##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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#                                                                            #
#            Copyright International Union of Crystallography                #
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##############################################################################
                                             
data_I
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
Bis(acetonitrile-κN)hexakis(μ₂-4-amino-3,5-dimethyl-1,2,4-\
triazole-κ²N¹:N²)tetrasilver(I)
tetrakis(trifluoromethanesulfonate) acetonitrile disolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C28 H54 Ag4 N26 4+ , 4C F3 S O3 - , 2C2 H3 N'
_chemical_formula_sum     'C36 H60 Ag4 F12 N28 O12 S4'
_chemical_formula_iupac
                          '[Ag4 (C4 H8 N4)6 (C2 H3 N)2] (C F3 O3 S)4 , 2C2 H3 N'
_chemical_formula_weight     1864.84
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     12.110(3)
_cell_length_b     12.695(3)
_cell_length_c     13.001(3)
_cell_angle_alpha     108.59(2)
_cell_angle_beta     92.84(2)
_cell_angle_gamma     108.68(2)
_cell_volume     1768.9(7)
_cell_formula_units_Z     1
_cell_measurement_reflns_used     12901
_cell_measurement_theta_min     3.2
_cell_measurement_theta_max     27.5
_cell_measurement_temperature     295(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.38
_exptl_crystal_size_mid     0.24
_exptl_crystal_size_min     0.18
_exptl_crystal_density_diffrn     1.751
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     928
_exptl_absorpt_coefficient_mu     1.310
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(ABSCOR; Higashi, 1995)'
_exptl_absorpt_correction_T_min     0.294
_exptl_absorpt_correction_T_max     0.790
_diffrn_ambient_temperature     295(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Rigaku R-AXIS RAPID IP'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     17453
_diffrn_reflns_av_R_equivalents     0.046
_diffrn_reflns_av_sigmaI/netI     0.062
_diffrn_reflns_theta_min     3.2
_diffrn_reflns_theta_max     27.5
_diffrn_reflns_theta_full     27.5
_diffrn_measured_fraction_theta_max     0.99
_diffrn_measured_fraction_theta_full     0.99
_diffrn_reflns_limit_h_min     -15
_diffrn_reflns_limit_h_max     15
_diffrn_reflns_limit_k_min     -16
_diffrn_reflns_limit_k_max     16
_diffrn_reflns_limit_l_min     -16
_diffrn_reflns_limit_l_max     16
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_reflns_number_total     8026
_reflns_number_gt     5532
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.097
_refine_ls_R_factor_gt     0.074
_refine_ls_wR_factor_gt     0.217
_refine_ls_wR_factor_ref     0.239
_refine_ls_goodness_of_fit_ref     1.07
_refine_ls_restrained_S_all     1.10
_refine_ls_number_reflns     8026
_refine_ls_number_parameters     440
_refine_ls_number_restraints     150
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.1356P)²+1.8203P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     2.27
_refine_diff_density_min     -1.07
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'F' 'F' 0.0171 0.0103
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ag' 'Ag' -0.8971 1.1015
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'RAPID-AUTO (Rigaku, 1998)'
_computing_cell_refinement     RAPID-AUTO
_computing_data_reduction     'CrystalStructure (Rigaku/MSC, 2002)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEPII (Johnson, 1976)'
_computing_publication_material     'publCIF (Westrip, 2007)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag1 0.88000(5) 0.37448(5) 0.53930(4) 0.0621(2) Uani d . 1 . .
    Ag Ag2 0.88609(5) 0.34115(5) 0.27393(5) 0.0638(2) Uani d . 1 . .
    S S1 0.7324(2) -0.2778(2) 0.18838(19) 0.0805(6) Uani d D 1 . .
    S S2 0.35409(18) 0.13112(19) 0.22789(16) 0.0712(5) Uani d D 1 . .
    F F1 0.9445(7) -0.1622(9) 0.2985(8) 0.170(4) Uani d DU 1 . .
    F F2 0.8266(7) -0.0761(8) 0.3487(7) 0.160(3) Uani d DU 1 . .
    F F3 0.8888(11) -0.0812(11) 0.2008(9) 0.217(5) Uani d DU 1 . .
    F F4 0.1809(7) -0.0452(7) 0.2334(7) 0.158(3) Uani d DU 1 . .
    F F5 0.1678(7) -0.0141(7) 0.0858(6) 0.160(3) Uani d DU 1 . .
    F F6 0.2856(7) -0.0934(6) 0.1161(7) 0.149(3) Uani d DU 1 . .
    O O1 0.6474(7) -0.2360(8) 0.1530(7) 0.132(3) Uani d DU 1 . .
    O O2 0.7789(8) -0.3403(8) 0.0991(6) 0.131(3) Uani d DU 1 . .
    O O3 0.7050(9) -0.3320(9) 0.2672(7) 0.159(4) Uani d DU 1 . .
    O O4 0.4239(6) 0.1125(7) 0.3072(6) 0.110(2) Uani d DU 1 . .
    O O5 0.4112(6) 0.1538(7) 0.1402(5) 0.111(2) Uani d DU 1 . .
    O O6 0.2899(6) 0.2062(6) 0.2726(5) 0.0957(19) Uani d DU 1 . .
    N N1 0.7678(5) 0.1969(5) 0.4177(4) 0.0578(13) Uani d . 1 . .
    N N2 0.7624(5) 0.1844(5) 0.3087(5) 0.0579(13) Uani d . 1 . .
    N N3 0.6319(5) 0.0297(5) 0.3212(5) 0.0582(13) Uani d . 1 . .
    N N4 0.5376(6) -0.0794(6) 0.2984(6) 0.0746(18) Uani d . 1 . .
    H H41 0.5009 -0.1217 0.2303 0.090 Uiso calc R 1 . .
    H H42 0.5155 -0.1049 0.3523 0.090 Uiso calc R 1 . .
    N N5 0.8361(5) 0.5079(5) 0.6744(4) 0.0562(13) Uani d . 1 . .
    N N6 0.7571(5) 0.5996(5) 0.8023(5) 0.0561(13) Uani d . 1 . .
    N N7 0.9223(5) 0.6100(5) 0.7420(5) 0.0561(13) Uani d . 1 . .
    N N8 0.6722(5) 0.6246(6) 0.8662(6) 0.0739(18) Uani d . 1 . .
    H H81 0.5984 0.5749 0.8477 0.089 Uiso calc R 1 . .
    H H82 0.6928 0.6899 0.9246 0.089 Uiso calc R 1 . .
    N N9 0.8379(5) 0.4932(5) 0.4025(5) 0.0561(13) Uani d . 1 . .
    N N10 0.9244(4) 0.6030(5) 0.4585(5) 0.0541(13) Uani d . 1 . .
    N N11 0.7536(4) 0.6201(5) 0.4680(4) 0.0517(12) Uani d . 1 . .
    N N12 0.6623(5) 0.6652(6) 0.4855(5) 0.0665(16) Uani d . 1 . .
    H H121 0.5886 0.6184 0.4565 0.080 Uiso calc R 1 . .
    H H112 0.6784 0.7404 0.5254 0.080 Uiso calc R 1 . .
    N N13 0.7755(9) 0.3396(10) 0.1152(8) 0.114(3) Uani d . 1 . .
    N N14 0.250(3) -0.308(3) 0.189(2) 0.264(11) Uani d U 1 . .
    C C1 0.6685(9) 0.0784(10) 0.5277(8) 0.097(3) Uani d . 1 . .
    H H1A 0.7029 0.0213 0.5322 0.145 Uiso calc R 1 . .
    H H1B 0.5851 0.0474 0.5278 0.145 Uiso calc R 1 . .
    H H1C 0.7045 0.1508 0.5897 0.145 Uiso calc R 1 . .
    C C2 0.6887(6) 0.1028(7) 0.4236(6) 0.0623(17) Uani d . 1 . .
    C C3 0.6779(6) 0.0828(6) 0.2511(6) 0.0569(15) Uani d . 1 . .
    C C4 0.6397(8) 0.0329(8) 0.1312(6) 0.075(2) Uani d . 1 . .
    H H4A 0.6872 0.0858 0.0985 0.113 Uiso calc R 1 . .
    H H4B 0.5582 0.0233 0.1144 0.113 Uiso calc R 1 . .
    H H4C 0.6487 -0.0429 0.1022 0.113 Uiso calc R 1 . .
    C C5 0.6178(7) 0.4084(9) 0.6657(9) 0.084(3) Uani d . 1 . .
    H H5A 0.6170 0.3615 0.5911 0.126 Uiso calc R 1 . .
    H H5B 0.5589 0.4444 0.6671 0.126 Uiso calc R 1 . .
    H H5C 0.6010 0.3585 0.7092 0.126 Uiso calc R 1 . .
    C C6 0.7363(6) 0.5028(7) 0.7115(6) 0.0579(16) Uani d . 1 . .
    C C7 0.8760(6) 0.6652(7) 0.8194(6) 0.0579(16) Uani d . 1 . .
    C C8 0.9362(8) 0.7778(9) 0.9108(8) 0.091(3) Uani d . 1 . .
    H H8A 1.0201 0.8008 0.9125 0.136 Uiso calc R 1 . .
    H H8B 0.9178 0.7680 0.9789 0.136 Uiso calc R 1 . .
    H H8C 0.9100 0.8382 0.9008 0.136 Uiso calc R 1 . .
    C C9 0.9304(7) 0.8075(7) 0.5646(8) 0.077(2) Uani d . 1 . .
    H H9A 0.9333 0.8188 0.6415 0.116 Uiso calc R 1 . .
    H H9B 0.8855 0.8506 0.5454 0.116 Uiso calc R 1 . .
    H H9C 1.0093 0.8363 0.5499 0.116 Uiso calc R 1 . .
    C C10 0.8730(5) 0.6783(6) 0.4979(5) 0.0538(15) Uani d . 1 . .
    C C11 0.7364(6) 0.5056(6) 0.4077(5) 0.0559(15) Uani d . 1 . .
    C C12 0.6179(6) 0.4146(7) 0.3571(7) 0.069(2) Uani d . 1 . .
    H H12C 0.6038 0.4019 0.2800 0.104 Uiso calc R 1 . .
    H H12D 0.5589 0.4413 0.3922 0.104 Uiso calc R 1 . .
    H H12E 0.6141 0.3414 0.3662 0.104 Uiso calc R 1 . .
    C C13 0.6966(9) 0.3471(10) 0.0752(8) 0.089(3) Uani d . 1 . .
    C C14 0.5926(9) 0.3532(13) 0.0198(10) 0.115(4) Uani d . 1 . .
    H H14A 0.5555 0.2814 -0.0426 0.172 Uiso calc R 1 . .
    H H14B 0.6158 0.4199 -0.0045 0.172 Uiso calc R 1 . .
    H H14C 0.5379 0.3625 0.0699 0.172 Uiso calc R 1 . .
    C C15 0.8526(9) -0.1444(10) 0.2621(8) 0.116(4) Uani d D 1 . .
    C C16 0.2423(8) -0.0117(9) 0.1627(7) 0.104(3) Uani d D 1 . .
    C C17 0.148(2) -0.3490(19) 0.1723(19) 0.167(7) Uani d U 1 . .
    C C18 0.021(3) -0.403(3) 0.146(3) 0.265(13) Uani d U 1 . .
    H H18A -0.0037 -0.4790 0.1551 0.398 Uiso calc R 1 . .
    H H18B -0.0053 -0.4133 0.0717 0.398 Uiso calc R 1 . .
    H H18C -0.0137 -0.3526 0.1952 0.398 Uiso calc R 1 . .
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 N1 . 2.232(5) yes
    Ag1 N5 . 2.238(5) yes
    Ag1 N10 2_766 2.290(5) yes
    Ag1 Ag2 . 3.3469(11) ?
    Ag2 N2 . 2.267(6) yes
    Ag2 N7 2_766 2.241(5) yes
    Ag2 N9 . 2.371(6) yes
    Ag2 N13 . 2.395(9) yes
    S1 O3 . 1.404(6) ?
    S1 O1 . 1.419(6) ?
    S1 O2 . 1.434(6) ?
    S1 C15 . 1.776(12) ?
    S2 O6 . 1.420(5) ?
    S2 O4 . 1.425(5) ?
    S2 O5 . 1.422(5) ?
    S2 C16 . 1.781(11) ?
    F1 C15 . 1.301(7) ?
    F2 C15 . 1.306(8) ?
    F3 C15 . 1.299(8) ?
    F4 C16 . 1.301(7) ?
    F5 C16 . 1.298(7) ?
    F6 C16 . 1.302(7) ?
    N1 C2 . 1.298(9) ?
    N1 N2 . 1.370(8) ?
    N2 C3 . 1.318(8) ?
    N3 C3 . 1.341(9) ?
    N3 C2 . 1.349(9) ?
    N3 N4 . 1.415(8) ?
    N4 H41 . 0.8800 ?
    N4 H42 . 0.8800 ?
    N5 C6 . 1.313(9) ?
    N5 N7 . 1.363(8) ?
    N6 C6 . 1.347(9) ?
    N6 C7 . 1.379(9) ?
    N6 N8 . 1.404(8) ?
    N7 C7 . 1.294(9) ?
    N7 Ag2 2_766 2.241(5) ?
    N8 H81 . 0.8800 ?
    N8 H82 . 0.8800 ?
    N9 C11 . 1.291(9) ?
    N9 N10 . 1.383(7) ?
    N10 C10 . 1.291(9) ?
    N10 Ag1 2_766 2.290(5) ?
    N11 C11 . 1.354(9) ?
    N11 C10 . 1.366(8) ?
    N11 N12 . 1.396(7) ?
    N12 H121 . 0.8800 ?
    N12 H112 . 0.8800 ?
    N13 C13 . 1.110(13) ?
    N14 C17 . 1.15(3) ?
    C1 C2 . 1.496(11) ?
    C1 H1A . 0.9600 ?
    C1 H1B . 0.9600 ?
    C1 H1C . 0.9600 ?
    C3 C4 . 1.469(9) ?
    C4 H4A . 0.9600 ?
    C4 H4B . 0.9600 ?
    C4 H4C . 0.9600 ?
    C5 C6 . 1.486(10) ?
    C5 H5A . 0.9600 ?
    C5 H5B . 0.9600 ?
    C5 H5C . 0.9600 ?
    C7 C8 . 1.466(11) ?
    C8 H8A . 0.9600 ?
    C8 H8B . 0.9600 ?
    C8 H8C . 0.9600 ?
    C9 C10 . 1.493(10) ?
    C9 H9A . 0.9600 ?
    C9 H9B . 0.9600 ?
    C9 H9C . 0.9600 ?
    C11 C12 . 1.479(9) ?
    C12 H12C . 0.9600 ?
    C12 H12D . 0.9600 ?
    C12 H12E . 0.9600 ?
    C13 C14 . 1.456(14) ?
    C14 H14A . 0.9600 ?
    C14 H14B . 0.9600 ?
    C14 H14C . 0.9600 ?
    C17 C18 . 1.44(3) ?
    C18 H18A . 0.9600 ?
    C18 H18B . 0.9600 ?
    C18 H18C . 0.9600 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N1 Ag1 N5 . . 131.8(2) yes
    N1 Ag1 N10 . 2_766 109.7(2) yes
    N5 Ag1 N10 . 2_766 117.2(2) yes
    N1 Ag1 Ag2 . . 64.14(15) ?
    N5 Ag1 Ag2 . . 131.10(16) ?
    N10 Ag1 Ag2 2_766 . 82.56(14) ?
    N2 Ag2 N9 . . 97.9(2) yes
    N2 Ag2 N7 . 2_766 130.8(2) yes
    N2 Ag2 N13 . . 102.6(3) yes
    N7 Ag2 N9 2_766 . 114.7(2) yes
    N7 Ag2 N13 2_766 . 109.4(3) yes
    N9 Ag2 N13 . . 95.6(3) yes
    N7 Ag2 Ag1 2_766 . 105.28(15) ?
    N2 Ag2 Ag1 . . 63.63(14) ?
    N9 Ag2 Ag1 . . 55.38(15) ?
    N13 Ag2 Ag1 . . 142.1(3) ?
    O3 S1 O1 . . 116.7(5) ?
    O3 S1 O2 . . 114.5(5) ?
    O1 S1 O2 . . 112.9(4) ?
    O3 S1 C15 . . 103.2(6) ?
    O1 S1 C15 . . 102.8(5) ?
    O2 S1 C15 . . 104.7(5) ?
    O6 S2 O4 . . 115.0(4) ?
    O6 S2 O5 . . 114.5(4) ?
    O4 S2 O5 . . 114.9(4) ?
    O6 S2 C16 . . 103.9(4) ?
    O4 S2 C16 . . 102.9(4) ?
    O5 S2 C16 . . 103.6(4) ?
    C2 N1 N2 . . 107.5(5) ?
    C2 N1 Ag1 . . 134.9(5) ?
    N2 N1 Ag1 . . 116.6(4) ?
    C3 N2 N1 . . 108.0(6) ?
    C3 N2 Ag2 . . 136.6(5) ?
    N1 N2 Ag2 . . 115.2(4) ?
    C3 N3 C2 . . 107.4(6) ?
    C3 N3 N4 . . 128.8(6) ?
    C2 N3 N4 . . 123.8(6) ?
    N3 N4 H41 . . 120.0 ?
    N3 N4 H42 . . 120.0 ?
    H41 N4 H42 . . 120.0 ?
    C6 N5 N7 . . 107.9(5) ?
    C6 N5 Ag1 . . 130.7(5) ?
    N7 N5 Ag1 . . 121.0(4) ?
    C6 N6 C7 . . 106.5(5) ?
    C6 N6 N8 . . 125.4(6) ?
    C7 N6 N8 . . 128.1(6) ?
    C7 N7 N5 . . 108.8(5) ?
    C7 N7 Ag2 . 2_766 127.3(5) ?
    N5 N7 Ag2 . 2_766 123.7(4) ?
    N6 N8 H81 . . 120.0 ?
    N6 N8 H82 . . 120.0 ?
    H81 N8 H82 . . 120.0 ?
    C11 N9 N10 . . 107.9(6) ?
    C11 N9 Ag2 . . 128.4(4) ?
    N10 N9 Ag2 . . 120.3(4) ?
    C10 N10 N9 . . 108.2(5) ?
    C10 N10 Ag1 . 2_766 131.8(4) ?
    N9 N10 Ag1 . 2_766 119.9(4) ?
    C11 N11 C10 . . 106.7(5) ?
    C11 N11 N12 . . 123.7(5) ?
    C10 N11 N12 . . 129.4(6) ?
    N11 N12 H121 . . 120.0 ?
    N11 N12 H112 . . 120.0 ?
    H121 N12 H112 . . 120.0 ?
    C13 N13 Ag2 . . 150.4(10) ?
    C2 C1 H1A . . 109.5 ?
    C2 C1 H1B . . 109.5 ?
    H1A C1 H1B . . 109.5 ?
    C2 C1 H1C . . 109.5 ?
    H1A C1 H1C . . 109.5 ?
    H1B C1 H1C . . 109.5 ?
    N1 C2 N3 . . 109.1(6) ?
    N1 C2 C1 . . 124.8(7) ?
    N3 C2 C1 . . 126.1(7) ?
    N2 C3 N3 . . 108.0(6) ?
    N2 C3 C4 . . 127.2(7) ?
    N3 C3 C4 . . 124.8(6) ?
    C3 C4 H4A . . 109.5 ?
    C3 C4 H4B . . 109.5 ?
    H4A C4 H4B . . 109.5 ?
    C3 C4 H4C . . 109.5 ?
    H4A C4 H4C . . 109.5 ?
    H4B C4 H4C . . 109.5 ?
    C6 C5 H5A . . 109.5 ?
    C6 C5 H5B . . 109.5 ?
    H5A C5 H5B . . 109.5 ?
    C6 C5 H5C . . 109.5 ?
    H5A C5 H5C . . 109.5 ?
    H5B C5 H5C . . 109.5 ?
    N5 C6 N6 . . 108.7(6) ?
    N5 C6 C5 . . 128.0(7) ?
    N6 C6 C5 . . 123.3(7) ?
    N7 C7 N6 . . 108.2(6) ?
    N7 C7 C8 . . 127.5(7) ?
    N6 C7 C8 . . 124.3(6) ?
    C7 C8 H8A . . 109.5 ?
    C7 C8 H8B . . 109.5 ?
    H8A C8 H8B . . 109.5 ?
    C7 C8 H8C . . 109.5 ?
    H8A C8 H8C . . 109.5 ?
    H8B C8 H8C . . 109.5 ?
    C10 C9 H9A . . 109.5 ?
    C10 C9 H9B . . 109.5 ?
    H9A C9 H9B . . 109.5 ?
    C10 C9 H9C . . 109.5 ?
    H9A C9 H9C . . 109.5 ?
    H9B C9 H9C . . 109.5 ?
    N10 C10 N11 . . 108.3(6) ?
    N10 C10 C9 . . 127.4(6) ?
    N11 C10 C9 . . 124.2(6) ?
    N9 C11 N11 . . 108.8(6) ?
    N9 C11 C12 . . 128.1(7) ?
    N11 C11 C12 . . 123.0(6) ?
    C11 C12 H12C . . 109.5 ?
    C11 C12 H12D . . 109.5 ?
    H12C C12 H12D . . 109.5 ?
    C11 C12 H12E . . 109.5 ?
    H12C C12 H12E . . 109.5 ?
    H12D C12 H12E . . 109.5 ?
    N13 C13 C14 . . 178.1(13) ?
    C13 C14 H14A . . 109.5 ?
    C13 C14 H14B . . 109.5 ?
    H14A C14 H14B . . 109.5 ?
    C13 C14 H14C . . 109.5 ?
    H14A C14 H14C . . 109.5 ?
    H14B C14 H14C . . 109.5 ?
    F3 C15 F1 . . 106.1(8) ?
    F3 C15 F2 . . 106.6(8) ?
    F1 C15 F2 . . 105.3(7) ?
    F3 C15 S1 . . 111.5(8) ?
    F1 C15 S1 . . 113.4(8) ?
    F2 C15 S1 . . 113.3(8) ?
    F5 C16 F4 . . 106.8(7) ?
    F5 C16 F6 . . 106.1(7) ?
    F4 C16 F6 . . 107.4(7) ?
    F5 C16 S2 . . 112.8(7) ?
    F4 C16 S2 . . 111.0(7) ?
    F6 C16 S2 . . 112.5(7) ?
    N14 C17 C18 . . 178(3) ?
    C17 C18 H18A . . 109.5 ?
    C17 C18 H18B . . 109.5 ?
    H18A C18 H18B . . 109.5 ?
    C17 C18 H18C . . 109.5 ?
    H18A C18 H18C . . 109.5 ?
    H18B C18 H18C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    N1 Ag1 Ag2 N7 . . . 2_766 -125.5(2) ?
    N5 Ag1 Ag2 N7 . . . 2_766 110.5(2) ?
    N10 Ag1 Ag2 N7 2_766 . . 2_766 -9.4(2) ?
    N1 Ag1 Ag2 N2 . . . . 2.8(2) ?
    N5 Ag1 Ag2 N2 . . . . -121.2(3) ?
    N10 Ag1 Ag2 N2 2_766 . . . 119.0(2) ?
    N1 Ag1 Ag2 N9 . . . . 124.7(2) ?
    N5 Ag1 Ag2 N9 . . . . 0.7(2) ?
    N10 Ag1 Ag2 N9 2_766 . . . -119.1(2) ?
    N1 Ag1 Ag2 N13 . . . . 78.8(5) ?
    N5 Ag1 Ag2 N13 . . . . -45.2(5) ?
    N10 Ag1 Ag2 N13 2_766 . . . -165.0(4) ?
    N5 Ag1 N1 C2 . . . . -48.6(8) ?
    N10 Ag1 N1 C2 2_766 . . . 117.3(7) ?
    Ag2 Ag1 N1 C2 . . . . -171.7(8) ?
    N5 Ag1 N1 N2 . . . . 118.5(5) ?
    N10 Ag1 N1 N2 2_766 . . . -75.6(5) ?
    Ag2 Ag1 N1 N2 . . . . -4.6(4) ?
    C2 N1 N2 C3 . . . . 1.0(8) ?
    Ag1 N1 N2 C3 . . . . -169.4(5) ?
    C2 N1 N2 Ag2 . . . . 177.3(5) ?
    Ag1 N1 N2 Ag2 . . . . 6.8(6) ?
    N7 Ag2 N2 C3 2_766 . . . -101.9(7) ?
    N9 Ag2 N2 C3 . . . . 125.4(7) ?
    N13 Ag2 N2 C3 . . . . 27.9(8) ?
    Ag1 Ag2 N2 C3 . . . . 170.3(8) ?
    N7 Ag2 N2 N1 2_766 . . . 83.2(5) ?
    N9 Ag2 N2 N1 . . . . -49.4(5) ?
    N13 Ag2 N2 N1 . . . . -146.9(5) ?
    Ag1 Ag2 N2 N1 . . . . -4.5(4) ?
    N1 Ag1 N5 C6 . . . . 4.8(8) ?
    N10 Ag1 N5 C6 2_766 . . . -160.3(6) ?
    Ag2 Ag1 N5 C6 . . . . 94.9(6) ?
    N1 Ag1 N5 N7 . . . . 177.3(4) ?
    N10 Ag1 N5 N7 2_766 . . . 12.2(6) ?
    Ag2 Ag1 N5 N7 . . . . -92.6(5) ?
    C6 N5 N7 C7 . . . . 0.6(8) ?
    Ag1 N5 N7 C7 . . . . -173.4(5) ?
    C6 N5 N7 Ag2 . . . 2_766 175.2(5) ?
    Ag1 N5 N7 Ag2 . . . 2_766 1.2(7) ?
    N7 Ag2 N9 C11 2_766 . . . 158.4(6) ?
    N2 Ag2 N9 C11 . . . . -59.5(6) ?
    N13 Ag2 N9 C11 . . . . 44.1(7) ?
    Ag1 Ag2 N9 C11 . . . . -109.6(6) ?
    N7 Ag2 N9 N10 2_766 . . . 1.8(6) ?
    N2 Ag2 N9 N10 . . . . 144.0(5) ?
    N13 Ag2 N9 N10 . . . . -112.5(5) ?
    Ag1 Ag2 N9 N10 . . . . 93.8(5) ?
    C11 N9 N10 C10 . . . . 1.2(8) ?
    Ag2 N9 N10 C10 . . . . 162.1(5) ?
    C11 N9 N10 Ag1 . . . 2_766 -175.9(4) ?
    Ag2 N9 N10 Ag1 . . . 2_766 -15.0(6) ?
    N7 Ag2 N13 C13 2_766 . . . -156(2) ?
    N2 Ag2 N13 C13 . . . . 62(2) ?
    N9 Ag2 N13 C13 . . . . -37(2) ?
    Ag1 Ag2 N13 C13 . . . . 0(2) ?
    N2 N1 C2 N3 . . . . -0.2(8) ?
    Ag1 N1 C2 N3 . . . . 167.7(5) ?
    N2 N1 C2 C1 . . . . 177.5(8) ?
    Ag1 N1 C2 C1 . . . . -14.6(13) ?
    C3 N3 C2 N1 . . . . -0.7(8) ?
    N4 N3 C2 N1 . . . . -177.8(7) ?
    C3 N3 C2 C1 . . . . -178.3(9) ?
    N4 N3 C2 C1 . . . . 4.5(13) ?
    N1 N2 C3 N3 . . . . -1.5(8) ?
    Ag2 N2 C3 N3 . . . . -176.5(5) ?
    N1 N2 C3 C4 . . . . 179.3(8) ?
    Ag2 N2 C3 C4 . . . . 4.3(13) ?
    C2 N3 C3 N2 . . . . 1.4(8) ?
    N4 N3 C3 N2 . . . . 178.3(7) ?
    C2 N3 C3 C4 . . . . -179.4(8) ?
    N4 N3 C3 C4 . . . . -2.5(13) ?
    N7 N5 C6 N6 . . . . -0.4(8) ?
    Ag1 N5 C6 N6 . . . . 172.8(5) ?
    N7 N5 C6 C5 . . . . -179.8(8) ?
    Ag1 N5 C6 C5 . . . . -6.6(12) ?
    C7 N6 C6 N5 . . . . 0.1(8) ?
    N8 N6 C6 N5 . . . . -179.0(6) ?
    C7 N6 C6 C5 . . . . 179.5(8) ?
    N8 N6 C6 C5 . . . . 0.5(12) ?
    N5 N7 C7 N6 . . . . -0.6(8) ?
    Ag2 N7 C7 N6 2_766 . . . -174.9(4) ?
    N5 N7 C7 C8 . . . . 179.2(9) ?
    Ag2 N7 C7 C8 2_766 . . . 4.9(12) ?
    C6 N6 C7 N7 . . . . 0.3(8) ?
    N8 N6 C7 N7 . . . . 179.3(7) ?
    C6 N6 C7 C8 . . . . -179.5(9) ?
    N8 N6 C7 C8 . . . . -0.5(12) ?
    N9 N10 C10 N11 . . . . -0.5(7) ?
    Ag1 N10 C10 N11 2_766 . . . 176.2(4) ?
    N9 N10 C10 C9 . . . . 179.7(8) ?
    Ag1 N10 C10 C9 2_766 . . . -3.5(12) ?
    C11 N11 C10 N10 . . . . -0.4(7) ?
    N12 N11 C10 N10 . . . . -175.7(6) ?
    C11 N11 C10 C9 . . . . 179.4(8) ?
    N12 N11 C10 C9 . . . . 4.1(11) ?
    N10 N9 C11 N11 . . . . -1.5(8) ?
    Ag2 N9 C11 N11 . . . . -160.3(5) ?
    N10 N9 C11 C12 . . . . 177.7(7) ?
    Ag2 N9 C11 C12 . . . . 18.8(11) ?
    C10 N11 C11 N9 . . . . 1.2(7) ?
    N12 N11 C11 N9 . . . . 176.9(6) ?
    C10 N11 C11 C12 . . . . -178.0(7) ?
    N12 N11 C11 C12 . . . . -2.4(11) ?
    O3 S1 C15 F3 . . . . -179.1(8) ?
    O1 S1 C15 F3 . . . . -57.3(8) ?
    O2 S1 C15 F3 . . . . 60.8(8) ?
    O3 S1 C15 F1 . . . . 61.2(8) ?
    O1 S1 C15 F1 . . . . -177.0(7) ?
    O2 S1 C15 F1 . . . . -58.9(8) ?
    O3 S1 C15 F2 . . . . -58.8(8) ?
    O1 S1 C15 F2 . . . . 63.0(8) ?
    O2 S1 C15 F2 . . . . -178.9(7) ?
    O6 S2 C16 F5 . . . . 60.0(7) ?
    O4 S2 C16 F5 . . . . -179.9(6) ?
    O5 S2 C16 F5 . . . . -59.9(7) ?
    O6 S2 C16 F4 . . . . -59.8(7) ?
    O4 S2 C16 F4 . . . . 60.4(7) ?
    O5 S2 C16 F4 . . . . -179.7(6) ?
    O6 S2 C16 F6 . . . . 179.9(6) ?
    O4 S2 C16 F6 . . . . -60.0(7) ?
    O5 S2 C16 F6 . . . . 60.0(7) ?
data_global
_journal_data_validation_number     ?
_journal_date_recd_electronic     2007-05-22
_journal_date_accepted     2007-05-30
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      7
_journal_page_first     m1801
_journal_page_last     m1801
_journal_paper_category     QM
_journal_coeditor_code     BT2378
_publ_contact_author_name     'Dr Seik Weng Ng'
_publ_contact_author_address
;
Department of Chemistry
University of Malaya
50603 Kuala Lumpur
Malaysia
;
_publ_contact_author_email     seikweng@um.edu.my
_publ_contact_author_fax     '603 7967 6778'
_publ_contact_author_phone     '603 7967 4913'
_publ_section_title
;\
Bis(acetonitrile-κN)hexakis(μ₂-4-amino-3,5-dimethyl-1,2,4-triazole-\
κ²N¹:N²)tetrasilver(I)
tetrakis(trifluoromethanesulfonate) acetonitrile disolvate
;
loop_
    _publ_author_name
    _publ_author_address
    'Wang, Ying-Li'
;
Department of Chemistry
Zhengzhou University
Zhengzhou 450001
People's Republic of China
;
    'Yang, Guang'
;
Department of Chemistry
Zhengzhou University
Zhengzhou 450001
People's Republic of China
;
    'Ng, Seik Weng'
;
Department of Chemistry
University of Malaya
50603 Kuala Lumpur
Malaysia
;
