##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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##############################################################################
                                             
data_global
_audit_creation_method     SHELXL97
_journal_date_recd_electronic     2007-05-10
_journal_date_accepted     2007-05-20
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      6
_journal_page_first     o2982
_journal_page_last     o2983
_journal_paper_category     QO
_journal_coeditor_code     DN2175
_publ_contact_author_name     'Dr Resat Ustabas'
_publ_contact_author_address
;
Teacher of Physics
Anatolian Trade High School
Merzifon 05300
Amasya
Turkey
;
_publ_contact_author_email     rustabas@omu.edu.tr
_publ_contact_author_fax     ' '
_publ_contact_author_phone     ' '
_publ_section_title
;
A flip-disorder in
1-(benzoylmethyl)-4-[(2,4-dichlorobenzylidene)amino]-3-(2-thienylmethyl)-
4,5-dihydro-1H-1,2,4-triazol-5-one
;
loop_
    _publ_author_name
    _publ_author_address
    'Ustabaş, Reşat'
;
Teacher of Physics
Anatolian Trade High School
Merzifon 05300
Amasya
Turkey
;
    'Çoruh, Ufuk'
;
Department of Computer Education and Instructional Technology
Educational Faculty
Ondokuz Mayıs University
55200 Atakum-Samsun
Turkey
;
    'Sancak, Kemal'
;
Department of Chemistry
Faculty of Arts and Sciences
Karadeniz Teknik University
61080 Trabzon
Turkey
;
    'Ünver, Yasemin'
;
Department of Chemistry
Faculty of Arts and Sciences
Karadeniz Teknik University
61080 Trabzon
Turkey
;
    'Vázquez-López, Ezequiel M.'
;
Departamento de Química Inorgánica
Facultade de Ciencias-Química
Universidade de Vigo
36200 Vigo
Galicia
Spain
;
data_I
_chemical_name_systematic
;
1-(benzoylmethyl)-4-[(2,4-dichlorobenzylidene)amino]-3-(2-thienylmethyl)-
4,5-dihydro-1H-1,2,4-triazol-5-one
;
_chemical_name_common     ?
_chemical_formula_moiety     'C22 H16 Cl2 N4 O2 S'
_chemical_formula_sum     'C22 H16 Cl2 N4 O2 S'
_chemical_formula_iupac     'C22 H16 Cl2 N4 O2 S'
_chemical_formula_weight     471.35
_chemical_melting_point     ?
_symmetry_cell_setting     orthorhombic
_symmetry_space_group_name_H-M     'P b c a'
_symmetry_space_group_name_Hall     '-P 2ac 2ab'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, -y, z+1/2'
    'x+1/2, -y+1/2, -z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, y, -z-1/2'
    '-x-1/2, y-1/2, z'
    'x, -y-1/2, z-1/2'
_cell_length_a     10.9045(13)
_cell_length_b     18.509(2)
_cell_length_c     21.228(3)
_cell_angle_alpha     90.00
_cell_angle_beta     90.00
_cell_angle_gamma     90.00
_cell_volume     4284.4(9)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     1671
_cell_measurement_theta_min     1.92
_cell_measurement_theta_max     28.03
_cell_measurement_temperature     293(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.30
_exptl_crystal_size_mid     0.25
_exptl_crystal_size_min     0.20
_exptl_crystal_density_diffrn     1.461
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1936
_exptl_absorpt_coefficient_mu     0.428
_exptl_absorpt_correction_type     none
_exptl_absorpt_process_details     ?
_exptl_absorpt_correction_T_min     ?
_exptl_absorpt_correction_T_max     ?
_exptl_special_details
;
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     20905
_diffrn_reflns_av_R_equivalents     0.1030
_diffrn_reflns_av_sigmaI/netI     0.1644
_diffrn_reflns_theta_min     1.92
_diffrn_reflns_theta_max     28.03
_diffrn_reflns_theta_full     28.03
_diffrn_measured_fraction_theta_max     0.993
_diffrn_measured_fraction_theta_full     0.993
_diffrn_reflns_limit_h_min     -14
_diffrn_reflns_limit_h_max     14
_diffrn_reflns_limit_k_min     -24
_diffrn_reflns_limit_k_max     18
_diffrn_reflns_limit_l_min     -27
_diffrn_reflns_limit_l_max     28
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     5052
_reflns_number_gt     1671
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.2328
_refine_ls_R_factor_gt     0.0494
_refine_ls_wR_factor_gt     0.0945
_refine_ls_wR_factor_ref     0.1310
_refine_ls_goodness_of_fit_ref     0.836
_refine_ls_restrained_S_all     0.875
_refine_ls_number_reflns     5052
_refine_ls_number_parameters     301
_refine_ls_number_restraints     148
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
               'calc w = 1/[σ²(Fo²)+(0.0469P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.454
_refine_diff_density_min     -0.252
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 1997)'
_computing_cell_refinement     'SAINT (Bruker, 1997)'
_computing_data_reduction     'SAINT'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material     'WinGX (Farrugia, 1999)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Cl Cl21 1.32634(11) 0.05797(7) 0.56626(5) 0.0926(4) Uani d . 1 . .
    Cl Cl22 1.36468(11) -0.14685(6) 0.39064(6) 0.1026(5) Uani d . 1 . .
    O O21 1.0206(2) 0.19915(13) 0.60310(11) 0.0607(7) Uani d . 1 . .
    N N21 0.9952(3) 0.12711(16) 0.47299(13) 0.0509(8) Uani d . 1 . .
    N N2 0.9344(2) 0.18406(16) 0.50114(13) 0.0480(7) Uani d . 1 . .
    N N1 0.7847(3) 0.26329(17) 0.50817(15) 0.0605(9) Uani d . 1 . .
    N N3 0.8565(3) 0.26362(16) 0.56198(14) 0.0570(8) Uani d . 1 . .
    C C21 1.0907(3) 0.1034(2) 0.50017(17) 0.0525(10) Uani d . 1 . .
    H H21 1.1181 0.1249 0.5371 0.063 Uiso calc R 1 . .
    C C22 1.1579(3) 0.04203(19) 0.47348(17) 0.0465(9) Uani d . 1 . .
    C C2 0.9483(3) 0.2137(2) 0.56163(18) 0.0497(9) Uani d . 1 . .
    C C26 1.3275(4) -0.0427(2) 0.4762(2) 0.0662(11) Uani d . 1 . .
    H H26 1.3978 -0.0599 0.4960 0.079 Uiso calc R 1 . .
    C C27 1.2647(3) 0.0163(2) 0.50036(17) 0.0547(10) Uani d . 1 . .
    C C33 0.8744(3) 0.4183(2) 0.68112(18) 0.0543(10) Uani d . 1 . .
    C C1 0.8337(3) 0.2147(2) 0.47287(17) 0.0533(10) Uani d . 1 B .
    C C31 0.8221(3) 0.30610(19) 0.61592(15) 0.0547(10) Uani d . 1 . .
    H H31A 0.8254 0.2758 0.6532 0.066 Uiso calc R 1 . .
    H H31B 0.7380 0.3221 0.6107 0.066 Uiso calc R 1 . .
    C C32 0.9029(3) 0.3716(2) 0.62635(18) 0.0531(10) Uani d . 1 . .
    O O31 0.9870(3) 0.38367(15) 0.59117(14) 0.0891(10) Uani d . 1 . .
    C C11 0.7843(3) 0.1924(2) 0.41043(16) 0.0578(9) Uani d DU 1 . .
    H H11A 0.6975 0.2038 0.4091 0.069 Uiso calc R 1 A 1
    H H11B 0.7922 0.1404 0.4066 0.069 Uiso calc R 1 A 1
    C C12 0.8453(5) 0.2270(3) 0.3550(2) 0.0571(9) Uani d PDU 0.785(3) B 1
    S S11 0.98134(13) 0.19883(9) 0.32561(8) 0.0713(6) Uani d PDU 0.785(3) B 1
    C C13 0.7886(6) 0.2802(4) 0.3212(3) 0.0666(12) Uani d PDU 0.785(3) B 1
    H H13 0.7121 0.3004 0.3294 0.080 Uiso calc PR 0.785(3) B 1
    C C14 0.8751(5) 0.3000(3) 0.2677(3) 0.0716(11) Uani d PDU 0.785(3) B 1
    H H14 0.8590 0.3364 0.2387 0.086 Uiso calc PR 0.785(3) B 1
    C C15 0.9759(5) 0.2598(3) 0.2667(3) 0.0725(12) Uani d PDU 0.785(3) B 1
    H H15 1.0372 0.2647 0.2366 0.087 Uiso calc PR 0.785(3) B 1
    C C12' 0.8527(12) 0.2212(7) 0.3532(3) 0.0616(14) Uiso d PDU 0.215(3) B 2
    S S11' 0.8163(7) 0.2950(4) 0.3095(4) 0.0722(14) Uiso d PDU 0.215(3) B 2
    C C13' 0.9566(14) 0.1860(9) 0.3320(8) 0.0663(19) Uiso d PDU 0.215(3) B 2
    H H13' 0.9914 0.1447 0.3495 0.080 Uiso calc PR 0.215(3) B 2
    C C14' 1.0039(14) 0.2273(9) 0.2747(8) 0.0687(19) Uiso d PDU 0.215(3) B 2
    H H14' 1.0734 0.2137 0.2522 0.082 Uiso calc PR 0.215(3) B 2
    C C15' 0.9356(11) 0.2849(8) 0.2600(6) 0.068(2) Uiso d PDU 0.215(3) B 2
    H H15' 0.9521 0.3157 0.2265 0.081 Uiso calc PR 0.215(3) B 2
    C C24 1.1791(4) -0.0510(2) 0.3943(2) 0.0761(12) Uani d . 1 . .
    H H24 1.1499 -0.0739 0.3583 0.091 Uiso calc R 1 . .
    C C38 0.7842(4) 0.4019(2) 0.72463(19) 0.0665(11) Uani d . 1 . .
    H H38 0.7378 0.3601 0.7198 0.080 Uiso calc R 1 . .
    C C25 1.2842(4) -0.0750(2) 0.4228(2) 0.0667(12) Uani d . 1 . .
    C C23 1.1168(3) 0.0070(2) 0.41901(19) 0.0625(11) Uani d . 1 . .
    H H23 1.0460 0.0232 0.3992 0.075 Uiso calc R 1 . .
    C C37 0.7628(5) 0.4467(3) 0.7749(2) 0.0892(14) Uani d . 1 . .
    H H37 0.7013 0.4354 0.8036 0.107 Uiso calc R 1 . .
    C C35 0.9191(6) 0.5250(3) 0.7406(3) 0.1083(18) Uani d . 1 . .
    H H35 0.9649 0.5669 0.7460 0.130 Uiso calc R 1 . .
    C C34 0.9415(4) 0.4808(3) 0.6892(2) 0.0797(13) Uani d . 1 . .
    H H34 1.0017 0.4932 0.6601 0.096 Uiso calc R 1 . .
    C C36 0.8312(6) 0.5078(3) 0.7831(3) 0.1050(18) Uani d . 1 . .
    H H36 0.8175 0.5374 0.8178 0.126 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Cl21 C27 . 1.733(4) ?
    Cl22 C25 . 1.733(4) ?
    O21 C2 . 1.212(4) ?
    N21 C21 . 1.269(4) ?
    N21 N2 . 1.381(4) ?
    N2 C1 . 1.374(4) ?
    N2 C2 . 1.405(4) ?
    N1 C1 . 1.287(4) ?
    N1 N3 . 1.385(4) ?
    N3 C2 . 1.362(4) ?
    N3 C31 . 1.439(4) ?
    C21 C22 . 1.465(5) ?
    C21 H21 . 0.9300 ?
    C22 C27 . 1.381(4) ?
    C22 C23 . 1.399(5) ?
    C26 C25 . 1.367(5) ?
    C26 C27 . 1.387(5) ?
    C26 H26 . 0.9300 ?
    C33 C34 . 1.378(5) ?
    C33 C38 . 1.383(5) ?
    C33 C32 . 1.482(5) ?
    C1 C11 . 1.489(5) ?
    C31 C32 . 1.516(5) ?
    C31 H31A . 0.9700 ?
    C31 H31B . 0.9700 ?
    C32 O31 . 1.204(4) ?
    C11 C12 . 1.495(5) ?
    C11 C12' . 1.522(8) ?
    C11 H11A . 0.9700 ?
    C11 H11B . 0.9700 ?
    C12 C13 . 1.367(8) ?
    C12 S11 . 1.692(6) ?
    S11 C15 . 1.685(5) ?
    C13 C14 . 1.522(9) ?
    C13 H13 . 0.9300 ?
    C14 C15 . 1.328(6) ?
    C14 H14 . 0.9300 ?
    C15 H15 . 0.9300 ?
    C12' C13' . 1.383(13) ?
    C12' S11' . 1.698(12) ?
    S11' C15' . 1.682(10) ?
    C13' C14' . 1.526(12) ?
    C13' H13' . 0.9300 ?
    C14' C15' . 1.337(11) ?
    C14' H14' . 0.9300 ?
    C15' H15' . 0.9300 ?
    C24 C25 . 1.370(5) ?
    C24 C23 . 1.374(5) ?
    C24 H24 . 0.9300 ?
    C38 C37 . 1.372(5) ?
    C38 H38 . 0.9300 ?
    C23 H23 . 0.9300 ?
    C37 C36 . 1.366(6) ?
    C37 H37 . 0.9300 ?
    C35 C36 . 1.355(7) ?
    C35 C34 . 1.386(6) ?
    C35 H35 . 0.9300 ?
    C34 H34 . 0.9300 ?
    C36 H36 . 0.9300 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C21 N21 N2 . . 117.5(3) ?
    C1 N2 N21 . . 120.6(3) ?
    C1 N2 C2 . . 108.9(3) ?
    N21 N2 C2 . . 130.0(3) ?
    C1 N1 N3 . . 104.4(3) ?
    C2 N3 N1 . . 114.1(3) ?
    C2 N3 C31 . . 124.5(3) ?
    N1 N3 C31 . . 120.8(3) ?
    N21 C21 C22 . . 120.2(3) ?
    N21 C21 H21 . . 119.9 ?
    C22 C21 H21 . . 119.9 ?
    C27 C22 C23 . . 116.8(3) ?
    C27 C22 C21 . . 121.9(3) ?
    C23 C22 C21 . . 121.2(4) ?
    O21 C2 N3 . . 128.7(4) ?
    O21 C2 N2 . . 130.3(3) ?
    N3 C2 N2 . . 101.0(3) ?
    C25 C26 C27 . . 118.7(4) ?
    C25 C26 H26 . . 120.7 ?
    C27 C26 H26 . . 120.7 ?
    C22 C27 C26 . . 122.4(4) ?
    C22 C27 Cl21 . . 120.5(3) ?
    C26 C27 Cl21 . . 117.1(3) ?
    C34 C33 C38 . . 118.7(4) ?
    C34 C33 C32 . . 118.4(4) ?
    C38 C33 C32 . . 123.0(4) ?
    N1 C1 N2 . . 111.5(3) ?
    N1 C1 C11 . . 124.2(3) ?
    N2 C1 C11 . . 124.3(4) ?
    N3 C31 C32 . . 113.7(3) ?
    N3 C31 H31A . . 108.8 ?
    C32 C31 H31A . . 108.8 ?
    N3 C31 H31B . . 108.8 ?
    C32 C31 H31B . . 108.8 ?
    H31A C31 H31B . . 107.7 ?
    O31 C32 C33 . . 122.6(4) ?
    O31 C32 C31 . . 120.0(3) ?
    C33 C32 C31 . . 117.4(3) ?
    C1 C11 C12 . . 114.9(3) ?
    C1 C11 C12' . . 115.8(3) ?
    C1 C11 H11A . . 108.6 ?
    C12 C11 H11A . . 108.6 ?
    C12' C11 H11A . . 112.3 ?
    C1 C11 H11B . . 108.6 ?
    C12 C11 H11B . . 108.6 ?
    C12' C11 H11B . . 103.7 ?
    H11A C11 H11B . . 107.5 ?
    C13 C12 C11 . . 121.4(5) ?
    C13 C12 S11 . . 115.1(4) ?
    C11 C12 S11 . . 123.3(5) ?
    C15 S11 C12 . . 92.1(3) ?
    C12 C13 C14 . . 106.6(5) ?
    C12 C13 H13 . . 126.7 ?
    C14 C13 H13 . . 126.7 ?
    C15 C14 C13 . . 112.9(5) ?
    C15 C14 H14 . . 123.5 ?
    C13 C14 H14 . . 123.5 ?
    C14 C15 S11 . . 113.1(4) ?
    C14 C15 H15 . . 123.4 ?
    S11 C15 H15 . . 123.4 ?
    C13' C12' C11 . . 119.7(12) ?
    C13' C12' S11' . . 113.1(8) ?
    C11 C12' S11' . . 127.1(11) ?
    C15' S11' C12' . . 94.1(6) ?
    C12' C13' C14' . . 107.5(10) ?
    C12' C13' H13' . . 126.3 ?
    C14' C13' H13' . . 126.3 ?
    C15' C14' C13' . . 113.4(11) ?
    C15' C14' H14' . . 123.3 ?
    C13' C14' H14' . . 123.3 ?
    C14' C15' S11' . . 112.0(9) ?
    C14' C15' H15' . . 124.0 ?
    S11' C15' H15' . . 124.0 ?
    C25 C24 C23 . . 119.9(4) ?
    C25 C24 H24 . . 120.1 ?
    C23 C24 H24 . . 120.1 ?
    C37 C38 C33 . . 120.5(4) ?
    C37 C38 H38 . . 119.8 ?
    C33 C38 H38 . . 119.8 ?
    C26 C25 C24 . . 120.9(4) ?
    C26 C25 Cl22 . . 119.1(4) ?
    C24 C25 Cl22 . . 119.9(4) ?
    C24 C23 C22 . . 121.3(4) ?
    C24 C23 H23 . . 119.3 ?
    C22 C23 H23 . . 119.3 ?
    C36 C37 C38 . . 120.5(5) ?
    C36 C37 H37 . . 119.8 ?
    C38 C37 H37 . . 119.8 ?
    C36 C35 C34 . . 120.7(5) ?
    C36 C35 H35 . . 119.6 ?
    C34 C35 H35 . . 119.6 ?
    C33 C34 C35 . . 119.9(5) ?
    C33 C34 H34 . . 120.0 ?
    C35 C34 H34 . . 120.0 ?
    C35 C36 C37 . . 119.7(5) ?
    C35 C36 H36 . . 120.2 ?
    C37 C36 H36 . . 120.2 ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    C21 H21 O21 . 0.93 2.231 2.916(4) 130 yes
    C13 H13 O21 3_456 0.93 2.532 3.355(7) 148 yes
