##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Bis(9-hydroxyfluorene-9-carboxylato-κ²O,O')bis(3-hydroxypyridine-
\kN)copper(II) methanol disolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     '2C14 H9 O3, 2C5 H5 N O, Cu, 2C H4 O'
_chemical_formula_sum     'C40 H36 Cu N2 O10'
_chemical_formula_iupac     '[Cu (C14 H9 O3)2 (C5 H5 N O)2], 2C H4 O'
_chemical_formula_weight     768.25
_chemical_melting_point     ?
_symmetry_cell_setting     Monoclinic
_symmetry_space_group_name_H-M     'P 21/n'
_symmetry_space_group_name_Hall     '-P 2yn'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     14.877(3)
_cell_length_b     7.872(2)
_cell_length_c     16.527(3)
_cell_angle_alpha     90.00
_cell_angle_beta     112.04(3)
_cell_angle_gamma     90.00
_cell_volume     1794.2(6)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     14783
_cell_measurement_theta_min     3.0
_cell_measurement_theta_max     27.5
_cell_measurement_temperature     295(2)
_exptl_crystal_description     Block
_exptl_crystal_colour     Blue
_exptl_crystal_size_max     0.38
_exptl_crystal_size_mid     0.26
_exptl_crystal_size_min     0.18
_exptl_crystal_density_diffrn     1.422
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     798
_exptl_absorpt_coefficient_mu     0.672
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(ABSCOR; Higashi, 1995)'
_exptl_absorpt_correction_T_min     0.684
_exptl_absorpt_correction_T_max     0.889
_diffrn_ambient_temperature     295(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Rigaku RAXIS-RAPID IP'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     16937
_diffrn_reflns_av_R_equivalents     0.019
_diffrn_reflns_av_sigmaI/netI     0.016
_diffrn_reflns_theta_min     3.0
_diffrn_reflns_theta_max     27.5
_diffrn_reflns_theta_full     27.5
_diffrn_measured_fraction_theta_max     1.00
_diffrn_measured_fraction_theta_full     1.00
_diffrn_reflns_limit_h_min     -19
_diffrn_reflns_limit_h_max     19
_diffrn_reflns_limit_k_min     -10
_diffrn_reflns_limit_k_max     10
_diffrn_reflns_limit_l_min     -21
_diffrn_reflns_limit_l_max     21
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_reflns_number_total     4101
_reflns_number_gt     3706
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.037
_refine_ls_R_factor_gt     0.033
_refine_ls_wR_factor_gt     0.099
_refine_ls_wR_factor_ref     0.101
_refine_ls_goodness_of_fit_ref     1.05
_refine_ls_restrained_S_all     1.06
_refine_ls_number_reflns     4101
_refine_ls_number_parameters     298
_refine_ls_number_restraints     93
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
     'calc w = 1/[σ²(Fo²)+(0.0675P)²+0.3683P] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.39
_refine_diff_density_min     -0.42
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cu' 'Cu' 0.3201 1.2651
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'RAPID-AUTO (Rigaku, 1998)'
_computing_cell_refinement     RAPID-AUTO
_computing_data_reduction     'CrystalStructure (Rigaku/MSC, 2002)'
_computing_structure_solution     'difference Fourier, with Cu at 1/2, 1/2, 1/2'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEPII (Johnson, 1976)'
_computing_publication_material     SHELXL97
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Cu1 0.5000 0.5000 0.5000 0.03060(10)
                                       Uani d S 1 . . Cu
    O1 0.52320(10)
                 0.70030(10)
                           0.43870(10)
                                     0.0356(2) Uani d . 1 . . O
    O2 0.62560(10)
                 0.87240(10)
                           0.41150(10)
                                     0.0454(3) Uani d . 1 . . O
    O3 0.65240(10)
                 0.45680(10)
                           0.49950(10)
                                     0.0331(2) Uani d . 1 . . O
    O5 0.73110(10)
                 0.1504(2) 0.50080(10)
                                     0.0563(3) Uani d . 1 . . O
    N1 0.43700(10)
                 0.3747(2) 0.38530(10)
                                     0.0358(3) Uani d D 1 . . N
    C1 0.60490(10)
                 0.7332(2) 0.43540(10)
                                     0.0305(3) Uani d . 1 . . C
    C2 0.68200(10)
                 0.5906(2) 0.45730(10)
                                     0.0289(3) Uani d . 1 . . C
    C3 0.69480(10)
                 0.5356(2) 0.37380(10)
                                     0.0320(3) Uani d . 1 . . C
    C4 0.62660(10)
                 0.4689(2) 0.29860(10)
                                     0.0423(4) Uani d . 1 . . C
    C5 0.6560(2) 0.4254(2) 0.23070(10)
                                     0.0520(4) Uani d . 1 . . C
    C6 0.7512(2) 0.4480(3) 0.23820(10)
                                     0.0546(5) Uani d . 1 . . C
    C7 0.8188(2) 0.5162(2) 0.31240(10)
                                     0.0469(4) Uani d . 1 . . C
    C8 0.79040(10)
                 0.5623(2) 0.38070(10)
                                     0.0356(3) Uani d . 1 . . C
    C9 0.84470(10)
                 0.6384(2) 0.46590(10)
                                     0.0359(3) Uani d . 1 . . C
    C10 0.94110(10)
                  0.6894(2) 0.50390(10)
                                      0.0485(4) Uani d . 1 . . C
    C11 0.97440(10)
                  0.7551(3) 0.58740(10)
                                      0.0547(5) Uani d . 1 . . C
    C12 0.91380(10)
                  0.7688(2) 0.63340(10)
                                      0.0518(4) Uani d . 1 . . C
    C13 0.81680(10)
                  0.7196(2) 0.59550(10)
                                      0.0420(4) Uani d . 1 . . C
    C14 0.78320(10)
                  0.6558(2) 0.51200(10)
                                      0.0320(3) Uani d . 1 . . C
    O4 0.4598(5) -0.0181(5) 0.2856(2) 0.090(2) Uani d PDU 0.660(10)
                                                                  A 1 O
    C15 0.4668(3) 0.2205(5) 0.3747(4) 0.0370(10)
                                               Uani d PDU 0.660(10)
                                                                  A 1 C
    C16 0.4288(4) 0.1357(5) 0.2957(3) 0.0480(10)
                                               Uani d PDU 0.660(10)
                                                                  A 1 C
    C17 0.3585(5) 0.2170(10)
                           0.2257(4) 0.053(2) Uani d PDU 0.660(10)
                                                                 A 1 C
    C18 0.3283(7) 0.3760(10)
                           0.2379(7) 0.050(2) Uani d PDU 0.660(10)
                                                                 A 1 C
    C19 0.3689(4) 0.4540(10)
                           0.3180(5) 0.0400(10)
                                              Uani d PDU 0.660(10)
                                                                 A 1 C
    C20 0.8202(2) 0.1491(3) 0.4902(2) 0.0653(6) Uani d . 1 . . C
    O4' 0.4092(6) -0.0694(9) 0.3085(5) 0.065(2) Uani d PDU 0.340(10)
                                                                   A 2 O
    C15' 0.4467(5) 0.2020(10)
                            0.3852(6) 0.0320(10)
                                               Uani d PDU 0.340(10)
                                                                  A 2 C
    C16' 0.4024(5) 0.1000(10)
                            0.3116(5) 0.041(2) Uani d PDU 0.340(10)
                                                                  A 2 C
    C17' 0.3445(8) 0.182(2) 0.2351(8) 0.043(2) Uani d PDU 0.340(10)
                                                                  A 2 C
    C18' 0.3340(10)
                  0.356(2) 0.2350(10)
                                    0.049(4) Uani d PDU 0.340(10)
                                                                A 2 C
    C19' 0.3813(7) 0.449(2) 0.3101(8) 0.038(3) Uani d PDU 0.340(10)
                                                                  A 2 C
    H3o 0.6530 0.3670 0.4746 0.040 Uiso calc R 1 . . H
    H5o 0.6957 0.0767 0.4699 0.068 Uiso calc R 1 . . H
    H4 0.5627 0.4535 0.2935 0.051 Uiso calc R 1 . . H
    H5 0.6111 0.3803 0.1795 0.062 Uiso calc R 1 . . H
    H6 0.7694 0.4165 0.1923 0.066 Uiso calc R 1 . . H
    H7 0.8825 0.5315 0.3171 0.056 Uiso calc R 1 . . H
    H10 0.9823 0.6794 0.4736 0.058 Uiso calc R 1 . . H
    H11 1.0385 0.7907 0.6132 0.066 Uiso calc R 1 . . H
    H12 0.9379 0.8112 0.6901 0.062 Uiso calc R 1 . . H
    H13 0.7759 0.7297 0.6261 0.050 Uiso calc R 1 . . H
    H4o 0.5023 -0.0646 0.3267 0.109 Uiso calc PR 0.660(10)
                                                         A 1 H
    H15 0.5146 0.1679 0.4216 0.045 Uiso calc PR 0.660(10)
                                                        A 1 H
    H17 0.3323 0.1637 0.1716 0.064 Uiso calc PR 0.660(10)
                                                        A 1 H
    H18 0.2804 0.4312 0.1920 0.060 Uiso calc PR 0.660(10)
                                                        A 1 H
    H19 0.3491 0.5633 0.3256 0.048 Uiso calc PR 0.660(10)
                                                        A 1 H
    H20a 0.8613 0.2365 0.5257 0.098 Uiso calc R 1 . . H
    H20b 0.8097 0.1693 0.4301 0.098 Uiso calc R 1 . . H
    H20c 0.8508 0.0406 0.5077 0.098 Uiso calc R 1 . . H
    H4'o 0.4426 -0.1222 0.3522 0.078 Uiso calc PR 0.340(10)
                                                          A 2 H
    H15' 0.4848 0.1491 0.4371 0.038 Uiso calc PR 0.340(10)
                                                         A 2 H
    H17' 0.3129 0.1195 0.1846 0.051 Uiso calc PR 0.340(10)
                                                         A 2 H
    H18' 0.2960 0.4118 0.1837 0.059 Uiso calc PR 0.340(10)
                                                         A 2 H
    H19' 0.3740 0.5663 0.3086 0.046 Uiso calc PR 0.340(10)
                                                         A 2 H
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Cu1 O1 . 1.9730(10)
                      yes
    Cu1 O1 3_666 1.9730(10)
                          no
    Cu1 N1 . 2.0280(10)
                      yes
    Cu1 N1 3_666 2.0280(10)
                          no
    Cu1 O3 . 2.2950(10)
                      yes
    Cu1 O3 3_666 2.2950(10)
                          no
    O1 C1 . 1.265(2) no
    O2 C1 . 1.242(2) no
    O3 C2 . 1.422(2) no
    O5 C20 . 1.402(2) no
    N1 C15 . 1.326(4) no
    N1 C19' . 1.341(9) no
    N1 C19 . 1.346(5) no
    N1 C15' . 1.368(8) no
    C1 C2 . 1.548(2) no
    C2 C14 . 1.525(2) no
    C2 C3 . 1.525(2) no
    C3 C4 . 1.379(2) no
    C3 C8 . 1.398(2) no
    C4 C5 . 1.392(2) no
    C5 C6 . 1.386(3) no
    C6 C7 . 1.371(3) no
    C7 C8 . 1.395(2) no
    C8 C9 . 1.462(2) no
    C9 C10 . 1.391(2) no
    C9 C14 . 1.400(2) no
    C10 C11 . 1.380(3) no
    C11 C12 . 1.385(3) no
    C12 C13 . 1.394(2) no
    C13 C14 . 1.375(2) no
    O4 C16 . 1.328(4) no
    C15 C16 . 1.384(5) no
    C16 C17 . 1.389(6) no
    C17 C18 . 1.373(6) no
    C18 C19 . 1.377(6) no
    O4' C16' . 1.340(6) no
    C15' C16' . 1.399(8) no
    C16' C17' . 1.392(9) no
    C17' C18' . 1.382(9) no
    C18' C19' . 1.386(9) no
    O3 H3o . 0.82 no
    O5 H5o . 0.82 no
    C4 H4 . 0.93 no
    C5 H5 . 0.93 no
    C6 H6 . 0.93 no
    C7 H7 . 0.93 no
    C10 H10 . 0.93 no
    C11 H11 . 0.93 no
    C12 H12 . 0.93 no
    C13 H13 . 0.93 no
    O4 H4o . 0.82 no
    C15 H15 . 0.93 no
    C17 H17 . 0.93 no
    C18 H18 . 0.93 no
    C19 H19 . 0.93 no
    C20 H20a . 0.96 no
    C20 H20b . 0.96 no
    C20 H20c . 0.96 no
    O4' H4'o . 0.82 no
    C15' H15' . 0.93 no
    C17' H17' . 0.93 no
    C18' H18' . 0.93 no
    C19' H19' . 0.93 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Cu1 O1 . 3_666 180 no
    O3 Cu1 O3 . 3_666 180 n
    N1 Cu1 N1 3_666 . 180 n
    O1 Cu1 O3 3_666 3_666 75.74(4) n
    O1 Cu1 O3 3_666 . 104.26(4) n
    O1 Cu1 N1 3_666 3_666 90.99(5) n
    O1 Cu1 N1 3_666 . 89.01(5) n
    O3 Cu1 N1 3_666 3_666 92.00(5) n
    O3 Cu1 N1 3_666 . 88.00(5) n
    O1 Cu1 O3 . . 75.74(4) yes
    O1 Cu1 O3 . 3_666 104.26(4) yes
    O1 Cu1 N1 . . 90.99(5) yes
    O1 Cu1 N1 . 3_666 89.01(5) yes
    O3 Cu1 N1 . . 92.00(5) yes
    O3 Cu1 N1 . 3_666 88.00(5) yes
    C1 O1 Cu1 . . 122.82(9) no
    C2 O3 Cu1 . . 112.37(8) no
    C15 N1 C19 . . 120.1(6) no
    C19' N1 C15' . . 117.0(10)
                            no
    C15 N1 Cu1 . . 120.6(3) no
    C19' N1 Cu1 . . 124.2(9) no
    C19 N1 Cu1 . . 119.1(5) no
    C15' N1 Cu1 . . 118.2(4) no
    O2 C1 O1 . . 123.50(10)
                          no
    O2 C1 C2 . . 117.70(10)
                          no
    O1 C1 C2 . . 118.80(10)
                          no
    O3 C2 C14 . . 112.20(10)
                           no
    O3 C2 C3 . . 113.60(10)
                          no
    C14 C2 C3 . . 101.60(10)
                           no
    O3 C2 C1 . . 108.20(10)
                          no
    C14 C2 C1 . . 112.00(10)
                           no
    C3 C2 C1 . . 109.10(10)
                          no
    C4 C3 C8 . . 120.9(2) no
    C4 C3 C2 . . 128.60(10)
                          no
    C8 C3 C2 . . 110.60(10)
                          no
    C3 C4 C5 . . 118.2(2) no
    C6 C5 C4 . . 121.1(2) no
    C7 C6 C5 . . 120.8(2) no
    C6 C7 C8 . . 118.9(2) no
    C7 C8 C3 . . 120.1(2) no
    C7 C8 C9 . . 131.3(2) no
    C3 C8 C9 . . 108.60(10)
                          no
    C10 C9 C14 . . 120.0(2) no
    C10 C9 C8 . . 131.1(2) no
    C14 C9 C8 . . 109.00(10)
                           no
    C11 C10 C9 . . 118.9(2) no
    C10 C11 C12 . . 121.0(2) no
    C11 C12 C13 . . 120.6(2) no
    C14 C13 C12 . . 118.6(2) no
    C13 C14 C9 . . 121.00(10)
                            no
    C13 C14 C2 . . 128.70(10)
                            no
    C9 C14 C2 . . 110.30(10)
                           no
    N1 C15 C16 . . 121.9(4) no
    O4 C16 C15 . . 121.3(4) no
    O4 C16 C17 . . 120.2(5) no
    C15 C16 C17 . . 118.5(5) no
    C18 C17 C16 . . 118.9(8) no
    C19 C18 C17 . . 120.0(10)
                           no
    N1 C19 C18 . . 121.0(10)
                          no
    N1 C15' C16' . . 123.8(8) no
    O4' C16' C17' . . 117.1(8) no
    O4' C16' C15' . . 125.9(6) no
    C17' C16' C15' . . 117.0(9) no
    C18' C17' C16' . . 120.0(10)
                              no
    C17' C18' C19' . . 120(2) no
    C2 O3 H3o . . 109.1 no
    Cu1 O3 H3o . . 109.1 no
    C20 O5 H5o . . 109.5 no
    C3 C4 H4 . . 120.9 no
    C5 C4 H4 . . 120.9 no
    C6 C5 H5 . . 119.5 no
    C4 C5 H5 . . 119.5 no
    C7 C6 H6 . . 119.6 no
    C5 C6 H6 . . 119.6 no
    C6 C7 H7 . . 120.6 no
    C8 C7 H7 . . 120.6 no
    C11 C10 H10 . . 120.6 no
    C9 C10 H10 . . 120.6 no
    C10 C11 H11 . . 119.5 no
    C12 C11 H11 . . 119.5 no
    C11 C12 H12 . . 119.7 no
    C13 C12 H12 . . 119.7 no
    C14 C13 H13 . . 120.7 no
    C12 C13 H13 . . 120.7 no
    C16 O4 H4o . . 120.0 no
    N1 C15 H15 . . 119.1 no
    C16 C15 H15 . . 119.1 no
    C18 C17 H17 . . 120.5 no
    C16 C17 H17 . . 120.5 no
    C19 C18 H18 . . 120.0 no
    C17 C18 H18 . . 120.0 no
    N1 C19 H19 . . 119.7 no
    C18 C19 H19 . . 119.7 no
    O5 C20 H20a . . 109.5 no
    O5 C20 H20b . . 109.5 no
    H20a C20 H20b . . 109.5 no
    O5 C20 H20C . . 109.5 no
    H20a C20 H20c . . 109.5 no
    H20b C20 H20c . . 109.5 no
    C16' O4' H4'o . . 120.0 no
    N1 C15' H15' . . 118.1 no
    C16' C15' H15' . . 118.1 no
    C18' C17' H17' . . 120.2 no
    C16' C17' H17' . . 120.2 no
    C17' C18' H18' . . 120.0 no
    C19' C18' H18' . . 120.0 no
    N1 C19' C18' . . 122.2(17) no
    N1 C19' H19' . . 118.9 no
    C18' C19' H19' . . 118.9 no
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    N1 Cu1 O1 C1 3_666 . . . 78.70(10)
                                     no
    N1 Cu1 O1 C1 . . . . -101.30(10)
                                   no
    O3 Cu1 O1 C1 3_666 . . . 170.50(10)
                                      no
    O3 Cu1 O1 C1 . . . . -9.50(10)
                                 no
    O1 Cu1 O3 C2 . . . .  0.00(10)
                                 no
    O1 Cu1 O3 C2 3_666 . . . 180.00(10)
                                      no
    N1 Cu1 O3 C2 3_666 . . . -89.50(10)
                                      no
    N1 Cu1 O3 C2 . . . . 90.50(10)
                                 no
    O1 Cu1 N1 C15 . . . . 127.4(2) no
    O1 Cu1 N1 C15 3_666 . . . -52.6(2) no
    O3 Cu1 N1 C15 3_666 . . . -128.4(2) no
    O3 Cu1 N1 C15 . . . . 51.6(2) no
    O1 Cu1 N1 C19' . . . . -36.2(5) no
    O1 Cu1 N1 C19' 3_666 . . . 143.8(5) no
    O3 Cu1 N1 C19' 3_666 . . . 68.0(5) no
    O3 Cu1 N1 C19' . . . . -112.0(5) no
    O1 Cu1 N1 C19 . . . . -48.1(3) no
    O1 Cu1 N1 C19 3_666 . . . 131.9(3) no
    O3 Cu1 N1 C19 3_666 . . . 56.1(3) no
    O3 Cu1 N1 C19 . . . . -123.9(3) no
    O1 Cu1 N1 C15' . . . . 148.0(3) no
    O1 Cu1 N1 C15' 3_666 . . . -32.0(3) no
    O3 Cu1 N1 C15' 3_666 . . . -107.7(3) no
    O3 Cu1 N1 C15' . . . . 72.3(3) no
    Cu1 O1 C1 O2 . . . . -166.30(10)
                                   no
    Cu1 O1 C1 C2 . . . . 17.1(2) no
    Cu1 O3 C2 C14 . . . . 130.90(10)
                                   no
    Cu1 O3 C2 C3 . . . . -114.60(10)
                                   no
    Cu1 O3 C2 C1 . . . . 6.80(10)
                                no
    O2 C1 C2 O3 . . . . 168.30(10)
                                 no
    O1 C1 C2 O3 . . . . -14.9(2) no
    O2 C1 C2 C14 . . . . 44.1(2) no
    O1 C1 C2 C14 . . . . -139.10(10)
                                   no
    O2 C1 C2 C3 . . . . -67.6(2) no
    O1 C1 C2 C3 . . . . 109.20(10)
                                 no
    O3 C2 C3 C4 . . . . 60.9(2) no
    C14 C2 C3 C4 . . . . -178.5(2) no
    C1 C2 C3 C4 . . . . -60.0(2) no
    O3 C2 C3 C8 . . . . -119.60(10)
                                  no
    C14 C2 C3 C8 . . . . 1.1(2) no
    C1 C2 C3 C8 . . . . 119.50(10)
                                 no
    C8 C3 C4 C5 . . . . 1.5(2) no
    C2 C3 C4 C5 . . . . -179.0(2) no
    C3 C4 C5 C6 . . . . 0.1(3) no
    C4 C5 C6 C7 . . . . -0.9(3) no
    C5 C6 C7 C8 . . . . 0.2(3) no
    C6 C7 C8 C3 . . . . 1.3(2) no
    C6 C7 C8 C9 . . . . -179.2(2) no
    C4 C3 C8 C7 . . . . -2.2(2) no
    C2 C3 C8 C7 . . . . 178.20(10)
                                 no
    C4 C3 C8 C9 . . . . 178.30(10)
                                 no
    C2 C3 C8 C9 . . . . -1.3(2) no
    C7 C8 C9 C10 . . . . 0.9(3) no
    C3 C8 C9 C10 . . . . -179.7(2) no
    C7 C8 C9 C14 . . . . -178.5(2) no
    C3 C8 C9 C14 . . . . 1.0(2) no
    C14 C9 C10 C11 . . . . 0.7(2) no
    C8 C9 C10 C11 . . . . -178.6(2) no
    C9 C10 C11 C12 . . . . 0.7(3) no
    C10 C11 C12 C13 . . . . -1.4(3) no
    C11 C12 C13 C14 . . . . 0.6(3) no
    C12 C13 C14 C9 . . . . 0.7(2) no
    C12 C13 C14 C2 . . . . 178.7(2) no
    C10 C9 C14 C13 . . . . -1.4(2) no
    C8 C9 C14 C13 . . . . 178.00(10)
                                   no
    C10 C9 C14 C2 . . . . -179.70(10)
                                    no
    C8 C9 C14 C2 . . . . -0.3(2) no
    O3 C2 C14 C13 . . . . -56.9(2) no
    C3 C2 C14 C13 . . . . -178.6(2) no
    C1 C2 C14 C13 . . . . 65.0(2) no
    O3 C2 C14 C9 . . . . 121.20(10)
                                  no
    C3 C2 C14 C9 . . . . -0.5(2) no
    C1 C2 C14 C9 . . . . -116.90(10)
                                   no
    C19' N1 C15 C16 . . . . -11.2(6) no
    C19 N1 C15 C16 . . . . -1.0(3) no
    C15' N1 C15 C16 . . . . 96(2) no
    Cu1 N1 C15 C16 . . . . -176.5(2) no
    N1 C15 C16 O4 . . . . 179.5(2) no
    N1 C15 C16 C17 . . . . 0.9(4) no
    O4 C16 C17 C18 . . . . -179.6(4) no
    C15 C16 C17 C18 . . . . -1.0(6) no
    C16 C17 C18 C19 . . . . 1.2(7) no
    C15 N1 C19 C18 . . . . 1.1(5) no
    C19' N1 C19 C18 . . . . 57(6) no
    C15' N1 C19 C18 . . . . -19.9(5) no
    Cu1 N1 C19 C18 . . . . 176.7(3) no
    C17 C18 C19 N1 . . . . -1.2(7) no
    C15 N1 C15' C16' . . . . -81(2) no
    C19' N1 C15' C16' . . . . 0.4(4) no
    C19 N1 C15' C16' . . . . 12.8(6) no
    Cu1 N1 C15' C16' . . . . 176.4(3) no
    N1 C15' C16' O4' . . . . -179.5(3) no
    N1 C15' C16' C17' . . . . -0.9(5) no
    O4' C16' C17' C18' . . . . 179.5(5) no
    C15' C16' C17' C18' . . . . 0.8(7) no
    C16' C17' C18' C19' . . . . -0.2(8) no
    C15 N1 C19' C18' . . . . 19.9(6) no
    C19 N1 C19' C18' . . . . -109(6) no
    C15' N1 C19' C18' . . . . 0.3(6) no
    Cu1 N1 C19' C18' . . . . -175.5(5) no
    C17' C18' C19' N1 . . . . -0.4(9) no
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    O3 H3o O5 . 0.82 2.02 2.677(2) 137 yes
    O5 H5o O2 1_545 0.82 1.96 2.773(2) 170 yes
    O4 H4o O2 1_545 0.82 1.91 2.702(4) 162 yes
    O4' H4'o O1 1_545 0.82 2.04 2.838(6) 166 yes
data_global
_journal_data_validation_number     ?
_journal_date_recd_electronic     2005-09-28
_journal_date_accepted     2005-09-30
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2005
_journal_volume     61
_journal_issue     11
_journal_page_first     m2192
_journal_page_last     m2193
_journal_paper_category     EM
_journal_coeditor_code     HB6278
_publ_contact_author_name     'Dr Seik Weng Ng'
_publ_contact_author_address
;
 Department of Chemistry
 University of Malaya
 50603 Kuala Lumpur
 Malaysia
;
_publ_contact_author_email     seikweng@um.edu.my
_publ_contact_author_fax     '603 7967 6778'
_publ_contact_author_phone     '603 7967 4193'
_publ_section_title
;\
Bis(9-hydroxyfluorene-9-carboxylato-κ²O,O')bis(3-\
hydroxypyridine- κN)copper(II) methanol disolvate
;
loop_
    _publ_author_name
    _publ_author_address
    'Gao, Shan'
;
 College of Chemistry and Materials Science
 Heilongjiang University
 Harbin 150080
 People's Republic of China
;
    'Huo, Li-Hua'
;
 College of Chemistry and Materials Science
 Heilongjiang University
 Harbin 150080
 People's Republic of China
;
    'Ng, Seik Weng'
;
 Department of Chemistry
 University of Malaya
 Kuala Lumpur 50603
 Malaysia
;
