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The title cobalt(II) coordination polymer, [Co(C16H8O8)(C10H8N2)2]n, was obtained by the reaction of Co(OAc)2·4H2O (OAc is acetate), 4,4′-bipyridine (4,4′-bpy) and biphenyl-3,4,3′,4′-tetra­carboxylic acid (H4L) under hydro­thermal conditions. Each CoII atom lies at the centre of a distorted octa­hedron, coordinated by four O atoms from three H2L2− and two N atoms from two monodentate 4,4′-bpy ligands. Each H2L2− ligand coordinates to three CoII centres through two carboxyl­ate groups, one acting as a bridging bidentate group and the other in a chelating bidentate fashion. Two Co atoms, two H2L2− and four 4,4′-bpy ligands form a ring dimer node, and these nodes link into an extended broad chain along the c axis.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805033842/rn6063sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805033842/rn6063Isup2.hkl
Contains datablock I

CCDC reference: 293971

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.043
  • wR factor = 0.101
  • Data-to-parameter ratio = 15.5

checkCIF/PLATON results

No syntax errors found



Alert level C ABSMU01_ALERT_1_C The ratio of given/expected absorption coefficient lies outside the range 0.99 <> 1.01 Calculated value of mu = 0.643 Value of mu given = 0.636 PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 1.04 PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_C Check the Reported _diffrn_ambient_temperature . 293 K PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.86 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.19 Ratio PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor .... 2.16 PLAT804_ALERT_4_C ARU-Pack Problem in PLATON Analysis ............ ! PLAT804_ALERT_4_C ARU-Pack Problem in PLATON Analysis ............ ! PLAT804_ALERT_4_C ARU-Pack Problem in PLATON Analysis ............ !
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 11 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 5 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO; data reduction: PROCESS-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL-Plus (Sheldrick, 1990); software used to prepare material for publication: SHELXL97.

poly[bis(4,4'-bipyridine)(µ3-4,4'-dicarboxy-biphenyl-3,3'- dicarboxylato)cobalt(II)] top
Crystal data top
[Co(C16H8O8)(C10H8N2)2]F(000) = 1436
Mr = 699.52Dx = 1.564 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 11.9781 (10) ÅCell parameters from 18156 reflections
b = 24.094 (2) Åθ = 1.7–28.3°
c = 10.7056 (9) ŵ = 0.64 mm1
β = 105.925 (2)°T = 293 K
V = 2971.1 (4) Å3Block, red
Z = 40.24 × 0.23 × 0.11 mm
Data collection top
Rigaku R-AXIS RAPID
diffractometer
6985 independent reflections
Radiation source: fine-focus sealed tube3983 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.049
Detector resolution: 10.0 pixels mm-1θmax = 28.3°, θmin = 1.7°
ω scansh = 1315
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
k = 3128
Tmin = 0.812, Tmax = 0.896l = 1412
18276 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.043Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.101H atoms treated by a mixture of independent and constrained refinement
S = 0.97 w = 1/[σ2(Fo2) + (0.0415P)2]
where P = (Fo2 + 2Fc2)/3
6985 reflections(Δ/σ)max = 0.033
450 parametersΔρmax = 0.68 e Å3
0 restraintsΔρmin = 0.46 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C10.6125 (2)0.19844 (11)0.6864 (2)0.0287 (6)
C20.8172 (2)0.11508 (10)0.7403 (2)0.0276 (6)
C31.0674 (2)0.06958 (10)1.4222 (2)0.0243 (6)
C41.2062 (2)0.16976 (11)1.5589 (3)0.0336 (7)
C50.7061 (2)0.19548 (9)0.8121 (2)0.0240 (6)
C60.79263 (19)0.15477 (9)0.8382 (2)0.0222 (5)
C70.8712 (2)0.15271 (10)0.9599 (2)0.0266 (6)
H70.92680.12470.97760.032*
C80.8700 (2)0.19108 (9)1.0572 (2)0.0234 (6)
C90.7865 (2)0.23281 (10)1.0279 (2)0.0298 (6)
H90.78570.26001.08920.036*
C100.7051 (2)0.23412 (10)0.9089 (2)0.0278 (6)
H100.64810.26140.89250.033*
C111.1115 (2)0.17317 (10)1.4335 (2)0.0306 (6)
C121.0790 (2)0.22566 (10)1.3811 (3)0.0415 (7)
H121.11070.25701.42850.050*
C131.0008 (2)0.23216 (11)1.2603 (3)0.0388 (7)
H130.97970.26761.22800.047*
C140.9538 (2)0.18605 (10)1.1872 (2)0.0251 (6)
C150.9829 (2)0.13392 (10)1.2421 (2)0.0255 (6)
H150.94980.10281.19500.031*
C161.05929 (19)0.12651 (9)1.3645 (2)0.0228 (5)
C170.7604 (2)0.11457 (11)0.3844 (2)0.0372 (7)
H170.78400.14390.44210.045*
C180.6946 (2)0.12655 (11)0.2606 (3)0.0369 (7)
H180.67440.16310.23700.044*
C190.6583 (2)0.08453 (11)0.1713 (2)0.0302 (6)
C200.6922 (2)0.03163 (11)0.2143 (3)0.0419 (7)
H200.67080.00180.15780.050*
C210.7574 (2)0.02255 (11)0.3400 (3)0.0420 (7)
H210.77800.01380.36560.050*
C220.4461 (2)0.14970 (12)0.1176 (3)0.0414 (7)
H220.39930.18110.13490.050*
C230.5153 (2)0.14227 (11)0.0077 (3)0.0385 (7)
H230.51460.16830.07160.046*
C240.5855 (2)0.09594 (11)0.0374 (2)0.0319 (6)
C250.5855 (2)0.06126 (12)0.0652 (3)0.0494 (8)
H250.63390.03040.05190.059*
C260.5132 (3)0.07234 (13)0.1882 (3)0.0500 (8)
H260.51550.04830.25550.060*
C271.3868 (3)0.17705 (14)1.3172 (3)0.0538 (9)
H271.39880.21451.33710.065*
C281.3058 (2)0.16252 (12)1.2025 (3)0.0487 (8)
H281.26490.19001.14760.058*
C291.2859 (2)0.10762 (11)1.1700 (3)0.0340 (6)
C301.3455 (3)0.06864 (13)1.2593 (3)0.0530 (9)
H301.33190.03091.24440.064*
C311.4255 (3)0.08717 (15)1.3711 (3)0.0637 (10)
H311.46590.06081.42960.076*
C321.1135 (2)0.10930 (11)0.8187 (2)0.0329 (6)
H321.10200.13360.74880.040*
C331.1871 (2)0.12533 (11)0.9353 (3)0.0352 (7)
H331.22400.15960.94240.042*
C341.2069 (2)0.09048 (10)1.0434 (2)0.0299 (6)
C351.1520 (2)0.03925 (11)1.0235 (3)0.0344 (7)
H351.16420.01371.09110.041*
C361.0792 (2)0.02643 (10)0.9028 (2)0.0308 (6)
H361.04300.00810.89180.037*
Co10.91816 (3)0.052633 (13)0.61614 (3)0.02609 (11)
N10.79286 (17)0.06296 (8)0.4272 (2)0.0305 (5)
N20.44195 (19)0.11485 (10)0.2150 (2)0.0402 (6)
N31.05768 (17)0.06101 (8)0.79996 (19)0.0283 (5)
N41.4478 (2)0.14026 (12)1.3997 (2)0.0511 (7)
O10.54251 (16)0.23581 (8)0.66041 (19)0.0464 (5)
O20.61500 (16)0.15656 (8)0.61008 (19)0.0399 (5)
O30.87348 (14)0.13393 (7)0.66506 (16)0.0302 (4)
O40.79670 (15)0.06433 (7)0.74458 (17)0.0352 (4)
O51.08982 (15)0.03004 (7)1.35570 (16)0.0320 (4)
O61.04652 (14)0.06467 (7)1.53016 (16)0.0312 (4)
O71.26811 (17)0.12420 (8)1.56766 (19)0.0412 (5)
O81.22466 (17)0.20579 (8)1.63992 (19)0.0566 (6)
H11.329 (3)0.1240 (15)1.636 (4)0.099 (14)*
H20.554 (3)0.1566 (12)0.538 (3)0.065 (10)*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.0273 (14)0.0326 (16)0.0244 (15)0.0029 (12)0.0039 (12)0.0024 (12)
C20.0296 (14)0.0274 (15)0.0191 (14)0.0063 (11)0.0046 (11)0.0007 (11)
C30.0224 (13)0.0271 (14)0.0194 (14)0.0002 (10)0.0010 (11)0.0010 (11)
C40.0381 (16)0.0329 (16)0.0233 (15)0.0029 (13)0.0024 (13)0.0037 (12)
C50.0282 (14)0.0235 (13)0.0186 (14)0.0002 (11)0.0036 (11)0.0044 (11)
C60.0290 (14)0.0207 (13)0.0168 (13)0.0004 (10)0.0061 (11)0.0005 (10)
C70.0325 (14)0.0232 (13)0.0222 (14)0.0086 (11)0.0041 (12)0.0024 (11)
C80.0302 (14)0.0209 (13)0.0158 (13)0.0005 (10)0.0011 (11)0.0005 (10)
C90.0416 (16)0.0251 (14)0.0215 (14)0.0075 (12)0.0066 (12)0.0041 (11)
C100.0343 (15)0.0232 (14)0.0245 (15)0.0125 (11)0.0054 (12)0.0012 (11)
C110.0375 (15)0.0258 (15)0.0238 (14)0.0002 (11)0.0007 (12)0.0010 (11)
C120.0556 (18)0.0262 (15)0.0290 (16)0.0071 (14)0.0116 (14)0.0038 (13)
C130.0538 (18)0.0206 (14)0.0318 (16)0.0009 (12)0.0057 (14)0.0021 (12)
C140.0301 (14)0.0257 (14)0.0160 (14)0.0032 (11)0.0004 (11)0.0001 (10)
C150.0328 (14)0.0208 (13)0.0199 (14)0.0002 (11)0.0022 (11)0.0033 (10)
C160.0280 (14)0.0222 (13)0.0165 (13)0.0042 (10)0.0030 (11)0.0011 (10)
C170.0466 (17)0.0360 (16)0.0226 (15)0.0016 (13)0.0012 (13)0.0034 (12)
C180.0489 (17)0.0327 (15)0.0242 (15)0.0055 (13)0.0018 (13)0.0043 (12)
C190.0265 (14)0.0415 (17)0.0197 (14)0.0017 (12)0.0014 (11)0.0028 (12)
C200.0489 (18)0.0351 (16)0.0302 (17)0.0079 (14)0.0088 (14)0.0109 (13)
C210.0523 (18)0.0329 (16)0.0297 (17)0.0127 (13)0.0076 (14)0.0012 (13)
C220.0355 (16)0.0440 (18)0.0396 (19)0.0078 (13)0.0019 (14)0.0113 (15)
C230.0409 (16)0.0393 (17)0.0293 (16)0.0026 (13)0.0006 (13)0.0006 (12)
C240.0276 (14)0.0393 (16)0.0250 (15)0.0010 (12)0.0010 (12)0.0008 (12)
C250.0506 (19)0.057 (2)0.0298 (17)0.0252 (16)0.0069 (14)0.0039 (15)
C260.0553 (19)0.060 (2)0.0253 (17)0.0119 (16)0.0044 (14)0.0063 (14)
C270.058 (2)0.051 (2)0.045 (2)0.0122 (16)0.0008 (17)0.0138 (16)
C280.0498 (19)0.0429 (19)0.0413 (19)0.0030 (15)0.0078 (15)0.0025 (14)
C290.0300 (15)0.0405 (17)0.0271 (15)0.0002 (13)0.0005 (12)0.0065 (13)
C300.062 (2)0.0466 (19)0.0342 (18)0.0103 (15)0.0144 (16)0.0101 (14)
C310.069 (2)0.067 (3)0.037 (2)0.0188 (19)0.0146 (17)0.0081 (17)
C320.0352 (15)0.0362 (16)0.0248 (15)0.0041 (12)0.0036 (12)0.0061 (12)
C330.0369 (16)0.0292 (15)0.0353 (17)0.0054 (12)0.0031 (13)0.0009 (12)
C340.0266 (14)0.0350 (15)0.0251 (15)0.0049 (12)0.0018 (12)0.0025 (12)
C350.0410 (16)0.0365 (16)0.0227 (15)0.0029 (13)0.0034 (13)0.0038 (12)
C360.0389 (15)0.0251 (14)0.0263 (16)0.0032 (12)0.0053 (13)0.0013 (11)
Co10.0344 (2)0.02349 (19)0.01775 (19)0.00300 (16)0.00274 (14)0.00093 (15)
N10.0339 (12)0.0301 (13)0.0225 (12)0.0037 (10)0.0003 (10)0.0015 (10)
N20.0363 (13)0.0526 (16)0.0253 (14)0.0002 (12)0.0025 (11)0.0051 (12)
N30.0300 (12)0.0329 (13)0.0205 (12)0.0001 (10)0.0046 (9)0.0005 (10)
N40.0432 (15)0.0666 (19)0.0356 (16)0.0016 (13)0.0024 (13)0.0145 (14)
O10.0436 (12)0.0460 (12)0.0378 (12)0.0164 (10)0.0085 (9)0.0020 (10)
O20.0365 (11)0.0467 (12)0.0276 (12)0.0030 (9)0.0064 (9)0.0098 (10)
O30.0391 (10)0.0313 (10)0.0201 (10)0.0032 (8)0.0078 (8)0.0003 (8)
O40.0487 (11)0.0245 (10)0.0310 (11)0.0019 (8)0.0087 (9)0.0043 (8)
O50.0494 (11)0.0200 (9)0.0258 (11)0.0034 (8)0.0092 (9)0.0017 (8)
O60.0364 (10)0.0375 (11)0.0186 (10)0.0006 (8)0.0057 (8)0.0036 (8)
O70.0362 (12)0.0481 (13)0.0299 (12)0.0053 (10)0.0067 (10)0.0016 (9)
O80.0711 (15)0.0450 (13)0.0335 (12)0.0032 (11)0.0195 (11)0.0148 (10)
Geometric parameters (Å, º) top
C1—O11.210 (3)C22—N21.330 (3)
C1—O21.304 (3)C22—C231.381 (3)
C1—C51.498 (3)C22—H220.9300
C2—O41.250 (3)C23—C241.382 (3)
C2—O31.267 (3)C23—H230.9300
C2—C61.507 (3)C24—C251.380 (4)
C3—O61.254 (3)C25—C261.389 (4)
C3—O51.261 (3)C25—H250.9300
C3—C161.496 (3)C26—N21.314 (3)
C4—O81.204 (3)C26—H260.9300
C4—O71.313 (3)C27—N41.321 (4)
C4—C111.504 (3)C27—C281.385 (4)
C5—C101.395 (3)C27—H270.9300
C5—C61.399 (3)C28—C291.372 (4)
C6—C71.383 (3)C28—H280.9300
C7—C81.395 (3)C29—C301.390 (4)
C7—H70.9300C29—C341.483 (3)
C8—C91.392 (3)C30—C311.385 (4)
C8—C141.481 (3)C30—H300.9300
C9—C101.376 (3)C31—N41.325 (4)
C9—H90.9300C31—H310.9300
C10—H100.9300C32—N31.329 (3)
C11—C161.395 (3)C32—C331.371 (3)
C11—C121.395 (3)C32—H320.9300
C12—C131.381 (3)C33—C341.396 (3)
C12—H120.9300C33—H330.9300
C13—C141.387 (3)C34—C351.387 (3)
C13—H130.9300C35—C361.381 (3)
C14—C151.390 (3)C35—H350.9300
C15—C161.389 (3)C36—N31.348 (3)
C15—H150.9300C36—H360.9300
C17—N11.345 (3)Co1—O6i2.0180 (17)
C17—C181.374 (3)Co1—O5ii2.0209 (16)
C17—H170.9300Co1—O32.1333 (16)
C18—C191.378 (3)Co1—N12.177 (2)
C18—H180.9300Co1—N32.214 (2)
C19—C201.378 (3)Co1—O42.2769 (18)
C19—C241.485 (3)O2—H20.91 (3)
C20—C211.375 (4)O5—Co1ii2.0209 (16)
C20—H200.9300O6—Co1iii2.0180 (17)
C21—N11.336 (3)O7—H10.88 (4)
C21—H210.9300
O1—C1—O2124.4 (2)C23—C24—C25116.0 (2)
O1—C1—C5122.9 (2)C23—C24—C19122.1 (2)
O2—C1—C5112.7 (2)C25—C24—C19121.9 (2)
O4—C2—O3121.2 (2)C24—C25—C26120.2 (3)
O4—C2—C6121.1 (2)C24—C25—H25119.9
O3—C2—C6117.0 (2)C26—C25—H25119.9
O6—C3—O5125.2 (2)N2—C26—C25123.7 (3)
O6—C3—C16117.4 (2)N2—C26—H26118.1
O5—C3—C16117.3 (2)C25—C26—H26118.1
O8—C4—O7124.3 (2)N4—C27—C28123.2 (3)
O8—C4—C11123.2 (2)N4—C27—H27118.4
O7—C4—C11112.5 (2)C28—C27—H27118.4
C10—C5—C6118.4 (2)C29—C28—C27120.0 (3)
C10—C5—C1118.6 (2)C29—C28—H28120.0
C6—C5—C1122.9 (2)C27—C28—H28120.0
C7—C6—C5119.3 (2)C28—C29—C30117.1 (3)
C7—C6—C2114.9 (2)C28—C29—C34121.6 (2)
C5—C6—C2125.6 (2)C30—C29—C34121.3 (2)
C6—C7—C8122.4 (2)C31—C30—C29118.7 (3)
C6—C7—H7118.8C31—C30—H30120.7
C8—C7—H7118.8C29—C30—H30120.7
C9—C8—C7117.6 (2)N4—C31—C30124.0 (3)
C9—C8—C14122.0 (2)N4—C31—H31118.0
C7—C8—C14120.3 (2)C30—C31—H31118.0
C10—C9—C8120.5 (2)N3—C32—C33123.7 (2)
C10—C9—H9119.7N3—C32—H32118.1
C8—C9—H9119.7C33—C32—H32118.1
C9—C10—C5121.6 (2)C32—C33—C34120.4 (2)
C9—C10—H10119.2C32—C33—H33119.8
C5—C10—H10119.2C34—C33—H33119.8
C16—C11—C12118.9 (2)C35—C34—C33116.3 (2)
C16—C11—C4123.2 (2)C35—C34—C29123.0 (2)
C12—C11—C4117.9 (2)C33—C34—C29120.7 (2)
C13—C12—C11121.5 (2)C36—C35—C34119.6 (2)
C13—C12—H12119.3C36—C35—H35120.2
C11—C12—H12119.3C34—C35—H35120.2
C12—C13—C14120.3 (2)N3—C36—C35123.8 (2)
C12—C13—H13119.9N3—C36—H36118.1
C14—C13—H13119.9C35—C36—H36118.1
C13—C14—C15118.0 (2)O6i—Co1—O5ii106.42 (7)
C13—C14—C8122.1 (2)O6i—Co1—O3104.71 (7)
C15—C14—C8119.9 (2)O5ii—Co1—O3147.47 (7)
C14—C15—C16122.6 (2)O6i—Co1—N188.69 (7)
C14—C15—H15118.7O5ii—Co1—N1101.68 (7)
C16—C15—H15118.7O3—Co1—N188.15 (7)
C15—C16—C11118.6 (2)O6i—Co1—N384.75 (7)
C15—C16—C3117.3 (2)O5ii—Co1—N390.71 (7)
C11—C16—C3123.5 (2)O3—Co1—N382.94 (7)
N1—C17—C18123.9 (2)N1—Co1—N3167.22 (8)
N1—C17—H17118.0O6i—Co1—O4161.94 (7)
C18—C17—H17118.0O5ii—Co1—O488.16 (6)
C17—C18—C19120.2 (2)O3—Co1—O459.55 (6)
C17—C18—H18119.9N1—Co1—O498.92 (7)
C19—C18—H18119.9N3—Co1—O484.46 (7)
C20—C19—C18116.1 (2)C21—N1—C17115.4 (2)
C20—C19—C24122.3 (2)C21—N1—Co1124.92 (17)
C18—C19—C24121.6 (2)C17—N1—Co1118.89 (17)
C21—C20—C19120.7 (2)C26—N2—C22116.0 (2)
C21—C20—H20119.7C32—N3—C36116.2 (2)
C19—C20—H20119.7C32—N3—Co1116.08 (16)
N1—C21—C20123.7 (3)C36—N3—Co1126.75 (17)
N1—C21—H21118.2C27—N4—C31116.9 (3)
C20—C21—H21118.2C1—O2—H2112.5 (19)
N2—C22—C23124.3 (3)C2—O3—Co192.28 (14)
N2—C22—H22117.9C2—O4—Co186.22 (15)
C23—C22—H22117.9C3—O5—Co1ii129.37 (16)
C24—C23—C22119.6 (3)C3—O6—Co1iii143.49 (16)
C24—C23—H23120.2C4—O7—H1113 (2)
C22—C23—H23120.2
O1—C1—C5—C107.0 (4)C27—C28—C29—C34175.0 (3)
O2—C1—C5—C10172.6 (2)C28—C29—C30—C313.7 (5)
O1—C1—C5—C6174.8 (2)C34—C29—C30—C31174.6 (3)
O2—C1—C5—C65.6 (3)C29—C30—C31—N41.1 (5)
C10—C5—C6—C72.6 (3)N3—C32—C33—C340.3 (4)
C1—C5—C6—C7175.7 (2)C32—C33—C34—C352.4 (4)
C10—C5—C6—C2170.9 (2)C32—C33—C34—C29179.7 (2)
C1—C5—C6—C210.9 (4)C28—C29—C34—C35156.2 (3)
O4—C2—C6—C775.3 (3)C30—C29—C34—C3525.7 (4)
O3—C2—C6—C795.5 (3)C28—C29—C34—C3326.0 (4)
O4—C2—C6—C5111.0 (3)C30—C29—C34—C33152.2 (3)
O3—C2—C6—C578.2 (3)C33—C34—C35—C362.4 (4)
C5—C6—C7—C82.2 (4)C29—C34—C35—C36179.7 (2)
C2—C6—C7—C8171.9 (2)C34—C35—C36—N30.4 (4)
C6—C7—C8—C90.5 (4)C20—C21—N1—C170.0 (4)
C6—C7—C8—C14178.1 (2)C20—C21—N1—Co1169.7 (2)
C7—C8—C9—C102.9 (4)C18—C17—N1—C210.5 (4)
C14—C8—C9—C10175.7 (2)C18—C17—N1—Co1170.9 (2)
C8—C9—C10—C52.6 (4)O6i—Co1—N1—C2185.4 (2)
C6—C5—C10—C90.2 (4)O5ii—Co1—N1—C2121.1 (2)
C1—C5—C10—C9178.1 (2)O3—Co1—N1—C21169.8 (2)
O8—C4—C11—C16154.0 (3)N3—Co1—N1—C21144.5 (3)
O7—C4—C11—C1628.0 (4)O4—Co1—N1—C21111.0 (2)
O8—C4—C11—C1229.3 (4)O6i—Co1—N1—C1783.96 (19)
O7—C4—C11—C12148.6 (3)O5ii—Co1—N1—C17169.53 (19)
C16—C11—C12—C133.1 (4)O3—Co1—N1—C1720.80 (19)
C4—C11—C12—C13173.7 (3)N3—Co1—N1—C1724.9 (5)
C11—C12—C13—C140.9 (4)O4—Co1—N1—C1779.6 (2)
C12—C13—C14—C153.4 (4)C25—C26—N2—C223.4 (4)
C12—C13—C14—C8179.8 (2)C23—C22—N2—C263.1 (4)
C9—C8—C14—C1336.5 (4)C33—C32—N3—C361.8 (4)
C7—C8—C14—C13144.9 (3)C33—C32—N3—Co1168.0 (2)
C9—C8—C14—C15140.2 (3)C35—C36—N3—C321.7 (4)
C7—C8—C14—C1538.4 (3)C35—C36—N3—Co1166.73 (19)
C13—C14—C15—C162.0 (4)O6i—Co1—N3—C3261.16 (18)
C8—C14—C15—C16178.9 (2)O5ii—Co1—N3—C32167.58 (18)
C14—C15—C16—C111.9 (4)O3—Co1—N3—C3244.41 (18)
C14—C15—C16—C3169.5 (2)N1—Co1—N3—C321.7 (5)
C12—C11—C16—C154.4 (4)O4—Co1—N3—C32104.34 (18)
C4—C11—C16—C15172.2 (2)O6i—Co1—N3—C36130.4 (2)
C12—C11—C16—C3166.4 (2)O5ii—Co1—N3—C3624.0 (2)
C4—C11—C16—C317.0 (4)O3—Co1—N3—C36124.1 (2)
O6—C3—C16—C15122.6 (2)N1—Co1—N3—C36170.2 (3)
O5—C3—C16—C1554.5 (3)O4—Co1—N3—C3664.1 (2)
O6—C3—C16—C1148.4 (3)C28—C27—N4—C312.6 (5)
O5—C3—C16—C11134.5 (2)C30—C31—N4—C272.0 (5)
N1—C17—C18—C190.5 (4)O4—C2—O3—Co19.0 (2)
C17—C18—C19—C200.1 (4)C6—C2—O3—Co1161.79 (18)
C17—C18—C19—C24179.0 (2)O6i—Co1—O3—C2165.48 (13)
C18—C19—C20—C210.6 (4)O5ii—Co1—O3—C22.7 (2)
C24—C19—C20—C21178.5 (3)N1—Co1—O3—C2106.35 (14)
C19—C20—C21—N10.6 (5)N3—Co1—O3—C282.83 (14)
N2—C22—C23—C240.3 (4)O4—Co1—O3—C24.88 (13)
C22—C23—C24—C253.4 (4)O3—C2—O4—Co18.4 (2)
C22—C23—C24—C19177.5 (2)C6—C2—O4—Co1162.0 (2)
C20—C19—C24—C23154.3 (3)O6i—Co1—O4—C226.5 (3)
C18—C19—C24—C2324.8 (4)O5ii—Co1—O4—C2170.99 (14)
C20—C19—C24—C2526.6 (4)O3—Co1—O4—C24.96 (13)
C18—C19—C24—C25154.3 (3)N1—Co1—O4—C287.48 (14)
C23—C24—C25—C263.1 (4)N3—Co1—O4—C280.10 (14)
C19—C24—C25—C26177.8 (3)O6—C3—O5—Co1ii8.1 (4)
C24—C25—C26—N20.3 (5)C16—C3—O5—Co1ii168.70 (15)
N4—C27—C28—C290.1 (5)O5—C3—O6—Co1iii89.1 (3)
C27—C28—C29—C303.2 (4)C16—C3—O6—Co1iii87.7 (3)
Symmetry codes: (i) x, y, z1; (ii) x+2, y, z+2; (iii) x, y, z+1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O7—H1···N2iv0.88 (4)1.80 (4)2.672 (4)171 (5)
O2—H2···N4v0.90 (3)1.71 (4)2.600 (3)166 (4)
Symmetry codes: (iv) x+1, y, z+2; (v) x1, y, z1.
 

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