##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section C. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section C, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_database_code_depnum_ccdc_archive 'CCDC 1836379'
_audit_creation_method     'SHELXL-2014/7'
_chemical_name_systematic
;
(2,2'-Biquinoline-κ²N,N')(carbamoylcyanonitrosomethanide-\
κ²N,O)chloridocopper(II) acetonitrile monosolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C21 H14 Cl Cu N5 O2, C2 H3 N'
_chemical_formula_sum     'C23 H17 Cl N6 O2'
_chemical_formula_iupac     '[Cu (C3 H2 N3 O2) Cl (C18 H12 N2)], C2 H3 N'
_chemical_formula_weight     508.42
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/c'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     11.82030(10)
_cell_length_b     9.12760(10)
_cell_length_c     21.15750(10)
_cell_angle_alpha     90
_cell_angle_beta     100.4680(10)
_cell_angle_gamma     90
_cell_volume     2244.71(3)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     21847
_cell_measurement_theta_min     4.2330
_cell_measurement_theta_max     67.6560
_cell_measurement_temperature     120(2)
_exptl_crystal_description     plate
_exptl_crystal_colour     'dark green'
_exptl_crystal_size_max     0.306
_exptl_crystal_size_mid     0.111
_exptl_crystal_size_min     0.028
_exptl_crystal_density_diffrn     1.504
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1036
_exptl_absorpt_coefficient_mu     2.750
_exptl_absorpt_correction_type     analytical
_exptl_absorpt_process_details
;
[CrysAlis PRO (Rigaku OD, 2017), based on expressions
derived by Clark & Reid (1995)]
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
_exptl_absorpt_correction_T_min     0.593
_exptl_absorpt_correction_T_max     0.927
_diffrn_ambient_temperature     120(2)
_diffrn_radiation_type     CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_measurement_device_type     'Rigaku Xcalibur AtlasS2 Gemini ultra'
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     5.1783
_diffrn_reflns_number     40629
_diffrn_reflns_av_R_equivalents     0.0301
_diffrn_reflns_theta_min     3.803
_diffrn_reflns_theta_max     67.586
_diffrn_reflns_theta_full     67.586
_diffrn_measured_fraction_theta_max     0.998
_diffrn_measured_fraction_theta_full     0.998
_diffrn_reflns_limit_h_min     -14
_diffrn_reflns_limit_h_max     14
_diffrn_reflns_limit_k_min     -10
_diffrn_reflns_limit_k_max     10
_diffrn_reflns_limit_l_min     -25
_diffrn_reflns_limit_l_max     25
_refine_special_details     ?
_reflns_number_total     4034
_reflns_number_gt     3765
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0259
_refine_ls_R_factor_gt     0.0237
_refine_ls_wR_factor_gt     0.0641
_refine_ls_wR_factor_ref     0.0656
_refine_ls_goodness_of_fit_ref     1.051
_refine_ls_restrained_S_all     1.051
_refine_ls_number_reflns     4034
_refine_ls_number_parameters     318
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0332P)²+1.4117P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.002
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.289
_refine_diff_density_min     -0.295
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0181 0.0091
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0311 0.0180
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0492 0.0322
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cu' 'Cu' -1.9646 0.5888
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.3639 0.7018
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015b) in WinGX (Farrugia, 2012)
;
_computing_molecular_graphics
;
DIAMOND (Brandenburg, 2009)
;
_computing_publication_material     ?
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Cu Cu1 0.84543(2) 0.67370(2) 0.62482(2) 0.01704(8) Uani d 1 . .
    Cl Cl1 0.98942(3) 0.52820(4) 0.67748(2) 0.02252(10) Uani d 1 . .
    O O2 0.74668(9) 0.61544(13) 0.68669(5) 0.0218(2) Uani d 1 . .
    O O1 0.74223(10) 0.96188(13) 0.58230(5) 0.0254(3) Uani d 1 . .
    N N20 0.94414(10) 0.75413(14) 0.56619(6) 0.0168(3) Uani d 1 . .
    N N10 0.77747(11) 0.55355(14) 0.53480(6) 0.0180(3) Uani d 1 . .
    N N1 0.74096(11) 0.85218(15) 0.61833(6) 0.0183(3) Uani d 1 . .
    N N2 0.59380(13) 0.67900(19) 0.73050(7) 0.0266(3) Uani d 1 . .
    N N3 0.51050(12) 1.04133(16) 0.66124(7) 0.0286(3) Uani d 1 . .
    C C21 0.93414(13) 0.69337(17) 0.50823(7) 0.0175(3) Uani d 1 . .
    C C22 1.02823(13) 0.85627(17) 0.58589(7) 0.0175(3) Uani d 1 . .
    C C27 1.10787(13) 0.89555(18) 0.54590(7) 0.0190(3) Uani d 1 . .
    N N4 0.37291(14) 0.82051(19) 0.74661(9) 0.0387(4) Uani d 1 . .
    C C1 0.66365(13) 0.84313(18) 0.65695(7) 0.0185(3) Uani d 1 . .
    C C12 0.69170(13) 0.45126(18) 0.52100(8) 0.0204(3) Uani d 1 . .
    C C11 0.83902(13) 0.58648(17) 0.48996(7) 0.0185(3) Uani d 1 . .
    C C2 0.66930(13) 0.70659(18) 0.69295(7) 0.0199(3) Uani d 1 . .
    C C17 0.66875(14) 0.37865(19) 0.46055(8) 0.0243(3) Uani d 1 . .
    C C29 1.01142(13) 0.72761(18) 0.46644(7) 0.0204(3) Uani d 1 . .
    H H29 1.0036 0.6819 0.4255 0.024 Uiso calc 1 . .
    C C3 0.58020(13) 0.95479(18) 0.65906(7) 0.0209(3) Uani d 1 . .
    C C28 1.09693(13) 0.82663(18) 0.48539(8) 0.0207(3) Uani d 1 . .
    H H28 1.1495 0.8494 0.4578 0.025 Uiso calc 1 . .
    C C23 1.03632(13) 0.92393(19) 0.64663(7) 0.0216(3) Uani d 1 . .
    H H23 0.9838 0.8980 0.6739 0.026 Uiso calc 1 . .
    C C26 1.19398(13) 1.00064(19) 0.56815(8) 0.0225(3) Uani d 1 . .
    H H26 1.2482 1.0268 0.5420 0.027 Uiso calc 1 . .
    C C24 1.11937(14) 1.0264(2) 0.66624(8) 0.0253(4) Uani d 1 . .
    H H24 1.1234 1.0726 0.7068 0.030 Uiso calc 1 . .
    C C19 0.81741(14) 0.5229(2) 0.42781(8) 0.0251(4) Uani d 1 . .
    H H19 0.8607 0.5522 0.3963 0.030 Uiso calc 1 . .
    C C25 1.19955(14) 1.0645(2) 0.62684(8) 0.0256(4) Uani d 1 . .
    H H25 1.2576 1.1350 0.6414 0.031 Uiso calc 1 . .
    C C13 0.62539(14) 0.41411(19) 0.56798(8) 0.0250(4) Uani d 1 . .
    H H13 0.6387 0.4627 0.6083 0.030 Uiso calc 1 . .
    C C4 0.29640(15) 0.7813(2) 0.76818(8) 0.0276(4) Uani d 1 . .
    C C5 0.19909(16) 0.7316(2) 0.79585(10) 0.0299(4) Uani d 1 . .
    C C18 0.73392(15) 0.4194(2) 0.41403(8) 0.0279(4) Uani d 1 . .
    H H18 0.7196 0.3745 0.3728 0.033 Uiso calc 1 . .
    C C16 0.58372(15) 0.2677(2) 0.45003(9) 0.0311(4) Uani d 1 . .
    H H16 0.5697 0.2168 0.4102 0.037 Uiso calc 1 . .
    C C14 0.54218(15) 0.3085(2) 0.55557(9) 0.0307(4) Uani d 1 . .
    H H14 0.4975 0.2854 0.5873 0.037 Uiso calc 1 . .
    C C15 0.52189(15) 0.2332(2) 0.49628(10) 0.0333(4) Uani d 1 . .
    H H15 0.4651 0.1585 0.4887 0.040 Uiso calc 1 . .
    H H2N2 0.5987(17) 0.600(3) 0.7498(10) 0.027(5) Uiso d 1 . .
    H H1N2 0.5418(19) 0.736(3) 0.7336(10) 0.034(6) Uiso d 1 . .
    H H1C5 0.2262(19) 0.673(3) 0.8336(11) 0.042(6) Uiso d 1 . .
    H H3C5 0.154(2) 0.816(3) 0.8048(11) 0.046(6) Uiso d 1 . .
    H H2C5 0.149(2) 0.667(3) 0.7654(12) 0.047(7) Uiso d 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Cu1 O2 . 1.9785(10) y
    Cu1 N20 . 1.9912(12) y
    Cu1 N1 . 2.0337(14) y
    Cu1 N10 . 2.2179(13) y
    Cu1 Cl1 . 2.2832(4) y
    O2 C2 . 1.261(2) y
    O1 N1 . 1.2602(17) y
    N20 C21 . 1.331(2) ?
    N20 C22 . 1.371(2) ?
    N10 C11 . 1.331(2) ?
    N10 C12 . 1.370(2) ?
    N1 C1 . 1.334(2) y
    N2 C2 . 1.322(2) y
    N2 H2N2 . 0.82(2) ?
    N2 H1N2 . 0.82(2) ?
    N3 C3 . 1.148(2) y
    C21 C29 . 1.417(2) ?
    C21 C11 . 1.486(2) ?
    C22 C23 . 1.413(2) ?
    C22 C27 . 1.421(2) ?
    C27 C28 . 1.411(2) ?
    C27 C26 . 1.416(2) ?
    N4 C4 . 1.142(2) ?
    C1 C3 . 1.425(2) y
    C1 C2 . 1.456(2) y
    C12 C13 . 1.414(2) ?
    C12 C17 . 1.422(2) ?
    C11 C19 . 1.418(2) ?
    C17 C18 . 1.406(3) ?
    C17 C16 . 1.416(2) ?
    C29 C28 . 1.361(2) ?
    C29 H29 . 0.9500 ?
    C28 H28 . 0.9500 ?
    C23 C24 . 1.365(2) ?
    C23 H23 . 0.9500 ?
    C26 C25 . 1.363(2) ?
    C26 H26 . 0.9500 ?
    C24 C25 . 1.415(2) ?
    C24 H24 . 0.9500 ?
    C19 C18 . 1.359(3) ?
    C19 H19 . 0.9500 ?
    C25 H25 . 0.9500 ?
    C13 C14 . 1.368(2) ?
    C13 H13 . 0.9500 ?
    C4 C5 . 1.455(3) ?
    C5 H1C5 . 0.97(2) ?
    C5 H3C5 . 0.98(2) ?
    C5 H2C5 . 0.99(2) ?
    C18 H18 . 0.9500 ?
    C16 C15 . 1.360(3) ?
    C16 H16 . 0.9500 ?
    C14 C15 . 1.412(3) ?
    C14 H14 . 0.9500 ?
    C15 H15 . 0.9500 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O2 Cu1 N20 . . 173.84(5) y
    O2 Cu1 N1 . . 80.56(5) y
    N20 Cu1 N1 . . 94.59(5) y
    O2 Cu1 N10 . . 105.67(5) y
    N20 Cu1 N10 . . 79.00(5) y
    N1 Cu1 N10 . . 102.55(5) y
    O2 Cu1 Cl1 . . 89.88(3) y
    N20 Cu1 Cl1 . . 92.82(4) y
    N1 Cu1 Cl1 . . 152.69(4) y
    N10 Cu1 Cl1 . . 104.66(4) y
    C2 O2 Cu1 . . 114.74(10) ?
    C21 N20 C22 . . 120.09(13) ?
    C21 N20 Cu1 . . 117.14(11) ?
    C22 N20 Cu1 . . 122.39(10) ?
    C11 N10 C12 . . 118.77(13) ?
    C11 N10 Cu1 . . 109.93(10) ?
    C12 N10 Cu1 . . 131.18(10) ?
    O1 N1 C1 . . 120.28(13) y
    O1 N1 Cu1 . . 127.12(10) ?
    C1 N1 Cu1 . . 112.58(10) ?
    C2 N2 H2N2 . . 118.1(14) ?
    C2 N2 H1N2 . . 121.6(15) ?
    H2N2 N2 H1N2 . . 120(2) ?
    N20 C21 C29 . . 121.57(15) ?
    N20 C21 C11 . . 116.71(13) ?
    C29 C21 C11 . . 121.72(14) ?
    N20 C22 C23 . . 119.94(13) ?
    N20 C22 C27 . . 120.83(14) ?
    C23 C22 C27 . . 119.23(14) ?
    C28 C27 C26 . . 123.07(14) ?
    C28 C27 C22 . . 117.79(15) ?
    C26 C27 C22 . . 119.14(14) ?
    N1 C1 C3 . . 122.00(14) y
    N1 C1 C2 . . 113.70(14) y
    C3 C1 C2 . . 124.21(14) y
    N10 C12 C13 . . 119.78(14) ?
    N10 C12 C17 . . 121.48(15) ?
    C13 C12 C17 . . 118.73(15) ?
    N10 C11 C19 . . 122.64(15) ?
    N10 C11 C21 . . 116.67(13) ?
    C19 C11 C21 . . 120.69(14) ?
    O2 C2 N2 . . 121.27(16) y
    O2 C2 C1 . . 118.36(13) y
    N2 C2 C1 . . 120.37(15) y
    C18 C17 C16 . . 122.89(16) ?
    C18 C17 C12 . . 117.84(15) ?
    C16 C17 C12 . . 119.27(16) ?
    C28 C29 C21 . . 119.42(15) ?
    C28 C29 H29 . . 120.3 ?
    C21 C29 H29 . . 120.3 ?
    N3 C3 C1 . . 177.75(17) y
    C29 C28 C27 . . 120.28(14) ?
    C29 C28 H28 . . 119.9 ?
    C27 C28 H28 . . 119.9 ?
    C24 C23 C22 . . 120.13(14) ?
    C24 C23 H23 . . 119.9 ?
    C22 C23 H23 . . 119.9 ?
    C25 C26 C27 . . 120.39(15) ?
    C25 C26 H26 . . 119.8 ?
    C27 C26 H26 . . 119.8 ?
    C23 C24 C25 . . 120.76(15) ?
    C23 C24 H24 . . 119.6 ?
    C25 C24 H24 . . 119.6 ?
    C18 C19 C11 . . 119.01(16) ?
    C18 C19 H19 . . 120.5 ?
    C11 C19 H19 . . 120.5 ?
    C26 C25 C24 . . 120.33(16) ?
    C26 C25 H25 . . 119.8 ?
    C24 C25 H25 . . 119.8 ?
    C14 C13 C12 . . 120.33(16) ?
    C14 C13 H13 . . 119.8 ?
    C12 C13 H13 . . 119.8 ?
    N4 C4 C5 . . 179.8(2) ?
    C4 C5 H1C5 . . 109.7(14) ?
    C4 C5 H3C5 . . 109.1(14) ?
    H1C5 C5 H3C5 . . 112.9(19) ?
    C4 C5 H2C5 . . 110.4(14) ?
    H1C5 C5 H2C5 . . 106.3(19) ?
    H3C5 C5 H2C5 . . 108.4(19) ?
    C19 C18 C17 . . 120.19(15) ?
    C19 C18 H18 . . 119.9 ?
    C17 C18 H18 . . 119.9 ?
    C15 C16 C17 . . 120.76(17) ?
    C15 C16 H16 . . 119.6 ?
    C17 C16 H16 . . 119.6 ?
    C13 C14 C15 . . 120.89(17) ?
    C13 C14 H14 . . 119.6 ?
    C15 C14 H14 . . 119.6 ?
    C16 C15 C14 . . 119.97(17) ?
    C16 C15 H15 . . 120.0 ?
    C14 C15 H15 . . 120.0 ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C19 H19 Cl1 3_766 0.95 2.67 3.4989(17) 146
    C13 H13 O2 . 0.95 2.36 3.230(2) 153
    N2 H2N2 N3 2_646 0.82(2) 2.53(2) 3.061(2) 123.8(17)
    N2 H2N2 N4 2_646 0.82(2) 2.57(2) 3.321(3) 151.3(18)
    N2 H1N2 N4 . 0.82(2) 2.20(2) 2.987(2) 161(2)
    C5 H1C5 O1 2_646 0.97(2) 2.60(2) 3.541(2) 163.6(18)
    C5 H3C5 Cl1 2_656 0.98(2) 2.65(3) 3.615(2) 173.0(19)
    C5 H2C5 Cl1 1_455 0.99(2) 2.71(3) 3.688(2) 171.0(19)
data_global
_journal_date_recd_electronic     2018-03-16
_journal_date_accepted     2018-04-11
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2018
_journal_volume     74
_journal_issue      5
_journal_page_first     584
_journal_page_last     589
_journal_paper_category     FA
_journal_paper_doi     10.1107/S2053229618005697
_journal_coeditor_code     SK3686
_publ_contact_author_name     'Ivan Potočňák'
_publ_contact_author_address
;
Institute of Chemistry
Faculty of Science, P.J. Šafárik University
Moyzesova 11
SK-041 54 Košice
Slovakia
;
_publ_contact_author_email     ivan.potocnak@upjs.sk
_publ_contact_author_fax     ' '
_publ_contact_author_phone     '+421 55 234 2335'
_publ_section_title
;
A CuII complex with an carbamoylcyanonitrosomethanide ligand formed in
situ by the nucleophilic addition of water to dicyanonitrosomethanide:
structure, spectral and magnetic properties
;
_publ_section_title_footnote
;
 Part XXXIII. Low-dimensional compounds containing cyanido groups.
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Potočňák, Ivan' .
;
P. J. Šafárik University in Košice
Faculty of Sciences
Institute of Chemistry
Department of Inorganic Chemistry
Moyzesova 11
SK-041 54 Košice
Slovakia
;
    'Bukrynov, Oleksandr' .
;
V.N. Karazin Kharkiv National University
Faculty of Chemistry
Department of Applied Chemistry
Svobody sq. 4
UA-61022 Kharkiv
Ukraine
;
    'Kliuikov, Andrii' .
;
P.J. Šafárik University in Košice
Faculty of Sciences
Institute of Physics,
Park Angelinum 9
SK-041 54 Košice
Slovakia
;
    'Čižmár, Erik' .
;
P.J. Šafárik University in Košice
Faculty of Sciences
Institute of Physics,
Park Angelinum 9
SK-041 54 Košice
Slovakia
;
    'Vitushkina, Svitlana' .
;
V.N. Karazin Kharkiv National University
Faculty of Chemistry
Department of Applied Chemistry
Svobody sq. 4
UA-61022 Kharkiv
Ukraine
;
    'Váhovská, Lucia' .
;
University of Veterinary Medicine and Pharmacy in Košice
Department of Chemistry, Biochemistry and Biophysics
Institute of Biochemistry
Komenského 73
SK-041 84 Košice
Slovakia
;
    'Dušek, Michal' .
;
Institute of Physics of the Czech Academy of Sciences
Na Slovance 2
CZ-182 21
Praha 8
Czech Republic
;
_publ_section_synopsis
;
The molecular [Cu(ccnm)Cl(biq)]\\cdotacn complex (acn is acetonitrile, biq is
2,2'-biquinoline and ccnm is carbamoylcyanonitrosomethanide) was obtained as a
result of nucleophilic addition of water to the dicyanonitrosomethanide ion in
the presence of CuII and biq, and its spectral and magnetic properties were
investigated.
;
