##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
{2,6-Bis[(dimethylamino-κ²N,N')methyl]-4-{[(2,5-dioxo-1-pyrrolidinyl)oxy]
carbonyl}phenyl-\kC}(diiodine)iodoplatinum(II) dichloromethane hemisolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C17 H22 I3 N3 O4 Pt , 0.5C H2 Cl2'
_chemical_formula_sum     'C17.50 H23 Cl I3 N3 O4 Pt'
_chemical_formula_iupac     '[Pt I (C17 H22 N3 O4) (I2)] , 0.5C H2 Cl2'
_chemical_formula_weight     950.63
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     8.70120(10)
_cell_length_b     15.1862(2)
_cell_length_c     19.8391(4)
_cell_angle_alpha     99.2137(14)
_cell_angle_beta     90.7250(15)
_cell_angle_gamma     103.7589(13)
_cell_volume     2509.90(7)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     102
_cell_measurement_theta_min     2.46
_cell_measurement_theta_max     22.13
_cell_measurement_temperature     150(2)
_exptl_crystal_description     needle
_exptl_crystal_colour     'dark red'
_exptl_crystal_size_max     0.42
_exptl_crystal_size_mid     0.09
_exptl_crystal_size_min     0.06
_exptl_crystal_density_diffrn     2.516
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1740
_exptl_absorpt_coefficient_mu     9.414
_exptl_absorpt_correction_type     analytical
_exptl_absorpt_process_details     '(de Meulenaer & Tompa, 1965)'
_exptl_absorpt_correction_T_min     0.14
_exptl_absorpt_correction_T_max     0.63
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     150(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'rotating anode'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Nonius KappaCCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     35716
_diffrn_reflns_av_R_equivalents     0.0359
_diffrn_reflns_av_sigmaI/netI     0.0516
_diffrn_reflns_theta_min     1.60
_diffrn_reflns_theta_max     27.50
_diffrn_reflns_theta_full     27.50
_diffrn_measured_fraction_theta_max     0.993
_diffrn_measured_fraction_theta_full     0.993
_diffrn_reflns_limit_h_min     -11
_diffrn_reflns_limit_h_max     11
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     19
_diffrn_reflns_limit_l_min     0
_diffrn_reflns_limit_l_max     25
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     11455
_reflns_number_gt     8859
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0365
_refine_ls_R_factor_gt     0.0236
_refine_ls_wR_factor_gt     0.0482
_refine_ls_wR_factor_ref     0.0536
_refine_ls_goodness_of_fit_ref     0.944
_refine_ls_restrained_S_all     0.946
_refine_ls_number_reflns     11455
_refine_ls_number_parameters     511
_refine_ls_number_restraints     162
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details     'calc w = 1/[σ²(Fo²)]'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.002
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     3.033
_refine_diff_density_min     -3.345
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'I' 'I' -0.4742 1.8119
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'COLLECT (Nonius, 1999)'
_computing_cell_refinement     'DIRAX (Duisenberg, 1992)'
_computing_data_reduction
;
EVALCCD (Duisenberg et al.,  2003) and SORTAV (Blessing,
1987)
;
_computing_structure_solution     'DIRDIF97 (Beurskens et al.,  1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'PLATON (Spek, 2003)'
_computing_publication_material     'manual editing of the SHELXL97 output'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Pt Pt1 0.403218(19) 0.509735(11) 0.301129(8) 0.01628(4) Uani d . 1 . .
    I I11 0.46577(4) 0.64528(2) 0.226128(17) 0.02933(7) Uani d . 1 . .
    I I21 0.22390(3) 0.580499(19) 0.404745(14) 0.02004(6) Uani d . 1 . .
    I I31 0.05150(4) 0.64807(2) 0.513372(15) 0.02557(7) Uani d . 1 . .
    N N11 0.6181(4) 0.5521(2) 0.36047(18) 0.0205(8) Uani d . 1 . .
    N N21 0.2035(4) 0.4249(2) 0.24287(18) 0.0195(8) Uani d . 1 . .
    O O11 0.4516(4) 0.1589(2) 0.47396(18) 0.0340(8) Uani d D 1 . .
    O O21 0.2112(4) 0.1018(2) 0.41800(16) 0.0285(8) Uani d D 1 . .
    O O31 0.1488(5) 0.0646(3) 0.55085(18) 0.0399(9) Uani d D 1 . .
    O O41 0.2943(5) -0.0461(3) 0.34078(18) 0.0409(9) Uani d D 1 . .
    N N31 0.2158(5) 0.0219(2) 0.44179(18) 0.0273(9) Uani d D 1 . .
    C C11 0.3743(5) 0.4058(3) 0.3494(2) 0.0168(9) Uani d D 1 . .
    C C21 0.4885(5) 0.4067(3) 0.3988(2) 0.0180(9) Uani d D 1 . .
    C C31 0.4782(5) 0.3282(3) 0.4271(2) 0.0202(9) Uani d D 1 . .
    H H31 0.5585 0.3253 0.4590 0.024 Uiso calc R 1 . .
    C C41 0.3487(5) 0.2535(3) 0.4084(2) 0.0192(9) Uani d D 1 . .
    C C51 0.2295(5) 0.2548(3) 0.3605(2) 0.0204(9) Uani d D 1 . .
    H H51 0.1417 0.2033 0.3486 0.024 Uiso calc R 1 . .
    C C61 0.2426(5) 0.3322(3) 0.3310(2) 0.0195(9) Uani d D 1 . .
    C C71 0.6065(5) 0.4972(3) 0.4188(2) 0.0222(10) Uani d D 1 . .
    H H71A 0.7114 0.4868 0.4296 0.027 Uiso calc R 1 . .
    H H71B 0.5731 0.5322 0.4602 0.027 Uiso calc R 1 . .
    C C81 0.7390(5) 0.5247(3) 0.3145(2) 0.0284(11) Uani d D 1 . .
    H H81A 0.7040 0.4591 0.2955 0.043 Uiso calc R 1 . .
    H H81B 0.8403 0.5366 0.3405 0.043 Uiso calc R 1 . .
    H H81C 0.7521 0.5606 0.2771 0.043 Uiso calc R 1 . .
    C C91 0.6728(5) 0.6518(3) 0.3891(2) 0.0265(10) Uani d D 1 . .
    H H91A 0.5939 0.6703 0.4194 0.040 Uiso calc R 1 . .
    H H91B 0.6863 0.6875 0.3517 0.040 Uiso calc R 1 . .
    H H91C 0.7741 0.6631 0.4151 0.040 Uiso calc R 1 . .
    C C101 0.1222(5) 0.3523(3) 0.2835(2) 0.0240(10) Uani d D 1 . .
    H H10A 0.0701 0.2953 0.2519 0.029 Uiso calc R 1 . .
    H H10B 0.0397 0.3742 0.3106 0.029 Uiso calc R 1 . .
    C C111 0.2680(6) 0.3783(3) 0.1813(2) 0.0287(11) Uani d D 1 . .
    H H11A 0.3486 0.3489 0.1959 0.043 Uiso calc R 1 . .
    H H11B 0.3158 0.4239 0.1530 0.043 Uiso calc R 1 . .
    H H11C 0.1819 0.3316 0.1547 0.043 Uiso calc R 1 . .
    C C121 0.0829(5) 0.4696(3) 0.2191(2) 0.0261(10) Uani d D 1 . .
    H H12A 0.0387 0.5004 0.2587 0.039 Uiso calc R 1 . .
    H H12B -0.0021 0.4229 0.1918 0.039 Uiso calc R 1 . .
    H H12C 0.1328 0.5150 0.1910 0.039 Uiso calc R 1 . .
    C C131 0.3506(5) 0.1700(3) 0.43748(16) 0.0241(10) Uani d D 1 . .
    C C141 0.1845(6) 0.0088(3) 0.5079(2) 0.0300(11) Uani d D 1 . .
    C C151 0.2005(7) -0.0872(3) 0.5113(3) 0.0391(13) Uani d D 1 . .
    H H15A 0.0990 -0.1258 0.5230 0.047 Uiso calc R 1 . .
    H H15B 0.2835 -0.0856 0.5464 0.047 Uiso calc R 1 . .
    C C161 0.2459(7) -0.1254(3) 0.4406(2) 0.0380(13) Uani d D 1 . .
    H H16A 0.3486 -0.1423 0.4436 0.046 Uiso calc R 1 . .
    H H16B 0.1641 -0.1806 0.4197 0.046 Uiso calc R 1 . .
    C C171 0.2579(6) -0.0497(3) 0.3989(2) 0.0287(11) Uani d D 1 . .
    Pt Pt2 0.642590(19) 1.053834(12) 0.207398(8) 0.01809(4) Uani d . 1 . .
    I I12 0.71756(4) 1.19710(3) 0.310314(18) 0.04301(10) Uani d . 1 A .
    I I22 0.87414(3) 1.10763(2) 0.114062(15) 0.02397(7) Uani d . 1 A .
    I I32 1.09867(4) 1.15734(3) 0.015155(17) 0.03413(8) Uani d . 1 . .
    N N12 0.4626(4) 1.0950(3) 0.1581(2) 0.0271(9) Uani d . 1 A .
    N N22 0.7647(5) 0.9690(3) 0.2481(2) 0.0295(9) Uani d . 1 A .
    O O12 0.2079(7) 0.6879(4) -0.0223(3) 0.0301(15) Uiso d PD 0.566(6) A 1
    O O22 0.4165(7) 0.6330(4) 0.0031(3) 0.0349(16) Uiso d PD 0.566(6) A 1
    O O32 0.3750(9) 0.5790(5) -0.1395(3) 0.0392(19) Uiso d PD 0.566(6) A 1
    O O42 0.2074(11) 0.5083(6) 0.0640(3) 0.053(2) Uiso d PD 0.566(6) A 1
    N N32 0.3302(8) 0.5499(4) -0.0328(3) 0.0294(18) Uiso d PD 0.566(6) A 1
    C C12 0.5611(13) 0.9447(5) 0.1372(5) 0.018(3) Uiso d PD 0.566(6) A 1
    C C22 0.4401(10) 0.9468(5) 0.0920(4) 0.016(2) Uiso d PD 0.566(6) A 1
    C C32 0.3683(9) 0.8658(5) 0.0489(4) 0.0196(18) Uiso d PD 0.566(6) A 1
    H H32 0.2797 0.8636 0.0196 0.023 Uiso calc PR 0.566(6) A 1
    C C42 0.4259(9) 0.7877(4) 0.0485(3) 0.0186(17) Uiso d PD 0.566(6) A 1
    C C52 0.5502(9) 0.7867(4) 0.0941(4) 0.0172(17) Uiso d PD 0.566(6) A 1
    H H52 0.5862 0.7324 0.0944 0.021 Uiso calc PR 0.566(6) A 1
    C C62 0.6187(10) 0.8668(5) 0.1384(4) 0.021(2) Uiso d PD 0.566(6) A 1
    C C72 0.4105(12) 1.0398(6) 0.0931(5) 0.024(3) Uiso d PD 0.566(6) A 1
    H H72A 0.4685 1.0691 0.0567 0.029 Uiso calc PR 0.566(6) A 1
    H H72B 0.2960 1.0341 0.0845 0.029 Uiso calc PR 0.566(6) A 1
    C C82 0.3309(17) 1.0891(9) 0.2079(6) 0.033(4) Uiso d PD 0.566(6) A 1
    H H82A 0.3719 1.1278 0.2518 0.049 Uiso calc PR 0.566(6) A 1
    H H82B 0.2919 1.0252 0.2145 0.049 Uiso calc PR 0.566(6) A 1
    H H82C 0.2440 1.1106 0.1894 0.049 Uiso calc PR 0.566(6) A 1
    C C92 0.5125(13) 1.1980(7) 0.1523(6) 0.027(3) Uiso d PD 0.566(6) A 1
    H H92A 0.5486 1.2344 0.1976 0.041 Uiso calc PR 0.566(6) A 1
    H H92B 0.4218 1.2170 0.1348 0.041 Uiso calc PR 0.566(6) A 1
    H H92C 0.5987 1.2081 0.1210 0.041 Uiso calc PR 0.566(6) A 1
    C C102 0.7626(10) 0.8850(6) 0.1868(4) 0.023(2) Uiso d PD 0.566(6) A 1
    H H10C 0.8597 0.8997 0.1611 0.028 Uiso calc PR 0.566(6) A 1
    H H10D 0.7626 0.8289 0.2062 0.028 Uiso calc PR 0.566(6) A 1
    C C112 0.6585(11) 0.9202(8) 0.2976(5) 0.023(3) Uiso d PD 0.566(6) A 1
    H H11D 0.5495 0.8996 0.2778 0.034 Uiso calc PR 0.566(6) A 1
    H H11E 0.6614 0.9625 0.3407 0.034 Uiso calc PR 0.566(6) A 1
    H H11F 0.6958 0.8669 0.3064 0.034 Uiso calc PR 0.566(6) A 1
    C C122 0.9239(10) 0.9999(7) 0.2774(5) 0.026(2) Uiso d PD 0.566(6) A 1
    H H12D 0.9957 1.0211 0.2425 0.039 Uiso calc PR 0.566(6) A 1
    H H12E 0.9548 0.9490 0.2942 0.039 Uiso calc PR 0.566(6) A 1
    H H12F 0.9297 1.0506 0.3154 0.039 Uiso calc PR 0.566(6) A 1
    C C132 0.3341(7) 0.7011(4) 0.0067(2) 0.026(2) Uiso d PD 0.566(6) A 1
    C C142 0.3078(11) 0.5293(5) -0.1025(3) 0.025(2) Uiso d PD 0.566(6) A 1
    C C152 0.1842(15) 0.4384(5) -0.1183(4) 0.024(4) Uiso d PD 0.566(6) A 1
    H H15C 0.2288 0.3910 -0.1458 0.029 Uiso calc PR 0.566(6) A 1
    H H15D 0.0910 0.4455 -0.1442 0.029 Uiso calc PR 0.566(6) A 1
    C C162 0.1371(15) 0.4114(6) -0.0491(4) 0.033(4) Uiso d PD 0.566(6) A 1
    H H16C 0.0213 0.4015 -0.0448 0.040 Uiso calc PR 0.566(6) A 1
    H H16D 0.1683 0.3544 -0.0434 0.040 Uiso calc PR 0.566(6) A 1
    C C172 0.2253(12) 0.4913(6) 0.0031(4) 0.036(3) Uiso d PD 0.566(6) A 1
    O O13 0.5078(10) 0.6249(5) 0.0126(4) 0.035(2) Uiso d PD 0.434(6) A 2
    O O23 0.2804(8) 0.6651(4) -0.0089(3) 0.029(2) Uiso d PD 0.434(6) A 2
    O O33 0.3159(10) 0.5897(5) -0.1470(4) 0.0251(19) Uiso d PD 0.434(6) A 2
    O O43 0.1521(11) 0.5200(6) 0.0609(3) 0.027(2) Uiso d PD 0.434(6) A 2
    N N33 0.2299(10) 0.5734(5) -0.0396(3) 0.029(2) Uiso d PD 0.434(6) A 2
    C C13 0.5836(16) 0.9431(7) 0.1422(7) 0.014(4) Uiso d PD 0.434(6) A 2
    C C23 0.4639(14) 0.9318(6) 0.0925(6) 0.020(3) Uiso d PD 0.434(6) A 2
    C C33 0.4100(12) 0.8459(5) 0.0517(5) 0.021(2) Uiso d PD 0.434(6) A 2
    H H33 0.3239 0.8348 0.0190 0.025 Uiso calc PR 0.434(6) A 2
    C C43 0.4844(11) 0.7767(5) 0.0597(5) 0.016(2) Uiso d PD 0.434(6) A 2
    C C53 0.6172(12) 0.7918(5) 0.1051(4) 0.019(2) Uiso d PD 0.434(6) A 2
    H H53 0.6733 0.7454 0.1061 0.022 Uiso calc PR 0.434(6) A 2
    C C63 0.6638(12) 0.8749(5) 0.1477(5) 0.014(2) Uiso d PD 0.434(6) A 2
    C C73 0.4145(17) 1.0187(7) 0.0873(6) 0.028(4) Uiso d PD 0.434(6) A 2
    H H73A 0.2984 1.0041 0.0778 0.034 Uiso calc PR 0.434(6) A 2
    H H73B 0.4660 1.0455 0.0485 0.034 Uiso calc PR 0.434(6) A 2
    C C83 0.322(2) 1.0720(12) 0.1988(8) 0.033(5) Uiso d PD 0.434(6) A 2
    H H83A 0.3111 1.0102 0.2098 0.049 Uiso calc PR 0.434(6) A 2
    H H83B 0.2276 1.0738 0.1725 0.049 Uiso calc PR 0.434(6) A 2
    H H83C 0.3355 1.1167 0.2412 0.049 Uiso calc PR 0.434(6) A 2
    C C93 0.4865(18) 1.1826(8) 0.1374(8) 0.032(4) Uiso d PD 0.434(6) A 2
    H H93A 0.5812 1.1933 0.1108 0.048 Uiso calc PR 0.434(6) A 2
    H H93B 0.5005 1.2306 0.1779 0.048 Uiso calc PR 0.434(6) A 2
    H H93C 0.3941 1.1842 0.1092 0.048 Uiso calc PR 0.434(6) A 2
    C C103 0.8006(12) 0.9036(8) 0.2004(5) 0.025(3) Uiso d PD 0.434(6) A 2
    H H10E 0.8129 0.8505 0.2213 0.030 Uiso calc PR 0.434(6) A 2
    H H10F 0.9005 0.9287 0.1792 0.030 Uiso calc PR 0.434(6) A 2
    C C113 0.6587(16) 0.9406(12) 0.3028(7) 0.031(5) Uiso d PD 0.434(6) A 2
    H H11G 0.6435 0.9954 0.3328 0.046 Uiso calc PR 0.434(6) A 2
    H H11H 0.7067 0.9041 0.3295 0.046 Uiso calc PR 0.434(6) A 2
    H H11I 0.5561 0.9035 0.2822 0.046 Uiso calc PR 0.434(6) A 2
    C C123 0.9245(14) 1.0290(9) 0.2904(7) 0.032(3) Uiso d PD 0.434(6) A 2
    H H12G 0.8984 1.0747 0.3262 0.048 Uiso calc PR 0.434(6) A 2
    H H12H 0.9966 1.0604 0.2594 0.048 Uiso calc PR 0.434(6) A 2
    H H12I 0.9759 0.9884 0.3113 0.048 Uiso calc PR 0.434(6) A 2
    C C133 0.4337(9) 0.6833(5) 0.0193(3) 0.029(3) Uiso d PD 0.434(6) A 2
    C C143 0.2580(15) 0.5424(6) -0.1063(4) 0.027(3) Uiso d PD 0.434(6) A 2
    C C153 0.211(2) 0.4380(6) -0.1156(5) 0.027(6) Uiso d PD 0.434(6) A 2
    H H15E 0.2996 0.4120 -0.1335 0.033 Uiso calc PR 0.434(6) A 2
    H H15F 0.1178 0.4131 -0.1480 0.033 Uiso calc PR 0.434(6) A 2
    C C163 0.172(2) 0.4136(6) -0.0448(5) 0.027(4) Uiso d PD 0.434(6) A 2
    H H16E 0.0651 0.3715 -0.0463 0.032 Uiso calc PR 0.434(6) A 2
    H H16F 0.2506 0.3840 -0.0277 0.032 Uiso calc PR 0.434(6) A 2
    C C173 0.1764(14) 0.5049(5) 0.0003(4) 0.020(3) Uiso d PD 0.434(6) A 2
    Cl Cl14 -0.0128(2) 0.74251(14) 0.28387(10) 0.0718(6) Uani d . 1 . .
    Cl Cl24 0.0919(2) 0.78774(14) 0.15204(11) 0.0788(6) Uani d . 1 . .
    C C14 0.1497(8) 0.7740(6) 0.2317(5) 0.087(3) Uani d . 1 . .
    H H14A 0.2213 0.8322 0.2547 0.105 Uiso calc R 1 . .
    H H14B 0.2101 0.7259 0.2269 0.105 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Pt1 C11 . 1.942(4) yes
    Pt1 N21 . 2.103(4) yes
    Pt1 N11 . 2.104(4) yes
    Pt1 I11 . 2.6862(3) yes
    Pt1 I21 . 2.8260(3) yes
    I21 I31 . 2.8379(4) yes
    N11 C91 . 1.488(6) ?
    N11 C81 . 1.491(6) ?
    N11 C71 . 1.522(5) ?
    N21 C121 . 1.488(5) ?
    N21 C111 . 1.496(6) ?
    N21 C101 . 1.515(5) ?
    O11 C131 . 1.191(5) ?
    O21 N31 . 1.380(4) ?
    O21 C131 . 1.398(5) ?
    O31 C141 . 1.201(5) ?
    O41 C171 . 1.206(5) ?
    N31 C141 . 1.378(5) ?
    N31 C171 . 1.393(5) ?
    C11 C21 . 1.383(5) ?
    C11 C61 . 1.395(5) ?
    C21 C31 . 1.383(5) ?
    C21 C71 . 1.498(6) ?
    C31 C41 . 1.394(5) ?
    C31 H31 . 0.9500 ?
    C41 C51 . 1.404(5) ?
    C41 C131 . 1.478(5) ?
    C51 C61 . 1.377(5) ?
    C51 H51 . 0.9500 ?
    C61 C101 . 1.515(6) ?
    C71 H71A . 0.9900 ?
    C71 H71B . 0.9900 ?
    C81 H81A . 0.9800 ?
    C81 H81B . 0.9800 ?
    C81 H81C . 0.9800 ?
    C91 H91A . 0.9800 ?
    C91 H91B . 0.9800 ?
    C91 H91C . 0.9800 ?
    C101 H10A . 0.9900 ?
    C101 H10B . 0.9900 ?
    C111 H11A . 0.9800 ?
    C111 H11B . 0.9800 ?
    C111 H11C . 0.9800 ?
    C121 H12A . 0.9800 ?
    C121 H12B . 0.9800 ?
    C121 H12C . 0.9800 ?
    C141 C151 . 1.509(6) ?
    C151 C161 . 1.524(6) ?
    C151 H15A . 0.9900 ?
    C151 H15B . 0.9900 ?
    C161 C171 . 1.504(6) ?
    C161 H16A . 0.9900 ?
    C161 H16B . 0.9900 ?
    Pt2 C13 . 1.908(9) yes
    Pt2 C12 . 1.966(8) yes
    Pt2 N22 . 2.098(4) yes
    Pt2 N12 . 2.103(4) yes
    Pt2 I12 . 2.6827(4) yes
    Pt2 I22 . 2.8198(3) yes
    I22 I32 . 2.8472(4) yes
    N12 C93 . 1.424(13) ?
    N12 C72 . 1.424(10) ?
    N12 C83 . 1.475(14) ?
    N12 C82 . 1.518(12) ?
    N12 C92 . 1.544(10) ?
    N12 C73 . 1.650(12) ?
    N22 C103 . 1.354(11) ?
    N22 C122 . 1.435(9) ?
    N22 C113 . 1.483(13) ?
    N22 C112 . 1.517(10) ?
    N22 C102 . 1.612(9) ?
    N22 C123 . 1.610(12) ?
    O12 C132 . 1.191(7) ?
    O22 N32 . 1.384(7) ?
    O22 C132 . 1.385(7) ?
    O32 C142 . 1.194(7) ?
    O42 C172 . 1.213(7) ?
    N32 C142 . 1.368(7) ?
    N32 C172 . 1.402(7) ?
    C12 C22 . 1.383(8) ?
    C12 C62 . 1.395(7) ?
    C22 C32 . 1.384(7) ?
    C22 C72 . 1.492(8) ?
    C32 C42 . 1.393(8) ?
    C32 H32 . 0.9500 ?
    C42 C52 . 1.405(8) ?
    C42 C132 . 1.480(7) ?
    C52 C62 . 1.381(7) ?
    C52 H52 . 0.9500 ?
    C62 C102 . 1.512(8) ?
    C72 H72A . 0.9900 ?
    C72 H72B . 0.9900 ?
    C82 H82A . 0.9800 ?
    C82 H82B . 0.9800 ?
    C82 H82C . 0.9800 ?
    C92 H92A . 0.9800 ?
    C92 H92B . 0.9800 ?
    C92 H92C . 0.9800 ?
    C102 H10C . 0.9900 ?
    C102 H10D . 0.9900 ?
    C112 H11D . 0.9800 ?
    C112 H11E . 0.9800 ?
    C112 H11F . 0.9800 ?
    C122 H12D . 0.9800 ?
    C122 H12E . 0.9800 ?
    C122 H12F . 0.9800 ?
    C142 C152 . 1.519(8) ?
    C152 C162 . 1.528(7) ?
    C152 H15C . 0.9900 ?
    C152 H15D . 0.9900 ?
    C162 C172 . 1.506(8) ?
    C162 H16C . 0.9900 ?
    C162 H16D . 0.9900 ?
    O13 C133 . 1.207(8) ?
    O23 C133 . 1.387(7) ?
    O23 N33 . 1.391(7) ?
    O33 C143 . 1.203(7) ?
    O43 C173 . 1.217(7) ?
    N33 C143 . 1.376(7) ?
    N33 C173 . 1.403(7) ?
    C13 C23 . 1.386(8) ?
    C13 C63 . 1.396(8) ?
    C23 C33 . 1.393(8) ?
    C23 C73 . 1.500(9) ?
    C33 C43 . 1.386(8) ?
    C33 H33 . 0.9500 ?
    C43 C53 . 1.407(8) ?
    C43 C133 . 1.476(8) ?
    C53 C63 . 1.370(8) ?
    C53 H53 . 0.9500 ?
    C63 C103 . 1.509(9) ?
    C73 H73A . 0.9900 ?
    C73 H73B . 0.9900 ?
    C83 H83A . 0.9800 ?
    C83 H83B . 0.9800 ?
    C83 H83C . 0.9800 ?
    C93 H93A . 0.9800 ?
    C93 H93B . 0.9800 ?
    C93 H93C . 0.9800 ?
    C103 H10E . 0.9900 ?
    C103 H10F . 0.9900 ?
    C113 H11G . 0.9800 ?
    C113 H11H . 0.9800 ?
    C113 H11I . 0.9800 ?
    C123 H12G . 0.9800 ?
    C123 H12H . 0.9800 ?
    C123 H12I . 0.9800 ?
    C143 C153 . 1.520(8) ?
    C153 C163 . 1.532(8) ?
    C153 H15E . 0.9900 ?
    C153 H15F . 0.9900 ?
    C163 C173 . 1.515(8) ?
    C163 H16E . 0.9900 ?
    C163 H16F . 0.9900 ?
    Cl14 C14 . 1.781(9) ?
    Cl24 C14 . 1.711(9) ?
    C14 H14A . 0.9900 ?
    C14 H14B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C11 Pt1 N21 . . 82.15(15) yes
    C11 Pt1 N11 . . 82.09(15) yes
    N21 Pt1 N11 . . 161.06(14) yes
    C11 Pt1 I11 . . 173.70(12) yes
    N21 Pt1 I11 . . 98.26(10) yes
    N11 Pt1 I11 . . 96.26(10) yes
    C11 Pt1 I21 . . 84.54(12) yes
    N21 Pt1 I21 . . 94.22(10) yes
    N11 Pt1 I21 . . 94.68(10) yes
    I11 Pt1 I21 . . 101.675(11) yes
    Pt1 I21 I31 . . 177.248(14) yes
    C91 N11 C81 . . 109.0(3) ?
    C91 N11 C71 . . 108.9(3) ?
    C81 N11 C71 . . 107.4(3) ?
    C91 N11 Pt1 . . 117.0(3) ?
    C81 N11 Pt1 . . 105.3(3) ?
    C71 N11 Pt1 . . 108.9(2) ?
    C121 N21 C111 . . 108.1(3) ?
    C121 N21 C101 . . 108.4(3) ?
    C111 N21 C101 . . 108.4(3) ?
    C121 N21 Pt1 . . 117.7(3) ?
    C111 N21 Pt1 . . 105.2(3) ?
    C101 N21 Pt1 . . 108.6(2) ?
    N31 O21 C131 . . 111.1(3) ?
    C141 N31 O21 . . 123.2(3) ?
    C141 N31 C171 . . 116.6(4) ?
    O21 N31 C171 . . 120.1(3) ?
    C21 C11 C61 . . 123.0(4) ?
    C21 C11 Pt1 . . 118.4(3) ?
    C61 C11 Pt1 . . 118.6(3) ?
    C31 C21 C11 . . 118.3(4) ?
    C31 C21 C71 . . 126.8(4) ?
    C11 C21 C71 . . 114.8(4) ?
    C21 C31 C41 . . 119.2(4) ?
    C21 C31 H31 . . 120.4 ?
    C41 C31 H31 . . 120.4 ?
    C31 C41 C51 . . 121.9(4) ?
    C31 C41 C131 . . 116.2(4) ?
    C51 C41 C131 . . 121.7(4) ?
    C61 C51 C41 . . 118.6(4) ?
    C61 C51 H51 . . 120.7 ?
    C41 C51 H51 . . 120.7 ?
    C51 C61 C11 . . 118.7(4) ?
    C51 C61 C101 . . 127.6(4) ?
    C11 C61 C101 . . 113.4(3) ?
    C21 C71 N11 . . 109.7(3) ?
    C21 C71 H71A . . 109.7 ?
    N11 C71 H71A . . 109.7 ?
    C21 C71 H71B . . 109.7 ?
    N11 C71 H71B . . 109.7 ?
    H71A C71 H71B . . 108.2 ?
    N11 C81 H81A . . 109.5 ?
    N11 C81 H81B . . 109.5 ?
    H81A C81 H81B . . 109.5 ?
    N11 C81 H81C . . 109.5 ?
    H81A C81 H81C . . 109.5 ?
    H81B C81 H81C . . 109.5 ?
    N11 C91 H91A . . 109.5 ?
    N11 C91 H91B . . 109.5 ?
    H91A C91 H91B . . 109.5 ?
    N11 C91 H91C . . 109.5 ?
    H91A C91 H91C . . 109.5 ?
    H91B C91 H91C . . 109.5 ?
    N21 C101 C61 . . 109.9(3) ?
    N21 C101 H10A . . 109.7 ?
    C61 C101 H10A . . 109.7 ?
    N21 C101 H10B . . 109.7 ?
    C61 C101 H10B . . 109.7 ?
    H10A C101 H10B . . 108.2 ?
    N21 C111 H11A . . 109.5 ?
    N21 C111 H11B . . 109.5 ?
    H11A C111 H11B . . 109.5 ?
    N21 C111 H11C . . 109.5 ?
    H11A C111 H11C . . 109.5 ?
    H11B C111 H11C . . 109.5 ?
    N21 C121 H12A . . 109.5 ?
    N21 C121 H12B . . 109.5 ?
    H12A C121 H12B . . 109.5 ?
    N21 C121 H12C . . 109.5 ?
    H12A C121 H12C . . 109.5 ?
    H12B C121 H12C . . 109.5 ?
    O11 C131 O21 . . 121.9(4) ?
    O11 C131 C41 . . 127.3(4) ?
    O21 C131 C41 . . 110.8(3) ?
    O31 C141 N31 . . 124.3(4) ?
    O31 C141 C151 . . 130.2(4) ?
    N31 C141 C151 . . 105.6(4) ?
    C141 C151 C161 . . 106.2(4) ?
    C141 C151 H15A . . 110.5 ?
    C161 C151 H15A . . 110.5 ?
    C141 C151 H15B . . 110.5 ?
    C161 C151 H15B . . 110.5 ?
    H15A C151 H15B . . 108.7 ?
    C171 C161 C151 . . 105.9(4) ?
    C171 C161 H16A . . 110.5 ?
    C151 C161 H16A . . 110.5 ?
    C171 C161 H16B . . 110.5 ?
    C151 C161 H16B . . 110.5 ?
    H16A C161 H16B . . 108.7 ?
    O41 C171 N31 . . 123.6(4) ?
    O41 C171 C161 . . 130.9(4) ?
    N31 C171 C161 . . 105.6(4) ?
    C13 Pt2 C12 . . 6.5(4) yes
    C13 Pt2 N22 . . 78.2(3) yes
    C12 Pt2 N22 . . 84.3(3) yes
    C13 Pt2 N12 . . 85.7(3) yes
    C12 Pt2 N12 . . 79.3(3) yes
    N22 Pt2 N12 . . 160.14(16) yes
    C13 Pt2 I12 . . 173.3(4) yes
    C12 Pt2 I12 . . 172.6(4) yes
    N22 Pt2 I12 . . 97.20(12) yes
    N12 Pt2 I12 . . 97.75(11) yes
    C13 Pt2 I22 . . 83.7(5) yes
    C12 Pt2 I22 . . 85.4(4) yes
    N22 Pt2 I22 . . 94.64(11) yes
    N12 Pt2 I22 . . 95.10(10) yes
    I12 Pt2 I22 . . 101.569(11) yes
    Pt2 I22 I32 . . 177.533(15) yes
    C93 N12 C83 . . 113.9(9) ?
    C72 N12 C82 . . 112.2(7) ?
    C72 N12 C92 . . 111.1(6) ?
    C82 N12 C92 . . 104.1(6) ?
    C93 N12 C73 . . 105.7(7) ?
    C83 N12 C73 . . 102.7(8) ?
    C93 N12 Pt2 . . 122.7(7) ?
    C72 N12 Pt2 . . 113.0(4) ?
    C83 N12 Pt2 . . 105.3(8) ?
    C82 N12 Pt2 . . 104.6(6) ?
    C92 N12 Pt2 . . 111.4(5) ?
    C73 N12 Pt2 . . 104.4(4) ?
    C103 N22 C113 . . 119.2(9) ?
    C122 N22 C112 . . 109.4(6) ?
    C122 N22 C102 . . 107.0(5) ?
    C112 N22 C102 . . 101.2(6) ?
    C103 N22 C123 . . 109.3(7) ?
    C113 N22 C123 . . 102.9(7) ?
    C103 N22 Pt2 . . 113.6(5) ?
    C122 N22 Pt2 . . 123.9(5) ?
    C113 N22 Pt2 . . 100.2(7) ?
    C112 N22 Pt2 . . 107.7(5) ?
    C102 N22 Pt2 . . 105.3(3) ?
    C123 N22 Pt2 . . 111.0(6) ?
    N32 O22 C132 . . 112.1(6) ?
    C142 N32 O22 . . 124.9(5) ?
    C142 N32 C172 . . 115.2(5) ?
    O22 N32 C172 . . 117.9(5) ?
    C22 C12 C62 . . 123.0(7) ?
    C22 C12 Pt2 . . 118.0(5) ?
    C62 C12 Pt2 . . 118.8(6) ?
    C12 C22 C32 . . 117.8(7) ?
    C12 C22 C72 . . 114.3(6) ?
    C32 C22 C72 . . 127.8(7) ?
    C22 C32 C42 . . 120.0(7) ?
    C22 C32 H32 . . 120.0 ?
    C42 C32 H32 . . 120.0 ?
    C32 C42 C52 . . 121.6(5) ?
    C32 C42 C132 . . 117.2(6) ?
    C52 C42 C132 . . 120.3(6) ?
    C62 C52 C42 . . 118.2(6) ?
    C62 C52 H52 . . 120.9 ?
    C42 C52 H52 . . 120.9 ?
    C52 C62 C12 . . 119.3(7) ?
    C52 C62 C102 . . 127.7(6) ?
    C12 C62 C102 . . 112.8(6) ?
    N12 C72 C22 . . 109.4(6) ?
    N12 C72 H72A . . 109.8 ?
    C22 C72 H72A . . 109.8 ?
    N12 C72 H72B . . 109.8 ?
    C22 C72 H72B . . 109.8 ?
    H72A C72 H72B . . 108.2 ?
    N12 C82 H82A . . 109.5 ?
    N12 C82 H82B . . 109.5 ?
    H82A C82 H82B . . 109.5 ?
    N12 C82 H82C . . 109.5 ?
    H82A C82 H82C . . 109.5 ?
    H82B C82 H82C . . 109.5 ?
    N12 C92 H92A . . 109.5 ?
    N12 C92 H92B . . 109.5 ?
    H92A C92 H92B . . 109.5 ?
    N12 C92 H92C . . 109.5 ?
    H92A C92 H92C . . 109.5 ?
    H92B C92 H92C . . 109.5 ?
    C62 C102 N22 . . 111.5(5) ?
    C62 C102 H10C . . 109.3 ?
    N22 C102 H10C . . 109.3 ?
    C62 C102 H10D . . 109.3 ?
    N22 C102 H10D . . 109.3 ?
    H10C C102 H10D . . 108.0 ?
    N22 C112 H11D . . 109.5 ?
    N22 C112 H11E . . 109.5 ?
    H11D C112 H11E . . 109.5 ?
    N22 C112 H11F . . 109.5 ?
    H11D C112 H11F . . 109.5 ?
    H11E C112 H11F . . 109.5 ?
    N22 C122 H12D . . 109.5 ?
    N22 C122 H12E . . 109.5 ?
    H12D C122 H12E . . 109.5 ?
    N22 C122 H12F . . 109.5 ?
    H12D C122 H12F . . 109.5 ?
    H12E C122 H12F . . 109.5 ?
    O12 C132 O22 . . 121.8(6) ?
    O12 C132 C42 . . 127.4(6) ?
    O22 C132 C42 . . 110.8(5) ?
    O32 C142 N32 . . 122.7(6) ?
    O32 C142 C152 . . 130.8(6) ?
    N32 C142 C152 . . 106.5(5) ?
    C142 C152 C162 . . 105.9(5) ?
    C142 C152 H15C . . 110.6 ?
    C162 C152 H15C . . 110.5 ?
    C142 C152 H15D . . 110.6 ?
    C162 C152 H15D . . 110.6 ?
    H15C C152 H15D . . 108.7 ?
    C172 C162 C152 . . 105.0(5) ?
    C172 C162 H16C . . 110.7 ?
    C152 C162 H16C . . 110.7 ?
    C172 C162 H16D . . 110.7 ?
    C152 C162 H16D . . 110.7 ?
    H16C C162 H16D . . 108.8 ?
    O42 C172 N32 . . 124.2(7) ?
    O42 C172 C162 . . 129.2(7) ?
    N32 C172 C162 . . 106.5(5) ?
    C133 O23 N33 . . 110.5(6) ?
    C143 N33 O23 . . 122.9(6) ?
    C143 N33 C173 . . 115.6(6) ?
    O23 N33 C173 . . 120.3(6) ?
    C23 C13 C63 . . 122.3(7) ?
    C23 C13 Pt2 . . 120.3(6) ?
    C63 C13 Pt2 . . 117.3(6) ?
    C13 C23 C33 . . 118.6(8) ?
    C13 C23 C73 . . 113.6(7) ?
    C33 C23 C73 . . 127.7(8) ?
    C43 C33 C23 . . 118.7(7) ?
    C43 C33 H33 . . 120.7 ?
    C23 C33 H33 . . 120.7 ?
    C33 C43 C53 . . 122.2(6) ?
    C33 C43 C133 . . 122.3(7) ?
    C53 C43 C133 . . 115.4(6) ?
    C63 C53 C43 . . 118.5(7) ?
    C63 C53 H53 . . 120.8 ?
    C43 C53 H53 . . 120.8 ?
    C53 C63 C13 . . 119.1(8) ?
    C53 C63 C103 . . 126.5(7) ?
    C13 C63 C103 . . 114.3(7) ?
    C23 C73 N12 . . 111.8(7) ?
    C23 C73 H73A . . 109.3 ?
    N12 C73 H73A . . 109.3 ?
    C23 C73 H73B . . 109.3 ?
    N12 C73 H73B . . 109.3 ?
    H73A C73 H73B . . 107.9 ?
    N12 C83 H83A . . 109.5 ?
    N12 C83 H83B . . 109.5 ?
    H83A C83 H83B . . 109.5 ?
    N12 C83 H83C . . 109.5 ?
    H83A C83 H83C . . 109.5 ?
    H83B C83 H83C . . 109.5 ?
    N12 C93 H93A . . 109.5 ?
    N12 C93 H93B . . 109.5 ?
    H93A C93 H93B . . 109.5 ?
    N12 C93 H93C . . 109.5 ?
    H93A C93 H93C . . 109.5 ?
    H93B C93 H93C . . 109.5 ?
    N22 C103 C63 . . 105.9(7) ?
    N22 C103 H10E . . 110.6 ?
    C63 C103 H10E . . 110.6 ?
    N22 C103 H10F . . 110.6 ?
    C63 C103 H10F . . 110.6 ?
    H10E C103 H10F . . 108.7 ?
    N22 C113 H11G . . 109.5 ?
    N22 C113 H11H . . 109.5 ?
    H11G C113 H11H . . 109.5 ?
    N22 C113 H11I . . 109.5 ?
    H11G C113 H11I . . 109.5 ?
    H11H C113 H11I . . 109.5 ?
    N22 C123 H12G . . 109.5 ?
    N22 C123 H12H . . 109.5 ?
    H12G C123 H12H . . 109.5 ?
    N22 C123 H12I . . 109.5 ?
    H12G C123 H12I . . 109.5 ?
    H12H C123 H12I . . 109.5 ?
    O13 C133 O23 . . 121.0(7) ?
    O13 C133 C43 . . 126.7(7) ?
    O23 C133 C43 . . 112.1(6) ?
    O33 C143 N33 . . 125.9(7) ?
    O33 C143 C153 . . 127.9(7) ?
    N33 C143 C153 . . 106.1(6) ?
    C143 C153 C163 . . 106.3(6) ?
    C143 C153 H15E . . 110.5 ?
    C163 C153 H15E . . 110.5 ?
    C143 C153 H15F . . 110.5 ?
    C163 C153 H15F . . 110.5 ?
    H15E C153 H15F . . 108.7 ?
    C173 C163 C153 . . 104.7(6) ?
    C173 C163 H16E . . 110.8 ?
    C153 C163 H16E . . 110.8 ?
    C173 C163 H16F . . 110.8 ?
    C153 C163 H16F . . 110.8 ?
    H16E C163 H16F . . 108.9 ?
    O43 C173 N33 . . 124.3(7) ?
    O43 C173 C163 . . 128.7(7) ?
    N33 C173 C163 . . 106.7(6) ?
    Cl24 C14 Cl14 . . 113.0(4) ?
    Cl24 C14 H14A . . 109.0 ?
    Cl14 C14 H14A . . 109.0 ?
    Cl24 C14 H14B . . 109.0 ?
    Cl14 C14 H14B . . 109.0 ?
    H14A C14 H14B . . 107.8 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C11 Pt1 N11 C91 . . . . -140.5(3) ?
    N21 Pt1 N11 C91 . . . . -174.5(4) ?
    I11 Pt1 N11 C91 . . . . 45.6(3) ?
    I21 Pt1 N11 C91 . . . . -56.7(3) ?
    C11 Pt1 N11 C81 . . . . 98.3(3) ?
    N21 Pt1 N11 C81 . . . . 64.3(5) ?
    I11 Pt1 N11 C81 . . . . -75.6(3) ?
    I21 Pt1 N11 C81 . . . . -177.9(3) ?
    C11 Pt1 N11 C71 . . . . -16.6(3) ?
    N21 Pt1 N11 C71 . . . . -50.6(6) ?
    I11 Pt1 N11 C71 . . . . 169.5(3) ?
    I21 Pt1 N11 C71 . . . . 67.2(3) ?
    C11 Pt1 N21 C121 . . . . 142.5(3) ?
    N11 Pt1 N21 C121 . . . . 176.4(4) ?
    I11 Pt1 N21 C121 . . . . -43.9(3) ?
    I21 Pt1 N21 C121 . . . . 58.6(3) ?
    C11 Pt1 N21 C111 . . . . -97.1(3) ?
    N11 Pt1 N21 C111 . . . . -63.1(5) ?
    I11 Pt1 N21 C111 . . . . 76.6(3) ?
    I21 Pt1 N21 C111 . . . . 179.1(3) ?
    C11 Pt1 N21 C101 . . . . 18.8(3) ?
    N11 Pt1 N21 C101 . . . . 52.8(5) ?
    I11 Pt1 N21 C101 . . . . -167.5(3) ?
    I21 Pt1 N21 C101 . . . . -65.0(3) ?
    C131 O21 N31 C141 . . . . 80.3(5) ?
    C131 O21 N31 C171 . . . . -97.8(4) ?
    N21 Pt1 C11 C21 . . . . 172.9(3) ?
    N11 Pt1 C11 C21 . . . . 3.4(3) ?
    I21 Pt1 C11 C21 . . . . -92.1(3) ?
    N21 Pt1 C11 C61 . . . . -4.9(3) ?
    N11 Pt1 C11 C61 . . . . -174.3(4) ?
    I21 Pt1 C11 C61 . . . . 90.2(3) ?
    C61 C11 C21 C31 . . . . 5.4(6) ?
    Pt1 C11 C21 C31 . . . . -172.2(3) ?
    C61 C11 C21 C71 . . . . -170.9(4) ?
    Pt1 C11 C21 C71 . . . . 11.5(5) ?
    C11 C21 C31 C41 . . . . -4.1(6) ?
    C71 C21 C31 C41 . . . . 171.7(4) ?
    C21 C31 C41 C51 . . . . 1.3(6) ?
    C21 C31 C41 C131 . . . . 176.3(3) ?
    C31 C41 C51 C61 . . . . 0.5(6) ?
    C131 C41 C51 C61 . . . . -174.3(3) ?
    C41 C51 C61 C11 . . . . 0.7(6) ?
    C41 C51 C61 C101 . . . . -173.9(4) ?
    C21 C11 C61 C51 . . . . -3.7(7) ?
    Pt1 C11 C61 C51 . . . . 173.9(3) ?
    C21 C11 C61 C101 . . . . 171.6(4) ?
    Pt1 C11 C61 C101 . . . . -10.8(5) ?
    C31 C21 C71 N11 . . . . 159.0(4) ?
    C11 C21 C71 N11 . . . . -25.0(5) ?
    C91 N11 C71 C21 . . . . 154.6(4) ?
    C81 N11 C71 C21 . . . . -87.5(4) ?
    Pt1 N11 C71 C21 . . . . 26.1(4) yes
    C121 N21 C101 C61 . . . . -157.6(4) ?
    C111 N21 C101 C61 . . . . 85.2(4) ?
    Pt1 N21 C101 C61 . . . . -28.6(4) yes
    C51 C61 C101 N21 . . . . -158.9(4) ?
    C11 C61 C101 N21 . . . . 26.3(5) ?
    N31 O21 C131 O11 . . . . -4.8(4) ?
    N31 O21 C131 C41 . . . . 176.7(2) ?
    C31 C41 C131 O11 . . . . -1.5(3) ?
    C51 C41 C131 O11 . . . . 173.5(4) ?
    C31 C41 C131 O21 . . . . 176.9(3) ?
    C51 C41 C131 O21 . . . . -8.1(4) ?
    O21 N31 C141 O31 . . . . 0.8(7) ?
    C171 N31 C141 O31 . . . . 179.1(5) ?
    O21 N31 C141 C151 . . . . 179.2(4) ?
    C171 N31 C141 C151 . . . . -2.6(6) ?
    O31 C141 C151 C161 . . . . 179.0(5) ?
    N31 C141 C151 C161 . . . . 0.7(6) ?
    C141 C151 C161 C171 . . . . 1.1(6) ?
    C141 N31 C171 O41 . . . . -177.1(5) ?
    O21 N31 C171 O41 . . . . 1.2(7) ?
    C141 N31 C171 C161 . . . . 3.3(6) ?
    O21 N31 C171 C161 . . . . -178.4(4) ?
    C151 C161 C171 O41 . . . . 177.9(5) ?
    C151 C161 C171 N31 . . . . -2.5(5) ?
    C13 Pt2 N12 C93 . . . . -131.5(9) ?
    C12 Pt2 N12 C93 . . . . -132.6(8) ?
    N22 Pt2 N12 C93 . . . . -167.3(8) ?
    I12 Pt2 N12 C93 . . . . 54.2(7) ?
    I22 Pt2 N12 C93 . . . . -48.2(7) ?
    C13 Pt2 N12 C72 . . . . -15.0(7) ?
    C12 Pt2 N12 C72 . . . . -16.0(6) ?
    N22 Pt2 N12 C72 . . . . -50.7(7) ?
    I12 Pt2 N12 C72 . . . . 170.8(5) ?
    I22 Pt2 N12 C72 . . . . 68.3(5) ?
    C13 Pt2 N12 C83 . . . . 96.1(9) ?
    C12 Pt2 N12 C83 . . . . 95.1(8) ?
    N22 Pt2 N12 C83 . . . . 60.4(9) ?
    I12 Pt2 N12 C83 . . . . -78.1(7) ?
    I22 Pt2 N12 C83 . . . . 179.4(7) ?
    C13 Pt2 N12 C82 . . . . 107.3(8) ?
    C12 Pt2 N12 C82 . . . . 106.2(7) ?
    N22 Pt2 N12 C82 . . . . 71.5(7) ?
    I12 Pt2 N12 C82 . . . . -67.0(6) ?
    I22 Pt2 N12 C82 . . . . -169.4(6) ?
    C13 Pt2 N12 C92 . . . . -140.9(7) ?
    C12 Pt2 N12 C92 . . . . -142.0(6) ?
    N22 Pt2 N12 C92 . . . . -176.7(5) ?
    I12 Pt2 N12 C92 . . . . 44.8(5) ?
    I22 Pt2 N12 C92 . . . . -57.6(5) ?
    C13 Pt2 N12 C73 . . . . -11.7(7) ?
    C12 Pt2 N12 C73 . . . . -12.8(7) ?
    N22 Pt2 N12 C73 . . . . -47.5(7) ?
    I12 Pt2 N12 C73 . . . . 174.0(5) ?
    I22 Pt2 N12 C73 . . . . 71.6(5) ?
    C13 Pt2 N22 C103 . . . . 27.0(8) ?
    C12 Pt2 N22 C103 . . . . 29.3(7) ?
    N12 Pt2 N22 C103 . . . . 63.5(8) ?
    I12 Pt2 N22 C103 . . . . -157.9(6) ?
    I22 Pt2 N22 C103 . . . . -55.6(6) ?
    C13 Pt2 N22 C122 . . . . 138.7(7) ?
    C12 Pt2 N22 C122 . . . . 141.0(7) ?
    N12 Pt2 N22 C122 . . . . 175.2(6) ?
    I12 Pt2 N22 C122 . . . . -46.2(5) ?
    I22 Pt2 N22 C122 . . . . 56.1(5) ?
    C13 Pt2 N22 C113 . . . . -101.3(8) ?
    C12 Pt2 N22 C113 . . . . -99.0(8) ?
    N12 Pt2 N22 C113 . . . . -64.8(8) ?
    I12 Pt2 N22 C113 . . . . 73.8(6) ?
    I22 Pt2 N22 C113 . . . . 176.1(6) ?
    C13 Pt2 N22 C112 . . . . -91.9(7) ?
    C12 Pt2 N22 C112 . . . . -89.5(6) ?
    N12 Pt2 N22 C112 . . . . -55.3(7) ?
    I12 Pt2 N22 C112 . . . . 83.2(5) ?
    I22 Pt2 N22 C112 . . . . -174.5(5) ?
    C13 Pt2 N22 C102 . . . . 15.4(6) ?
    C12 Pt2 N22 C102 . . . . 17.8(5) ?
    N12 Pt2 N22 C102 . . . . 52.0(6) ?
    I12 Pt2 N22 C102 . . . . -169.5(4) ?
    I22 Pt2 N22 C102 . . . . -67.2(4) ?
    C13 Pt2 N22 C123 . . . . 150.5(8) ?
    C12 Pt2 N22 C123 . . . . 152.9(7) ?
    N12 Pt2 N22 C123 . . . . -172.9(6) ?
    I12 Pt2 N22 C123 . . . . -34.4(6) ?
    I22 Pt2 N22 C123 . . . . 67.9(6) ?
    C132 O22 N32 C142 . . . . 76.3(9) ?
    C132 O22 N32 C172 . . . . -86.4(8) ?
    C13 Pt2 C12 C22 . . . . -169(8) ?
    N22 Pt2 C12 C22 . . . . 170.4(10) ?
    N12 Pt2 C12 C22 . . . . 1.6(9) ?
    I22 Pt2 C12 C22 . . . . -94.5(10) ?
    C13 Pt2 C12 C62 . . . . 16(7) ?
    N22 Pt2 C12 C62 . . . . -4.7(9) ?
    N12 Pt2 C12 C62 . . . . -173.5(10) ?
    I22 Pt2 C12 C62 . . . . 90.5(10) ?
    C62 C12 C22 C32 . . . . 3.6(17) ?
    Pt2 C12 C22 C32 . . . . -171.2(8) ?
    C62 C12 C22 C72 . . . . -172.6(11) ?
    Pt2 C12 C22 C72 . . . . 12.6(14) ?
    C12 C22 C32 C42 . . . . -4.6(14) ?
    C72 C22 C32 C42 . . . . 170.9(9) ?
    C22 C32 C42 C52 . . . . 4.0(12) ?
    C22 C32 C42 C132 . . . . 173.8(7) ?
    C32 C42 C52 C62 . . . . -2.1(11) ?
    C132 C42 C52 C62 . . . . -171.6(6) ?
    C42 C52 C62 C12 . . . . 0.9(13) ?
    C42 C52 C62 C102 . . . . -173.6(8) ?
    C22 C12 C62 C52 . . . . -1.7(17) ?
    Pt2 C12 C62 C52 . . . . 173.0(7) ?
    C22 C12 C62 C102 . . . . 173.6(10) ?
    Pt2 C12 C62 C102 . . . . -11.6(13) ?
    C93 N12 C72 C22 . . . . 156.4(9) ?
    C83 N12 C72 C22 . . . . -86.9(11) ?
    C82 N12 C72 C22 . . . . -91.9(10) ?
    C92 N12 C72 C22 . . . . 152.0(7) ?
    C73 N12 C72 C22 . . . . 5(5) ?
    Pt2 N12 C72 C22 . . . . 25.9(9) yes
    C12 C22 C72 N12 . . . . -25.2(12) ?
    C32 C22 C72 N12 . . . . 159.2(9) ?
    C52 C62 C102 N22 . . . . -158.3(8) ?
    C12 C62 C102 N22 . . . . 26.9(11) ?
    C103 N22 C102 C62 . . . . -158(3) ?
    C122 N22 C102 C62 . . . . -161.9(7) ?
    C113 N22 C102 C62 . . . . 79.7(10) ?
    C112 N22 C102 C62 . . . . 83.6(8) ?
    C123 N22 C102 C62 . . . . -156.6(8) ?
    Pt2 N22 C102 C62 . . . . -28.4(7) yes
    N32 O22 C132 O12 . . . . -4.4(5) ?
    N32 O22 C132 C42 . . . . 177.0(3) ?
    C32 C42 C132 O12 . . . . -7.2(6) ?
    C52 C42 C132 O12 . . . . 162.7(6) ?
    C32 C42 C132 O22 . . . . 171.2(6) ?
    C52 C42 C132 O22 . . . . -18.8(6) ?
    O22 N32 C142 O32 . . . . 7.8(15) ?
    C172 N32 C142 O32 . . . . 170.9(10) ?
    O22 N32 C142 C152 . . . . -170.4(9) ?
    C172 N32 C142 C152 . . . . -7.3(13) ?
    O32 C142 C152 C162 . . . . -176.8(12) ?
    N32 C142 C152 C162 . . . . 1.2(13) ?
    C142 C152 C162 C172 . . . . 4.5(14) ?
    C142 N32 C172 O42 . . . . -165.6(11) ?
    O22 N32 C172 O42 . . . . -1.2(16) ?
    C142 N32 C172 C162 . . . . 10.3(13) ?
    O22 N32 C172 C162 . . . . 174.7(9) ?
    C152 C162 C172 O42 . . . . 167.1(13) ?
    C152 C162 C172 N32 . . . . -8.5(13) ?
    C133 O23 N33 C143 . . . . -87.1(11) ?
    C133 O23 N33 C173 . . . . 79.5(10) ?
    C12 Pt2 C13 C23 . . . . 10(6) ?
    N22 Pt2 C13 C23 . . . . 169.4(13) ?
    N12 Pt2 C13 C23 . . . . 1.1(12) ?
    I22 Pt2 C13 C23 . . . . -94.6(13) ?
    C12 Pt2 C13 C63 . . . . -169(8) ?
    N22 Pt2 C13 C63 . . . . -9.6(11) ?
    N12 Pt2 C13 C63 . . . . -177.9(12) ?
    I22 Pt2 C13 C63 . . . . 86.5(11) ?
    C63 C13 C23 C33 . . . . 7(2) ?
    Pt2 C13 C23 C33 . . . . -171.6(10) ?
    C63 C13 C23 C73 . . . . -169.4(13) ?
    Pt2 C13 C23 C73 . . . . 11.8(18) ?
    C13 C23 C33 C43 . . . . -3.7(18) ?
    C73 C23 C33 C43 . . . . 172.4(12) ?
    C23 C33 C43 C53 . . . . -3.3(16) ?
    C23 C33 C43 C133 . . . . 179.2(10) ?
    C33 C43 C53 C63 . . . . 6.9(15) ?
    C133 C43 C53 C63 . . . . -175.4(8) ?
    C43 C53 C63 C13 . . . . -3.4(16) ?
    C43 C53 C63 C103 . . . . 179.0(10) ?
    C23 C13 C63 C53 . . . . -4(2) ?
    Pt2 C13 C63 C53 . . . . 175.2(9) ?
    C23 C13 C63 C103 . . . . 174.3(13) ?
    Pt2 C13 C63 C103 . . . . -6.8(16) ?
    C13 C23 C73 N12 . . . . -21.5(16) ?
    C33 C23 C73 N12 . . . . 162.2(12) ?
    C93 N12 C73 C23 . . . . 151.1(11) ?
    C72 N12 C73 C23 . . . . -179(6) ?
    C83 N12 C73 C23 . . . . -89.2(13) ?
    C82 N12 C73 C23 . . . . -92.5(12) ?
    C92 N12 C73 C23 . . . . 145.3(10) ?
    Pt2 N12 C73 C23 . . . . 20.5(11) yes
    C122 N22 C103 C63 . . . . -164.6(8) ?
    C113 N22 C103 C63 . . . . 82.7(11) ?
    C112 N22 C103 C63 . . . . 83.8(9) ?
    C102 N22 C103 C63 . . . . 20(2) ?
    C123 N22 C103 C63 . . . . -159.6(8) ?
    Pt2 N22 C103 C63 . . . . -35.1(9) yes
    C53 C63 C103 N22 . . . . -154.5(10) ?
    C13 C63 C103 N22 . . . . 27.7(14) ?
    N33 O23 C133 O13 . . . . 3.6(6) ?
    N33 O23 C133 C43 . . . . -172.9(6) ?
    C33 C43 C133 O13 . . . . 164.2(7) ?
    C53 C43 C133 O13 . . . . -13.5(11) ?
    C33 C43 C133 O23 . . . . -19.5(11) ?
    C53 C43 C133 O23 . . . . 162.8(7) ?
    O23 N33 C143 O33 . . . . -7(2) ?
    C173 N33 C143 O33 . . . . -173.7(13) ?
    O23 N33 C143 C153 . . . . 170.1(11) ?
    C173 N33 C143 C153 . . . . 2.9(16) ?
    O33 C143 C153 C163 . . . . 170.2(15) ?
    N33 C143 C153 C163 . . . . -6.3(18) ?
    C143 C153 C163 C173 . . . . 7.3(18) ?
    C143 N33 C173 O43 . . . . 176.8(12) ?
    O23 N33 C173 O43 . . . . 9.2(17) ?
    C143 N33 C173 C163 . . . . 1.9(15) ?
    O23 N33 C173 C163 . . . . -165.7(11) ?
    C153 C163 C173 O43 . . . . 179.7(14) ?
    C153 C163 C173 N33 . . . . -5.7(16) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C161 H16A O11 2_656 0.99 2.46 3.296(7) 142
data_global
_journal_date_recd_electronic     2007-03-16
_journal_date_accepted     2007-03-21
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      5
_journal_page_first     m1223
_journal_page_last     m1225
_journal_paper_category     EM
_journal_coeditor_code     FJ2006
_publ_contact_author_name     'Lars S. von Chrzanowski'
_publ_contact_author_address
;
Bijvoet Center for Biomolecular Research
Crystal and Structural Chemistry
Utrecht University
Padualaan 8
3584 CH Utrecht
The Netherlands
;
_publ_contact_author_email     'l.vonchrzanowski@chem.uu.nl'
_publ_contact_author_fax     '[+31] 30 2533940'
_publ_contact_author_phone     '[+31] 30 2533902'
_publ_section_title
;\
{2,6-Bis[(dimethylamino-κ²N,N')methyl]-4-{[(2,5-dioxo-1-\
pyrrolidinyl)oxy]carbonyl}phenyl-κC}(diiodine)iodoplatinum(II)
dichloromethane hemisolvate
;
loop_
    _publ_author_name
    _publ_author_address
    'von Chrzanowski, Lars S.'
;
Bijvoet Center for Biomolecular Research
Crystal and Structural Chemistry
Utrecht University
Padualaan 8
3584 CH Utrecht
The Netherlands
;
    'Lutz, Martin'
;
Bijvoet Center for Biomolecular Research
Crystal and Structural Chemistry
Utrecht University
Padualaan 8
3584 CH Utrecht
The Netherlands
;
    'Spek, Anthony L.'
;
Bijvoet Center for Biomolecular Research
Crystal and Structural Chemistry
Utrecht University
Padualaan 8
3584 CH Utrecht
The Netherlands
;
    'Suijkerbuijk, Bart M. J. M.'
;
Organic Chemistry and Catalysis
Faculty of Science
Utrecht University
Padualaan 8
3584 CH Utrecht
The Netherlands
;
    'Klein Gebbink, Robertus J. M.'
;
Organic Chemistry and Catalysis
Faculty of Science
Utrecht University
Padualaan 8
3584 CH Utrecht
The Netherlands
;
