##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.4.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
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data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Bis[N'-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I)
trifluoromethanesulfonate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C28 H20 Ag N8 O2 +, C F3 O3 S -'
_chemical_formula_sum     'C29 H20 Ag F3 N8 O5 S'
_chemical_formula_iupac     '[Ag (C14 H10 N4 O)2] C F3 S O3'
_chemical_formula_weight     757.46
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     7.5481(17)
_cell_length_b     14.164(3)
_cell_length_c     14.175(3)
_cell_angle_alpha     87.895(4)
_cell_angle_beta     89.918(4)
_cell_angle_gamma     81.355(4)
_cell_volume     1497.2(6)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     2331
_cell_measurement_theta_min     2.01
_cell_measurement_theta_max     25.50
_cell_measurement_temperature     173(2)
_exptl_crystal_description     needle
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.32
_exptl_crystal_size_mid     0.22
_exptl_crystal_size_min     0.17
_exptl_crystal_density_diffrn     1.680
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     760
_exptl_absorpt_coefficient_mu     0.816
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2005)'
_exptl_absorpt_correction_T_min     0.7801
_exptl_absorpt_correction_T_max     0.8737
_exptl_special_details     ?
_diffrn_ambient_temperature     173(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     8251
_diffrn_reflns_av_R_equivalents     0.0230
_diffrn_reflns_av_sigmaI/netI     0.0465
_diffrn_reflns_theta_min     2.01
_diffrn_reflns_theta_max     25.50
_diffrn_reflns_theta_full     25.50
_diffrn_measured_fraction_theta_max     0.980
_diffrn_measured_fraction_theta_full     0.980
_diffrn_reflns_limit_h_min     -8
_diffrn_reflns_limit_h_max     9
_diffrn_reflns_limit_k_min     -15
_diffrn_reflns_limit_k_max     17
_diffrn_reflns_limit_l_min     -15
_diffrn_reflns_limit_l_max     17
_diffrn_standards_number     ?
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details     ?
_reflns_number_total     5461
_reflns_number_gt     3857
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0861
_refine_ls_R_factor_gt     0.0603
_refine_ls_wR_factor_gt     0.1552
_refine_ls_wR_factor_ref     0.1752
_refine_ls_goodness_of_fit_ref     1.033
_refine_ls_restrained_S_all     1.033
_refine_ls_number_reflns     5461
_refine_ls_number_parameters     433
_refine_ls_number_restraints     0
_refine_ls_number_constraints     0
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0934P)²+1.7184P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.042
_refine_diff_density_min     -0.870
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ag' 'Ag' -0.8971 1.1015
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'F' 'F' 0.0171 0.0103
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2005)'
_computing_cell_refinement     'SAINT (Bruker, 2005)'
_computing_data_reduction     'SAINT (Bruker, 2005)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics
                    'SHELXL97 (Sheldrick, 2008) and DIAMOND (Brandenburg, 2005)'
_computing_publication_material     'SHELXL97 (Sheldrick, 2008)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag1 0.93777(7) 0.21340(3) 0.17729(3) 0.0685(2) Uani d . 1 . .
    N N1 0.8202(6) 0.1314(3) 0.0743(3) 0.0514(11) Uani d . 1 . .
    N N2 0.5612(6) -0.0094(4) -0.2091(3) 0.0513(11) Uani d . 1 . .
    N N3 0.5110(6) -0.0664(3) -0.2783(3) 0.0521(11) Uani d . 1 . .
    N N4 0.0251(8) 0.0449(4) -0.7023(4) 0.0721(14) Uani d . 1 . .
    N N5 1.0223(6) 0.3075(3) 0.2790(3) 0.0537(11) Uani d . 1 . .
    N N6 1.2968(6) 0.4563(4) 0.5530(3) 0.0513(11) Uani d . 1 . .
    N N7 1.3579(6) 0.5147(3) 0.6166(3) 0.0505(10) Uani d . 1 . .
    N N8 1.8445(9) 0.4103(5) 1.0418(4) 0.0814(16) Uani d . 1 . .
    O O1 0.7156(6) -0.1358(3) -0.1262(3) 0.0635(11) Uani d . 1 . .
    O O2 1.2202(6) 0.5775(3) 0.4444(3) 0.0660(11) Uani d . 1 . .
    O O3 0.2036(7) 0.2847(3) 0.6588(3) 0.0823(14) Uani d . 1 . .
    O O4 0.1417(11) 0.1451(4) 0.7472(4) 0.120(2) Uani d . 1 . .
    O O5 0.4103(8) 0.2082(5) 0.7702(4) 0.124(2) Uani d . 1 . .
    S S3 0.2325(3) 0.22699(11) 0.74187(11) 0.0677(5) Uani d . 1 . .
    F F1 -0.0500(8) 0.3171(5) 0.8159(4) 0.135(2) Uani d . 1 . .
    F F2 0.1803(8) 0.3828(3) 0.8371(3) 0.1131(17) Uani d . 1 . .
    F F3 0.1446(7) 0.2578(3) 0.9181(3) 0.0987(14) Uani d . 1 . .
    C C1 0.8156(7) 0.0385(4) 0.0907(4) 0.0512(13) Uani d . 1 . .
    H H1 0.8508 0.0115 0.1513 0.061 Uiso calc R 1 . .
    C C2 0.7630(7) -0.0201(4) 0.0248(4) 0.0498(12) Uani d . 1 . .
    H H2 0.7614 -0.0859 0.0398 0.060 Uiso calc R 1 . .
    C C3 0.7118(6) 0.0181(4) -0.0644(3) 0.0425(11) Uani d . 1 . .
    C C4 0.7153(9) 0.1136(4) -0.0820(4) 0.0589(15) Uani d . 1 . .
    H H4 0.6811 0.1424 -0.1422 0.071 Uiso calc R 1 . .
    C C5 0.7688(9) 0.1674(4) -0.0114(4) 0.0617(15) Uani d . 1 . .
    H H5 0.7693 0.2336 -0.0243 0.074 Uiso calc R 1 . .
    C C6 0.6637(7) -0.0506(4) -0.1360(4) 0.0471(12) Uani d . 1 . .
    C C7 0.4229(7) -0.0216(4) -0.3474(4) 0.0524(13) Uani d . 1 . .
    H H7 0.4010 0.0463 -0.3488 0.063 Uiso calc R 1 . .
    C C8 0.3555(7) -0.0722(4) -0.4237(3) 0.0473(12) Uani d . 1 . .
    C C9 0.3767(9) -0.1707(4) -0.4261(4) 0.0662(16) Uani d . 1 . .
    H H9 0.4402 -0.2080 -0.3765 0.079 Uiso calc R 1 . .
    C C10 0.3077(11) -0.2158(5) -0.4991(5) 0.082(2) Uani d . 1 . .
    H H10 0.3247 -0.2836 -0.4997 0.098 Uiso calc R 1 . .
    C C11 0.2132(10) -0.1621(5) -0.5717(5) 0.0746(19) Uani d . 1 . .
    H H11 0.1631 -0.1929 -0.6214 0.089 Uiso calc R 1 . .
    C C12 0.1925(8) -0.0643(4) -0.5713(4) 0.0559(14) Uani d . 1 . .
    C C13 0.2621(7) -0.0184(4) -0.4967(3) 0.0484(12) Uani d . 1 . .
    H H13 0.2454 0.0494 -0.4962 0.058 Uiso calc R 1 . .
    C C14 0.0978(8) -0.0051(5) -0.6452(4) 0.0572(14) Uani d . 1 . .
    C C15 1.0095(7) 0.4007(4) 0.2630(4) 0.0520(13) Uani d . 1 . .
    H H15 0.9526 0.4275 0.2064 0.062 Uiso calc R 1 . .
    C C16 1.0737(7) 0.4608(4) 0.3233(4) 0.0495(12) Uani d . 1 . .
    H H16 1.0617 0.5273 0.3079 0.059 Uiso calc R 1 . .
    C C17 1.1562(7) 0.4243(4) 0.4069(3) 0.0442(11) Uani d . 1 . .
    C C18 1.1695(10) 0.3279(4) 0.4243(4) 0.0723(19) Uani d . 1 . .
    H H18 1.2229 0.2998 0.4813 0.087 Uiso calc R 1 . .
    C C19 1.1061(11) 0.2720(4) 0.3597(5) 0.078(2) Uani d . 1 . .
    H H19 1.1216 0.2048 0.3721 0.093 Uiso calc R 1 . .
    C C20 1.2263(7) 0.4947(4) 0.4696(4) 0.0477(12) Uani d . 1 . .
    C C21 1.4326(7) 0.4693(4) 0.6902(4) 0.0510(13) Uani d . 1 . .
    H H21 1.4425 0.4016 0.6954 0.061 Uiso calc R 1 . .
    C C22 1.5024(7) 0.5212(4) 0.7661(4) 0.0490(12) Uani d . 1 . .
    C C23 1.4820(8) 0.6210(4) 0.7655(4) 0.0575(14) Uani d . 1 . .
    H H23 1.4170 0.6576 0.7158 0.069 Uiso calc R 1 . .
    C C24 1.5556(9) 0.6667(4) 0.8366(4) 0.0648(16) Uani d . 1 . .
    H H24 1.5403 0.7345 0.8364 0.078 Uiso calc R 1 . .
    C C25 1.6511(8) 0.6137(4) 0.9077(4) 0.0615(15) Uani d . 1 . .
    H H25 1.7058 0.6451 0.9553 0.074 Uiso calc R 1 . .
    C C26 1.6686(7) 0.5153(4) 0.9106(4) 0.0535(13) Uani d . 1 . .
    C C27 1.5949(7) 0.4690(4) 0.8391(4) 0.0504(12) Uani d . 1 . .
    H H27 1.6082 0.4012 0.8406 0.060 Uiso calc R 1 . .
    C C28 1.7683(8) 0.4570(4) 0.9849(4) 0.0581(14) Uani d . 1 . .
    C C29 0.1274(11) 0.2994(4) 0.8338(5) 0.0696(17) Uani d . 1 . .
    H H28 1.287(7) 0.397(4) 0.575(4) 0.047(15) Uiso d . 1 . .
    H H29 0.529(8) 0.051(4) -0.217(4) 0.055(17) Uiso d . 1 . .
_geom_special_details     ?
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 N5 . 2.160(4) y
    Ag1 N1 . 2.169(4) y
    N1 C1 . 1.333(7) ?
    N1 C5 . 1.335(7) ?
    N2 C6 . 1.354(7) ?
    N2 N3 . 1.381(6) ?
    N2 H29 . 0.86(6) ?
    N3 C7 . 1.278(7) ?
    N4 C14 . 1.140(7) ?
    N5 C15 . 1.320(7) ?
    N5 C19 . 1.351(8) ?
    N6 C20 . 1.359(7) ?
    N6 N7 . 1.371(6) ?
    N6 H28 . 0.90(5) ?
    N7 C21 . 1.291(7) ?
    N8 C28 . 1.126(8) ?
    O1 C6 . 1.215(6) ?
    O2 C20 . 1.207(6) ?
    O3 S3 . 1.407(4) ?
    O4 S3 . 1.432(6) ?
    O5 S3 . 1.385(6) ?
    S3 C29 . 1.798(7) ?
    F1 C29 . 1.347(9) ?
    F2 C29 . 1.305(8) ?
    F3 C29 . 1.310(7) ?
    C1 C2 . 1.371(7) ?
    C1 H1 . 0.9500 ?
    C2 C3 . 1.389(7) ?
    C2 H2 . 0.9500 ?
    C3 C4 . 1.371(7) ?
    C3 C6 . 1.514(7) ?
    C4 C5 . 1.377(7) ?
    C4 H4 . 0.9500 ?
    C5 H5 . 0.9500 ?
    C7 C8 . 1.453(7) ?
    C7 H7 . 0.9500 ?
    C8 C9 . 1.381(8) ?
    C8 C13 . 1.390(7) ?
    C9 C10 . 1.379(8) ?
    C9 H9 . 0.9500 ?
    C10 C11 . 1.389(9) ?
    C10 H10 . 0.9500 ?
    C11 C12 . 1.370(9) ?
    C11 H11 . 0.9500 ?
    C12 C13 . 1.404(7) ?
    C12 C14 . 1.439(8) ?
    C13 H13 . 0.9500 ?
    C15 C16 . 1.366(7) ?
    C15 H15 . 0.9500 ?
    C16 C17 . 1.386(7) ?
    C16 H16 . 0.9500 ?
    C17 C18 . 1.368(8) ?
    C17 C20 . 1.513(7) ?
    C18 C19 . 1.365(8) ?
    C18 H18 . 0.9500 ?
    C19 H19 . 0.9500 ?
    C21 C22 . 1.467(7) ?
    C21 H21 . 0.9500 ?
    C22 C27 . 1.377(7) ?
    C22 C23 . 1.399(8) ?
    C23 C24 . 1.379(8) ?
    C23 H23 . 0.9500 ?
    C24 C25 . 1.371(9) ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.380(8) ?
    C25 H25 . 0.9500 ?
    C26 C27 . 1.389(7) ?
    C26 C28 . 1.452(8) ?
    C27 H27 . 0.9500 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N5 Ag1 N1 . . 172.56(17) y
    C1 N1 C5 . . 116.7(4) ?
    C1 N1 Ag1 . . 120.4(3) ?
    C5 N1 Ag1 . . 122.4(4) ?
    C6 N2 N3 . . 119.1(5) ?
    C6 N2 H29 . . 124(4) ?
    N3 N2 H29 . . 116(4) ?
    C7 N3 N2 . . 115.2(5) ?
    C15 N5 C19 . . 116.4(5) ?
    C15 N5 Ag1 . . 122.6(3) ?
    C19 N5 Ag1 . . 120.7(4) ?
    C20 N6 N7 . . 119.2(5) ?
    C20 N6 H28 . . 124(4) ?
    N7 N6 H28 . . 116(4) ?
    C21 N7 N6 . . 113.5(4) ?
    O5 S3 O3 . . 113.8(4) ?
    O5 S3 O4 . . 114.0(4) ?
    O3 S3 O4 . . 115.9(3) ?
    O5 S3 C29 . . 103.2(4) ?
    O3 S3 C29 . . 105.1(3) ?
    O4 S3 C29 . . 102.8(4) ?
    N1 C1 C2 . . 123.6(5) ?
    N1 C1 H1 . . 118.2 ?
    C2 C1 H1 . . 118.2 ?
    C1 C2 C3 . . 118.9(5) ?
    C1 C2 H2 . . 120.5 ?
    C3 C2 H2 . . 120.5 ?
    C4 C3 C2 . . 118.1(5) ?
    C4 C3 C6 . . 125.1(4) ?
    C2 C3 C6 . . 116.8(4) ?
    C3 C4 C5 . . 119.1(5) ?
    C3 C4 H4 . . 120.5 ?
    C5 C4 H4 . . 120.5 ?
    N1 C5 C4 . . 123.6(5) ?
    N1 C5 H5 . . 118.2 ?
    C4 C5 H5 . . 118.2 ?
    O1 C6 N2 . . 124.3(5) ?
    O1 C6 C3 . . 120.7(4) ?
    N2 C6 C3 . . 114.9(4) ?
    N3 C7 C8 . . 121.4(5) ?
    N3 C7 H7 . . 119.3 ?
    C8 C7 H7 . . 119.3 ?
    C9 C8 C13 . . 118.7(5) ?
    C9 C8 C7 . . 123.2(5) ?
    C13 C8 C7 . . 118.0(5) ?
    C10 C9 C8 . . 121.4(6) ?
    C10 C9 H9 . . 119.3 ?
    C8 C9 H9 . . 119.3 ?
    C9 C10 C11 . . 119.9(6) ?
    C9 C10 H10 . . 120.0 ?
    C11 C10 H10 . . 120.0 ?
    C12 C11 C10 . . 119.6(5) ?
    C12 C11 H11 . . 120.2 ?
    C10 C11 H11 . . 120.2 ?
    C11 C12 C13 . . 120.4(5) ?
    C11 C12 C14 . . 122.0(5) ?
    C13 C12 C14 . . 117.6(5) ?
    C8 C13 C12 . . 119.9(5) ?
    C8 C13 H13 . . 120.0 ?
    C12 C13 H13 . . 120.0 ?
    N4 C14 C12 . . 177.3(6) ?
    N5 C15 C16 . . 123.6(5) ?
    N5 C15 H15 . . 118.2 ?
    C16 C15 H15 . . 118.2 ?
    C15 C16 C17 . . 119.8(5) ?
    C15 C16 H16 . . 120.1 ?
    C17 C16 H16 . . 120.1 ?
    C18 C17 C16 . . 117.0(5) ?
    C18 C17 C20 . . 126.1(5) ?
    C16 C17 C20 . . 116.9(4) ?
    C19 C18 C17 . . 120.0(5) ?
    C19 C18 H18 . . 120.0 ?
    C17 C18 H18 . . 120.0 ?
    N5 C19 C18 . . 123.1(5) ?
    N5 C19 H19 . . 118.4 ?
    C18 C19 H19 . . 118.4 ?
    O2 C20 N6 . . 124.5(5) ?
    O2 C20 C17 . . 120.9(5) ?
    N6 C20 C17 . . 114.5(4) ?
    N7 C21 C22 . . 120.6(5) ?
    N7 C21 H21 . . 119.7 ?
    C22 C21 H21 . . 119.7 ?
    C27 C22 C23 . . 119.4(5) ?
    C27 C22 C21 . . 118.2(5) ?
    C23 C22 C21 . . 122.4(5) ?
    C24 C23 C22 . . 120.3(6) ?
    C24 C23 H23 . . 119.8 ?
    C22 C23 H23 . . 119.8 ?
    C25 C24 C23 . . 119.7(6) ?
    C25 C24 H24 . . 120.2 ?
    C23 C24 H24 . . 120.2 ?
    C24 C25 C26 . . 120.7(5) ?
    C24 C25 H25 . . 119.7 ?
    C26 C25 H25 . . 119.7 ?
    C25 C26 C27 . . 119.8(5) ?
    C25 C26 C28 . . 122.2(5) ?
    C27 C26 C28 . . 118.0(5) ?
    C22 C27 C26 . . 120.1(5) ?
    C22 C27 H27 . . 120.0 ?
    C26 C27 H27 . . 120.0 ?
    N8 C28 C26 . . 178.7(6) ?
    F2 C29 F3 . . 108.7(6) ?
    F2 C29 F1 . . 106.0(6) ?
    F3 C29 F1 . . 106.0(6) ?
    F2 C29 S3 . . 113.5(5) ?
    F3 C29 S3 . . 113.9(4) ?
    F1 C29 S3 . . 108.1(5) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C6 N2 N3 C7 . . . . -176.3(5) ?
    C20 N6 N7 C21 . . . . -175.6(5) ?
    C5 N1 C1 C2 . . . . 0.4(8) ?
    Ag1 N1 C1 C2 . . . . -172.1(4) ?
    N1 C1 C2 C3 . . . . 0.3(8) ?
    C1 C2 C3 C4 . . . . -0.5(8) ?
    C1 C2 C3 C6 . . . . 177.1(5) ?
    C2 C3 C4 C5 . . . . 0.1(9) ?
    C6 C3 C4 C5 . . . . -177.3(5) ?
    C1 N1 C5 C4 . . . . -0.9(9) ?
    Ag1 N1 C5 C4 . . . . 171.4(5) ?
    C3 C4 C5 N1 . . . . 0.7(10) ?
    N3 N2 C6 O1 . . . . -0.2(8) ?
    N3 N2 C6 C3 . . . . 179.8(4) ?
    C4 C3 C6 O1 . . . . 156.7(6) ?
    C2 C3 C6 O1 . . . . -20.7(8) ?
    C4 C3 C6 N2 . . . . -23.3(8) ?
    C2 C3 C6 N2 . . . . 159.3(5) ?
    N2 N3 C7 C8 . . . . -177.8(5) ?
    N3 C7 C8 C9 . . . . 1.9(9) ?
    N3 C7 C8 C13 . . . . -179.5(5) ?
    C13 C8 C9 C10 . . . . 0.1(10) ?
    C7 C8 C9 C10 . . . . 178.7(6) ?
    C8 C9 C10 C11 . . . . -0.6(12) ?
    C9 C10 C11 C12 . . . . 1.4(12) ?
    C10 C11 C12 C13 . . . . -1.7(10) ?
    C10 C11 C12 C14 . . . . 179.2(7) ?
    C9 C8 C13 C12 . . . . -0.4(8) ?
    C7 C8 C13 C12 . . . . -179.1(5) ?
    C11 C12 C13 C8 . . . . 1.2(9) ?
    C14 C12 C13 C8 . . . . -179.6(5) ?
    C19 N5 C15 C16 . . . . -0.8(9) ?
    Ag1 N5 C15 C16 . . . . -175.2(4) ?
    N5 C15 C16 C17 . . . . -0.5(9) ?
    C15 C16 C17 C18 . . . . 0.3(8) ?
    C15 C16 C17 C20 . . . . 179.1(5) ?
    C16 C17 C18 C19 . . . . 1.3(10) ?
    C20 C17 C18 C19 . . . . -177.5(6) ?
    C15 N5 C19 C18 . . . . 2.4(11) ?
    Ag1 N5 C19 C18 . . . . 176.9(6) ?
    C17 C18 C19 N5 . . . . -2.7(12) ?
    N7 N6 C20 O2 . . . . 3.5(8) ?
    N7 N6 C20 C17 . . . . -177.5(4) ?
    C18 C17 C20 O2 . . . . 174.2(6) ?
    C16 C17 C20 O2 . . . . -4.5(8) ?
    C18 C17 C20 N6 . . . . -4.8(8) ?
    C16 C17 C20 N6 . . . . 176.4(5) ?
    N6 N7 C21 C22 . . . . -178.9(5) ?
    N7 C21 C22 C27 . . . . -174.4(5) ?
    N7 C21 C22 C23 . . . . 4.1(8) ?
    C27 C22 C23 C24 . . . . 0.8(9) ?
    C21 C22 C23 C24 . . . . -177.6(5) ?
    C22 C23 C24 C25 . . . . 0.8(9) ?
    C23 C24 C25 C26 . . . . -2.4(10) ?
    C24 C25 C26 C27 . . . . 2.5(9) ?
    C24 C25 C26 C28 . . . . -179.8(6) ?
    C23 C22 C27 C26 . . . . -0.8(8) ?
    C21 C22 C27 C26 . . . . 177.7(5) ?
    C25 C26 C27 C22 . . . . -0.9(8) ?
    C28 C26 C27 C22 . . . . -178.6(5) ?
    O5 S3 C29 F2 . . . . 66.4(6) ?
    O3 S3 C29 F2 . . . . -53.2(6) ?
    O4 S3 C29 F2 . . . . -174.8(5) ?
    O5 S3 C29 F3 . . . . -58.8(7) ?
    O3 S3 C29 F3 . . . . -178.3(5) ?
    O4 S3 C29 F3 . . . . 60.0(7) ?
    O5 S3 C29 F1 . . . . -176.3(5) ?
    O3 S3 C29 F1 . . . . 64.1(6) ?
    O4 S3 C29 F1 . . . . -57.6(6) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N2 H29 O5 1_554 0.86(6) 2.27(6) 3.125(9) 173(5) yes
    N6 H28 O3 1_655 0.90(5) 2.12(6) 2.982(7) 161(5) yes
data_global
_journal_date_recd_electronic     2009-08-24
_journal_date_accepted     2009-09-29
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2009
_journal_volume     65
_journal_issue     11
_journal_page_first     m1285
_journal_page_last     m1285
_journal_paper_category     QM
_journal_coeditor_code     BH2248
_publ_contact_author_name     'Cao-Yuan Niu'
_publ_contact_author_address
;College of Sciences
Henan Agricultural University
Zhengzhou 450002
P. R. China
;
_publ_contact_author_email     niu_cy2000@yahoo.com.cn
_publ_contact_author_fax     '86 371 63554576'
_publ_contact_author_phone     '86 371 63978906'
_publ_section_title
;
Bis[N'-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I)
trifluoromethanesulfonate
;
loop_
    _publ_author_name
    _publ_author_address
    "Niu, Cao-Yuan"
;
College of Sciences
Henan Agricultural University
Zhengzhou 450002
People's Republic of China
;
    "Zhang, Hai-Yan"
;
College of Sciences
Henan Agricultural University
Zhengzhou 450002
People's Republic of China
;
    "Wan, Xin-Sheng"
;
College of Sciences
Henan Agricultural University
Zhengzhou 450002
People's Republic of China
;
_publ_section_synopsis     .
