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###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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#                                                                            #
#            Copyright International Union of Crystallography                #
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##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Bis(cinnamato-\kO)bis[2-(dimethylamino)ethanol-κ²N,O]copper(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C26 H36 Cu N2 O6'
_chemical_formula_sum     'C26 H36 Cu N2 O6'
_chemical_formula_iupac     '[Cu (C9 H7 O2) (C4 H11 N O)2]'
_chemical_formula_weight     536.11
_chemical_melting_point     ?
_symmetry_cell_setting     Orthorhombic
_symmetry_space_group_name_H-M     'P b c a'
_symmetry_space_group_name_Hall     '-P 2ac 2ab'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, -y, z+1/2'
    '-x, y+1/2, -z+1/2'
    'x+1/2, -y+1/2, -z'
    '-x, -y, -z'
    'x-1/2, y, -z-1/2'
    'x, -y-1/2, z-1/2'
    '-x-1/2, y-1/2, z'
_cell_length_a     10.45700(10)
_cell_length_b     10.45200(10)
_cell_length_c     23.2770(4)
_cell_angle_alpha     90.00
_cell_angle_beta     90.00
_cell_angle_gamma     90.00
_cell_volume     2544.10(6)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     34803
_cell_measurement_theta_min     2.910
_cell_measurement_theta_max     27.485
_cell_measurement_temperature     150(2)
_exptl_crystal_description     Block
_exptl_crystal_colour     'Pale turquoise'
_exptl_crystal_size_max     0.25
_exptl_crystal_size_mid     0.20
_exptl_crystal_size_min     0.20
_exptl_crystal_density_diffrn     1.400
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1132
_exptl_absorpt_coefficient_mu     0.902
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SORTAV; Blessing, 1995)'
_exptl_absorpt_correction_T_min     0.763
_exptl_absorpt_correction_T_max     0.835
_exptl_special_details
;
;
_diffrn_ambient_temperature     150(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Nonius KappaCCD'
_diffrn_measurement_method     KappaCCD
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     34803
_diffrn_reflns_av_R_equivalents     0.0529
_diffrn_reflns_av_sigmaI/netI     0.0267
_diffrn_reflns_theta_min     3.26
_diffrn_reflns_theta_max     27.48
_diffrn_reflns_theta_full     27.48
_diffrn_measured_fraction_theta_max     0.998
_diffrn_measured_fraction_theta_full     0.998
_diffrn_reflns_limit_h_min     -13
_diffrn_reflns_limit_h_max     13
_diffrn_reflns_limit_k_min     -13
_diffrn_reflns_limit_k_max     13
_diffrn_reflns_limit_l_min     -30
_diffrn_reflns_limit_l_max     30
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     2913
_reflns_number_gt     2210
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0540
_refine_ls_R_factor_gt     0.0385
_refine_ls_wR_factor_gt     0.0994
_refine_ls_wR_factor_ref     0.1084
_refine_ls_goodness_of_fit_ref     1.145
_refine_ls_restrained_S_all     1.155
_refine_ls_number_reflns     2913
_refine_ls_number_parameters     178
_refine_ls_number_restraints     9
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0621P)²+0.3589P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.424
_refine_diff_density_min     -0.385
_refine_ls_extinction_method     SHELXL97
_refine_ls_extinction_coef     0.0251(19)
_refine_ls_extinction_expression
                                  'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cu' 'Cu' 0.3201 1.2651
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'COLLECT (Nonius, 2000)'
_computing_cell_refinement     'SCALEPACK (Otwinowski & Minor, 1997)'
_computing_data_reduction     'SCALEPACK and DENZO (Otwinowski & Minor, 1997)'
_computing_structure_solution     'SIR97 (Altomare et al.,  1999)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material     'WinGX (Farrugia, 1999)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C1 0.72313(16) -0.03852(18) 0.57656(8) 0.0231(4) Uani d . 1 A .
    C C2 0.82838(17) 0.03099(18) 0.60617(8) 0.0248(4) Uani d . 1 . .
    H H2 0.8413 0.1189 0.5976 0.030 Uiso calc R 1 . .
    C C3 0.90499(16) -0.02489(17) 0.64408(7) 0.0232(4) Uani d . 1 . .
    H H3 0.8943 -0.1144 0.6493 0.028 Uiso calc R 1 . .
    C C4 1.00455(14) 0.0370(2) 0.67889(8) 0.0225(4) Uani d . 1 . .
    C C5 1.02622(17) 0.16855(19) 0.67799(8) 0.0290(4) Uani d . 1 . .
    H H5 0.9764 0.2218 0.6537 0.035 Uiso calc R 1 . .
    C C6 1.12054(18) 0.2222(2) 0.71256(8) 0.0342(5) Uani d . 1 . .
    H H6 1.1355 0.3118 0.7113 0.041 Uiso calc R 1 . .
    C C7 1.19285(19) 0.1460(2) 0.74877(9) 0.0371(5) Uani d . 1 . .
    H H7 1.2565 0.1831 0.7726 0.045 Uiso calc R 1 . .
    C C8 1.1719(2) 0.01596(19) 0.75000(9) 0.0367(5) Uani d . 1 . .
    H H8 1.2212 -0.0367 0.7748 0.044 Uiso calc R 1 . .
    C C9 1.07902(18) -0.0385(2) 0.71522(8) 0.0299(4) Uani d . 1 . .
    H H9 1.0660 -0.1284 0.7161 0.036 Uiso calc R 1 . .
    C C10A 0.4830(2) 0.2843(2) 0.51709(11) 0.0380(5) Uani d PD 0.876(2) A 1
    H H10A 0.4570 0.3718 0.5057 0.046 Uiso calc PR 0.876(2) A 1
    H H10B 0.5597 0.2916 0.5418 0.046 Uiso calc PR 0.876(2) A 1
    C C11A 0.3775(2) 0.2237(2) 0.55055(10) 0.0357(5) Uani d PD 0.876(2) A 1
    H H11A 0.3585 0.2774 0.5845 0.043 Uiso calc PR 0.876(2) A 1
    H H11B 0.2996 0.2209 0.5264 0.043 Uiso calc PR 0.876(2) A 1
    C C12A 0.2908(2) 0.0225(3) 0.58604(12) 0.0414(7) Uani d PD 0.876(2) A 1
    H H12A 0.2481 0.0669 0.6178 0.062 Uiso calc PR 0.876(2) A 1
    H H12B 0.3134 -0.0645 0.5981 0.062 Uiso calc PR 0.876(2) A 1
    H H12C 0.2331 0.0183 0.5529 0.062 Uiso calc PR 0.876(2) A 1
    C C13A 0.4872(2) 0.1012(3) 0.62330(10) 0.0349(6) Uani d PD 0.876(2) A 1
    H H13A 0.5625 0.1545 0.6160 0.052 Uiso calc PR 0.876(2) A 1
    H H13B 0.5146 0.0152 0.6347 0.052 Uiso calc PR 0.876(2) A 1
    H H13C 0.4362 0.1393 0.6542 0.052 Uiso calc PR 0.876(2) A 1
    C C10B 0.4830(2) 0.2843(2) 0.51709(11) 0.0380(5) Uani d PD 0.124(2) A 2
    H H10C 0.4035 0.3321 0.5085 0.046 Uiso calc PR 0.124(2) A 2
    H H10D 0.5513 0.3487 0.5226 0.046 Uiso calc PR 0.124(2) A 2
    C C11B 0.4646(17) 0.2216(12) 0.5714(6) 0.0357(5) Uani d PD 0.124(2) A 2
    H H11C 0.4091 0.2767 0.5954 0.043 Uiso calc PR 0.124(2) A 2
    H H11D 0.5486 0.2158 0.5908 0.043 Uiso calc PR 0.124(2) A 2
    C C12B 0.4164(17) 0.0223(17) 0.6232(6) 0.0414(7) Uani d PD 0.124(2) A 2
    H H12D 0.5055 -0.0021 0.6303 0.062 Uiso calc PR 0.124(2) A 2
    H H12E 0.3635 -0.0549 0.6206 0.062 Uiso calc PR 0.124(2) A 2
    H H12F 0.3858 0.0760 0.6549 0.062 Uiso calc PR 0.124(2) A 2
    C C13B 0.2641(11) 0.1099(17) 0.5594(7) 0.0349(6) Uani d PD 0.124(2) A 2
    H H13D 0.2241 0.1466 0.5937 0.052 Uiso calc PR 0.124(2) A 2
    H H13E 0.2254 0.0265 0.5510 0.052 Uiso calc PR 0.124(2) A 2
    H H13F 0.2509 0.1674 0.5267 0.052 Uiso calc PR 0.124(2) A 2
    Cu Cu1 0.5000 0.0000 0.5000 0.01941(15) Uani d S 1 . .
    N N1 0.40817(14) 0.09281(15) 0.56994(6) 0.0279(4) Uani d D 1 . .
    O O1 0.66630(11) 0.02623(12) 0.53766(5) 0.0259(3) Uani d . 1 . .
    O O2 0.69552(12) -0.14999(12) 0.59127(6) 0.0318(3) Uani d . 1 . .
    O O3 0.51449(12) 0.21311(13) 0.46707(6) 0.0302(3) Uani d D 1 . .
    H H3A 0.4506(18) 0.207(2) 0.4486(9) 0.045 Uiso d D 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 O2 . 1.248(2) ?
    C1 O1 . 1.277(2) ?
    C1 C2 . 1.488(2) ?
    C2 C3 . 1.327(3) ?
    C2 H2 . 0.9500 ?
    C3 C4 . 1.470(2) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.393(3) ?
    C4 C9 . 1.394(3) ?
    C5 C6 . 1.391(3) ?
    C5 H5 . 0.9500 ?
    C6 C7 . 1.385(3) ?
    C6 H6 . 0.9500 ?
    C7 C8 . 1.377(3) ?
    C7 H7 . 0.9500 ?
    C8 C9 . 1.386(3) ?
    C8 H8 . 0.9500 ?
    C9 H9 . 0.9500 ?
    C10A O3 . 1.421(3) ?
    C10A C11A . 1.492(3) ?
    C10A H10A . 0.9900 ?
    C10A H10B . 0.9900 ?
    C11A N1 . 1.476(3) ?
    C11A H11A . 0.9900 ?
    C11A H11B . 0.9900 ?
    C12A N1 . 1.479(3) ?
    C12A H12A . 0.9800 ?
    C12A H12B . 0.9800 ?
    C12A H12C . 0.9800 ?
    C13A N1 . 1.494(3) ?
    C13A H13A . 0.9800 ?
    C13A H13B . 0.9800 ?
    C13A H13C . 0.9800 ?
    C11B N1 . 1.470(13) ?
    C11B H11C . 0.9900 ?
    C11B H11D . 0.9900 ?
    C12B N1 . 1.445(13) ?
    C12B H12D . 0.9800 ?
    C12B H12E . 0.9800 ?
    C12B H12F . 0.9800 ?
    C13B N1 . 1.537(12) ?
    C13B H13D . 0.9800 ?
    C13B H13E . 0.9800 ?
    C13B H13F . 0.9800 ?
    Cu1 O1 . 1.9666(12) y
    Cu1 O1 5_656 1.9667(12) y
    Cu1 N1 . 2.1246(14) y
    Cu1 N1 5_656 2.1246(14) y
    Cu1 O3 5_656 2.3605(14) y
    Cu1 O3 . 2.3605(14) y
    O3 H3A . 0.797(16) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O2 C1 O1 . . 125.55(16) ?
    O2 C1 C2 . . 119.98(16) ?
    O1 C1 C2 . . 114.45(16) ?
    C3 C2 C1 . . 122.65(17) ?
    C3 C2 H2 . . 118.7 ?
    C1 C2 H2 . . 118.7 ?
    C2 C3 C4 . . 126.90(18) ?
    C2 C3 H3 . . 116.6 ?
    C4 C3 H3 . . 116.6 ?
    C5 C4 C9 . . 118.47(17) ?
    C5 C4 C3 . . 122.78(17) ?
    C9 C4 C3 . . 118.73(19) ?
    C6 C5 C4 . . 120.28(18) ?
    C6 C5 H5 . . 119.9 ?
    C4 C5 H5 . . 119.9 ?
    C7 C6 C5 . . 120.50(19) ?
    C7 C6 H6 . . 119.7 ?
    C5 C6 H6 . . 119.7 ?
    C8 C7 C6 . . 119.57(18) ?
    C8 C7 H7 . . 120.2 ?
    C6 C7 H7 . . 120.2 ?
    C7 C8 C9 . . 120.31(19) ?
    C7 C8 H8 . . 119.8 ?
    C9 C8 H8 . . 119.8 ?
    C8 C9 C4 . . 120.9(2) ?
    C8 C9 H9 . . 119.6 ?
    C4 C9 H9 . . 119.6 ?
    O3 C10A C11A . . 112.13(17) ?
    O3 C10A H10A . . 109.2 ?
    C11A C10A H10A . . 109.2 ?
    O3 C10A H10B . . 109.2 ?
    C11A C10A H10B . . 109.2 ?
    H10A C10A H10B . . 107.9 ?
    N1 C11A C10A . . 113.14(17) ?
    N1 C11A H11A . . 109.0 ?
    C10A C11A H11A . . 109.0 ?
    N1 C11A H11B . . 109.0 ?
    C10A C11A H11B . . 109.0 ?
    H11A C11A H11B . . 107.8 ?
    N1 C12A H12A . . 109.5 ?
    N1 C12A H12B . . 109.5 ?
    N1 C12A H12C . . 109.5 ?
    N1 C13A H13A . . 109.5 ?
    N1 C13A H13B . . 109.5 ?
    N1 C13A H13C . . 109.5 ?
    N1 C11B H11C . . 108.1 ?
    N1 C11B H11D . . 108.1 ?
    H11C C11B H11D . . 107.3 ?
    N1 C12B H12D . . 109.5 ?
    N1 C12B H12E . . 109.5 ?
    H12D C12B H12E . . 109.5 ?
    N1 C12B H12F . . 109.5 ?
    H12D C12B H12F . . 109.5 ?
    H12E C12B H12F . . 109.5 ?
    N1 C13B H13D . . 109.5 ?
    N1 C13B H13E . . 109.5 ?
    H13D C13B H13E . . 109.5 ?
    N1 C13B H13F . . 109.5 ?
    H13D C13B H13F . . 109.5 ?
    H13E C13B H13F . . 109.5 ?
    O1 Cu1 O1 . 5_656 180.0 y
    O1 Cu1 N1 . . 89.68(5) y
    O1 Cu1 N1 5_656 . 90.32(5) ?
    O1 Cu1 N1 . 5_656 90.32(5) y
    O1 Cu1 N1 5_656 5_656 89.68(5) ?
    N1 Cu1 N1 . 5_656 180.0 y
    O1 Cu1 O3 . 5_656 92.50(5) y
    O1 Cu1 O3 5_656 5_656 87.50(5) y
    N1 Cu1 O3 . 5_656 98.80(6) y
    N1 Cu1 O3 5_656 5_656 81.20(6) ?
    O1 Cu1 O3 . . 87.50(5) ?
    O1 Cu1 O3 5_656 . 92.50(5) ?
    N1 Cu1 O3 . . 81.20(6) y
    N1 Cu1 O3 5_656 . 98.80(6) ?
    O3 Cu1 O3 5_656 . 179.9980(10)
                                 y
    C12B N1 C11B . . 115.1(9) ?
    C11A N1 C12A . . 110.98(17) ?
    C11A N1 C13A . . 108.67(16) ?
    C12A N1 C13A . . 106.10(17) ?
    C12B N1 C13B . . 104.8(10) ?
    C11B N1 C13B . . 106.9(10) ?
    C12B N1 Cu1 . . 113.4(7) ?
    C11B N1 Cu1 . . 104.7(6) ?
    C11A N1 Cu1 . . 106.68(12) ?
    C12A N1 Cu1 . . 110.02(13) ?
    C13A N1 Cu1 . . 114.44(12) ?
    C13B N1 Cu1 . . 111.9(6) ?
    C1 O1 Cu1 . . 130.82(12) ?
    C10A O3 Cu1 . . 102.32(12) ?
    C10A O3 H3A . . 106.7(17) ?
    Cu1 O3 H3A . . 92.9(18) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O2 C1 C2 C3 . . . . 7.4(3) ?
    O1 C1 C2 C3 . . . . -173.90(17) ?
    C1 C2 C3 C4 . . . . -174.79(16) ?
    C2 C3 C4 C5 . . . . 3.4(3) ?
    C2 C3 C4 C9 . . . . -177.79(18) ?
    C9 C4 C5 C6 . . . . 0.2(3) ?
    C3 C4 C5 C6 . . . . 178.99(17) ?
    C4 C5 C6 C7 . . . . -0.8(3) ?
    C5 C6 C7 C8 . . . . 0.7(3) ?
    C6 C7 C8 C9 . . . . 0.0(3) ?
    C7 C8 C9 C4 . . . . -0.6(3) ?
    C5 C4 C9 C8 . . . . 0.5(3) ?
    C3 C4 C9 C8 . . . . -178.31(18) ?
    O3 C10A C11A N1 . . . . 59.4(3) ?
    C10A C11A N1 C12B . . . . 122.4(11) ?
    C10A C11A N1 C11B . . . . 51.3(9) ?
    C10A C11A N1 C12A . . . . -161.99(19) ?
    C10A C11A N1 C13A . . . . 81.7(2) ?
    C10A C11A N1 C13B . . . . -149.6(6) ?
    C10A C11A N1 Cu1 . . . . -42.1(2) ?
    O1 Cu1 N1 C12B . . . . -66.8(8) ?
    O1 Cu1 N1 C12B 5_656 . . . 113.2(8) ?
    O3 Cu1 N1 C12B 5_656 . . . 25.7(8) ?
    O3 Cu1 N1 C12B . . . . -154.3(8) ?
    O1 Cu1 N1 C11B . . . . 59.5(7) ?
    O1 Cu1 N1 C11B 5_656 . . . -120.5(7) ?
    O3 Cu1 N1 C11B 5_656 . . . 152.0(7) ?
    O3 Cu1 N1 C11B . . . . -28.0(7) ?
    O1 Cu1 N1 C11A . . . . 102.10(13) ?
    O1 Cu1 N1 C11A 5_656 . . . -77.90(13) ?
    O3 Cu1 N1 C11A 5_656 . . . -165.42(12) ?
    O3 Cu1 N1 C11A . . . . 14.58(12) ?
    O1 Cu1 N1 C12A . . . . -137.44(15) ?
    O1 Cu1 N1 C12A 5_656 . . . 42.56(15) ?
    O3 Cu1 N1 C12A 5_656 . . . -44.96(15) ?
    O3 Cu1 N1 C12A . . . . 135.04(15) ?
    O1 Cu1 N1 C13A . . . . -18.11(15) ?
    O1 Cu1 N1 C13A 5_656 . . . 161.89(15) ?
    O3 Cu1 N1 C13A 5_656 . . . 74.37(14) ?
    O3 Cu1 N1 C13A . . . . -105.63(14) ?
    O1 Cu1 N1 C13B . . . . 174.9(7) ?
    O1 Cu1 N1 C13B 5_656 . . . -5.1(7) ?
    O3 Cu1 N1 C13B 5_656 . . . -92.6(7) ?
    O3 Cu1 N1 C13B . . . . 87.4(7) ?
    O2 C1 O1 Cu1 . . . . 15.8(3) ?
    C2 C1 O1 Cu1 . . . . -162.77(12) ?
    N1 Cu1 O1 C1 . . . . 83.37(16) ?
    N1 Cu1 O1 C1 5_656 . . . -96.63(16) ?
    O3 Cu1 O1 C1 5_656 . . . -15.43(16) ?
    O3 Cu1 O1 C1 . . . . 164.57(16) ?
    C11A C10A O3 Cu1 . . . . -39.50(19) ?
    O1 Cu1 O3 C10A . . . . -76.72(11) ?
    O1 Cu1 O3 C10A 5_656 . . . 103.28(11) ?
    N1 Cu1 O3 C10A . . . . 13.34(11) ?
    N1 Cu1 O3 C10A 5_656 . . . -166.66(11) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    O3 H3A O2 5_656 0.797(16) 1.886(17) 2.6650(18) 166(2)
data_global
_journal_date_recd_electronic     2007-03-09
_journal_date_accepted     2007-03-20
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      5
_journal_page_first     m1243
_journal_page_last     m1245
_journal_paper_category     EM
_journal_coeditor_code     SJ2247
_publ_contact_author_name     'Prof. Dr. Muhammad Mazhar'
_publ_contact_author_address
;
Department of Chemistry, Quaid-i-Azam University Islamabad, 45320 Pakistan
;
_publ_contact_author_email     mazhar42pk@yahoo.com
_publ_contact_author_fax     ' +92-051-9219888'
_publ_contact_author_phone
                    92000000000000E294
_publ_section_title
;\
Bis(cinnamato-κO)bis[2-(dimethylamino)ethanol-κ²N,O]\
copper(II)
;
loop_
    _publ_author_name
    _publ_author_address
    'Tahir, Asif A.'
;
Department of Chemistry
Quaid-i-Azam University
Islamabad 45320
Pakistan
;
    'Hamid, Mazhar'
;
Department of Chemistry
Quaid-i-Azam University
Islamabad 45320
Pakistan
;
    'Mazhar, Muhammad'
;
Department of Chemistry
Quaid-i-Azam University
Islamabad 45320
Pakistan
;
    'Molloy. Kieran C. '
;
Department of Chemistry
University of Bath
Claverton Down
Bath BA2 7AY
England
;
