##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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##############################################################################
                                             
data_global
_audit_creation_method     'SHELXL97'
_journal_date_recd_electronic     2007-10-02
_journal_date_accepted     2007-10-05
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue     11
_journal_page_first     m2700
_journal_page_last     m2700
_journal_paper_category     QM
_journal_coeditor_code     BT2528
_publ_contact_author_name     'Dr. Jin Yang'
_publ_contact_author_address
;
Department of Chemistry,
Northeast Normal University,
Changchun 130024,
People's Republic of China
;
_publ_contact_author_email     yangjinnenu@yahoo.com.cn
_publ_contact_author_fax     '?'
_publ_contact_author_phone     '?'
_publ_section_title
;\
catena-Poly[[(2-amino-5-chlorobenzenesulfonato-κ²N,O)\
silver(I)]-μ-2,5-dimethylpyrazine-κ²N:N']
;
loop_
    _publ_author_name
    _publ_author_address
    'Hai-Yan Liu'
;
Department of Chemistry,
Northeast Normal University,
Changchun 130024,
People's Republic of China
;
    'Ji-Cheng Ma'
;
Department of Chemistry,
Northeast Normal University,
Changchun 130024,
People's Republic of China
;
    'Jin Yang'
;
Department of Chemistry,
Northeast Normal University,
Changchun 130024,
People's Republic of China
;
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
catena-Poly[[(2-amino-5-chlorobenzenesulfonato-κ²N,O)silver(I)]-μ-
2,5-dimethylpyrazine-κ²N:N']
;
_chemical_name_common     ?
_chemical_formula_moiety     'C12 H13 Ag Cl N3 O3 S'
_chemical_formula_sum     'C12 H13 Ag Cl N3 O3 S'
_chemical_formula_iupac     '[Ag (C6 H5 Cl N O3 S) (C6 H8 N2)]'
_chemical_formula_weight     422.63
_chemical_melting_point     ?
_symmetry_cell_setting     orthorhombic
_symmetry_space_group_name_H-M     'P n a 21'
_symmetry_space_group_name_hall     'P 2c -2n'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, z+1/2'
    '-x+1/2, y+1/2, z+1/2'
    'x+1/2, -y+1/2, z'
_cell_length_a     14.671(3)
_cell_length_b     11.947(2)
_cell_length_c     8.2025(16)
_cell_angle_alpha     90.00
_cell_angle_beta     90.00
_cell_angle_gamma     90.00
_cell_volume     1437.7(5)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     10124
_cell_measurement_theta_min     3.0
_cell_measurement_theta_max     27.5
_cell_measurement_temperature     293(2)
_exptl_crystal_description     platelet
_exptl_crystal_colour     colorless
_exptl_crystal_size_max     0.319
_exptl_crystal_size_mid     0.225
_exptl_crystal_size_min     0.056
_exptl_crystal_density_diffrn     1.953
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     840
_exptl_absorpt_coefficient_mu     1.745
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(ABSCOR; Higashi, 1995)'
_exptl_absorpt_correction_T_min     0.653
_exptl_absorpt_correction_T_max     0.906
_exptl_special_details
;
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Rigaku R-AXIS RAPID'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     10.0
_diffrn_reflns_number     11475
_diffrn_reflns_av_R_equivalents     0.0342
_diffrn_reflns_av_sigmaI/netI     0.0309
_diffrn_reflns_theta_min     3.01
_diffrn_reflns_theta_max     27.48
_diffrn_reflns_theta_full     27.48
_diffrn_measured_fraction_theta_max     0.995
_diffrn_measured_fraction_theta_full     0.995
_diffrn_reflns_limit_h_min     -18
_diffrn_reflns_limit_h_max     19
_diffrn_reflns_limit_k_min     -15
_diffrn_reflns_limit_k_max     15
_diffrn_reflns_limit_l_min     -10
_diffrn_reflns_limit_l_max     8
_diffrn_standards_number     ?
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     2935
_reflns_number_gt     2638
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0304
_refine_ls_R_factor_gt     0.0254
_refine_ls_wR_factor_gt     0.0509
_refine_ls_wR_factor_ref     0.0527
_refine_ls_goodness_of_fit_ref     1.053
_refine_ls_restrained_S_all     1.053
_refine_ls_number_reflns     2935
_refine_ls_number_parameters     200
_refine_ls_number_restraints     4
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0213P)²+0.3336P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.367
_refine_diff_density_min     -0.334
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
_refine_ls_abs_structure_details     'Flack (1983), 1172 Friedel pairs'
_refine_ls_abs_structure_Flack     -0.03(3)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ag' 'Ag' -0.8971 1.1015
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'PROCESS-AUTO (Rigaku, 1998)'
_computing_cell_refinement     'PROCESS-AUTO (Rigaku, 1998)'
_computing_data_reduction     'PROCESS-AUTO (Rigaku, 1998)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'SHELXTL-Plus (Sheldrick, 1990)'
_computing_publication_material     'SHELXL97 (Sheldrick, 1997)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag1 0.243272(14) 0.646505(19) 0.76476(5) 0.03722(8) Uani d . 1 . .
    S S1 0.07812(5) 0.76842(6) 1.01266(12) 0.03172(17) Uani d . 1 . .
    Cl Cl1 0.08916(7) 0.48754(8) 1.52741(16) 0.0547(3) Uani d . 1 . .
    O O3 0.08442(16) 0.7030(2) 0.8637(3) 0.0456(6) Uani d . 1 . .
    O O1 -0.01398(14) 0.77287(18) 1.0795(3) 0.0389(6) Uani d . 1 . .
    N N2 0.24774(17) 0.7932(2) 0.5917(4) 0.0280(6) Uani d . 1 . .
    C C10 0.3268(2) 0.8382(3) 0.5426(4) 0.0305(7) Uani d . 1 . .
    N N1 0.28661(17) 0.7479(2) 1.0269(4) 0.0348(6) Uani d D 1 . .
    O O2 0.12086(18) 0.87723(19) 1.0001(4) 0.0523(8) Uani d . 1 . .
    C C1 0.14351(19) 0.6928(2) 1.1575(4) 0.0261(6) Uani d . 1 . .
    C C6 0.23964(19) 0.6899(3) 1.1469(4) 0.0291(7) Uani d . 1 . .
    C C7 0.1702(2) 0.8401(3) 0.5413(4) 0.0312(7) Uani d . 1 . .
    H H7 0.1152 0.8104 0.5772 0.037 Uiso calc R 1 . .
    C C2 0.09859(17) 0.6303(2) 1.2728(6) 0.0287(6) Uani d . 1 . .
    H H2 0.0353 0.6322 1.2789 0.034 Uiso calc R 1 . .
    C C3 0.1481(2) 0.5643(3) 1.3803(4) 0.0316(7) Uani d . 1 . .
    C C4 0.2415(2) 0.5588(3) 1.3718(5) 0.0355(8) Uani d . 1 . .
    H H4 0.2737 0.5136 1.4439 0.043 Uiso calc R 1 . .
    C C5 0.28739(18) 0.6210(2) 1.2549(7) 0.0340(7) Uani d . 1 . .
    H H5 0.3506 0.6169 1.2485 0.041 Uiso calc R 1 . .
    C C11 0.4135(2) 0.7864(3) 0.5991(6) 0.0501(10) Uani d . 1 . .
    H H11A 0.4174 0.7917 0.7157 0.075 Uiso calc R 1 . .
    H H11B 0.4641 0.8250 0.5508 0.075 Uiso calc R 1 . .
    H H11C 0.4148 0.7091 0.5673 0.075 Uiso calc R 1 . .
    C C8 0.1686(2) 0.9322(3) 0.4367(4) 0.0280(7) Uani d . 1 . .
    N N3 0.24766(18) 0.9781(2) 0.3873(4) 0.0288(6) Uani d . 1 . .
    C C12 0.0810(2) 0.9820(3) 0.3801(6) 0.0438(9) Uani d . 1 . .
    H H12A 0.0731 1.0544 0.4291 0.066 Uiso calc R 1 . .
    H H12B 0.0314 0.9342 0.4113 0.066 Uiso calc R 1 . .
    H H12C 0.0821 0.9896 0.2636 0.066 Uiso calc R 1 . .
    C C9 0.3255(2) 0.9311(3) 0.4415(4) 0.0335(8) Uani d . 1 . .
    H H9 0.3807 0.9624 0.4097 0.040 Uiso calc R 1 . .
    H HN1 0.3438(7) 0.752(2) 1.029(4) 0.027(8) Uiso d D 1 . .
    H HN2 0.272(2) 0.8154(13) 1.015(8) 0.070(16) Uiso d D 1 . .
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_22
    _atom_site_aniso_U_33
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_23
    Ag1 0.04065(13) 0.03172(11) 0.03929(14) 0.00103(10) 0.0046(2) 0.01531(14)
    S1 0.0169(3) 0.0350(4) 0.0432(5) 0.0006(3) 0.0003(4) 0.0113(4)
    Cl1 0.0565(6) 0.0521(5) 0.0554(6) 0.0058(4) 0.0073(5) 0.0249(5)
    O3 0.0299(13) 0.0725(19) 0.0345(14) 0.0059(12) -0.0044(11) 0.0053(13)
    O1 0.0198(10) 0.0398(13) 0.0572(18) 0.0037(9) 0.0060(10) 0.0130(11)
    N2 0.0311(13) 0.0232(13) 0.0299(15) -0.0038(11) 0.0025(12) 0.0020(11)
    C10 0.0270(15) 0.0314(17) 0.0332(19) -0.0036(12) -0.0011(14) 0.0031(13)
    N1 0.0170(12) 0.0399(17) 0.0477(19) -0.0027(11) 0.0030(14) -0.0003(15)
    O2 0.0325(13) 0.0378(15) 0.087(2) -0.0034(10) 0.0017(15) 0.0254(15)
    C1 0.0207(14) 0.0237(15) 0.0340(18) 0.0016(12) -0.0033(13) -0.0013(12)
    C6 0.0209(14) 0.0313(16) 0.0353(18) -0.0039(13) 0.0010(14) -0.0038(13)
    C7 0.0286(16) 0.0260(16) 0.039(2) -0.0036(13) 0.0015(15) 0.0016(13)
    C2 0.0229(11) 0.0259(13) 0.0374(17) -0.0007(10) 0.000(2) -0.0027(15)
    C3 0.0365(17) 0.0261(16) 0.0322(18) 0.0014(13) -0.0031(15) 0.0021(13)
    C4 0.0373(18) 0.0335(18) 0.0358(19) 0.0115(14) -0.0049(16) -0.0030(15)
    C5 0.0207(12) 0.0389(16) 0.0424(18) 0.0078(11) -0.008(2) -0.007(2)
    C11 0.0356(19) 0.052(2) 0.063(3) 0.0027(16) -0.0062(19) 0.0296(19)
    C8 0.0298(15) 0.0229(16) 0.0314(17) 0.0013(13) -0.0028(13) -0.0026(12)
    N3 0.0326(14) 0.0246(13) 0.0293(15) -0.0002(11) 0.0032(12) 0.0032(11)
    C12 0.0335(18) 0.038(2) 0.060(3) 0.0036(15) -0.0027(18) 0.0071(17)
    C9 0.0277(15) 0.0351(19) 0.038(2) -0.0035(14) 0.0037(15) 0.0085(14)
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 N3 3_545 2.253(3) .
    Ag1 N2 . 2.256(3) .
    Ag1 N1 . 2.549(3) .
    Ag1 O3 . 2.559(2) .
    S1 O2 . 1.447(2) ?
    S1 O3 . 1.453(3) ?
    S1 O1 . 1.459(2) ?
    S1 C1 . 1.774(3) ?
    Cl1 C3 . 1.746(3) ?
    N2 C7 . 1.334(4) ?
    N2 C10 . 1.341(4) ?
    C10 C9 . 1.385(4) ?
    C10 C11 . 1.488(5) ?
    N1 C6 . 1.387(5) ?
    N1 HN1 . 0.841(10) ?
    N1 HN2 . 0.840(10) ?
    C1 C2 . 1.374(5) ?
    C1 C6 . 1.413(4) ?
    C6 C5 . 1.397(6) ?
    C7 C8 . 1.396(4) ?
    C7 H7 . 0.9300 ?
    C2 C3 . 1.388(5) ?
    C2 H2 . 0.9300 ?
    C3 C4 . 1.372(5) ?
    C4 C5 . 1.388(6) ?
    C4 H4 . 0.9300 ?
    C5 H5 . 0.9300 ?
    C11 H11A . 0.9600 ?
    C11 H11B . 0.9600 ?
    C11 H11C . 0.9600 ?
    C8 N3 . 1.345(4) ?
    C8 C12 . 1.491(4) ?
    N3 C9 . 1.347(4) ?
    N3 Ag1 3_554 2.253(3) ?
    C12 H12A . 0.9600 ?
    C12 H12B . 0.9600 ?
    C12 H12C . 0.9600 ?
    C9 H9 . 0.9300 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N3 Ag1 N2 3_545 . 166.54(11) .
    N3 Ag1 N1 3_545 . 91.92(10) .
    N2 Ag1 N1 . . 98.89(10) .
    N3 Ag1 O3 3_545 . 98.52(9) .
    N2 Ag1 O3 . . 91.20(9) .
    N1 Ag1 O3 . . 80.45(8) .
    O2 S1 O3 . . 113.29(18) ?
    O2 S1 O1 . . 113.28(15) ?
    O3 S1 O1 . . 113.24(15) ?
    O2 S1 C1 . . 105.71(16) ?
    O3 S1 C1 . . 104.77(15) ?
    O1 S1 C1 . . 105.53(15) ?
    S1 O3 Ag1 . . 117.81(13) ?
    C7 N2 C10 . . 118.4(3) ?
    C7 N2 Ag1 . . 119.8(2) ?
    C10 N2 Ag1 . . 121.7(2) ?
    N2 C10 C9 . . 119.2(3) ?
    N2 C10 C11 . . 118.6(3) ?
    C9 C10 C11 . . 122.1(3) ?
    C6 N1 Ag1 . . 103.7(2) ?
    C6 N1 HN1 . . 120(2) ?
    Ag1 N1 HN1 . . 107(2) ?
    C6 N1 HN2 . . 116(4) ?
    Ag1 N1 HN2 . . 107(4) ?
    HN1 N1 HN2 . . 102.0(15) ?
    C2 C1 C6 . . 120.5(3) ?
    C2 C1 S1 . . 118.6(2) ?
    C6 C1 S1 . . 120.8(3) ?
    N1 C6 C5 . . 119.7(3) ?
    N1 C6 C1 . . 121.8(3) ?
    C5 C6 C1 . . 118.4(3) ?
    N2 C7 C8 . . 122.4(3) ?
    N2 C7 H7 . . 118.8 ?
    C8 C7 H7 . . 118.8 ?
    C1 C2 C3 . . 119.7(3) ?
    C1 C2 H2 . . 120.2 ?
    C3 C2 H2 . . 120.2 ?
    C4 C3 C2 . . 121.2(3) ?
    C4 C3 Cl1 . . 120.3(3) ?
    C2 C3 Cl1 . . 118.5(3) ?
    C3 C4 C5 . . 119.6(3) ?
    C3 C4 H4 . . 120.2 ?
    C5 C4 H4 . . 120.2 ?
    C4 C5 C6 . . 120.7(3) ?
    C4 C5 H5 . . 119.7 ?
    C6 C5 H5 . . 119.7 ?
    C10 C11 H11A . . 109.5 ?
    C10 C11 H11B . . 109.5 ?
    H11A C11 H11B . . 109.5 ?
    C10 C11 H11C . . 109.5 ?
    H11A C11 H11C . . 109.5 ?
    H11B C11 H11C . . 109.5 ?
    N3 C8 C7 . . 119.5(3) ?
    N3 C8 C12 . . 119.2(3) ?
    C7 C8 C12 . . 121.4(3) ?
    C8 N3 C9 . . 117.5(3) ?
    C8 N3 Ag1 . 3_554 123.3(2) ?
    C9 N3 Ag1 . 3_554 118.0(2) ?
    C8 C12 H12A . . 109.5 ?
    C8 C12 H12B . . 109.5 ?
    H12A C12 H12B . . 109.5 ?
    C8 C12 H12C . . 109.5 ?
    H12A C12 H12C . . 109.5 ?
    H12B C12 H12C . . 109.5 ?
    N3 C9 C10 . . 122.9(3) ?
    N3 C9 H9 . . 118.5 ?
    C10 C9 H9 . . 118.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O2 S1 O3 Ag1 . . . . 63.33(19) ?
    O1 S1 O3 Ag1 . . . . -165.89(13) ?
    C1 S1 O3 Ag1 . . . . -51.40(18) ?
    N3 Ag1 O3 S1 3_545 . . . 92.60(17) ?
    N2 Ag1 O3 S1 . . . . -96.73(17) ?
    N1 Ag1 O3 S1 . . . . 2.08(16) ?
    N3 Ag1 N2 C7 3_545 . . . 113.6(4) ?
    N1 Ag1 N2 C7 . . . . -103.3(2) ?
    O3 Ag1 N2 C7 . . . . -22.8(3) ?
    N3 Ag1 N2 C10 3_545 . . . -69.3(5) ?
    N1 Ag1 N2 C10 . . . . 73.8(3) ?
    O3 Ag1 N2 C10 . . . . 154.3(3) ?
    C7 N2 C10 C9 . . . . -0.2(5) ?
    Ag1 N2 C10 C9 . . . . -177.4(2) ?
    C7 N2 C10 C11 . . . . 179.7(3) ?
    Ag1 N2 C10 C11 . . . . 2.6(4) ?
    N3 Ag1 N1 C6 3_545 . . . -40.2(2) ?
    N2 Ag1 N1 C6 . . . . 147.8(2) ?
    O3 Ag1 N1 C6 . . . . 58.1(2) ?
    O2 S1 C1 C2 . . . . 136.8(3) ?
    O3 S1 C1 C2 . . . . -103.3(3) ?
    O1 S1 C1 C2 . . . . 16.5(3) ?
    O2 S1 C1 C6 . . . . -48.0(3) ?
    O3 S1 C1 C6 . . . . 71.9(3) ?
    O1 S1 C1 C6 . . . . -168.3(3) ?
    Ag1 N1 C6 C5 . . . . 108.1(3) ?
    Ag1 N1 C6 C1 . . . . -67.9(3) ?
    C2 C1 C6 N1 . . . . 176.9(3) ?
    S1 C1 C6 N1 . . . . 1.8(5) ?
    C2 C1 C6 C5 . . . . 0.8(5) ?
    S1 C1 C6 C5 . . . . -174.3(3) ?
    C10 N2 C7 C8 . . . . 1.6(5) ?
    Ag1 N2 C7 C8 . . . . 178.8(2) ?
    C6 C1 C2 C3 . . . . 0.4(5) ?
    S1 C1 C2 C3 . . . . 175.6(3) ?
    C1 C2 C3 C4 . . . . -1.1(5) ?
    C1 C2 C3 Cl1 . . . . 179.1(3) ?
    C2 C3 C4 C5 . . . . 0.7(5) ?
    Cl1 C3 C4 C5 . . . . -179.5(3) ?
    C3 C4 C5 C6 . . . . 0.5(6) ?
    N1 C6 C5 C4 . . . . -177.4(3) ?
    C1 C6 C5 C4 . . . . -1.3(5) ?
    N2 C7 C8 N3 . . . . -1.8(5) ?
    N2 C7 C8 C12 . . . . 179.0(3) ?
    C7 C8 N3 C9 . . . . 0.5(5) ?
    C12 C8 N3 C9 . . . . 179.7(3) ?
    C7 C8 N3 Ag1 . . . 3_554 -166.4(2) ?
    C12 C8 N3 Ag1 . . . 3_554 12.8(4) ?
    C8 N3 C9 C10 . . . . 0.9(5) ?
    Ag1 N3 C9 C10 3_554 . . . 168.5(3) ?
    N2 C10 C9 N3 . . . . -1.1(5) ?
    C11 C10 C9 N3 . . . . 179.0(4) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    N1 HN1 O1 4_565 0.841(10) 2.146(12) 2.968(3) 165(3)
    N1 HN2 O2 . 0.840(10) 2.34(3) 2.890(4) 124(3)
