##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Hexaaquazinc(II) D-camphor-10-sulfonate
;
_chemical_name_common     ?
_chemical_formula_moiety     'H12 O6 Zn 2+, 2(C10 H15 O4 S -)'
_chemical_formula_sum     'C20 H42 O14 S2 Zn'
_chemical_formula_iupac     '[Zn (H2 O)6] (C10 H15 O4 S)2'
_chemical_formula_weight     636.03
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21'
_symmetry_space_group_name_Hall     P2yb
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z'
_cell_length_a     11.7293(14)
_cell_length_b     7.0854(8)
_cell_length_c     17.169(2)
_cell_angle_alpha     90.00
_cell_angle_beta     93.841(10)
_cell_angle_gamma     90.00
_cell_volume     1423.7(3)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     66
_cell_measurement_theta_min     3
_cell_measurement_theta_max     12.5
_cell_measurement_temperature     173(2)
_exptl_crystal_description     plate
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.60
_exptl_crystal_size_mid     0.60
_exptl_crystal_size_min     0.20
_exptl_crystal_density_diffrn     1.484
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     672
_exptl_absorpt_coefficient_mu     1.073
_exptl_absorpt_correction_type     'empirical'
_exptl_absorpt_process_details     '(Siemens, 1994)'
_exptl_absorpt_correction_T_min     0.5654
_exptl_absorpt_correction_T_max     0.8141
_exptl_special_details
;
;
_diffrn_ambient_temperature     173(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Siemens P4'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     7590
_diffrn_reflns_av_R_equivalents     0.0230
_diffrn_reflns_av_sigmaI/netI     0.0345
_diffrn_reflns_theta_min     3.04
_diffrn_reflns_theta_max     28.75
_diffrn_reflns_theta_full     28.75
_diffrn_measured_fraction_theta_max     0.996
_diffrn_measured_fraction_theta_full     0.996
_diffrn_reflns_limit_h_min     -15
_diffrn_reflns_limit_h_max     15
_diffrn_reflns_limit_k_min     -9
_diffrn_reflns_limit_k_max     9
_diffrn_reflns_limit_l_min     0
_diffrn_reflns_limit_l_max     22
_diffrn_standards_number     3
_diffrn_standards_interval_count     247
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     0
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     7364
_reflns_number_gt     5903
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0454
_refine_ls_R_factor_gt     0.0339
_refine_ls_wR_factor_gt     0.0834
_refine_ls_wR_factor_ref     0.0871
_refine_ls_goodness_of_fit_ref     0.972
_refine_ls_restrained_S_all     0.972
_refine_ls_number_reflns     7364
_refine_ls_number_parameters     334
_refine_ls_number_restraints     1
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                 'calc w=1/[σ²(Fo²)+(0.0537P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.005
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.509
_refine_diff_density_min     -0.475
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
_refine_ls_abs_structure_details     'Flack (1983), 3392 Friedel pairs'
_refine_ls_abs_structure_Flack     -0.005(10)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Zn' 'Zn' 0.2839 1.4301
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'XSCANS (Fait, 1991)'
_computing_cell_refinement     'XSCANS'
_computing_data_reduction     'XSCANS'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'SHELXTL-Plus (Siemens, 1995)'
_computing_publication_material     'SHELXTL-Plus'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Zn Zn 0.24152(2) 0.23602(6) 0.494431(14) 0.01905(7) Uani d . 1 . .
    O O11 0.35940(15) 0.2373(4) 0.58803(11) 0.0380(4) Uani d . 1 . .
    H H01 0.4241 0.2623 0.5725 0.046 Uiso d . 1 . .
    H H02 0.3635 0.1211 0.5973 0.046 Uiso d . 1 . .
    O O12 0.12659(17) 0.2322(4) 0.39833(12) 0.0437(5) Uani d . 1 . .
    H H03 0.0773 0.1569 0.4132 0.052 Uiso d . 1 . .
    H H04 0.0907 0.3348 0.3941 0.052 Uiso d . 1 . .
    O O13 0.1539(2) 0.4604(3) 0.54210(15) 0.0260(5) Uani d . 1 . .
    H H05 0.0868 0.4420 0.5548 0.031 Uiso d . 1 . .
    H H06 0.1535 0.5749 0.5296 0.031 Uiso d . 1 . .
    O O14 0.32956(19) 0.0144(3) 0.44599(15) 0.0263(6) Uani d . 1 . .
    H H07 0.3961 0.0090 0.4308 0.032 Uiso d . 1 . .
    H H08 0.3149 -0.0984 0.4564 0.032 Uiso d . 1 . .
    O O15 0.1528(2) 0.0204(3) 0.54855(15) 0.0265(5) Uani d . 1 . .
    H H09 0.1738 -0.0927 0.5527 0.032 Uiso d . 1 . .
    H H10 0.0843 0.0168 0.5597 0.032 Uiso d . 1 . .
    O O16 0.3304(2) 0.4525(3) 0.44272(16) 0.0316(6) Uani d . 1 . .
    H H11 0.3119 0.5651 0.4333 0.038 Uiso d . 1 . .
    H H12 0.3971 0.4458 0.4281 0.038 Uiso d . 1 . .
    S S -0.08148(4) 0.23795(13) 0.66721(3) 0.01718(10) Uani d . 1 . .
    O O1 -0.0216(2) 0.0609(3) 0.65366(14) 0.0227(5) Uani d . 1 . .
    O O2 -0.01836(19) 0.4015(3) 0.64225(14) 0.0237(5) Uani d . 1 . .
    O O3 -0.19981(12) 0.2363(4) 0.63493(9) 0.0248(3) Uani d . 1 . .
    C C1 0.00787(17) 0.2248(5) 0.82661(12) 0.0186(4) Uani d . 1 . .
    C C2 -0.0241(2) 0.2782(4) 0.90868(15) 0.0279(7) Uani d . 1 . .
    C C3 0.0859(2) 0.2888(5) 0.96047(16) 0.0353(8) Uani d . 1 . .
    H H3A 0.0855 0.1982 1.0044 0.042 Uiso calc R 1 . .
    H H3B 0.0994 0.4177 0.9814 0.042 Uiso calc R 1 . .
    C C4 0.17475(19) 0.2344(6) 0.90275(13) 0.0268(5) Uani d . 1 . .
    H H4 0.2548 0.2727 0.9193 0.032 Uiso calc R 1 . .
    C C5 0.1589(2) 0.0215(4) 0.88764(16) 0.0280(6) Uani d . 1 . .
    H H5A 0.1549 -0.0490 0.9372 0.034 Uiso calc R 1 . .
    H H5B 0.2219 -0.0302 0.8585 0.034 Uiso calc R 1 . .
    C C6 0.0428(2) 0.0126(4) 0.83773(16) 0.0226(5) Uani d . 1 . .
    H H6A -0.0152 -0.0576 0.8655 0.027 Uiso calc R 1 . .
    H H6B 0.0522 -0.0489 0.7868 0.027 Uiso calc R 1 . .
    C C7 0.1269(2) 0.3230(4) 0.82407(15) 0.0203(5) Uani d . 1 . .
    C C8 0.1166(3) 0.5399(4) 0.8263(2) 0.0358(7) Uani d . 1 . .
    H H8A 0.1923 0.5953 0.8383 0.043 Uiso calc R 1 . .
    H H8B 0.0655 0.5766 0.8665 0.043 Uiso calc R 1 . .
    H H8C 0.0855 0.5857 0.7753 0.043 Uiso calc R 1 . .
    C C9 0.1999(2) 0.2681(4) 0.75685(14) 0.0260(7) Uani d . 1 . .
    H H9A 0.2798 0.3017 0.7704 0.031 Uiso calc R 1 . .
    H H9B 0.1725 0.3356 0.7094 0.031 Uiso calc R 1 . .
    H H9C 0.1940 0.1318 0.7478 0.031 Uiso calc R 1 . .
    O O4 -0.11982(18) 0.3062(4) 0.92834(12) 0.0454(6) Uani d . 1 . .
    C C10 -0.09305(19) 0.2637(4) 0.76947(13) 0.0199(6) Uani d . 1 . .
    H H11A -0.1178 0.3950 0.7786 0.024 Uiso calc R 1 . .
    H H11B -0.1561 0.1804 0.7839 0.024 Uiso calc R 1 . .
    S S' 0.40990(4) -0.26391(13) 0.65060(3) 0.01825(10) Uani d . 1 . .
    O O1' 0.4675(2) -0.4357(3) 0.62698(15) 0.0253(5) Uani d . 1 . .
    O O2' 0.46865(19) -0.0944(3) 0.62639(15) 0.0234(5) Uani d . 1 . .
    O O3' 0.28824(12) -0.2646(4) 0.62623(9) 0.0255(3) Uani d . 1 . .
    C C1' 0.53121(17) -0.2603(5) 0.79946(12) 0.0202(4) Uani d . 1 . .
    C C2' 0.5312(3) -0.3858(4) 0.87247(17) 0.0281(6) Uani d . 1 . .
    C C3' 0.6312(3) -0.3214(4) 0.92760(18) 0.0368(8) Uani d . 1 . .
    H H3'1 0.6872 -0.4244 0.9381 0.044 Uiso calc R 1 . .
    H H3'2 0.6048 -0.2750 0.9777 0.044 Uiso calc R 1 . .
    C C4' 0.6823(2) -0.1597(4) 0.88023(16) 0.0271(6) Uani d . 1 . .
    H H4' 0.7314 -0.0691 0.9121 0.033 Uiso calc R 1 . .
    C C5' 0.74126(19) -0.2540(6) 0.81366(15) 0.0301(5) Uani d . 1 . .
    H H5'1 0.7911 -0.3587 0.8333 0.036 Uiso calc R 1 . .
    H H5'2 0.7876 -0.1618 0.7861 0.036 Uiso calc R 1 . .
    C C6' 0.6400(2) -0.3285(4) 0.75948(16) 0.0245(6) Uani d . 1 . .
    H H6'1 0.6419 -0.4679 0.7560 0.029 Uiso calc R 1 . .
    H H6'2 0.6421 -0.2750 0.7063 0.029 Uiso calc R 1 . .
    C C7' 0.5732(2) -0.0704(4) 0.83839(15) 0.0218(5) Uani d . 1 . .
    C C8' 0.4922(3) 0.0105(5) 0.8950(2) 0.0334(8) Uani d . 1 . .
    H H8'1 0.4646 -0.0911 0.9276 0.040 Uiso calc R 1 . .
    H H8'2 0.4271 0.0699 0.8658 0.040 Uiso calc R 1 . .
    H H8'3 0.5324 0.1049 0.9283 0.040 Uiso calc R 1 . .
    C C9' 0.6006(2) 0.0861(4) 0.78097(17) 0.0288(6) Uani d . 1 . .
    H H9'1 0.5295 0.1317 0.7541 0.035 Uiso calc R 1 . .
    H H9'2 0.6509 0.0361 0.7425 0.035 Uiso calc R 1 . .
    H H9'3 0.6389 0.1905 0.8095 0.035 Uiso calc R 1 . .
    O O4' 0.4641(2) -0.5084(3) 0.88454(15) 0.0405(6) Uani d . 1 . .
    C C10' 0.41553(17) -0.2650(6) 0.75433(12) 0.0228(4) Uani d . 1 . .
    H H11C 0.3713 -0.1549 0.7711 0.027 Uiso calc R 1 . .
    H H11D 0.3751 -0.3795 0.7707 0.027 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Zn O11 . 2.0485(17) ?
    Zn O12 . 2.0597(17) ?
    Zn O14 . 2.083(2) ?
    Zn O16 . 2.086(2) ?
    Zn O13 . 2.090(2) ?
    Zn O15 . 2.100(2) ?
    O11 H01 . 0.8405 ?
    O11 H02 . 0.8387 ?
    O12 H03 . 0.8394 ?
    O12 H04 . 0.8407 ?
    O13 H05 . 0.8401 ?
    O13 H06 . 0.8394 ?
    O14 H07 . 0.8404 ?
    O14 H08 . 0.8397 ?
    O15 H09 . 0.8403 ?
    O15 H10 . 0.8391 ?
    O16 H11 . 0.8392 ?
    O16 H12 . 0.8396 ?
    S O2 . 1.455(2) ?
    S O3 . 1.4596(14) ?
    S O1 . 1.464(2) ?
    S C10 . 1.779(2) ?
    C1 C10 . 1.511(3) ?
    C1 C2 . 1.530(3) ?
    C1 C7 . 1.563(3) ?
    C1 C6 . 1.566(4) ?
    C2 O4 . 1.210(3) ?
    C2 C3 . 1.519(4) ?
    C3 C4 . 1.535(4) ?
    C3 H3A . 0.9900 ?
    C3 H3B . 0.9900 ?
    C4 C5 . 1.540(5) ?
    C4 C7 . 1.560(3) ?
    C4 H4 . 1.0000 ?
    C5 C6 . 1.561(3) ?
    C5 H5A . 0.9900 ?
    C5 H5B . 0.9900 ?
    C6 H6A . 0.9900 ?
    C6 H6B . 0.9900 ?
    C7 C9 . 1.533(3) ?
    C7 C8 . 1.543(4) ?
    C8 H8A . 0.9800 ?
    C8 H8B . 0.9800 ?
    C8 H8C . 0.9800 ?
    C9 H9A . 0.9800 ?
    C9 H9B . 0.9800 ?
    C9 H9C . 0.9800 ?
    C10 H11A . 0.9900 ?
    C10 H11B . 0.9900 ?
    S' O2' . 1.459(2) ?
    S' O3' . 1.4600(14) ?
    S' O1' . 1.462(2) ?
    S' C10' . 1.778(2) ?
    C1' C10' . 1.517(3) ?
    C1' C2' . 1.537(4) ?
    C1' C6' . 1.566(3) ?
    C1' C7' . 1.567(4) ?
    C2' O4' . 1.200(4) ?
    C2' C3' . 1.527(4) ?
    C3' C4' . 1.549(4) ?
    C3' H3'1 . 0.9900 ?
    C3' H3'2 . 0.9900 ?
    C4' C5' . 1.529(4) ?
    C4' C7' . 1.559(4) ?
    C4' H4' . 1.0000 ?
    C5' C6' . 1.551(3) ?
    C5' H5'1 . 0.9900 ?
    C5' H5'2 . 0.9900 ?
    C6' H6'1 . 0.9900 ?
    C6' H6'2 . 0.9900 ?
    C7' C8' . 1.517(4) ?
    C7' C9' . 1.532(4) ?
    C8' H8'1 . 0.9800 ?
    C8' H8'2 . 0.9800 ?
    C8' H8'3 . 0.9800 ?
    C9' H9'1 . 0.9800 ?
    C9' H9'2 . 0.9800 ?
    C9' H9'3 . 0.9800 ?
    C10' H11C . 0.9900 ?
    C10' H11D . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O11 Zn O12 . . 178.36(9) ?
    O11 Zn O14 . . 89.42(10) ?
    O12 Zn O14 . . 89.18(11) ?
    O11 Zn O16 . . 90.03(11) ?
    O12 Zn O16 . . 89.28(11) ?
    O14 Zn O16 . . 96.27(6) ?
    O11 Zn O13 . . 90.77(11) ?
    O12 Zn O13 . . 90.62(11) ?
    O14 Zn O13 . . 179.36(12) ?
    O16 Zn O13 . . 83.13(11) ?
    O11 Zn O15 . . 89.10(11) ?
    O12 Zn O15 . . 91.61(11) ?
    O14 Zn O15 . . 84.37(11) ?
    O16 Zn O15 . . 178.92(12) ?
    O13 Zn O15 . . 96.24(6) ?
    Zn O11 H01 . . 109.1 ?
    Zn O11 H02 . . 99.9 ?
    H01 O11 H02 . . 103.0 ?
    Zn O12 H03 . . 101.0 ?
    Zn O12 H04 . . 110.8 ?
    H03 O12 H04 . . 103.0 ?
    Zn O13 H05 . . 118.5 ?
    Zn O13 H06 . . 128.9 ?
    H05 O13 H06 . . 103.2 ?
    Zn O14 H07 . . 130.8 ?
    Zn O14 H08 . . 121.2 ?
    H07 O14 H08 . . 103.3 ?
    Zn O15 H09 . . 125.5 ?
    Zn O15 H10 . . 129.3 ?
    H09 O15 H10 . . 103.4 ?
    Zn O16 H11 . . 130.6 ?
    Zn O16 H12 . . 126.0 ?
    H11 O16 H12 . . 103.3 ?
    O2 S O3 . . 112.59(15) ?
    O2 S O1 . . 112.13(10) ?
    O3 S O1 . . 112.77(16) ?
    O2 S C10 . . 106.45(14) ?
    O3 S C10 . . 104.01(10) ?
    O1 S C10 . . 108.28(14) ?
    C10 C1 C2 . . 108.9(2) ?
    C10 C1 C7 . . 124.3(2) ?
    C2 C1 C7 . . 100.9(2) ?
    C10 C1 C6 . . 116.2(2) ?
    C2 C1 C6 . . 101.7(2) ?
    C7 C1 C6 . . 101.77(19) ?
    O4 C2 C3 . . 126.6(3) ?
    O4 C2 C1 . . 125.9(2) ?
    C3 C2 C1 . . 107.5(2) ?
    C2 C3 C4 . . 101.3(2) ?
    C2 C3 H3A . . 111.5 ?
    C4 C3 H3A . . 111.5 ?
    C2 C3 H3B . . 111.5 ?
    C4 C3 H3B . . 111.5 ?
    H3A C3 H3B . . 109.3 ?
    C3 C4 C5 . . 106.0(2) ?
    C3 C4 C7 . . 103.7(2) ?
    C5 C4 C7 . . 102.5(2) ?
    C3 C4 H4 . . 114.4 ?
    C5 C4 H4 . . 114.4 ?
    C7 C4 H4 . . 114.4 ?
    C4 C5 C6 . . 102.9(2) ?
    C4 C5 H5A . . 111.2 ?
    C6 C5 H5A . . 111.2 ?
    C4 C5 H5B . . 111.2 ?
    C6 C5 H5B . . 111.2 ?
    H5A C5 H5B . . 109.1 ?
    C5 C6 C1 . . 103.9(2) ?
    C5 C6 H6A . . 111.0 ?
    C1 C6 H6A . . 111.0 ?
    C5 C6 H6B . . 111.0 ?
    C1 C6 H6B . . 111.0 ?
    H6A C6 H6B . . 109.0 ?
    C9 C7 C8 . . 108.6(2) ?
    C9 C7 C4 . . 111.3(2) ?
    C8 C7 C4 . . 113.8(3) ?
    C9 C7 C1 . . 116.9(2) ?
    C8 C7 C1 . . 111.8(2) ?
    C4 C7 C1 . . 93.85(19) ?
    C7 C8 H8A . . 109.5 ?
    C7 C8 H8B . . 109.5 ?
    H8A C8 H8B . . 109.5 ?
    C7 C8 H8C . . 109.5 ?
    H8A C8 H8C . . 109.5 ?
    H8B C8 H8C . . 109.5 ?
    C7 C9 H9A . . 109.5 ?
    C7 C9 H9B . . 109.5 ?
    H9A C9 H9B . . 109.5 ?
    C7 C9 H9C . . 109.5 ?
    H9A C9 H9C . . 109.5 ?
    H9B C9 H9C . . 109.5 ?
    C1 C10 S . . 120.91(16) ?
    C1 C10 H11A . . 107.1 ?
    S C10 H11A . . 107.1 ?
    C1 C10 H11B . . 107.1 ?
    S C10 H11B . . 107.1 ?
    H11A C10 H11B . . 106.8 ?
    O2' S' O3' . . 113.11(15) ?
    O2' S' O1' . . 111.75(9) ?
    O3' S' O1' . . 112.23(15) ?
    O2' S' C10' . . 107.61(17) ?
    O3' S' C10' . . 104.89(9) ?
    O1' S' C10' . . 106.69(17) ?
    C10' C1' C2' . . 110.8(2) ?
    C10' C1' C6' . . 119.8(2) ?
    C2' C1' C6' . . 102.9(2) ?
    C10' C1' C7' . . 118.8(3) ?
    C2' C1' C7' . . 99.55(19) ?
    C6' C1' C7' . . 102.11(19) ?
    O4' C2' C3' . . 126.5(3) ?
    O4' C2' C1' . . 126.6(3) ?
    C3' C2' C1' . . 106.9(2) ?
    C2' C3' C4' . . 101.7(2) ?
    C2' C3' H3'1 . . 111.4 ?
    C4' C3' H3'1 . . 111.4 ?
    C2' C3' H3'2 . . 111.4 ?
    C4' C3' H3'2 . . 111.4 ?
    H3'1 C3' H3'2 . . 109.3 ?
    C5' C4' C3' . . 106.2(3) ?
    C5' C4' C7' . . 103.4(2) ?
    C3' C4' C7' . . 102.0(2) ?
    C5' C4' H4' . . 114.6 ?
    C3' C4' H4' . . 114.6 ?
    C7' C4' H4' . . 114.6 ?
    C4' C5' C6' . . 103.34(19) ?
    C4' C5' H5'1 . . 111.1 ?
    C6' C5' H5'1 . . 111.1 ?
    C4' C5' H5'2 . . 111.1 ?
    C6' C5' H5'2 . . 111.1 ?
    H5'1 C5' H5'2 . . 109.1 ?
    C5' C6' C1' . . 104.2(2) ?
    C5' C6' H6'1 . . 110.9 ?
    C1' C6' H6'1 . . 110.9 ?
    C5' C6' H6'2 . . 110.9 ?
    C1' C6' H6'2 . . 110.9 ?
    H6'1 C6' H6'2 . . 108.9 ?
    C8' C7' C9' . . 107.8(2) ?
    C8' C7' C4' . . 112.8(2) ?
    C9' C7' C4' . . 112.9(2) ?
    C8' C7' C1' . . 113.9(2) ?
    C9' C7' C1' . . 114.9(2) ?
    C4' C7' C1' . . 94.2(2) ?
    C7' C8' H8'1 . . 109.5 ?
    C7' C8' H8'2 . . 109.5 ?
    H8'1 C8' H8'2 . . 109.5 ?
    C7' C8' H8'3 . . 109.5 ?
    H8'1 C8' H8'3 . . 109.5 ?
    H8'2 C8' H8'3 . . 109.5 ?
    C7' C9' H9'1 . . 109.5 ?
    C7' C9' H9'2 . . 109.5 ?
    H9'1 C9' H9'2 . . 109.5 ?
    C7' C9' H9'3 . . 109.5 ?
    H9'1 C9' H9'3 . . 109.5 ?
    H9'2 C9' H9'3 . . 109.5 ?
    C1' C10' S' . . 118.91(14) ?
    C1' C10' H11C . . 107.6 ?
    S' C10' H11C . . 107.6 ?
    C1' C10' H11D . . 107.6 ?
    S' C10' H11D . . 107.6 ?
    H11C C10' H11D . . 107.0 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C10 C1 C2 O4 . . . . 15.3(4) ?
    C7 C1 C2 O4 . . . . 147.5(3) ?
    C6 C1 C2 O4 . . . . -107.9(3) ?
    C10 C1 C2 C3 . . . . -164.9(2) ?
    C7 C1 C2 C3 . . . . -32.7(3) ?
    C6 C1 C2 C3 . . . . 71.9(2) ?
    O4 C2 C3 C4 . . . . 178.5(3) ?
    C1 C2 C3 C4 . . . . -1.3(3) ?
    C2 C3 C4 C5 . . . . -72.1(3) ?
    C2 C3 C4 C7 . . . . 35.4(3) ?
    C3 C4 C5 C6 . . . . 71.2(2) ?
    C7 C4 C5 C6 . . . . -37.2(2) ?
    C4 C5 C6 C1 . . . . 2.5(2) ?
    C10 C1 C6 C5 . . . . 170.7(2) ?
    C2 C1 C6 C5 . . . . -71.2(2) ?
    C7 C1 C6 C5 . . . . 32.7(2) ?
    C3 C4 C7 C9 . . . . -175.0(2) ?
    C5 C4 C7 C9 . . . . -64.9(3) ?
    C3 C4 C7 C8 . . . . 61.9(3) ?
    C5 C4 C7 C8 . . . . 172.0(2) ?
    C3 C4 C7 C1 . . . . -54.1(3) ?
    C5 C4 C7 C1 . . . . 56.1(2) ?
    C10 C1 C7 C9 . . . . -70.6(4) ?
    C2 C1 C7 C9 . . . . 167.4(2) ?
    C6 C1 C7 C9 . . . . 62.8(3) ?
    C10 C1 C7 C8 . . . . 55.5(3) ?
    C2 C1 C7 C8 . . . . -66.5(3) ?
    C6 C1 C7 C8 . . . . -171.1(2) ?
    C10 C1 C7 C4 . . . . 173.1(3) ?
    C2 C1 C7 C4 . . . . 51.1(3) ?
    C6 C1 C7 C4 . . . . -53.5(2) ?
    C2 C1 C10 S . . . . 174.2(2) ?
    C7 C1 C10 S . . . . 55.8(4) ?
    C6 C1 C10 S . . . . -71.7(3) ?
    O2 S C10 C1 . . . . -75.9(3) ?
    O3 S C10 C1 . . . . 165.0(3) ?
    O1 S C10 C1 . . . . 44.9(3) ?
    C10' C1' C2' O4' . . . . 18.1(5) ?
    C6' C1' C2' O4' . . . . -111.2(3) ?
    C7' C1' C2' O4' . . . . 144.0(3) ?
    C10' C1' C2' C3' . . . . -160.6(3) ?
    C6' C1' C2' C3' . . . . 70.2(3) ?
    C7' C1' C2' C3' . . . . -34.7(3) ?
    O4' C2' C3' C4' . . . . -178.8(3) ?
    C1' C2' C3' C4' . . . . -0.2(3) ?
    C2' C3' C4' C5' . . . . -72.4(3) ?
    C2' C3' C4' C7' . . . . 35.5(3) ?
    C3' C4' C5' C6' . . . . 70.7(3) ?
    C7' C4' C5' C6' . . . . -36.3(3) ?
    C4' C5' C6' C1' . . . . 2.4(3) ?
    C10' C1' C6' C5' . . . . 165.4(3) ?
    C2' C1' C6' C5' . . . . -71.2(3) ?
    C7' C1' C6' C5' . . . . 31.7(3) ?
    C5' C4' C7' C8' . . . . 172.5(3) ?
    C3' C4' C7' C8' . . . . 62.3(3) ?
    C5' C4' C7' C9' . . . . -64.9(3) ?
    C3' C4' C7' C9' . . . . -175.1(2) ?
    C5' C4' C7' C1' . . . . 54.3(2) ?
    C3' C4' C7' C1' . . . . -55.8(2) ?
    C10' C1' C7' C8' . . . . 57.0(3) ?
    C2' C1' C7' C8' . . . . -63.2(3) ?
    C6' C1' C7' C8' . . . . -168.8(2) ?
    C10' C1' C7' C9' . . . . -68.1(3) ?
    C2' C1' C7' C9' . . . . 171.7(2) ?
    C6' C1' C7' C9' . . . . 66.1(3) ?
    C10' C1' C7' C4' . . . . 174.2(2) ?
    C2' C1' C7' C4' . . . . 54.0(2) ?
    C6' C1' C7' C4' . . . . -51.5(2) ?
    C2' C1' C10' S' . . . . -142.1(3) ?
    C6' C1' C10' S' . . . . -22.6(5) ?
    C7' C1' C10' S' . . . . 103.6(3) ?
    O2' S' C10' C1' . . . . -58.0(3) ?
    O3' S' C10' C1' . . . . -178.7(3) ?
    O1' S' C10' C1' . . . . 62.1(3) ?
data_global
_journal_date_recd_electronic     2007-06-29
_journal_date_accepted     2007-06-30
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      8
_journal_page_first     m2071
_journal_page_last     m2071
_journal_paper_category     QM
_journal_coeditor_code     BT2423
_publ_contact_author
;
        Prof. Frank T. Edelmann
        Chemisches Institut
        Otto-von-Guericke-Universität Magdeburg
        Universitätsplatz 2
        39106 Magdeburg
        Germany
;
_publ_contact_author_email     frank.edelmann@vst.uni-magdeburg.de
_publ_contact_author_fax     '049 391 67-12933'
_publ_contact_author_phone     '049 391 67-18327'
_publ_section_title
;
Hexaaquazinc(II) D-camphor-10-sulfonate
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Schepke, Manuela' .
;
Chemisches Institut der Otto-von-Guericke-Universität
Universitätsplatz 2
D-39116 Magdeburg
Germany
;
    'Edelmann, Frank T.' .
;
Chemisches Institut der Otto-von-Guericke-Universität
Universitätsplatz 2
D-39116 Magdeburg
Germany
;
    'Blaurock, Steffen' .
;
Chemisches Institut der Otto-von-Guericke-Universität
Universitätsplatz 2
D-39116 Magdeburg
Germany
;
