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###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
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data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Poly[μ₃-aqua-μ₂-2,4-dinitrophenolato-rubidium(I)]
;
_chemical_name_common     ?
_chemical_formula_moiety     'C6 H5 N2 O6 Rb'
_chemical_formula_sum     'C6 H5 N2 O6 Rb'
_chemical_formula_iupac     '[Rb (C6 H3 N2 O5) (H2 O)]'
_chemical_formula_weight     286.59
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/c'
_symmetry_space_group_name_Hall     '-P 2ybc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     5.8519(18)
_cell_length_b     20.846(7)
_cell_length_c     7.412(2)
_cell_angle_alpha     90.00
_cell_angle_beta     93.148(5)
_cell_angle_gamma     90.00
_cell_volume     902.8(5)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     1599
_cell_measurement_theta_min     1.95
_cell_measurement_theta_max     25.10
_cell_measurement_temperature     293(2)
_exptl_crystal_description     block
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.40
_exptl_crystal_size_mid     0.35
_exptl_crystal_size_min     0.30
_exptl_crystal_density_diffrn     2.109
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     560
_exptl_absorpt_coefficient_mu     5.497
_exptl_absorpt_correction_type     'multi-scan'
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min     0.125
_exptl_absorpt_correction_T_max     0.202
_exptl_special_details
;
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     4449
_diffrn_reflns_av_R_equivalents     0.0631
_diffrn_reflns_av_sigmaI/netI     0.0635
_diffrn_reflns_theta_min     1.95
_diffrn_reflns_theta_max     25.10
_diffrn_reflns_theta_full     25.10
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -6
_diffrn_reflns_limit_h_max     6
_diffrn_reflns_limit_k_min     -20
_diffrn_reflns_limit_k_max     24
_diffrn_reflns_limit_l_min     -7
_diffrn_reflns_limit_l_max     8
_diffrn_standards_number     0
_diffrn_standards_interval_count     .
_diffrn_standards_interval_time     .
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     1599
_reflns_number_gt     1214
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0543
_refine_ls_R_factor_gt     0.0368
_refine_ls_wR_factor_gt     0.0948
_refine_ls_wR_factor_ref     0.1009
_refine_ls_goodness_of_fit_ref     1.001
_refine_ls_restrained_S_all     1.000
_refine_ls_number_reflns     1599
_refine_ls_number_parameters     143
_refine_ls_number_restraints     3
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
           'calc w=1/[σ²(Fo²)+(0.0556P)²+0.12P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.002
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.496
_refine_diff_density_min     -0.707
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 1997a)'
_refine_ls_extinction_coef     0.0120(18)
_refine_ls_extinction_expression
                                  'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Rb' 'Rb' -0.9393 2.9676
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2006)'
_computing_cell_refinement     'APEX2 (Bruker, 2006)'
_computing_data_reduction     'SAINT (Bruker, 2005)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997a)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997a)'
_computing_molecular_graphics
           'SHELXTL (Sheldrick, 1997b) and DIAMOND (Brandenburg & Brendt, 2001)'
_computing_publication_material     'SHELXTL (Sheldrick, 1997b)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Rb Rb1 0.18947(8) 1.00955(2) 0.24241(6) 0.0381(2) Uani d . 1 . .
    O O1 -0.0671(5) 0.91314(15) 0.4428(4) 0.0404(8) Uani d . 1 . .
    O O2 0.3775(6) 0.93503(16) 0.5483(5) 0.0580(11) Uani d . 1 . .
    O O3 0.5150(5) 0.86504(16) 0.7365(4) 0.0456(9) Uani d . 1 . .
    O O4 0.3512(6) 0.64498(16) 0.6287(5) 0.0537(10) Uani d . 1 . .
    O O5 0.0559(6) 0.61696(16) 0.4603(5) 0.0562(10) Uani d . 1 . .
    O O6 0.3268(7) 1.03788(18) -0.1415(5) 0.0526(9) Uani d D 1 . .
    H H6A 0.382(10) 1.0686(17) -0.086(6) 0.079 Uiso d D 1 . .
    H H6B 0.281(10) 1.053(2) -0.239(4) 0.079 Uiso d D 1 . .
    N N1 0.3753(6) 0.88137(18) 0.6150(5) 0.0331(9) Uani d . 1 . .
    N N2 0.1790(7) 0.65827(18) 0.5345(5) 0.0373(9) Uani d . 1 . .
    C C1 -0.0063(7) 0.8557(2) 0.4619(5) 0.0290(10) Uani d . 1 . .
    C C2 0.2080(7) 0.8349(2) 0.5482(5) 0.0261(10) Uani d . 1 . .
    C C3 0.2641(7) 0.7709(2) 0.5735(5) 0.0269(10) Uani d . 1 . .
    H H3 0.4019 0.7594 0.6333 0.032 Uiso calc R 1 . .
    C C4 0.1145(7) 0.7246(2) 0.5096(5) 0.0289(10) Uani d . 1 . .
    C C5 -0.0968(7) 0.7407(2) 0.4243(6) 0.0346(11) Uani d . 1 . .
    H H5 -0.1973 0.7088 0.3830 0.042 Uiso calc R 1 . .
    C C6 -0.1537(7) 0.8033(2) 0.4023(6) 0.0357(11) Uani d . 1 . .
    H H6 -0.2952 0.8131 0.3458 0.043 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Rb1 O2 . 2.914(3) ?
    Rb1 O1 3_576 2.956(3) ?
    Rb1 O1 . 2.957(3) ?
    Rb1 O5 2 3.016(3) ?
    Rb1 O6 . 3.057(4) ?
    Rb1 O2 3_676 3.119(3) ?
    Rb1 O6 3_675 3.127(4) ?
    Rb1 O3 3_676 3.134(3) ?
    Rb1 O6 3_575 3.228(4) ?
    Rb1 O5 4_575 3.429(4) ?
    Rb1 O4 4_575 3.474(4) ?
    Rb1 N1 3_676 3.533(4) ?
    Rb1 H6A . 3.00(5) ?
    O1 C1 . 1.255(5) ?
    O1 Rb1 3_576 2.956(3) ?
    O2 N1 . 1.223(5) ?
    O2 Rb1 3_676 3.119(3) ?
    O3 N1 . 1.231(4) ?
    O3 Rb1 3_676 3.134(3) ?
    O4 N2 . 1.226(5) ?
    O4 Rb1 4_576 3.474(4) ?
    O5 N2 . 1.232(5) ?
    O5 Rb1 2_545 3.016(3) ?
    O5 Rb1 4_576 3.429(4) ?
    O6 Rb1 3_675 3.127(4) ?
    O6 Rb1 3_575 3.228(4) ?
    O6 H6A . 0.818(10) ?
    O6 H6B . 0.820(10) ?
    N1 C2 . 1.446(5) ?
    N1 Rb1 3_676 3.533(4) ?
    N2 C4 . 1.443(5) ?
    C1 C2 . 1.443(5) ?
    C1 C6 . 1.446(6) ?
    C2 C3 . 1.384(6) ?
    C3 C4 . 1.369(6) ?
    C3 H3 . 0.9300 ?
    C4 C5 . 1.398(6) ?
    C5 C6 . 1.353(6) ?
    C5 H5 . 0.9300 ?
    C6 H6 . 0.9300 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O2 Rb1 O1 . 3_576 76.94(10) ?
    O2 Rb1 O1 . . 55.06(9) ?
    O1 Rb1 O1 3_576 . 79.77(10) ?
    O2 Rb1 O5 . 2 158.84(11) ?
    O1 Rb1 O5 3_576 2 81.90(10) ?
    O1 Rb1 O5 . 2 120.93(10) ?
    O2 Rb1 O6 . . 136.06(12) ?
    O1 Rb1 O6 3_576 . 135.80(9) ?
    O1 Rb1 O6 . . 139.96(10) ?
    O5 Rb1 O6 2 . 62.29(11) ?
    O2 Rb1 O2 . 3_676 63.18(11) ?
    O1 Rb1 O2 3_576 3_676 68.35(10) ?
    O1 Rb1 O2 . 3_676 115.03(9) ?
    O5 Rb1 O2 2 3_676 108.92(10) ?
    O6 Rb1 O2 . 3_676 98.24(10) ?
    O2 Rb1 O6 . 3_675 73.11(11) ?
    O1 Rb1 O6 3_576 3_675 128.52(9) ?
    O1 Rb1 O6 . 3_675 113.35(9) ?
    O5 Rb1 O6 2 3_675 121.87(11) ?
    O6 Rb1 O6 . 3_675 63.31(11) ?
    O2 Rb1 O6 3_676 3_675 60.97(10) ?
    O2 Rb1 O3 . 3_676 102.84(9) ?
    O1 Rb1 O3 3_576 3_676 70.30(9) ?
    O1 Rb1 O3 . 3_676 146.73(9) ?
    O5 Rb1 O3 2 3_676 69.62(9) ?
    O6 Rb1 O3 . 3_676 73.29(9) ?
    O2 Rb1 O3 3_676 3_676 40.11(8) ?
    O6 Rb1 O3 3_675 3_676 76.78(9) ?
    O2 Rb1 O6 . 3_575 109.00(9) ?
    O1 Rb1 O6 3_576 3_575 94.91(10) ?
    O1 Rb1 O6 . 3_575 54.09(9) ?
    O5 Rb1 O6 2 3_575 72.43(10) ?
    O6 Rb1 O6 . 3_575 97.71(9) ?
    O2 Rb1 O6 3_676 3_575 162.41(11) ?
    O6 Rb1 O6 3_675 3_575 134.09(13) ?
    O3 Rb1 O6 3_676 3_575 140.73(9) ?
    O2 Rb1 O5 . 4_575 97.36(9) ?
    O1 Rb1 O5 3_576 4_575 147.52(9) ?
    O1 Rb1 O5 . 4_575 71.24(9) ?
    O5 Rb1 O5 2 4_575 100.42(8) ?
    O6 Rb1 O5 . 4_575 69.13(9) ?
    O2 Rb1 O5 3_676 4_575 137.72(10) ?
    O6 Rb1 O5 3_675 4_575 77.88(10) ?
    O3 Rb1 O5 3_676 4_575 141.14(9) ?
    O6 Rb1 O5 3_575 4_575 56.22(10) ?
    O2 Rb1 O4 . 4_575 66.31(9) ?
    O1 Rb1 O4 3_576 4_575 141.08(9) ?
    O1 Rb1 O4 . 4_575 69.16(9) ?
    O5 Rb1 O4 2 4_575 134.11(9) ?
    O6 Rb1 O4 . 4_575 82.20(10) ?
    O2 Rb1 O4 3_676 4_575 103.85(9) ?
    O6 Rb1 O4 3_675 4_575 52.17(9) ?
    O3 Rb1 O4 3_676 4_575 128.95(9) ?
    O6 Rb1 O4 3_575 4_575 85.63(9) ?
    O5 Rb1 O4 4_575 4_575 36.39(8) ?
    O2 Rb1 N1 . 3_676 82.82(9) ?
    O1 Rb1 N1 3_576 3_676 67.35(9) ?
    O1 Rb1 N1 . 3_676 131.67(9) ?
    O5 Rb1 N1 2 3_676 89.25(10) ?
    O6 Rb1 N1 . 3_676 86.10(9) ?
    O2 Rb1 N1 3_676 3_676 19.97(8) ?
    O6 Rb1 N1 3_675 3_676 68.15(9) ?
    O3 Rb1 N1 3_676 3_676 20.16(8) ?
    O6 Rb1 N1 3_575 3_676 156.48(9) ?
    O5 Rb1 N1 4_575 3_676 144.49(9) ?
    O4 Rb1 N1 4_575 3_676 117.89(9) ?
    O2 Rb1 H6A . . 135.0(11) ?
    O1 Rb1 H6A 3_576 . 122.3(6) ?
    O1 Rb1 H6A . . 155.4(2) ?
    O5 Rb1 H6A 2 . 58.7(11) ?
    O6 Rb1 H6A . . 15.5(2) ?
    O2 Rb1 H6A 3_676 . 85.5(6) ?
    O6 Rb1 H6A 3_675 . 63.4(11) ?
    O3 Rb1 H6A 3_676 . 57.8(2) ?
    O6 Rb1 H6A 3_575 . 109.0(8) ?
    O5 Rb1 H6A 4_575 . 84.5(3) ?
    O4 Rb1 H6A 4_575 . 93.7(8) ?
    N1 Rb1 H6A 3_676 . 71.5(4) ?
    C1 O1 Rb1 . 3_576 120.7(3) ?
    C1 O1 Rb1 . . 123.8(3) ?
    Rb1 O1 Rb1 3_576 . 100.23(10) ?
    N1 O2 Rb1 . . 142.2(3) ?
    N1 O2 Rb1 . 3_676 99.5(2) ?
    Rb1 O2 Rb1 . 3_676 116.82(11) ?
    N1 O3 Rb1 . 3_676 98.5(2) ?
    N2 O4 Rb1 . 4_576 97.0(3) ?
    N2 O5 Rb1 . 2_545 172.5(3) ?
    N2 O5 Rb1 . 4_576 99.1(3) ?
    Rb1 O5 Rb1 2_545 4_576 79.58(8) ?
    Rb1 O6 Rb1 . 3_675 116.69(11) ?
    Rb1 O6 Rb1 . 3_575 82.29(9) ?
    Rb1 O6 Rb1 3_675 3_575 134.09(13) ?
    Rb1 O6 H6A . . 78(4) ?
    Rb1 O6 H6A 3_675 . 92(4) ?
    Rb1 O6 H6A 3_575 . 134(4) ?
    Rb1 O6 H6B . . 144(4) ?
    Rb1 O6 H6B 3_675 . 100(4) ?
    Rb1 O6 H6B 3_575 . 70(4) ?
    H6A O6 H6B . . 104.1(17) ?
    O2 N1 O3 . . 121.8(4) ?
    O2 N1 C2 . . 119.8(3) ?
    O3 N1 C2 . . 118.4(4) ?
    O2 N1 Rb1 . 3_676 60.6(2) ?
    O3 N1 Rb1 . 3_676 61.3(2) ?
    C2 N1 Rb1 . 3_676 176.1(3) ?
    O4 N2 O5 . . 122.6(4) ?
    O4 N2 C4 . . 119.4(4) ?
    O5 N2 C4 . . 118.1(4) ?
    O1 C1 C2 . . 124.8(4) ?
    O1 C1 C6 . . 121.7(4) ?
    C2 C1 C6 . . 113.4(4) ?
    C3 C2 C1 . . 123.0(4) ?
    C3 C2 N1 . . 116.7(3) ?
    C1 C2 N1 . . 120.4(4) ?
    C4 C3 C2 . . 119.3(4) ?
    C4 C3 H3 . . 120.3 ?
    C2 C3 H3 . . 120.3 ?
    C3 C4 C5 . . 121.3(4) ?
    C3 C4 N2 . . 118.2(4) ?
    C5 C4 N2 . . 120.5(4) ?
    C6 C5 C4 . . 119.5(4) ?
    C6 C5 H5 . . 120.3 ?
    C4 C5 H5 . . 120.3 ?
    C5 C6 C1 . . 123.5(4) ?
    C5 C6 H6 . . 118.2 ?
    C1 C6 H6 . . 118.2 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O2 Rb1 O1 C1 . . . . -57.1(3) ?
    O1 Rb1 O1 C1 3_576 . . . -138.2(4) ?
    O5 Rb1 O1 C1 2 . . . 147.8(3) ?
    O6 Rb1 O1 C1 . . . . 65.2(4) ?
    O2 Rb1 O1 C1 3_676 . . . -78.1(3) ?
    O6 Rb1 O1 C1 3_675 . . . -10.5(3) ?
    O3 Rb1 O1 C1 3_676 . . . -112.3(3) ?
    O6 Rb1 O1 C1 3_575 . . . 118.0(4) ?
    O5 Rb1 O1 C1 4_575 . . . 56.7(3) ?
    O4 Rb1 O1 C1 4_575 . . . 18.0(3) ?
    N1 Rb1 O1 C1 3_676 . . . -91.4(3) ?
    O2 Rb1 O1 Rb1 . . . 3_576 81.14(12) ?
    O1 Rb1 O1 Rb1 3_576 . . 3_576 0.0 ?
    O5 Rb1 O1 Rb1 2 . . 3_576 -74.03(13) ?
    O6 Rb1 O1 Rb1 . . . 3_576 -156.60(12) ?
    O2 Rb1 O1 Rb1 3_676 . . 3_576 60.13(12) ?
    O6 Rb1 O1 Rb1 3_675 . . 3_576 127.69(9) ?
    O3 Rb1 O1 Rb1 3_676 . . 3_576 25.93(19) ?
    O6 Rb1 O1 Rb1 3_575 . . 3_576 -103.77(13) ?
    O5 Rb1 O1 Rb1 4_575 . . 3_576 -165.14(11) ?
    O4 Rb1 O1 Rb1 4_575 . . 3_576 156.16(11) ?
    N1 Rb1 O1 Rb1 3_676 . . 3_576 46.81(14) ?
    O1 Rb1 O2 N1 3_576 . . . 125.8(5) ?
    O1 Rb1 O2 N1 . . . . 39.3(5) ?
    O5 Rb1 O2 N1 2 . . . 125.4(5) ?
    O6 Rb1 O2 N1 . . . . -89.1(5) ?
    O2 Rb1 O2 N1 3_676 . . . -162.0(6) ?
    O6 Rb1 O2 N1 3_675 . . . -96.5(5) ?
    O3 Rb1 O2 N1 3_676 . . . -168.2(5) ?
    O6 Rb1 O2 N1 3_575 . . . 35.1(5) ?
    O5 Rb1 O2 N1 4_575 . . . -21.6(5) ?
    O4 Rb1 O2 N1 4_575 . . . -41.1(5) ?
    N1 Rb1 O2 N1 3_676 . . . -165.8(5) ?
    O1 Rb1 O2 Rb1 3_576 . . 3_676 -72.12(14) ?
    O1 Rb1 O2 Rb1 . . . 3_676 -158.66(19) ?
    O5 Rb1 O2 Rb1 2 . . 3_676 -72.6(3) ?
    O6 Rb1 O2 Rb1 . . . 3_676 72.95(19) ?
    O2 Rb1 O2 Rb1 3_676 . . 3_676 0.0 ?
    O6 Rb1 O2 Rb1 3_675 . . 3_676 65.50(14) ?
    O3 Rb1 O2 Rb1 3_676 . . 3_676 -6.18(17) ?
    O6 Rb1 O2 Rb1 3_575 . . 3_676 -162.86(13) ?
    O5 Rb1 O2 Rb1 4_575 . . 3_676 140.40(14) ?
    O4 Rb1 O2 Rb1 4_575 . . 3_676 120.98(17) ?
    N1 Rb1 O2 Rb1 3_676 . . 3_676 -3.78(13) ?
    O2 Rb1 O6 Rb1 . . . 3_675 -8.0(2) ?
    O1 Rb1 O6 Rb1 3_576 . . 3_675 118.88(14) ?
    O1 Rb1 O6 Rb1 . . . 3_675 -95.23(16) ?
    O5 Rb1 O6 Rb1 2 . . 3_675 158.67(17) ?
    O2 Rb1 O6 Rb1 3_676 . . 3_675 51.57(14) ?
    O6 Rb1 O6 Rb1 3_675 . . 3_675 0.0 ?
    O3 Rb1 O6 Rb1 3_676 . . 3_675 83.33(12) ?
    O6 Rb1 O6 Rb1 3_575 . . 3_675 -135.87(16) ?
    O5 Rb1 O6 Rb1 4_575 . . 3_675 -86.57(13) ?
    O4 Rb1 O6 Rb1 4_575 . . 3_675 -51.39(12) ?
    N1 Rb1 O6 Rb1 3_676 . . 3_675 67.47(12) ?
    O2 Rb1 O6 Rb1 . . . 3_575 127.89(11) ?
    O1 Rb1 O6 Rb1 3_576 . . 3_575 -105.25(12) ?
    O1 Rb1 O6 Rb1 . . . 3_575 40.64(17) ?
    O5 Rb1 O6 Rb1 2 . . 3_575 -65.46(10) ?
    O2 Rb1 O6 Rb1 3_676 . . 3_575 -172.56(9) ?
    O6 Rb1 O6 Rb1 3_675 . . 3_575 135.87(16) ?
    O3 Rb1 O6 Rb1 3_676 . . 3_575 -140.81(10) ?
    O6 Rb1 O6 Rb1 3_575 . . 3_575 0.0 ?
    O5 Rb1 O6 Rb1 4_575 . . 3_575 49.30(8) ?
    O4 Rb1 O6 Rb1 4_575 . . 3_575 84.48(8) ?
    N1 Rb1 O6 Rb1 3_676 . . 3_575 -156.66(9) ?
    Rb1 O2 N1 O3 . . . . 167.0(4) ?
    Rb1 O2 N1 O3 3_676 . . . 3.2(5) ?
    Rb1 O2 N1 C2 . . . . -11.7(7) ?
    Rb1 O2 N1 C2 3_676 . . . -175.5(3) ?
    Rb1 O2 N1 Rb1 . . . 3_676 163.8(6) ?
    Rb1 O3 N1 O2 3_676 . . . -3.2(5) ?
    Rb1 O3 N1 C2 3_676 . . . 175.5(3) ?
    Rb1 O4 N2 O5 4_576 . . . -23.8(5) ?
    Rb1 O4 N2 C4 4_576 . . . 155.5(3) ?
    Rb1 O5 N2 O4 4_576 . . . 24.3(5) ?
    Rb1 O5 N2 C4 4_576 . . . -155.1(3) ?
    Rb1 O1 C1 C2 3_576 . . . -70.6(5) ?
    Rb1 O1 C1 C2 . . . . 59.7(5) ?
    Rb1 O1 C1 C6 3_576 . . . 107.4(4) ?
    Rb1 O1 C1 C6 . . . . -122.3(4) ?
    O1 C1 C2 C3 . . . . 177.1(4) ?
    C6 C1 C2 C3 . . . . -1.0(6) ?
    O1 C1 C2 N1 . . . . -2.2(7) ?
    C6 C1 C2 N1 . . . . 179.7(4) ?
    O2 N1 C2 C3 . . . . 155.4(4) ?
    O3 N1 C2 C3 . . . . -23.3(6) ?
    O2 N1 C2 C1 . . . . -25.2(6) ?
    O3 N1 C2 C1 . . . . 156.0(4) ?
    C1 C2 C3 C4 . . . . 2.1(7) ?
    N1 C2 C3 C4 . . . . -178.6(4) ?
    C2 C3 C4 C5 . . . . -2.0(6) ?
    C2 C3 C4 N2 . . . . 178.8(4) ?
    O4 N2 C4 C3 . . . . 8.2(6) ?
    O5 N2 C4 C3 . . . . -172.4(4) ?
    O4 N2 C4 C5 . . . . -171.0(4) ?
    O5 N2 C4 C5 . . . . 8.3(7) ?
    C3 C4 C5 C6 . . . . 0.8(7) ?
    N2 C4 C5 C6 . . . . -180.0(4) ?
    C4 C5 C6 C1 . . . . 0.3(7) ?
    O1 C1 C6 C5 . . . . -178.4(4) ?
    C2 C1 C6 C5 . . . . -0.2(6) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    O6 H6B O1 3_575 0.820(10) 2.03(2) 2.822(5) 161(6)
    O6 H6A O4 2_655 0.818(10) 2.27(4) 2.919(5) 137(5)
data_global
_journal_date_recd_electronic     2007-11-16
_journal_date_accepted     2007-12-13
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2008
_journal_volume     64
_journal_issue      1
_journal_page_first     m225
_journal_page_last     m225
_journal_paper_category     QM
_journal_coeditor_code     PK2074
_publ_contact_author_name     'Mancheng Hu'
_publ_contact_author_address
;
       School of Chemistry and Materials Science
       ShaanXi Normal University
       Xi'an 710062
       People's Republic of China
;
_publ_contact_author_email     hmch@snnu.edu.cn
_publ_contact_author_fax      862985307774
_publ_contact_author_phone      862985307765
_publ_section_title
;
Poly[μ₃-aqua-μ₂-2,4-dinitrophenolato-rubidium(I)]
;
loop_
    _publ_author_name
    _publ_author_address
    'Zhangqin Yang'
;
School of Chemistry and Materials Science
ShaanXi Normal University
Xi'an 710062
People's Republic of China
;
    'Mancheng Hu'
;
School of Chemistry and Materials Science
ShaanXi Normal University
Xi'an 710062
People's Republic of China
;
    'Xiuhang Wang'
;
School of Chemistry and Materials Science
ShaanXi Normal University
Xi'an 710062
People's Republic of China
;
