##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
(E)-N-Benzoyl-N'-(3-hydroxy-4-methoxybenzylidene)hydrazine
;
_chemical_name_common     ?
_chemical_formula_moiety     'C15 H14 N2 O3'
_chemical_formula_sum     'C15 H14 N2 O3'
_chemical_formula_iupac     'C15 H14 N2 O3'
_chemical_formula_weight     270.28
_chemical_melting_point     ?
_symmetry_cell_setting     Monoclinic
_symmetry_space_group_name_H-M     'P 21/c'
_symmetry_space_group_name_Hall     '-P 2ybc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     7.5209(10)
_cell_length_b     19.221(3)
_cell_length_c     18.971(3)
_cell_angle_alpha     90.00
_cell_angle_beta     96.265(2)
_cell_angle_gamma     90.00
_cell_volume     2726.1(7)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     4256
_cell_measurement_theta_min     2.38
_cell_measurement_theta_max     26.33
_cell_measurement_temperature     294(2)
_exptl_crystal_description     block
_exptl_crystal_colour     colorless
_exptl_crystal_size_max     0.28
_exptl_crystal_size_mid     0.20
_exptl_crystal_size_min     0.16
_exptl_crystal_density_diffrn     1.317
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1136
_exptl_absorpt_coefficient_mu     0.093
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min     0.968
_exptl_absorpt_correction_T_max     0.985
_exptl_special_details
;
;
_diffrn_ambient_temperature     294(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     15237
_diffrn_reflns_av_R_equivalents     0.0384
_diffrn_reflns_av_sigmaI/netI     0.0433
_diffrn_reflns_theta_min     1.51
_diffrn_reflns_theta_max     26.42
_diffrn_reflns_theta_full     26.42
_diffrn_measured_fraction_theta_max     0.996
_diffrn_measured_fraction_theta_full     0.996
_diffrn_reflns_limit_h_min     -8
_diffrn_reflns_limit_h_max     9
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     24
_diffrn_reflns_limit_l_min     -21
_diffrn_reflns_limit_l_max     23
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     0
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     5591
_reflns_number_gt     3644
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0808
_refine_ls_R_factor_gt     0.0445
_refine_ls_wR_factor_gt     0.1016
_refine_ls_wR_factor_ref     0.1205
_refine_ls_goodness_of_fit_ref     1.007
_refine_ls_restrained_S_all     1.007
_refine_ls_number_reflns     5591
_refine_ls_number_parameters     365
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
     'calc w = 1/[σ²(Fo²)+(0.0598P)²+0.3319P] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.206
_refine_diff_density_min     -0.285
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 1999)'
_computing_cell_refinement     'SAINT (Bruker, 1999)'
_computing_data_reduction     SAINT
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997a)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997a)'
_computing_molecular_graphics     'SHELXTL (Sheldrick, 1997b)'
_computing_publication_material     SHELXTL
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    O1 0.22104(16) 0.49241(6) 0.34639(6) 0.0389(3) Uani d . 1 . . O
    O2 -0.01024(17) 0.48060(8) 0.23475(6) 0.0464(4) Uani d . 1 . . O
    H2 -0.0681 0.4737 0.1962 0.070 Uiso calc R 1 . . H
    O3 0.19886(19) 0.54233(7) -0.10911(6) 0.0509(4) Uani d . 1 . . O
    O4 0.70930(16) 0.66483(6) 0.98049(7) 0.0450(3) Uani d . 1 . . O
    O5 0.52636(17) 0.76736(6) 1.02395(8) 0.0483(4) Uani d . 1 . . O
    H5 0.4692 0.8022 1.0322 0.072 Uiso calc R 1 . . H
    O6 0.68601(17) 1.12078(6) 0.95065(7) 0.0464(4) Uani d . 1 . . O
    N1 0.2972(2) 0.58172(8) 0.02872(7) 0.0368(4) Uani d . 1 . . N
    N2 0.3473(2) 0.61580(8) -0.03039(7) 0.0402(4) Uani d . 1 . . N
    H2A 0.4160 0.6516 -0.0245 0.048 Uiso calc R 1 . . H
    N3 0.80036(19) 0.99006(7) 0.91895(8) 0.0348(4) Uani d . 1 . . N
    N4 0.86725(19) 1.05138(7) 0.89390(8) 0.0376(4) Uani d . 1 . . N
    H4 0.9496 1.0493 0.8659 0.045 Uiso calc R 1 . . H
    C1 0.3255(3) 0.51014(13) 0.41168(10) 0.0573(6) Uani d . 1 . . C
    H1A 0.4424 0.4899 0.4126 0.086 Uiso calc R 1 . . H
    H1B 0.2679 0.4926 0.4508 0.086 Uiso calc R 1 . . H
    H1C 0.3361 0.5598 0.4154 0.086 Uiso calc R 1 . . H
    C2 0.2720(2) 0.51966(9) 0.28518(8) 0.0306(4) Uani d . 1 . . C
    C3 0.4319(2) 0.55323(10) 0.27973(9) 0.0369(4) Uani d . 1 . . C
    H3 0.5135 0.5593 0.3197 0.044 Uiso calc R 1 . . H
    C4 0.4709(2) 0.57802(9) 0.21435(9) 0.0384(4) Uani d . 1 . . C
    H4A 0.5783 0.6011 0.2110 0.046 Uiso calc R 1 . . H
    C5 0.3518(2) 0.56875(9) 0.15414(9) 0.0326(4) Uani d . 1 . . C
    C6 0.1892(2) 0.53519(8) 0.16016(9) 0.0312(4) Uani d . 1 . . C
    H6 0.1082 0.5288 0.1200 0.037 Uiso calc R 1 . . H
    C7 0.1476(2) 0.51141(8) 0.22482(9) 0.0299(4) Uani d . 1 . . C
    C8 0.3940(2) 0.59616(9) 0.08600(9) 0.0370(4) Uani d . 1 . . C
    H8 0.4935 0.6247 0.0846 0.044 Uiso calc R 1 . . H
    C9 0.2917(2) 0.59464(10) -0.09644(9) 0.0342(4) Uani d . 1 . . C
    C10 0.3540(2) 0.63949(9) -0.15305(9) 0.0338(4) Uani d . 1 . . C
    C11 0.4196(3) 0.60800(11) -0.21068(10) 0.0456(5) Uani d . 1 . . C
    H11 0.4223 0.5597 -0.2140 0.055 Uiso calc R 1 . . H
    C12 0.4812(3) 0.64868(14) -0.26333(10) 0.0573(6) Uani d . 1 . . C
    H12 0.5290 0.6277 -0.3012 0.069 Uiso calc R 1 . . H
    C13 0.4718(3) 0.71961(14) -0.25967(12) 0.0627(7) Uani d . 1 . . C
    H13 0.5108 0.7466 -0.2956 0.075 Uiso calc R 1 . . H
    C14 0.4049(3) 0.75124(12) -0.20304(12) 0.0617(6) Uani d . 1 . . C
    H14 0.3978 0.7995 -0.2010 0.074 Uiso calc R 1 . . H
    C15 0.3483(3) 0.71120(10) -0.14917(10) 0.0472(5) Uani d . 1 . . C
    H15 0.3063 0.7326 -0.1103 0.057 Uiso calc R 1 . . H
    C16 0.7970(3) 0.60512(10) 0.95419(13) 0.0613(6) Uani d . 1 . . C
    H16A 0.7712 0.6028 0.9036 0.092 Uiso calc R 1 . . H
    H16B 0.7544 0.5637 0.9750 0.092 Uiso calc R 1 . . H
    H16C 0.9238 0.6091 0.9665 0.092 Uiso calc R 1 . . H
    C17 0.7524(2) 0.72910(9) 0.95657(10) 0.0347(4) Uani d . 1 . . C
    C18 0.8789(2) 0.74182(9) 0.91115(10) 0.0425(5) Uani d . 1 . . C
    H18 0.9412 0.7050 0.8936 0.051 Uiso calc R 1 . . H
    C19 0.9137(2) 0.80934(10) 0.89158(10) 0.0436(5) Uani d . 1 . . C
    H19 0.9997 0.8175 0.8609 0.052 Uiso calc R 1 . . H
    C20 0.8224(2) 0.86521(9) 0.91698(9) 0.0351(4) Uani d . 1 . . C
    C21 0.6913(2) 0.85164(9) 0.96238(9) 0.0341(4) Uani d . 1 . . C
    H21 0.6283 0.8884 0.9796 0.041 Uiso calc R 1 . . H
    C22 0.6549(2) 0.78468(9) 0.98165(9) 0.0336(4) Uani d . 1 . . C
    C23 0.8687(2) 0.93510(9) 0.89594(10) 0.0376(4) Uani d . 1 . . C
    H23 0.9529 0.9399 0.8639 0.045 Uiso calc R 1 . . H
    C24 0.8069(2) 1.11409(9) 0.91222(9) 0.0324(4) Uani d . 1 . . C
    C25 0.8973(2) 1.17505(9) 0.88255(9) 0.0324(4) Uani d . 1 . . C
    C26 0.8900(2) 1.23892(9) 0.91598(10) 0.0411(5) Uani d . 1 . . C
    H26 0.8315 1.2428 0.9565 0.049 Uiso calc R 1 . . H
    C27 0.9691(3) 1.29687(10) 0.88962(12) 0.0525(5) Uani d . 1 . . C
    H27 0.9647 1.3394 0.9128 0.063 Uiso calc R 1 . . H
    C28 1.0537(3) 1.29199(11) 0.82951(12) 0.0576(6) Uani d . 1 . . C
    H28 1.1056 1.3312 0.8116 0.069 Uiso calc R 1 . . H
    C29 1.0620(3) 1.22904(11) 0.79560(12) 0.0555(6) Uani d . 1 . . C
    H29 1.1197 1.2258 0.7548 0.067 Uiso calc R 1 . . H
    C30 0.9854(3) 1.17077(10) 0.82167(10) 0.0450(5) Uani d . 1 . . C
    H30 0.9924 1.1283 0.7986 0.054 Uiso calc R 1 . . H
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    O1 C2 . 1.3665(19) ?
    O1 C1 . 1.434(2) ?
    O2 C7 . 1.3578(19) ?
    O2 H2 . 0.8200 ?
    O3 C9 . 1.233(2) ?
    O4 C17 . 1.367(2) ?
    O4 C16 . 1.440(2) ?
    O5 C22 . 1.363(2) ?
    O5 H5 . 0.8200 ?
    O6 C24 . 1.2324(19) ?
    N1 C8 . 1.271(2) ?
    N1 N2 . 1.3860(18) ?
    N2 C9 . 1.340(2) ?
    N2 H2A . 0.8600 ?
    N3 C23 . 1.273(2) ?
    N3 N4 . 1.3858(19) ?
    N4 C24 . 1.347(2) ?
    N4 H4 . 0.8600 ?
    C1 H1A . 0.9600 ?
    C1 H1B . 0.9600 ?
    C1 H1C . 0.9600 ?
    C2 C3 . 1.378(2) ?
    C2 C7 . 1.407(2) ?
    C3 C4 . 1.390(2) ?
    C3 H3 . 0.9300 ?
    C4 C5 . 1.384(2) ?
    C4 H4A . 0.9300 ?
    C5 C6 . 1.398(2) ?
    C5 C8 . 1.462(2) ?
    C6 C7 . 1.377(2) ?
    C6 H6 . 0.9300 ?
    C8 H8 . 0.9300 ?
    C9 C10 . 1.492(2) ?
    C10 C15 . 1.381(3) ?
    C10 C11 . 1.387(2) ?
    C11 C12 . 1.388(3) ?
    C11 H11 . 0.9300 ?
    C12 C13 . 1.367(3) ?
    C12 H12 . 0.9300 ?
    C13 C14 . 1.376(3) ?
    C13 H13 . 0.9300 ?
    C14 C15 . 1.383(3) ?
    C14 H14 . 0.9300 ?
    C15 H15 . 0.9300 ?
    C16 H16A . 0.9600 ?
    C16 H16B . 0.9600 ?
    C16 H16C . 0.9600 ?
    C17 C18 . 1.373(2) ?
    C17 C22 . 1.408(2) ?
    C18 C19 . 1.383(3) ?
    C18 H18 . 0.9300 ?
    C19 C20 . 1.389(2) ?
    C19 H19 . 0.9300 ?
    C20 C21 . 1.403(2) ?
    C20 C23 . 1.455(2) ?
    C21 C22 . 1.374(2) ?
    C21 H21 . 0.9300 ?
    C23 H23 . 0.9300 ?
    C24 C25 . 1.495(2) ?
    C25 C26 . 1.386(2) ?
    C25 C30 . 1.395(2) ?
    C26 C27 . 1.382(3) ?
    C26 H26 . 0.9300 ?
    C27 C28 . 1.368(3) ?
    C27 H27 . 0.9300 ?
    C28 C29 . 1.375(3) ?
    C28 H28 . 0.9300 ?
    C29 C30 . 1.376(3) ?
    C29 H29 . 0.9300 ?
    C30 H30 . 0.9300 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C2 O1 C1 . . 117.71(14) ?
    C7 O2 H2 . . 109.5 ?
    C17 O4 C16 . . 118.10(15) ?
    C22 O5 H5 . . 109.5 ?
    C8 N1 N2 . . 114.06(14) ?
    C9 N2 N1 . . 121.90(14) ?
    C9 N2 H2A . . 119.1 ?
    N1 N2 H2A . . 119.1 ?
    C23 N3 N4 . . 114.40(14) ?
    C24 N4 N3 . . 121.83(14) ?
    C24 N4 H4 . . 119.1 ?
    N3 N4 H4 . . 119.1 ?
    O1 C1 H1A . . 109.5 ?
    O1 C1 H1B . . 109.5 ?
    H1A C1 H1B . . 109.5 ?
    O1 C1 H1C . . 109.5 ?
    H1A C1 H1C . . 109.5 ?
    H1B C1 H1C . . 109.5 ?
    O1 C2 C3 . . 124.83(16) ?
    O1 C2 C7 . . 115.16(14) ?
    C3 C2 C7 . . 120.02(15) ?
    C2 C3 C4 . . 119.89(17) ?
    C2 C3 H3 . . 120.1 ?
    C4 C3 H3 . . 120.1 ?
    C5 C4 C3 . . 120.78(16) ?
    C5 C4 H4A . . 119.6 ?
    C3 C4 H4A . . 119.6 ?
    C4 C5 C6 . . 119.02(15) ?
    C4 C5 C8 . . 119.97(15) ?
    C6 C5 C8 . . 120.97(16) ?
    C7 C6 C5 . . 120.80(16) ?
    C7 C6 H6 . . 119.6 ?
    C5 C6 H6 . . 119.6 ?
    O2 C7 C6 . . 123.76(15) ?
    O2 C7 C2 . . 116.77(14) ?
    C6 C7 C2 . . 119.47(15) ?
    N1 C8 C5 . . 121.17(15) ?
    N1 C8 H8 . . 119.4 ?
    C5 C8 H8 . . 119.4 ?
    O3 C9 N2 . . 122.84(15) ?
    O3 C9 C10 . . 123.13(16) ?
    N2 C9 C10 . . 114.03(15) ?
    C15 C10 C11 . . 119.56(17) ?
    C15 C10 C9 . . 121.62(16) ?
    C11 C10 C9 . . 118.82(16) ?
    C10 C11 C12 . . 119.8(2) ?
    C10 C11 H11 . . 120.1 ?
    C12 C11 H11 . . 120.1 ?
    C13 C12 C11 . . 120.1(2) ?
    C13 C12 H12 . . 119.9 ?
    C11 C12 H12 . . 119.9 ?
    C12 C13 C14 . . 120.4(2) ?
    C12 C13 H13 . . 119.8 ?
    C14 C13 H13 . . 119.8 ?
    C13 C14 C15 . . 119.9(2) ?
    C13 C14 H14 . . 120.0 ?
    C15 C14 H14 . . 120.0 ?
    C10 C15 C14 . . 120.13(19) ?
    C10 C15 H15 . . 119.9 ?
    C14 C15 H15 . . 119.9 ?
    O4 C16 H16A . . 109.5 ?
    O4 C16 H16B . . 109.5 ?
    H16A C16 H16B . . 109.5 ?
    O4 C16 H16C . . 109.5 ?
    H16A C16 H16C . . 109.5 ?
    H16B C16 H16C . . 109.5 ?
    O4 C17 C18 . . 125.08(16) ?
    O4 C17 C22 . . 114.97(15) ?
    C18 C17 C22 . . 119.94(16) ?
    C17 C18 C19 . . 119.99(16) ?
    C17 C18 H18 . . 120.0 ?
    C19 C18 H18 . . 120.0 ?
    C18 C19 C20 . . 121.17(16) ?
    C18 C19 H19 . . 119.4 ?
    C20 C19 H19 . . 119.4 ?
    C19 C20 C21 . . 118.45(16) ?
    C19 C20 C23 . . 118.48(16) ?
    C21 C20 C23 . . 123.06(16) ?
    C22 C21 C20 . . 120.76(16) ?
    C22 C21 H21 . . 119.6 ?
    C20 C21 H21 . . 119.6 ?
    O5 C22 C21 . . 124.07(15) ?
    O5 C22 C17 . . 116.28(15) ?
    C21 C22 C17 . . 119.65(15) ?
    N3 C23 C20 . . 123.70(16) ?
    N3 C23 H23 . . 118.1 ?
    C20 C23 H23 . . 118.1 ?
    O6 C24 N4 . . 122.49(16) ?
    O6 C24 C25 . . 122.42(15) ?
    N4 C24 C25 . . 115.09(14) ?
    C26 C25 C30 . . 118.50(17) ?
    C26 C25 C24 . . 118.66(15) ?
    C30 C25 C24 . . 122.83(16) ?
    C27 C26 C25 . . 120.57(18) ?
    C27 C26 H26 . . 119.7 ?
    C25 C26 H26 . . 119.7 ?
    C28 C27 C26 . . 120.26(19) ?
    C28 C27 H27 . . 119.9 ?
    C26 C27 H27 . . 119.9 ?
    C27 C28 C29 . . 119.95(19) ?
    C27 C28 H28 . . 120.0 ?
    C29 C28 H28 . . 120.0 ?
    C28 C29 C30 . . 120.40(19) ?
    C28 C29 H29 . . 119.8 ?
    C30 C29 H29 . . 119.8 ?
    C29 C30 C25 . . 120.32(18) ?
    C29 C30 H30 . . 119.8 ?
    C25 C30 H30 . . 119.8 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C8 N1 N2 C9 . . . . 163.02(17) ?
    C23 N3 N4 C24 . . . . 178.86(16) ?
    C1 O1 C2 C3 . . . . 11.4(3) ?
    C1 O1 C2 C7 . . . . -168.67(16) ?
    O1 C2 C3 C4 . . . . 179.02(16) ?
    C7 C2 C3 C4 . . . . -0.9(3) ?
    C2 C3 C4 C5 . . . . -0.7(3) ?
    C3 C4 C5 C6 . . . . 1.3(3) ?
    C3 C4 C5 C8 . . . . 179.06(17) ?
    C4 C5 C6 C7 . . . . -0.2(3) ?
    C8 C5 C6 C7 . . . . -177.92(16) ?
    C5 C6 C7 O2 . . . . 177.63(16) ?
    C5 C6 C7 C2 . . . . -1.4(3) ?
    O1 C2 C7 O2 . . . . 2.9(2) ?
    C3 C2 C7 O2 . . . . -177.16(16) ?
    O1 C2 C7 C6 . . . . -177.95(15) ?
    C3 C2 C7 C6 . . . . 2.0(2) ?
    N2 N1 C8 C5 . . . . 175.45(16) ?
    C4 C5 C8 N1 . . . . 171.98(17) ?
    C6 C5 C8 N1 . . . . -10.3(3) ?
    N1 N2 C9 O3 . . . . -2.9(3) ?
    N1 N2 C9 C10 . . . . 177.80(15) ?
    O3 C9 C10 C15 . . . . 136.6(2) ?
    N2 C9 C10 C15 . . . . -44.2(2) ?
    O3 C9 C10 C11 . . . . -43.7(3) ?
    N2 C9 C10 C11 . . . . 135.60(18) ?
    C15 C10 C11 C12 . . . . 0.9(3) ?
    C9 C10 C11 C12 . . . . -178.87(18) ?
    C10 C11 C12 C13 . . . . -2.2(3) ?
    C11 C12 C13 C14 . . . . 1.4(3) ?
    C12 C13 C14 C15 . . . . 0.6(3) ?
    C11 C10 C15 C14 . . . . 1.1(3) ?
    C9 C10 C15 C14 . . . . -179.15(18) ?
    C13 C14 C15 C10 . . . . -1.8(3) ?
    C16 O4 C17 C18 . . . . -2.7(3) ?
    C16 O4 C17 C22 . . . . 176.84(17) ?
    O4 C17 C18 C19 . . . . -178.77(17) ?
    C22 C17 C18 C19 . . . . 1.7(3) ?
    C17 C18 C19 C20 . . . . -0.1(3) ?
    C18 C19 C20 C21 . . . . -1.0(3) ?
    C18 C19 C20 C23 . . . . 178.33(18) ?
    C19 C20 C21 C22 . . . . 0.4(3) ?
    C23 C20 C21 C22 . . . . -178.83(17) ?
    C20 C21 C22 O5 . . . . -178.20(17) ?
    C20 C21 C22 C17 . . . . 1.1(3) ?
    O4 C17 C22 O5 . . . . -2.4(2) ?
    C18 C17 C22 O5 . . . . 177.15(17) ?
    O4 C17 C22 C21 . . . . 178.21(16) ?
    C18 C17 C22 C21 . . . . -2.2(3) ?
    N4 N3 C23 C20 . . . . 178.03(16) ?
    C19 C20 C23 N3 . . . . -176.20(18) ?
    C21 C20 C23 N3 . . . . 3.1(3) ?
    N3 N4 C24 O6 . . . . -1.9(3) ?
    N3 N4 C24 C25 . . . . 178.05(14) ?
    O6 C24 C25 C26 . . . . 21.6(3) ?
    N4 C24 C25 C26 . . . . -158.39(16) ?
    O6 C24 C25 C30 . . . . -156.95(18) ?
    N4 C24 C25 C30 . . . . 23.1(2) ?
    C30 C25 C26 C27 . . . . -0.3(3) ?
    C24 C25 C26 C27 . . . . -178.86(17) ?
    C25 C26 C27 C28 . . . . 0.8(3) ?
    C26 C27 C28 C29 . . . . -0.7(3) ?
    C27 C28 C29 C30 . . . . 0.1(3) ?
    C28 C29 C30 C25 . . . . 0.5(3) ?
    C26 C25 C30 C29 . . . . -0.4(3) ?
    C24 C25 C30 C29 . . . . 178.14(18) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    O2 H2 O3 3_565 0.82 1.85 2.6739(17) 180 yes
    O5 H5 O6 3_677 0.82 1.94 2.7521(18) 175 yes
    N2 H2A O4 1_554 0.86 2.21 2.867(2) 133 yes
    N2 H2A O5 1_554 0.86 2.51 3.326(2) 158 yes
    N4 H4 O1 4_676 0.86 2.26 3.0206(19) 147 yes
    N4 H4 O2 4_676 0.86 2.60 3.309(2) 140 yes
data_global
_journal_date_recd_electronic     2005-10-18
_journal_date_accepted     2005-10-25
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2005
_journal_volume     61
_journal_issue     11
_journal_page_first     o3917
_journal_page_last     o3918
_journal_paper_category     EO
_journal_coeditor_code     IS6140
_publ_contact_author_name     'Jun Shi'
_publ_contact_author_address
;
Department of Basic Course
Tianjin Agricultural College
Tianjin 300384
P. R. China.
School of Chemical Engineering and Technology
Tianjin University
Tianjin 300072
P. R. China.
;
_publ_contact_author_email     shi_jun99@163.com
_publ_contact_author_fax     '086(022)23781295'
_publ_contact_author_phone     '086(022)23340268'
_publ_section_title
;\
(E)-N-Benzoyl-N'-(3-hydroxy-4-methoxybenzylidene)\
hydrazine
;
loop_
    _publ_author_name
    _publ_author_address
    'Shi, Jun'
;
Department of Basic Course
Tianjin Agricultural College
Tianjin 300384
People's Republic of China
School of Chemical Engineering and Technology
Tianjin University
Tianjin 300072
People's Republic of China
;
