##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_global
_audit_creation_method     'WinGX routine CIF_UPDATE'
_audit_conform_dict_name     cif_core.dic
_audit_conform_dict_version     2.3
_journal_date_recd_electronic     2006-09-15
_journal_date_accepted     2006-10-17
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2006
_journal_volume     62
_journal_issue     11
_journal_page_first     m3056
_journal_page_last     m3058
_journal_paper_category     EM
_journal_coeditor_code     BG2008
_publ_contact_author_name     'Meijboom, Reinout'
_publ_contact_author_address
;
Department of Chemistry
University of the Free State
PO Box 339
Bloemfontein 9300
South Africa
;
_publ_contact_author_email     meijboomr.sci@mail.uovs.ac.za
_publ_contact_author_fax     '+27-51-430 7805'
_publ_contact_author_phone     '+27-51-401 9526'
_publ_section_title
;
(p-Toluenesulfonato)tris(triphenylarsine)silver(I)
;
loop_
    _publ_author_name
    _publ_author_address
    'Meijboom, Reinout'
;
Department of Chemistry
University of the Free State
PO Box 339
Bloemfontein 9300
South Africa
;
    'Janse van Rensburg, J. Marthinus'
;
Department of Chemistry
University of the Free State
PO Box 339
Bloemfontein 9300
South Africa
;
    'Senekal, Nadine D.'
;
Department of Chemistry
University of the Free State
PO Box 339
Bloemfontein 9300
South Africa
;
    'Venter, Jacobus S.'
;
Department of Chemistry
University of the Free State
PO Box 339
Bloemfontein 9300
South Africa
;
data_I
_audit_creation_method     'WinGX routine CIF_UPDATE'
_chemical_name_systematic
;
(p-Toluenesulfonato)tris(triphenylarsine)silver(I)
;
_chemical_formula_moiety     'C61 H52 Ag As3 O3 S'
_chemical_formula_sum     'C61 H52 Ag As3 O3 S'
_chemical_formula_iupac     '[Ag (C7 H7 O3 S) (C18 H15 As)3]'
_chemical_formula_weight     1197.72
_symmetry_cell_setting     Triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     13.1327(8)
_cell_length_b     13.8625(7)
_cell_length_c     14.3603(8)
_cell_angle_alpha     87.473(2)
_cell_angle_beta     81.202(2)
_cell_angle_gamma     85.870(2)
_cell_volume     2575.4(2)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     8130
_cell_measurement_theta_min     2.87
_cell_measurement_theta_max     28.29
_cell_measurement_temperature     100(2)
_exptl_crystal_description     plate
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.29
_exptl_crystal_size_mid     0.25
_exptl_crystal_size_min     0.11
_exptl_crystal_density_diffrn     1.545
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1208
_exptl_absorpt_coefficient_mu     2.391
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2004)'
_exptl_absorpt_correction_T_min     0.539
_exptl_absorpt_correction_T_max     0.7711
_exptl_special_details
;
The intensity data were collected on a Bruker X8 Apex II 4K Kappa CCD
diffractometer using an exposure time of 10 seconds/frame.  A total of 1407
frames were collected with a frame width of 0.5° covering up to θ = 28.31°
with 99.8% completeness accomplished.
;
_diffrn_ambient_temperature     100(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker X8 APEXII 4K KappaCCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     0
_diffrn_reflns_number     38157
_diffrn_reflns_av_R_equivalents     0.0283
_diffrn_reflns_theta_min     1.47
_diffrn_reflns_theta_max     28.31
_diffrn_reflns_theta_full     28.31
_diffrn_measured_fraction_theta_max     0.998
_diffrn_measured_fraction_theta_full     0.998
_diffrn_reflns_limit_h_min     -17
_diffrn_reflns_limit_h_max     17
_diffrn_reflns_limit_k_min     -18
_diffrn_reflns_limit_k_max     18
_diffrn_reflns_limit_l_min     -19
_diffrn_reflns_limit_l_max     19
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_decay_%     0
_reflns_number_total     12804
_reflns_number_gt     11099
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_gt     0.0236
_refine_ls_wR_factor_ref     0.0655
_refine_ls_goodness_of_fit_ref     1.088
_refine_ls_restrained_S_all     1.088
_refine_ls_number_reflns     12804
_refine_ls_number_parameters     623
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.0316P)²+0.5342P] where P=(Fo²+2Fc²)/3'
_refine_ls_shift/su_max     0.002
_refine_ls_shift/su_mean     0
_refine_diff_density_max     0.478
_refine_diff_density_min     -0.388
_refine_ls_extinction_method     none
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2005)'
_computing_cell_refinement     'SAINT-Plus (Bruker, 2004)'
_computing_data_reduction     'SAINT-Plus and XPREP (Bruker 2004)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'DIAMOND (Brandenburg & Putz, 2005)'
_computing_publication_material     'SHELXTL (Bruker 2004)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag 0.249754(11) 0.704263(9) 0.209858(10) 0.01332(4) Uani d . 1 . .
    As As1 0.253726(15) 0.526319(13) 0.269888(13) 0.01339(5) Uani d . 1 . .
    As As2 0.199292(16) 0.735434(13) 0.041933(13) 0.01400(5) Uani d . 1 . .
    As As3 0.152252(16) 0.823665(13) 0.333139(14) 0.01462(5) Uani d . 1 . .
    S S 0.49951(4) 0.74231(3) 0.21563(3) 0.01623(10) Uani d . 1 . .
    O O1 0.42598(11) 0.73519(10) 0.14907(10) 0.0190(3) Uani d . 1 . .
    O O2 0.47585(13) 0.68055(10) 0.29922(11) 0.0261(3) Uani d . 1 . .
    O O3 0.60606(11) 0.73258(11) 0.17055(12) 0.0274(4) Uani d . 1 . .
    C C1 0.47906(15) 0.86298(13) 0.25489(14) 0.0171(4) Uani d . 1 . .
    C C2 0.40917(16) 0.92799(14) 0.21880(15) 0.0198(4) Uani d . 1 . .
    H H2 0.3729 0.9091 0.1709 0.024 Uiso calc R 1 . .
    C C3 0.39215(17) 1.02072(15) 0.25251(18) 0.0275(5) Uani d . 1 . .
    H H3 0.3441 1.0651 0.2273 0.033 Uiso calc R 1 . .
    C C4 0.44373(19) 1.04965(16) 0.3220(2) 0.0344(6) Uani d . 1 . .
    C C5 0.5148(2) 0.98447(18) 0.3567(2) 0.0401(7) Uani d . 1 . .
    H H5 0.5518 1.0039 0.4039 0.048 Uiso calc R 1 . .
    C C6 0.53299(19) 0.89123(16) 0.32365(17) 0.0292(5) Uani d . 1 . .
    H H6 0.582 0.8472 0.348 0.035 Uiso calc R 1 . .
    C C7 0.4229(2) 1.15133(18) 0.3581(3) 0.0576(9) Uani d . 1 . .
    H H7A 0.4759 1.1926 0.326 0.086 Uiso calc R 1 . .
    H H7B 0.4245 1.1498 0.4261 0.086 Uiso calc R 1 . .
    H H7C 0.3548 1.1773 0.3455 0.086 Uiso calc R 1 . .
    C C11 0.32397(15) 0.43015(13) 0.18465(13) 0.0143(4) Uani d . 1 . .
    C C12 0.28817(16) 0.33852(14) 0.18210(14) 0.0197(4) Uani d . 1 . .
    H H12 0.2284 0.3214 0.2239 0.024 Uiso calc R 1 . .
    C C13 0.33912(17) 0.27182(15) 0.11880(15) 0.0228(4) Uani d . 1 . .
    H H13 0.3138 0.2096 0.1169 0.027 Uiso calc R 1 . .
    C C14 0.42634(17) 0.29591(15) 0.05893(14) 0.0227(4) Uani d . 1 . .
    H H14 0.4607 0.2506 0.015 0.027 Uiso calc R 1 . .
    C C15 0.46401(18) 0.38585(16) 0.06258(16) 0.0262(5) Uani d . 1 . .
    H H15 0.5252 0.4017 0.0222 0.031 Uiso calc R 1 . .
    C C16 0.41284(17) 0.45341(15) 0.12503(15) 0.0227(4) Uani d . 1 . .
    H H16 0.4387 0.5154 0.1269 0.027 Uiso calc R 1 . .
    C C21 0.30916(15) 0.48749(13) 0.38456(13) 0.0144(4) Uani d . 1 . .
    C C22 0.27659(18) 0.53910(15) 0.46530(15) 0.0242(5) Uani d . 1 . .
    H H22 0.2266 0.5921 0.4643 0.029 Uiso calc R 1 . .
    C C23 0.31653(19) 0.51382(17) 0.54767(16) 0.0291(5) Uani d . 1 . .
    H H23 0.2931 0.5491 0.603 0.035 Uiso calc R 1 . .
    C C24 0.39027(17) 0.43762(15) 0.54992(15) 0.0222(4) Uani d . 1 . .
    H H24 0.4177 0.4204 0.6063 0.027 Uiso calc R 1 . .
    C C25 0.42333(18) 0.38710(15) 0.46905(15) 0.0247(5) Uani d . 1 . .
    H H25 0.4743 0.335 0.4697 0.03 Uiso calc R 1 . .
    C C26 0.38317(18) 0.41143(14) 0.38719(15) 0.0226(5) Uani d . 1 . .
    H H26 0.4065 0.3757 0.3321 0.027 Uiso calc R 1 . .
    C C31 0.11704(15) 0.47616(13) 0.29217(14) 0.0153(4) Uani d . 1 . .
    C C32 0.08555(16) 0.41223(14) 0.36715(14) 0.0193(4) Uani d . 1 . .
    H H32 0.1296 0.3949 0.4127 0.023 Uiso calc R 1 . .
    C C33 -0.01059(18) 0.37410(16) 0.37481(17) 0.0272(5) Uani d . 1 . .
    H H33 -0.032 0.3303 0.4256 0.033 Uiso calc R 1 . .
    C C34 -0.07527(17) 0.39958(16) 0.30890(17) 0.0293(5) Uani d . 1 . .
    H H34 -0.1402 0.3722 0.3138 0.035 Uiso calc R 1 . .
    C C35 -0.04543(17) 0.46509(16) 0.23572(17) 0.0273(5) Uani d . 1 . .
    H H35 -0.0904 0.4838 0.1913 0.033 Uiso calc R 1 . .
    C C36 0.05037(17) 0.50307(14) 0.22781(15) 0.0209(4) Uani d . 1 . .
    H H36 0.0707 0.5481 0.1778 0.025 Uiso calc R 1 . .
    C C41 0.26063(16) 0.65443(13) -0.06187(13) 0.0163(4) Uani d . 1 . .
    C C42 0.26745(17) 0.55476(14) -0.04558(15) 0.0212(4) Uani d . 1 . .
    H H42 0.2394 0.5278 0.014 0.025 Uiso calc R 1 . .
    C C43 0.31522(18) 0.49455(15) -0.11633(16) 0.0255(5) Uani d . 1 . .
    H H43 0.3206 0.4265 -0.1047 0.031 Uiso calc R 1 . .
    C C44 0.35485(19) 0.53295(16) -0.20335(15) 0.0275(5) Uani d . 1 . .
    H H44 0.3879 0.4915 -0.2515 0.033 Uiso calc R 1 . .
    C C45 0.34633(19) 0.63216(16) -0.22052(15) 0.0268(5) Uani d . 1 . .
    H H45 0.3725 0.6586 -0.2809 0.032 Uiso calc R 1 . .
    C C46 0.29962(18) 0.69308(15) -0.14970(15) 0.0229(5) Uani d . 1 . .
    H H46 0.2944 0.7611 -0.1615 0.028 Uiso calc R 1 . .
    C C51 0.22369(16) 0.86270(13) -0.01603(14) 0.0169(4) Uani d . 1 . .
    C C52 0.32159(17) 0.89563(14) -0.01807(15) 0.0219(4) Uani d . 1 . .
    H H52 0.3723 0.8573 0.01 0.026 Uiso calc R 1 . .
    C C53 0.34517(18) 0.98436(15) -0.06104(17) 0.0290(5) Uani d . 1 . .
    H H53 0.4123 1.0064 -0.0628 0.035 Uiso calc R 1 . .
    C C54 0.2716(2) 1.04103(16) -0.10135(19) 0.0347(6) Uani d . 1 . .
    H H54 0.2879 1.102 -0.1305 0.042 Uiso calc R 1 . .
    C C55 0.1741(2) 1.00871(17) -0.0991(2) 0.0385(6) Uani d . 1 . .
    H H55 0.1235 1.0477 -0.1268 0.046 Uiso calc R 1 . .
    C C56 0.14955(19) 0.91931(15) -0.05653(17) 0.0291(5) Uani d . 1 . .
    H H56 0.0825 0.8973 -0.0553 0.035 Uiso calc R 1 . .
    C C61 0.05311(16) 0.72451(13) 0.04043(14) 0.0158(4) Uani d . 1 . .
    C C62 -0.01491(17) 0.74506(14) 0.12257(14) 0.0207(4) Uani d . 1 . .
    H H62 0.011 0.7649 0.1764 0.025 Uiso calc R 1 . .
    C C63 -0.11984(18) 0.73687(15) 0.12643(16) 0.0253(5) Uani d . 1 . .
    H H63 -0.1656 0.7513 0.1827 0.03 Uiso calc R 1 . .
    C C64 -0.15818(17) 0.70767(15) 0.04864(16) 0.0243(5) Uani d . 1 . .
    H H64 -0.2303 0.7033 0.0507 0.029 Uiso calc R 1 . .
    C C65 -0.09040(18) 0.68477(16) -0.03253(16) 0.0266(5) Uani d . 1 . .
    H H65 -0.1164 0.6629 -0.0855 0.032 Uiso calc R 1 . .
    C C66 0.01474(17) 0.69346(15) -0.03710(15) 0.0226(4) Uani d . 1 . .
    H H66 0.0604 0.6782 -0.0932 0.027 Uiso calc R 1 . .
    C C71 0.19412(16) 0.82757(13) 0.45646(14) 0.0164(4) Uani d . 1 . .
    C C72 0.12585(17) 0.85718(15) 0.53557(14) 0.0214(4) Uani d . 1 . .
    H H72 0.0551 0.8723 0.5308 0.026 Uiso calc R 1 . .
    C C73 0.16050(18) 0.86476(15) 0.62135(15) 0.0239(5) Uani d . 1 . .
    H H73 0.1134 0.8842 0.6753 0.029 Uiso calc R 1 . .
    C C74 0.2633(2) 0.84410(16) 0.62812(16) 0.0296(5) Uani d . 1 . .
    H H74 0.2877 0.8507 0.6863 0.036 Uiso calc R 1 . .
    C C75 0.3311(2) 0.8137(2) 0.54977(18) 0.0383(6) Uani d . 1 . .
    H H75 0.402 0.7993 0.5546 0.046 Uiso calc R 1 . .
    C C76 0.29678(18) 0.80402(16) 0.46456(16) 0.0263(5) Uani d . 1 . .
    H H76 0.3435 0.7813 0.4117 0.032 Uiso calc R 1 . .
    C C81 0.00657(16) 0.79982(13) 0.36716(13) 0.0166(4) Uani d . 1 . .
    C C82 -0.02103(17) 0.70452(14) 0.37875(14) 0.0205(4) Uani d . 1 . .
    H H82 0.0313 0.6532 0.3722 0.025 Uiso calc R 1 . .
    C C83 -0.12318(18) 0.68361(15) 0.39954(15) 0.0249(5) Uani d . 1 . .
    H H83 -0.1407 0.6181 0.4068 0.03 Uiso calc R 1 . .
    C C84 -0.20044(18) 0.75743(17) 0.40989(17) 0.0291(5) Uani d . 1 . .
    H H84 -0.2708 0.743 0.4243 0.035 Uiso calc R 1 . .
    C C85 -0.17384(18) 0.85301(17) 0.39887(19) 0.0339(6) Uani d . 1 . .
    H H85 -0.2263 0.9041 0.4061 0.041 Uiso calc R 1 . .
    C C86 -0.07107(17) 0.87412(15) 0.37742(17) 0.0265(5) Uani d . 1 . .
    H H86 -0.0536 0.9396 0.3697 0.032 Uiso calc R 1 . .
    C C91 0.13918(15) 0.96044(13) 0.29733(14) 0.0171(4) Uani d . 1 . .
    C C92 0.12371(16) 0.98448(14) 0.20535(15) 0.0208(4) Uani d . 1 . .
    H H92 0.1241 0.9349 0.1617 0.025 Uiso calc R 1 . .
    C C93 0.10768(17) 1.08086(15) 0.17688(16) 0.0245(5) Uani d . 1 . .
    H H93 0.097 1.0971 0.114 0.029 Uiso calc R 1 . .
    C C94 0.10734(17) 1.15300(14) 0.24041(17) 0.0251(5) Uani d . 1 . .
    H H94 0.0946 1.2188 0.2215 0.03 Uiso calc R 1 . .
    C C95 0.12549(17) 1.12977(14) 0.33143(16) 0.0231(5) Uani d . 1 . .
    H H95 0.1269 1.1797 0.3744 0.028 Uiso calc R 1 . .
    C C96 0.14168(16) 1.03356(14) 0.36020(15) 0.0202(4) Uani d . 1 . .
    H H96 0.1544 1.0177 0.4226 0.024 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag O1 . 2.4070(14) y
    Ag As1 . 2.5765(3) y
    Ag As3 . 2.6025(3) y
    Ag As2 . 2.6071(3) y
    As1 C11 . 1.9360(18) ?
    As1 C21 . 1.9400(19) ?
    As1 C31 . 1.9474(19) ?
    As2 C61 . 1.940(2) ?
    As2 C51 . 1.9437(19) ?
    As2 C41 . 1.9447(19) ?
    As3 C71 . 1.937(2) ?
    As3 C91 . 1.9450(19) ?
    As3 C81 . 1.949(2) ?
    S O3 . 1.4487(15) y
    S O2 . 1.4506(16) y
    S O1 . 1.4698(15) y
    S C1 . 1.7777(18) ?
    C1 C2 . 1.381(3) ?
    C1 C6 . 1.385(3) ?
    C2 C3 . 1.385(3) ?
    C2 H2 . 0.95 ?
    C3 C4 . 1.377(3) ?
    C3 H3 . 0.95 ?
    C4 C5 . 1.385(4) ?
    C4 C7 . 1.515(3) ?
    C5 C6 . 1.388(3) ?
    C5 H5 . 0.95 ?
    C6 H6 . 0.95 ?
    C7 H7A . 0.98 ?
    C7 H7B . 0.98 ?
    C7 H7C . 0.98 ?
    C11 C16 . 1.387(3) ?
    C11 C12 . 1.390(3) ?
    C12 C13 . 1.388(3) ?
    C12 H12 . 0.95 ?
    C13 C14 . 1.375(3) ?
    C13 H13 . 0.95 ?
    C14 C15 . 1.380(3) ?
    C14 H14 . 0.95 ?
    C15 C16 . 1.390(3) ?
    C15 H15 . 0.95 ?
    C16 H16 . 0.95 ?
    C21 C22 . 1.384(3) ?
    C21 C26 . 1.385(3) ?
    C22 C23 . 1.387(3) ?
    C22 H22 . 0.95 ?
    C23 C24 . 1.383(3) ?
    C23 H23 . 0.95 ?
    C24 C25 . 1.379(3) ?
    C24 H24 . 0.95 ?
    C25 C26 . 1.379(3) ?
    C25 H25 . 0.95 ?
    C26 H26 . 0.95 ?
    C31 C36 . 1.389(3) ?
    C31 C32 . 1.396(3) ?
    C32 C33 . 1.391(3) ?
    C32 H32 . 0.95 ?
    C33 C34 . 1.384(3) ?
    C33 H33 . 0.95 ?
    C34 C35 . 1.387(3) ?
    C34 H34 . 0.95 ?
    C35 C36 . 1.385(3) ?
    C35 H35 . 0.95 ?
    C36 H36 . 0.95 ?
    C41 C46 . 1.386(3) ?
    C41 C42 . 1.390(3) ?
    C42 C43 . 1.388(3) ?
    C42 H42 . 0.95 ?
    C43 C44 . 1.378(3) ?
    C43 H43 . 0.95 ?
    C44 C45 . 1.386(3) ?
    C44 H44 . 0.95 ?
    C45 C46 . 1.391(3) ?
    C45 H45 . 0.95 ?
    C46 H46 . 0.95 ?
    C51 C56 . 1.388(3) ?
    C51 C52 . 1.391(3) ?
    C52 C53 . 1.385(3) ?
    C52 H52 . 0.95 ?
    C53 C54 . 1.382(3) ?
    C53 H53 . 0.95 ?
    C54 C55 . 1.381(3) ?
    C54 H54 . 0.95 ?
    C55 C56 . 1.394(3) ?
    C55 H55 . 0.95 ?
    C56 H56 . 0.95 ?
    C61 C66 . 1.387(3) ?
    C61 C62 . 1.393(3) ?
    C62 C63 . 1.383(3) ?
    C62 H62 . 0.95 ?
    C63 C64 . 1.381(3) ?
    C63 H63 . 0.95 ?
    C64 C65 . 1.388(3) ?
    C64 H64 . 0.95 ?
    C65 C66 . 1.386(3) ?
    C65 H65 . 0.95 ?
    C66 H66 . 0.95 ?
    C71 C76 . 1.385(3) ?
    C71 C72 . 1.393(3) ?
    C72 C73 . 1.388(3) ?
    C72 H72 . 0.95 ?
    C73 C74 . 1.377(3) ?
    C73 H73 . 0.95 ?
    C74 C75 . 1.385(3) ?
    C74 H74 . 0.95 ?
    C75 C76 . 1.382(3) ?
    C75 H75 . 0.95 ?
    C76 H76 . 0.95 ?
    C81 C82 . 1.391(3) ?
    C81 C86 . 1.392(3) ?
    C82 C83 . 1.378(3) ?
    C82 H82 . 0.95 ?
    C83 C84 . 1.384(3) ?
    C83 H83 . 0.95 ?
    C84 C85 . 1.391(3) ?
    C84 H84 . 0.95 ?
    C85 C86 . 1.387(3) ?
    C85 H85 . 0.95 ?
    C86 H86 . 0.95 ?
    C91 C92 . 1.389(3) ?
    C91 C96 . 1.392(3) ?
    C92 C93 . 1.391(3) ?
    C92 H92 . 0.95 ?
    C93 C94 . 1.382(3) ?
    C93 H93 . 0.95 ?
    C94 C95 . 1.384(3) ?
    C94 H94 . 0.95 ?
    C95 C96 . 1.390(3) ?
    C95 H95 . 0.95 ?
    C96 H96 . 0.95 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Ag As1 . . 105.81(3) y
    O1 Ag As3 . . 116.50(3) y
    As1 Ag As3 . . 113.505(9) y
    O1 Ag As2 . . 90.17(3) y
    As1 Ag As2 . . 115.463(8) y
    As3 Ag As2 . . 113.207(9) y
    C11 As1 C21 . . 100.80(8) ?
    C11 As1 C31 . . 99.07(8) ?
    C21 As1 C31 . . 102.96(8) ?
    C11 As1 Ag . . 117.55(6) ?
    C21 As1 Ag . . 120.85(5) ?
    C31 As1 Ag . . 112.48(6) ?
    C61 As2 C51 . . 103.25(8) ?
    C61 As2 C41 . . 101.49(8) ?
    C51 As2 C41 . . 100.00(8) ?
    C61 As2 Ag . . 112.46(6) ?
    C51 As2 Ag . . 116.31(6) ?
    C41 As2 Ag . . 120.84(6) ?
    C71 As3 C91 . . 101.81(8) ?
    C71 As3 C81 . . 101.10(8) ?
    C91 As3 C81 . . 99.42(8) ?
    C71 As3 Ag . . 119.95(6) ?
    C91 As3 Ag . . 118.52(6) ?
    C81 As3 Ag . . 112.80(5) ?
    O3 S O2 . . 114.59(10) ?
    O3 S O1 . . 112.66(9) ?
    O2 S O1 . . 112.10(9) ?
    O3 S C1 . . 105.75(9) ?
    O2 S C1 . . 105.79(9) ?
    O1 S C1 . . 105.00(9) ?
    S O1 Ag . . 118.95(8) ?
    C2 C1 C6 . . 119.88(18) ?
    C2 C1 S . . 120.87(16) ?
    C6 C1 S . . 119.24(16) ?
    C1 C2 C3 . . 119.9(2) ?
    C1 C2 H2 . . 120.1 ?
    C3 C2 H2 . . 120.1 ?
    C4 C3 C2 . . 121.1(2) ?
    C4 C3 H3 . . 119.5 ?
    C2 C3 H3 . . 119.5 ?
    C3 C4 C5 . . 118.6(2) ?
    C3 C4 C7 . . 119.9(2) ?
    C5 C4 C7 . . 121.5(2) ?
    C4 C5 C6 . . 121.1(2) ?
    C4 C5 H5 . . 119.5 ?
    C6 C5 H5 . . 119.5 ?
    C1 C6 C5 . . 119.4(2) ?
    C1 C6 H6 . . 120.3 ?
    C5 C6 H6 . . 120.3 ?
    C4 C7 H7A . . 109.5 ?
    C4 C7 H7B . . 109.5 ?
    H7A C7 H7B . . 109.5 ?
    C4 C7 H7C . . 109.5 ?
    H7A C7 H7C . . 109.5 ?
    H7B C7 H7C . . 109.5 ?
    C16 C11 C12 . . 119.27(18) ?
    C16 C11 As1 . . 118.90(14) ?
    C12 C11 As1 . . 121.83(15) ?
    C13 C12 C11 . . 120.43(19) ?
    C13 C12 H12 . . 119.8 ?
    C11 C12 H12 . . 119.8 ?
    C14 C13 C12 . . 119.95(19) ?
    C14 C13 H13 . . 120 ?
    C12 C13 H13 . . 120 ?
    C13 C14 C15 . . 120.05(19) ?
    C13 C14 H14 . . 120 ?
    C15 C14 H14 . . 120 ?
    C14 C15 C16 . . 120.3(2) ?
    C14 C15 H15 . . 119.8 ?
    C16 C15 H15 . . 119.8 ?
    C11 C16 C15 . . 119.92(19) ?
    C11 C16 H16 . . 120 ?
    C15 C16 H16 . . 120 ?
    C22 C21 C26 . . 118.90(19) ?
    C22 C21 As1 . . 119.26(15) ?
    C26 C21 As1 . . 121.80(14) ?
    C21 C22 C23 . . 120.31(19) ?
    C21 C22 H22 . . 119.8 ?
    C23 C22 H22 . . 119.8 ?
    C24 C23 C22 . . 120.51(19) ?
    C24 C23 H23 . . 119.7 ?
    C22 C23 H23 . . 119.7 ?
    C25 C24 C23 . . 119.0(2) ?
    C25 C24 H24 . . 120.5 ?
    C23 C24 H24 . . 120.5 ?
    C24 C25 C26 . . 120.7(2) ?
    C24 C25 H25 . . 119.6 ?
    C26 C25 H25 . . 119.6 ?
    C25 C26 C21 . . 120.57(18) ?
    C25 C26 H26 . . 119.7 ?
    C21 C26 H26 . . 119.7 ?
    C36 C31 C32 . . 119.36(19) ?
    C36 C31 As1 . . 117.68(15) ?
    C32 C31 As1 . . 122.91(16) ?
    C33 C32 C31 . . 119.7(2) ?
    C33 C32 H32 . . 120.2 ?
    C31 C32 H32 . . 120.2 ?
    C34 C33 C32 . . 120.4(2) ?
    C34 C33 H33 . . 119.8 ?
    C32 C33 H33 . . 119.8 ?
    C33 C34 C35 . . 120.1(2) ?
    C33 C34 H34 . . 120 ?
    C35 C34 H34 . . 120 ?
    C36 C35 C34 . . 119.6(2) ?
    C36 C35 H35 . . 120.2 ?
    C34 C35 H35 . . 120.2 ?
    C35 C36 C31 . . 120.8(2) ?
    C35 C36 H36 . . 119.6 ?
    C31 C36 H36 . . 119.6 ?
    C46 C41 C42 . . 119.66(18) ?
    C46 C41 As2 . . 122.17(14) ?
    C42 C41 As2 . . 118.15(15) ?
    C43 C42 C41 . . 120.0(2) ?
    C43 C42 H42 . . 120 ?
    C41 C42 H42 . . 120 ?
    C44 C43 C42 . . 120.34(19) ?
    C44 C43 H43 . . 119.8 ?
    C42 C43 H43 . . 119.8 ?
    C43 C44 C45 . . 119.81(19) ?
    C43 C44 H44 . . 120.1 ?
    C45 C44 H44 . . 120.1 ?
    C44 C45 C46 . . 120.2(2) ?
    C44 C45 H45 . . 119.9 ?
    C46 C45 H45 . . 119.9 ?
    C41 C46 C45 . . 119.93(19) ?
    C41 C46 H46 . . 120 ?
    C45 C46 H46 . . 120 ?
    C56 C51 C52 . . 119.78(19) ?
    C56 C51 As2 . . 123.09(16) ?
    C52 C51 As2 . . 117.10(15) ?
    C53 C52 C51 . . 120.1(2) ?
    C53 C52 H52 . . 120 ?
    C51 C52 H52 . . 120 ?
    C54 C53 C52 . . 120.4(2) ?
    C54 C53 H53 . . 119.8 ?
    C52 C53 H53 . . 119.8 ?
    C55 C54 C53 . . 119.7(2) ?
    C55 C54 H54 . . 120.1 ?
    C53 C54 H54 . . 120.1 ?
    C54 C55 C56 . . 120.5(2) ?
    C54 C55 H55 . . 119.8 ?
    C56 C55 H55 . . 119.8 ?
    C51 C56 C55 . . 119.6(2) ?
    C51 C56 H56 . . 120.2 ?
    C55 C56 H56 . . 120.2 ?
    C66 C61 C62 . . 119.23(19) ?
    C66 C61 As2 . . 122.81(15) ?
    C62 C61 As2 . . 117.90(15) ?
    C63 C62 C61 . . 120.6(2) ?
    C63 C62 H62 . . 119.7 ?
    C61 C62 H62 . . 119.7 ?
    C64 C63 C62 . . 120.1(2) ?
    C64 C63 H63 . . 119.9 ?
    C62 C63 H63 . . 119.9 ?
    C63 C64 C65 . . 119.4(2) ?
    C63 C64 H64 . . 120.3 ?
    C65 C64 H64 . . 120.3 ?
    C66 C65 C64 . . 120.7(2) ?
    C66 C65 H65 . . 119.6 ?
    C64 C65 H65 . . 119.6 ?
    C65 C66 C61 . . 119.8(2) ?
    C65 C66 H66 . . 120.1 ?
    C61 C66 H66 . . 120.1 ?
    C76 C71 C72 . . 119.35(19) ?
    C76 C71 As3 . . 118.29(15) ?
    C72 C71 As3 . . 122.29(16) ?
    C73 C72 C71 . . 120.4(2) ?
    C73 C72 H72 . . 119.8 ?
    C71 C72 H72 . . 119.8 ?
    C74 C73 C72 . . 119.8(2) ?
    C74 C73 H73 . . 120.1 ?
    C72 C73 H73 . . 120.1 ?
    C73 C74 C75 . . 119.8(2) ?
    C73 C74 H74 . . 120.1 ?
    C75 C74 H74 . . 120.1 ?
    C76 C75 C74 . . 120.7(2) ?
    C76 C75 H75 . . 119.7 ?
    C74 C75 H75 . . 119.7 ?
    C75 C76 C71 . . 119.8(2) ?
    C75 C76 H76 . . 120.1 ?
    C71 C76 H76 . . 120.1 ?
    C82 C81 C86 . . 118.75(19) ?
    C82 C81 As3 . . 118.54(15) ?
    C86 C81 As3 . . 122.69(15) ?
    C83 C82 C81 . . 120.9(2) ?
    C83 C82 H82 . . 119.6 ?
    C81 C82 H82 . . 119.6 ?
    C82 C83 C84 . . 120.4(2) ?
    C82 C83 H83 . . 119.8 ?
    C84 C83 H83 . . 119.8 ?
    C83 C84 C85 . . 119.3(2) ?
    C83 C84 H84 . . 120.4 ?
    C85 C84 H84 . . 120.4 ?
    C86 C85 C84 . . 120.4(2) ?
    C86 C85 H85 . . 119.8 ?
    C84 C85 H85 . . 119.8 ?
    C85 C86 C81 . . 120.3(2) ?
    C85 C86 H86 . . 119.8 ?
    C81 C86 H86 . . 119.8 ?
    C92 C91 C96 . . 119.62(18) ?
    C92 C91 As3 . . 117.47(14) ?
    C96 C91 As3 . . 122.88(16) ?
    C91 C92 C93 . . 120.30(19) ?
    C91 C92 H92 . . 119.9 ?
    C93 C92 H92 . . 119.9 ?
    C94 C93 C92 . . 119.8(2) ?
    C94 C93 H93 . . 120.1 ?
    C92 C93 H93 . . 120.1 ?
    C93 C94 C95 . . 120.24(19) ?
    C93 C94 H94 . . 119.9 ?
    C95 C94 H94 . . 119.9 ?
    C94 C95 C96 . . 120.18(19) ?
    C94 C95 H95 . . 119.9 ?
    C96 C95 H95 . . 119.9 ?
    C95 C96 C91 . . 119.8(2) ?
    C95 C96 H96 . . 120.1 ?
    C91 C96 H96 . . 120.1 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O1 Ag As1 C11 . . . . -51.09(7) ?
    As3 Ag As1 C11 . . . . 179.94(6) ?
    As2 Ag As1 C11 . . . . 46.86(7) ?
    O1 Ag As1 C21 . . . . 72.82(7) ?
    As3 Ag As1 C21 . . . . -56.15(7) ?
    As2 Ag As1 C21 . . . . 170.77(7) ?
    O1 Ag As1 C31 . . . . -165.18(7) ?
    As3 Ag As1 C31 . . . . 65.85(6) ?
    As2 Ag As1 C31 . . . . -67.23(6) ?
    O1 Ag As2 C61 . . . . -178.50(7) ?
    As1 Ag As2 C61 . . . . 73.85(6) ?
    As3 Ag As2 C61 . . . . -59.36(6) ?
    O1 Ag As2 C51 . . . . -59.74(7) ?
    As1 Ag As2 C51 . . . . -167.39(7) ?
    As3 Ag As2 C51 . . . . 59.40(7) ?
    O1 Ag As2 C41 . . . . 61.64(8) ?
    As1 Ag As2 C41 . . . . -46.01(7) ?
    As3 Ag As2 C41 . . . . -179.22(7) ?
    O1 Ag As3 C71 . . . . -67.23(8) ?
    As1 Ag As3 C71 . . . . 56.06(7) ?
    As2 Ag As3 C71 . . . . -169.79(7) ?
    O1 Ag As3 C91 . . . . 58.36(8) ?
    As1 Ag As3 C91 . . . . -178.35(7) ?
    As2 Ag As3 C91 . . . . -44.20(7) ?
    O1 Ag As3 C81 . . . . 173.87(7) ?
    As1 Ag As3 C81 . . . . -62.85(7) ?
    As2 Ag As3 C81 . . . . 71.31(7) ?
    O3 S O1 Ag . . . . 163.03(8) ?
    O2 S O1 Ag . . . . 32.01(11) ?
    C1 S O1 Ag . . . . -82.37(10) ?
    As1 Ag O1 S . . . . -71.84(8) ?
    As3 Ag O1 S . . . . 55.35(9) ?
    As2 Ag O1 S . . . . 171.57(8) ?
    O3 S C1 C2 . . . . 116.39(18) ?
    O2 S C1 C2 . . . . -121.67(18) ?
    O1 S C1 C2 . . . . -2.95(19) ?
    O3 S C1 C6 . . . . -64.6(2) ?
    O2 S C1 C6 . . . . 57.3(2) ?
    O1 S C1 C6 . . . . 176.03(18) ?
    C6 C1 C2 C3 . . . . -1.0(3) ?
    S C1 C2 C3 . . . . 178.01(17) ?
    C1 C2 C3 C4 . . . . -0.2(3) ?
    C2 C3 C4 C5 . . . . 1.2(4) ?
    C2 C3 C4 C7 . . . . -179.5(2) ?
    C3 C4 C5 C6 . . . . -1.1(4) ?
    C7 C4 C5 C6 . . . . 179.6(3) ?
    C2 C1 C6 C5 . . . . 1.0(4) ?
    S C1 C6 C5 . . . . -178.0(2) ?
    C4 C5 C6 C1 . . . . 0.0(4) ?
    C21 As1 C11 C16 . . . . -96.85(17) ?
    C31 As1 C11 C16 . . . . 157.98(17) ?
    Ag As1 C11 C16 . . . . 36.65(18) ?
    C21 As1 C11 C12 . . . . 82.71(17) ?
    C31 As1 C11 C12 . . . . -22.46(18) ?
    Ag As1 C11 C12 . . . . -143.78(15) ?
    C16 C11 C12 C13 . . . . -1.8(3) ?
    As1 C11 C12 C13 . . . . 178.69(16) ?
    C11 C12 C13 C14 . . . . 0.8(3) ?
    C12 C13 C14 C15 . . . . 0.9(3) ?
    C13 C14 C15 C16 . . . . -1.6(3) ?
    C12 C11 C16 C15 . . . . 1.1(3) ?
    As1 C11 C16 C15 . . . . -179.37(16) ?
    C14 C15 C16 C11 . . . . 0.6(3) ?
    C11 As1 C21 C22 . . . . -179.41(17) ?
    C31 As1 C21 C22 . . . . -77.37(17) ?
    Ag As1 C21 C22 . . . . 49.10(18) ?
    C11 As1 C21 C26 . . . . 2.80(18) ?
    C31 As1 C21 C26 . . . . 104.84(17) ?
    Ag As1 C21 C26 . . . . -128.69(15) ?
    C26 C21 C22 C23 . . . . -1.0(3) ?
    As1 C21 C22 C23 . . . . -178.82(18) ?
    C21 C22 C23 C24 . . . . 0.8(4) ?
    C22 C23 C24 C25 . . . . -0.1(4) ?
    C23 C24 C25 C26 . . . . -0.5(3) ?
    C24 C25 C26 C21 . . . . 0.3(3) ?
    C22 C21 C26 C25 . . . . 0.4(3) ?
    As1 C21 C26 C25 . . . . 178.19(17) ?
    C11 As1 C31 C36 . . . . -85.13(15) ?
    C21 As1 C31 C36 . . . . 171.49(14) ?
    Ag As1 C31 C36 . . . . 39.83(15) ?
    C11 As1 C31 C32 . . . . 92.35(16) ?
    C21 As1 C31 C32 . . . . -11.03(17) ?
    Ag As1 C31 C32 . . . . -142.69(14) ?
    C36 C31 C32 C33 . . . . 2.0(3) ?
    As1 C31 C32 C33 . . . . -175.47(15) ?
    C31 C32 C33 C34 . . . . -0.4(3) ?
    C32 C33 C34 C35 . . . . -1.4(3) ?
    C33 C34 C35 C36 . . . . 1.5(3) ?
    C34 C35 C36 C31 . . . . 0.2(3) ?
    C32 C31 C36 C35 . . . . -1.9(3) ?
    As1 C31 C36 C35 . . . . 175.69(15) ?
    C61 As2 C41 C46 . . . . 101.76(19) ?
    C51 As2 C41 C46 . . . . -4.1(2) ?
    Ag As2 C41 C46 . . . . -133.11(16) ?
    C61 As2 C41 C42 . . . . -79.95(17) ?
    C51 As2 C41 C42 . . . . 174.18(17) ?
    Ag As2 C41 C42 . . . . 45.18(19) ?
    C46 C41 C42 C43 . . . . 1.5(3) ?
    As2 C41 C42 C43 . . . . -176.85(17) ?
    C41 C42 C43 C44 . . . . -0.9(3) ?
    C42 C43 C44 C45 . . . . -0.4(4) ?
    C43 C44 C45 C46 . . . . 1.2(4) ?
    C42 C41 C46 C45 . . . . -0.8(3) ?
    As2 C41 C46 C45 . . . . 177.50(17) ?
    C44 C45 C46 C41 . . . . -0.6(4) ?
    C61 As2 C51 C56 . . . . -6.9(2) ?
    C41 As2 C51 C56 . . . . 97.51(19) ?
    Ag As2 C51 C56 . . . . -130.59(17) ?
    C61 As2 C51 C52 . . . . 174.73(15) ?
    C41 As2 C51 C52 . . . . -80.83(16) ?
    Ag As2 C51 C52 . . . . 51.07(17) ?
    C56 C51 C52 C53 . . . . -0.5(3) ?
    As2 C51 C52 C53 . . . . 177.91(16) ?
    C51 C52 C53 C54 . . . . 0.6(3) ?
    C52 C53 C54 C55 . . . . -0.3(4) ?
    C53 C54 C55 C56 . . . . 0.0(4) ?
    C52 C51 C56 C55 . . . . 0.1(3) ?
    As2 C51 C56 C55 . . . . -178.16(19) ?
    C54 C55 C56 C51 . . . . 0.1(4) ?
    C51 As2 C61 C66 . . . . 84.65(17) ?
    C41 As2 C61 C66 . . . . -18.64(18) ?
    Ag As2 C61 C66 . . . . -149.19(15) ?
    C51 As2 C61 C62 . . . . -98.11(16) ?
    C41 As2 C61 C62 . . . . 158.60(15) ?
    Ag As2 C61 C62 . . . . 28.05(16) ?
    C66 C61 C62 C63 . . . . -1.5(3) ?
    As2 C61 C62 C63 . . . . -178.82(15) ?
    C61 C62 C63 C64 . . . . 0.3(3) ?
    C62 C63 C64 C65 . . . . 1.3(3) ?
    C63 C64 C65 C66 . . . . -1.8(3) ?
    C64 C65 C66 C61 . . . . 0.6(3) ?
    C62 C61 C66 C65 . . . . 1.0(3) ?
    As2 C61 C66 C65 . . . . 178.23(16) ?
    C91 As3 C71 C76 . . . . -103.77(17) ?
    C81 As3 C71 C76 . . . . 154.02(16) ?
    Ag As3 C71 C76 . . . . 29.34(18) ?
    C91 As3 C71 C72 . . . . 73.33(17) ?
    C81 As3 C71 C72 . . . . -28.88(17) ?
    Ag As3 C71 C72 . . . . -153.55(14) ?
    C76 C71 C72 C73 . . . . 1.2(3) ?
    As3 C71 C72 C73 . . . . -175.91(15) ?
    C71 C72 C73 C74 . . . . 0.8(3) ?
    C72 C73 C74 C75 . . . . -1.5(3) ?
    C73 C74 C75 C76 . . . . 0.2(4) ?
    C74 C75 C76 C71 . . . . 1.8(4) ?
    C72 C71 C76 C75 . . . . -2.5(3) ?
    As3 C71 C76 C75 . . . . 174.70(19) ?
    C71 As3 C81 C82 . . . . -89.23(16) ?
    C91 As3 C81 C82 . . . . 166.65(16) ?
    Ag As3 C81 C82 . . . . 40.15(17) ?
    C71 As3 C81 C86 . . . . 92.82(18) ?
    C91 As3 C81 C86 . . . . -11.30(19) ?
    Ag As3 C81 C86 . . . . -137.80(16) ?
    C86 C81 C82 C83 . . . . 0.3(3) ?
    As3 C81 C82 C83 . . . . -177.71(16) ?
    C81 C82 C83 C84 . . . . -0.4(3) ?
    C82 C83 C84 C85 . . . . 0.1(3) ?
    C83 C84 C85 C86 . . . . 0.2(4) ?
    C84 C85 C86 C81 . . . . -0.3(4) ?
    C82 C81 C86 C85 . . . . 0.0(3) ?
    As3 C81 C86 C85 . . . . 177.99(19) ?
    C71 As3 C91 C92 . . . . 171.16(16) ?
    C81 As3 C91 C92 . . . . -85.30(17) ?
    Ag As3 C91 C92 . . . . 37.21(18) ?
    C71 As3 C91 C96 . . . . -10.75(19) ?
    C81 As3 C91 C96 . . . . 92.79(18) ?
    Ag As3 C91 C96 . . . . -144.71(15) ?
    C96 C91 C92 C93 . . . . -2.0(3) ?
    As3 C91 C92 C93 . . . . 176.20(16) ?
    C91 C92 C93 C94 . . . . 0.1(3) ?
    C92 C93 C94 C95 . . . . 1.6(3) ?
    C93 C94 C95 C96 . . . . -1.6(3) ?
    C94 C95 C96 C91 . . . . -0.3(3) ?
    C92 C91 C96 C95 . . . . 2.0(3) ?
    As3 C91 C96 C95 . . . . -176.02(16) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C24 H24 O2 2_666 0.95 2.43 3.302(3) 153.4
    C43 H43 O3 2_665 0.95 2.51 3.330(2) 145
    C64 H64 O3 1_455 0.95 2.56 3.318(3) 137.1
    C76 H76 O2 . 0.95 2.56 3.488(3) 164.5
