##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Tetramethylammonium bis(2-benzoylbenzoato-κO)triphenylstannate(IV)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C50 H45 N O6 Sn'
_chemical_formula_sum     'C50 H45 N O6 Sn'
_chemical_formula_iupac     '(C4 H12 N) [Sn (C6 H5)3 (C14 H9 O3)2]'
_chemical_formula_weight     874.56
_chemical_melting_point     ?
_symmetry_cell_setting     'monoclinic'
_symmetry_space_group_name_H-M     'P 21/n'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     9.7481(11)
_cell_length_b     29.787(5)
_cell_length_c     14.704(5)
_cell_angle_alpha     90.00
_cell_angle_beta     98.793(14)
_cell_angle_gamma     90.00
_cell_volume     4219.3(16)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     25
_cell_measurement_theta_min     13.16
_cell_measurement_theta_max     13.83
_cell_measurement_temperature     293(2)
_exptl_crystal_description     'prism'
_exptl_crystal_colour     'colourless'
_exptl_crystal_size_max     0.50
_exptl_crystal_size_mid     0.30
_exptl_crystal_size_min     0.30
_exptl_crystal_density_diffrn     1.377
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1800
_exptl_absorpt_coefficient_mu     0.657
_exptl_absorpt_correction_type     empirical
_exptl_absorpt_process_details     'ψ scan (North et al.,  1968)'
_exptl_absorpt_correction_T_min     0.7348
_exptl_absorpt_correction_T_max     0.8273
_exptl_special_details
;
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Enraf--Nonius MACH3'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     18605
_diffrn_reflns_av_R_equivalents     0.0543
_diffrn_reflns_av_sigmaI/netI     0.2400
_diffrn_reflns_theta_min     2.22
_diffrn_reflns_theta_max     34.24
_diffrn_reflns_theta_full     34.24
_diffrn_measured_fraction_theta_max     0.999
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -15
_diffrn_reflns_limit_h_max     0
_diffrn_reflns_limit_k_min     0
_diffrn_reflns_limit_k_max     47
_diffrn_reflns_limit_l_min     -23
_diffrn_reflns_limit_l_max     23
_diffrn_standards_number     3
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     120
_diffrn_standards_decay_%     0
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     17529
_reflns_number_gt     6852
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.2418
_refine_ls_R_factor_gt     0.0528
_refine_ls_wR_factor_gt     0.0908
_refine_ls_wR_factor_ref     0.1211
_refine_ls_goodness_of_fit_ref     0.964
_refine_ls_restrained_S_all     0.964
_refine_ls_number_reflns     17529
_refine_ls_number_parameters     527
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                 'calc w=1/[σ²(Fo²)+(0.0351P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.663
_refine_diff_density_min     -1.878
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'Sn' 'Sn' -0.6537 1.4246
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'CAD-4 EXPRESS (Enraf--Nonius, 1994)'
_computing_cell_refinement     'CAD-4 EXPRESS'
_computing_data_reduction     'GENHKL (Kretschmar, 1997)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'PLATON99 (Spek, 1999)'
_computing_publication_material     SHELXL97
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Sn Sn1 0.05137(2) 0.120998(6) 0.701655(14) 0.03251(6) Uani d . 1 . .
    O O41 0.1075(2) 0.19325(7) 0.68249(15) 0.0426(5) Uani d . 1 . .
    O O42 0.3198(2) 0.20560(7) 0.76120(17) 0.0523(6) Uani d . 1 . .
    O O43 0.4707(3) 0.26604(9) 0.64239(17) 0.0667(8) Uani d . 1 . .
    O O61 -0.0244(2) 0.05184(6) 0.71583(14) 0.0383(5) Uani d . 1 . .
    O O62 -0.2021(2) 0.07088(8) 0.78754(18) 0.0595(7) Uani d . 1 . .
    O O63 0.0909(3) -0.04671(10) 0.6440(2) 0.0854(10) Uani d . 1 . .
    C C11 -0.1295(3) 0.13715(10) 0.6065(2) 0.0352(7) Uani d . 1 . .
    C C12 -0.1661(3) 0.10951(11) 0.5312(2) 0.0449(8) Uani d . 1 . .
    H H12 -0.1178 0.0829 0.5271 0.054 Uiso calc R 1 . .
    C C13 -0.2726(4) 0.12056(14) 0.4619(3) 0.0614(10) Uani d . 1 . .
    H H13 -0.2944 0.1015 0.4117 0.074 Uiso calc R 1 . .
    C C14 -0.3464(4) 0.15923(15) 0.4662(3) 0.0669(11) Uani d . 1 . .
    H H14 -0.4176 0.1668 0.4191 0.080 Uiso calc R 1 . .
    C C15 -0.3137(4) 0.18682(13) 0.5415(3) 0.0667(12) Uani d . 1 . .
    H H15 -0.3647 0.2129 0.5461 0.080 Uiso calc R 1 . .
    C C16 -0.2057(4) 0.17603(11) 0.6103(3) 0.0503(9) Uani d . 1 . .
    H H16 -0.1838 0.1953 0.6601 0.060 Uiso calc R 1 . .
    C C21 0.0865(3) 0.13229(10) 0.8466(2) 0.0382(7) Uani d . 1 . .
    C C22 0.0685(4) 0.17350(12) 0.8858(3) 0.0582(10) Uani d . 1 . .
    H H22 0.0373 0.1976 0.8480 0.070 Uiso calc R 1 . .
    C C23 0.0957(5) 0.17984(15) 0.9797(3) 0.0795(14) Uani d . 1 . .
    H H23 0.0823 0.2079 1.0045 0.095 Uiso calc R 1 . .
    C C24 0.1427(5) 0.14456(19) 1.0369(3) 0.0828(15) Uani d . 1 . .
    H H24 0.1604 0.1486 1.1003 0.099 Uiso calc R 1 . .
    C C25 0.1633(4) 0.10334(16) 0.9990(3) 0.0717(12) Uani d . 1 . .
    H H25 0.1975 0.0796 1.0369 0.086 Uiso calc R 1 . .
    C C26 0.1332(4) 0.09715(12) 0.9051(2) 0.0523(9) Uani d . 1 . .
    H H26 0.1445 0.0689 0.8805 0.063 Uiso calc R 1 . .
    C C31 0.2143(3) 0.09266(10) 0.6381(2) 0.0360(7) Uani d . 1 . .
    C C32 0.3432(3) 0.11260(11) 0.6441(2) 0.0481(9) Uani d . 1 . .
    H H32 0.3590 0.1397 0.6753 0.058 Uiso calc R 1 . .
    C C33 0.4497(4) 0.09351(14) 0.6049(3) 0.0621(11) Uani d . 1 . .
    H H33 0.5361 0.1074 0.6110 0.075 Uiso calc R 1 . .
    C C34 0.4270(4) 0.05410(13) 0.5571(3) 0.0604(10) Uani d . 1 . .
    H H34 0.4983 0.0410 0.5309 0.073 Uiso calc R 1 . .
    C C35 0.2995(4) 0.03394(12) 0.5478(3) 0.0629(11) Uani d . 1 . .
    H H35 0.2837 0.0075 0.5143 0.075 Uiso calc R 1 . .
    C C36 0.1941(4) 0.05293(11) 0.5883(2) 0.0520(9) Uani d . 1 . .
    H H36 0.1081 0.0388 0.5820 0.062 Uiso calc R 1 . .
    C C41 0.2087(3) 0.21802(10) 0.7176(2) 0.0356(7) Uani d . 1 . .
    C C42 0.1822(3) 0.26829(10) 0.7067(2) 0.0338(7) Uani d . 1 . .
    C C43 0.0486(4) 0.28496(11) 0.6975(2) 0.0470(8) Uani d . 1 . .
    H H43 -0.0260 0.2652 0.6924 0.056 Uiso calc R 1 . .
    C C44 0.0243(4) 0.33082(12) 0.6957(2) 0.0566(10) Uani d . 1 . .
    H H44 -0.0661 0.3417 0.6892 0.068 Uiso calc R 1 . .
    C C45 0.1343(4) 0.36020(12) 0.7035(3) 0.0583(10) Uani d . 1 . .
    H H45 0.1183 0.3910 0.7034 0.070 Uiso calc R 1 . .
    C C46 0.2684(4) 0.34403(11) 0.7117(2) 0.0524(9) Uani d . 1 . .
    H H46 0.3424 0.3640 0.7164 0.063 Uiso calc R 1 . .
    C C47 0.2937(3) 0.29816(10) 0.7129(2) 0.0382(7) Uani d . 1 . .
    C C48 0.4400(4) 0.28256(11) 0.7118(2) 0.0428(8) Uani d . 1 . .
    C C49 0.5466(3) 0.29081(10) 0.7944(2) 0.0396(7) Uani d . 1 . .
    C C50 0.5108(4) 0.30348(12) 0.8785(2) 0.0528(9) Uani d . 1 . .
    H H50 0.4182 0.3082 0.8841 0.063 Uiso calc R 1 . .
    C C51 0.6123(5) 0.30904(14) 0.9537(3) 0.0695(12) Uani d . 1 . .
    H H51 0.5878 0.3180 1.0096 0.083 Uiso calc R 1 . .
    C C52 0.7492(5) 0.30157(15) 0.9470(3) 0.0742(13) Uani d . 1 . .
    H H52 0.8168 0.3050 0.9984 0.089 Uiso calc R 1 . .
    C C53 0.7865(4) 0.28910(13) 0.8643(3) 0.0643(11) Uani d . 1 . .
    H H53 0.8794 0.2842 0.8597 0.077 Uiso calc R 1 . .
    C C54 0.6859(4) 0.28388(11) 0.7879(3) 0.0492(9) Uani d . 1 . .
    H H54 0.7115 0.2757 0.7319 0.059 Uiso calc R 1 . .
    C C61 -0.1389(3) 0.04399(10) 0.7468(2) 0.0380(7) Uani d . 1 . .
    C C62 -0.1970(3) -0.00272(10) 0.7274(2) 0.0392(7) Uani d . 1 . .
    C C63 -0.3387(4) -0.00844(12) 0.7236(3) 0.0524(9) Uani d . 1 . .
    H H63 -0.3932 0.0156 0.7371 0.063 Uiso calc R 1 . .
    C C64 -0.4001(4) -0.04973(14) 0.6997(3) 0.0695(12) Uani d . 1 . .
    H H64 -0.4951 -0.0534 0.6984 0.083 Uiso calc R 1 . .
    C C65 -0.3219(5) -0.08466(13) 0.6784(3) 0.0752(13) Uani d . 1 . .
    H H65 -0.3638 -0.1121 0.6616 0.090 Uiso calc R 1 . .
    C C66 -0.1823(5) -0.07988(11) 0.6813(3) 0.0645(11) Uani d . 1 . .
    H H66 -0.1299 -0.1041 0.6665 0.077 Uiso calc R 1 . .
    C C67 -0.1170(4) -0.03903(10) 0.7062(2) 0.0456(8) Uani d . 1 . .
    C C68 0.0386(4) -0.03697(11) 0.7104(3) 0.0539(10) Uani d . 1 . .
    C C69 0.1260(4) -0.02751(11) 0.8003(3) 0.0530(10) Uani d . 1 . .
    C C70 0.0771(4) -0.03359(12) 0.8829(3) 0.0624(11) Uani d . 1 . .
    H H70 -0.0143 -0.0426 0.8826 0.075 Uiso calc R 1 . .
    C C71 0.1616(5) -0.02650(15) 0.9657(3) 0.0853(15) Uani d . 1 . .
    H H71 0.1280 -0.0311 1.0209 0.102 Uiso calc R 1 . .
    C C72 0.2967(7) -0.01256(17) 0.9659(5) 0.109(2) Uani d . 1 . .
    H H72 0.3547 -0.0073 1.0212 0.131 Uiso calc R 1 . .
    C C73 0.3450(5) -0.00648(18) 0.8831(5) 0.108(2) Uani d . 1 . .
    H H73 0.4359 0.0030 0.8831 0.130 Uiso calc R 1 . .
    C C74 0.2612(4) -0.01418(13) 0.8013(4) 0.0745(13) Uani d . 1 . .
    H H74 0.2957 -0.0104 0.7462 0.089 Uiso calc R 1 . .
    N N1 0.1092(3) 0.34922(10) 0.4033(2) 0.0514(8) Uani d . 1 . .
    C C1 0.1423(4) 0.33287(12) 0.3134(2) 0.0609(10) Uani d . 1 . .
    H H1A 0.1758 0.3574 0.2807 0.091 Uiso calc R 1 . .
    H H1B 0.0600 0.3207 0.2777 0.091 Uiso calc R 1 . .
    H H1C 0.2122 0.3100 0.3240 0.091 Uiso calc R 1 . .
    C C2 0.0415(6) 0.31328(16) 0.4493(3) 0.114(2) Uani d . 1 . .
    H H2A -0.0365 0.3019 0.4080 0.171 Uiso calc R 1 . .
    H H2B 0.0102 0.3251 0.5033 0.171 Uiso calc R 1 . .
    H H2C 0.1066 0.2895 0.4666 0.171 Uiso calc R 1 . .
    C C3 0.2387(5) 0.36385(16) 0.4622(3) 0.0860(14) Uani d . 1 . .
    H H3A 0.2960 0.3382 0.4801 0.129 Uiso calc R 1 . .
    H H3B 0.2161 0.3785 0.5161 0.129 Uiso calc R 1 . .
    H H3C 0.2880 0.3843 0.4285 0.129 Uiso calc R 1 . .
    C C4 0.0155(5) 0.38824(16) 0.3847(4) 0.1048(18) Uani d . 1 . .
    H H4A 0.0614 0.4115 0.3556 0.157 Uiso calc R 1 . .
    H H4B -0.0085 0.3992 0.4416 0.157 Uiso calc R 1 . .
    H H4C -0.0673 0.3793 0.3448 0.157 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Sn1 C11 . 2.132(3) y
    Sn1 C21 . 2.133(3) y
    Sn1 C31 . 2.136(3) y
    Sn1 O61 . 2.2092(19) y
    Sn1 O41 . 2.249(2) y
    O41 C41 . 1.276(3) ?
    O42 C41 . 1.228(4) ?
    O43 C48 . 1.211(4) ?
    O61 C61 . 1.290(4) ?
    O62 C61 . 1.221(4) ?
    O63 C68 . 1.203(4) ?
    C11 C16 . 1.381(4) ?
    C11 C12 . 1.382(4) ?
    C12 C13 . 1.378(5) ?
    C12 H12 . 0.9300 ?
    C13 C14 . 1.365(5) ?
    C13 H13 . 0.9300 ?
    C14 C15 . 1.376(5) ?
    C14 H14 . 0.9300 ?
    C15 C16 . 1.382(5) ?
    C15 H15 . 0.9300 ?
    C16 H16 . 0.9300 ?
    C21 C22 . 1.379(4) ?
    C21 C26 . 1.387(4) ?
    C22 C23 . 1.378(5) ?
    C22 H22 . 0.9300 ?
    C23 C24 . 1.380(6) ?
    C23 H23 . 0.9300 ?
    C24 C25 . 1.375(6) ?
    C24 H24 . 0.9300 ?
    C25 C26 . 1.380(5) ?
    C25 H25 . 0.9300 ?
    C26 H26 . 0.9300 ?
    C31 C32 . 1.381(4) ?
    C31 C36 . 1.390(4) ?
    C32 C33 . 1.384(5) ?
    C32 H32 . 0.9300 ?
    C33 C34 . 1.369(5) ?
    C33 H33 . 0.9300 ?
    C34 C35 . 1.368(5) ?
    C34 H34 . 0.9300 ?
    C35 C36 . 1.384(5) ?
    C35 H35 . 0.9300 ?
    C36 H36 . 0.9300 ?
    C41 C42 . 1.524(4) ?
    C42 C43 . 1.382(4) ?
    C42 C47 . 1.396(4) ?
    C43 C44 . 1.386(5) ?
    C43 H43 . 0.9300 ?
    C44 C45 . 1.375(5) ?
    C44 H44 . 0.9300 ?
    C45 C46 . 1.381(5) ?
    C45 H45 . 0.9300 ?
    C46 C47 . 1.388(4) ?
    C46 H46 . 0.9300 ?
    C47 C48 . 1.502(4) ?
    C48 C49 . 1.493(5) ?
    C49 C50 . 1.387(4) ?
    C49 C54 . 1.391(4) ?
    C50 C51 . 1.376(5) ?
    C50 H50 . 0.9300 ?
    C51 C52 . 1.371(6) ?
    C51 H51 . 0.9300 ?
    C52 C53 . 1.372(5) ?
    C52 H52 . 0.9300 ?
    C53 C54 . 1.382(5) ?
    C53 H53 . 0.9300 ?
    C54 H54 . 0.9300 ?
    C61 C62 . 1.513(4) ?
    C62 C63 . 1.384(4) ?
    C62 C67 . 1.396(4) ?
    C63 C64 . 1.389(5) ?
    C63 H63 . 0.9300 ?
    C64 C65 . 1.355(6) ?
    C64 H64 . 0.9300 ?
    C65 C66 . 1.362(5) ?
    C65 H65 . 0.9300 ?
    C66 C67 . 1.396(4) ?
    C66 H66 . 0.9300 ?
    C67 C68 . 1.510(5) ?
    C68 C69 . 1.486(5) ?
    C69 C74 . 1.375(5) ?
    C69 C70 . 1.384(5) ?
    C70 C71 . 1.378(6) ?
    C70 H70 . 0.9300 ?
    C71 C72 . 1.381(7) ?
    C71 H71 . 0.9300 ?
    C72 C73 . 1.383(8) ?
    C72 H72 . 0.9300 ?
    C73 C74 . 1.366(7) ?
    C73 H73 . 0.9300 ?
    C74 H74 . 0.9300 ?
    N1 C2 . 1.476(5) ?
    N1 C4 . 1.478(5) ?
    N1 C3 . 1.483(5) ?
    N1 C1 . 1.488(4) ?
    C1 H1A . 0.9600 ?
    C1 H1B . 0.9600 ?
    C1 H1C . 0.9600 ?
    C2 H2A . 0.9600 ?
    C2 H2B . 0.9600 ?
    C2 H2C . 0.9600 ?
    C3 H3A . 0.9600 ?
    C3 H3B . 0.9600 ?
    C3 H3C . 0.9600 ?
    C4 H4A . 0.9600 ?
    C4 H4B . 0.9600 ?
    C4 H4C . 0.9600 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C11 Sn1 C21 . . 127.64(12) y
    C11 Sn1 C31 . . 113.45(12) y
    C21 Sn1 C31 . . 118.86(12) y
    C11 Sn1 O61 . . 90.99(10) y
    C21 Sn1 O61 . . 93.31(10) y
    C31 Sn1 O61 . . 87.39(10) y
    C11 Sn1 O41 . . 83.95(10) y
    C21 Sn1 O41 . . 88.24(10) y
    C31 Sn1 O41 . . 96.43(10) y
    O61 Sn1 O41 . . 174.56(8) y
    C41 O41 Sn1 . . 133.7(2) ?
    C61 O61 Sn1 . . 121.49(18) ?
    C16 C11 C12 . . 117.2(3) ?
    C16 C11 Sn1 . . 123.9(2) ?
    C12 C11 Sn1 . . 118.5(2) ?
    C13 C12 C11 . . 121.5(3) ?
    C13 C12 H12 . . 119.2 ?
    C11 C12 H12 . . 119.2 ?
    C14 C13 C12 . . 120.7(4) ?
    C14 C13 H13 . . 119.7 ?
    C12 C13 H13 . . 119.7 ?
    C13 C14 C15 . . 118.8(4) ?
    C13 C14 H14 . . 120.6 ?
    C15 C14 H14 . . 120.6 ?
    C14 C15 C16 . . 120.5(4) ?
    C14 C15 H15 . . 119.8 ?
    C16 C15 H15 . . 119.8 ?
    C11 C16 C15 . . 121.3(3) ?
    C11 C16 H16 . . 119.4 ?
    C15 C16 H16 . . 119.4 ?
    C22 C21 C26 . . 117.6(3) ?
    C22 C21 Sn1 . . 123.2(3) ?
    C26 C21 Sn1 . . 119.2(2) ?
    C23 C22 C21 . . 121.6(4) ?
    C23 C22 H22 . . 119.2 ?
    C21 C22 H22 . . 119.2 ?
    C22 C23 C24 . . 120.1(4) ?
    C22 C23 H23 . . 120.0 ?
    C24 C23 H23 . . 120.0 ?
    C25 C24 C23 . . 119.3(4) ?
    C25 C24 H24 . . 120.4 ?
    C23 C24 H24 . . 120.4 ?
    C24 C25 C26 . . 120.2(4) ?
    C24 C25 H25 . . 119.9 ?
    C26 C25 H25 . . 119.9 ?
    C25 C26 C21 . . 121.3(4) ?
    C25 C26 H26 . . 119.4 ?
    C21 C26 H26 . . 119.4 ?
    C32 C31 C36 . . 117.0(3) ?
    C32 C31 Sn1 . . 122.2(2) ?
    C36 C31 Sn1 . . 120.8(2) ?
    C31 C32 C33 . . 122.0(3) ?
    C31 C32 H32 . . 119.0 ?
    C33 C32 H32 . . 119.0 ?
    C34 C33 C32 . . 119.6(4) ?
    C34 C33 H33 . . 120.2 ?
    C32 C33 H33 . . 120.2 ?
    C35 C34 C33 . . 120.1(4) ?
    C35 C34 H34 . . 120.0 ?
    C33 C34 H34 . . 120.0 ?
    C34 C35 C36 . . 120.0(3) ?
    C34 C35 H35 . . 120.0 ?
    C36 C35 H35 . . 120.0 ?
    C35 C36 C31 . . 121.3(3) ?
    C35 C36 H36 . . 119.3 ?
    C31 C36 H36 . . 119.3 ?
    O42 C41 O41 . . 127.0(3) ?
    O42 C41 C42 . . 118.2(3) ?
    O41 C41 C42 . . 114.7(3) ?
    C43 C42 C47 . . 119.3(3) ?
    C43 C42 C41 . . 120.4(3) ?
    C47 C42 C41 . . 120.1(3) ?
    C42 C43 C44 . . 120.8(3) ?
    C42 C43 H43 . . 119.6 ?
    C44 C43 H43 . . 119.6 ?
    C45 C44 C43 . . 119.8(4) ?
    C45 C44 H44 . . 120.1 ?
    C43 C44 H44 . . 120.1 ?
    C44 C45 C46 . . 120.1(3) ?
    C44 C45 H45 . . 120.0 ?
    C46 C45 H45 . . 120.0 ?
    C45 C46 C47 . . 120.5(3) ?
    C45 C46 H46 . . 119.7 ?
    C47 C46 H46 . . 119.7 ?
    C46 C47 C42 . . 119.4(3) ?
    C46 C47 C48 . . 118.1(3) ?
    C42 C47 C48 . . 122.2(3) ?
    O43 C48 C49 . . 121.4(3) ?
    O43 C48 C47 . . 119.5(3) ?
    C49 C48 C47 . . 119.0(3) ?
    C50 C49 C54 . . 118.8(3) ?
    C50 C49 C48 . . 122.1(3) ?
    C54 C49 C48 . . 119.0(3) ?
    C51 C50 C49 . . 120.1(4) ?
    C51 C50 H50 . . 120.0 ?
    C49 C50 H50 . . 120.0 ?
    C52 C51 C50 . . 120.7(4) ?
    C52 C51 H51 . . 119.6 ?
    C50 C51 H51 . . 119.6 ?
    C51 C52 C53 . . 120.0(4) ?
    C51 C52 H52 . . 120.0 ?
    C53 C52 H52 . . 120.0 ?
    C52 C53 C54 . . 119.9(4) ?
    C52 C53 H53 . . 120.0 ?
    C54 C53 H53 . . 120.0 ?
    C53 C54 C49 . . 120.4(3) ?
    C53 C54 H54 . . 119.8 ?
    C49 C54 H54 . . 119.8 ?
    O62 C61 O61 . . 125.6(3) ?
    O62 C61 C62 . . 119.6(3) ?
    O61 C61 C62 . . 114.8(3) ?
    C63 C62 C67 . . 118.9(3) ?
    C63 C62 C61 . . 117.6(3) ?
    C67 C62 C61 . . 123.3(3) ?
    C62 C63 C64 . . 120.5(4) ?
    C62 C63 H63 . . 119.7 ?
    C64 C63 H63 . . 119.7 ?
    C65 C64 C63 . . 120.2(4) ?
    C65 C64 H64 . . 119.9 ?
    C63 C64 H64 . . 119.9 ?
    C64 C65 C66 . . 120.5(4) ?
    C64 C65 H65 . . 119.8 ?
    C66 C65 H65 . . 119.8 ?
    C65 C66 C67 . . 120.8(4) ?
    C65 C66 H66 . . 119.6 ?
    C67 C66 H66 . . 119.6 ?
    C66 C67 C62 . . 119.1(3) ?
    C66 C67 C68 . . 117.5(3) ?
    C62 C67 C68 . . 123.5(3) ?
    O63 C68 C69 . . 120.7(4) ?
    O63 C68 C67 . . 120.3(4) ?
    C69 C68 C67 . . 118.7(3) ?
    C74 C69 C70 . . 119.1(4) ?
    C74 C69 C68 . . 118.9(4) ?
    C70 C69 C68 . . 121.9(4) ?
    C71 C70 C69 . . 121.1(4) ?
    C71 C70 H70 . . 119.5 ?
    C69 C70 H70 . . 119.5 ?
    C70 C71 C72 . . 119.2(5) ?
    C70 C71 H71 . . 120.4 ?
    C72 C71 H71 . . 120.4 ?
    C71 C72 C73 . . 119.4(5) ?
    C71 C72 H72 . . 120.3 ?
    C73 C72 H72 . . 120.3 ?
    C74 C73 C72 . . 121.0(5) ?
    C74 C73 H73 . . 119.5 ?
    C72 C73 H73 . . 119.5 ?
    C73 C74 C69 . . 120.1(5) ?
    C73 C74 H74 . . 119.9 ?
    C69 C74 H74 . . 119.9 ?
    C2 N1 C4 . . 110.4(4) ?
    C2 N1 C3 . . 110.2(3) ?
    C4 N1 C3 . . 108.9(3) ?
    C2 N1 C1 . . 110.1(3) ?
    C4 N1 C1 . . 107.7(3) ?
    C3 N1 C1 . . 109.5(3) ?
    N1 C1 H1A . . 109.5 ?
    N1 C1 H1B . . 109.5 ?
    H1A C1 H1B . . 109.5 ?
    N1 C1 H1C . . 109.5 ?
    H1A C1 H1C . . 109.5 ?
    H1B C1 H1C . . 109.5 ?
    N1 C2 H2A . . 109.5 ?
    N1 C2 H2B . . 109.5 ?
    H2A C2 H2B . . 109.5 ?
    N1 C2 H2C . . 109.5 ?
    H2A C2 H2C . . 109.5 ?
    H2B C2 H2C . . 109.5 ?
    N1 C3 H3A . . 109.5 ?
    N1 C3 H3B . . 109.5 ?
    H3A C3 H3B . . 109.5 ?
    N1 C3 H3C . . 109.5 ?
    H3A C3 H3C . . 109.5 ?
    H3B C3 H3C . . 109.5 ?
    N1 C4 H4A . . 109.5 ?
    N1 C4 H4B . . 109.5 ?
    H4A C4 H4B . . 109.5 ?
    N1 C4 H4C . . 109.5 ?
    H4A C4 H4C . . 109.5 ?
    H4B C4 H4C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C11 Sn1 O41 C41 . . . . 177.5(3) ?
    C21 Sn1 O41 C41 . . . . 49.4(3) ?
    C31 Sn1 O41 C41 . . . . -69.5(3) ?
    O61 Sn1 O41 C41 . . . . 156.0(7) ?
    C11 Sn1 O61 C61 . . . . -61.3(2) ?
    C21 Sn1 O61 C61 . . . . 66.5(2) ?
    C31 Sn1 O61 C61 . . . . -174.7(2) ?
    O41 Sn1 O61 C61 . . . . -39.9(9) ?
    C21 Sn1 C11 C16 . . . . 39.3(3) ?
    C31 Sn1 C11 C16 . . . . -138.2(3) ?
    O61 Sn1 C11 C16 . . . . 134.2(3) ?
    O41 Sn1 C11 C16 . . . . -43.8(3) ?
    C21 Sn1 C11 C12 . . . . -147.2(2) ?
    C31 Sn1 C11 C12 . . . . 35.3(3) ?
    O61 Sn1 C11 C12 . . . . -52.3(3) ?
    O41 Sn1 C11 C12 . . . . 129.7(3) ?
    C16 C11 C12 C13 . . . . 1.0(5) ?
    Sn1 C11 C12 C13 . . . . -172.9(3) ?
    C11 C12 C13 C14 . . . . -0.6(6) ?
    C12 C13 C14 C15 . . . . -0.7(6) ?
    C13 C14 C15 C16 . . . . 1.6(6) ?
    C12 C11 C16 C15 . . . . -0.1(5) ?
    Sn1 C11 C16 C15 . . . . 173.4(3) ?
    C14 C15 C16 C11 . . . . -1.2(6) ?
    C11 Sn1 C21 C22 . . . . -52.3(3) ?
    C31 Sn1 C21 C22 . . . . 125.1(3) ?
    O61 Sn1 C21 C22 . . . . -146.1(3) ?
    O41 Sn1 C21 C22 . . . . 28.7(3) ?
    C11 Sn1 C21 C26 . . . . 129.5(3) ?
    C31 Sn1 C21 C26 . . . . -53.2(3) ?
    O61 Sn1 C21 C26 . . . . 35.7(3) ?
    O41 Sn1 C21 C26 . . . . -149.5(3) ?
    C26 C21 C22 C23 . . . . 0.0(6) ?
    Sn1 C21 C22 C23 . . . . -178.3(3) ?
    C21 C22 C23 C24 . . . . 0.3(7) ?
    C22 C23 C24 C25 . . . . 0.6(7) ?
    C23 C24 C25 C26 . . . . -1.9(7) ?
    C24 C25 C26 C21 . . . . 2.2(6) ?
    C22 C21 C26 C25 . . . . -1.3(5) ?
    Sn1 C21 C26 C25 . . . . 177.1(3) ?
    C11 Sn1 C31 C32 . . . . 119.8(3) ?
    C21 Sn1 C31 C32 . . . . -57.9(3) ?
    O61 Sn1 C31 C32 . . . . -150.2(3) ?
    O41 Sn1 C31 C32 . . . . 33.6(3) ?
    C11 Sn1 C31 C36 . . . . -60.0(3) ?
    C21 Sn1 C31 C36 . . . . 122.3(3) ?
    O61 Sn1 C31 C36 . . . . 30.0(3) ?
    O41 Sn1 C31 C36 . . . . -146.2(3) ?
    C36 C31 C32 C33 . . . . -2.0(5) ?
    Sn1 C31 C32 C33 . . . . 178.2(3) ?
    C31 C32 C33 C34 . . . . 1.3(6) ?
    C32 C33 C34 C35 . . . . 0.4(6) ?
    C33 C34 C35 C36 . . . . -1.3(6) ?
    C34 C35 C36 C31 . . . . 0.6(6) ?
    C32 C31 C36 C35 . . . . 1.0(5) ?
    Sn1 C31 C36 C35 . . . . -179.2(3) ?
    Sn1 O41 C41 O42 . . . . 15.1(5) ?
    Sn1 O41 C41 C42 . . . . -161.87(19) ?
    O42 C41 C42 C43 . . . . -150.9(3) ?
    O41 C41 C42 C43 . . . . 26.4(4) ?
    O42 C41 C42 C47 . . . . 24.4(4) ?
    O41 C41 C42 C47 . . . . -158.4(3) ?
    C47 C42 C43 C44 . . . . -1.0(5) ?
    C41 C42 C43 C44 . . . . 174.3(3) ?
    C42 C43 C44 C45 . . . . -0.2(5) ?
    C43 C44 C45 C46 . . . . 1.0(6) ?
    C44 C45 C46 C47 . . . . -0.6(6) ?
    C45 C46 C47 C42 . . . . -0.7(5) ?
    C45 C46 C47 C48 . . . . 173.7(3) ?
    C43 C42 C47 C46 . . . . 1.5(5) ?
    C41 C42 C47 C46 . . . . -173.8(3) ?
    C43 C42 C47 C48 . . . . -172.6(3) ?
    C41 C42 C47 C48 . . . . 12.1(4) ?
    C46 C47 C48 O43 . . . . -106.9(4) ?
    C42 C47 C48 O43 . . . . 67.2(4) ?
    C46 C47 C48 C49 . . . . 68.8(4) ?
    C42 C47 C48 C49 . . . . -117.1(3) ?
    O43 C48 C49 C50 . . . . -170.4(3) ?
    C47 C48 C49 C50 . . . . 14.0(5) ?
    O43 C48 C49 C54 . . . . 7.0(5) ?
    C47 C48 C49 C54 . . . . -168.6(3) ?
    C54 C49 C50 C51 . . . . 0.1(5) ?
    C48 C49 C50 C51 . . . . 177.5(3) ?
    C49 C50 C51 C52 . . . . -0.9(6) ?
    C50 C51 C52 C53 . . . . 1.0(7) ?
    C51 C52 C53 C54 . . . . -0.3(7) ?
    C52 C53 C54 C49 . . . . -0.6(6) ?
    C50 C49 C54 C53 . . . . 0.7(5) ?
    C48 C49 C54 C53 . . . . -176.9(3) ?
    Sn1 O61 C61 O62 . . . . -15.2(5) ?
    Sn1 O61 C61 C62 . . . . 163.38(19) ?
    O62 C61 C62 C63 . . . . 24.3(5) ?
    O61 C61 C62 C63 . . . . -154.4(3) ?
    O62 C61 C62 C67 . . . . -161.0(3) ?
    O61 C61 C62 C67 . . . . 20.3(5) ?
    C67 C62 C63 C64 . . . . 0.5(5) ?
    C61 C62 C63 C64 . . . . 175.5(3) ?
    C62 C63 C64 C65 . . . . -1.1(6) ?
    C63 C64 C65 C66 . . . . 0.9(7) ?
    C64 C65 C66 C67 . . . . 0.0(7) ?
    C65 C66 C67 C62 . . . . -0.6(6) ?
    C65 C66 C67 C68 . . . . 178.3(4) ?
    C63 C62 C67 C66 . . . . 0.3(5) ?
    C61 C62 C67 C66 . . . . -174.3(3) ?
    C63 C62 C67 C68 . . . . -178.4(3) ?
    C61 C62 C67 C68 . . . . 6.9(5) ?
    C66 C67 C68 O63 . . . . 56.5(5) ?
    C62 C67 C68 O63 . . . . -124.7(4) ?
    C66 C67 C68 C69 . . . . -117.0(4) ?
    C62 C67 C68 C69 . . . . 61.7(5) ?
    O63 C68 C69 C74 . . . . 23.1(5) ?
    C67 C68 C69 C74 . . . . -163.4(3) ?
    O63 C68 C69 C70 . . . . -154.1(4) ?
    C67 C68 C69 C70 . . . . 19.5(5) ?
    C74 C69 C70 C71 . . . . 0.0(6) ?
    C68 C69 C70 C71 . . . . 177.2(3) ?
    C69 C70 C71 C72 . . . . 0.8(6) ?
    C70 C71 C72 C73 . . . . -0.7(8) ?
    C71 C72 C73 C74 . . . . -0.2(8) ?
    C72 C73 C74 C69 . . . . 1.0(8) ?
    C70 C69 C74 C73 . . . . -0.9(6) ?
    C68 C69 C74 C73 . . . . -178.2(4) ?
data_global
_journal_date_recd_electronic     2007-01-03
_journal_date_accepted     2007-01-06
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2007
_journal_volume     63
_journal_issue      2
_journal_page_first     m465
_journal_page_last     m467
_journal_paper_category     EM
_journal_coeditor_code     NG2199
_publ_contact_author_name     'Diop Cheikh Abdoul Khadir'
_publ_contact_author_address
;
Département de Chimie Faculté des Sciences et Techniques -
Université Cheikh Anta Diop Daka - Sénégal
;
_publ_contact_author_email     cakdiop@ucad.sn
_publ_contact_author_fax     '221 824 63 18'
_publ_contact_author_phone     '221 860 12 96'
_publ_section_title
;
Tetramethylammonium bis(2-benzoylbenzoato-κO)triphenylstannate(IV)
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Cheikh Abdoul Khadir Diop' .
;
Département de Chimie, Faculté des Sciences et Techniques
Université Cheikh Anta Diop Daka
Senegal
;
    'Assane Touré' .
;
Département de Chimie, Faculté des Sciences et Techniques
Université Cheikh Anta Diop Daka
Senegal
;
    'Libasse Diop' .
;
Département de Chimie, Faculté des Sciences et Techniques
Université Cheikh Anta Diop Daka
Senegal
;
    'Augustin Sanchez-Dias' .
;
Departemento de Quimica Inorganica
Facultad de Farmacia, Universidad de Santiago de Compostela
Santiago de Compostela 15706
Spain
;
    'Alfonso Castineiras' .
;
Departemento de Quimica Inorganica
Facultad de Farmacia, Universidad de Santiago de Compostela
Santiago de Compostela 15706
Spain
;
    'Umberto Russo' .
;
Dipartimento di Chimica Inorganica, Metallorganica ed Analitica,
Universita degli Studi di Padova, via Loredan 4, 1-35131 Padova
Italy
;
