##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
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##############################################################################
data_I
_audit_creation_method     SHELXL-97
_journal_date_recd_electronic     2011-08-12
_journal_date_accepted     2011-09-05
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2011
_journal_volume     67
_journal_issue     10
_journal_page_first     m1357
_journal_page_last     m1357
_journal_paper_category     QM
_journal_coeditor_code     WM2524
_publ_contact_author_name     'Guo-Liang Zhao'
_publ_contact_author_address
;
  College of Chemistry and Life Sciences,
  Zhejiang Normal University,
  Jinhua, Zhejiang 321004,
  People's Republic of China
  Zhejiang Normal University Xingzhi College,
  Jinhua, Zhejiang 321004,
  People's Republic of China
;
_publ_contact_author_email     'sky53@zjnu.cn'
_publ_contact_author_fax     '86-579-82282595'
_publ_contact_author_phone     '86-579-82283925'
_publ_section_title
;\
Tetrakis(μ₂-2-phenoxypropionato)-κ³O,O':O';\
κ³O:O,O';κ⁴O:O'-bis[(1,10-\
phenanthroline-κ²N,N')(2-phenoxypropionato-κ²O,\
O')gadolinium(III)]
;
loop_
    _publ_author_name
    _publ_author_address
    'Jin-Bei Shen'
;
  College of Chemistry and Life Science,
  Zhejiang Normal University,
  Jinhua 321004, Zhejiang,
  People's Republic of China
;
    'Jia-Lu Liu '
;
  College of Chemistry and Life Science,
  Zhejiang Normal University,
  Jinhua 321004, Zhejiang,
  People's Republic of China
;
    'Guo-Liang Zhao'
;
  College of Chemistry and Life Sciences,
  Zhejiang Normal University,
  Jinhua, Zhejiang 321004,
  People's Republic of China
  Zhejiang Normal University Xingzhi College,
  Jinhua, Zhejiang 321004,
  People's Republic of China
;
_chemical_name_systematic
;
Tetrakis(μ₂-2-phenoxypropionato)-κ³O,O':O';\
κ³O:O,O';κ⁴O:O'-bis[(1,10-\
phenanthroline-κ²N,N')(2-phenoxypropionato-\
κ²O,O')gadolinium(III)]
;
_chemical_name_common     ?
_chemical_formula_moiety     'C78 H70 Gd2 N4 O18'
_chemical_formula_sum     'C78 H70 Gd2 N4 O18'
_chemical_formula_iupac     '[Gd2 (C9 H9 O3)6 (C12 H8 N2)2]'
_chemical_formula_weight     1665.88
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/c'
_symmetry_space_group_name_Hall     '-P 2ybc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     11.4876(2)
_cell_length_b     25.8305(4)
_cell_length_c     13.8715(2)
_cell_angle_alpha     90.00
_cell_angle_beta     120.5540(10)
_cell_angle_gamma     90.00
_cell_volume     3544.58(10)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     9931
_cell_measurement_theta_min     1.58
_cell_measurement_theta_max     25.00
_cell_measurement_temperature     296(2)
_exptl_crystal_description     block
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.49
_exptl_crystal_size_mid     0.24
_exptl_crystal_size_min     0.16
_exptl_crystal_density_diffrn     1.561
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1676
_exptl_absorpt_coefficient_mu     1.930
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min     0.585
_exptl_absorpt_correction_T_max     0.741
_exptl_special_details     ?
_diffrn_ambient_temperature     296(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII CCD'
_diffrn_measurement_method     'phi and omega scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     47235
_diffrn_reflns_av_R_equivalents     0.0221
_diffrn_reflns_av_sigmaI/netI     0.0125
_diffrn_reflns_theta_min     1.58
_diffrn_reflns_theta_max     25.00
_diffrn_reflns_theta_full     25.00
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -13
_diffrn_reflns_limit_h_max     13
_diffrn_reflns_limit_k_min     -30
_diffrn_reflns_limit_k_max     30
_diffrn_reflns_limit_l_min     -16
_diffrn_reflns_limit_l_max     16
_diffrn_standards_number     0
_diffrn_standards_interval_count     .
_diffrn_standards_interval_time     .
_diffrn_standards_decay_%     ?
_refine_special_details
;
Refinement of F² against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F², conventional
R-factors R are based on F, with F set to zero for
negative F². The threshold expression of F² >
σ(F²) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F² are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger.
;
_reflns_number_total     6250
_reflns_number_gt     5788
_reflns_threshold_expression     >2sigma(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0234
_refine_ls_R_factor_gt     0.0205
_refine_ls_wR_factor_gt     0.0421
_refine_ls_wR_factor_ref     0.0431
_refine_ls_goodness_of_fit_ref     1.149
_refine_ls_restrained_S_all     1.149
_refine_ls_number_reflns     6250
_refine_ls_number_parameters     463
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0115P)²+2.8127P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.002
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.716
_refine_diff_density_min     -0.365
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Gd' 'Gd' -0.1653 3.9035
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2006)'
_computing_cell_refinement     'SAINT (Bruker, 2006)'
_computing_data_reduction     'SAINT (Bruker, 2006)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics
               'XP in SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material     'SHELXL97 (Sheldrick, 2008)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_symmetry_multiplicity
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Gd Gd1 -0.046556(10) 0.002766(4) 0.340014(8) 0.02550(4) Uani d . 1 1 . .
    O O1 0.03272(16) 0.08532(6) 0.30126(14) 0.0388(4) Uani d . 1 1 . .
    O O2 0.12120(18) 0.01332(6) 0.28277(15) 0.0436(4) Uani d . 1 1 . .
    O O3 0.0952(2) 0.13429(7) 0.15485(15) 0.0528(5) Uani d . 1 1 . .
    O O4 0.08324(17) -0.07056(6) 0.43696(13) 0.0384(4) Uani d . 1 1 . .
    O O6 0.32842(18) -0.15230(7) 0.65428(16) 0.0521(5) Uani d . 1 1 . .
    O O7 -0.11813(15) -0.03158(6) 0.48067(12) 0.0337(3) Uani d . 1 1 . .
    O O8 -0.25649(15) -0.04212(6) 0.30075(12) 0.0346(4) Uani d . 1 1 . .
    O O9 -0.40902(16) -0.11065(6) 0.34329(14) 0.0432(4) Uani d . 1 1 . .
    N N1 -0.12084(19) -0.06791(7) 0.18422(15) 0.0326(4) Uani d . 1 1 . .
    N N2 -0.21912(19) 0.03043(7) 0.14094(15) 0.0323(4) Uani d . 1 1 . .
    C C1 0.1032(2) 0.06142(9) 0.27068(19) 0.0352(5) Uani d . 1 1 . .
    C C2 0.1743(3) 0.09170(10) 0.2203(2) 0.0455(6) Uani d . 1 1 . .
    H H2A 0.1931 0.0685 0.1739 0.055 Uiso calc R 1 1 . .
    C C3 0.3056(3) 0.11432(14) 0.3127(3) 0.0679(9) Uani d . 1 1 . .
    H H3A 0.3490 0.1334 0.2803 0.102 Uiso calc R 1 1 . .
    H H3B 0.3639 0.0868 0.3583 0.102 Uiso calc R 1 1 . .
    H H3C 0.2871 0.1371 0.3580 0.102 Uiso calc R 1 1 . .
    C C4 -0.0128(3) 0.12487(10) 0.0496(2) 0.0440(6) Uani d . 1 1 . .
    C C5 -0.0846(3) 0.16847(12) -0.0071(3) 0.0577(7) Uani d . 1 1 . .
    H H5A -0.0609 0.2007 0.0277 0.069 Uiso calc R 1 1 . .
    C C6 -0.1906(3) 0.16423(14) -0.1145(3) 0.0700(9) Uani d . 1 1 . .
    H H6A -0.2386 0.1937 -0.1525 0.084 Uiso calc R 1 1 . .
    C C7 -0.2270(3) 0.11702(16) -0.1669(3) 0.0694(9) Uani d . 1 1 . .
    H H7A -0.2990 0.1144 -0.2400 0.083 Uiso calc R 1 1 . .
    C C8 -0.1560(3) 0.07369(14) -0.1103(3) 0.0655(9) Uani d . 1 1 . .
    H H8A -0.1798 0.0417 -0.1458 0.079 Uiso calc R 1 1 . .
    C C9 -0.0490(3) 0.07709(11) -0.0010(2) 0.0521(7) Uani d . 1 1 . .
    H H9A -0.0025 0.0475 0.0376 0.063 Uiso calc R 1 1 . .
    C C10 0.1572(2) -0.08655(8) 0.53581(18) 0.0307(5) Uani d . 1 1 . .
    C C11 0.2403(2) -0.13458(9) 0.5442(2) 0.0394(6) Uani d . 1 1 . .
    H H11A 0.1772 -0.1626 0.5023 0.047 Uiso calc R 1 1 . .
    C C12 0.3250(3) -0.12420(12) 0.4913(3) 0.0610(8) Uani d . 1 1 . .
    H H12A 0.3728 -0.1551 0.4938 0.092 Uiso calc R 1 1 . .
    H H12B 0.3887 -0.0971 0.5317 0.092 Uiso calc R 1 1 . .
    H H12C 0.2674 -0.1138 0.4149 0.092 Uiso calc R 1 1 . .
    C C13 0.2779(3) -0.18232(9) 0.7067(2) 0.0487(7) Uani d . 1 1 . .
    C C14 0.3765(4) -0.20978(11) 0.7975(3) 0.0701(9) Uani d . 1 1 . .
    H H14A 0.4662 -0.2085 0.8154 0.084 Uiso calc R 1 1 . .
    C C15 0.3401(6) -0.23875(15) 0.8606(3) 0.0996(15) Uani d . 1 1 . .
    H H15A 0.4056 -0.2574 0.9215 0.120 Uiso calc R 1 1 . .
    C C16 0.2094(7) -0.24059(16) 0.8351(4) 0.1070(17) Uani d . 1 1 . .
    H H16A 0.1859 -0.2602 0.8789 0.128 Uiso calc R 1 1 . .
    C C17 0.1127(5) -0.21372(13) 0.7455(4) 0.0870(12) Uani d . 1 1 . .
    H H17A 0.0232 -0.2152 0.7282 0.104 Uiso calc R 1 1 . .
    C C18 0.1463(3) -0.18461(10) 0.6806(3) 0.0580(8) Uani d . 1 1 . .
    H H18A 0.0799 -0.1665 0.6192 0.070 Uiso calc R 1 1 . .
    C C19 -0.2279(2) -0.04794(8) 0.39940(17) 0.0269(4) Uani d . 1 1 . .
    C C20 -0.3273(2) -0.07336(9) 0.42604(19) 0.0359(5) Uani d . 1 1 . .
    H H20A -0.2777 -0.0902 0.4994 0.043 Uiso calc R 1 1 . .
    C C21 -0.4223(3) -0.03319(11) 0.4272(2) 0.0516(7) Uani d . 1 1 . .
    H H21A -0.4863 -0.0497 0.4423 0.077 Uiso calc R 1 1 . .
    H H21B -0.4696 -0.0163 0.3557 0.077 Uiso calc R 1 1 . .
    H H21C -0.3715 -0.0080 0.4844 0.077 Uiso calc R 1 1 . .
    C C22 -0.3458(3) -0.15389(9) 0.3341(2) 0.0463(6) Uani d . 1 1 . .
    C C23 -0.4223(3) -0.18490(11) 0.2430(3) 0.0632(8) Uani d . 1 1 . .
    H H23A -0.5110 -0.1758 0.1913 0.076 Uiso calc R 1 1 . .
    C C24 -0.3678(4) -0.22961(13) 0.2280(3) 0.0848(11) Uani d . 1 1 . .
    H H24A -0.4201 -0.2503 0.1658 0.102 Uiso calc R 1 1 . .
    C C25 -0.2378(4) -0.24390(13) 0.3034(4) 0.0945(13) Uani d . 1 1 . .
    H H25A -0.2016 -0.2742 0.2933 0.113 Uiso calc R 1 1 . .
    C C26 -0.1626(4) -0.21295(14) 0.3934(4) 0.1075(16) Uani d . 1 1 . .
    H H26A -0.0742 -0.2224 0.4452 0.129 Uiso calc R 1 1 . .
    C C27 -0.2152(3) -0.16744(12) 0.4096(3) 0.0825(12) Uani d . 1 1 . .
    H H27A -0.1621 -0.1464 0.4710 0.099 Uiso calc R 1 1 . .
    C C28 -0.2628(2) 0.07881(9) 0.1182(2) 0.0390(5) Uani d . 1 1 . .
    H H28A -0.2200 0.1036 0.1741 0.047 Uiso calc R 1 1 . .
    C C29 -0.3701(3) 0.09441(10) 0.0145(2) 0.0436(6) Uani d . 1 1 . .
    H H29A -0.3968 0.1289 0.0018 0.052 Uiso calc R 1 1 . .
    C C30 -0.4353(3) 0.05859(10) -0.0678(2) 0.0434(6) Uani d . 1 1 . .
    H H30A -0.5084 0.0682 -0.1368 0.052 Uiso calc R 1 1 . .
    C C31 -0.4547(3) -0.03305(11) -0.1292(2) 0.0452(6) Uani d . 1 1 . .
    H H31A -0.5297 -0.0252 -0.1985 0.054 Uiso calc R 1 1 . .
    C C32 -0.4083(3) -0.08174(11) -0.1075(2) 0.0472(6) Uani d . 1 1 . .
    H H32A -0.4519 -0.1071 -0.1619 0.057 Uiso calc R 1 1 . .
    C C33 -0.2382(3) -0.14554(10) 0.0230(2) 0.0505(7) Uani d . 1 1 . .
    H H33A -0.2772 -0.1718 -0.0300 0.061 Uiso calc R 1 1 . .
    C C34 -0.1286(3) -0.15558(10) 0.1248(2) 0.0530(7) Uani d . 1 1 . .
    H H34A -0.0909 -0.1886 0.1420 0.064 Uiso calc R 1 1 . .
    C C35 -0.0732(3) -0.11570(9) 0.2033(2) 0.0438(6) Uani d . 1 1 . .
    H H35A 0.0016 -0.1232 0.2729 0.053 Uiso calc R 1 1 . .
    C C36 -0.3912(2) 0.00715(9) -0.04773(19) 0.0367(5) Uani d . 1 1 . .
    C C37 -0.2806(2) -0.00555(8) 0.05864(18) 0.0310(5) Uani d . 1 1 . .
    C C38 -0.2924(2) -0.09551(9) -0.0020(2) 0.0385(5) Uani d . 1 1 . .
    C C39 -0.2296(2) -0.05740(9) 0.08161(18) 0.0314(5) Uani d . 1 1 . .
    O O5 0.16714(16) -0.06792(6) 0.62245(12) 0.0340(3) Uani d . 1 1 . .
_geom_special_details
;
All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Gd1 O7 3_556 2.3528(14) y
    Gd1 O4 . 2.3624(15) y
    Gd1 O5 3_556 2.3991(15) y
    Gd1 O2 . 2.4443(16) y
    Gd1 O8 . 2.4742(15) y
    Gd1 O1 . 2.4826(15) y
    Gd1 N2 . 2.5496(18) y
    Gd1 N1 . 2.6184(18) y
    Gd1 O7 . 2.6270(15) y
    Gd1 Gd1 3_556 4.0047(2) ?
    O1 C1 . 1.251(3) ?
    O2 C1 . 1.257(3) ?
    O3 C4 . 1.375(3) ?
    O3 C2 . 1.422(3) ?
    O4 C10 . 1.260(3) ?
    O6 C13 . 1.377(3) ?
    O6 C11 . 1.412(3) ?
    O7 C19 . 1.263(2) ?
    O7 Gd1 3_556 2.3528(14) ?
    O8 C19 . 1.243(2) ?
    O9 C22 . 1.373(3) ?
    O9 C20 . 1.425(3) ?
    N1 C35 . 1.322(3) ?
    N1 C39 . 1.361(3) ?
    N2 C28 . 1.324(3) ?
    N2 C37 . 1.359(3) ?
    C1 C2 . 1.532(3) ?
    C2 C3 . 1.514(4) ?
    C2 H2A . 0.9800 ?
    C3 H3A . 0.9600 ?
    C3 H3B . 0.9600 ?
    C3 H3C . 0.9600 ?
    C4 C9 . 1.375(4) ?
    C4 C5 . 1.381(4) ?
    C5 C6 . 1.368(4) ?
    C5 H5A . 0.9300 ?
    C6 C7 . 1.371(5) ?
    C6 H6A . 0.9300 ?
    C7 C8 . 1.372(5) ?
    C7 H7A . 0.9300 ?
    C8 C9 . 1.387(4) ?
    C8 H8A . 0.9300 ?
    C9 H9A . 0.9300 ?
    C10 O5 . 1.245(3) ?
    C10 C11 . 1.534(3) ?
    C11 C12 . 1.510(4) ?
    C11 H11A . 0.9800 ?
    C12 H12A . 0.9600 ?
    C12 H12B . 0.9600 ?
    C12 H12C . 0.9600 ?
    C13 C18 . 1.365(4) ?
    C13 C14 . 1.387(4) ?
    C14 C15 . 1.368(6) ?
    C14 H14A . 0.9300 ?
    C15 C16 . 1.357(6) ?
    C15 H15A . 0.9300 ?
    C16 C17 . 1.363(6) ?
    C16 H16A . 0.9300 ?
    C17 C18 . 1.370(4) ?
    C17 H17A . 0.9300 ?
    C18 H18A . 0.9300 ?
    C19 C20 . 1.517(3) ?
    C20 C21 . 1.513(3) ?
    C20 H20A . 0.9800 ?
    C21 H21A . 0.9600 ?
    C21 H21B . 0.9600 ?
    C21 H21C . 0.9600 ?
    C22 C27 . 1.368(4) ?
    C22 C23 . 1.372(4) ?
    C23 C24 . 1.379(5) ?
    C23 H23A . 0.9300 ?
    C24 C25 . 1.368(5) ?
    C24 H24A . 0.9300 ?
    C25 C26 . 1.358(5) ?
    C25 H25A . 0.9300 ?
    C26 C27 . 1.391(5) ?
    C26 H26A . 0.9300 ?
    C27 H27A . 0.9300 ?
    C28 C29 . 1.396(3) ?
    C28 H28A . 0.9300 ?
    C29 C30 . 1.361(4) ?
    C29 H29A . 0.9300 ?
    C30 C36 . 1.398(3) ?
    C30 H30A . 0.9300 ?
    C31 C32 . 1.339(4) ?
    C31 C36 . 1.432(3) ?
    C31 H31A . 0.9300 ?
    C32 C38 . 1.435(4) ?
    C32 H32A . 0.9300 ?
    C33 C34 . 1.356(4) ?
    C33 C38 . 1.399(4) ?
    C33 H33A . 0.9300 ?
    C34 C35 . 1.396(4) ?
    C34 H34A . 0.9300 ?
    C35 H35A . 0.9300 ?
    C36 C37 . 1.412(3) ?
    C37 C39 . 1.431(3) ?
    C38 C39 . 1.408(3) ?
    O5 Gd1 3_556 2.3991(15) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O7 Gd1 O4 3_556 . 73.51(5) ?
    O7 Gd1 O5 3_556 3_556 77.96(5) ?
    O4 Gd1 O5 . 3_556 134.90(5) ?
    O7 Gd1 O2 3_556 . 88.00(6) ?
    O4 Gd1 O2 . . 84.30(6) ?
    O5 Gd1 O2 3_556 . 129.04(5) ?
    O7 Gd1 O8 3_556 . 123.43(5) ?
    O4 Gd1 O8 . . 90.69(6) ?
    O5 Gd1 O8 3_556 . 76.75(5) ?
    O2 Gd1 O8 . . 145.29(5) ?
    O7 Gd1 O1 3_556 . 76.76(5) ?
    O4 Gd1 O1 . . 128.11(6) ?
    O5 Gd1 O1 3_556 . 76.13(5) ?
    O2 Gd1 O1 . . 52.93(5) ?
    O8 Gd1 O1 . . 141.14(5) ?
    O7 Gd1 N2 3_556 . 145.19(6) ?
    O4 Gd1 N2 . . 139.42(6) ?
    O5 Gd1 N2 3_556 . 79.73(5) ?
    O2 Gd1 N2 . . 85.65(6) ?
    O8 Gd1 N2 . . 76.04(5) ?
    O1 Gd1 N2 . . 72.15(6) ?
    O7 Gd1 N1 3_556 . 147.42(6) ?
    O4 Gd1 N1 . . 75.96(5) ?
    O5 Gd1 N1 3_556 . 133.34(5) ?
    O2 Gd1 N1 . . 77.85(6) ?
    O8 Gd1 N1 . . 67.63(5) ?
    O1 Gd1 N1 . . 114.94(6) ?
    N2 Gd1 N1 . . 63.50(6) ?
    O7 Gd1 O7 3_556 . 73.06(6) ?
    O4 Gd1 O7 . . 69.62(5) ?
    O5 Gd1 O7 3_556 . 69.05(5) ?
    O2 Gd1 O7 . . 151.06(5) ?
    O8 Gd1 O7 . . 50.74(5) ?
    O1 Gd1 O7 . . 137.62(5) ?
    N2 Gd1 O7 . . 122.31(5) ?
    N1 Gd1 O7 . . 106.49(5) ?
    O7 Gd1 C1 3_556 . 83.56(6) ?
    O4 Gd1 C1 . . 107.99(6) ?
    O5 Gd1 C1 3_556 . 102.59(6) ?
    O2 Gd1 C1 . . 26.59(6) ?
    O8 Gd1 C1 . . 151.29(6) ?
    O1 Gd1 C1 . . 26.50(6) ?
    N2 Gd1 C1 . . 75.63(6) ?
    N1 Gd1 C1 . . 95.34(6) ?
    O7 Gd1 C1 . . 156.27(6) ?
    O7 Gd1 C19 3_556 . 98.61(6) ?
    O4 Gd1 C19 . . 79.26(6) ?
    O5 Gd1 C19 3_556 . 71.28(5) ?
    O2 Gd1 C19 . . 159.67(6) ?
    O8 Gd1 C19 . . 25.04(5) ?
    O1 Gd1 C19 . . 147.31(5) ?
    N2 Gd1 C19 . . 99.11(6) ?
    N1 Gd1 C19 . . 86.56(6) ?
    O7 Gd1 C19 . . 25.70(5) ?
    C1 Gd1 C19 . . 172.75(6) ?
    O7 Gd1 Gd1 3_556 3_556 38.87(4) ?
    O4 Gd1 Gd1 . 3_556 66.72(4) ?
    O5 Gd1 Gd1 3_556 3_556 69.07(3) ?
    O2 Gd1 Gd1 . 3_556 123.61(4) ?
    O8 Gd1 Gd1 . 3_556 84.75(3) ?
    O1 Gd1 Gd1 . 3_556 110.48(4) ?
    N2 Gd1 Gd1 . 3_556 146.41(4) ?
    N1 Gd1 Gd1 . 3_556 132.94(4) ?
    O7 Gd1 Gd1 . 3_556 34.20(3) ?
    C1 Gd1 Gd1 . 3_556 122.32(5) ?
    C19 Gd1 Gd1 . 3_556 59.79(4) ?
    C1 O1 Gd1 . . 91.23(13) ?
    C1 O2 Gd1 . . 92.88(14) ?
    C4 O3 C2 . . 118.7(2) ?
    C10 O4 Gd1 . . 139.77(14) ?
    C13 O6 C11 . . 119.4(2) ?
    C19 O7 Gd1 . 3_556 162.02(14) ?
    C19 O7 Gd1 . . 89.85(12) ?
    Gd1 O7 Gd1 3_556 . 106.94(5) ?
    C19 O8 Gd1 . . 97.57(12) ?
    C22 O9 C20 . . 117.49(18) ?
    C35 N1 C39 . . 117.5(2) ?
    C35 N1 Gd1 . . 123.93(16) ?
    C39 N1 Gd1 . . 117.70(14) ?
    C28 N2 C37 . . 118.3(2) ?
    C28 N2 Gd1 . . 120.95(15) ?
    C37 N2 Gd1 . . 120.28(14) ?
    O1 C1 O2 . . 122.2(2) ?
    O1 C1 C2 . . 119.3(2) ?
    O2 C1 C2 . . 118.4(2) ?
    O1 C1 Gd1 . . 62.28(12) ?
    O2 C1 Gd1 . . 60.53(12) ?
    C2 C1 Gd1 . . 174.03(16) ?
    O3 C2 C3 . . 106.3(2) ?
    O3 C2 C1 . . 111.7(2) ?
    C3 C2 C1 . . 110.1(2) ?
    O3 C2 H2A . . 109.6 ?
    C3 C2 H2A . . 109.6 ?
    C1 C2 H2A . . 109.6 ?
    C2 C3 H3A . . 109.5 ?
    C2 C3 H3B . . 109.5 ?
    H3A C3 H3B . . 109.5 ?
    C2 C3 H3C . . 109.5 ?
    H3A C3 H3C . . 109.5 ?
    H3B C3 H3C . . 109.5 ?
    O3 C4 C9 . . 125.2(2) ?
    O3 C4 C5 . . 114.6(2) ?
    C9 C4 C5 . . 120.2(3) ?
    C6 C5 C4 . . 119.9(3) ?
    C6 C5 H5A . . 120.1 ?
    C4 C5 H5A . . 120.1 ?
    C5 C6 C7 . . 120.7(3) ?
    C5 C6 H6A . . 119.6 ?
    C7 C6 H6A . . 119.6 ?
    C6 C7 C8 . . 119.4(3) ?
    C6 C7 H7A . . 120.3 ?
    C8 C7 H7A . . 120.3 ?
    C7 C8 C9 . . 120.8(3) ?
    C7 C8 H8A . . 119.6 ?
    C9 C8 H8A . . 119.6 ?
    C4 C9 C8 . . 119.0(3) ?
    C4 C9 H9A . . 120.5 ?
    C8 C9 H9A . . 120.5 ?
    O5 C10 O4 . . 127.2(2) ?
    O5 C10 C11 . . 119.46(19) ?
    O4 C10 C11 . . 113.38(19) ?
    O6 C11 C12 . . 107.3(2) ?
    O6 C11 C10 . . 114.85(19) ?
    C12 C11 C10 . . 110.5(2) ?
    O6 C11 H11A . . 108.0 ?
    C12 C11 H11A . . 108.0 ?
    C10 C11 H11A . . 108.0 ?
    C11 C12 H12A . . 109.5 ?
    C11 C12 H12B . . 109.5 ?
    H12A C12 H12B . . 109.5 ?
    C11 C12 H12C . . 109.5 ?
    H12A C12 H12C . . 109.5 ?
    H12B C12 H12C . . 109.5 ?
    C18 C13 O6 . . 126.3(2) ?
    C18 C13 C14 . . 120.1(3) ?
    O6 C13 C14 . . 113.5(3) ?
    C15 C14 C13 . . 119.1(4) ?
    C15 C14 H14A . . 120.4 ?
    C13 C14 H14A . . 120.4 ?
    C16 C15 C14 . . 120.6(4) ?
    C16 C15 H15A . . 119.7 ?
    C14 C15 H15A . . 119.7 ?
    C15 C16 C17 . . 120.0(4) ?
    C15 C16 H16A . . 120.0 ?
    C17 C16 H16A . . 120.0 ?
    C16 C17 C18 . . 120.5(4) ?
    C16 C17 H17A . . 119.8 ?
    C18 C17 H17A . . 119.8 ?
    C13 C18 C17 . . 119.6(3) ?
    C13 C18 H18A . . 120.2 ?
    C17 C18 H18A . . 120.2 ?
    O8 C19 O7 . . 121.83(19) ?
    O8 C19 C20 . . 120.67(19) ?
    O7 C19 C20 . . 117.46(19) ?
    O8 C19 Gd1 . . 57.39(11) ?
    O7 C19 Gd1 . . 64.45(11) ?
    C20 C19 Gd1 . . 177.62(15) ?
    O9 C20 C21 . . 106.8(2) ?
    O9 C20 C19 . . 111.46(18) ?
    C21 C20 C19 . . 110.04(19) ?
    O9 C20 H20A . . 109.5 ?
    C21 C20 H20A . . 109.5 ?
    C19 C20 H20A . . 109.5 ?
    C20 C21 H21A . . 109.5 ?
    C20 C21 H21B . . 109.5 ?
    H21A C21 H21B . . 109.5 ?
    C20 C21 H21C . . 109.5 ?
    H21A C21 H21C . . 109.5 ?
    H21B C21 H21C . . 109.5 ?
    C27 C22 C23 . . 119.7(3) ?
    C27 C22 O9 . . 124.2(3) ?
    C23 C22 O9 . . 116.1(2) ?
    C22 C23 C24 . . 120.0(3) ?
    C22 C23 H23A . . 120.0 ?
    C24 C23 H23A . . 120.0 ?
    C25 C24 C23 . . 120.9(3) ?
    C25 C24 H24A . . 119.6 ?
    C23 C24 H24A . . 119.6 ?
    C26 C25 C24 . . 118.7(3) ?
    C26 C25 H25A . . 120.6 ?
    C24 C25 H25A . . 120.6 ?
    C25 C26 C27 . . 121.4(4) ?
    C25 C26 H26A . . 119.3 ?
    C27 C26 H26A . . 119.3 ?
    C22 C27 C26 . . 119.3(3) ?
    C22 C27 H27A . . 120.3 ?
    C26 C27 H27A . . 120.3 ?
    N2 C28 C29 . . 123.2(2) ?
    N2 C28 H28A . . 118.4 ?
    C29 C28 H28A . . 118.4 ?
    C30 C29 C28 . . 119.3(2) ?
    C30 C29 H29A . . 120.3 ?
    C28 C29 H29A . . 120.3 ?
    C29 C30 C36 . . 119.3(2) ?
    C29 C30 H30A . . 120.3 ?
    C36 C30 H30A . . 120.3 ?
    C32 C31 C36 . . 121.3(2) ?
    C32 C31 H31A . . 119.4 ?
    C36 C31 H31A . . 119.4 ?
    C31 C32 C38 . . 121.2(2) ?
    C31 C32 H32A . . 119.4 ?
    C38 C32 H32A . . 119.4 ?
    C34 C33 C38 . . 119.7(2) ?
    C34 C33 H33A . . 120.2 ?
    C38 C33 H33A . . 120.2 ?
    C33 C34 C35 . . 119.0(2) ?
    C33 C34 H34A . . 120.5 ?
    C35 C34 H34A . . 120.5 ?
    N1 C35 C34 . . 123.7(2) ?
    N1 C35 H35A . . 118.1 ?
    C34 C35 H35A . . 118.1 ?
    C30 C36 C37 . . 118.1(2) ?
    C30 C36 C31 . . 123.0(2) ?
    C37 C36 C31 . . 118.9(2) ?
    N2 C37 C36 . . 121.8(2) ?
    N2 C37 C39 . . 118.29(19) ?
    C36 C37 C39 . . 119.9(2) ?
    C33 C38 C39 . . 117.7(2) ?
    C33 C38 C32 . . 123.1(2) ?
    C39 C38 C32 . . 119.2(2) ?
    N1 C39 C38 . . 122.4(2) ?
    N1 C39 C37 . . 118.26(19) ?
    C38 C39 C37 . . 119.4(2) ?
    C10 O5 Gd1 . 3_556 134.51(14) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O7 Gd1 O1 C1 3_556 . . . 102.35(14) ?
    O4 Gd1 O1 C1 . . . . 46.07(15) ?
    O5 Gd1 O1 C1 3_556 . . . -177.01(14) ?
    O2 Gd1 O1 C1 . . . . 4.72(13) ?
    O8 Gd1 O1 C1 . . . . -130.06(13) ?
    N2 Gd1 O1 C1 . . . . -93.53(14) ?
    N1 Gd1 O1 C1 . . . . -45.34(14) ?
    O7 Gd1 O1 C1 . . . . 147.77(12) ?
    C19 Gd1 O1 C1 . . . . -172.36(13) ?
    Gd1 Gd1 O1 C1 3_556 . . . 122.00(12) ?
    O7 Gd1 O2 C1 3_556 . . . -79.58(14) ?
    O4 Gd1 O2 C1 . . . . -153.20(14) ?
    O5 Gd1 O2 C1 3_556 . . . -6.86(17) ?
    O8 Gd1 O2 C1 . . . . 123.85(14) ?
    O1 Gd1 O2 C1 . . . . -4.70(13) ?
    N2 Gd1 O2 C1 . . . . 66.17(14) ?
    N1 Gd1 O2 C1 . . . . 129.97(15) ?
    O7 Gd1 O2 C1 . . . . -127.86(14) ?
    C19 Gd1 O2 C1 . . . . 170.75(16) ?
    Gd1 Gd1 O2 C1 3_556 . . . -96.11(14) ?
    O7 Gd1 O4 C10 3_556 . . . 24.2(2) ?
    O5 Gd1 O4 C10 3_556 . . . -28.8(3) ?
    O2 Gd1 O4 C10 . . . . 113.8(2) ?
    O8 Gd1 O4 C10 . . . . -100.7(2) ?
    O1 Gd1 O4 C10 . . . . 81.8(2) ?
    N2 Gd1 O4 C10 . . . . -169.8(2) ?
    N1 Gd1 O4 C10 . . . . -167.4(2) ?
    O7 Gd1 O4 C10 . . . . -53.5(2) ?
    C1 Gd1 O4 C10 . . . . 101.5(2) ?
    C19 Gd1 O4 C10 . . . . -78.3(2) ?
    Gd1 Gd1 O4 C10 3_556 . . . -16.7(2) ?
    O7 Gd1 O7 C19 3_556 . . . 173.47(15) ?
    O4 Gd1 O7 C19 . . . . -108.27(13) ?
    O5 Gd1 O7 C19 3_556 . . . 90.18(12) ?
    O2 Gd1 O7 C19 . . . . -135.29(13) ?
    O8 Gd1 O7 C19 . . . . 0.41(11) ?
    O1 Gd1 O7 C19 . . . . 127.01(12) ?
    N2 Gd1 O7 C19 . . . . 28.09(14) ?
    N1 Gd1 O7 C19 . . . . -40.59(13) ?
    C1 Gd1 O7 C19 . . . . 163.26(16) ?
    Gd1 Gd1 O7 C19 3_556 . . . 173.47(15) ?
    O7 Gd1 O7 Gd1 3_556 . . 3_556 0.0 ?
    O4 Gd1 O7 Gd1 . . . 3_556 78.27(6) ?
    O5 Gd1 O7 Gd1 3_556 . . 3_556 -83.28(6) ?
    O2 Gd1 O7 Gd1 . . . 3_556 51.24(13) ?
    O8 Gd1 O7 Gd1 . . . 3_556 -173.05(9) ?
    O1 Gd1 O7 Gd1 . . . 3_556 -46.45(10) ?
    N2 Gd1 O7 Gd1 . . . 3_556 -145.37(6) ?
    N1 Gd1 O7 Gd1 . . . 3_556 145.94(6) ?
    C1 Gd1 O7 Gd1 . . . 3_556 -10.20(18) ?
    C19 Gd1 O7 Gd1 . . . 3_556 -173.47(15) ?
    O7 Gd1 O8 C19 3_556 . . . -8.40(15) ?
    O4 Gd1 O8 C19 . . . . 62.20(13) ?
    O5 Gd1 O8 C19 3_556 . . . -74.05(12) ?
    O2 Gd1 O8 C19 . . . . 143.17(13) ?
    O1 Gd1 O8 C19 . . . . -120.83(13) ?
    N2 Gd1 O8 C19 . . . . -156.56(13) ?
    N1 Gd1 O8 C19 . . . . 136.70(14) ?
    O7 Gd1 O8 C19 . . . . -0.42(11) ?
    C1 Gd1 O8 C19 . . . . -166.13(14) ?
    Gd1 Gd1 O8 C19 3_556 . . . -4.34(12) ?
    O7 Gd1 N1 C35 3_556 . . . 21.8(2) ?
    O4 Gd1 N1 C35 . . . . 0.91(19) ?
    O5 Gd1 N1 C35 3_556 . . . -138.95(18) ?
    O2 Gd1 N1 C35 . . . . 88.00(19) ?
    O8 Gd1 N1 C35 . . . . -95.8(2) ?
    O1 Gd1 N1 C35 . . . . 126.74(19) ?
    N2 Gd1 N1 C35 . . . . 179.2(2) ?
    O7 Gd1 N1 C35 . . . . -62.4(2) ?
    C1 Gd1 N1 C35 . . . . 108.15(19) ?
    C19 Gd1 N1 C35 . . . . -78.86(19) ?
    Gd1 Gd1 N1 C35 3_556 . . . -37.0(2) ?
    O7 Gd1 N1 C39 3_556 . . . -169.06(13) ?
    O4 Gd1 N1 C39 . . . . 170.09(16) ?
    O5 Gd1 N1 C39 3_556 . . . 30.23(18) ?
    O2 Gd1 N1 C39 . . . . -102.83(16) ?
    O8 Gd1 N1 C39 . . . . 73.41(15) ?
    O1 Gd1 N1 C39 . . . . -64.09(16) ?
    N2 Gd1 N1 C39 . . . . -11.64(14) ?
    O7 Gd1 N1 C39 . . . . 106.74(15) ?
    C1 Gd1 N1 C39 . . . . -82.67(16) ?
    C19 Gd1 N1 C39 . . . . 90.32(15) ?
    Gd1 Gd1 N1 C39 3_556 . . . 132.20(13) ?
    O7 Gd1 N2 C28 3_556 . . . -18.1(2) ?
    O4 Gd1 N2 C28 . . . . -174.25(16) ?
    O5 Gd1 N2 C28 3_556 . . . 32.72(17) ?
    O2 Gd1 N2 C28 . . . . -98.25(18) ?
    O8 Gd1 N2 C28 . . . . 111.48(18) ?
    O1 Gd1 N2 C28 . . . . -45.88(17) ?
    N1 Gd1 N2 C28 . . . . -176.84(19) ?
    O7 Gd1 N2 C28 . . . . 89.72(18) ?
    C1 Gd1 N2 C28 . . . . -73.25(18) ?
    C19 Gd1 N2 C28 . . . . 101.66(18) ?
    Gd1 Gd1 N2 C28 3_556 . . . 54.5(2) ?
    O7 Gd1 N2 C37 3_556 . . . 170.22(14) ?
    O4 Gd1 N2 C37 . . . . 14.0(2) ?
    O5 Gd1 N2 C37 3_556 . . . -138.98(16) ?
    O2 Gd1 N2 C37 . . . . 90.05(16) ?
    O8 Gd1 N2 C37 . . . . -60.22(16) ?
    O1 Gd1 N2 C37 . . . . 142.42(17) ?
    N1 Gd1 N2 C37 . . . . 11.46(15) ?
    O7 Gd1 N2 C37 . . . . -81.98(16) ?
    C1 Gd1 N2 C37 . . . . 115.05(17) ?
    C19 Gd1 N2 C37 . . . . -70.04(16) ?
    Gd1 Gd1 N2 C37 3_556 . . . -117.23(15) ?
    Gd1 O1 C1 O2 . . . . -8.7(2) ?
    Gd1 O1 C1 C2 . . . . 173.45(19) ?
    Gd1 O2 C1 O1 . . . . 8.8(2) ?
    Gd1 O2 C1 C2 . . . . -173.29(18) ?
    O7 Gd1 C1 O1 3_556 . . . -73.12(13) ?
    O4 Gd1 C1 O1 . . . . -143.43(12) ?
    O5 Gd1 C1 O1 3_556 . . . 2.97(14) ?
    O2 Gd1 C1 O1 . . . . -171.6(2) ?
    O8 Gd1 C1 O1 . . . . 88.32(17) ?
    N2 Gd1 C1 O1 . . . . 78.74(13) ?
    N1 Gd1 C1 O1 . . . . 139.62(13) ?
    O7 Gd1 C1 O1 . . . . -63.3(2) ?
    Gd1 Gd1 C1 O1 3_556 . . . -70.07(14) ?
    O7 Gd1 C1 O2 3_556 . . . 98.45(14) ?
    O4 Gd1 C1 O2 . . . . 28.14(15) ?
    O5 Gd1 C1 O2 3_556 . . . 174.55(13) ?
    O8 Gd1 C1 O2 . . . . -100.11(17) ?
    O1 Gd1 C1 O2 . . . . 171.6(2) ?
    N2 Gd1 C1 O2 . . . . -109.69(14) ?
    N1 Gd1 C1 O2 . . . . -48.80(14) ?
    O7 Gd1 C1 O2 . . . . 108.27(18) ?
    Gd1 Gd1 C1 O2 3_556 . . . 101.51(14) ?
    C4 O3 C2 C3 . . . . 163.1(2) ?
    C4 O3 C2 C1 . . . . -76.8(3) ?
    O1 C1 C2 O3 . . . . -35.4(3) ?
    O2 C1 C2 O3 . . . . 146.6(2) ?
    O1 C1 C2 C3 . . . . 82.4(3) ?
    O2 C1 C2 C3 . . . . -95.5(3) ?
    C2 O3 C4 C9 . . . . -2.7(4) ?
    C2 O3 C4 C5 . . . . 179.2(2) ?
    O3 C4 C5 C6 . . . . 177.1(3) ?
    C9 C4 C5 C6 . . . . -1.1(4) ?
    C4 C5 C6 C7 . . . . 0.2(5) ?
    C5 C6 C7 C8 . . . . 0.1(5) ?
    C6 C7 C8 C9 . . . . 0.5(5) ?
    O3 C4 C9 C8 . . . . -176.3(3) ?
    C5 C4 C9 C8 . . . . 1.8(4) ?
    C7 C8 C9 C4 . . . . -1.5(5) ?
    Gd1 O4 C10 O5 . . . . 13.8(4) ?
    Gd1 O4 C10 C11 . . . . -166.83(17) ?
    C13 O6 C11 C12 . . . . -155.8(2) ?
    C13 O6 C11 C10 . . . . 81.0(3) ?
    O5 C10 C11 O6 . . . . -3.0(3) ?
    O4 C10 C11 O6 . . . . 177.6(2) ?
    O5 C10 C11 C12 . . . . -124.5(2) ?
    O4 C10 C11 C12 . . . . 56.0(3) ?
    C11 O6 C13 C18 . . . . -22.0(4) ?
    C11 O6 C13 C14 . . . . 161.6(2) ?
    C18 C13 C14 C15 . . . . -0.4(5) ?
    O6 C13 C14 C15 . . . . 176.3(3) ?
    C13 C14 C15 C16 . . . . -0.2(6) ?
    C14 C15 C16 C17 . . . . 0.5(7) ?
    C15 C16 C17 C18 . . . . -0.2(6) ?
    O6 C13 C18 C17 . . . . -175.5(3) ?
    C14 C13 C18 C17 . . . . 0.7(4) ?
    C16 C17 C18 C13 . . . . -0.4(5) ?
    Gd1 O8 C19 O7 . . . . 0.8(2) ?
    Gd1 O8 C19 C20 . . . . 178.39(17) ?
    Gd1 O7 C19 O8 3_556 . . . 158.6(3) ?
    Gd1 O7 C19 O8 . . . . -0.8(2) ?
    Gd1 O7 C19 C20 3_556 . . . -19.1(6) ?
    Gd1 O7 C19 C20 . . . . -178.41(17) ?
    Gd1 O7 C19 Gd1 3_556 . . . 159.3(5) ?
    O7 Gd1 C19 O8 3_556 . . . 172.92(12) ?
    O4 Gd1 C19 O8 . . . . -115.80(13) ?
    O5 Gd1 C19 O8 3_556 . . . 98.83(13) ?
    O2 Gd1 C19 O8 . . . . -79.2(2) ?
    O1 Gd1 C19 O8 . . . . 94.06(15) ?
    N2 Gd1 C19 O8 . . . . 23.01(13) ?
    N1 Gd1 C19 O8 . . . . -39.45(13) ?
    O7 Gd1 C19 O8 . . . . 179.2(2) ?
    Gd1 Gd1 C19 O8 3_556 . . . 175.00(14) ?
    O7 Gd1 C19 O7 3_556 . . . -6.32(15) ?
    O4 Gd1 C19 O7 . . . . 64.96(12) ?
    O5 Gd1 C19 O7 3_556 . . . -80.41(12) ?
    O2 Gd1 C19 O7 . . . . 101.55(19) ?
    O8 Gd1 C19 O7 . . . . -179.2(2) ?
    O1 Gd1 C19 O7 . . . . -85.18(15) ?
    N2 Gd1 C19 O7 . . . . -156.23(12) ?
    N1 Gd1 C19 O7 . . . . 141.31(12) ?
    Gd1 Gd1 C19 O7 3_556 . . . -4.24(10) ?
    C22 O9 C20 C21 . . . . -174.0(2) ?
    C22 O9 C20 C19 . . . . 65.8(3) ?
    O8 C19 C20 O9 . . . . 30.7(3) ?
    O7 C19 C20 O9 . . . . -151.64(19) ?
    O8 C19 C20 C21 . . . . -87.6(3) ?
    O7 C19 C20 C21 . . . . 90.1(2) ?
    C20 O9 C22 C27 . . . . 10.8(4) ?
    C20 O9 C22 C23 . . . . -170.1(2) ?
    C27 C22 C23 C24 . . . . 0.3(5) ?
    O9 C22 C23 C24 . . . . -178.9(3) ?
    C22 C23 C24 C25 . . . . 0.4(6) ?
    C23 C24 C25 C26 . . . . -0.5(7) ?
    C24 C25 C26 C27 . . . . -0.1(8) ?
    C23 C22 C27 C26 . . . . -0.8(6) ?
    O9 C22 C27 C26 . . . . 178.2(4) ?
    C25 C26 C27 C22 . . . . 0.8(7) ?
    C37 N2 C28 C29 . . . . 1.0(4) ?
    Gd1 N2 C28 C29 . . . . -170.91(18) ?
    N2 C28 C29 C30 . . . . 0.9(4) ?
    C28 C29 C30 C36 . . . . -1.6(4) ?
    C36 C31 C32 C38 . . . . -0.4(4) ?
    C38 C33 C34 C35 . . . . 0.9(4) ?
    C39 N1 C35 C34 . . . . -0.5(4) ?
    Gd1 N1 C35 C34 . . . . 168.7(2) ?
    C33 C34 C35 N1 . . . . -0.5(4) ?
    C29 C30 C36 C37 . . . . 0.6(4) ?
    C29 C30 C36 C31 . . . . 179.4(2) ?
    C32 C31 C36 C30 . . . . 178.9(2) ?
    C32 C31 C36 C37 . . . . -2.3(4) ?
    C28 N2 C37 C36 . . . . -2.0(3) ?
    Gd1 N2 C37 C36 . . . . 169.90(16) ?
    C28 N2 C37 C39 . . . . 177.3(2) ?
    Gd1 N2 C37 C39 . . . . -10.7(3) ?
    C30 C36 C37 N2 . . . . 1.3(3) ?
    C31 C36 C37 N2 . . . . -177.6(2) ?
    C30 C36 C37 C39 . . . . -178.1(2) ?
    C31 C36 C37 C39 . . . . 3.1(3) ?
    C34 C33 C38 C39 . . . . -0.3(4) ?
    C34 C33 C38 C32 . . . . -179.9(3) ?
    C31 C32 C38 C33 . . . . -178.1(3) ?
    C31 C32 C38 C39 . . . . 2.3(4) ?
    C35 N1 C39 C38 . . . . 1.1(3) ?
    Gd1 N1 C39 C38 . . . . -168.80(16) ?
    C35 N1 C39 C37 . . . . -178.6(2) ?
    Gd1 N1 C39 C37 . . . . 11.5(2) ?
    C33 C38 C39 N1 . . . . -0.7(3) ?
    C32 C38 C39 N1 . . . . 178.9(2) ?
    C33 C38 C39 C37 . . . . 178.9(2) ?
    C32 C38 C39 C37 . . . . -1.5(3) ?
    N2 C37 C39 N1 . . . . -0.9(3) ?
    C36 C37 C39 N1 . . . . 178.46(19) ?
    N2 C37 C39 C38 . . . . 179.4(2) ?
    C36 C37 C39 C38 . . . . -1.2(3) ?
    O4 C10 O5 Gd1 . . . 3_556 8.9(4) ?
    C11 C10 O5 Gd1 . . . 3_556 -170.47(15) ?
