##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_global
_audit_creation_method     ' SHELXL-97 and manual editing of form.cif'
_journal_data_validation_number     ?
_journal_date_recd_electronic     2007-06-01
_journal_date_accepted     2007-06-07
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      7
_journal_page_first     m1910
_journal_page_last     m1910
_journal_paper_category     QM
_journal_coeditor_code     BI2193
_publ_contact_author_name     'Dr. Wen-Bing Sun'
_publ_contact_author_address
;
Department of chemistry and Environmental Engineering
Hubei Normal Univeristy
Huangshi
Hubei 435002
People's Republic of China
;
_publ_contact_author_email     sun-wen-bing@163.com
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;\
(13,27-Dimethyl-3,6,9,17,20,23-hexaazatricyclo[23.3.1.1^11,15^]
triaconta-1(29),2,9,
11,13,15(30),16,23,25,27-decaene-29,30-diol-
κ⁵N³,N⁶,N⁹,O²⁹,O³⁰)\
bis(nitrato-κ²O,O')dysprosium(III) nitrate monohydrate
;
loop_
    _publ_author_name
    _publ_author_address
    'Sun, Wen-Bing'
;
Department of Chemistry and Environmental Engineering
Hubei Normal University
Huangshi
Hubei 435002
People's Republic of China
;
data_I
_chemical_name_systematic
;
(13,27-Dimethyl-3,6,9,17,20,23-hexaazatricyclo[23.3.1.1^11,15^]triaconta-
1(29),2,9,11,13,15(30),16,23,25,27-decaene-29,30-diol-
κ⁵N³,N⁶,N⁹,O²⁹,O³⁰)bis(nitrato-κ²O,O')dysprosium(III)
nitrate monohydrate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C26 H34 Dy N8 O8, N O3, H2 O'
_chemical_formula_sum     'C26 H36 Dy N9 O12'
_chemical_formula_iupac     '[Dy (C26 H34 N6 O2) (N O3)2] N O3, H2 O'
_chemical_formula_weight     829.14
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     14.005(3)
_cell_length_b     14.045(3)
_cell_length_c     21.896(4)
_cell_angle_alpha     96.386(3)
_cell_angle_beta     99.094(3)
_cell_angle_gamma     118.217(3)
_cell_volume     3661.0(13)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     6195
_cell_measurement_theta_min     2.51
_cell_measurement_theta_max     22.71
_cell_measurement_temperature     292(2)
_exptl_crystal_description     block
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     0.30
_exptl_crystal_size_mid     0.22
_exptl_crystal_size_min     0.20
_exptl_crystal_density_diffrn     1.504
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1668
_exptl_absorpt_coefficient_mu     2.107
_exptl_absorpt_correction_type     'multi-scan'
_exptl_absorpt_process_details     '(SADABS; Bruker, 2000)'
_exptl_absorpt_correction_T_min     0.58
_exptl_absorpt_correction_T_max     0.66
_exptl_special_details     ?
_diffrn_ambient_temperature     292(2)
_diffrn_radiation_type     'MoK\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'sealed tube'
_diffrn_radiation_monochromator     'graphite'
_diffrn_measurement_device_type     'Bruker SMART CCD'
_diffrn_measurement_method     'φ and ω'
_diffrn_reflns_number     36705
_diffrn_reflns_av_R_equivalents     0.0418
_diffrn_reflns_av_sigmaI/netI     0.0574
_diffrn_reflns_theta_min     0.96
_diffrn_reflns_theta_max     26.00
_diffrn_reflns_theta_full     26.00
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -17
_diffrn_reflns_limit_h_max     17
_diffrn_reflns_limit_k_min     -17
_diffrn_reflns_limit_k_max     17
_diffrn_reflns_limit_l_min     -27
_diffrn_reflns_limit_l_max     27
_diffrn_standards_number     0
_diffrn_standards_interval_count     .
_diffrn_standards_interval_time     .
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     14395
_reflns_number_gt     10889
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     fullcycle
_refine_ls_R_factor_all     0.0728
_refine_ls_R_factor_gt     0.0514
_refine_ls_wR_factor_gt     0.1095
_refine_ls_wR_factor_ref     0.1149
_refine_ls_goodness_of_fit_ref     1.043
_refine_ls_restrained_S_all     1.043
_refine_ls_number_reflns     14395
_refine_ls_number_parameters     872
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                   'calc w=1/[σ²(Fo²)+(0.06P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.454
_refine_diff_density_min     -1.420
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Dy' 'Dy' -0.1892 4.4098
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 2000)'
_computing_cell_refinement     'SAINT (Bruker, 2000)'
_computing_data_reduction     'SAINT'
_computing_structure_solution     'SHELXTL (Bruker, 2000)'
_computing_structure_refinement     'SHELXTL'
_computing_molecular_graphics     'SHELXTL'
_computing_publication_material     'SHELXTL'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C1 0.47785(19) 0.8435(3) 0.33060(16) 0.0424(11) Uani d G 1 . .
    C C2 0.3861(3) 0.7491(2) 0.33767(16) 0.0457(11) Uani d G 1 . .
    C C3 0.2811(2) 0.7395(2) 0.32526(17) 0.0501(12) Uani d G 1 . .
    H H3 0.2197 0.6763 0.3300 0.060 Uiso calc R 1 . .
    C C4 0.2679(2) 0.8243(3) 0.30578(16) 0.0487(12) Uani d G 1 . .
    C C5 0.3597(3) 0.9188(2) 0.29872(17) 0.0518(12) Uani d G 1 . .
    H H5 0.3509 0.9755 0.2857 0.062 Uiso calc R 1 . .
    C C6 0.4647(2) 0.9284(2) 0.31113(17) 0.0626(15) Uani d G 1 . .
    C C7 0.3928(4) 0.6602(4) 0.3563(2) 0.0423(11) Uani d . 1 . .
    H H7 0.3267 0.5988 0.3580 0.051 Uiso calc R 1 . .
    C C8 0.1511(5) 0.8098(5) 0.2895(3) 0.0620(15) Uani d . 1 . .
    H H8A 0.1469 0.8625 0.3192 0.093 Uiso calc R 1 . .
    H H8B 0.0972 0.7363 0.2915 0.093 Uiso calc R 1 . .
    H H8C 0.1357 0.8214 0.2475 0.093 Uiso calc R 1 . .
    C C9 0.5574(5) 1.0360(5) 0.3046(3) 0.0622(14) Uani d . 1 . .
    H H9 0.5392 1.0901 0.2970 0.075 Uiso calc R 1 . .
    C C10 0.8457(3) 0.7694(3) 0.34372(15) 0.0533(13) Uani d G 1 . .
    C C11 0.9485(3) 0.83720(19) 0.38639(15) 0.0465(11) Uani d G 1 . .
    C C12 1.0079(2) 0.7912(2) 0.41481(14) 0.0528(13) Uani d G 1 . .
    H H12 1.0767 0.8365 0.4434 0.063 Uiso calc R 1 . .
    C C13 0.9645(3) 0.6774(2) 0.40058(15) 0.0461(11) Uani d G 1 . .
    C C14 0.8618(3) 0.60959(19) 0.35791(16) 0.0528(13) Uani d G 1 . .
    H H14 0.8327 0.5334 0.3484 0.063 Uiso calc R 1 . .
    C C15 0.8024(2) 0.6556(2) 0.32948(14) 0.0560(13) Uani d G 1 . .
    C C16 1.0050(5) 0.9589(5) 0.4031(2) 0.0616(15) Uani d . 1 . .
    H H16 1.0794 0.9956 0.4254 0.074 Uiso calc R 1 . .
    C C17 1.0299(4) 0.6233(5) 0.4289(2) 0.0531(13) Uani d . 1 . .
    H H17A 1.0693 0.6117 0.3994 0.080 Uiso calc R 1 . .
    H H17B 0.9788 0.5536 0.4371 0.080 Uiso calc R 1 . .
    H H17C 1.0823 0.6711 0.4677 0.080 Uiso calc R 1 . .
    C C18 0.6876(5) 0.5791(5) 0.2826(2) 0.0580(14) Uani d . 1 . .
    H H18 0.6739 0.5032 0.2730 0.070 Uiso calc R 1 . .
    C C19 0.4863(4) 0.5560(4) 0.3875(3) 0.0500(12) Uani d . 1 . .
    H H19A 0.4148 0.4912 0.3668 0.060 Uiso calc R 1 . .
    H H19B 0.4963 0.5611 0.4328 0.060 Uiso calc R 1 . .
    C C20 0.5788(5) 0.5432(5) 0.3666(3) 0.0619(15) Uani d . 1 . .
    H H20A 0.6477 0.5863 0.3992 0.074 Uiso calc R 1 . .
    H H20B 0.5595 0.4662 0.3604 0.074 Uiso calc R 1 . .
    C C21 0.4973(4) 0.5106(5) 0.2517(3) 0.0616(16) Uani d . 1 . .
    H H21A 0.4337 0.5200 0.2547 0.074 Uiso calc R 1 . .
    H H21B 0.4751 0.4330 0.2476 0.074 Uiso calc R 1 . .
    C C22 0.5480(4) 0.5575(4) 0.1967(2) 0.0515(13) Uani d . 1 . .
    H H22A 0.5254 0.6091 0.1837 0.062 Uiso calc R 1 . .
    H H22B 0.5255 0.4986 0.1605 0.062 Uiso calc R 1 . .
    C C23 1.0414(4) 1.1413(5) 0.4118(3) 0.0549(14) Uani d . 1 . .
    H H23A 1.0911 1.1567 0.4524 0.066 Uiso calc R 1 . .
    H H23B 1.0865 1.1675 0.3816 0.066 Uiso calc R 1 . .
    C C24 0.9790(4) 1.1999(4) 0.4176(2) 0.0549(14) Uani d . 1 . .
    H H24A 1.0294 1.2791 0.4253 0.066 Uiso calc R 1 . .
    H H24B 0.9446 1.1842 0.4531 0.066 Uiso calc R 1 . .
    C C25 0.8306(4) 1.2242(5) 0.3592(2) 0.0531(13) Uani d . 1 . .
    H H25A 0.8800 1.3012 0.3592 0.064 Uiso calc R 1 . .
    H H25B 0.8029 1.2212 0.3973 0.064 Uiso calc R 1 . .
    C C26 0.7338(5) 1.1730(5) 0.3014(3) 0.0654(15) Uani d . 1 . .
    H H26A 0.6969 1.2165 0.2990 0.078 Uiso calc R 1 . .
    H H26B 0.7599 1.1696 0.2632 0.078 Uiso calc R 1 . .
    C C27 0.2983(4) -0.1020(4) 0.1215(2) 0.0450(11) Uani d . 1 . .
    C C28 0.3961(4) -0.1080(5) 0.1358(2) 0.0473(12) Uani d . 1 . .
    C C29 0.3941(4) -0.2033(4) 0.1516(2) 0.0446(11) Uani d . 1 . .
    H H29 0.4603 -0.2049 0.1612 0.054 Uiso calc R 1 . .
    C C30 0.2948(4) -0.2947(4) 0.1532(2) 0.0450(11) Uani d . 1 . .
    C C31 0.1949(5) -0.2905(5) 0.1391(3) 0.0565(13) Uani d . 1 . .
    H H31 0.1278 -0.3508 0.1405 0.068 Uiso calc R 1 . .
    C C32 0.1965(5) -0.1951(4) 0.1228(3) 0.0531(12) Uani d . 1 . .
    C C33 0.5050(4) -0.0196(5) 0.1327(2) 0.0498(12) Uani d . 1 . .
    H H33 0.5624 -0.0360 0.1379 0.060 Uiso calc R 1 . .
    C C34 0.2921(5) -0.3957(5) 0.1720(3) 0.0557(13) Uani d . 1 . .
    H H34A 0.2948 -0.4404 0.1366 0.084 Uiso calc R 1 . .
    H H34B 0.2246 -0.4377 0.1852 0.084 Uiso calc R 1 . .
    H H34C 0.3553 -0.3734 0.2064 0.084 Uiso calc R 1 . .
    C C35 0.0938(4) -0.2017(4) 0.1077(2) 0.0420(11) Uani d . 1 . .
    H H35 0.0314 -0.2654 0.1109 0.050 Uiso calc R 1 . .
    C C36 0.2392(4) 0.2650(4) 0.1082(3) 0.0543(13) Uani d . 1 . .
    C C37 0.2605(4) 0.3269(4) 0.0600(2) 0.0492(12) Uani d . 1 . .
    C C38 0.1853(4) 0.3658(4) 0.0384(3) 0.0514(13) Uani d . 1 . .
    H H38 0.1995 0.4079 0.0076 0.062 Uiso calc R 1 . .
    C C39 0.0952(5) 0.3430(4) 0.0615(3) 0.0572(15) Uani d . 1 . .
    C C40 0.0692(5) 0.2750(4) 0.1055(2) 0.0539(13) Uani d . 1 . .
    H H40 0.0034 0.2540 0.1187 0.065 Uiso calc R 1 . .
    C C41 0.1393(4) 0.2397(4) 0.1287(2) 0.0433(11) Uani d . 1 . .
    C C42 0.3492(4) 0.3483(4) 0.0306(2) 0.0421(10) Uani d . 1 . .
    H H42A 0.3568 0.3914 0.0004 0.050 Uiso calc R 1 . .
    C C43 0.0218(4) 0.3921(4) 0.0331(2) 0.0550(14) Uani d . 1 . .
    H H43A 0.0479 0.4641 0.0582 0.083 Uiso calc R 1 . .
    H H43B -0.0547 0.3442 0.0333 0.083 Uiso calc R 1 . .
    H H43C 0.0274 0.3979 -0.0097 0.083 Uiso calc R 1 . .
    C C44 0.1037(5) 0.1637(4) 0.1756(3) 0.0586(14) Uani d . 1 . .
    H H44 0.0403 0.1628 0.1897 0.070 Uiso calc R 1 . .
    C C45 0.1679(4) 0.0949(5) 0.2612(2) 0.0517(12) Uani d . 1 . .
    H H45A 0.2276 0.0775 0.2676 0.062 Uiso calc R 1 . .
    H H45B 0.1478 0.1033 0.3011 0.062 Uiso calc R 1 . .
    C C46 0.0712(4) 0.0098(5) 0.2122(2) 0.0463(11) Uani d . 1 . .
    H H46A 0.0727 -0.0589 0.2058 0.056 Uiso calc R 1 . .
    H H46B 0.0021 -0.0040 0.2232 0.056 Uiso calc R 1 . .
    C C47 -0.0090(4) -0.0068(4) 0.1010(3) 0.0521(13) Uani d . 1 . .
    H H47A 0.0066 0.0308 0.0662 0.062 Uiso calc R 1 . .
    H H47B -0.0762 -0.0110 0.1103 0.062 Uiso calc R 1 . .
    C C48 -0.0293(4) -0.1248(4) 0.0808(2) 0.0458(11) Uani d . 1 . .
    H H48A -0.0734 -0.1719 0.1065 0.055 Uiso calc R 1 . .
    H H48B -0.0705 -0.1552 0.0369 0.055 Uiso calc R 1 . .
    C C49 0.6479(4) 0.1487(4) 0.1208(2) 0.0435(11) Uani d . 1 . .
    H H49A 0.6855 0.1059 0.1196 0.052 Uiso calc R 1 . .
    H H49B 0.6874 0.2086 0.1580 0.052 Uiso calc R 1 . .
    C C50 0.6474(4) 0.1958(4) 0.0607(2) 0.0470(11) Uani d . 1 . .
    H H50A 0.7235 0.2443 0.0584 0.056 Uiso calc R 1 . .
    H H50B 0.6116 0.1358 0.0236 0.056 Uiso calc R 1 . .
    C C51 0.5600(4) 0.2838(5) -0.0015(2) 0.0520(13) Uani d . 1 . .
    H H51A 0.5052 0.2163 -0.0318 0.062 Uiso calc R 1 . .
    H H51B 0.6265 0.3184 -0.0175 0.062 Uiso calc R 1 . .
    C C52 0.5134(4) 0.3620(4) 0.0067(2) 0.0483(12) Uani d . 1 . .
    H H52A 0.5722 0.4342 0.0310 0.058 Uiso calc R 1 . .
    H H52B 0.4850 0.3707 -0.0344 0.058 Uiso calc R 1 . .
    Dy Dy1 0.75925(2) 0.95316(2) 0.336610(11) 0.05113(8) Uani d . 1 . .
    Dy Dy2 0.407500(18) 0.16379(2) 0.100570(12) 0.04739(8) Uani d . 1 . .
    N N1 0.4865(4) 0.6566(4) 0.3717(2) 0.0529(11) Uani d . 1 . .
    H H1A 0.5490 0.7138 0.3725 0.063 Uiso d R 1 . .
    N N2 0.6562(4) 1.0606(4) 0.3082(2) 0.0573(12) Uani d . 1 . .
    N N3 0.8918(4) 1.1639(3) 0.3585(2) 0.0463(10) Uani d . 1 . .
    H H3A 0.9267 1.1785 0.3262 0.056 Uiso calc R 1 . .
    N N4 0.9631(4) 1.0184(4) 0.3904(2) 0.0538(11) Uani d . 1 . .
    N N5 0.6776(4) 0.6179(4) 0.2258(2) 0.0601(12) Uani d . 1 . .
    H H5A 0.7121 0.5997 0.1992 0.072 Uiso calc R 1 . .
    H H5B 0.7072 0.6918 0.2342 0.072 Uiso calc R 1 . .
    N N6 0.5944(3) 0.5815(4) 0.3070(2) 0.0537(11) Uani d . 1 . .
    N N7 0.7380(4) 0.9146(4) 0.1990(2) 0.0596(12) Uani d . 1 . .
    N N8 0.7392(4) 0.9437(4) 0.4685(2) 0.0592(13) Uani d . 1 . .
    N N9 0.5318(4) 0.0781(4) 0.1236(2) 0.0586(12) Uani d . 1 . .
    N N10 0.0796(3) -0.1221(4) 0.0888(2) 0.0480(10) Uani d . 1 . .
    H H10A 0.1353 -0.0669 0.0810 0.058 Uiso d R 1 . .
    N N11 0.0828(3) 0.0565(3) 0.15591(19) 0.0438(9) Uani d . 1 . .
    N N12 0.2046(4) 0.2077(4) 0.2318(2) 0.0575(12) Uani d . 1 . .
    H H12A 0.2115 0.2641 0.2597 0.069 Uiso calc R 1 . .
    H H12B 0.2686 0.2291 0.2192 0.069 Uiso calc R 1 . .
    N N13 0.4212(4) 0.3152(4) 0.0404(2) 0.0567(12) Uani d . 1 . .
    N N14 0.5880(3) 0.2569(3) 0.06133(18) 0.0430(9) Uani d . 1 . .
    H H14A 0.6345 0.3227 0.0891 0.052 Uiso calc R 1 . .
    N N15 0.5202(4) 0.2597(3) 0.2372(2) 0.0504(11) Uani d . 1 . .
    N N16 0.2567(3) 0.0129(3) -0.01617(18) 0.0423(9) Uani d . 1 . .
    N N17 0.1430(4) 0.3787(3) 0.3121(2) 0.0550(12) Uani d . 1 . .
    N N18 0.8148(4) 0.5559(4) 0.1309(2) 0.0554(11) Uani d . 1 . .
    O O1 0.5778(3) 0.8473(3) 0.33876(17) 0.0556(9) Uani d . 1 . .
    O O2 0.7896(3) 0.8106(3) 0.31100(18) 0.0645(11) Uani d . 1 . .
    O O3 0.6560(3) 0.8534(3) 0.22214(19) 0.0638(11) Uani d . 1 . .
    O O4 0.8157(3) 0.9962(3) 0.23469(16) 0.0511(9) Uani d . 1 . .
    O O5 0.7318(3) 0.8909(3) 0.14592(18) 0.0582(10) Uani d . 1 . .
    O O6 0.7480(3) 0.8677(3) 0.43658(16) 0.0534(9) Uani d . 1 . .
    O O7 0.7562(3) 1.0260(3) 0.44466(17) 0.0566(10) Uani d . 1 . .
    O O8 0.7203(3) 0.9337(3) 0.52032(18) 0.0593(10) Uani d . 1 . .
    O O9 0.2978(3) -0.0141(3) 0.10996(16) 0.0466(8) Uani d . 1 . .
    O O10 0.3063(3) 0.2363(3) 0.13515(16) 0.0457(8) Uani d . 1 . .
    O O11 0.4298(3) 0.1682(3) 0.21994(16) 0.0539(9) Uani d . 1 . .
    O O12 0.5602(3) 0.3048(3) 0.19477(16) 0.0469(8) Uani d . 1 . .
    O O13 0.5665(3) 0.3021(3) 0.29462(19) 0.0620(10) Uani d . 1 . .
    O O14 0.3596(2) 0.0465(3) -0.00753(15) 0.0410(7) Uani d . 1 . .
    O O15 0.2248(3) 0.0671(3) 0.01518(15) 0.0483(8) Uani d . 1 . .
    O O16 0.1887(3) -0.0741(3) -0.05426(17) 0.0627(11) Uani d . 1 . .
    O O17 0.0664(3) 0.2836(3) 0.28828(18) 0.0665(12) Uani d . 1 . .
    O O18 0.2305(3) 0.4028(3) 0.29827(19) 0.0637(11) Uani d . 1 . .
    O O19 0.1357(3) 0.4538(3) 0.34430(18) 0.0616(10) Uani d . 1 . .
    O O20 0.7317(3) 0.5001(3) 0.13864(19) 0.0686(12) Uani d . 1 . .
    O O21 0.8556(4) 0.6503(4) 0.15550(19) 0.0661(11) Uani d . 1 . .
    O O22 0.8672(3) 0.5325(4) 0.09746(18) 0.0649(11) Uani d . 1 . .
    O O23 0.9291(9) 0.4352(9) 0.2281(5) 0.071(3) Uani d P 0.40 . .
    H H23D 0.9409 0.4081 0.2593 0.085 Uiso d PR 0.40 . .
    H H23E 0.8911 0.3836 0.1953 0.085 Uiso d PR 0.40 . .
    O O24 0.2786(8) 0.5461(8) 0.5132(4) 0.058(2) Uani d P 0.40 . .
    H H24C 0.2583 0.4991 0.5366 0.069 Uiso d PR 0.40 . .
    H H24E 0.2217 0.5358 0.4866 0.069 Uiso d PR 0.40 . .
    O O25 0.6348(8) 0.7333(8) 0.5865(4) 0.065(3) Uani d P 0.40 . .
    H H25D 0.6597 0.6894 0.5920 0.078 Uiso d PR 0.40 . .
    H H25E 0.6646 0.7713 0.5603 0.078 Uiso d PR 0.40 . .
    O O26 0.4610(10) 0.8251(10) 0.5315(6) 0.087(4) Uani d P 0.40 . .
    H H26E 0.5163 0.8174 0.5460 0.105 Uiso d PR 0.40 . .
    H H26D 0.4735 0.8536 0.4993 0.105 Uiso d PR 0.40 . .
    O O27 0.3462(10) 0.6915(12) 0.5223(5) 0.097(5) Uani d P 0.40 . .
    H H27C 0.3388 0.6655 0.5556 0.117 Uiso d PR 0.40 . .
    H H27A 0.2893 0.6967 0.5076 0.117 Uiso d PR 0.40 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 O1 . 1.358(4) ?
    C1 C2 . 1.390 ?
    C1 C6 . 1.390 ?
    C2 C3 . 1.390 ?
    C2 C7 . 1.396(6) ?
    C3 C4 . 1.390 ?
    C3 H3 . 0.930 ?
    C4 C5 . 1.390 ?
    C4 C8 . 1.526(6) ?
    C5 C6 . 1.390 ?
    C5 H5 . 0.930 ?
    C6 C9 . 1.498(6) ?
    C7 N1 . 1.328(5) ?
    C7 H7 . 0.930 ?
    C8 H8A . 0.960 ?
    C8 H8B . 0.960 ?
    C8 H8C . 0.960 ?
    C9 N2 . 1.244(6) ?
    C9 H9 . 0.930 ?
    C10 O2 . 1.346(4) ?
    C10 C11 . 1.390 ?
    C10 C15 . 1.390 ?
    C11 C12 . 1.390 ?
    C11 C16 . 1.474(7) ?
    C12 C13 . 1.390 ?
    C12 H12 . 0.930 ?
    C13 C14 . 1.390 ?
    C13 C17 . 1.542(6) ?
    C14 C15 . 1.390 ?
    C14 H14 . 0.930 ?
    C15 C18 . 1.546(5) ?
    C16 N4 . 1.259(7) ?
    C16 H16 . 0.930 ?
    C17 H17A . 0.960 ?
    C17 H17B . 0.960 ?
    C17 H17C . 0.960 ?
    C18 N5 . 1.425(6) ?
    C18 N6 . 1.501(6) ?
    C18 H18 . 0.980 ?
    C19 N1 . 1.490(5) ?
    C19 C20 . 1.519(8) ?
    C19 H19A . 0.970 ?
    C19 H19B . 0.970 ?
    C20 N6 . 1.475(6) ?
    C20 H20A . 0.970 ?
    C20 H20B . 0.970 ?
    C21 N6 . 1.495(5) ?
    C21 C22 . 1.548(8) ?
    C21 H21A . 0.970 ?
    C21 H21B . 0.970 ?
    C22 N5 . 1.575(5) ?
    C22 H22A . 0.970 ?
    C22 H22B . 0.970 ?
    C23 C24 . 1.467(8) ?
    C23 N4 . 1.506(6) ?
    C23 H23A . 0.970 ?
    C23 H23B . 0.970 ?
    C24 N3 . 1.480(5) ?
    C24 H24A . 0.970 ?
    C24 H24B . 0.970 ?
    C25 N3 . 1.463(6) ?
    C25 C26 . 1.513(8) ?
    C25 H25A . 0.970 ?
    C25 H25B . 0.970 ?
    C26 N2 . 1.475(6) ?
    C26 H26A . 0.970 ?
    C26 H26B . 0.970 ?
    C27 O9 . 1.291(5) ?
    C27 C28 . 1.401(7) ?
    C27 C32 . 1.415(7) ?
    C28 C29 . 1.408(7) ?
    C28 C33 . 1.460(7) ?
    C29 C30 . 1.385(7) ?
    C29 H29 . 0.930 ?
    C30 C31 . 1.414(7) ?
    C30 C34 . 1.507(7) ?
    C31 C32 . 1.416(8) ?
    C31 H31 . 0.930 ?
    C32 C35 . 1.379(7) ?
    C33 N9 . 1.289(6) ?
    C33 H33 . 0.930 ?
    C34 H34A . 0.960 ?
    C34 H34B . 0.960 ?
    C34 H34C . 0.960 ?
    C35 N10 . 1.321(5) ?
    C35 H35 . 0.930 ?
    C36 O10 . 1.276(6) ?
    C36 C37 . 1.421(8) ?
    C36 C41 . 1.431(6) ?
    C37 C42 . 1.411(5) ?
    C37 C38 . 1.442(7) ?
    C38 C39 . 1.343(8) ?
    C38 H38 . 0.930 ?
    C39 C40 . 1.400(8) ?
    C39 C43 . 1.576(5) ?
    C40 C41 . 1.353(6) ?
    C40 H40 . 0.930 ?
    C41 C44 . 1.530(8) ?
    C42 N13 . 1.296(7) ?
    C42 H42A . 0.930 ?
    C43 H43A . 0.960 ?
    C43 H43B . 0.960 ?
    C43 H43C . 0.960 ?
    C44 N11 . 1.391(7) ?
    C44 N12 . 1.533(7) ?
    C44 H44 . 0.980 ?
    C45 C46 . 1.463(7) ?
    C45 N12 . 1.659(7) ?
    C45 H45A . 0.970 ?
    C45 H45B . 0.970 ?
    C46 N11 . 1.455(6) ?
    C46 H46A . 0.970 ?
    C46 H46B . 0.970 ?
    C47 N11 . 1.443(6) ?
    C47 C48 . 1.541(7) ?
    C47 H47A . 0.970 ?
    C47 H47B . 0.970 ?
    C48 N10 . 1.490(6) ?
    C48 H48A . 0.970 ?
    C48 H48B . 0.970 ?
    C49 N9 . 1.467(6) ?
    C49 C50 . 1.538(7) ?
    C49 H49A . 0.970 ?
    C49 H49B . 0.970 ?
    C50 N14 . 1.451(7) ?
    C50 H50A . 0.970 ?
    C50 H50B . 0.970 ?
    C51 N14 . 1.507(6) ?
    C51 C52 . 1.528(8) ?
    C51 H51A . 0.970 ?
    C51 H51B . 0.970 ?
    C52 N13 . 1.500(6) ?
    C52 H52A . 0.970 ?
    C52 H52B . 0.970 ?
    Dy1 O2 . 2.265(4) ?
    Dy1 O1 . 2.269(4) ?
    Dy1 O7 . 2.486(3) ?
    Dy1 O4 . 2.525(3) ?
    Dy1 O3 . 2.548(4) ?
    Dy1 N4 . 2.569(5) ?
    Dy1 N3 . 2.578(4) ?
    Dy1 N2 . 2.595(5) ?
    Dy1 O6 . 2.602(3) ?
    Dy2 O10 . 2.270(3) ?
    Dy2 O9 . 2.287(3) ?
    Dy2 O14 . 2.520(3) ?
    Dy2 O12 . 2.538(3) ?
    Dy2 O15 . 2.555(3) ?
    Dy2 N9 . 2.564(5) ?
    Dy2 N13 . 2.571(5) ?
    Dy2 O11 . 2.573(3) ?
    Dy2 N14 . 2.578(4) ?
    N1 H1A . 0.860 ?
    N3 H3A . 0.910 ?
    N5 H5A . 0.900 ?
    N5 H5B . 0.900 ?
    N7 O5 . 1.151(6) ?
    N7 O4 . 1.209(6) ?
    N7 O3 . 1.288(6) ?
    N8 O8 . 1.214(6) ?
    N8 O7 . 1.257(7) ?
    N8 O6 . 1.275(6) ?
    N10 H10A . 0.860 ?
    N12 H12A . 0.900 ?
    N12 H12B . 0.900 ?
    N14 H14A . 0.910 ?
    N15 O12 . 1.240(6) ?
    N15 O13 . 1.252(5) ?
    N15 O11 . 1.265(6) ?
    N16 O16 . 1.231(5) ?
    N16 O15 . 1.246(5) ?
    N16 O14 . 1.259(5) ?
    N17 O18 . 1.206(6) ?
    N17 O17 . 1.233(5) ?
    N17 O19 . 1.257(6) ?
    N18 O20 . 1.107(6) ?
    N18 O21 . 1.185(6) ?
    N18 O22 . 1.235(6) ?
    O23 H23D . 0.850 ?
    O23 H23E . 0.850 ?
    O24 H24C . 0.850 ?
    O24 H24E . 0.850 ?
    O25 H25D . 0.850 ?
    O25 H25E . 0.850 ?
    O26 H26E . 0.850 ?
    O26 H26D . 0.850 ?
    O27 H27C . 0.850 ?
    O27 H27A . 0.850 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 C1 C2 . . 118.6(2) ?
    O1 C1 C6 . . 121.2(2) ?
    C2 C1 C6 . . 120.0 ?
    C1 C2 C3 . . 120.0 ?
    C1 C2 C7 . . 123.1(3) ?
    C3 C2 C7 . . 116.9(3) ?
    C4 C3 C2 . . 120.0 ?
    C4 C3 H3 . . 120.0 ?
    C2 C3 H3 . . 120.0 ?
    C3 C4 C5 . . 120.0 ?
    C3 C4 C8 . . 119.1(3) ?
    C5 C4 C8 . . 120.9(3) ?
    C6 C5 C4 . . 120.0 ?
    C6 C5 H5 . . 120.0 ?
    C4 C5 H5 . . 120.0 ?
    C5 C6 C1 . . 120.0 ?
    C5 C6 C9 . . 114.8(3) ?
    C1 C6 C9 . . 125.1(3) ?
    N1 C7 C2 . . 124.9(4) ?
    N1 C7 H7 . . 117.5 ?
    C2 C7 H7 . . 117.5 ?
    C4 C8 H8A . . 109.5 ?
    C4 C8 H8B . . 109.5 ?
    H8A C8 H8B . . 109.5 ?
    C4 C8 H8C . . 109.5 ?
    H8A C8 H8C . . 109.5 ?
    H8B C8 H8C . . 109.5 ?
    N2 C9 C6 . . 126.7(5) ?
    N2 C9 H9 . . 116.7 ?
    C6 C9 H9 . . 116.7 ?
    O2 C10 C11 . . 122.2(2) ?
    O2 C10 C15 . . 117.6(2) ?
    C11 C10 C15 . . 120.0 ?
    C12 C11 C10 . . 120.0 ?
    C12 C11 C16 . . 115.1(3) ?
    C10 C11 C16 . . 124.9(3) ?
    C11 C12 C13 . . 120.0 ?
    C11 C12 H12 . . 120.0 ?
    C13 C12 H12 . . 120.0 ?
    C12 C13 C14 . . 120.0 ?
    C12 C13 C17 . . 121.7(3) ?
    C14 C13 C17 . . 118.3(3) ?
    C15 C14 C13 . . 120.0 ?
    C15 C14 H14 . . 120.0 ?
    C13 C14 H14 . . 120.0 ?
    C14 C15 C10 . . 120.0 ?
    C14 C15 C18 . . 119.4(3) ?
    C10 C15 C18 . . 120.6(3) ?
    N4 C16 C11 . . 126.8(5) ?
    N4 C16 H16 . . 116.6 ?
    C11 C16 H16 . . 116.6 ?
    C13 C17 H17A . . 109.5 ?
    C13 C17 H17B . . 109.5 ?
    H17A C17 H17B . . 109.5 ?
    C13 C17 H17C . . 109.5 ?
    H17A C17 H17C . . 109.5 ?
    H17B C17 H17C . . 109.5 ?
    N5 C18 N6 . . 100.7(4) ?
    N5 C18 C15 . . 112.2(4) ?
    N6 C18 C15 . . 111.9(3) ?
    N5 C18 H18 . . 110.5 ?
    N6 C18 H18 . . 110.5 ?
    C15 C18 H18 . . 110.5 ?
    N1 C19 C20 . . 111.3(4) ?
    N1 C19 H19A . . 109.4 ?
    C20 C19 H19A . . 109.4 ?
    N1 C19 H19B . . 109.4 ?
    C20 C19 H19B . . 109.4 ?
    H19A C19 H19B . . 108.0 ?
    N6 C20 C19 . . 109.7(5) ?
    N6 C20 H20A . . 109.7 ?
    C19 C20 H20A . . 109.7 ?
    N6 C20 H20B . . 109.7 ?
    C19 C20 H20B . . 109.7 ?
    H20A C20 H20B . . 108.2 ?
    N6 C21 C22 . . 100.6(4) ?
    N6 C21 H21A . . 111.7 ?
    C22 C21 H21A . . 111.7 ?
    N6 C21 H21B . . 111.7 ?
    C22 C21 H21B . . 111.7 ?
    H21A C21 H21B . . 109.4 ?
    C21 C22 N5 . . 103.5(3) ?
    C21 C22 H22A . . 111.1 ?
    N5 C22 H22A . . 111.1 ?
    C21 C22 H22B . . 111.1 ?
    N5 C22 H22B . . 111.1 ?
    H22A C22 H22B . . 109.0 ?
    C24 C23 N4 . . 110.8(4) ?
    C24 C23 H23A . . 109.5 ?
    N4 C23 H23A . . 109.5 ?
    C24 C23 H23B . . 109.5 ?
    N4 C23 H23B . . 109.5 ?
    H23A C23 H23B . . 108.1 ?
    C23 C24 N3 . . 109.5(4) ?
    C23 C24 H24A . . 109.8 ?
    N3 C24 H24A . . 109.8 ?
    C23 C24 H24B . . 109.8 ?
    N3 C24 H24B . . 109.8 ?
    H24A C24 H24B . . 108.2 ?
    N3 C25 C26 . . 109.5(4) ?
    N3 C25 H25A . . 109.8 ?
    C26 C25 H25A . . 109.8 ?
    N3 C25 H25B . . 109.8 ?
    C26 C25 H25B . . 109.8 ?
    H25A C25 H25B . . 108.2 ?
    N2 C26 C25 . . 106.7(4) ?
    N2 C26 H26A . . 110.4 ?
    C25 C26 H26A . . 110.4 ?
    N2 C26 H26B . . 110.4 ?
    C25 C26 H26B . . 110.4 ?
    H26A C26 H26B . . 108.6 ?
    O9 C27 C28 . . 123.0(4) ?
    O9 C27 C32 . . 118.8(4) ?
    C28 C27 C32 . . 118.1(5) ?
    C27 C28 C29 . . 121.3(5) ?
    C27 C28 C33 . . 123.0(5) ?
    C29 C28 C33 . . 115.7(4) ?
    C30 C29 C28 . . 121.0(4) ?
    C30 C29 H29 . . 119.5 ?
    C28 C29 H29 . . 119.5 ?
    C29 C30 C31 . . 118.8(5) ?
    C29 C30 C34 . . 121.4(4) ?
    C31 C30 C34 . . 119.8(5) ?
    C30 C31 C32 . . 120.4(5) ?
    C30 C31 H31 . . 119.8 ?
    C32 C31 H31 . . 119.8 ?
    C35 C32 C27 . . 124.1(5) ?
    C35 C32 C31 . . 115.5(5) ?
    C27 C32 C31 . . 120.4(5) ?
    N9 C33 C28 . . 128.5(4) ?
    N9 C33 H33 . . 115.7 ?
    C28 C33 H33 . . 115.7 ?
    C30 C34 H34A . . 109.5 ?
    C30 C34 H34B . . 109.5 ?
    H34A C34 H34B . . 109.5 ?
    C30 C34 H34C . . 109.5 ?
    H34A C34 H34C . . 109.5 ?
    H34B C34 H34C . . 109.5 ?
    N10 C35 C32 . . 123.4(4) ?
    N10 C35 H35 . . 118.3 ?
    C32 C35 H35 . . 118.3 ?
    O10 C36 C37 . . 123.3(5) ?
    O10 C36 C41 . . 119.8(4) ?
    C37 C36 C41 . . 116.8(5) ?
    C42 C37 C36 . . 123.2(4) ?
    C42 C37 C38 . . 118.5(5) ?
    C36 C37 C38 . . 118.3(5) ?
    C39 C38 C37 . . 121.9(6) ?
    C39 C38 H38 . . 119.0 ?
    C37 C38 H38 . . 119.0 ?
    C38 C39 C40 . . 119.9(5) ?
    C38 C39 C43 . . 115.6(5) ?
    C40 C39 C43 . . 124.4(5) ?
    C41 C40 C39 . . 120.1(5) ?
    C41 C40 H40 . . 119.9 ?
    C39 C40 H40 . . 119.9 ?
    C40 C41 C36 . . 122.7(4) ?
    C40 C41 C44 . . 116.9(4) ?
    C36 C41 C44 . . 120.3(4) ?
    N13 C42 C37 . . 127.9(4) ?
    N13 C42 H42A . . 116.1 ?
    C37 C42 H42A . . 116.1 ?
    C39 C43 H43A . . 109.5 ?
    C39 C43 H43B . . 109.5 ?
    H43A C43 H43B . . 109.5 ?
    C39 C43 H43C . . 109.5 ?
    H43A C43 H43C . . 109.5 ?
    H43B C43 H43C . . 109.5 ?
    N11 C44 C41 . . 116.3(5) ?
    N11 C44 N12 . . 100.6(4) ?
    C41 C44 N12 . . 107.4(4) ?
    N11 C44 H44 . . 110.7 ?
    C41 C44 H44 . . 110.7 ?
    N12 C44 H44 . . 110.7 ?
    C46 C45 N12 . . 102.9(4) ?
    C46 C45 H45A . . 111.2 ?
    N12 C45 H45A . . 111.2 ?
    C46 C45 H45B . . 111.2 ?
    N12 C45 H45B . . 111.2 ?
    H45A C45 H45B . . 109.1 ?
    N11 C46 C45 . . 103.9(4) ?
    N11 C46 H46A . . 111.0 ?
    C45 C46 H46A . . 111.0 ?
    N11 C46 H46B . . 111.0 ?
    C45 C46 H46B . . 111.0 ?
    H46A C46 H46B . . 109.0 ?
    N11 C47 C48 . . 112.1(4) ?
    N11 C47 H47A . . 109.2 ?
    C48 C47 H47A . . 109.2 ?
    N11 C47 H47B . . 109.2 ?
    C48 C47 H47B . . 109.2 ?
    H47A C47 H47B . . 107.9 ?
    N10 C48 C47 . . 109.7(4) ?
    N10 C48 H48A . . 109.7 ?
    C47 C48 H48A . . 109.7 ?
    N10 C48 H48B . . 109.7 ?
    C47 C48 H48B . . 109.7 ?
    H48A C48 H48B . . 108.2 ?
    N9 C49 C50 . . 108.3(4) ?
    N9 C49 H49A . . 110.0 ?
    C50 C49 H49A . . 110.0 ?
    N9 C49 H49B . . 110.0 ?
    C50 C49 H49B . . 110.0 ?
    H49A C49 H49B . . 108.4 ?
    N14 C50 C49 . . 110.2(4) ?
    N14 C50 H50A . . 109.6 ?
    C49 C50 H50A . . 109.6 ?
    N14 C50 H50B . . 109.6 ?
    C49 C50 H50B . . 109.6 ?
    H50A C50 H50B . . 108.1 ?
    N14 C51 C52 . . 109.6(4) ?
    N14 C51 H51A . . 109.7 ?
    C52 C51 H51A . . 109.7 ?
    N14 C51 H51B . . 109.7 ?
    C52 C51 H51B . . 109.7 ?
    H51A C51 H51B . . 108.2 ?
    N13 C52 C51 . . 109.2(4) ?
    N13 C52 H52A . . 109.8 ?
    C51 C52 H52A . . 109.8 ?
    N13 C52 H52B . . 109.8 ?
    C51 C52 H52B . . 109.8 ?
    H52A C52 H52B . . 108.3 ?
    O2 Dy1 O1 . . 96.09(15) ?
    O2 Dy1 O7 . . 124.77(15) ?
    O1 Dy1 O7 . . 77.37(13) ?
    O2 Dy1 O4 . . 82.30(14) ?
    O1 Dy1 O4 . . 121.63(12) ?
    O7 Dy1 O4 . . 147.27(13) ?
    O2 Dy1 O3 . . 70.77(14) ?
    O1 Dy1 O3 . . 74.58(13) ?
    O7 Dy1 O3 . . 149.38(13) ?
    O4 Dy1 O3 . . 49.67(12) ?
    O2 Dy1 N4 . . 72.73(14) ?
    O1 Dy1 N4 . . 145.61(14) ?
    O7 Dy1 N4 . . 82.75(14) ?
    O4 Dy1 N4 . . 89.71(13) ?
    O3 Dy1 N4 . . 127.77(14) ?
    O2 Dy1 N3 . . 130.87(14) ?
    O1 Dy1 N3 . . 133.02(14) ?
    O7 Dy1 N3 . . 74.39(13) ?
    O4 Dy1 N3 . . 73.54(12) ?
    O3 Dy1 N3 . . 117.53(13) ?
    N4 Dy1 N3 . . 65.19(14) ?
    O2 Dy1 N2 . . 149.91(14) ?
    O1 Dy1 N2 . . 71.76(14) ?
    O7 Dy1 N2 . . 80.41(14) ?
    O4 Dy1 N2 . . 81.32(12) ?
    O3 Dy1 N2 . . 79.39(14) ?
    N4 Dy1 N2 . . 132.06(15) ?
    N3 Dy1 N2 . . 67.11(14) ?
    O2 Dy1 O6 . . 75.76(14) ?
    O1 Dy1 O6 . . 70.35(12) ?
    O7 Dy1 O6 . . 50.09(13) ?
    O4 Dy1 O6 . . 156.28(13) ?
    O3 Dy1 O6 . . 127.74(12) ?
    N4 Dy1 O6 . . 75.35(13) ?
    N3 Dy1 O6 . . 114.73(12) ?
    N2 Dy1 O6 . . 122.36(12) ?
    O10 Dy2 O9 . . 98.05(12) ?
    O10 Dy2 O14 . . 125.75(11) ?
    O9 Dy2 O14 . . 74.94(12) ?
    O10 Dy2 O12 . . 83.54(12) ?
    O9 Dy2 O12 . . 119.82(12) ?
    O14 Dy2 O12 . . 147.03(10) ?
    O10 Dy2 O15 . . 76.39(12) ?
    O9 Dy2 O15 . . 69.21(12) ?
    O14 Dy2 O15 . . 50.44(10) ?
    O12 Dy2 O15 . . 159.19(11) ?
    O10 Dy2 N9 . . 149.36(14) ?
    O9 Dy2 N9 . . 71.61(13) ?
    O14 Dy2 N9 . . 80.44(13) ?
    O12 Dy2 N9 . . 77.60(13) ?
    O15 Dy2 N9 . . 122.92(13) ?
    O10 Dy2 N13 . . 71.20(14) ?
    O9 Dy2 N13 . . 145.54(13) ?
    O14 Dy2 N13 . . 85.04(13) ?
    O12 Dy2 N13 . . 92.10(13) ?
    O15 Dy2 N13 . . 76.39(13) ?
    N9 Dy2 N13 . . 132.80(15) ?
    O10 Dy2 O11 . . 72.68(13) ?
    O9 Dy2 O11 . . 73.55(12) ?
    O14 Dy2 O11 . . 145.53(12) ?
    O12 Dy2 O11 . . 49.39(12) ?
    O15 Dy2 O11 . . 126.79(12) ?
    N9 Dy2 O11 . . 76.71(14) ?
    N13 Dy2 O11 . . 129.33(14) ?
    O10 Dy2 N14 . . 129.84(13) ?
    O9 Dy2 N14 . . 132.09(13) ?
    O14 Dy2 N14 . . 75.68(11) ?
    O12 Dy2 N14 . . 73.20(11) ?
    O15 Dy2 N14 . . 116.04(12) ?
    N9 Dy2 N14 . . 66.83(14) ?
    N13 Dy2 N14 . . 66.10(14) ?
    O11 Dy2 N14 . . 117.08(12) ?
    C7 N1 C19 . . 121.9(3) ?
    C7 N1 H1A . . 119.1 ?
    C19 N1 H1A . . 119.0 ?
    C9 N2 C26 . . 117.1(4) ?
    C9 N2 Dy1 . . 130.9(3) ?
    C26 N2 Dy1 . . 111.7(3) ?
    C25 N3 C24 . . 112.7(3) ?
    C25 N3 Dy1 . . 111.6(2) ?
    C24 N3 Dy1 . . 110.0(2) ?
    C25 N3 H3A . . 107.4 ?
    C24 N3 H3A . . 107.4 ?
    Dy1 N3 H3A . . 107.4 ?
    C16 N4 C23 . . 115.4(3) ?
    C16 N4 Dy1 . . 127.2(3) ?
    C23 N4 Dy1 . . 117.3(2) ?
    C18 N5 C22 . . 104.1(3) ?
    C18 N5 H5A . . 110.9 ?
    C22 N5 H5A . . 110.9 ?
    C18 N5 H5B . . 110.9 ?
    C22 N5 H5B . . 110.9 ?
    H5A N5 H5B . . 108.9 ?
    C20 N6 C21 . . 113.7(3) ?
    C20 N6 C18 . . 115.4(3) ?
    C21 N6 C18 . . 101.1(3) ?
    O5 N7 O4 . . 123.9(5) ?
    O5 N7 O3 . . 118.9(5) ?
    O4 N7 O3 . . 117.2(4) ?
    O8 N8 O7 . . 125.0(5) ?
    O8 N8 O6 . . 118.0(5) ?
    O7 N8 O6 . . 116.8(4) ?
    C33 N9 C49 . . 116.4(4) ?
    C33 N9 Dy2 . . 129.3(3) ?
    C49 N9 Dy2 . . 114.2(3) ?
    C35 N10 C48 . . 122.3(4) ?
    C35 N10 H10A . . 118.7 ?
    C48 N10 H10A . . 119.0 ?
    C44 N11 C47 . . 113.7(4) ?
    C44 N11 C46 . . 104.9(4) ?
    C47 N11 C46 . . 115.4(4) ?
    C44 N12 C45 . . 99.6(4) ?
    C44 N12 H12A . . 111.8 ?
    C45 N12 H12A . . 111.8 ?
    C44 N12 H12B . . 111.8 ?
    C45 N12 H12B . . 111.8 ?
    H12A N12 H12B . . 109.6 ?
    C42 N13 C52 . . 115.2(5) ?
    C42 N13 Dy2 . . 126.2(4) ?
    C52 N13 Dy2 . . 118.2(3) ?
    C50 N14 C51 . . 114.0(4) ?
    C50 N14 Dy2 . . 114.4(3) ?
    C51 N14 Dy2 . . 108.1(3) ?
    C50 N14 H14A . . 106.6 ?
    C51 N14 H14A . . 106.6 ?
    Dy2 N14 H14A . . 106.6 ?
    O12 N15 O13 . . 122.0(4) ?
    O12 N15 O11 . . 117.0(4) ?
    O13 N15 O11 . . 121.0(5) ?
    O16 N16 O15 . . 120.7(4) ?
    O16 N16 O14 . . 120.0(4) ?
    O15 N16 O14 . . 119.4(4) ?
    O18 N17 O17 . . 115.5(5) ?
    O18 N17 O19 . . 117.9(4) ?
    O17 N17 O19 . . 126.3(5) ?
    O20 N18 O21 . . 115.5(5) ?
    O20 N18 O22 . . 128.0(5) ?
    O21 N18 O22 . . 116.4(5) ?
    C1 O1 Dy1 . . 143.9(2) ?
    C10 O2 Dy1 . . 133.4(2) ?
    N7 O3 Dy1 . . 94.4(3) ?
    N7 O4 Dy1 . . 97.7(3) ?
    N8 O6 Dy1 . . 93.0(3) ?
    N8 O7 Dy1 . . 99.0(3) ?
    C27 O9 Dy2 . . 144.3(2) ?
    C36 O10 Dy2 . . 134.5(3) ?
    N15 O11 Dy2 . . 95.6(3) ?
    N15 O12 Dy2 . . 98.0(3) ?
    N16 O14 Dy2 . . 93.6(2) ?
    N16 O15 Dy2 . . 92.4(3) ?
    H23D O23 H23E . . 109.5 ?
    H24C O24 H24E . . 109.5 ?
    H25D O25 H25E . . 109.5 ?
    H26E O26 H26D . . 107.3 ?
    H27C O27 H27A . . 109.8 ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N14 H14A O20 . 0.91 2.23 3.118(6) 165.6 y
    N12 H12B O10 . 0.90 1.99 2.696(6) 133.8 y
    N12 H12A N17 . 0.90 2.50 3.332(7) 154.9 y
    N12 H12A O17 . 0.90 2.34 2.972(7) 126.9 y
    N12 H12A O18 . 0.90 1.91 2.786(6) 163.6 y
    N5 H5B O2 . 0.90 1.97 2.684(6) 135.1 y
    N5 H5A N18 . 0.90 2.45 3.348(7) 177.1 y
    N5 H5A O21 . 0.90 2.21 3.015(7) 149.1 y
    N5 H5A O20 . 0.90 1.96 2.809(6) 155.9 y
    N1 H1A O1 . 0.86 1.98 2.610(5) 129.5 y
    N10 H10A O9 . 0.86 1.99 2.620(5) 128.9 y
    N3 H3A O17 1_665 0.91 2.18 3.008(5) 150.9 y
