 B2 F7 . . 109.3(3) ?
    N1 C1 Br1 . . 116.0(2) ?
    N1 C1 C2 . . 125.7(3) ?
    C2 C1 Br1 . . 118.3(2) ?
    C1 C2 H2 . . 121.5 ?
    C3 C2 C1 . . 117.1(3) ?
    C3 C2 H2 . . 121.5 ?
    C2 C3 H3 . . 120.2 ?
    C2 C3 C4 . . 119.5(3) ?
    C4 C3 H3 . . 120.2 ?
    C3 C4 H4 . . 120.5 ?
    C3 C4 C5 . . 119.0(3) ?
    C5 C4 H4 . . 120.5 ?
    N1 C5 C4 . . 122.1(3) ?
    N1 C5 C6 . . 115.6(3) ?
    C4 C5 C6 . . 122.3(3) ?
    N2 C6 C5 . . 115.3(3) ?
    N2 C6 H6 . . 122.4 ?
    C5 C6 H6 . . 122.4 ?
    N3 C7 C8 . . 116.1(3) ?
    O1 C7 N3 . . 126.0(3) ?
    O1 C7 C8 . . 117.9(3) ?
    C9 C8 C7 . . 120.0(3) ?
    C9 C8 C13 . . 119.2(3) ?
    C13 C8 C7 . . 120.7(3) ?
    C8 C9 H9A . . 119.3 ?
    C10 C9 C8 . . 121.5(3) ?
    C10 C9 H9A . . 119.3 ?
    C9 C10 H10A . . 120.3 ?
    C9 C10 C11 . . 119.4(3) ?
    C11 C10 H10A . . 120.3 ?
    C10 C11 H11 . . 120.0 ?
    C10 C11 C12 . . 120.0(3) ?
    C12 C11 H11 . . 120.0 ?
    C11 C12 H12 . . 119.4 ?
    C11 C12 C13 . . 121.1(3) ?
    C13 C12 H12 . . 119.4 ?
    C8 C13 C14 . . 124.2(3) ?
    C12 C13 C8 . . 118.8(3) ?
    C12 C13 C14 . . 117.0(3) ?
    C15 C14 C13 . . 121.5(3) ?
    C15 C14 C26 . . 118.4(3) ?
    C26 C14 C13 . . 119.7(3) ?
    C14 C15 C16 . . 124.8(3) ?
    C14 C15 C20 . . 119.7(3) ?
    C20 C15 C16 . . 115.5(3) ?
    C15 C16 H16 . . 118.6 ?
    C17 C16 C15 . . 122.8(3) ?
    C17 C16 H16 . . 118.6 ?
    C16 C17 C18 . . 119.4(3) ?
    C16 C17 C27 . . 122.2(3) ?
    C18 C17 C27 . . 118.4(3) ?
    N8 C18 C17 . . 119.2(3) ?
    N8 C18 C19 . . 121.7(3) ?
    C19 C18 C17 . . 119.1(3) ?
    C18 C19 H19 . . 120.3 ?
    C20 C19 C18 . . 119.3(3) ?
    C20 C19 H19 . . 120.3 ?
    O3 C20 C15 . . 120.9(3) ?
    O3 C20 C19 . . 115.5(3) ?
    C19 C20 C15 . . 123.7(3) ?
    O3 C21 C22 . . 115.1(3) ?
    O3 C21 C26 . . 121.0(3) ?
    C22 C21 C26 . . 123.9(3) ?
    C21 C22 H22 . . 120.5 ?
    C21 C22 C23 . . 119.0(3) ?
    C23 C22 H22 . . 120.5 ?
    N7 C23 C22 . . 121.8(3) ?
    N7 C23 C24 . . 119.1(3) ?
    C22 C23 C24 . . 119.1(3) ?
    C23 C24 C30 . . 119.0(3) ?
    C25 C24 C23 . . 119.5(3) ?
    C25 C24 C30 . . 121.5(3) ?
    C24 C25 H25 . . 118.6 ?
    C24 C25 C26 . . 122.8(3) ?
    C26 C25 H25 . . 118.6 ?
    C14 C26 C25 . . 124.6(3) ?
    C21 C26 C14 . . 119.7(3) ?
    C21 C26 C25 . . 115.7(3) ?
    C17 C27 H27A . . 109.5 ?
    C17 C27 H27B . . 109.5 ?
    C17 C27 H27C . . 109.5 ?
    H27A C27 H27B . . 109.5 ?
    H27A C27 H27C . . 109.5 ?
    H27B C27 H27C . . 109.5 ?
    N8 C28 H28A . . 109.0 ?
    N8 C28 H28B . . 109.0 ?
    N8 C28 C29 . . 113.1(3) ?
    H28A C28 H28B . . 107.8 ?
    C29 C28 H28A . . 109.0 ?
    C29 C28 H28B . . 109.0 ?
    C28 C29 H29A . . 109.5 ?
    C28 C29 H29B . . 109.5 ?
    C28 C29 H29C . . 109.5 ?
    H29A C29 H29B . . 109.5 ?
    H29A C29 H29C . . 109.5 ?
    H29B C29 H29C . . 109.5 ?
    C24 C30 H30A . . 109.5 ?
    C24 C30 H30B . . 109.5 ?
    C24 C30 H30C . . 109.5 ?
    H30A C30 H30B . . 109.5 ?
    H30A C30 H30C . . 109.5 ?
    H30B C30 H30C . . 109.5 ?
    N7 C31 H31A . . 109.1 ?
    N7 C31 H31B . . 109.1 ?
    N7 C31 C32 . . 112.6(3) ?
    H31A C31 H31B . . 107.8 ?
    C32 C31 H31A . . 109.1 ?
    C32 C31 H31B . . 109.1 ?
    C31 C32 H32A . . 109.5 ?
    C31 C32 H32B . . 109.5 ?
    C31 C32 H32C . . 109.5 ?
    H32A C32 H32B . . 109.5 ?
    H32A C32 H32C . . 109.5 ?
    H32B C32 H32C . . 109.5 ?
    N4 C33 Br2 . . 116.9(2) ?
    N4 C33 C34 . . 124.8(3) ?
    C34 C33 Br2 . . 118.3(2) ?
    C33 C34 H34 . . 121.3 ?
    C35 C34 C33 . . 117.5(3) ?
    C35 C34 H34 . . 121.3 ?
    C34 C35 H35 . . 120.2 ?
    C34 C35 C36 . . 119.5(3) ?
    C36 C35 H35 . . 120.2 ?
    C35 C36 H36 . . 120.5 ?
    C37 C36 C35 . . 119.0(3) ?
    C37 C36 H36 . . 120.5 ?
    N4 C37 C36 . . 122.2(3) ?
    N4 C37 C38 . . 116.1(3) ?
    C36 C37 C38 . . 121.7(3) ?
    N5 C38 C37 . . 115.3(3) ?
    N5 C38 H38 . . 122.4 ?
    C37 C38 H38 . . 122.4 ?
    N6 C39 C40 . . 117.9(3) ?
    O2 C39 N6 . . 125.5(3) ?
    O2 C39 C40 . . 116.6(3) ?
    C41 C40 C39 . . 121.3(3) ?
    C41 C40 C45 . . 119.5(3) ?
    C45 C40 C39 . . 119.1(3) ?
    C40 C41 H41 . . 119.8 ?
    C40 C41 C42 . . 120.4(3) ?
    C42 C41 H41 . . 119.8 ?
    C41 C42 H42 . . 120.1 ?
    C43 C42 C41 . . 119.8(3) ?
    C43 C42 H42 . . 120.1 ?
    C42 C43 H43 . . 119.8 ?
    C44 C43 C42 . . 120.3(3) ?
    C44 C43 H43 . . 119.8 ?
    C43 C44 H44 . . 119.9 ?
    C43 C44 C45 . . 120.2(3) ?
    C45 C44 H44 . . 119.9 ?
    C40 C45 C46 . . 123.9(3) ?
    C44 C45 C40 . . 119.7(3) ?
    C44 C45 C46 . . 116.4(3) ?
    C47 C46 C45 . . 121.1(3) ?
    C47 C46 C58 . . 118.8(3) ?
    C58 C46 C45 . . 119.9(3) ?
    C46 C47 C48 . . 124.3(3) ?
    C46 C47 C52 . . 119.5(3) ?
    C52 C47 C48 . . 116.0(3) ?
    C47 C48 H48 . . 118.5 ?
    C49 C48 C47 . . 122.9(3) ?
    C49 C48 H48 . . 118.5 ?
    C48 C49 C50 . . 118.9(3) ?
    C48 C49 C59 . . 122.6(3) ?
    C50 C49 C59 . . 118.6(3) ?
    N10 C50 C49 . . 118.6(3) ?
    N10 C50 C51 . . 121.9(3) ?
    C51 C50 C49 . . 119.5(3) ?
    C50 C51 H51 . . 120.4 ?
    C52 C51 C50 . . 119.2(3) ?
    C52 C51 H51 . . 120.4 ?
    O4 C52 C47 . . 120.8(3) ?
    C51 C52 O4 . . 115.8(3) ?
    C51 C52 C47 . . 123.4(3) ?
    O4 C53 C54 . . 115.8(3) ?
    O4 C53 C58 . . 121.5(3) ?
    C54 C53 C58 . . 122.8(3) ?
    C53 C54 H54 . . 120.2 ?
    C53 C54 C55 . . 119.5(3) ?
    C55 C54 H54 . . 120.2 ?
    N9 C55 C54 . . 121.4(3) ?
    N9 C55 C56 . . 118.9(3) ?
    C54 C55 C56 . . 119.6(3) ?
    C55 C56 C62 . . 119.1(3) ?
    C57 C56 C55 . . 118.8(3) ?
    C57 C56 C62 . . 122.1(3) ?
    C56 C57 H57 . . 118.6 ?
    C56 C57 C58 . . 122.8(3) ?
    C58 C57 H57 . . 118.6 ?
    C53 C58 C46 . . 119.0(3) ?
    C53 C58 C57 . . 116.4(3) ?
    C57 C58 C46 . . 124.6(3) ?
    C49 C59 H59A . . 109.5 ?
    C49 C59 H59B . . 109.5 ?
    C49 C59 H59C . . 109.5 ?
    H59A C59 H59B . . 109.5 ?
    H59A C59 H59C . . 109.5 ?
    H59B C59 H59C . . 109.5 ?
    N10 C60 H60A . . 109.2 ?
    N10 C60 H60B . . 109.2 ?
    N10 C60 C61 . . 111.9(4) ?
    H60A C60 H60B . . 107.9 ?
    C61 C60 H60A . . 109.2 ?
    C61 C60 H60B . . 109.2 ?
    C60 C61 H61A . . 109.5 ?
    C60 C61 H61B . . 109.5 ?
    C60 C61 H61C . . 109.5 ?
    H61A C61 H61B . . 109.5 ?
    H61A C61 H61C . . 109.5 ?
    H61B C61 H61C . . 109.5 ?
    C56 C62 H62A . . 109.5 ?
    C56 C62 H62B . . 109.5 ?
    C56 C62 H62C . . 109.5 ?
    H62A C62 H62B . . 109.5 ?
    H62A C62 H62C . . 109.5 ?
    H62B C62 H62C . . 109.5 ?
    N9 C63 H63A . . 109.6 ?
    N9 C63 H63B . . 109.6 ?
    N9 C63 C64 . . 110.2(4) ?
    H63A C63 H63B . . 108.1 ?
    C64 C63 H63A . . 109.6 ?
    C64 C63 H63B . . 109.6 ?
    C63 C64 H64A . . 109.5 ?
    C63 C64 H64B . . 109.5 ?
    C63 C64 H64C . . 109.5 ?
    H64A C64 H64B . . 109.5 ?
    H64A C64 H64C . . 109.5 ?
    H64B C64 H64C . . 109.5 ?
    O5 C65 H65A . . 109.5 ?
    O5 C65 H65B . . 109.5 ?
    O5 C65 H65C . . 109.5 ?
    H65A C65 H65B . . 109.5 ?
    H65A C65 H65C . . 109.5 ?
    H65B C65 H65C . . 109.5 ?
    O6 C66 H66A . . 109.5 ?
    O6 C66 H66B . . 109.5 ?
    O6 C66 H66C . . 109.5 ?
    H66A C66 H66B . . 109.5 ?
    H66A C66 H66C . . 109.5 ?
    H66B C66 H66C . . 109.5 ?
    Cl1 C67 Cl2 . . 111.8(3) ?
    Cl1 C67 H67A . . 109.3 ?
    Cl1 C67 H67B . . 109.3 ?
    Cl2 C67 H67A . . 109.3 ?
    Cl2 C67 H67B . . 109.3 ?
    H67A C67 H67B . . 107.9 ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    N7 H7 F3 . 0.88 2.25 2.903(4) 130.4
    N8 H8 O6 . 0.88 2.10 2.900(4) 150.6
    N10 H10 O5 . 0.88 2.07 2.882(4) 152.7
    O5 H5 F4 1_554 0.84 2.22 2.897(11) 137.4
    O5 H5 F1A 1_554 0.84 1.99 2.762(10) 152.5
    O6 H6A F6 . 0.84 2.06 2.809(4) 148.7
    C2 H2 F7 1_545 0.95 2.43 3.142(4) 132.0
    C4 H4 F2 2_766 0.95 2.40 3.275(6) 152.9
    C6 H6 F3 2_766 0.95 2.50 3.323(4) 145.6
    C12 H12 O3 2_776 0.95 2.46 3.379(4) 161.5
    C22 H22 F8 2_676 0.95 2.52 3.466(4) 179.0
    C31 H31B F7 2_676 0.99 2.43 3.302(4) 147.1
    C44 H44 F2 1_454 0.95 2.46 3.177(6) 132.7
    C67 H67B N6 . 0.99 2.34 3.277(6) 157.8
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
data_global
_journal_data_validation_number     ?
_journal_date_recd_electronic     2018-08-28
_journal_date_accepted     2018-11-02
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2018
_journal_volume     74
_journal_issue     12
_journal_page_first               1622
_journal_page_last                1628
_journal_paper_category     FA
_journal_paper_doi     10.1107/S2053229618015541
_journal_coeditor_code     CU3135
loop_
    _publ_contact_author_name
    _publ_contact_author_address
    _publ_contact_author_email
    'Juan Yuan'
;
School of Pharmacy
Henan University of Chinese Medicine
Zhengzhou
Henan Province 450046
People's Republic of China
Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China, Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China
;
 hnzz_yuan@163.com
    'Hui-Zhong Kou'
;
Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China, Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China
;
 kouhz@tsinghua.edu.cn
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;
Two new cobalt(II) rhodamine 6G hydrazone complexes: structure, fluorescence and
magnetism
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Juan Yuan' .
;
School of Pharmacy
Henan University of Chinese Medicine
Zhengzhou
Henan Province 450046
People's Republic of China
Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China
;
    'Xia Wang' .
;
School of Pharmacy
Henan University of Chinese Medicine
Zhengzhou
Henan Province 450046
People's Republic of China
;
    'Nan Zhang' .
;
Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China
;
    'Mei-Jiao Liu' .
;
Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China
;
    'Hui-Zhong Kou' .
;
Department of Chemistry
Tsinghua Univiersity
Beijing 100084
People's Republic of China
;
_publ_section_synopsis
;
Rhodamine 6G-labelled hydrozone CoII complexes with an N₄O₂ donor set
show intermolecular π--π stacking interactions between xanthene moieties to
form a supramolecular one-dimensional chain structure. The ring-opened
rhodamine 6G ligands are responsible for the green fluorescence in ethanol,
and the temperature-dependent magnetic susceptibilities of the complexes are
dominated by the structural distortion and spin-orbit coupling of CoII.
;
