data_SuperNova
_audit_creation_date               2022-11-30
_audit_creation_method
;
Olex2 1.5
(compiled 2021.07.19 svn.r715e62df for OlexSys, GUI svn.r6383)
;
_shelx_SHELXL_version_number       '2018/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2008). Acta Cryst. A64, 112-122.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'K4 O20 P8 Pt2'
_chemical_formula_sum              'H12 K4 O22 P8 Pt2'
_chemical_formula_weight           1158.44
_chemical_melting_point            ?
_chemical_oxdiff_formula           K4Pt2P8H12O22
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'K' 'K' 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt' 'Pt' -1.7033 8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'tetragonal'
_space_group_IT_number             87
_space_group_name_H-M_alt          'I 4/m'
_space_group_name_Hall             '-I 4'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, z'
 '-y, x, z'
 'y, -x, z'
 'x+1/2, y+1/2, z+1/2'
 '-x+1/2, -y+1/2, z+1/2'
 '-y+1/2, x+1/2, z+1/2'
 'y+1/2, -x+1/2, z+1/2'
 '-x, -y, -z'
 'x, y, -z'
 'y, -x, -z'
 '-y, x, -z'
 '-x+1/2, -y+1/2, -z+1/2'
 'x+1/2, y+1/2, -z+1/2'
 'y+1/2, -x+1/2, -z+1/2'
 '-y+1/2, x+1/2, -z+1/2'

_cell_length_a                     9.3113(3)
_cell_length_b                     9.3113(3)
_cell_length_c                     15.9547(11)
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  90
_cell_volume                       1383.28(13)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      4690
_cell_measurement_temperature      293(2)
_cell_measurement_theta_max        30.7830
_cell_measurement_theta_min        4.0380
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      11.249
_exptl_absorpt_correction_T_max    0.48006
_exptl_absorpt_correction_T_min    0.46840
_exptl_absorpt_correction_type     sphere
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Spherical absorption correction
using equivalent radius and absorption coefficient.
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              ?
_exptl_crystal_density_diffrn      2.781
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         sphere
_exptl_crystal_F_000               1080
_exptl_crystal_size_max            ?
_exptl_crystal_size_mid            ?
_exptl_crystal_size_min            ?
_exptl_crystal_size_rad            0.400
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0482
_diffrn_reflns_av_unetI/netI       0.0297
_diffrn_reflns_Laue_measured_fraction_full  0.995
_diffrn_reflns_Laue_measured_fraction_max  0.943
_diffrn_reflns_limit_h_max         12
_diffrn_reflns_limit_h_min         -11
_diffrn_reflns_limit_k_max         13
_diffrn_reflns_limit_k_min         -12
_diffrn_reflns_limit_l_max         22
_diffrn_reflns_limit_l_min         -20
_diffrn_reflns_number              7706
_diffrn_reflns_point_group_measured_fraction_full  0.995
_diffrn_reflns_point_group_measured_fraction_max  0.943
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           30.970
_diffrn_reflns_theta_min           4.013
_diffrn_ambient_temperature        293(2)
_diffrn_detector                   'CCD plate'
_diffrn_detector_area_resol_mean   10.3590
_diffrn_detector_type              Atlas
_diffrn_measured_fraction_theta_full  0.995
_diffrn_measured_fraction_theta_max  0.943
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -41.00  61.00   0.50   40.24    --  -14.53  32.00 154.00  204
  2  ω    -42.00  18.00   0.50   40.24    --  -14.53 -77.00   0.00  120
  3  ω    -60.00  38.00   0.50   40.24    --   13.91 -38.00 -60.00  196
  4  ω    -15.00  23.00   0.50   40.24    --   13.91 -99.00-120.00   76
  5  ω    -42.00  18.00   0.50   40.24    --  -14.53 -77.00-180.00  120
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type   
 'SuperNova, Single source at offset/far, Atlas'
_diffrn_measurement_method         'ω scans'
_diffrn_orient_matrix_type        
 'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11        0.0077128000
_diffrn_orient_matrix_UB_12        0.0451979000
_diffrn_orient_matrix_UB_13        -0.0355166000
_diffrn_orient_matrix_UB_21        0.0304501000
_diffrn_orient_matrix_UB_22        -0.0578060000
_diffrn_orient_matrix_UB_23        -0.0227978000
_diffrn_orient_matrix_UB_31        -0.0694196000
_diffrn_orient_matrix_UB_32        -0.0204010000
_diffrn_orient_matrix_UB_33        -0.0139693000
_diffrn_radiation_monochromator    mirror
_diffrn_radiation_probe            x-ray
_diffrn_radiation_type             'Mo K\a'
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'micro-focus sealed X-ray tube'
_diffrn_source_type                'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  1023
_reflns_number_total               1074
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_collection         'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_reduction          'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'XL  (Sheldrick, 2008)'
_computing_structure_solution      'XT  (Sheldrick, 2015)'
_refine_diff_density_max           4.329
_refine_diff_density_min           -1.029
_refine_diff_density_rms           0.335
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.159
_refine_ls_hydrogen_treatment      undef
_refine_ls_matrix_type             full
_refine_ls_number_parameters       45
_refine_ls_number_reflns           1074
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0385
_refine_ls_R_factor_gt             0.0368
_refine_ls_restrained_S_all        1.159
_refine_ls_shift/su_max            0.000
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0573P)²+22.3142P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1043
_refine_ls_wR_factor_ref           0.1058
_refine_special_details            ?
_olex2_refinement_description
;
1. Others
 Fixed Sof: K4(0.25)
;
_atom_sites_solution_hydrogens     .
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Pt1 Pt 0.500000 0.500000 0.59069(2) 0.01136(16) Uani 1 4 d S T P . .
 K2 K 0.500000 0.000000 0.750000 0.0154(5) Uani 1 4 d S T P . .
 P3 P 0.48753(17) 0.25190(17) 0.59270(9) 0.0131(3) Uani 1 1 d . . . . .
 K4 K 0.7826(3) 0.0216(3) 0.500000 0.0120(6) Uani 0.5 2 d S T P . .
 O5 O 0.4463(8) 0.1922(7) 0.500000 0.0204(13) Uani 1 2 d S T P . .
 O6 O 0.6191(5) 0.1689(4) 0.6209(3) 0.0181(8) Uani 1 1 d . . . . .
 O7 O 0.3573(5) 0.1910(5) 0.6455(3) 0.0184(8) Uani 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Pt1 Pt1 2.8940(8) 9_666 ?
 Pt1 P3 2.3133(16) 3_655 ?
 Pt1 P3 2.3133(16) . ?
 Pt1 P3 2.3133(16) 2_665 ?
 Pt1 P3 2.3133(16) 4_565 ?
 K2 P3 3.4370(15) 2_655 ?
 K2 P3 3.4370(15) 15_556 ?
 K2 P3 3.4370(15) . ?
 K2 P3 3.4370(15) 16_546 ?
 K2 O6 2.818(5) 15_556 ?
 K2 O6 2.818(5) 2_655 ?
 K2 O6 2.818(5) . ?
 K2 O6 2.818(5) 16_546 ?
 K2 O7 2.777(4) . ?
 K2 O7 2.777(4) 16_546 ?
 K2 O7 2.777(4) 15_556 ?
 K2 O7 2.777(4) 2_655 ?
 P3 K4 3.786(3) . ?
 P3 O5 1.626(3) . ?
 P3 O6 1.517(4) . ?
 P3 O7 1.581(4) . ?
 K4 K4 2.877(4) 3_645 ?
 K4 K4 2.877(4) 11_666 ?
 K4 K4 4.069(6) 9_756 ?
 K4 O5 2.916(7) 9_656 ?
 K4 O6 2.814(5) 10_556 ?
 K4 O6 2.814(5) . ?
 K4 O7 3.317(5) 2_655 ?
 K4 O7 3.317(5) 9_656 ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 P3 Pt1 Pt1 90.79(4) . 9_666 ?
 P3 Pt1 Pt1 90.79(4) 4_565 9_666 ?
 P3 Pt1 Pt1 90.79(4) 3_655 9_666 ?
 P3 Pt1 Pt1 90.79(4) 2_665 9_666 ?
 P3 Pt1 P3 89.989(1) 2_665 4_565 ?
 P3 Pt1 P3 89.988(1) . 4_565 ?
 P3 Pt1 P3 89.990(1) . 3_655 ?
 P3 Pt1 P3 178.42(7) 3_655 4_565 ?
 P3 Pt1 P3 178.41(7) . 2_665 ?
 P3 Pt1 P3 89.989(1) 2_665 3_655 ?
 P3 K2 P3 86.20(5) 15_556 16_546 ?
 P3 K2 P3 122.22(3) 15_556 2_655 ?
 P3 K2 P3 86.20(5) . 2_655 ?
 P3 K2 P3 122.22(3) . 15_556 ?
 P3 K2 P3 122.22(3) 2_655 16_546 ?
 P3 K2 P3 122.22(3) . 16_546 ?
 O6 K2 P3 25.71(9) 15_556 15_556 ?
 O6 K2 P3 25.71(9) 16_546 16_546 ?
 O6 K2 P3 25.72(9) . . ?
 O6 K2 P3 80.43(10) 16_546 15_556 ?
 O6 K2 P3 104.25(10) 2_655 16_546 ?
 O6 K2 P3 80.43(10) 2_655 . ?
 O6 K2 P3 104.25(10) 16_546 . ?
 O6 K2 P3 80.43(10) . 2_655 ?
 O6 K2 P3 145.18(9) . 16_546 ?
 O6 K2 P3 25.71(9) 2_655 2_655 ?
 O6 K2 P3 80.43(10) 15_556 16_546 ?
 O6 K2 P3 104.25(10) 15_556 2_655 ?
 O6 K2 P3 145.18(9) 15_556 . ?
 O6 K2 P3 104.25(10) . 15_556 ?
 O6 K2 P3 145.18(9) 2_655 15_556 ?
 O6 K2 P3 145.18(9) 16_546 2_655 ?
 O6 K2 O6 86.10(19) . 2_655 ?
 O6 K2 O6 122.27(11) 2_655 16_546 ?
 O6 K2 O6 122.28(11) . 16_546 ?
 O6 K2 O6 122.27(11) . 15_556 ?
 O6 K2 O6 122.27(11) 2_655 15_556 ?
 O6 K2 O6 86.10(19) 15_556 16_546 ?
 O7 K2 P3 97.68(9) 16_546 2_655 ?
 O7 K2 P3 90.84(10) 16_546 15_556 ?
 O7 K2 P3 26.90(9) 16_546 16_546 ?
 O7 K2 P3 90.84(10) . 2_655 ?
 O7 K2 P3 26.90(9) 2_655 2_655 ?
 O7 K2 P3 138.03(10) 15_556 2_655 ?
 O7 K2 P3 97.68(9) . 16_546 ?
 O7 K2 P3 97.68(9) 15_556 . ?
 O7 K2 P3 138.03(10) . 15_556 ?
 O7 K2 P3 138.03(10) 16_546 . ?
 O7 K2 P3 138.03(10) 2_655 16_546 ?
 O7 K2 P3 26.90(9) 15_556 15_556 ?
 O7 K2 P3 90.84(10) 2_655 . ?
 O7 K2 P3 97.68(9) 2_655 15_556 ?
 O7 K2 P3 90.84(10) 15_556 16_546 ?
 O7 K2 P3 26.90(9) . . ?
 O7 K2 O6 74.34(13) 15_556 16_546 ?
 O7 K2 O6 163.31(13) 15_556 2_655 ?
 O7 K2 O6 85.41(13) 2_655 15_556 ?
 O7 K2 O6 163.31(13) 2_655 16_546 ?
 O7 K2 O6 74.34(13) . 2_655 ?
 O7 K2 O6 52.56(12) 16_546 16_546 ?
 O7 K2 O6 163.31(13) . 15_556 ?
 O7 K2 O6 85.41(13) . 16_546 ?
 O7 K2 O6 52.56(12) 2_655 2_655 ?
 O7 K2 O6 85.41(13) 15_556 . ?
 O7 K2 O6 52.56(12) 15_556 15_556 ?
 O7 K2 O6 74.34(13) 2_655 . ?
 O7 K2 O6 74.34(13) 16_546 15_556 ?
 O7 K2 O6 163.31(13) 16_546 . ?
 O7 K2 O6 52.56(12) . . ?
 O7 K2 O6 85.41(13) 16_546 2_655 ?
 O7 K2 O7 111.15(10) 15_556 2_655 ?
 O7 K2 O7 111.15(10) 2_655 16_546 ?
 O7 K2 O7 111.15(10) 16_546 . ?
 O7 K2 O7 111.15(10) 15_556 . ?
 O7 K2 O7 106.17(19) 2_655 . ?
 O7 K2 O7 106.17(19) 15_556 16_546 ?
 Pt1 P3 K2 133.62(6) . . ?
 Pt1 P3 K4 121.59(7) . . ?
 K2 P3 K4 82.77(4) . . ?
 O5 P3 Pt1 109.9(2) . . ?
 O5 P3 K2 116.0(2) . . ?
 O5 P3 K4 67.8(3) . . ?
 O6 P3 Pt1 118.20(18) . . ?
 O6 P3 K2 53.72(18) . . ?
 O6 P3 K4 40.64(19) . . ?
 O6 P3 O5 106.6(3) . . ?
 O6 P3 O7 106.2(3) . . ?
 O7 P3 Pt1 113.82(18) . . ?
 O7 P3 K2 52.60(16) . . ?
 O7 P3 K4 124.15(18) . . ?
 O7 P3 O5 100.4(3) . . ?
 K2 K4 K2 113.03(6) 9_656 . ?
 P3 K4 K2 87.16(6) . 9_656 ?
 P3 K4 K2 45.48(3) 10_556 9_656 ?
 P3 K4 K2 45.48(3) . . ?
 P3 K4 K2 87.16(6) 10_556 . ?
 P3 K4 P3 45.99(6) 10_556 . ?
 P3 K4 K4 141.08(11) 10_556 9_756 ?
 P3 K4 K4 141.08(11) . 9_756 ?
 K4 K4 K2 108.43(7) 3_645 9_656 ?
 K4 K4 K2 116.88(6) 11_666 . ?
 K4 K4 K2 108.43(7) 3_645 . ?
 K4 K4 K2 116.88(6) 11_666 9_656 ?
 K4 K4 K2 122.91(3) 9_756 . ?
 K4 K4 K2 122.91(3) 9_756 9_656 ?
 K4 K4 P3 101.67(13) 11_666 10_556 ?
 K4 K4 P3 153.90(7) 3_645 10_556 ?
 K4 K4 P3 153.90(7) 3_645 . ?
 K4 K4 P3 101.67(13) 11_666 . ?
 K4 K4 K4 45.0 3_645 9_756 ?
 K4 K4 K4 45.0 11_666 9_756 ?
 K4 K4 K4 90.000(1) 3_645 11_666 ?
 K4 K4 O5 86.3(2) 3_645 9_656 ?
 K4 K4 O5 176.3(2) 11_666 9_656 ?
 K4 K4 O7 133.00(8) 11_666 2_655 ?
 K4 K4 O7 133.00(8) 11_666 9_656 ?
 K4 K4 O7 77.71(13) 3_645 9_656 ?
 K4 K4 O7 77.71(13) 3_645 2_655 ?
 O5 K4 K2 64.49(6) 9_656 . ?
 O5 K4 K2 64.49(6) 9_656 9_656 ?
 O5 K4 P3 81.74(15) 9_656 . ?
 O5 K4 P3 81.74(15) 9_656 10_556 ?
 O5 K4 K4 131.3(2) 9_656 9_756 ?
 O5 K4 O7 46.03(9) 9_656 9_656 ?
 O5 K4 O7 46.03(9) 9_656 2_655 ?
 O6 K4 K2 107.14(12) . 9_656 ?
 O6 K4 K2 31.91(9) 10_556 9_656 ?
 O6 K4 K2 31.91(9) . . ?
 O6 K4 K2 107.14(12) 10_556 . ?
 O6 K4 P3 20.56(10) 10_556 10_556 ?
 O6 K4 P3 20.56(10) . . ?
 O6 K4 P3 66.38(11) . 10_556 ?
 O6 K4 P3 66.38(11) 10_556 . ?
 O6 K4 K4 136.03(11) . 3_645 ?
 O6 K4 K4 96.29(15) 10_556 11_666 ?
 O6 K4 K4 96.29(15) . 11_666 ?
 O6 K4 K4 125.90(13) . 9_756 ?
 O6 K4 K4 125.90(13) 10_556 9_756 ?
 O6 K4 K4 136.03(11) 10_556 3_645 ?
 O6 K4 O5 86.41(15) 10_556 9_656 ?
 O6 K4 O5 86.41(15) . 9_656 ?
 O6 K4 O6 86.6(2) . 10_556 ?
 O6 K4 O7 66.35(12) 10_556 9_656 ?
 O6 K4 O7 123.93(15) 10_556 2_655 ?
 O6 K4 O7 66.35(12) . 2_655 ?
 O6 K4 O7 123.93(15) . 9_656 ?
 O7 K4 K2 110.03(10) 9_656 . ?
 O7 K4 K2 34.45(8) 9_656 9_656 ?
 O7 K4 K2 110.03(10) 2_655 9_656 ?
 O7 K4 K2 34.45(8) 2_655 . ?
 O7 K4 P3 77.28(9) 9_656 10_556 ?
 O7 K4 P3 77.28(9) 2_655 . ?
 O7 K4 P3 109.06(11) 2_655 10_556 ?
 O7 K4 P3 109.06(11) 9_656 . ?
 O7 K4 K4 109.37(11) 2_655 9_756 ?
 O7 K4 K4 109.37(11) 9_656 9_756 ?
 O7 K4 O7 88.81(17) 9_656 2_655 ?
 P3 O5 P3 130.9(4) 10_556 . ?
 P3 O5 K4 114.0(2) 10_556 9_656 ?
 P3 O5 K4 114.0(2) . 9_656 ?
 P3 O6 K2 100.6(2) . . ?
 P3 O6 K4 118.8(3) . . ?
 K4 O6 K2 116.23(15) . . ?
 K2 O7 K4 103.05(14) . 9_656 ?
 P3 O7 K2 100.5(2) . . ?
 P3 O7 K4 98.2(2) . 9_656 ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Pt1 P3 O5 P3 34.1(7) . . . 10_556 ?
 Pt1 P3 O5 K4 -132.5(2) . . . 9_656 ?
 Pt1 P3 O6 K2 125.27(12) . . . . ?
 Pt1 P3 O6 K4 -106.7(2) . . . . ?
 Pt1 P3 O7 K2 -127.72(11) . . . . ?
 Pt1 P3 O7 K4 127.28(11) . . . 9_656 ?
 K2 P3 O5 P3 -152.4(5) . . . 10_556 ?
 K2 P3 O5 K4 41.0(4) . . . 9_656 ?
 K2 P3 O6 K4 128.0(3) . . . . ?
 K2 P3 O7 K4 -105.00(18) . . . 9_656 ?
 K4 P3 O5 P3 -82.9(6) . . . 10_556 ?
 K4 P3 O5 K4 110.5(3) . . . 9_656 ?
 K4 P3 O6 K2 -128.0(3) . . . . ?
 K4 P3 O7 K2 44.8(2) . . . . ?
 K4 P3 O7 K4 -60.2(2) . . . 9_656 ?
 O5 P3 O6 K2 -110.4(2) . . . . ?
 O5 P3 O6 K4 17.6(3) . . . . ?
 O5 P3 O7 K2 114.9(3) . . . . ?
 O5 P3 O7 K4 9.9(3) . . . 9_656 ?
 O6 P3 O5 P3 -95.2(6) . . . 10_556 ?
 O6 P3 O5 K4 98.3(3) . . . 9_656 ?
 O6 P3 O7 K2 4.0(3) . . . . ?
 O6 P3 O7 K4 -101.0(2) . . . 9_656 ?
 O7 P3 O5 P3 154.3(5) . . . 10_556 ?
 O7 P3 O5 K4 -12.3(4) . . . 9_656 ?
 O7 P3 O6 K2 -4.0(3) . . . . ?
 O7 P3 O6 K4 124.0(3) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max  3.825
_oxdiff_exptl_absorpt_empirical_full_min  0.283
