##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
catena-Poly[[aqua[(2,4-dichlorophenoxy)acetato]neodymium(III)]-di-μ-\
(2,4-dichlorophenoxy)acetato]
;
_chemical_name_common     ?
_chemical_formula_moiety     'C24 H17 Cl6 Nd O10'
_chemical_formula_sum     'C24 H17 Cl6 Nd O10'
_chemical_formula_iupac     '[Nd (C8 H5 Cl2 O3)3 (H2 O)]'
_chemical_formula_weight     822.32
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/c'
_symmetry_space_group_name_Hall     '-P 2ybc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     10.1801(2)
_cell_length_b     35.4768(6)
_cell_length_c     8.1456(2)
_cell_angle_alpha     90.00
_cell_angle_beta     97.1440(10)
_cell_angle_gamma     90.00
_cell_volume     2919.00(10)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     8000
_cell_measurement_theta_min     1.66
_cell_measurement_theta_max     26.00
_cell_measurement_temperature     293(2)
_exptl_crystal_description     platelet
_exptl_crystal_colour     purple
_exptl_crystal_size_max     0.25
_exptl_crystal_size_mid     0.20
_exptl_crystal_size_min     0.20
_exptl_crystal_density_diffrn     1.871
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1612
_exptl_absorpt_coefficient_mu     2.382
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min     0.566
_exptl_absorpt_correction_T_max     0.626
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     31522
_diffrn_reflns_av_R_equivalents     0.0378
_diffrn_reflns_av_sigmaI/netI     0.0274
_diffrn_reflns_theta_min     1.15
_diffrn_reflns_theta_max     26.00
_diffrn_reflns_theta_full     26.00
_diffrn_measured_fraction_theta_max     0.982
_diffrn_measured_fraction_theta_full     0.982
_diffrn_reflns_limit_h_min     -12
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -43
_diffrn_reflns_limit_k_max     43
_diffrn_reflns_limit_l_min     -10
_diffrn_reflns_limit_l_max     8
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     5617
_reflns_number_gt     5062
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0367
_refine_ls_R_factor_gt     0.0310
_refine_ls_wR_factor_gt     0.0774
_refine_ls_wR_factor_ref     0.0875
_refine_ls_goodness_of_fit_ref     1.234
_refine_ls_restrained_S_all     1.234
_refine_ls_number_reflns     5617
_refine_ls_number_parameters     370
_refine_ls_number_restraints     3
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0401P)²+2.8846P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.738
_refine_diff_density_min     -1.538
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Nd' 'Nd' -0.1943 3.0179
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEXII (Bruker, 2004)'
_computing_cell_refinement     'SAINT (Bruker, 2004)'
_computing_data_reduction     SAINT
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'SHELXTL (Bruker, 2004)'
_computing_publication_material     'SHELXTL'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C1 0.2331(3) 0.23189(10) 0.4591(5) 0.0211(8) Uani d . 1 . .
    C C2 0.1116(4) 0.22703(12) 0.3335(5) 0.0310(9) Uani d . 1 . .
    H H2A 0.0752 0.2516 0.3022 0.037 Uiso calc R 1 . .
    H H2B 0.1370 0.2151 0.2350 0.037 Uiso calc R 1 . .
    C C3 0.0273(4) 0.16667(11) 0.3963(5) 0.0284(8) Uani d . 1 . .
    C C4 0.1374(4) 0.14754(13) 0.3584(6) 0.0456(12) Uani d . 1 . .
    H H4 0.2118 0.1609 0.3359 0.055 Uiso calc R 1 . .
    C C5 0.1378(5) 0.10843(14) 0.3535(8) 0.0592(15) Uani d . 1 . .
    H H5 0.2119 0.0957 0.3260 0.071 Uiso calc R 1 . .
    C C6 0.0302(5) 0.08870(13) 0.3888(8) 0.0546(13) Uani d . 1 . .
    C C7 -0.0803(4) 0.10688(13) 0.4312(7) 0.0470(12) Uani d . 1 . .
    H H7 -0.1530 0.0932 0.4570 0.056 Uiso calc R 1 . .
    C C8 -0.0809(4) 0.14578(12) 0.4346(5) 0.0337(9) Uani d . 1 . .
    C C9 0.7044(3) 0.22777(10) 0.9310(5) 0.0234(8) Uani d . 1 . .
    C C10 0.8244(4) 0.22184(12) 1.0600(5) 0.0300(9) Uani d . 1 . .
    H H10A 0.8602 0.2462 1.0970 0.036 Uiso calc R 1 . .
    H H10B 0.7969 0.2089 1.1550 0.036 Uiso calc R 1 . .
    C C11 0.9044(4) 0.16244(11) 0.9735(5) 0.0298(9) Uani d . 1 . .
    C C12 0.7919(4) 0.14320(13) 1.0026(6) 0.0422(11) Uani d . 1 . .
    H H12 0.7219 0.1563 1.0389 0.051 Uiso calc R 1 . .
    C C13 0.7817(5) 0.10486(15) 0.9785(7) 0.0569(14) Uani d . 1 . .
    H H13 0.7057 0.0923 1.0003 0.068 Uiso calc R 1 . .
    C C14 0.8829(6) 0.08520(14) 0.9227(8) 0.0597(15) Uani d . 1 . .
    C C15 0.9975(5) 0.10342(14) 0.8931(7) 0.0536(13) Uani d . 1 . .
    H H15 1.0669 0.0900 0.8569 0.064 Uiso calc R 1 . .
    C C16 1.0074(4) 0.14191(13) 0.9182(6) 0.0400(10) Uani d . 1 . .
    C C17 0.4793(3) 0.15799(11) 0.6587(5) 0.0292(9) Uani d . 1 . .
    C C18 0.5042(5) 0.11663(12) 0.6386(6) 0.0456(11) Uani d . 1 . .
    H H18A 0.5941 0.1105 0.6851 0.055 Uiso calc R 1 . .
    H H18B 0.4440 0.1021 0.6972 0.055 Uiso calc R 1 . .
    C C19 0.5380(4) 0.07433(12) 0.4211(6) 0.0426(11) Uani d . 1 . .
    C C20 0.6068(5) 0.04845(12) 0.5265(7) 0.0518(13) Uani d . 1 . .
    H H20 0.6182 0.0528 0.6399 0.062 Uiso calc R 1 . .
    C C21 0.6589(5) 0.01595(14) 0.4636(9) 0.0635(16) Uani d . 1 . .
    H H21 0.7055 -0.0012 0.5348 0.076 Uiso calc R 1 . .
    C C22 0.6413(6) 0.00947(13) 0.2979(9) 0.0632(16) Uani d . 1 . .
    C C23 0.5724(6) 0.03446(14) 0.1902(8) 0.0604(15) Uani d . 1 . .
    H H23 0.5605 0.0297 0.0770 0.072 Uiso calc R 1 . .
    C C24 0.5212(5) 0.06667(13) 0.2532(7) 0.0493(12) Uani d . 1 . .
    Cl Cl1 -0.21982(12) 0.16884(4) 0.4836(2) 0.0636(4) Uani d . 1 . .
    Cl Cl2 0.02712(19) 0.03967(4) 0.3748(3) 0.1027(7) Uani d . 1 . .
    Cl Cl3 1.15126(13) 0.16473(4) 0.8836(2) 0.0710(4) Uani d . 1 . .
    Cl Cl4 0.8703(2) 0.03676(4) 0.8933(3) 0.1017(7) Uani d . 1 . .
    Cl Cl5 0.43592(16) 0.09847(4) 0.11576(19) 0.0678(4) Uani d . 1 . .
    Cl Cl6 0.7043(2) -0.03135(4) 0.2194(3) 0.1014(7) Uani d . 1 . .
    Nd Nd1 0.469125(17) 0.237244(5) 0.69698(2) 0.01875(8) Uani d . 1 . .
    O O1 0.2348(2) 0.21996(8) 0.6017(3) 0.0319(6) Uani d . 1 . .
    O O2 0.3345(2) 0.24889(8) 0.4157(3) 0.0265(6) Uani d . 1 . .
    O O3 0.0130(2) 0.20488(7) 0.3960(4) 0.0309(6) Uani d . 1 . .
    O O4 0.6009(3) 0.24198(8) 0.9835(3) 0.0290(4) Uani d . 1 . .
    O O5 0.7074(2) 0.22086(8) 0.7852(3) 0.0290(4) Uani d . 1 . .
    O O6 0.9254(2) 0.20022(8) 0.9956(3) 0.0318(6) Uani d . 1 . .
    O O7 0.4680(3) 0.17038(8) 0.8010(4) 0.0334(6) Uani d . 1 . .
    O O8 0.4773(3) 0.17940(7) 0.5340(3) 0.0320(6) Uani d . 1 . .
    O O9 0.4849(3) 0.10728(8) 0.4683(4) 0.0457(8) Uani d . 1 . .
    O O1W 0.4630(4) 0.30741(9) 0.7056(4) 0.0515(9) Uani d D 1 . .
    H H1W 0.469(6) 0.3196(12) 0.790(3) 0.062 Uiso d D 1 . .
    H H2W 0.459(6) 0.3203(12) 0.623(3) 0.062 Uiso d D 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 O1 . 1.235(5) ?
    C1 O2 . 1.282(4) ?
    C1 C2 . 1.514(5) ?
    C2 O3 . 1.418(4) ?
    C2 H2A . 0.9700 ?
    C2 H2B . 0.9700 ?
    C3 O3 . 1.364(5) ?
    C3 C4 . 1.378(6) ?
    C3 C8 . 1.394(5) ?
    C4 C5 . 1.388(7) ?
    C4 H4 . 0.9300 ?
    C5 C6 . 1.361(7) ?
    C5 H5 . 0.9300 ?
    C6 C7 . 1.377(7) ?
    C6 Cl2 . 1.743(5) ?
    C7 C8 . 1.380(6) ?
    C7 H7 . 0.9300 ?
    C8 Cl1 . 1.724(4) ?
    C9 O5 . 1.217(5) ?
    C9 O4 . 1.288(4) ?
    C9 C10 . 1.524(5) ?
    C10 O6 . 1.434(4) ?
    C10 H10A . 0.9700 ?
    C10 H10B . 0.9700 ?
    C11 O6 . 1.366(5) ?
    C11 C12 . 1.379(6) ?
    C11 C16 . 1.396(6) ?
    C12 C13 . 1.376(7) ?
    C12 H12 . 0.9300 ?
    C13 C14 . 1.367(8) ?
    C13 H13 . 0.9300 ?
    C14 C15 . 1.381(8) ?
    C14 Cl4 . 1.737(5) ?
    C15 C16 . 1.382(7) ?
    C15 H15 . 0.9300 ?
    C16 Cl3 . 1.727(5) ?
    C17 O7 . 1.258(5) ?
    C17 O8 . 1.266(5) ?
    C17 C18 . 1.501(6) ?
    C18 O9 . 1.416(6) ?
    C18 H18A . 0.9700 ?
    C18 H18B . 0.9700 ?
    C19 O9 . 1.363(5) ?
    C19 C24 . 1.384(7) ?
    C19 C20 . 1.386(7) ?
    C20 C21 . 1.393(7) ?
    C20 H20 . 0.9300 ?
    C21 C22 . 1.359(9) ?
    C21 H21 . 0.9300 ?
    C22 C23 . 1.376(8) ?
    C22 Cl6 . 1.738(5) ?
    C23 C24 . 1.381(7) ?
    C23 H23 . 0.9300 ?
    C24 Cl5 . 1.743(6) ?
    Nd1 O2 4_566 2.430(3) Y
    Nd1 O4 4_565 2.439(3) Y
    Nd1 O8 . 2.451(3) Y
    Nd1 O1W . 2.491(3) Y
    Nd1 O1 . 2.492(2) Y
    Nd1 O5 . 2.511(2) Y
    Nd1 O7 . 2.519(3) Y
    Nd1 O4 . 2.549(3) Y
    Nd1 O2 . 2.553(3) Y
    O2 Nd1 4_565 2.430(3) ?
    O4 Nd1 4_566 2.439(3) ?
    O1W H1W . 0.811(19) ?
    O1W H2W . 0.807(19) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 C1 O2 . . 120.2(3) ?
    O1 C1 C2 . . 120.8(3) ?
    O2 C1 C2 . . 119.0(3) ?
    O3 C2 C1 . . 112.1(3) ?
    O3 C2 H2A . . 109.2 ?
    C1 C2 H2A . . 109.2 ?
    O3 C2 H2B . . 109.2 ?
    C1 C2 H2B . . 109.2 ?
    H2A C2 H2B . . 107.9 ?
    O3 C3 C4 . . 125.4(4) ?
    O3 C3 C8 . . 116.2(3) ?
    C4 C3 C8 . . 118.4(4) ?
    C3 C4 C5 . . 120.3(4) ?
    C3 C4 H4 . . 119.9 ?
    C5 C4 H4 . . 119.9 ?
    C6 C5 C4 . . 120.2(4) ?
    C6 C5 H5 . . 119.9 ?
    C4 C5 H5 . . 119.9 ?
    C5 C6 C7 . . 121.1(4) ?
    C5 C6 Cl2 . . 120.5(4) ?
    C7 C6 Cl2 . . 118.4(4) ?
    C6 C7 C8 . . 118.6(4) ?
    C6 C7 H7 . . 120.7 ?
    C8 C7 H7 . . 120.7 ?
    C7 C8 C3 . . 121.4(4) ?
    C7 C8 Cl1 . . 119.0(3) ?
    C3 C8 Cl1 . . 119.6(3) ?
    O5 C9 O4 . . 121.6(3) ?
    O5 C9 C10 . . 122.0(3) ?
    O4 C9 C10 . . 116.3(3) ?
    O6 C10 C9 . . 111.8(3) ?
    O6 C10 H10A . . 109.3 ?
    C9 C10 H10A . . 109.3 ?
    O6 C10 H10B . . 109.3 ?
    C9 C10 H10B . . 109.3 ?
    H10A C10 H10B . . 107.9 ?
    O6 C11 C12 . . 125.6(4) ?
    O6 C11 C16 . . 116.3(4) ?
    C12 C11 C16 . . 118.1(4) ?
    C13 C12 C11 . . 120.9(4) ?
    C13 C12 H12 . . 119.5 ?
    C11 C12 H12 . . 119.5 ?
    C14 C13 C12 . . 120.3(5) ?
    C14 C13 H13 . . 119.8 ?
    C12 C13 H13 . . 119.8 ?
    C13 C14 C15 . . 120.4(5) ?
    C13 C14 Cl4 . . 120.3(5) ?
    C15 C14 Cl4 . . 119.2(4) ?
    C14 C15 C16 . . 119.0(5) ?
    C14 C15 H15 . . 120.5 ?
    C16 C15 H15 . . 120.5 ?
    C15 C16 C11 . . 121.3(4) ?
    C15 C16 Cl3 . . 119.1(4) ?
    C11 C16 Cl3 . . 119.6(3) ?
    O7 C17 O8 . . 122.3(4) ?
    O7 C17 C18 . . 118.6(4) ?
    O8 C17 C18 . . 119.0(4) ?
    O9 C18 C17 . . 109.3(4) ?
    O9 C18 H18A . . 109.8 ?
    C17 C18 H18A . . 109.8 ?
    O9 C18 H18B . . 109.8 ?
    C17 C18 H18B . . 109.8 ?
    H18A C18 H18B . . 108.3 ?
    O9 C19 C24 . . 116.3(4) ?
    O9 C19 C20 . . 125.6(5) ?
    C24 C19 C20 . . 118.2(4) ?
    C19 C20 C21 . . 120.5(5) ?
    C19 C20 H20 . . 119.8 ?
    C21 C20 H20 . . 119.8 ?
    C22 C21 C20 . . 119.7(5) ?
    C22 C21 H21 . . 120.1 ?
    C20 C21 H21 . . 120.1 ?
    C21 C22 C23 . . 121.2(5) ?
    C21 C22 Cl6 . . 119.8(5) ?
    C23 C22 Cl6 . . 119.0(5) ?
    C22 C23 C24 . . 118.8(6) ?
    C22 C23 H23 . . 120.6 ?
    C24 C23 H23 . . 120.6 ?
    C23 C24 C19 . . 121.6(5) ?
    C23 C24 Cl5 . . 118.5(5) ?
    C19 C24 Cl5 . . 119.9(4) ?
    O2 Nd1 O4 4_566 4_565 150.72(10) ?
    O2 Nd1 O8 4_566 . 128.82(9) ?
    O4 Nd1 O8 4_565 . 78.94(9) ?
    O2 Nd1 O1W 4_566 . 76.03(11) ?
    O4 Nd1 O1W 4_565 . 74.69(11) ?
    O8 Nd1 O1W . . 148.70(10) Y
    O2 Nd1 O1 4_566 . 70.88(9) ?
    O4 Nd1 O1 4_565 . 116.28(9) ?
    O8 Nd1 O1 . . 73.80(9) Y
    O1W Nd1 O1 . . 103.20(11) Y
    O2 Nd1 O5 4_566 . 116.76(8) ?
    O4 Nd1 O5 4_565 . 71.11(9) ?
    O8 Nd1 O5 . . 82.21(9) Y
    O1W Nd1 O5 . . 104.47(11) Y
    O1 Nd1 O5 . . 152.33(10) Y
    O2 Nd1 O7 4_566 . 85.27(9) ?
    O4 Nd1 O7 4_565 . 123.39(9) ?
    O8 Nd1 O7 . . 52.82(9) Y
    O1W Nd1 O7 . . 158.46(10) Y
    O1 Nd1 O7 . . 80.13(9) Y
    O5 Nd1 O7 . . 74.37(9) Y
    O2 Nd1 O4 4_566 . 66.17(8) ?
    O4 Nd1 O4 4_565 . 111.05(9) ?
    O8 Nd1 O4 . . 120.11(9) Y
    O1W Nd1 O4 . . 85.44(10) Y
    O1 Nd1 O4 . . 132.52(9) Y
    O5 Nd1 O4 . . 51.21(8) Y
    O7 Nd1 O4 . . 77.18(9) Y
    O2 Nd1 O2 4_566 . 109.66(8) ?
    O4 Nd1 O2 4_565 . 65.98(8) ?
    O8 Nd1 O2 . . 72.55(9) Y
    O1W Nd1 O2 . . 81.43(10) Y
    O1 Nd1 O2 . . 51.24(8) Y
    O5 Nd1 O2 . . 133.31(8) Y
    O7 Nd1 O2 . . 115.44(9) Y
    O4 Nd1 O2 . . 166.86(9) Y
    C1 O1 Nd1 . . 96.3(2) Y
    C1 O2 Nd1 . 4_565 147.6(2) ?
    C1 O2 Nd1 . . 92.1(2) ?
    Nd1 O2 Nd1 4_565 . 113.70(9) ?
    C3 O3 C2 . . 118.1(3) ?
    C9 O4 Nd1 . 4_566 154.2(2) ?
    C9 O4 Nd1 . . 91.6(2) ?
    Nd1 O4 Nd1 4_566 . 113.52(10) ?
    C9 O5 Nd1 . . 95.3(2) ?
    C11 O6 C10 . . 117.8(3) ?
    C17 O7 Nd1 . . 90.8(2) ?
    C17 O8 Nd1 . . 93.8(2) ?
    C19 O9 C18 . . 117.7(4) ?
    Nd1 O1W H1W . . 124(3) ?
    Nd1 O1W H2W . . 123(3) ?
    H1W O1W H2W . . 113(3) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O1 C1 C2 O3 . . . . -5.7(5) ?
    O2 C1 C2 O3 . . . . 174.8(3) ?
    O3 C3 C4 C5 . . . . -176.3(5) ?
    C8 C3 C4 C5 . . . . 2.1(7) ?
    C3 C4 C5 C6 . . . . -1.1(9) ?
    C4 C5 C6 C7 . . . . -0.5(9) ?
    C4 C5 C6 Cl2 . . . . 177.4(5) ?
    C5 C6 C7 C8 . . . . 1.1(9) ?
    Cl2 C6 C7 C8 . . . . -176.9(4) ?
    C6 C7 C8 C3 . . . . 0.0(8) ?
    C6 C7 C8 Cl1 . . . . 178.8(4) ?
    O3 C3 C8 C7 . . . . 176.9(4) ?
    C4 C3 C8 C7 . . . . -1.6(7) ?
    O3 C3 C8 Cl1 . . . . -1.8(5) ?
    C4 C3 C8 Cl1 . . . . 179.7(3) ?
    O5 C9 C10 O6 . . . . -12.6(5) ?
    O4 C9 C10 O6 . . . . 170.1(3) ?
    O6 C11 C12 C13 . . . . -179.0(4) ?
    C16 C11 C12 C13 . . . . 0.3(7) ?
    C11 C12 C13 C14 . . . . -1.0(8) ?
    C12 C13 C14 C15 . . . . 1.3(9) ?
    C12 C13 C14 Cl4 . . . . 179.7(4) ?
    C13 C14 C15 C16 . . . . -1.0(8) ?
    Cl4 C14 C15 C16 . . . . -179.4(4) ?
    C14 C15 C16 C11 . . . . 0.4(8) ?
    C14 C15 C16 Cl3 . . . . 179.3(4) ?
    O6 C11 C16 C15 . . . . 179.3(4) ?
    C12 C11 C16 C15 . . . . 0.0(7) ?
    O6 C11 C16 Cl3 . . . . 0.5(5) ?
    C12 C11 C16 Cl3 . . . . -178.9(3) ?
    O7 C17 C18 O9 . . . . 167.3(3) ?
    O8 C17 C18 O9 . . . . -16.3(5) ?
    O9 C19 C20 C21 . . . . -178.8(4) ?
    C24 C19 C20 C21 . . . . 0.9(7) ?
    C19 C20 C21 C22 . . . . -0.5(8) ?
    C20 C21 C22 C23 . . . . -0.1(8) ?
    C20 C21 C22 Cl6 . . . . -179.2(4) ?
    C21 C22 C23 C24 . . . . 0.3(8) ?
    Cl6 C22 C23 C24 . . . . 179.3(4) ?
    C22 C23 C24 C19 . . . . 0.2(8) ?
    C22 C23 C24 Cl5 . . . . 179.2(4) ?
    O9 C19 C24 C23 . . . . 178.9(4) ?
    C20 C19 C24 C23 . . . . -0.8(7) ?
    O9 C19 C24 Cl5 . . . . 0.0(6) ?
    C20 C19 C24 Cl5 . . . . -179.7(4) ?
    O2 C1 O1 Nd1 . . . . -3.9(4) ?
    C2 C1 O1 Nd1 . . . . 176.7(3) ?
    O2 Nd1 O1 C1 4_566 . . . 139.4(2) ?
    O4 Nd1 O1 C1 4_565 . . . -9.7(3) ?
    O8 Nd1 O1 C1 . . . . -78.2(2) ?
    O1W Nd1 O1 C1 . . . . 69.5(2) ?
    O5 Nd1 O1 C1 . . . . -109.2(3) ?
    O7 Nd1 O1 C1 . . . . -132.2(2) ?
    O4 Nd1 O1 C1 . . . . 165.5(2) ?
    O2 Nd1 O1 C1 . . . . 2.1(2) ?
    O1 C1 O2 Nd1 . . . 4_565 147.7(3) ?
    C2 C1 O2 Nd1 . . . 4_565 -32.8(6) ?
    O1 C1 O2 Nd1 . . . . 3.7(4) ?
    C2 C1 O2 Nd1 . . . . -176.8(3) ?
    O2 Nd1 O2 C1 4_566 . . . -44.94(17) ?
    O4 Nd1 O2 C1 4_565 . . . 166.3(2) ?
    O8 Nd1 O2 C1 . . . . 80.9(2) ?
    O1W Nd1 O2 C1 . . . . -116.7(2) ?
    O1 Nd1 O2 C1 . . . . -2.06(19) ?
    O5 Nd1 O2 C1 . . . . 141.5(2) ?
    O7 Nd1 O2 C1 . . . . 49.2(2) ?
    O4 Nd1 O2 C1 . . . . -114.0(4) ?
    O2 Nd1 O2 Nd1 4_566 . . 4_565 155.20(14) ?
    O4 Nd1 O2 Nd1 4_565 . . 4_565 6.46(9) ?
    O8 Nd1 O2 Nd1 . . . 4_565 -78.96(12) ?
    O1W Nd1 O2 Nd1 . . . 4_565 83.44(13) ?
    O1 Nd1 O2 Nd1 . . . 4_565 -161.91(17) ?
    O5 Nd1 O2 Nd1 . . . 4_565 -18.41(18) ?
    O7 Nd1 O2 Nd1 . . . 4_565 -110.62(11) ?
    O4 Nd1 O2 Nd1 . . . 4_565 86.1(3) ?
    C4 C3 O3 C2 . . . . 7.8(6) ?
    C8 C3 O3 C2 . . . . -170.5(3) ?
    C1 C2 O3 C3 . . . . -79.9(4) y
    O5 C9 O4 Nd1 . . . 4_566 173.1(4) ?
    C10 C9 O4 Nd1 . . . 4_566 -9.7(7) ?
    O5 C9 O4 Nd1 . . . . 5.1(4) ?
    C10 C9 O4 Nd1 . . . . -177.7(3) ?
    O2 Nd1 O4 C9 4_566 . . . 167.9(2) ?
    O4 Nd1 O4 C9 4_565 . . . -43.72(17) ?
    O8 Nd1 O4 C9 . . . . 45.5(2) ?
    O1W Nd1 O4 C9 . . . . -115.4(2) ?
    O1 Nd1 O4 C9 . . . . 140.9(2) ?
    O5 Nd1 O4 C9 . . . . -2.70(19) ?
    O7 Nd1 O4 C9 . . . . 77.4(2) ?
    O2 Nd1 O4 C9 . . . . -118.1(3) ?
    O2 Nd1 O4 Nd1 4_566 . . 4_566 -6.45(9) ?
    O4 Nd1 O4 Nd1 4_565 . . 4_566 141.95(15) ?
    O8 Nd1 O4 Nd1 . . . 4_566 -128.87(11) ?
    O1W Nd1 O4 Nd1 . . . 4_566 70.29(13) ?
    O1 Nd1 O4 Nd1 . . . 4_566 -33.46(18) ?
    O5 Nd1 O4 Nd1 . . . 4_566 -177.03(17) ?
    O7 Nd1 O4 Nd1 . . . 4_566 -96.91(12) ?
    O2 Nd1 O4 Nd1 . . . 4_566 67.6(4) ?
    O4 C9 O5 Nd1 . . . . -5.2(4) ?
    C10 C9 O5 Nd1 . . . . 177.7(3) ?
    O2 Nd1 O5 C9 4_566 . . . -6.8(2) ?
    O4 Nd1 O5 C9 4_565 . . . 142.5(2) ?
    O8 Nd1 O5 C9 . . . . -136.6(2) ?
    O1W Nd1 O5 C9 . . . . 74.6(2) ?
    O1 Nd1 O5 C9 . . . . -106.7(3) ?
    O7 Nd1 O5 C9 . . . . -83.1(2) ?
    O4 Nd1 O5 C9 . . . . 2.9(2) ?
    O2 Nd1 O5 C9 . . . . 166.5(2) ?
    C12 C11 O6 C10 . . . . 2.3(6) ?
    C16 C11 O6 C10 . . . . -177.0(4) ?
    C9 C10 O6 C11 . . . . -73.9(4) y
    O8 C17 O7 Nd1 . . . . -4.8(4) ?
    C18 C17 O7 Nd1 . . . . 171.5(3) ?
    O2 Nd1 O7 C17 4_566 . . . 151.1(2) ?
    O4 Nd1 O7 C17 4_565 . . . -35.4(2) ?
    O8 Nd1 O7 C17 . . . . 2.6(2) ?
    O1W Nd1 O7 C17 . . . . -179.3(3) ?
    O1 Nd1 O7 C17 . . . . 79.7(2) ?
    O5 Nd1 O7 C17 . . . . -89.4(2) ?
    O4 Nd1 O7 C17 . . . . -142.3(2) ?
    O2 Nd1 O7 C17 . . . . 41.6(2) ?
    O7 C17 O8 Nd1 . . . . 4.9(4) ?
    C18 C17 O8 Nd1 . . . . -171.4(3) ?
    O2 Nd1 O8 C17 4_566 . . . -44.6(2) ?
    O4 Nd1 O8 C17 4_565 . . . 145.8(2) ?
    O1W Nd1 O8 C17 . . . . 178.8(2) ?
    O1 Nd1 O8 C17 . . . . -92.4(2) ?
    O5 Nd1 O8 C17 . . . . 73.7(2) ?
    O7 Nd1 O8 C17 . . . . -2.6(2) ?
    O4 Nd1 O8 C17 . . . . 37.8(2) ?
    O2 Nd1 O8 C17 . . . . -146.1(2) ?
    C24 C19 O9 C18 . . . . -177.9(4) ?
    C20 C19 O9 C18 . . . . 1.8(6) ?
    C17 C18 O9 C19 . . . . 161.7(4) y
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    O1W H1W O8 4_566 0.811(19) 1.98(3) 2.702(4) 148(4)
    O1W H2W Cl5 4_566 0.807(19) 2.89(4) 3.422(4) 125(4)
    O1W H2W O7 4_565 0.807(19) 2.66(2) 3.395(5) 152(4)
data_global
_journal_date_recd_electronic     2007-04-25
_journal_date_accepted     2007-05-01
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      6
_journal_page_first     m1595
_journal_page_last     m1595
_journal_paper_category     QM
_journal_coeditor_code     ZL2021
_publ_contact_author_name     'Wei-Jun, Liang'
_publ_contact_author_address
;
Department of Cardiology, Guang Dong Medical College,
Zhan jiang 524023
P.R. China
;
_publ_contact_author_email     liangwj60@126.com
_publ_contact_author_fax     '86 0759 2383636'
_publ_contact_author_phone     '86 0 13902507873'
_publ_section_title
;\
catena-Poly[[aqua[(2,4-dichlorophenoxy)acetato]neodymium(III)]-di-μ-\
(2,4-dichlorophenoxy)acetato]
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Jian Guo' .
;
Department of Cardiology, Guang Dong Medical College,
Zhanjiang 524023
People's Republic of China
;
    'Wei-Jun Liang' .
;
Department of Cardiology, Guang Dong Medical College,
Zhanjiang 524023
People's Republic of China
;
    'Wen-Dong Song' .
;
College of Science
Guang Dong Ocean University
Zhanjiang 524088
People's Republic of China
;
