##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Carbonyl{3,3'-di-tert-butyl-5,5'-dimethoxy-2,2'-bis[(4,4,5,5-
tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-
κ²P,P'}hydrido(triphenylphosphane-κP)rhodium(I)
diethyl ether trisolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C93 H84 O9 P3 Rh, 3 (C4 H10 O)'
_chemical_formula_sum     'C105 H114 O12 P3 Rh'
_chemical_formula_iupac
                           '[Rh H (C74 H68 O8 P2) (C18 H15 P) (C O)], 3C4 H10 O'
_chemical_formula_weight     1763.78
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     21.1611(4)
_cell_length_b     22.1298(4)
_cell_length_c     22.6020(4)
_cell_angle_alpha     112.3450(10)
_cell_angle_beta     101.1350(10)
_cell_angle_gamma     96.7570(10)
_cell_volume     9389.9(3)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     9259
_cell_measurement_theta_min     2.25
_cell_measurement_theta_max     28.65
_cell_measurement_temperature     150(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     colorless
_exptl_crystal_size_max     0.44
_exptl_crystal_size_mid     0.39
_exptl_crystal_size_min     0.18
_exptl_crystal_density_diffrn     1.248
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     3720
_exptl_absorpt_coefficient_mu     0.293
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2008)'
_exptl_absorpt_correction_T_min     0.94
_exptl_absorpt_correction_T_max     1.00
_exptl_special_details
;
;
_diffrn_ambient_temperature     150(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     'curved graphite'
_diffrn_measurement_device_type     'Bruker Kappa APEXII DUO'
_diffrn_measurement_method     'omega scans'
_diffrn_detector_area_resol_mean     8.3333
_diffrn_reflns_number     388867
_diffrn_reflns_av_R_equivalents     0.0726
_diffrn_reflns_av_sigmaI/netI     0.0405
_diffrn_reflns_theta_min     1.45
_diffrn_reflns_theta_max     27.50
_diffrn_reflns_theta_full     27.50
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -27
_diffrn_reflns_limit_h_max     27
_diffrn_reflns_limit_k_min     -28
_diffrn_reflns_limit_k_max     28
_diffrn_reflns_limit_l_min     -29
_diffrn_reflns_limit_l_max     29
_diffrn_standards_number     ?
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
Refinement of F² against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F², conventional
R-factors R are based on F, with F set to zero for
negative F². The threshold expression of F² >
σ(F²) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F² are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger.
;
_reflns_number_total     43155
_reflns_number_gt     32017
_reflns_threshold_expression     I>2sigma(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0779
_refine_ls_R_factor_gt     0.0532
_refine_ls_wR_factor_gt     0.1410
_refine_ls_wR_factor_ref     0.1523
_refine_ls_goodness_of_fit_ref     1.046
_refine_ls_restrained_S_all     1.055
_refine_ls_number_reflns     43155
_refine_ls_number_parameters     1866
_refine_ls_number_restraints     55
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0834P)²+5.5129P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.427
_refine_diff_density_min     -0.992
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Rh' 'Rh' -1.1178 0.9187
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2011)'
_computing_cell_refinement     'SAINT (Bruker, 2009)'
_computing_data_reduction     'SAINT (Bruker, 2009)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics     'XP in SHELXTL (Sheldrick, 2008)'
_computing_publication_material     'SHELXTL (Sheldrick, 2008)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_symmetry_multiplicity
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C181 -0.14393(10) 0.43500(17) 0.21835(17) 0.0714(8) Uani d GU 1 1 . .
    C C182 -0.18041(12) 0.46717(16) 0.18632(17) 0.0725(9) Uani d GU 1 1 . .
    H H182 -0.1587 0.4978 0.1728 0.087 Uiso calc R 1 1 . .
    C C183 -0.24866(12) 0.45451(19) 0.17406(18) 0.0876(10) Uani d GU 1 1 . .
    H H183 -0.2736 0.4765 0.1522 0.105 Uiso calc R 1 1 . .
    C C184 -0.28042(10) 0.40967(19) 0.1938(2) 0.1025(11) Uani d GU 1 1 . .
    H H184 -0.3271 0.4010 0.1855 0.123 Uiso calc R 1 1 . .
    C C185 -0.24395(13) 0.37750(18) 0.2259(2) 0.1012(10) Uani d GU 1 1 . .
    H H185 -0.2657 0.3469 0.2394 0.121 Uiso calc R 1 1 . .
    C C186 -0.17570(13) 0.39016(18) 0.23812(19) 0.0873(9) Uani d GU 1 1 . .
    H H186 -0.1508 0.3682 0.2600 0.105 Uiso calc R 1 1 . .
    O O19 0.1836(3) 0.8334(3) 0.1238(3) 0.0631(15) Uani d PD 0.50 1 . .
    C C187 0.1235(3) 0.8479(4) 0.0984(4) 0.077(2) Uani d PDU 0.50 1 . .
    H H18A 0.1114 0.8838 0.1338 0.093 Uiso calc PR 0.50 1 . .
    H H18B 0.0875 0.8077 0.0794 0.093 Uiso calc PR 0.50 1 . .
    C C188 0.1356(4) 0.8703(4) 0.0452(4) 0.070(2) Uani d PDU 0.50 1 . .
    H H18C 0.0955 0.8815 0.0258 0.105 Uiso calc PR 0.50 1 . .
    H H18D 0.1474 0.8342 0.0106 0.105 Uiso calc PR 0.50 1 . .
    H H18E 0.1717 0.9098 0.0648 0.105 Uiso calc PR 0.50 1 . .
    C C189 0.1735(5) 0.8107(6) 0.1728(5) 0.098(3) Uani d PDU 0.50 1 . .
    H H18F 0.1392 0.7690 0.1534 0.117 Uiso calc PR 0.50 1 . .
    H H18G 0.1605 0.8451 0.2088 0.117 Uiso calc PR 0.50 1 . .
    C C190 0.2406(5) 0.7985(6) 0.1977(6) 0.102(3) Uani d PDU 0.50 1 . .
    H H19A 0.2391 0.7824 0.2323 0.154 Uiso calc PR 0.50 1 . .
    H H19B 0.2736 0.8403 0.2159 0.154 Uiso calc PR 0.50 1 . .
    H H19C 0.2525 0.7649 0.1609 0.154 Uiso calc PR 0.50 1 . .
    C C1 0.57231(16) 0.83998(16) 0.26418(15) 0.0344(7) Uani d . 1 1 . .
    C C2 0.63930(9) 0.99152(8) 0.45993(9) 0.0312(6) Uani d G 1 1 . .
    C C3 0.57380(8) 0.99575(9) 0.44256(8) 0.0379(7) Uani d G 1 1 . .
    H H3 0.5431 0.9593 0.4069 0.046 Uiso calc R 1 1 . .
    C C4 0.55321(8) 1.05328(11) 0.47742(10) 0.0463(9) Uani d G 1 1 . .
    H H4 0.5084 1.0562 0.4655 0.056 Uiso calc R 1 1 . .
    C C5 0.59811(11) 1.10659(9) 0.52964(10) 0.0481(9) Uani d G 1 1 . .
    H H5 0.5840 1.1459 0.5535 0.058 Uiso calc R 1 1 . .
    C C6 0.66360(9) 1.10236(9) 0.54702(9) 0.0461(8) Uani d G 1 1 . .
    H H6 0.6943 1.1388 0.5827 0.055 Uiso calc R 1 1 . .
    C C7 0.68420(7) 1.04483(10) 0.51216(9) 0.0368(7) Uani d G 1 1 . .
    H H7 0.7290 1.0419 0.5240 0.044 Uiso calc R 1 1 . .
    C C8 0.61093(9) 0.84922(9) 0.41973(10) 0.0330(7) Uani d G 1 1 . .
    C C9 0.57987(11) 0.86408(9) 0.47088(9) 0.0393(8) Uani d G 1 1 . .
    H H9 0.5848 0.9092 0.5010 0.047 Uiso calc R 1 1 . .
    C C10 0.54166(11) 0.81294(12) 0.47794(10) 0.0499(9) Uani d G 1 1 . .
    H H10 0.5204 0.8231 0.5129 0.060 Uiso calc R 1 1 . .
    C C11 0.53451(11) 0.74694(10) 0.43386(12) 0.0552(10) Uani d G 1 1 . .
    H H11 0.5084 0.7120 0.4387 0.066 Uiso calc R 1 1 . .
    C C12 0.56557(12) 0.73208(8) 0.38271(11) 0.0543(9) Uani d G 1 1 . .
    H H12 0.5607 0.6870 0.3526 0.065 Uiso calc R 1 1 . .
    C C13 0.60378(11) 0.78322(10) 0.37564(9) 0.0408(8) Uani d G 1 1 . .
    H H13 0.6250 0.7731 0.3407 0.049 Uiso calc R 1 1 . .
    C C14 0.74426(8) 0.92469(10) 0.46391(8) 0.0321(6) Uani d G 1 1 . .
    C C15 0.74770(9) 0.91243(11) 0.52025(10) 0.0421(8) Uani d G 1 1 . .
    H H15 0.7094 0.8906 0.5260 0.050 Uiso calc R 1 1 . .
    C C16 0.80712(12) 0.93219(12) 0.56824(8) 0.0535(10) Uani d G 1 1 . .
    H H16 0.8095 0.9238 0.6067 0.064 Uiso calc R 1 1 . .
    C C17 0.86311(9) 0.96420(12) 0.55989(10) 0.0560(11) Uani d G 1 1 . .
    H H17 0.9037 0.9777 0.5927 0.067 Uiso calc R 1 1 . .
    C C18 0.85968(8) 0.97646(12) 0.50354(11) 0.0509(9) Uani d G 1 1 . .
    H H18 0.8979 0.9983 0.4978 0.061 Uiso calc R 1 1 . .
    C C19 0.80026(9) 0.95671(11) 0.45556(9) 0.0402(8) Uani d G 1 1 . .
    H H19 0.7979 0.9651 0.4171 0.048 Uiso calc R 1 1 . .
    C C20 0.76745(14) 0.73280(14) 0.23918(14) 0.0277(6) Uani d . 1 1 . .
    C C21 0.82714(14) 0.79459(13) 0.25618(13) 0.0253(6) Uani d . 1 1 . .
    C C22 0.76466(14) 0.71297(15) 0.29712(14) 0.0294(6) Uani d . 1 1 . .
    C C23 0.76259(15) 0.76163(15) 0.35759(14) 0.0314(6) Uani d . 1 1 . .
    H H23 0.7636 0.8063 0.3625 0.038 Uiso calc R 1 1 . .
    C C24 0.75911(16) 0.74548(17) 0.41073(15) 0.0371(7) Uani d . 1 1 . .
    H H24 0.7586 0.7793 0.4519 0.045 Uiso calc R 1 1 . .
    C C25 0.75643(18) 0.68015(17) 0.40378(16) 0.0423(8) Uani d . 1 1 . .
    H H25 0.7540 0.6690 0.4400 0.051 Uiso calc R 1 1 . .
    C C26 0.7573(2) 0.63168(18) 0.34410(17) 0.0474(9) Uani d . 1 1 . .
    H H26 0.7549 0.5867 0.3389 0.057 Uiso calc R 1 1 . .
    C C27 0.76189(18) 0.64815(16) 0.29107(16) 0.0415(8) Uani d . 1 1 . .
    H H27 0.7631 0.6143 0.2502 0.050 Uiso calc R 1 1 . .
    C C28 0.76360(10) 0.67045(8) 0.17628(8) 0.0317(6) Uani d G 1 1 . .
    C C29 0.70394(8) 0.63975(10) 0.12864(10) 0.0414(8) Uani d G 1 1 . .
    H H29 0.6662 0.6585 0.1339 0.050 Uiso calc R 1 1 . .
    C C30 0.69953(10) 0.58161(10) 0.07329(9) 0.0539(10) Uani d G 1 1 . .
    H H30 0.6588 0.5606 0.0407 0.065 Uiso calc R 1 1 . .
    C C31 0.75479(12) 0.55416(9) 0.06559(9) 0.0518(10) Uani d G 1 1 . .
    H H31 0.7518 0.5144 0.0278 0.062 Uiso calc R 1 1 . .
    C C32 0.81446(10) 0.58486(10) 0.11324(10) 0.0435(8) Uani d G 1 1 . .
    H H32 0.8522 0.5661 0.1080 0.052 Uiso calc R 1 1 . .
    C C33 0.81887(8) 0.64300(9) 0.16858(9) 0.0368(7) Uani d G 1 1 . .
    H H33 0.8596 0.6640 0.2011 0.044 Uiso calc R 1 1 . .
    C C34 0.86246(14) 0.78453(14) 0.20024(14) 0.0289(6) Uani d . 1 1 . .
    C C35 0.82838(16) 0.77862(15) 0.13847(14) 0.0326(6) Uani d . 1 1 . .
    H H35 0.7827 0.7792 0.1302 0.039 Uiso calc R 1 1 . .
    C C36 0.86027(18) 0.77191(16) 0.08858(16) 0.0403(7) Uani d . 1 1 . .
    H H36 0.8364 0.7685 0.0469 0.048 Uiso calc R 1 1 . .
    C C37 0.92653(18) 0.77015(17) 0.09948(17) 0.0445(8) Uani d . 1 1 . .
    H H37 0.9484 0.7664 0.0657 0.053 Uiso calc R 1 1 . .
    C C38 0.96053(18) 0.77392(17) 0.15953(18) 0.0439(8) Uani d . 1 1 . .
    H H38 1.0057 0.7713 0.1668 0.053 Uiso calc R 1 1 . .
    C C39 0.92890(16) 0.78156(17) 0.20955(17) 0.0398(8) Uani d . 1 1 . .
    H H39 0.9531 0.7848 0.2511 0.048 Uiso calc R 1 1 . .
    C C40 0.88030(14) 0.81697(15) 0.32105(14) 0.0281(6) Uani d . 1 1 . .
    C C41 0.90873(15) 0.77224(17) 0.34205(15) 0.0349(7) Uani d . 1 1 . .
    H H41 0.8907 0.7257 0.3190 0.042 Uiso calc R 1 1 . .
    C C42 0.96277(17) 0.7950(2) 0.39597(18) 0.0474(9) Uani d . 1 1 . .
    H H42 0.9812 0.7640 0.4099 0.057 Uiso calc R 1 1 . .
    C C43 0.99033(17) 0.8625(2) 0.42983(18) 0.0501(9) Uani d . 1 1 . .
    H H43 1.0277 0.8779 0.4668 0.060 Uiso calc R 1 1 . .
    C C44 0.96293(17) 0.90744(19) 0.40935(17) 0.0453(8) Uani d . 1 1 . .
    H H44 0.9816 0.9539 0.4321 0.054 Uiso calc R 1 1 . .
    C C45 0.90819(15) 0.88456(16) 0.35559(15) 0.0351(7) Uani d . 1 1 . .
    H H45 0.8895 0.9158 0.3422 0.042 Uiso calc R 1 1 . .
    C C46 0.67384(14) 0.86482(15) 0.13299(13) 0.0273(6) Uani d . 1 1 . .
    C C47 0.62165(14) 0.83177(16) 0.07520(14) 0.0317(6) Uani d . 1 1 . .
    C C48 0.60251(16) 0.86930(17) 0.03994(14) 0.0353(7) Uani d . 1 1 . .
    H H48 0.5679 0.8485 0.0004 0.042 Uiso calc R 1 1 . .
    C C49 0.63162(16) 0.93487(17) 0.06013(14) 0.0370(7) Uani d . 1 1 . .
    C C50 0.68016(15) 0.96774(15) 0.11859(14) 0.0307(6) Uani d . 1 1 . .
    H H50 0.6986 1.0139 0.1337 0.037 Uiso calc R 1 1 . .
    C C51 0.70198(14) 0.93198(14) 0.15555(13) 0.0265(6) Uani d . 1 1 . .
    C C52 0.75892(14) 0.97027(14) 0.21497(13) 0.0256(6) Uani d . 1 1 . .
    C C53 0.82131(14) 0.95697(14) 0.21089(14) 0.0279(6) Uani d . 1 1 . .
    H H53 0.8264 0.9215 0.1731 0.033 Uiso calc R 1 1 . .
    C C54 0.87523(14) 0.99607(15) 0.26254(16) 0.0320(6) Uani d . 1 1 . .
    C C55 0.86843(15) 1.04907(15) 0.31751(16) 0.0327(6) Uani d . 1 1 . .
    H H55 0.9065 1.0753 0.3523 0.039 Uiso calc R 1 1 . .
    C C56 0.80727(14) 1.06460(14) 0.32281(14) 0.0279(6) Uani d . 1 1 . .
    C C57 0.75257(13) 1.02281(14) 0.27075(13) 0.0255(6) Uani d . 1 1 . .
    C C58 0.58923(16) 0.75755(17) 0.04770(15) 0.0382(7) Uani d . 1 1 . .
    C C59 0.52858(19) 0.7380(2) -0.01132(18) 0.0547(10) Uani d . 1 1 . .
    H H59A 0.5068 0.6914 -0.0252 0.082 Uiso calc R 1 1 . .
    H H59B 0.5427 0.7431 -0.0483 0.082 Uiso calc R 1 1 . .
    H H59C 0.4977 0.7671 0.0020 0.082 Uiso calc R 1 1 . .
    C C60 0.63865(19) 0.71500(18) 0.02257(17) 0.0469(8) Uani d . 1 1 . .
    H H60A 0.6778 0.7261 0.0590 0.070 Uiso calc R 1 1 . .
    H H60B 0.6514 0.7242 -0.0131 0.070 Uiso calc R 1 1 . .
    H H60C 0.6183 0.6675 0.0058 0.070 Uiso calc R 1 1 . .
    C C61 0.56379(18) 0.74027(19) 0.09960(17) 0.0456(8) Uani d . 1 1 . .
    H H61A 0.6010 0.7479 0.1368 0.068 Uiso calc R 1 1 . .
    H H61B 0.5410 0.6932 0.0796 0.068 Uiso calc R 1 1 . .
    H H61C 0.5331 0.7686 0.1155 0.068 Uiso calc R 1 1 . .
    C C62 0.6526(2) 1.0214(2) 0.0235(2) 0.0568(10) Uani d . 1 1 . .
    H H62A 0.6602 1.0573 0.0678 0.085 Uiso calc R 1 1 . .
    H H62B 0.6328 1.0364 -0.0100 0.085 Uiso calc R 1 1 . .
    H H62C 0.6946 1.0098 0.0165 0.085 Uiso calc R 1 1 . .
    C C63 0.94820(18) 0.93748(18) 0.2054(2) 0.0538(10) Uani d . 1 1 . .
    H H63A 0.9232 0.8939 0.1979 0.081 Uiso calc R 1 1 . .
    H H63B 0.9951 0.9363 0.2110 0.081 Uiso calc R 1 1 . .
    H H63C 0.9324 0.9478 0.1673 0.081 Uiso calc R 1 1 . .
    C C64 0.80299(15) 1.12667(15) 0.38167(14) 0.0311(6) Uani d . 1 1 . .
    C C65 0.87094(17) 1.16401(18) 0.42862(17) 0.0472(8) Uani d . 1 1 . .
    H H65A 0.8665 1.2042 0.4646 0.071 Uiso calc R 1 1 . .
    H H65B 0.8995 1.1769 0.4042 0.071 Uiso calc R 1 1 . .
    H H65C 0.8904 1.1349 0.4471 0.071 Uiso calc R 1 1 . .
    C C66 0.77412(19) 1.17556(17) 0.35638(17) 0.0448(8) Uani d . 1 1 . .
    H H66A 0.7288 1.1548 0.3292 0.067 Uiso calc R 1 1 . .
    H H66B 0.8009 1.1866 0.3296 0.067 Uiso calc R 1 1 . .
    H H66C 0.7742 1.2165 0.3942 0.067 Uiso calc R 1 1 . .
    C C67 0.76009(18) 1.10851(18) 0.42264(16) 0.0447(8) Uani d . 1 1 . .
    H H67A 0.7159 1.0848 0.3941 0.067 Uiso calc R 1 1 . .
    H H67B 0.7570 1.1494 0.4586 0.067 Uiso calc R 1 1 . .
    H H67C 0.7800 1.0797 0.4413 0.067 Uiso calc R 1 1 . .
    C C68 0.53496(14) 1.05328(16) 0.28807(14) 0.0303(6) Uani d . 1 1 . .
    C C69 0.53080(14) 1.01804(15) 0.20919(13) 0.0285(6) Uani d . 1 1 . .
    C C70 0.54424(10) 1.12928(8) 0.32133(9) 0.0346(7) Uani d G 1 1 . .
    C C71 0.58078(11) 1.16100(10) 0.38704(9) 0.0447(8) Uani d G 1 1 . .
    H H71 0.6034 1.1365 0.4074 0.054 Uiso calc R 1 1 . .
    C C72 0.58424(12) 1.22864(11) 0.42292(8) 0.0572(10) Uani d G 1 1 . .
    H H72 0.6092 1.2503 0.4678 0.069 Uiso calc R 1 1 . .
    C C73 0.55115(13) 1.26456(8) 0.39311(11) 0.0585(10) Uani d G 1 1 . .
    H H73 0.5535 1.3108 0.4176 0.070 Uiso calc R 1 1 . .
    C C74 0.51461(12) 1.23284(10) 0.32741(11) 0.0494(9) Uani d G 1 1 . .
    H H74 0.4920 1.2574 0.3070 0.059 Uiso calc R 1 1 . .
    C C75 0.51116(10) 1.16520(10) 0.29152(8) 0.0396(7) Uani d G 1 1 . .
    H H75 0.4862 1.1435 0.2466 0.048 Uiso calc R 1 1 . .
    C C76 0.47551(8) 1.02122(11) 0.30545(10) 0.0369(7) Uani d G 1 1 . .
    C C77 0.43269(11) 1.05876(10) 0.33438(10) 0.0470(9) Uani d G 1 1 . .
    H H77 0.4390 1.1050 0.3435 0.056 Uiso calc R 1 1 . .
    C C78 0.38070(10) 1.02872(14) 0.34997(11) 0.0610(12) Uani d G 1 1 . .
    H H78 0.3514 1.0544 0.3697 0.073 Uiso calc R 1 1 . .
    C C79 0.37154(9) 0.96113(15) 0.33662(13) 0.0712(14) Uani d G 1 1 . .
    H H79 0.3360 0.9406 0.3473 0.085 Uiso calc R 1 1 . .
    C C80 0.41436(12) 0.92358(11) 0.30769(13) 0.0625(12) Uani d G 1 1 . .
    H H80 0.4081 0.8774 0.2986 0.075 Uiso calc R 1 1 . .
    C C81 0.46635(10) 0.95362(11) 0.29210(11) 0.0447(8) Uani d G 1 1 . .
    H H81 0.4956 0.9280 0.2723 0.054 Uiso calc R 1 1 . .
    C C82 0.55575(9) 1.06648(9) 0.17980(9) 0.0321(7) Uani d G 1 1 . .
    C C83 0.61258(9) 1.11574(10) 0.21531(8) 0.0381(7) Uani d G 1 1 . .
    H H83 0.6367 1.1188 0.2568 0.046 Uiso calc R 1 1 . .
    C C84 0.63407(9) 1.16046(10) 0.19014(11) 0.0488(9) Uani d G 1 1 . .
    H H84 0.6729 1.1941 0.2144 0.059 Uiso calc R 1 1 . .
    C C85 0.59872(12) 1.15592(12) 0.12945(12) 0.0602(11) Uani d G 1 1 . .
    H H85 0.6134 1.1865 0.1122 0.072 Uiso calc R 1 1 . .
    C C86 0.54189(11) 1.10666(13) 0.09394(9) 0.0538(10) Uani d G 1 1 . .
    H H86 0.5177 1.1036 0.0525 0.065 Uiso calc R 1 1 . .
    C C87 0.52041(9) 1.06194(10) 0.11912(9) 0.0403(8) Uani d G 1 1 . .
    H H87 0.4816 1.0283 0.0948 0.048 Uiso calc R 1 1 . .
    C C88 0.46316(15) 0.97476(17) 0.16744(14) 0.0337(7) Uani d . 1 1 . .
    C C89 0.40626(15) 1.00146(18) 0.16901(15) 0.0378(7) Uani d . 1 1 . .
    H H89 0.4098 1.0474 0.1958 0.045 Uiso calc R 1 1 . .
    C C90 0.34496(17) 0.9614(2) 0.13177(17) 0.0488(9) Uani d . 1 1 . .
    H H90 0.3068 0.9800 0.1335 0.059 Uiso calc R 1 1 . .
    C C91 0.33892(19) 0.8947(2) 0.0922(2) 0.0615(11) Uani d . 1 1 . .
    H H91 0.2967 0.8669 0.0678 0.074 Uiso calc R 1 1 . .
    C C92 0.3949(2) 0.8688(2) 0.0885(2) 0.0674(12) Uani d . 1 1 . .
    H H92 0.3914 0.8235 0.0599 0.081 Uiso calc R 1 1 . .
    C C93 0.45604(17) 0.90829(19) 0.12602(18) 0.0495(9) Uani d . 1 1 . .
    H H93 0.4940 0.8894 0.1233 0.059 Uiso calc R 1 1 . .
    C C94 0.14778(17) 0.42773(16) 0.31172(15) 0.0359(7) Uani d . 1 1 . .
    C C95 0.07871(9) 0.25826(7) 0.38265(9) 0.0282(6) Uani d G 1 1 . .
    C C96 0.09739(9) 0.25617(8) 0.44416(7) 0.0358(7) Uani d G 1 1 . .
    H H96 0.1217 0.2953 0.4817 0.043 Uiso calc R 1 1 . .
    C C97 0.08046(11) 0.19684(10) 0.45073(8) 0.0436(8) Uani d G 1 1 . .
    H H97 0.0932 0.1954 0.4928 0.052 Uiso calc R 1 1 . .
    C C98 0.04483(11) 0.13962(8) 0.39579(11) 0.0454(9) Uani d G 1 1 . .
    H H98 0.0333 0.0991 0.4003 0.055 Uiso calc R 1 1 . .
    C C99 0.02615(10) 0.14171(7) 0.33428(9) 0.0413(8) Uani d G 1 1 . .
    H H99 0.0018 0.1026 0.2967 0.050 Uiso calc R 1 1 . .
    C C100 0.04309(10) 0.20103(9) 0.32772(7) 0.0341(7) Uani d G 1 1 . .
    H H100 0.0303 0.2025 0.2857 0.041 Uiso calc R 1 1 . .
    C C101 0.01423(15) 0.36582(15) 0.40033(13) 0.0298(6) Uani d . 1 1 . .
    C C102 -0.03515(15) 0.32549(15) 0.40886(15) 0.0338(7) Uani d . 1 1 . .
    H H102 -0.0310 0.2818 0.4044 0.041 Uiso calc R 1 1 . .
    C C103 -0.09081(17) 0.34881(17) 0.42397(17) 0.0425(8) Uani d . 1 1 . .
    H H103 -0.1246 0.3208 0.4296 0.051 Uiso calc R 1 1 . .
    C C104 -0.09737(17) 0.41216(17) 0.43088(17) 0.0429(8) Uani d . 1 1 . .
    H H104 -0.1355 0.4279 0.4413 0.052 Uiso calc R 1 1 . .
    C C105 -0.04833(18) 0.45252(17) 0.42263(17) 0.0438(8) Uani d . 1 1 . .
    H H105 -0.0526 0.4962 0.4273 0.053 Uiso calc R 1 1 . .
    C C106 0.00737(17) 0.42973(16) 0.40760(15) 0.0364(7) Uani d . 1 1 . .
    H H106 0.0411 0.4580 0.4022 0.044 Uiso calc R 1 1 . .
    C C107 0.15474(16) 0.39268(15) 0.44692(14) 0.0339(7) Uani d . 1 1 . .
    C C108 0.21837(18) 0.39996(18) 0.43974(17) 0.0465(8) Uani d . 1 1 . .
    H H108 0.2259 0.3786 0.3973 0.056 Uiso calc R 1 1 . .
    C C109 0.2713(2) 0.4382(2) 0.4940(2) 0.0656(12) Uani d . 1 1 . .
    H H109 0.3149 0.4422 0.4889 0.079 Uiso calc R 1 1 . .
    C C110 0.2598(3) 0.4703(2) 0.5555(2) 0.0666(13) Uani d . 1 1 . .
    H H110 0.2957 0.4971 0.5926 0.080 Uiso calc R 1 1 . .
    C C111 0.1968(2) 0.46388(18) 0.56333(17) 0.0545(11) Uani d . 1 1 . .
    H H111 0.1894 0.4862 0.6057 0.065 Uiso calc R 1 1 . .
    C C112 0.14446(19) 0.42505(16) 0.50976(15) 0.0427(8) Uani d . 1 1 . .
    H H112 0.1011 0.4202 0.5155 0.051 Uiso calc R 1 1 . .
    C C113 0.20157(13) 0.16831(14) 0.19164(13) 0.0267(6) Uani d . 1 1 . .
    C C114 0.26218(14) 0.22995(15) 0.23807(14) 0.0306(6) Uani d . 1 1 . .
    C C115 0.19264(9) 0.11448(8) 0.21912(10) 0.0300(6) Uani d G 1 1 . .
    C C116 0.24282(8) 0.08072(10) 0.22697(10) 0.0407(8) Uani d G 1 1 . .
    H H116 0.2839 0.0935 0.2194 0.049 Uiso calc R 1 1 . .
    C C117 0.23286(10) 0.02820(10) 0.24587(11) 0.0488(9) Uani d G 1 1 . .
    H H117 0.2672 0.0051 0.2512 0.059 Uiso calc R 1 1 . .
    C C118 0.17271(11) 0.00945(9) 0.25692(11) 0.0476(9) Uani d G 1 1 . .
    H H118 0.1659 -0.0264 0.2698 0.057 Uiso calc R 1 1 . .
    C C119 0.12252(9) 0.04320(10) 0.24907(11) 0.0440(8) Uani d G 1 1 . .
    H H119 0.0814 0.0304 0.2566 0.053 Uiso calc R 1 1 . .
    C C120 0.13249(8) 0.09572(10) 0.23018(10) 0.0348(7) Uani d G 1 1 . .
    H H120 0.0982 0.1188 0.2248 0.042 Uiso calc R 1 1 . .
    C C121 0.20064(14) 0.13413(15) 0.11772(14) 0.0302(6) Uani d . 1 1 . .
    C C122 0.17908(15) 0.06569(17) 0.08276(14) 0.0363(7) Uani d . 1 1 . .
    H H122 0.1647 0.0396 0.1046 0.044 Uiso calc R 1 1 . .
    C C123 0.17812(17) 0.03434(18) 0.01602(15) 0.0421(8) Uani d . 1 1 . .
    H H123 0.1630 -0.0127 -0.0072 0.051 Uiso calc R 1 1 . .
    C C124 0.19894(17) 0.07119(19) -0.01630(15) 0.0446(8) Uani d . 1 1 . .
    H H124 0.1989 0.0497 -0.0616 0.054 Uiso calc R 1 1 . .
    C C125 0.21982(17) 0.13913(18) 0.01714(15) 0.0406(8) Uani d . 1 1 . .
    H H125 0.2340 0.1647 -0.0052 0.049 Uiso calc R 1 1 . .
    C C126 0.22042(15) 0.17098(17) 0.08366(14) 0.0344(7) Uani d . 1 1 . .
    H H126 0.2344 0.2182 0.1061 0.041 Uiso calc R 1 1 . .
    C C127 0.32285(15) 0.23608(19) 0.21114(15) 0.0379(7) Uani d . 1 1 . .
    C C128 0.35709(18) 0.2994(2) 0.22595(19) 0.0531(10) Uani d . 1 1 . .
    H H128 0.3410 0.3374 0.2495 0.064 Uiso calc R 1 1 . .
    C C129 0.4154(2) 0.3080(3) 0.2066(2) 0.0728(14) Uani d . 1 1 . .
    H H129 0.4383 0.3517 0.2165 0.087 Uiso calc R 1 1 . .
    C C130 0.4396(2) 0.2531(3) 0.1731(2) 0.0730(15) Uani d . 1 1 . .
    H H130 0.4796 0.2590 0.1608 0.088 Uiso calc R 1 1 . .
    C C131 0.40539(19) 0.1898(3) 0.15759(18) 0.0617(13) Uani d . 1 1 . .
    H H131 0.4213 0.1518 0.1337 0.074 Uiso calc R 1 1 . .
    C C132 0.34760(17) 0.1815(2) 0.17701(16) 0.0472(9) Uani d . 1 1 . .
    H H132 0.3247 0.1377 0.1667 0.057 Uiso calc R 1 1 . .
    C C133 0.28359(14) 0.23236(16) 0.30859(14) 0.0325(6) Uani d . 1 1 . .
    C C134 0.23849(15) 0.23868(17) 0.34682(15) 0.0357(7) Uani d . 1 1 . .
    H H134 0.1952 0.2425 0.3297 0.043 Uiso calc R 1 1 . .
    C C135 0.25592(16) 0.23949(18) 0.40963(15) 0.0416(8) Uani d . 1 1 . .
    H H135 0.2245 0.2438 0.4351 0.050 Uiso calc R 1 1 . .
    C C136 0.31843(17) 0.23402(19) 0.43509(16) 0.0438(8) Uani d . 1 1 . .
    H H136 0.3303 0.2344 0.4780 0.053 Uiso calc R 1 1 . .
    C C137 0.36367(17) 0.2280(2) 0.39774(17) 0.0505(9) Uani d . 1 1 . .
    H H137 0.4070 0.2244 0.4151 0.061 Uiso calc R 1 1 . .
    C C138 0.34619(16) 0.2270(2) 0.33488(16) 0.0448(8) Uani d . 1 1 . .
    H H138 0.3777 0.2226 0.3096 0.054 Uiso calc R 1 1 . .
    C C139 0.11452(14) 0.30685(13) 0.11023(13) 0.0249(6) Uani d . 1 1 . .
    C C140 0.14003(15) 0.35849(14) 0.09394(14) 0.0302(6) Uani d . 1 1 . .
    C C141 0.09580(16) 0.37419(15) 0.04957(14) 0.0333(7) Uani d . 1 1 . .
    H H141 0.1115 0.4082 0.0369 0.040 Uiso calc R 1 1 . .
    C C142 0.03095(16) 0.34220(15) 0.02404(13) 0.0313(7) Uani d . 1 1 . .
    C C143 0.00610(15) 0.29394(15) 0.04343(13) 0.0286(6) Uani d . 1 1 . .
    H H143 -0.0393 0.2731 0.0272 0.034 Uiso calc R 1 1 . .
    C C144 0.04787(14) 0.27602(13) 0.08684(12) 0.0244(6) Uani d . 1 1 . .
    C C145 0.01722(13) 0.22148(13) 0.10247(12) 0.0238(5) Uani d . 1 1 . .
    C C146 0.03493(13) 0.15995(14) 0.07974(13) 0.0253(6) Uani d . 1 1 . .
    H H146 0.0682 0.1533 0.0564 0.030 Uiso calc R 1 1 . .
    C C147 0.00396(14) 0.10776(14) 0.09116(13) 0.0274(6) Uani d . 1 1 . .
    C C148 -0.04746(14) 0.11583(14) 0.12117(13) 0.0283(6) Uani d . 1 1 . .
    H H148 -0.0693 0.0791 0.1268 0.034 Uiso calc R 1 1 . .
    C C149 -0.06831(14) 0.17682(14) 0.14359(13) 0.0271(6) Uani d . 1 1 . .
    C C150 -0.03293(14) 0.23007(13) 0.13598(13) 0.0253(6) Uani d . 1 1 . .
    C C151 0.21271(17) 0.39603(16) 0.11998(16) 0.0382(7) Uani d . 1 1 . .
    C C152 0.23336(19) 0.42886(19) 0.19566(17) 0.0486(9) Uani d . 1 1 . .
    H H15A 0.2313 0.3942 0.2127 0.073 Uiso calc R 1 1 . .
    H H15B 0.2035 0.4582 0.2119 0.073 Uiso calc R 1 1 . .
    H H15C 0.2785 0.4552 0.2109 0.073 Uiso calc R 1 1 . .
    C C153 0.2238(2) 0.4533(2) 0.0976(2) 0.0572(10) Uani d . 1 1 . .
    H H15D 0.1946 0.4839 0.1126 0.086 Uiso calc R 1 1 . .
    H H15E 0.2142 0.4347 0.0491 0.086 Uiso calc R 1 1 . .
    H H15F 0.2698 0.4777 0.1168 0.086 Uiso calc R 1 1 . .
    C C154 0.25774(18) 0.34884(19) 0.0937(2) 0.0536(10) Uani d . 1 1 . .
    H H15G 0.3033 0.3741 0.1085 0.080 Uiso calc R 1 1 . .
    H H15H 0.2440 0.3280 0.0452 0.080 Uiso calc R 1 1 . .
    H H15I 0.2549 0.3141 0.1105 0.080 Uiso calc R 1 1 . .
    C C155 0.0104(2) 0.40039(19) -0.04448(18) 0.0515(10) Uani d . 1 1 . .
    H H15J 0.0248 0.4444 -0.0071 0.077 Uiso calc R 1 1 . .
    H H15K -0.0250 0.4020 -0.0786 0.077 Uiso calc R 1 1 . .
    H H15L 0.0476 0.3881 -0.0630 0.077 Uiso calc R 1 1 . .
    C C156 -0.00040(17) -0.00332(15) 0.08294(17) 0.0402(7) Uani d . 1 1 . .
    H H15M 0.0030 0.0120 0.1304 0.060 Uiso calc R 1 1 . .
    H H15N 0.0231 -0.0398 0.0689 0.060 Uiso calc R 1 1 . .
    H H15O -0.0469 -0.0193 0.0582 0.060 Uiso calc R 1 1 . .
    C C157 -0.12895(15) 0.18259(15) 0.17211(15) 0.0333(6) Uani d . 1 1 . .
    C C158 -0.16003(18) 0.11615(17) 0.17183(18) 0.0461(8) Uani d . 1 1 . .
    H H15P -0.1731 0.0815 0.1264 0.069 Uiso calc R 1 1 . .
    H H15Q -0.1989 0.1215 0.1893 0.069 Uiso calc R 1 1 . .
    H H15R -0.1279 0.1030 0.1996 0.069 Uiso calc R 1 1 . .
    C C159 -0.18161(16) 0.2013(2) 0.12850(18) 0.0481(9) Uani d . 1 1 . .
    H H15S -0.1915 0.1686 0.0824 0.072 Uiso calc R 1 1 . .
    H H15T -0.1650 0.2459 0.1314 0.072 Uiso calc R 1 1 . .
    H H15U -0.2218 0.2014 0.1440 0.072 Uiso calc R 1 1 . .
    C C160 -0.11179(17) 0.23403(16) 0.24380(15) 0.0387(7) Uani d . 1 1 . .
    H H16A -0.1523 0.2395 0.2584 0.058 Uiso calc R 1 1 . .
    H H16B -0.0893 0.2770 0.2471 0.058 Uiso calc R 1 1 . .
    H H16C -0.0827 0.2187 0.2720 0.058 Uiso calc R 1 1 . .
    C C161 -0.03418(15) 0.45161(14) 0.17801(14) 0.0296(6) Uani d . 1 1 . .
    C C162 -0.06867(16) 0.45134(15) 0.23706(14) 0.0339(7) Uani d . 1 1 . .
    C C163 0.00807(16) 0.51957(15) 0.19385(14) 0.0326(7) Uani d . 1 1 . .
    C C164 -0.01801(17) 0.57729(15) 0.21039(14) 0.0351(7) Uani d . 1 1 . .
    H H164 -0.0627 0.5745 0.2123 0.042 Uiso calc R 1 1 . .
    C C165 0.0205(2) 0.63833(16) 0.22394(16) 0.0451(8) Uani d . 1 1 . .
    H H165 0.0020 0.6770 0.2350 0.054 Uiso calc R 1 1 . .
    C C166 0.0854(2) 0.64360(18) 0.22156(19) 0.0510(9) Uani d . 1 1 . .
    H H166 0.1121 0.6857 0.2319 0.061 Uiso calc R 1 1 . .
    C C167 0.1110(2) 0.58625(18) 0.20382(19) 0.0513(9) Uani d . 1 1 . .
    H H167 0.1554 0.5891 0.2010 0.062 Uiso calc R 1 1 . .
    C C168 0.07275(17) 0.52500(16) 0.19012(16) 0.0384(7) Uani d . 1 1 . .
    H H168 0.0912 0.4863 0.1780 0.046 Uiso calc R 1 1 . .
    C C169 -0.08256(15) 0.42383(15) 0.10878(14) 0.0315(6) Uani d . 1 1 . .
    C C170 -0.12519(16) 0.36185(17) 0.08348(17) 0.0404(7) Uani d . 1 1 . .
    H H170 -0.1243 0.3364 0.1092 0.048 Uiso calc R 1 1 . .
    C C171 -0.16906(18) 0.33647(19) 0.02126(19) 0.0496(9) Uani d . 1 1 . .
    H H171 -0.1972 0.2937 0.0047 0.059 Uiso calc R 1 1 . .
    C C172 -0.1721(2) 0.3727(2) -0.01670(18) 0.0519(9) Uani d . 1 1 . .
    H H172 -0.2029 0.3558 -0.0588 0.062 Uiso calc R 1 1 . .
    C C173 -0.12977(19) 0.43401(19) 0.00750(16) 0.0459(9) Uani d . 1 1 . .
    H H173 -0.1312 0.4593 -0.0184 0.055 Uiso calc R 1 1 . .
    C C174 -0.08501(17) 0.45926(16) 0.06938(14) 0.0369(7) Uani d . 1 1 . .
    H H174 -0.0557 0.5012 0.0849 0.044 Uiso calc R 1 1 . .
    C C175 -0.04194(11) 0.51649(8) 0.30102(9) 0.0416(8) Uani d G 1 1 . .
    C C176 0.02482(11) 0.53268(10) 0.33272(10) 0.0450(9) Uani d G 1 1 . .
    H H176 0.0527 0.5036 0.3155 0.054 Uiso calc R 1 1 . .
    C C177 0.05072(12) 0.59142(11) 0.38958(10) 0.0607(11) Uani d G 1 1 . .
    H H177 0.0963 0.6025 0.4112 0.073 Uiso calc R 1 1 . .
    C C178 0.00987(16) 0.63398(9) 0.41475(9) 0.0757(16) Uani d G 1 1 . .
    H H178 0.0276 0.6741 0.4536 0.091 Uiso calc R 1 1 . .
    C C179 -0.05689(15) 0.61779(11) 0.38305(12) 0.0752(16) Uani d G 1 1 . .
    H H179 -0.0848 0.6469 0.4003 0.090 Uiso calc R 1 1 . .
    C C180 -0.08280(11) 0.55904(12) 0.32619(11) 0.0553(11) Uani d G 1 1 . .
    H H180 -0.1284 0.5480 0.3045 0.066 Uiso calc R 1 1 . .
    O O1 0.52189(12) 0.80423(14) 0.24419(13) 0.0511(6) Uani d . 1 1 . .
    O O2 0.70751(9) 0.75800(10) 0.22791(9) 0.0278(4) Uani d . 1 1 . .
    O O3 0.79497(9) 0.85067(9) 0.26313(9) 0.0242(4) Uani d . 1 1 . .
    O O4 0.70120(10) 0.82558(10) 0.16318(9) 0.0279(4) Uani d . 1 1 . .
    O O5 0.60947(13) 0.96466(13) 0.01826(11) 0.0490(6) Uani d . 1 1 . .
    O O6 0.93927(11) 0.98817(11) 0.26420(13) 0.0479(6) Uani d . 1 1 . .
    O O7 0.59318(9) 1.03691(10) 0.31967(9) 0.0291(4) Uani d . 1 1 . .
    O O8 0.57541(9) 0.97188(10) 0.20592(9) 0.0284(4) Uani d . 1 1 . .
    O O9 0.69029(9) 1.03652(10) 0.27378(9) 0.0272(4) Uani d . 1 1 . .
    O O10 0.18001(15) 0.48054(13) 0.33593(13) 0.0581(7) Uani d . 1 1 . .
    O O11 0.14430(9) 0.19901(9) 0.19634(9) 0.0245(4) Uani d . 1 1 . .
    O O12 0.23554(9) 0.28976(10) 0.24581(10) 0.0296(4) Uani d . 1 1 . .
    O O13 0.15871(9) 0.28411(10) 0.14680(9) 0.0266(4) Uani d . 1 1 . .
    O O14 -0.01313(12) 0.35224(11) -0.02241(10) 0.0406(5) Uani d . 1 1 . .
    O O15 0.02806(11) 0.05070(10) 0.07027(11) 0.0349(5) Uani d . 1 1 . .
    O O16 0.01124(10) 0.40691(10) 0.17689(9) 0.0291(4) Uani d . 1 1 . .
    O O17 -0.04602(10) 0.39883(10) 0.25383(9) 0.0299(4) Uani d . 1 1 . .
    O O18 -0.04884(9) 0.29258(9) 0.16054(9) 0.0270(4) Uani d . 1 1 . .
    P P1 0.66318(4) 0.91475(4) 0.40864(3) 0.02728(16) Uani d . 1 1 . .
    P P2 0.71557(3) 0.83615(4) 0.24085(3) 0.02297(14) Uani d . 1 1 . .
    P P3 0.62843(3) 0.98398(4) 0.27309(3) 0.02525(15) Uani d . 1 1 . .
    P P4 0.08712(4) 0.33859(4) 0.37468(3) 0.02542(15) Uani d . 1 1 . .
    P P5 0.00459(4) 0.35991(4) 0.21620(3) 0.02480(15) Uani d . 1 1 . .
    P P6 0.15651(3) 0.27847(4) 0.21677(3) 0.02324(14) Uani d . 1 1 . .
    Rh Rh1 0.656131(10) 0.900667(11) 0.300209(10) 0.02435(6) Uani d . 1 1 . .
    Rh Rh2 0.093304(11) 0.340364(10) 0.273920(10) 0.02364(6) Uani d . 1 1 . .
    O O20 0.1879(3) 0.7752(3) 0.3581(3) 0.0785(18) Uiso d PD 0.50 1 . .
    C C192 0.1299(5) 0.8518(4) 0.3392(5) 0.072(2) Uiso d PD 0.50 1 . .
    H H19D 0.0942 0.8754 0.3484 0.108 Uiso calc PR 0.50 1 . .
    H H19E 0.1209 0.8249 0.2915 0.108 Uiso calc PR 0.50 1 . .
    H H19F 0.1716 0.8843 0.3544 0.108 Uiso calc PR 0.50 1 . .
    C C191 0.1348(5) 0.8064(5) 0.3754(5) 0.090(3) Uiso d PD 0.50 1 . .
    H H19G 0.1445 0.8326 0.4238 0.108 Uiso calc PR 0.50 1 . .
    H H19H 0.0933 0.7727 0.3605 0.108 Uiso calc PR 0.50 1 . .
    C C193 0.1918(5) 0.7289(5) 0.3884(5) 0.080(3) Uiso d PD 0.50 1 . .
    H H19I 0.1503 0.6949 0.3709 0.096 Uiso calc PR 0.50 1 . .
    H H19J 0.1996 0.7526 0.4370 0.096 Uiso calc PR 0.50 1 . .
    C C194 0.2489(7) 0.6960(8) 0.3717(8) 0.149(6) Uiso d PD 0.50 1 . .
    H H19K 0.2531 0.6635 0.3912 0.223 Uiso calc PR 0.50 1 . .
    H H19L 0.2898 0.7302 0.3897 0.223 Uiso calc PR 0.50 1 . .
    H H19M 0.2408 0.6732 0.3235 0.223 Uiso calc PR 0.50 1 . .
    H H1 0.7142(18) 0.9498(19) 0.3316(18) 0.059(11) Uiso d . 1 1 . .
    H H2 0.0502(18) 0.2781(18) 0.2480(18) 0.053(10) Uiso d . 1 1 . .
_geom_special_details
;
All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C181 C182 . 1.3900 ?
    C181 C186 . 1.3900 ?
    C181 C162 . 1.528(4) ?
    C182 C183 . 1.3900 ?
    C182 H182 . 0.9500 ?
    C183 C184 . 1.3900 ?
    C183 H183 . 0.9500 ?
    C184 C185 . 1.3900 ?
    C184 H184 . 0.9500 ?
    C185 C186 . 1.3900 ?
    C185 H185 . 0.9500 ?
    C186 H186 . 0.9500 ?
    O19 C187 . 1.417(2) ?
    O19 C189 . 1.417(2) ?
    C187 C188 . 1.517(2) ?
    C187 H18A . 0.9900 ?
    C187 H18B . 0.9900 ?
    C188 H18C . 0.9800 ?
    C188 H18D . 0.9800 ?
    C188 H18E . 0.9800 ?
    C189 C190 . 1.518(2) ?
    C189 H18F . 0.9900 ?
    C189 H18G . 0.9900 ?
    C190 H19A . 0.9800 ?
    C190 H19B . 0.9800 ?
    C190 H19C . 0.9800 ?
    C1 O1 . 1.145(4) ?
    C1 Rh1 . 1.914(4) ?
    C2 C3 . 1.3900 ?
    C2 C7 . 1.3900 ?
    C2 P1 . 1.8483(15) ?
    C3 C4 . 1.3900 ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.3900 ?
    C4 H4 . 0.9500 ?
    C5 C6 . 1.3900 ?
    C5 H5 . 0.9500 ?
    C6 C7 . 1.3900 ?
    C6 H6 . 0.9500 ?
    C7 H7 . 0.9500 ?
    C8 C9 . 1.3900 ?
    C8 C13 . 1.3900 ?
    C8 P1 . 1.8423(16) ?
    C9 C10 . 1.3900 ?
    C9 H9 . 0.9500 ?
    C10 C11 . 1.3900 ?
    C10 H10 . 0.9500 ?
    C11 C12 . 1.3900 ?
    C11 H11 . 0.9500 ?
    C12 C13 . 1.3900 ?
    C12 H12 . 0.9500 ?
    C13 H13 . 0.9500 ?
    C14 C15 . 1.3900 ?
    C14 C19 . 1.3900 ?
    C14 P1 . 1.8514(15) ?
    C15 C16 . 1.3900 ?
    C15 H15 . 0.9500 ?
    C16 C17 . 1.3900 ?
    C16 H16 . 0.9500 ?
    C17 C18 . 1.3900 ?
    C17 H17 . 0.9500 ?
    C18 C19 . 1.3900 ?
    C18 H18 . 0.9500 ?
    C19 H19 . 0.9500 ?
    C20 O2 . 1.461(3) ?
    C20 C28 . 1.539(3) ?
    C20 C22 . 1.540(4) ?
    C20 C21 . 1.619(4) ?
    C21 O3 . 1.456(3) ?
    C21 C40 . 1.530(4) ?
    C21 C34 . 1.548(4) ?
    C22 C27 . 1.381(4) ?
    C22 C23 . 1.395(4) ?
    C23 C24 . 1.389(4) ?
    C23 H23 . 0.9500 ?
    C24 C25 . 1.387(4) ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.373(5) ?
    C25 H25 . 0.9500 ?
    C26 C27 . 1.395(4) ?
    C26 H26 . 0.9500 ?
    C27 H27 . 0.9500 ?
    C28 C29 . 1.3900 ?
    C28 C33 . 1.3900 ?
    C29 C30 . 1.3900 ?
    C29 H29 . 0.9500 ?
    C30 C31 . 1.3900 ?
    C30 H30 . 0.9500 ?
    C31 C32 . 1.3900 ?
    C31 H31 . 0.9500 ?
    C32 C33 . 1.3900 ?
    C32 H32 . 0.9500 ?
    C33 H33 . 0.9500 ?
    C34 C35 . 1.392(4) ?
    C34 C39 . 1.394(4) ?
    C35 C36 . 1.393(4) ?
    C35 H35 . 0.9500 ?
    C36 C37 . 1.384(5) ?
    C36 H36 . 0.9500 ?
    C37 C38 . 1.375(5) ?
    C37 H37 . 0.9500 ?
    C38 C39 . 1.389(4) ?
    C38 H38 . 0.9500 ?
    C39 H39 . 0.9500 ?
    C40 C45 . 1.386(4) ?
    C40 C41 . 1.398(4) ?
    C41 C42 . 1.381(5) ?
    C41 H41 . 0.9500 ?
    C42 C43 . 1.381(5) ?
    C42 H42 . 0.9500 ?
    C43 C44 . 1.387(5) ?
    C43 H43 . 0.9500 ?
    C44 C45 . 1.388(4) ?
    C44 H44 . 0.9500 ?
    C45 H45 . 0.9500 ?
    C46 C51 . 1.386(4) ?
    C46 O4 . 1.404(3) ?
    C46 C47 . 1.410(4) ?
    C47 C48 . 1.395(4) ?
    C47 C58 . 1.533(5) ?
    C48 C49 . 1.368(5) ?
    C48 H48 . 0.9500 ?
    C49 C50 . 1.378(4) ?
    C49 O5 . 1.388(3) ?
    C50 C51 . 1.406(4) ?
    C50 H50 . 0.9500 ?
    C51 C52 . 1.498(4) ?
    C52 C57 . 1.395(4) ?
    C52 C53 . 1.398(4) ?
    C53 C54 . 1.378(4) ?
    C53 H53 . 0.9500 ?
    C54 O6 . 1.382(3) ?
    C54 C55 . 1.393(4) ?
    C55 C56 . 1.393(4) ?
    C55 H55 . 0.9500 ?
    C56 C57 . 1.405(4) ?
    C56 C64 . 1.533(4) ?
    C57 O9 . 1.395(3) ?
    C58 C61 . 1.532(4) ?
    C58 C60 . 1.535(5) ?
    C58 C59 . 1.544(5) ?
    C59 H59A . 0.9800 ?
    C59 H59B . 0.9800 ?
    C59 H59C . 0.9800 ?
    C60 H60A . 0.9800 ?
    C60 H60B . 0.9800 ?
    C60 H60C . 0.9800 ?
    C61 H61A . 0.9800 ?
    C61 H61B . 0.9800 ?
    C61 H61C . 0.9800 ?
    C62 O5 . 1.413(5) ?
    C62 H62A . 0.9800 ?
    C62 H62B . 0.9800 ?
    C62 H62C . 0.9800 ?
    C63 O6 . 1.440(4) ?
    C63 H63A . 0.9800 ?
    C63 H63B . 0.9800 ?
    C63 H63C . 0.9800 ?
    C64 C65 . 1.530(5) ?
    C64 C66 . 1.537(4) ?
    C64 C67 . 1.538(4) ?
    C65 H65A . 0.9800 ?
    C65 H65B . 0.9800 ?
    C65 H65C . 0.9800 ?
    C66 H66A . 0.9800 ?
    C66 H66B . 0.9800 ?
    C66 H66C . 0.9800 ?
    C67 H67A . 0.9800 ?
    C67 H67B . 0.9800 ?
    C67 H67C . 0.9800 ?
    C68 O7 . 1.456(3) ?
    C68 C70 . 1.529(3) ?
    C68 C76 . 1.560(3) ?
    C68 C69 . 1.631(4) ?
    C69 O8 . 1.462(3) ?
    C69 C88 . 1.525(4) ?
    C69 C82 . 1.553(3) ?
    C70 C71 . 1.3900 ?
    C70 C75 . 1.3900 ?
    C71 C72 . 1.3900 ?
    C71 H71 . 0.9500 ?
    C72 C73 . 1.3900 ?
    C72 H72 . 0.9500 ?
    C73 C74 . 1.3900 ?
    C73 H73 . 0.9500 ?
    C74 C75 . 1.3900 ?
    C74 H74 . 0.9500 ?
    C75 H75 . 0.9500 ?
    C76 C77 . 1.3900 ?
    C76 C81 . 1.3900 ?
    C77 C78 . 1.3900 ?
    C77 H77 . 0.9500 ?
    C78 C79 . 1.3900 ?
    C78 H78 . 0.9500 ?
    C79 C80 . 1.3900 ?
    C79 H79 . 0.9500 ?
    C80 C81 . 1.3900 ?
    C80 H80 . 0.9500 ?
    C81 H81 . 0.9500 ?
    C82 C83 . 1.3900 ?
    C82 C87 . 1.3900 ?
    C83 C84 . 1.3900 ?
    C83 H83 . 0.9500 ?
    C84 C85 . 1.3900 ?
    C84 H84 . 0.9500 ?
    C85 C86 . 1.3900 ?
    C85 H85 . 0.9500 ?
    C86 C87 . 1.3900 ?
    C86 H86 . 0.9500 ?
    C87 H87 . 0.9500 ?
    C88 C93 . 1.382(5) ?
    C88 C89 . 1.403(4) ?
    C89 C90 . 1.384(5) ?
    C89 H89 . 0.9500 ?
    C90 C91 . 1.380(6) ?
    C90 H90 . 0.9500 ?
    C91 C92 . 1.378(6) ?
    C91 H91 . 0.9500 ?
    C92 C93 . 1.379(5) ?
    C92 H92 . 0.9500 ?
    C93 H93 . 0.9500 ?
    C94 O10 . 1.145(4) ?
    C94 Rh2 . 1.907(3) ?
    C95 C96 . 1.3900 ?
    C95 C100 . 1.3900 ?
    C95 P4 . 1.8455(14) ?
    C96 C97 . 1.3900 ?
    C96 H96 . 0.9500 ?
    C97 C98 . 1.3900 ?
    C97 H97 . 0.9500 ?
    C98 C99 . 1.3900 ?
    C98 H98 . 0.9500 ?
    C99 C100 . 1.3900 ?
    C99 H99 . 0.9500 ?
    C100 H100 . 0.9500 ?
    C101 C102 . 1.384(4) ?
    C101 C106 . 1.389(4) ?
    C101 P4 . 1.838(3) ?
    C102 C103 . 1.391(4) ?
    C102 H102 . 0.9500 ?
    C103 C104 . 1.377(5) ?
    C103 H103 . 0.9500 ?
    C104 C105 . 1.376(5) ?
    C104 H104 . 0.9500 ?
    C105 C106 . 1.387(4) ?
    C105 H105 . 0.9500 ?
    C106 H106 . 0.9500 ?
    C107 C108 . 1.385(5) ?
    C107 C112 . 1.400(4) ?
    C107 P4 . 1.832(3) ?
    C108 C109 . 1.390(5) ?
    C108 H108 . 0.9500 ?
    C109 C110 . 1.385(6) ?
    C109 H109 . 0.9500 ?
    C110 C111 . 1.376(6) ?
    C110 H110 . 0.9500 ?
    C111 C112 . 1.378(5) ?
    C111 H111 . 0.9500 ?
    C112 H112 . 0.9500 ?
    C113 O11 . 1.460(3) ?
    C113 C121 . 1.545(4) ?
    C113 C115 . 1.548(3) ?
    C113 C114 . 1.608(4) ?
    C114 O12 . 1.462(3) ?
    C114 C127 . 1.536(4) ?
    C114 C133 . 1.549(4) ?
    C115 C116 . 1.3900 ?
    C115 C120 . 1.3900 ?
    C116 C117 . 1.3900 ?
    C116 H116 . 0.9500 ?
    C117 C118 . 1.3900 ?
    C117 H117 . 0.9500 ?
    C118 C119 . 1.3900 ?
    C118 H118 . 0.9500 ?
    C119 C120 . 1.3900 ?
    C119 H119 . 0.9500 ?
    C120 H120 . 0.9500 ?
    C121 C122 . 1.384(4) ?
    C121 C126 . 1.398(4) ?
    C122 C123 . 1.395(4) ?
    C122 H122 . 0.9500 ?
    C123 C124 . 1.373(5) ?
    C123 H123 . 0.9500 ?
    C124 C125 . 1.370(5) ?
    C124 H124 . 0.9500 ?
    C125 C126 . 1.394(4) ?
    C125 H125 . 0.9500 ?
    C126 H126 . 0.9500 ?
    C127 C128 . 1.383(5) ?
    C127 C132 . 1.387(5) ?
    C128 C129 . 1.403(5) ?
    C128 H128 . 0.9500 ?
    C129 C130 . 1.382(7) ?
    C129 H129 . 0.9500 ?
    C130 C131 . 1.380(7) ?
    C130 H130 . 0.9500 ?
    C131 C132 . 1.392(5) ?
    C131 H131 . 0.9500 ?
    C132 H132 . 0.9500 ?
    C133 C138 . 1.381(4) ?
    C133 C134 . 1.391(4) ?
    C134 C135 . 1.389(4) ?
    C134 H134 . 0.9500 ?
    C135 C136 . 1.376(4) ?
    C135 H135 . 0.9500 ?
    C136 C137 . 1.380(5) ?
    C136 H136 . 0.9500 ?
    C137 C138 . 1.389(4) ?
    C137 H137 . 0.9500 ?
    C138 H138 . 0.9500 ?
    C139 O13 . 1.393(3) ?
    C139 C144 . 1.395(4) ?
    C139 C140 . 1.409(4) ?
    C140 C141 . 1.408(4) ?
    C140 C151 . 1.543(5) ?
    C141 C142 . 1.368(5) ?
    C141 H141 . 0.9500 ?
    C142 O14 . 1.367(3) ?
    C142 C143 . 1.386(4) ?
    C143 C144 . 1.394(4) ?
    C143 H143 . 0.9500 ?
    C144 C145 . 1.494(4) ?
    C145 C146 . 1.386(4) ?
    C145 C150 . 1.409(4) ?
    C146 C147 . 1.394(4) ?
    C146 H146 . 0.9500 ?
    C147 O15 . 1.367(3) ?
    C147 C148 . 1.384(4) ?
    C148 C149 . 1.407(4) ?
    C148 H148 . 0.9500 ?
    C149 C150 . 1.405(4) ?
    C149 C157 . 1.541(4) ?
    C150 O18 . 1.390(3) ?
    C151 C154 . 1.527(5) ?
    C151 C152 . 1.528(5) ?
    C151 C153 . 1.544(4) ?
    C152 H15A . 0.9800 ?
    C152 H15B . 0.9800 ?
    C152 H15C . 0.9800 ?
    C153 H15D . 0.9800 ?
    C153 H15E . 0.9800 ?
    C153 H15F . 0.9800 ?
    C154 H15G . 0.9800 ?
    C154 H15H . 0.9800 ?
    C154 H15I . 0.9800 ?
    C155 O14 . 1.417(4) ?
    C155 H15J . 0.9800 ?
    C155 H15K . 0.9800 ?
    C155 H15L . 0.9800 ?
    C156 O15 . 1.425(4) ?
    C156 H15M . 0.9800 ?
    C156 H15N . 0.9800 ?
    C156 H15O . 0.9800 ?
    C157 C160 . 1.525(4) ?
    C157 C158 . 1.536(4) ?
    C157 C159 . 1.542(4) ?
    C158 H15P . 0.9800 ?
    C158 H15Q . 0.9800 ?
    C158 H15R . 0.9800 ?
    C159 H15S . 0.9800 ?
    C159 H15T . 0.9800 ?
    C159 H15U . 0.9800 ?
    C160 H16A . 0.9800 ?
    C160 H16B . 0.9800 ?
    C160 H16C . 0.9800 ?
    C161 O16 . 1.455(3) ?
    C161 C163 . 1.530(4) ?
    C161 C169 . 1.542(4) ?
    C161 C162 . 1.642(4) ?
    C162 O17 . 1.456(3) ?
    C162 C175 . 1.548(4) ?
    C163 C168 . 1.382(4) ?
    C163 C164 . 1.399(4) ?
    C164 C165 . 1.383(5) ?
    C164 H164 . 0.9500 ?
    C165 C166 . 1.379(5) ?
    C165 H165 . 0.9500 ?
    C166 C167 . 1.387(5) ?
    C166 H166 . 0.9500 ?
    C167 C168 . 1.384(5) ?
    C167 H167 . 0.9500 ?
    C168 H168 . 0.9500 ?
    C169 C174 . 1.390(4) ?
    C169 C170 . 1.391(5) ?
    C170 C171 . 1.388(5) ?
    C170 H170 . 0.9500 ?
    C171 C172 . 1.378(5) ?
    C171 H171 . 0.9500 ?
    C172 C173 . 1.379(5) ?
    C172 H172 . 0.9500 ?
    C173 C174 . 1.391(5) ?
    C173 H173 . 0.9500 ?
    C174 H174 . 0.9500 ?
    C175 C176 . 1.3900 ?
    C175 C180 . 1.3900 ?
    C176 C177 . 1.3900 ?
    C176 H176 . 0.9500 ?
    C177 C178 . 1.3900 ?
    C177 H177 . 0.9500 ?
    C178 C179 . 1.3900 ?
    C178 H178 . 0.9500 ?
    C179 C180 . 1.3900 ?
    C179 H179 . 0.9500 ?
    C180 H180 . 0.9500 ?
    O2 P2 . 1.622(2) ?
    O3 P2 . 1.6135(19) ?
    O4 P2 . 1.6412(18) ?
    O7 P3 . 1.6150(19) ?
    O8 P3 . 1.6117(19) ?
    O9 P3 . 1.639(2) ?
    O11 P6 . 1.6130(19) ?
    O12 P6 . 1.626(2) ?
    O13 P6 . 1.6419(18) ?
    O16 P5 . 1.6148(18) ?
    O17 P5 . 1.6199(18) ?
    O18 P5 . 1.646(2) ?
    P1 Rh1 . 2.3221(7) ?
    P2 Rh1 . 2.2447(7) ?
    P3 Rh1 . 2.2569(7) ?
    P4 Rh2 . 2.3209(7) ?
    P5 Rh2 . 2.2555(7) ?
    P6 Rh2 . 2.2553(7) ?
    Rh1 H1 . 1.40(4) ?
    Rh2 H2 . 1.40(4) ?
    O20 C191 . 1.429(8) ?
    O20 C193 . 1.433(8) ?
    C192 C191 . 1.517(2) ?
    C192 H19D . 0.9800 ?
    C192 H19E . 0.9800 ?
    C192 H19F . 0.9800 ?
    C191 H19G . 0.9900 ?
    C191 H19H . 0.9900 ?
    C193 C194 . 1.519(2) ?
    C193 H19I . 0.9900 ?
    C193 H19J . 0.9900 ?
    C194 H19K . 0.9800 ?
    C194 H19L . 0.9800 ?
    C194 H19M . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C182 C181 C186 . . 120.0 ?
    C182 C181 C162 . . 121.45(18) ?
    C186 C181 C162 . . 118.41(18) ?
    C183 C182 C181 . . 120.0 ?
    C183 C182 H182 . . 120.0 ?
    C181 C182 H182 . . 120.0 ?
    C184 C183 C182 . . 120.0 ?
    C184 C183 H183 . . 120.0 ?
    C182 C183 H183 . . 120.0 ?
    C183 C184 C185 . . 120.0 ?
    C183 C184 H184 . . 120.0 ?
    C185 C184 H184 . . 120.0 ?
    C186 C185 C184 . . 120.0 ?
    C186 C185 H185 . . 120.0 ?
    C184 C185 H185 . . 120.0 ?
    C185 C186 C181 . . 120.0 ?
    C185 C186 H186 . . 120.0 ?
    C181 C186 H186 . . 120.0 ?
    C187 O19 C189 . . 107.0(7) ?
    O19 C187 C188 . . 105.6(6) ?
    O19 C187 H18A . . 110.6 ?
    C188 C187 H18A . . 110.6 ?
    O19 C187 H18B . . 110.6 ?
    C188 C187 H18B . . 110.6 ?
    H18A C187 H18B . . 108.7 ?
    C187 C188 H18C . . 109.5 ?
    C187 C188 H18D . . 109.5 ?
    H18C C188 H18D . . 109.5 ?
    C187 C188 H18E . . 109.5 ?
    H18C C188 H18E . . 109.5 ?
    H18D C188 H18E . . 109.5 ?
    O19 C189 C190 . . 102.6(7) ?
    O19 C189 H18F . . 111.2 ?
    C190 C189 H18F . . 111.2 ?
    O19 C189 H18G . . 111.2 ?
    C190 C189 H18G . . 111.2 ?
    H18F C189 H18G . . 109.2 ?
    C189 C190 H19A . . 109.5 ?
    C189 C190 H19B . . 109.5 ?
    H19A C190 H19B . . 109.5 ?
    C189 C190 H19C . . 109.5 ?
    H19A C190 H19C . . 109.5 ?
    H19B C190 H19C . . 109.5 ?
    O1 C1 Rh1 . . 178.3(3) ?
    C3 C2 C7 . . 120.0 ?
    C3 C2 P1 . . 117.11(11) ?
    C7 C2 P1 . . 122.83(11) ?
    C4 C3 C2 . . 120.0 ?
    C4 C3 H3 . . 120.0 ?
    C2 C3 H3 . . 120.0 ?
    C3 C4 C5 . . 120.0 ?
    C3 C4 H4 . . 120.0 ?
    C5 C4 H4 . . 120.0 ?
    C6 C5 C4 . . 120.0 ?
    C6 C5 H5 . . 120.0 ?
    C4 C5 H5 . . 120.0 ?
    C5 C6 C7 . . 120.0 ?
    C5 C6 H6 . . 120.0 ?
    C7 C6 H6 . . 120.0 ?
    C6 C7 C2 . . 120.0 ?
    C6 C7 H7 . . 120.0 ?
    C2 C7 H7 . . 120.0 ?
    C9 C8 C13 . . 120.0 ?
    C9 C8 P1 . . 121.94(11) ?
    C13 C8 P1 . . 118.05(11) ?
    C8 C9 C10 . . 120.0 ?
    C8 C9 H9 . . 120.0 ?
    C10 C9 H9 . . 120.0 ?
    C11 C10 C9 . . 120.0 ?
    C11 C10 H10 . . 120.0 ?
    C9 C10 H10 . . 120.0 ?
    C10 C11 C12 . . 120.0 ?
    C10 C11 H11 . . 120.0 ?
    C12 C11 H11 . . 120.0 ?
    C11 C12 C13 . . 120.0 ?
    C11 C12 H12 . . 120.0 ?
    C13 C12 H12 . . 120.0 ?
    C12 C13 C8 . . 120.0 ?
    C12 C13 H13 . . 120.0 ?
    C8 C13 H13 . . 120.0 ?
    C15 C14 C19 . . 120.0 ?
    C15 C14 P1 . . 120.13(11) ?
    C19 C14 P1 . . 118.69(11) ?
    C14 C15 C16 . . 120.0 ?
    C14 C15 H15 . . 120.0 ?
    C16 C15 H15 . . 120.0 ?
    C17 C16 C15 . . 120.0 ?
    C17 C16 H16 . . 120.0 ?
    C15 C16 H16 . . 120.0 ?
    C16 C17 C18 . . 120.0 ?
    C16 C17 H17 . . 120.0 ?
    C18 C17 H17 . . 120.0 ?
    C17 C18 C19 . . 120.0 ?
    C17 C18 H18 . . 120.0 ?
    C19 C18 H18 . . 120.0 ?
    C18 C19 C14 . . 120.0 ?
    C18 C19 H19 . . 120.0 ?
    C14 C19 H19 . . 120.0 ?
    O2 C20 C28 . . 107.8(2) ?
    O2 C20 C22 . . 104.6(2) ?
    C28 C20 C22 . . 110.0(2) ?
    O2 C20 C21 . . 104.92(19) ?
    C28 C20 C21 . . 114.3(2) ?
    C22 C20 C21 . . 114.4(2) ?
    O3 C21 C40 . . 105.8(2) ?
    O3 C21 C34 . . 107.8(2) ?
    C40 C21 C34 . . 107.5(2) ?
    O3 C21 C20 . . 104.0(2) ?
    C40 C21 C20 . . 117.2(2) ?
    C34 C21 C20 . . 113.8(2) ?
    C27 C22 C23 . . 118.3(3) ?
    C27 C22 C20 . . 122.6(3) ?
    C23 C22 C20 . . 119.1(2) ?
    C24 C23 C22 . . 120.8(3) ?
    C24 C23 H23 . . 119.6 ?
    C22 C23 H23 . . 119.6 ?
    C25 C24 C23 . . 120.1(3) ?
    C25 C24 H24 . . 119.9 ?
    C23 C24 H24 . . 119.9 ?
    C26 C25 C24 . . 119.5(3) ?
    C26 C25 H25 . . 120.2 ?
    C24 C25 H25 . . 120.2 ?
    C25 C26 C27 . . 120.3(3) ?
    C25 C26 H26 . . 119.8 ?
    C27 C26 H26 . . 119.8 ?
    C22 C27 C26 . . 121.0(3) ?
    C22 C27 H27 . . 119.5 ?
    C26 C27 H27 . . 119.5 ?
    C29 C28 C33 . . 120.0 ?
    C29 C28 C20 . . 119.83(16) ?
    C33 C28 C20 . . 120.10(16) ?
    C30 C29 C28 . . 120.0 ?
    C30 C29 H29 . . 120.0 ?
    C28 C29 H29 . . 120.0 ?
    C29 C30 C31 . . 120.0 ?
    C29 C30 H30 . . 120.0 ?
    C31 C30 H30 . . 120.0 ?
    C30 C31 C32 . . 120.0 ?
    C30 C31 H31 . . 120.0 ?
    C32 C31 H31 . . 120.0 ?
    C31 C32 C33 . . 120.0 ?
    C31 C32 H32 . . 120.0 ?
    C33 C32 H32 . . 120.0 ?
    C32 C33 C28 . . 120.0 ?
    C32 C33 H33 . . 120.0 ?
    C28 C33 H33 . . 120.0 ?
    C35 C34 C39 . . 117.6(3) ?
    C35 C34 C21 . . 120.5(2) ?
    C39 C34 C21 . . 121.9(3) ?
    C34 C35 C36 . . 120.9(3) ?
    C34 C35 H35 . . 119.6 ?
    C36 C35 H35 . . 119.6 ?
    C37 C36 C35 . . 120.3(3) ?
    C37 C36 H36 . . 119.8 ?
    C35 C36 H36 . . 119.8 ?
    C38 C37 C36 . . 119.6(3) ?
    C38 C37 H37 . . 120.2 ?
    C36 C37 H37 . . 120.2 ?
    C37 C38 C39 . . 120.0(3) ?
    C37 C38 H38 . . 120.0 ?
    C39 C38 H38 . . 120.0 ?
    C38 C39 C34 . . 121.5(3) ?
    C38 C39 H39 . . 119.2 ?
    C34 C39 H39 . . 119.2 ?
    C45 C40 C41 . . 118.1(3) ?
    C45 C40 C21 . . 118.1(2) ?
    C41 C40 C21 . . 123.1(3) ?
    C42 C41 C40 . . 120.7(3) ?
    C42 C41 H41 . . 119.6 ?
    C40 C41 H41 . . 119.6 ?
    C41 C42 C43 . . 120.6(3) ?
    C41 C42 H42 . . 119.7 ?
    C43 C42 H42 . . 119.7 ?
    C42 C43 C44 . . 119.3(3) ?
    C42 C43 H43 . . 120.3 ?
    C44 C43 H43 . . 120.3 ?
    C43 C44 C45 . . 120.0(3) ?
    C43 C44 H44 . . 120.0 ?
    C45 C44 H44 . . 120.0 ?
    C40 C45 C44 . . 121.2(3) ?
    C40 C45 H45 . . 119.4 ?
    C44 C45 H45 . . 119.4 ?
    C51 C46 O4 . . 120.6(2) ?
    C51 C46 C47 . . 121.7(2) ?
    O4 C46 C47 . . 117.3(3) ?
    C48 C47 C46 . . 116.3(3) ?
    C48 C47 C58 . . 119.6(3) ?
    C46 C47 C58 . . 123.9(3) ?
    C49 C48 C47 . . 122.6(3) ?
    C49 C48 H48 . . 118.7 ?
    C47 C48 H48 . . 118.7 ?
    C48 C49 C50 . . 120.6(3) ?
    C48 C49 O5 . . 115.9(3) ?
    C50 C49 O5 . . 123.4(3) ?
    C49 C50 C51 . . 119.1(3) ?
    C49 C50 H50 . . 120.5 ?
    C51 C50 H50 . . 120.5 ?
    C46 C51 C50 . . 119.5(3) ?
    C46 C51 C52 . . 125.2(2) ?
    C50 C51 C52 . . 115.1(3) ?
    C57 C52 C53 . . 119.6(3) ?
    C57 C52 C51 . . 122.0(2) ?
    C53 C52 C51 . . 118.1(2) ?
    C54 C53 C52 . . 119.0(3) ?
    C54 C53 H53 . . 120.5 ?
    C52 C53 H53 . . 120.5 ?
    C53 C54 O6 . . 124.4(3) ?
    C53 C54 C55 . . 121.0(3) ?
    O6 C54 C55 . . 114.6(3) ?
    C56 C55 C54 . . 121.7(3) ?
    C56 C55 H55 . . 119.1 ?
    C54 C55 H55 . . 119.1 ?
    C55 C56 C57 . . 116.5(3) ?
    C55 C56 C64 . . 119.7(3) ?
    C57 C56 C64 . . 123.7(2) ?
    O9 C57 C52 . . 119.2(2) ?
    O9 C57 C56 . . 118.6(2) ?
    C52 C57 C56 . . 122.2(2) ?
    C61 C58 C47 . . 111.6(3) ?
    C61 C58 C60 . . 110.9(3) ?
    C47 C58 C60 . . 109.4(3) ?
    C61 C58 C59 . . 105.8(3) ?
    C47 C58 C59 . . 111.6(3) ?
    C60 C58 C59 . . 107.4(3) ?
    C58 C59 H59A . . 109.5 ?
    C58 C59 H59B . . 109.5 ?
    H59A C59 H59B . . 109.5 ?
    C58 C59 H59C . . 109.5 ?
    H59A C59 H59C . . 109.5 ?
    H59B C59 H59C . . 109.5 ?
    C58 C60 H60A . . 109.5 ?
    C58 C60 H60B . . 109.5 ?
    H60A C60 H60B . . 109.5 ?
    C58 C60 H60C . . 109.5 ?
    H60A C60 H60C . . 109.5 ?
    H60B C60 H60C . . 109.5 ?
    C58 C61 H61A . . 109.5 ?
    C58 C61 H61B . . 109.5 ?
    H61A C61 H61B . . 109.5 ?
    C58 C61 H61C . . 109.5 ?
    H61A C61 H61C . . 109.5 ?
    H61B C61 H61C . . 109.5 ?
    O5 C62 H62A . . 109.5 ?
    O5 C62 H62B . . 109.5 ?
    H62A C62 H62B . . 109.5 ?
    O5 C62 H62C . . 109.5 ?
    H62A C62 H62C . . 109.5 ?
    H62B C62 H62C . . 109.5 ?
    O6 C63 H63A . . 109.5 ?
    O6 C63 H63B . . 109.5 ?
    H63A C63 H63B . . 109.5 ?
    O6 C63 H63C . . 109.5 ?
    H63A C63 H63C . . 109.5 ?
    H63B C63 H63C . . 109.5 ?
    C65 C64 C56 . . 111.8(2) ?
    C65 C64 C66 . . 107.0(3) ?
    C56 C64 C66 . . 109.6(2) ?
    C65 C64 C67 . . 107.3(3) ?
    C56 C64 C67 . . 111.7(3) ?
    C66 C64 C67 . . 109.3(3) ?
    C64 C65 H65A . . 109.5 ?
    C64 C65 H65B . . 109.5 ?
    H65A C65 H65B . . 109.5 ?
    C64 C65 H65C . . 109.5 ?
    H65A C65 H65C . . 109.5 ?
    H65B C65 H65C . . 109.5 ?
    C64 C66 H66A . . 109.5 ?
    C64 C66 H66B . . 109.5 ?
    H66A C66 H66B . . 109.5 ?
    C64 C66 H66C . . 109.5 ?
    H66A C66 H66C . . 109.5 ?
    H66B C66 H66C . . 109.5 ?
    C64 C67 H67A . . 109.5 ?
    C64 C67 H67B . . 109.5 ?
    H67A C67 H67B . . 109.5 ?
    C64 C67 H67C . . 109.5 ?
    H67A C67 H67C . . 109.5 ?
    H67B C67 H67C . . 109.5 ?
    O7 C68 C70 . . 106.3(2) ?
    O7 C68 C76 . . 106.3(2) ?
    C70 C68 C76 . . 108.60(19) ?
    O7 C68 C69 . . 104.31(19) ?
    C70 C68 C69 . . 118.5(2) ?
    C76 C68 C69 . . 111.9(2) ?
    O8 C69 C88 . . 105.9(2) ?
    O8 C69 C82 . . 108.01(19) ?
    C88 C69 C82 . . 111.3(2) ?
    O8 C69 C68 . . 102.87(19) ?
    C88 C69 C68 . . 113.1(2) ?
    C82 C69 C68 . . 114.8(2) ?
    C71 C70 C75 . . 120.0 ?
    C71 C70 C68 . . 116.89(15) ?
    C75 C70 C68 . . 122.57(16) ?
    C70 C71 C72 . . 120.0 ?
    C70 C71 H71 . . 120.0 ?
    C72 C71 H71 . . 120.0 ?
    C73 C72 C71 . . 120.0 ?
    C73 C72 H72 . . 120.0 ?
    C71 C72 H72 . . 120.0 ?
    C72 C73 C74 . . 120.0 ?
    C72 C73 H73 . . 120.0 ?
    C74 C73 H73 . . 120.0 ?
    C75 C74 C73 . . 120.0 ?
    C75 C74 H74 . . 120.0 ?
    C73 C74 H74 . . 120.0 ?
    C74 C75 C70 . . 120.0 ?
    C74 C75 H75 . . 120.0 ?
    C70 C75 H75 . . 120.0 ?
    C77 C76 C81 . . 120.0 ?
    C77 C76 C68 . . 121.55(16) ?
    C81 C76 C68 . . 118.44(16) ?
    C76 C77 C78 . . 120.0 ?
    C76 C77 H77 . . 120.0 ?
    C78 C77 H77 . . 120.0 ?
    C79 C78 C77 . . 120.0 ?
    C79 C78 H78 . . 120.0 ?
    C77 C78 H78 . . 120.0 ?
    C80 C79 C78 . . 120.0 ?
    C80 C79 H79 . . 120.0 ?
    C78 C79 H79 . . 120.0 ?
    C79 C80 C81 . . 120.0 ?
    C79 C80 H80 . . 120.0 ?
    C81 C80 H80 . . 120.0 ?
    C80 C81 C76 . . 120.0 ?
    C80 C81 H81 . . 120.0 ?
    C76 C81 H81 . . 120.0 ?
    C83 C82 C87 . . 120.0 ?
    C83 C82 C69 . . 119.75(16) ?
    C87 C82 C69 . . 120.22(16) ?
    C84 C83 C82 . . 120.0 ?
    C84 C83 H83 . . 120.0 ?
    C82 C83 H83 . . 120.0 ?
    C85 C84 C83 . . 120.0 ?
    C85 C84 H84 . . 120.0 ?
    C83 C84 H84 . . 120.0 ?
    C84 C85 C86 . . 120.0 ?
    C84 C85 H85 . . 120.0 ?
    C86 C85 H85 . . 120.0 ?
    C85 C86 C87 . . 120.0 ?
    C85 C86 H86 . . 120.0 ?
    C87 C86 H86 . . 120.0 ?
    C86 C87 C82 . . 120.0 ?
    C86 C87 H87 . . 120.0 ?
    C82 C87 H87 . . 120.0 ?
    C93 C88 C89 . . 117.8(3) ?
    C93 C88 C69 . . 121.1(3) ?
    C89 C88 C69 . . 121.0(3) ?
    C90 C89 C88 . . 120.5(3) ?
    C90 C89 H89 . . 119.7 ?
    C88 C89 H89 . . 119.7 ?
    C91 C90 C89 . . 120.5(3) ?
    C91 C90 H90 . . 119.7 ?
    C89 C90 H90 . . 119.7 ?
    C92 C91 C90 . . 119.1(4) ?
    C92 C91 H91 . . 120.4 ?
    C90 C91 H91 . . 120.4 ?
    C91 C92 C93 . . 120.6(4) ?
    C91 C92 H92 . . 119.7 ?
    C93 C92 H92 . . 119.7 ?
    C92 C93 C88 . . 121.3(3) ?
    C92 C93 H93 . . 119.4 ?
    C88 C93 H93 . . 119.4 ?
    O10 C94 Rh2 . . 178.2(3) ?
    C96 C95 C100 . . 120.0 ?
    C96 C95 P4 . . 121.00(10) ?
    C100 C95 P4 . . 118.11(10) ?
    C95 C96 C97 . . 120.0 ?
    C95 C96 H96 . . 120.0 ?
    C97 C96 H96 . . 120.0 ?
    C98 C97 C96 . . 120.0 ?
    C98 C97 H97 . . 120.0 ?
    C96 C97 H97 . . 120.0 ?
    C97 C98 C99 . . 120.0 ?
    C97 C98 H98 . . 120.0 ?
    C99 C98 H98 . . 120.0 ?
    C100 C99 C98 . . 120.0 ?
    C100 C99 H99 . . 120.0 ?
    C98 C99 H99 . . 120.0 ?
    C99 C100 C95 . . 120.0 ?
    C99 C100 H100 . . 120.0 ?
    C95 C100 H100 . . 120.0 ?
    C102 C101 C106 . . 118.9(3) ?
    C102 C101 P4 . . 124.1(2) ?
    C106 C101 P4 . . 116.9(2) ?
    C101 C102 C103 . . 120.1(3) ?
    C101 C102 H102 . . 119.9 ?
    C103 C102 H102 . . 119.9 ?
    C104 C103 C102 . . 120.6(3) ?
    C104 C103 H103 . . 119.7 ?
    C102 C103 H103 . . 119.7 ?
    C105 C104 C103 . . 119.5(3) ?
    C105 C104 H104 . . 120.3 ?
    C103 C104 H104 . . 120.3 ?
    C104 C105 C106 . . 120.3(3) ?
    C104 C105 H105 . . 119.8 ?
    C106 C105 H105 . . 119.8 ?
    C105 C106 C101 . . 120.5(3) ?
    C105 C106 H106 . . 119.7 ?
    C101 C106 H106 . . 119.7 ?
    C108 C107 C112 . . 118.9(3) ?
    C108 C107 P4 . . 119.1(2) ?
    C112 C107 P4 . . 122.0(3) ?
    C107 C108 C109 . . 120.7(4) ?
    C107 C108 H108 . . 119.6 ?
    C109 C108 H108 . . 119.6 ?
    C110 C109 C108 . . 119.3(4) ?
    C110 C109 H109 . . 120.3 ?
    C108 C109 H109 . . 120.3 ?
    C111 C110 C109 . . 120.6(4) ?
    C111 C110 H110 . . 119.7 ?
    C109 C110 H110 . . 119.7 ?
    C110 C111 C112 . . 120.1(4) ?
    C110 C111 H111 . . 120.0 ?
    C112 C111 H111 . . 120.0 ?
    C111 C112 C107 . . 120.4(4) ?
    C111 C112 H112 . . 119.8 ?
    C107 C112 H112 . . 119.8 ?
    O11 C113 C121 . . 108.1(2) ?
    O11 C113 C115 . . 106.26(19) ?
    C121 C113 C115 . . 109.3(2) ?
    O11 C113 C114 . . 103.1(2) ?
    C121 C113 C114 . . 116.5(2) ?
    C115 C113 C114 . . 112.9(2) ?
    O12 C114 C127 . . 106.9(2) ?
    O12 C114 C133 . . 105.9(2) ?
    C127 C114 C133 . . 109.9(2) ?
    O12 C114 C113 . . 105.0(2) ?
    C127 C114 C113 . . 116.9(2) ?
    C133 C114 C113 . . 111.5(2) ?
    C116 C115 C120 . . 120.0 ?
    C116 C115 C113 . . 119.75(14) ?
    C120 C115 C113 . . 119.99(14) ?
    C115 C116 C117 . . 120.0 ?
    C115 C116 H116 . . 120.0 ?
    C117 C116 H116 . . 120.0 ?
    C118 C117 C116 . . 120.0 ?
    C118 C117 H117 . . 120.0 ?
    C116 C117 H117 . . 120.0 ?
    C119 C118 C117 . . 120.0 ?
    C119 C118 H118 . . 120.0 ?
    C117 C118 H118 . . 120.0 ?
    C118 C119 C120 . . 120.0 ?
    C118 C119 H119 . . 120.0 ?
    C120 C119 H119 . . 120.0 ?
    C119 C120 C115 . . 120.0 ?
    C119 C120 H120 . . 120.0 ?
    C115 C120 H120 . . 120.0 ?
    C122 C121 C126 . . 117.8(3) ?
    C122 C121 C113 . . 120.7(3) ?
    C126 C121 C113 . . 121.5(3) ?
    C121 C122 C123 . . 121.1(3) ?
    C121 C122 H122 . . 119.4 ?
    C123 C122 H122 . . 119.4 ?
    C124 C123 C122 . . 120.3(3) ?
    C124 C123 H123 . . 119.9 ?
    C122 C123 H123 . . 119.9 ?
    C125 C124 C123 . . 119.6(3) ?
    C125 C124 H124 . . 120.2 ?
    C123 C124 H124 . . 120.2 ?
    C124 C125 C126 . . 120.6(3) ?
    C124 C125 H125 . . 119.7 ?
    C126 C125 H125 . . 119.7 ?
    C125 C126 C121 . . 120.6(3) ?
    C125 C126 H126 . . 119.7 ?
    C121 C126 H126 . . 119.7 ?
    C128 C127 C132 . . 118.5(3) ?
    C128 C127 C114 . . 118.2(3) ?
    C132 C127 C114 . . 123.1(3) ?
    C127 C128 C129 . . 120.6(4) ?
    C127 C128 H128 . . 119.7 ?
    C129 C128 H128 . . 119.7 ?
    C130 C129 C128 . . 120.2(5) ?
    C130 C129 H129 . . 119.9 ?
    C128 C129 H129 . . 119.9 ?
    C131 C130 C129 . . 119.6(4) ?
    C131 C130 H130 . . 120.2 ?
    C129 C130 H130 . . 120.2 ?
    C130 C131 C132 . . 120.0(4) ?
    C130 C131 H131 . . 120.0 ?
    C132 C131 H131 . . 120.0 ?
    C127 C132 C131 . . 121.2(4) ?
    C127 C132 H132 . . 119.4 ?
    C131 C132 H132 . . 119.4 ?
    C138 C133 C134 . . 118.2(3) ?
    C138 C133 C114 . . 122.1(3) ?
    C134 C133 C114 . . 119.7(2) ?
    C135 C134 C133 . . 120.9(3) ?
    C135 C134 H134 . . 119.6 ?
    C133 C134 H134 . . 119.6 ?
    C136 C135 C134 . . 120.3(3) ?
    C136 C135 H135 . . 119.9 ?
    C134 C135 H135 . . 119.9 ?
    C135 C136 C137 . . 119.4(3) ?
    C135 C136 H136 . . 120.3 ?
    C137 C136 H136 . . 120.3 ?
    C136 C137 C138 . . 120.4(3) ?
    C136 C137 H137 . . 119.8 ?
    C138 C137 H137 . . 119.8 ?
    C133 C138 C137 . . 121.0(3) ?
    C133 C138 H138 . . 119.5 ?
    C137 C138 H138 . . 119.5 ?
    O13 C139 C144 . . 120.6(2) ?
    O13 C139 C140 . . 117.9(3) ?
    C144 C139 C140 . . 121.4(2) ?
    C141 C140 C139 . . 116.6(3) ?
    C141 C140 C151 . . 119.5(3) ?
    C139 C140 C151 . . 123.9(3) ?
    C142 C141 C140 . . 122.4(3) ?
    C142 C141 H141 . . 118.8 ?
    C140 C141 H141 . . 118.8 ?
    O14 C142 C141 . . 124.9(3) ?
    O14 C142 C143 . . 115.0(3) ?
    C141 C142 C143 . . 120.0(3) ?
    C142 C143 C144 . . 119.9(3) ?
    C142 C143 H143 . . 120.0 ?
    C144 C143 H143 . . 120.0 ?
    C143 C144 C139 . . 119.5(2) ?
    C143 C144 C145 . . 116.0(3) ?
    C139 C144 C145 . . 124.4(2) ?
    C146 C145 C150 . . 119.3(2) ?
    C146 C145 C144 . . 119.7(2) ?
    C150 C145 C144 . . 120.9(2) ?
    C145 C146 C147 . . 119.9(2) ?
    C145 C146 H146 . . 120.0 ?
    C147 C146 H146 . . 120.0 ?
    O15 C147 C148 . . 124.9(3) ?
    O15 C147 C146 . . 115.0(2) ?
    C148 C147 C146 . . 120.1(2) ?
    C147 C148 C149 . . 121.9(3) ?
    C147 C148 H148 . . 119.1 ?
    C149 C148 H148 . . 119.1 ?
    C150 C149 C148 . . 116.7(2) ?
    C150 C149 C157 . . 122.7(2) ?
    C148 C149 C157 . . 120.5(3) ?
    O18 C150 C149 . . 119.3(2) ?
    O18 C150 C145 . . 118.9(2) ?
    C149 C150 C145 . . 121.8(2) ?
    C154 C151 C152 . . 110.2(3) ?
    C154 C151 C140 . . 110.7(3) ?
    C152 C151 C140 . . 111.1(3) ?
    C154 C151 C153 . . 107.4(3) ?
    C152 C151 C153 . . 105.9(3) ?
    C140 C151 C153 . . 111.3(3) ?
    C151 C152 H15A . . 109.5 ?
    C151 C152 H15B . . 109.5 ?
    H15A C152 H15B . . 109.5 ?
    C151 C152 H15C . . 109.5 ?
    H15A C152 H15C . . 109.5 ?
    H15B C152 H15C . . 109.5 ?
    C151 C153 H15D . . 109.5 ?
    C151 C153 H15E . . 109.5 ?
    H15D C153 H15E . . 109.5 ?
    C151 C153 H15F . . 109.5 ?
    H15D C153 H15F . . 109.5 ?
    H15E C153 H15F . . 109.5 ?
    C151 C154 H15G . . 109.5 ?
    C151 C154 H15H . . 109.5 ?
    H15G C154 H15H . . 109.5 ?
    C151 C154 H15I . . 109.5 ?
    H15G C154 H15I . . 109.5 ?
    H15H C154 H15I . . 109.5 ?
    O14 C155 H15J . . 109.5 ?
    O14 C155 H15K . . 109.5 ?
    H15J C155 H15K . . 109.5 ?
    O14 C155 H15L . . 109.5 ?
    H15J C155 H15L . . 109.5 ?
    H15K C155 H15L . . 109.5 ?
    O15 C156 H15M . . 109.5 ?
    O15 C156 H15N . . 109.5 ?
    H15M C156 H15N . . 109.5 ?
    O15 C156 H15O . . 109.5 ?
    H15M C156 H15O . . 109.5 ?
    H15N C156 H15O . . 109.5 ?
    C160 C157 C158 . . 106.3(2) ?
    C160 C157 C149 . . 112.2(3) ?
    C158 C157 C149 . . 111.9(2) ?
    C160 C157 C159 . . 110.1(3) ?
    C158 C157 C159 . . 107.4(3) ?
    C149 C157 C159 . . 108.8(2) ?
    C157 C158 H15P . . 109.5 ?
    C157 C158 H15Q . . 109.5 ?
    H15P C158 H15Q . . 109.5 ?
    C157 C158 H15R . . 109.5 ?
    H15P C158 H15R . . 109.5 ?
    H15Q C158 H15R . . 109.5 ?
    C157 C159 H15S . . 109.5 ?
    C157 C159 H15T . . 109.5 ?
    H15S C159 H15T . . 109.5 ?
    C157 C159 H15U . . 109.5 ?
    H15S C159 H15U . . 109.5 ?
    H15T C159 H15U . . 109.5 ?
    C157 C160 H16A . . 109.5 ?
    C157 C160 H16B . . 109.5 ?
    H16A C160 H16B . . 109.5 ?
    C157 C160 H16C . . 109.5 ?
    H16A C160 H16C . . 109.5 ?
    H16B C160 H16C . . 109.5 ?
    O16 C161 C163 . . 106.1(2) ?
    O16 C161 C169 . . 108.0(2) ?
    C163 C161 C169 . . 110.7(2) ?
    O16 C161 C162 . . 103.63(19) ?
    C163 C161 C162 . . 113.4(2) ?
    C169 C161 C162 . . 114.2(2) ?
    O17 C162 C181 . . 107.8(2) ?
    O17 C162 C175 . . 105.6(2) ?
    C181 C162 C175 . . 110.2(2) ?
    O17 C162 C161 . . 104.14(19) ?
    C181 C162 C161 . . 116.1(2) ?
    C175 C162 C161 . . 112.2(2) ?
    C168 C163 C164 . . 118.3(3) ?
    C168 C163 C161 . . 120.5(3) ?
    C164 C163 C161 . . 121.3(3) ?
    C165 C164 C163 . . 120.7(3) ?
    C165 C164 H164 . . 119.6 ?
    C163 C164 H164 . . 119.6 ?
    C166 C165 C164 . . 120.7(3) ?
    C166 C165 H165 . . 119.7 ?
    C164 C165 H165 . . 119.7 ?
    C165 C166 C167 . . 118.7(3) ?
    C165 C166 H166 . . 120.6 ?
    C167 C166 H166 . . 120.6 ?
    C168 C167 C166 . . 120.9(4) ?
    C168 C167 H167 . . 119.6 ?
    C166 C167 H167 . . 119.6 ?
    C163 C168 C167 . . 120.7(3) ?
    C163 C168 H168 . . 119.7 ?
    C167 C168 H168 . . 119.7 ?
    C174 C169 C170 . . 117.7(3) ?
    C174 C169 C161 . . 121.6(3) ?
    C170 C169 C161 . . 120.7(3) ?
    C171 C170 C169 . . 121.2(3) ?
    C171 C170 H170 . . 119.4 ?
    C169 C170 H170 . . 119.4 ?
    C172 C171 C170 . . 120.6(4) ?
    C172 C171 H171 . . 119.7 ?
    C170 C171 H171 . . 119.7 ?
    C171 C172 C173 . . 118.9(3) ?
    C171 C172 H172 . . 120.6 ?
    C173 C172 H172 . . 120.6 ?
    C172 C173 C174 . . 120.8(3) ?
    C172 C173 H173 . . 119.6 ?
    C174 C173 H173 . . 119.6 ?
    C169 C174 C173 . . 120.8(3) ?
    C169 C174 H174 . . 119.6 ?
    C173 C174 H174 . . 119.6 ?
    C176 C175 C180 . . 120.0 ?
    C176 C175 C162 . . 118.47(17) ?
    C180 C175 C162 . . 121.52(17) ?
    C177 C176 C175 . . 120.0 ?
    C177 C176 H176 . . 120.0 ?
    C175 C176 H176 . . 120.0 ?
    C176 C177 C178 . . 120.0 ?
    C176 C177 H177 . . 120.0 ?
    C178 C177 H177 . . 120.0 ?
    C177 C178 C179 . . 120.0 ?
    C177 C178 H178 . . 120.0 ?
    C179 C178 H178 . . 120.0 ?
    C180 C179 C178 . . 120.0 ?
    C180 C179 H179 . . 120.0 ?
    C178 C179 H179 . . 120.0 ?
    C179 C180 C175 . . 120.0 ?
    C179 C180 H180 . . 120.0 ?
    C175 C180 H180 . . 120.0 ?
    C20 O2 P2 . . 117.82(17) ?
    C21 O3 P2 . . 118.67(17) ?
    C46 O4 P2 . . 129.59(17) ?
    C49 O5 C62 . . 116.8(3) ?
    C54 O6 C63 . . 115.6(3) ?
    C68 O7 P3 . . 118.27(16) ?
    C69 O8 P3 . . 118.24(17) ?
    C57 O9 P3 . . 124.14(17) ?
    C113 O11 P6 . . 117.13(17) ?
    C114 O12 P6 . . 116.84(18) ?
    C139 O13 P6 . . 127.78(16) ?
    C142 O14 C155 . . 117.0(3) ?
    C147 O15 C156 . . 117.2(2) ?
    C161 O16 P5 . . 118.77(16) ?
    C162 O17 P5 . . 118.79(15) ?
    C150 O18 P5 . . 122.75(17) ?
    C8 P1 C2 . . 102.39(9) ?
    C8 P1 C14 . . 102.36(9) ?
    C2 P1 C14 . . 99.09(9) ?
    C8 P1 Rh1 . . 116.38(7) ?
    C2 P1 Rh1 . . 114.35(7) ?
    C14 P1 Rh1 . . 119.52(7) ?
    O3 P2 O2 . . 93.57(10) ?
    O3 P2 O4 . . 102.08(10) ?
    O2 P2 O4 . . 97.60(10) ?
    O3 P2 Rh1 . . 122.83(7) ?
    O2 P2 Rh1 . . 120.72(7) ?
    O4 P2 Rh1 . . 115.15(7) ?
    O8 P3 O7 . . 93.33(9) ?
    O8 P3 O9 . . 102.00(10) ?
    O7 P3 O9 . . 98.97(11) ?
    O8 P3 Rh1 . . 123.67(8) ?
    O7 P3 Rh1 . . 118.87(7) ?
    O9 P3 Rh1 . . 115.28(7) ?
    C107 P4 C101 . . 102.62(14) ?
    C107 P4 C95 . . 102.58(11) ?
    C101 P4 C95 . . 99.81(11) ?
    C107 P4 Rh2 . . 116.69(10) ?
    C101 P4 Rh2 . . 113.21(9) ?
    C95 P4 Rh2 . . 119.36(6) ?
    O16 P5 O17 . . 93.19(9) ?
    O16 P5 O18 . . 102.91(10) ?
    O17 P5 O18 . . 98.55(11) ?
    O16 P5 Rh2 . . 122.23(8) ?
    O17 P5 Rh2 . . 120.32(8) ?
    O18 P5 Rh2 . . 115.10(7) ?
    O11 P6 O12 . . 93.41(10) ?
    O11 P6 O13 . . 103.04(10) ?
    O12 P6 O13 . . 97.12(10) ?
    O11 P6 Rh2 . . 120.49(7) ?
    O12 P6 Rh2 . . 122.85(8) ?
    O13 P6 Rh2 . . 115.26(7) ?
    C1 Rh1 P2 . . 99.50(9) ?
    C1 Rh1 P3 . . 99.19(9) ?
    P2 Rh1 P3 . . 117.18(2) ?
    C1 Rh1 P1 . . 94.90(9) ?
    P2 Rh1 P1 . . 120.36(2) ?
    P3 Rh1 P1 . . 116.96(3) ?
    C1 Rh1 H1 . . 173.7(16) ?
    P2 Rh1 H1 . . 86.8(15) ?
    P3 Rh1 H1 . . 78.3(15) ?
    P1 Rh1 H1 . . 81.2(15) ?
    C94 Rh2 P6 . . 101.63(9) ?
    C94 Rh2 P5 . . 98.77(10) ?
    P6 Rh2 P5 . . 117.99(2) ?
    C94 Rh2 P4 . . 95.09(9) ?
    P6 Rh2 P4 . . 118.93(2) ?
    P5 Rh2 P4 . . 116.62(3) ?
    C94 Rh2 H2 . . 176.3(15) ?
    P6 Rh2 H2 . . 82.1(15) ?
    P5 Rh2 H2 . . 79.1(15) ?
    P4 Rh2 H2 . . 83.2(15) ?
    C191 O20 C193 . . 105.9(7) ?
    C191 C192 H19D . . 109.5 ?
    C191 C192 H19E . . 109.5 ?
    H19D C192 H19E . . 109.5 ?
    C191 C192 H19F . . 109.5 ?
    H19D C192 H19F . . 109.5 ?
    H19E C192 H19F . . 109.5 ?
    O20 C191 C192 . . 104.1(8) ?
    O20 C191 H19G . . 110.9 ?
    C192 C191 H19G . . 110.9 ?
    O20 C191 H19H . . 110.9 ?
    C192 C191 H19H . . 110.9 ?
    H19G C191 H19H . . 109.0 ?
    O20 C193 C194 . . 106.7(10) ?
    O20 C193 H19I . . 110.4 ?
    C194 C193 H19I . . 110.4 ?
    O20 C193 H19J . . 110.4 ?
    C194 C193 H19J . . 110.4 ?
    H19I C193 H19J . . 108.6 ?
    C193 C194 H19K . . 109.5 ?
    C193 C194 H19L . . 109.5 ?
    H19K C194 H19L . . 109.5 ?
    C193 C194 H19M . . 109.5 ?
    H19K C194 H19M . . 109.5 ?
    H19L C194 H19M . . 109.5 ?
loop_
    _platon_squeeze_void_nr
    _platon_squeeze_void_average_x
    _platon_squeeze_void_average_y
    _platon_squeeze_void_average_z
    _platon_squeeze_void_volume
    _platon_squeeze_void_count_electrons
    1 0.500 0.500 0.498 1790.2 213.6
_platon_squeeze_details
;
Contributions of further disordered solvent molecules were removed
from the diffraction data with PLATON / SQUEEZE (Spek, 2009).
;
data_global
_journal_date_recd_electronic     2012-10-26
_journal_date_accepted     2012-11-29
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2013
_journal_volume     69
_journal_issue      1
_journal_page_first     m14
_journal_page_last     m14
_journal_paper_category     QM
_journal_paper_doi     10.1107/S1600536812049124
_journal_coeditor_code     WM2697
_publ_contact_author_name     'Detlef Selent'
_publ_contact_author_address
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
_publ_contact_author_email     detlef.selent@catalysis.de
_publ_contact_author_fax     '+49(381)1281-51169'
_publ_contact_author_phone     '+49(381)1281-169'
_publ_section_title
;\
Carbonyl{3,3'-di-tert-butyl-5,5'-dimethoxy-2,2'-bis[(4,4,5,5-\
tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ²P,P'}\
hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate
;
loop_
    _publ_author_name
    _publ_author_address
    'Selent, Detlef'
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Spannenberg, Anke'
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Börner, Armin'
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
