##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
catena-Poly[tris(μ₂-oxalato-κ⁴O,O':O''O''')bis(μ₂-4,4'-bipyridyl-
κ²N,N')bis(4,4'-bipyridyl-\kN)trimanganese(II)]
;
_chemical_name_common     ?
_chemical_formula_moiety     'C46 H32 Mn3 N8 O12'
_chemical_formula_sum     'C46 H32 Mn3 N8 O12'
_chemical_formula_iupac     '[Mn3 (C2 O4)3 (C10 H8 N2)4]'
_chemical_formula_weight     1053.62
_chemical_melting_point     ?
_symmetry_cell_setting     Monoclinic
_symmetry_space_group_name_H-M     'P 21/c'
_symmetry_space_group_name_Hall     '-P 2ybc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     16.289(2)
_cell_length_b     16.220(2)
_cell_length_c     16.452(2)
_cell_angle_alpha     90.00
_cell_angle_beta     94.981(2)
_cell_angle_gamma     90.00
_cell_volume     4330.1(9)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     976
_cell_measurement_theta_min     3.0
_cell_measurement_theta_max     26.7
_cell_measurement_temperature     295(2)
_exptl_crystal_description     block
_exptl_crystal_colour     'pale yellow'
_exptl_crystal_size_max     0.32
_exptl_crystal_size_mid     0.16
_exptl_crystal_size_min     0.12
_exptl_crystal_density_diffrn     1.616
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     2140
_exptl_absorpt_coefficient_mu     0.938
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2002)'
_exptl_absorpt_correction_T_min     0.766
_exptl_absorpt_correction_T_max     0.896
_diffrn_ambient_temperature     295(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     35776
_diffrn_reflns_av_R_equivalents     0.022
_diffrn_reflns_av_sigmaI/netI     0.022
_diffrn_reflns_theta_min     1.3
_diffrn_reflns_theta_max     27.0
_diffrn_reflns_theta_full     27.0
_diffrn_measured_fraction_theta_max     0.99
_diffrn_measured_fraction_theta_full     0.99
_diffrn_reflns_limit_h_min     -20
_diffrn_reflns_limit_h_max     20
_diffrn_reflns_limit_k_min     -20
_diffrn_reflns_limit_k_max     20
_diffrn_reflns_limit_l_min     -21
_diffrn_reflns_limit_l_max     20
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_reflns_number_total     9421
_reflns_number_gt     7912
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.039
_refine_ls_R_factor_gt     0.031
_refine_ls_wR_factor_gt     0.087
_refine_ls_wR_factor_ref     0.094
_refine_ls_goodness_of_fit_ref     1.01
_refine_ls_restrained_S_all     1.01
_refine_ls_number_reflns     9421
_refine_ls_number_parameters     622
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.0565P)²+0.9427P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.38
_refine_diff_density_min     -0.29
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Mn' 'Mn' 0.3368 0.7283
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 2002)'
_computing_cell_refinement     'SAINT (Bruker, 2002)'
_computing_data_reduction     SAINT
_computing_structure_solution
            'Atomic coordinates taken from the Fe analogue (Zheng et al., 1999)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEPII (Johnson, 1976)'
_computing_publication_material     SHELXL97
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Mn1 0.78469(2) 0.224340(10)
                              0.46029(2) 0.02469(7) Uani d . 1 . . Mn
    Mn2 0.743990(10)
                   0.557380(10)
                              0.508430(10)
                                         0.02472(7) Uani d . 1 . . Mn
    Mn3 0.726290(10)
                   0.893670(10)
                              0.525120(10)
                                         0.02543(7) Uani d . 1 . . Mn
    O1 0.72260(10)
                 0.32800(10)
                           0.40200(10)
                                     0.0284(2) Uani d . 1 . . O
    O2 0.70180(10)
                 0.46120(10)
                           0.42500(10)
                                     0.0282(2) Uani d . 1 . . O
    O3 0.84660(10)
                 0.32540(10)
                           0.52280(10)
                                     0.0287(2) Uani d . 1 . . O
    O4 0.82970(10)
                 0.45950(10)
                           0.54390(10)
                                     0.0295(2) Uani d . 1 . . O
    O5 0.65860(10)
                 0.65500(10)
                           0.47080(10)
                                     0.0281(2) Uani d . 1 . . O
    O6 0.65610(10)
                 0.79210(10)
                           0.47440(10)
                                     0.0284(2) Uani d . 1 . . O
    O7 0.78680(10)
                 0.65540(10)
                           0.58980(10)
                                     0.0268(2) Uani d . 1 . . O
    O8 0.77820(10)
                 0.79210(10)
                           0.59700(10)
                                     0.0285(2) Uani d . 1 . . O
    O9 0.68520(10)
                 0.99110(10)
                           0.44150(10)
                                     0.0317(3) Uani d . 1 . . O
    O10 0.71150(10)
                  1.12160(10)
                            0.41220(10)
                                      0.0300(3) Uani d . 1 . . O
    O11 0.80260(10)
                  0.99630(10)
                            0.56910(10)
                                      0.0307(3) Uani d . 1 . . O
    O12 0.83450(10)
                  1.12380(10)
                            0.53440(10)
                                      0.0319(3) Uani d . 1 . . O
    N1 0.68730(10)
                 0.23300(10)
                           0.55920(10)
                                     0.0345(3) Uani d . 1 . . N
    N2 0.39160(10)
                 0.21530(10)
                           0.85130(10)
                                     0.0378(3) Uani d . 1 . . N
    N3 0.87800(10)
                 0.19870(10)
                           0.36730(10)
                                     0.0320(3) Uani d . 1 . . N
    N4 1.17030(10)
                 0.11370(10)
                           0.08310(10)
                                     0.0304(3) Uani d . 1 . . N
    N5 0.65790(10)
                 0.50610(10)
                           0.60050(10)
                                     0.0324(3) Uani d . 1 . . N
    N6 0.36800(10)
                 0.43230(10)
                           0.88860(10)
                                     0.0324(3) Uani d . 1 . . N
    N7 0.82650(10)
                 0.87210(10)
                           0.43440(10)
                                     0.0361(3) Uani d . 1 . . N
    N8 1.11390(10)
                 0.92400(10)
                           0.13930(10)
                                     0.0404(4) Uani d . 1 . . N
    C1 0.60650(10)
                 0.22680(10)
                           0.53740(10)
                                     0.0406(4) Uani d . 1 . . C
    C2 0.54680(10)
                 0.22440(10)
                           0.59210(10)
                                     0.0409(5) Uani d . 1 . . C
    C3 0.57060(10)
                 0.22730(10)
                           0.67510(10)
                                     0.0318(4) Uani d . 1 . . C
    C4 0.65410(10)
                 0.23380(10)
                           0.69810(10)
                                     0.0463(5) Uani d . 1 . . C
    C5 0.70930(10)
                 0.23680(10)
                           0.63860(10)
                                     0.0463(5) Uani d . 1 . . C
    C6 0.50860(10)
                 0.22340(10)
                           0.73620(10)
                                     0.0310(4) Uani d . 1 . . C
    C7 0.52850(10)
                 0.19030(10)
                           0.81340(10)
                                     0.0366(4) Uani d . 1 . . C
    C8 0.46790(10)
                 0.18760(10)
                           0.86780(10)
                                     0.0387(4) Uani d . 1 . . C
    C9 0.37350(10)
                 0.24700(10)
                           0.77730(10)
                                     0.0381(4) Uani d . 1 . . C
    C10 0.42870(10)
                  0.25210(10)
                            0.71810(10)
                                      0.0354(4) Uani d . 1 . . C
    C11 0.85710(10)
                  0.16180(10)
                            0.29560(10)
                                      0.0370(4) Uani d . 1 . . C
    C12 0.91260(10)
                  0.14560(10)
                            0.23870(10)
                                      0.0363(4) Uani d . 1 . . C
    C13 0.99490(10)
                  0.16660(10)
                            0.25620(10)
                                      0.0297(3) Uani d . 1 . . C
    C14 1.01730(10)
                  0.20330(10)
                            0.33110(10)
                                      0.0354(4) Uani d . 1 . . C
    C15 0.95720(10)
                  0.21870(10)
                            0.38340(10)
                                      0.0356(4) Uani d . 1 . . C
    C16 1.05680(10)
                  0.15030(10)
                            0.19650(10)
                                      0.0297(3) Uani d . 1 . . C
    C17 1.03560(10)
                  0.15630(10)
                            0.11310(10)
                                      0.0356(4) Uani d . 1 . . C
    C18 1.09400(10)
                  0.13880(10)
                            0.05970(10)
                                      0.0355(4) Uani d . 1 . . C
    C19 1.19070(10)
                  0.10990(10)
                            0.16320(10)
                                      0.0392(4) Uani d . 1 . . C
    C20 1.13700(10)
                  0.12780(10)
                            0.22140(10)
                                      0.0391(4) Uani d . 1 . . C
    C21 0.58350(10)
                  0.47510(10)
                            0.57800(10)
                                      0.0381(4) Uani d . 1 . . C
    C22 0.52490(10)
                  0.45880(10)
                            0.63180(10)
                                      0.0386(4) Uani d . 1 . . C
    C23 0.54390(10)
                  0.47390(10)
                            0.71420(10)
                                      0.0315(4) Uani d . 1 . . C
    C24 0.62220(10)
                  0.50280(10)
                            0.73870(10)
                                      0.0388(4) Uani d . 1 . . C
    C25 0.67610(10)
                  0.51860(10)
                            0.68020(10)
                                      0.0410(4) Uani d . 1 . . C
    C26 0.48290(10)
                  0.46010(10)
                            0.77480(10)
                                      0.0312(4) Uani d . 1 . . C
    C27 0.50640(10)
                  0.42550(10)
                            0.85050(10)
                                      0.0376(4) Uani d . 1 . . C
    C28 0.44740(10)
                  0.41220(10)
                            0.90430(10)
                                      0.0386(4) Uani d . 1 . . C
    C29 0.34620(10)
                  0.46760(10)
                            0.81660(10)
                                      0.0348(4) Uani d . 1 . . C
    C30 0.40050(10)
                  0.48220(10)
                            0.75820(10)
                                      0.0362(4) Uani d . 1 . . C
    C31 0.80570(10)
                  0.85680(10)
                            0.35560(10)
                                      0.0396(4) Uani d . 1 . . C
    C32 0.85920(10)
                  0.86520(10)
                            0.29560(10)
                                      0.0362(4) Uani d . 1 . . C
    C33 0.93960(10)
                  0.89050(10)
                            0.31680(10)
                                      0.0320(4) Uani d . 1 . . C
    C34 0.96240(10)
                  0.90380(10)
                            0.39940(10)
                                      0.0417(5) Uani d . 1 . . C
    C35 0.90440(10)
                  0.89380(10)
                            0.45490(10)
                                      0.0424(5) Uani d . 1 . . C
    C36 0.99950(10)
                  0.90260(10)
                            0.25510(10)
                                      0.0314(4) Uani d . 1 . . C
    C37 1.08270(10)
                  0.88650(10)
                            0.27380(10)
                                      0.0390(4) Uani d . 1 . . C
    C38 1.13630(10)
                  0.89750(10)
                            0.21420(10)
                                      0.0426(4) Uani d . 1 . . C
    C39 1.03450(10)
                  0.94050(10)
                            0.12220(10)
                                      0.0396(4) Uani d . 1 . . C
    C40 0.97500(10)
                  0.93090(10)
                            0.17710(10)
                                      0.0366(4) Uani d . 1 . . C
    C41 0.73960(10)
                  0.39450(10)
                            0.43850(10)
                                      0.0221(3) Uani d . 1 . . C
    C42 0.81210(10)
                  0.39350(10)
                            0.50750(10)
                                      0.0228(3) Uani d . 1 . . C
    C43 0.68340(10)
                  0.72320(10)
                            0.49870(10)
                                      0.0224(3) Uani d . 1 . . C
    C44 0.75550(10)
                  0.72350(10)
                            0.56820(10)
                                      0.0220(3) Uani d . 1 . . C
    C45 0.72350(10)
                  1.05690(10)
                            0.45330(10)
                                      0.0250(3) Uani d . 1 . . C
    C46 0.79300(10)
                  1.05920(10)
                            0.52580(10)
                                      0.0248(3) Uani d . 1 . . C
    H1 0.5895 0.2238 0.4820 0.049 Uiso calc R 1 . . H
    H2 0.4914 0.2208 0.5736 0.049 Uiso calc R 1 . . H
    H4 0.6731 0.2362 0.7530 0.056 Uiso calc R 1 . . H
    H5 0.7651 0.2416 0.6554 0.056 Uiso calc R 1 . . H
    H7 0.5812 0.1705 0.8283 0.044 Uiso calc R 1 . . H
    H8 0.4817 0.1648 0.9190 0.046 Uiso calc R 1 . . H
    H9 0.3204 0.2668 0.7644 0.046 Uiso calc R 1 . . H
    H10 0.4126 0.2744 0.6672 0.043 Uiso calc R 1 . . H
    H11 0.8025 0.1462 0.2835 0.044 Uiso calc R 1 . . H
    H12 0.8950 0.1209 0.1892 0.044 Uiso calc R 1 . . H
    H14 1.0719 0.2174 0.3458 0.042 Uiso calc R 1 . . H
    H15 0.9729 0.2444 0.4328 0.043 Uiso calc R 1 . . H
    H17 0.9826 0.1719 0.0935 0.043 Uiso calc R 1 . . H
    H18 1.0793 0.1449 0.0041 0.043 Uiso calc R 1 . . H
    H19 1.2442 0.0944 0.1810 0.047 Uiso calc R 1 . . H
    H20 1.1545 0.1246 0.2766 0.047 Uiso calc R 1 . . H
    H21 0.5703 0.4639 0.5230 0.046 Uiso calc R 1 . . H
    H22 0.4735 0.4380 0.6129 0.046 Uiso calc R 1 . . H
    H24 0.6382 0.5114 0.7937 0.047 Uiso calc R 1 . . H
    H25 0.7281 0.5391 0.6974 0.049 Uiso calc R 1 . . H
    H27 0.5612 0.4116 0.8647 0.045 Uiso calc R 1 . . H
    H28 0.4637 0.3877 0.9542 0.046 Uiso calc R 1 . . H
    H29 0.2915 0.4833 0.8052 0.042 Uiso calc R 1 . . H
    H30 0.3823 0.5063 0.7086 0.043 Uiso calc R 1 . . H
    H31 0.7521 0.8395 0.3403 0.047 Uiso calc R 1 . . H
    H32 0.8416 0.8540 0.2415 0.043 Uiso calc R 1 . . H
    H34 1.0160 0.9192 0.4169 0.050 Uiso calc R 1 . . H
    H36 0.9206 0.9028 0.5098 0.051 Uiso calc R 1 . . H
    H37 1.1020 0.8686 0.3257 0.047 Uiso calc R 1 . . H
    H38 1.1917 0.8855 0.2274 0.051 Uiso calc R 1 . . H
    H39 1.0175 0.9596 0.0701 0.048 Uiso calc R 1 . . H
    H40 0.9201 0.9432 0.1619 0.044 Uiso calc R 1 . . H
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Mn1 O1 . 2.1440(10)
                      yes
    Mn1 O3 . 2.1390(10)
                      yes
    Mn1 O10 1_545 2.1600(10)
                           yes
    Mn1 O12 1_545 2.1510(10)
                           yes
    Mn1 N1 . 2.3740(10)
                      yes
    Mn1 N3 . 2.2860(10)
                      yes
    Mn2 O2 . 2.1510(10)
                      yes
    Mn2 O4 . 2.1600(10)
                      yes
    Mn2 O5 . 2.1620(10)
                      yes
    Mn2 O7 . 2.1550(10)
                      yes
    Mn2 N4 2_755 2.3280(10)
                          yes
    Mn2 N5 . 2.3070(10)
                      yes
    Mn3 O6 . 2.1330(10)
                      yes
    Mn3 O8 . 2.1570(10)
                      yes
    Mn3 O9 . 2.1630(10)
                      yes
    Mn3 O11 . 2.1650(10)
                       yes
    Mn3 N6 2_656 2.2680(10)
                          yes
    Mn3 N7 . 2.3320(10)
                      yes
    O1 C41 . 1.254(2) no
    O2 C41 . 1.254(2) no
    O3 C42 . 1.254(2) no
    O4 C42 . 1.249(2) no
    O5 C43 . 1.251(2) no
    O6 C43 . 1.255(2) no
    O7 C44 . 1.255(2) no
    O8 C44 . 1.253(2) no
    O9 C45 . 1.243(2) no
    O10 C45 . 1.255(2) no
    O11 C46 . 1.246(2) no
    O12 C46 . 1.249(2) no
    N1 C5 . 1.326(2) no
    N1 C1 . 1.337(2) no
    N2 C8 . 1.328(2) no
    N2 C9 . 1.331(2) no
    N3 C15 . 1.335(2) no
    N3 C11 . 1.340(2) no
    N4 C18 . 1.332(2) no
    N4 C19 . 1.332(2) no
    N5 C25 . 1.335(2) no
    N5 C21 . 1.334(2) no
    N6 C29 . 1.335(2) no
    N6 C28 . 1.337(2) no
    N7 C35 . 1.332(2) no
    N7 C31 . 1.333(2) no
    N8 C39 . 1.328(2) no
    N8 C38 . 1.326(2) no
    C1 C2 . 1.382(2) no
    C2 C3 . 1.387(2) no
    C3 C4 . 1.384(2) no
    C3 C6 . 1.488(2) no
    C4 C5 . 1.385(3) no
    C6 C10 . 1.391(2) no
    C6 C7 . 1.390(2) no
    C7 C8 . 1.388(2) no
    C9 C10 . 1.383(2) no
    C11 C12 . 1.380(2) no
    C12 C13 . 1.389(2) no
    C13 C14 . 1.388(2) no
    C13 C16 . 1.491(2) no
    C14 C15 . 1.380(2) no
    C16 C20 . 1.384(2) no
    C16 C17 . 1.389(2) no
    C17 C18 . 1.381(2) no
    C19 C20 . 1.382(2) no
    C21 C22 . 1.382(2) no
    C22 C23 . 1.387(2) no
    C23 C24 . 1.385(2) no
    C23 C26 . 1.484(2) no
    C24 C25 . 1.382(2) no
    C26 C27 . 1.390(2) no
    C26 C30 . 1.393(2) no
    C27 C28 . 1.379(2) no
    C29 C30 . 1.381(2) no
    C31 C32 . 1.379(2) no
    C32 C33 . 1.388(2) no
    C33 C34 . 1.394(2) no
    C33 C36 . 1.482(2) no
    C34 C35 . 1.378(2) no
    C36 C37 . 1.388(2) no
    C36 C40 . 1.388(2) no
    C37 C38 . 1.379(2) no
    C39 C40 . 1.389(2) no
    C41 C42 . 1.566(2) no
    C43 C44 . 1.566(2) no
    C45 C46 . 1.572(2) no
    C1 H1 . 0.93 no
    C2 H2 . 0.93 no
    C4 H4 . 0.93 no
    C5 H5 . 0.93 no
    C7 H7 . 0.93 no
    C8 H8 . 0.93 no
    C9 H9 . 0.93 no
    C10 H10 . 0.93 no
    C11 H11 . 0.93 no
    C12 H12 . 0.93 no
    C14 H14 . 0.93 no
    C15 H15 . 0.93 no
    C17 H17 . 0.93 no
    C18 H18 . 0.93 no
    C19 H19 . 0.93 no
    C20 H20 . 0.93 no
    C21 H21 . 0.93 no
    C22 H22 . 0.93 no
    C24 H24 . 0.93 no
    C25 H25 . 0.93 no
    C27 H27 . 0.93 no
    C28 H28 . 0.93 no
    C29 H29 . 0.93 no
    C30 H30 . 0.93 no
    C31 H31 . 0.93 no
    C32 H32 . 0.93 no
    C34 H34 . 0.93 no
    C35 H36 . 0.93 no
    C37 H37 . 0.93 no
    C38 H38 . 0.93 no
    C39 H39 . 0.93 no
    C40 H40 . 0.93 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Mn1 O3 . . 78.38(4) yes
    O1 Mn1 O10 . 1_545 102.53(4) yes
    O1 Mn1 O12 . 1_545 170.80(5) yes
    O1 Mn1 N1 . . 86.73(5) yes
    O1 Mn1 N3 . . 99.08(5) yes
    O3 Mn1 O10 . 1_545 171.66(4) yes
    O3 Mn1 O12 . 1_545 99.76(4) yes
    O3 Mn1 N1 . . 86.58(5) yes
    O3 Mn1 N3 . . 98.51(5) yes
    O10 Mn1 O12 1_545 1_545 78.00(4) yes
    O10 Mn1 N1 1_545 . 85.20(5) yes
    O10 Mn1 N3 1_545 . 89.57(5) yes
    O12 Mn1 N1 1_545 . 84.16(5) yes
    O12 Mn1 N3 1_545 . 90.10(5) yes
    N1 Mn1 N3 . . 172.92(5) yes
    O2 Mn2 O4 . . 78.60(4) yes
    O2 Mn2 O5 . . 100.77(4) yes
    O2 Mn2 O7 . . 178.76(4) yes
    O2 Mn2 N4 . 2_755 92.75(5) yes
    O2 Mn2 N5 . . 88.78(5) yes
    O4 Mn2 O5 . . 179.04(4) yes
    O4 Mn2 O7 . . 101.97(4) yes
    O4 Mn2 N4 . 2_755 93.06(5) yes
    O4 Mn2 N5 . . 88.43(5) yes
    O5 Mn2 O7 . . 78.65(4) yes
    O5 Mn2 N4 . 2_755 86.25(5) yes
    O5 Mn2 N5 . . 92.28(5) yes
    O7 Mn2 N4 . 2_755 86.12(5) yes
    O7 Mn2 N5 . . 92.34(5) yes
    N4 Mn2 N5 2_755 . 178.05(5) yes
    O6 Mn3 O8 . . 78.22(4) yes
    O6 Mn3 O9 . . 100.94(4) yes
    O6 Mn3 O11 . . 175.91(5) yes
    O6 Mn3 N6 . 2_656 95.13(5) yes
    O6 Mn3 N7 . . 90.83(5) yes
    O8 Mn3 O9 . . 172.57(5) yes
    O8 Mn3 O11 . . 102.57(4) yes
    O8 Mn3 N6 . 2_656 97.03(5) yes
    O8 Mn3 N7 . . 88.49(5) yes
    O9 Mn3 O11 . . 77.76(4) yes
    O9 Mn3 N6 . 2_656 90.39(5) yes
    O9 Mn3 N7 . . 84.13(5) yes
    O11 Mn3 N6 . 2_656 88.77(5) yes
    O11 Mn3 N7 . . 85.18(5) yes
    N6 Mn3 N7 2_656 . 172.58(5) yes
    C41 O1 Mn1 . . 112.60(10)
                            no
    C41 O2 Mn2 . . 112.90(10)
                            no
    C42 O3 Mn1 . . 113.20(10)
                            no
    C42 O4 Mn2 . . 112.70(10)
                            no
    C43 O5 Mn2 . . 111.30(10)
                            no
    C43 O6 Mn3 . . 113.60(10)
                            no
    C44 O7 Mn2 . . 111.80(10)
                            no
    C44 O8 Mn3 . . 112.50(10)
                            no
    C45 O9 Mn3 . . 113.90(10)
                            no
    C45 O10 Mn1 . 1_565 113.10(10)
                                 no
    C46 O11 Mn3 . . 113.50(10)
                             no
    C46 O12 Mn1 . 1_565 113.50(10)
                                 no
    C5 N1 C1 . . 116.3(2) no
    C5 N1 Mn1 . . 122.60(10)
                           no
    C1 N1 Mn1 . . 120.80(10)
                           no
    C8 N2 C9 . . 116.50(10)
                          no
    C15 N3 C11 . . 116.70(10)
                            no
    C15 N3 Mn1 . . 120.70(10)
                            no
    C11 N3 Mn1 . . 122.60(10)
                            no
    C18 N4 C19 . . 116.60(10)
                            no
    C18 N4 Mn2 . 2_745 121.90(10)
                                no
    C19 N4 Mn2 . 2_745 120.60(10)
                                no
    C25 N5 C21 . . 116.70(10)
                            no
    C25 N5 Mn2 . . 119.70(10)
                            no
    C21 N5 Mn2 . . 122.90(10)
                            no
    C29 N6 C28 . . 117.00(10)
                            no
    C29 N6 Mn3 . 2_646 122.10(10)
                                no
    C28 N6 Mn3 . 2_646 120.50(10)
                                no
    C35 N7 C31 . . 116.9(2) no
    C35 N7 Mn3 . . 120.10(10)
                            no
    C31 N7 Mn3 . . 121.10(10)
                            no
    C39 N8 C38 . . 116.5(2) no
    N1 C1 C2 . . 123.9(2) no
    C1 C2 C3 . . 119.2(2) no
    C4 C3 C2 . . 117.2(2) no
    C4 C3 C6 . . 121.8(2) no
    C2 C3 C6 . . 121.1(2) no
    C3 C4 C5 . . 119.4(2) no
    N1 C5 C4 . . 123.9(2) no
    C10 C6 C7 . . 117.6(2) no
    C10 C6 C3 . . 121.2(2) no
    C7 C6 C3 . . 121.1(2) no
    C8 C7 C6 . . 118.6(2) no
    N2 C8 C7 . . 124.2(2) no
    N2 C9 C10 . . 124.1(2) no
    C9 C10 C6 . . 118.9(2) no
    N3 C11 C12 . . 123.4(2) no
    C11 C12 C13 . . 119.3(2) no
    C14 C13 C12 . . 117.6(2) no
    C14 C13 C16 . . 121.3(2) no
    C12 C13 C16 . . 121.1(2) no
    C15 C14 C13 . . 119.0(2) no
    N3 C15 C14 . . 123.9(2) no
    C20 C16 C17 . . 117.2(2) no
    C20 C16 C13 . . 121.8(2) no
    C17 C16 C13 . . 120.9(2) no
    C18 C17 C16 . . 119.3(2) no
    N4 C18 C17 . . 123.7(2) no
    N4 C19 C20 . . 123.8(2) no
    C19 C20 C16 . . 119.3(2) no
    N5 C21 C22 . . 123.8(2) no
    C21 C22 C23 . . 118.9(2) no
    C22 C23 C24 . . 117.8(2) no
    C22 C23 C26 . . 121.6(2) no
    C24 C23 C26 . . 120.6(2) no
    C25 C24 C23 . . 119.0(2) no
    N5 C25 C24 . . 123.8(2) no
    C27 C26 C30 . . 117.7(2) no
    C27 C26 C23 . . 120.9(2) no
    C30 C26 C23 . . 121.4(2) no
    C28 C27 C26 . . 119.0(2) no
    N6 C28 C27 . . 123.7(2) no
    N6 C29 C30 . . 123.6(2) no
    C29 C30 C26 . . 119.0(2) no
    N7 C31 C32 . . 123.6(2) no
    C31 C32 C33 . . 119.4(2) no
    C32 C33 C34 . . 117.1(2) no
    C32 C33 C36 . . 122.0(2) no
    C34 C33 C36 . . 120.8(2) no
    C35 C34 C33 . . 119.2(2) no
    C37 C36 C40 . . 117.7(2) no
    C37 C36 C33 . . 120.8(2) no
    C40 C36 C33 . . 121.6(2) no
    N7 C35 C34 . . 123.7(2) no
    C38 C37 C36 . . 118.9(2) no
    N8 C38 C37 . . 124.3(2) no
    N8 C39 C40 . . 124.2(2) no
    C39 C40 C36 . . 118.5(2) no
    O2 C41 O1 . . 125.00(10)
                           no
    O2 C41 C42 . . 117.70(10)
                            no
    O1 C41 C42 . . 117.30(10)
                            no
    O4 C42 O3 . . 125.40(10)
                           no
    O4 C42 C41 . . 117.80(10)
                            no
    O3 C42 C41 . . 116.80(10)
                            no
    O5 C43 O6 . . 125.20(10)
                           no
    O5 C43 C44 . . 117.90(10)
                            no
    O6 C43 C44 . . 116.90(10)
                            no
    O8 C44 O7 . . 125.10(10)
                           no
    O8 C44 C43 . . 117.20(10)
                            no
    O7 C44 C43 . . 117.70(10)
                            no
    O9 C45 O10 . . 125.50(10)
                            no
    O9 C45 C46 . . 117.20(10)
                            no
    O10 C45 C46 . . 117.20(10)
                             no
    O11 C46 O12 . . 125.70(10)
                             no
    O11 C46 C45 . . 117.50(10)
                             no
    O12 C46 C45 . . 116.90(10)
                             no
    N1 C1 H1 . . 118.0 no
    C2 C1 H1 . . 118.0 no
    C1 C2 H2 . . 120.4 no
    C3 C2 H2 . . 120.4 no
    C3 C4 H4 . . 120.3 no
    C5 C4 H4 . . 120.3 no
    N1 C5 H5 . . 118.0 no
    C4 C5 H5 . . 118.0 no
    C8 C7 H7 . . 120.7 no
    C6 C7 H7 . . 120.7 no
    N2 C8 H8 . . 117.9 no
    C7 C8 H8 . . 117.9 no
    N2 C9 H9 . . 117.9 no
    C10 C9 H9 . . 117.9 no
    C9 C10 H10 . . 120.6 no
    C6 C10 H10 . . 120.6 no
    N3 C11 H11 . . 118.3 no
    C12 C11 H11 . . 118.3 no
    C11 C12 H12 . . 120.4 no
    C13 C12 H12 . . 120.4 no
    C15 C14 H14 . . 120.5 no
    C13 C14 H14 . . 120.5 no
    N3 C15 H15 . . 118.0 no
    C14 C15 H15 . . 118.0 no
    C18 C17 H17 . . 120.4 no
    C16 C17 H17 . . 120.4 no
    N4 C18 H18 . . 118.1 no
    C17 C18 H18 . . 118.1 no
    N4 C19 H19 . . 118.1 no
    C20 C19 H19 . . 118.1 no
    C19 C20 H20 . . 120.4 no
    C16 C20 H20 . . 120.4 no
    N5 C21 H21 . . 118.1 no
    C22 C21 H21 . . 118.1 no
    C21 C22 H22 . . 120.5 no
    C23 C22 H22 . . 120.5 no
    C25 C24 H24 . . 120.5 no
    C23 C24 H24 . . 120.5 no
    N5 C25 H25 . . 118.1 no
    C24 C25 H25 . . 118.1 no
    C28 C27 H27 . . 120.5 no
    C26 C27 H27 . . 120.5 no
    N6 C28 H28 . . 118.1 no
    C27 C28 H28 . . 118.1 no
    N6 C29 H29 . . 118.2 no
    C30 C29 H29 . . 118.2 no
    C29 C30 H30 . . 120.5 no
    C26 C30 H30 . . 120.5 no
    N7 C31 H31 . . 118.2 no
    C32 C31 H31 . . 118.2 no
    C31 C32 H32 . . 120.3 no
    C33 C32 H32 . . 120.3 no
    C35 C34 H34 . . 120.4 no
    C33 C34 H34 . . 120.4 no
    N7 C35 H36 . . 118.1 no
    C34 C35 H36 . . 118.1 no
    C38 C37 H37 . . 120.6 no
    C36 C37 H37 . . 120.6 no
    N8 C38 H38 . . 117.9 no
    C37 C38 H38 . . 117.9 no
    N8 C39 H39 . . 117.9 no
    C40 C39 H39 . . 117.9 no
    C39 C40 H40 . . 120.7 no
    C36 C40 H40 . . 120.7 no
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O3 Mn1 O1 C41 . . . . -11.30(10)
                                   no
    O10 Mn1 O1 C41 1_545 . . . 160.20(10)
                                        no
    N3 Mn1 O1 C41 . . . . -108.20(10)
                                    no
    N1 Mn1 O1 C41 . . . . 75.90(10)
                                  no
    O4 Mn2 O2 C41 . . . . 5.10(10)
                                 no
    O5 Mn2 O2 C41 . . . . -175.70(10)
                                    no
    N5 Mn2 O2 C41 . . . . -83.60(10)
                                   no
    N4 Mn2 O2 C41 2_755 . . . 97.60(10)
                                      no
    O1 Mn1 O3 C42 . . . . 10.30(10)
                                  no
    O12 Mn1 O3 C42 1_545 . . . -160.50(10)
                                         no
    N3 Mn1 O3 C42 . . . . 107.90(10)
                                   no
    N1 Mn1 O3 C42 . . . . -77.10(10)
                                   no
    O2 Mn2 O4 C42 . . . . -6.00(10)
                                  no
    O7 Mn2 O4 C42 . . . . 175.10(10)
                                   no
    N5 Mn2 O4 C42 . . . . 83.10(10)
                                  no
    N4 Mn2 O4 C42 2_755 . . . -98.20(10)
                                       no
    O2 Mn2 O5 C43 . . . . -164.60(10)
                                    no
    O7 Mn2 O5 C43 . . . . 14.30(10)
                                  no
    N5 Mn2 O5 C43 . . . . 106.20(10)
                                   no
    N4 Mn2 O5 C43 2_755 . . . -72.50(10)
                                       no
    O8 Mn3 O6 C43 . . . . -9.90(10)
                                  no
    O9 Mn3 O6 C43 . . . . 162.60(10)
                                   no
    N6 Mn3 O6 C43 2_656 . . . -106.00(10)
                                        no
    N7 Mn3 O6 C43 . . . . 78.40(10)
                                  no
    O4 Mn2 O7 C44 . . . . 166.50(10)
                                   no
    O5 Mn2 O7 C44 . . . . -12.70(10)
                                   no
    N5 Mn2 O7 C44 . . . . -104.60(10)
                                    no
    N4 Mn2 O7 C44 2_755 . . . 74.20(10)
                                      no
    O6 Mn3 O8 C44 . . . . 11.60(10)
                                  no
    O11 Mn3 O8 C44 . . . . -164.30(10)
                                     no
    N6 Mn3 O8 C44 2_656 . . . 105.40(10)
                                       no
    N7 Mn3 O8 C44 . . . . -79.60(10)
                                   no
    O6 Mn3 O9 C45 . . . . -173.40(10)
                                    no
    O11 Mn3 O9 C45 . . . . 2.70(10)
                                  no
    N6 Mn3 O9 C45 2_656 . . . 91.30(10)
                                      no
    N7 Mn3 O9 C45 . . . . -83.70(10)
                                   no
    O8 Mn3 O11 C46 . . . . 168.00(10)
                                    no
    O9 Mn3 O11 C46 . . . . -4.40(10)
                                   no
    N6 Mn3 O11 C46 2_656 . . . -95.10(10)
                                        no
    N7 Mn3 O11 C46 . . . . 80.60(10)
                                   no
    O3 Mn1 N1 C5 . . . . -49.0(2) no
    O1 Mn1 N1 C5 . . . . -127.5(2) no
    O12 Mn1 N1 C5 1_545 . . . 51.2(2) no
    O10 Mn1 N1 C5 1_545 . . . 129.6(2) no
    O3 Mn1 N1 C1 . . . . 137.20(10)
                                  no
    O1 Mn1 N1 C1 . . . . 58.70(10)
                                 no
    O12 Mn1 N1 C1 1_545 . . . -122.60(10)
                                        no
    O10 Mn1 N1 C1 1_545 . . . -44.20(10)
                                       no
    O3 Mn1 N3 C15 . . . . 26.10(10)
                                  no
    O1 Mn1 N3 C15 . . . . 105.60(10)
                                   no
    O12 Mn1 N3 C15 1_545 . . . -73.80(10)
                                        no
    O10 Mn1 N3 C15 1_545 . . . -151.80(10)
                                         no
    O3 Mn1 N3 C11 . . . . -155.50(10)
                                    no
    O1 Mn1 N3 C11 . . . . -76.00(10)
                                   no
    O12 Mn1 N3 C11 1_545 . . . 104.60(10)
                                        no
    O10 Mn1 N3 C11 1_545 . . . 26.60(10)
                                       no
    O2 Mn2 N5 C25 . . . . 153.70(10)
                                   no
    O7 Mn2 N5 C25 . . . . -26.80(10)
                                   no
    O4 Mn2 N5 C25 . . . . 75.10(10)
                                  no
    O5 Mn2 N5 C25 . . . . -105.60(10)
                                    no
    O2 Mn2 N5 C21 . . . . -37.00(10)
                                   no
    O7 Mn2 N5 C21 . . . . 142.40(10)
                                   no
    O4 Mn2 N5 C21 . . . . -115.70(10)
                                    no
    O5 Mn2 N5 C21 . . . . 63.70(10)
                                  no
    O6 Mn3 N7 C35 . . . . -151.9(2) no
    O8 Mn3 N7 C35 . . . . -73.7(2) no
    O9 Mn3 N7 C35 . . . . 107.2(2) no
    O11 Mn3 N7 C35 . . . . 29.10(10)
                                   no
    O6 Mn3 N7 C31 . . . . 44.20(10)
                                  no
    O8 Mn3 N7 C31 . . . . 122.40(10)
                                   no
    O9 Mn3 N7 C31 . . . . -56.70(10)
                                   no
    O11 Mn3 N7 C31 . . . . -134.9(2) no
    C5 N1 C1 C2 . . . . 0.2(3) no
    Mn1 N1 C1 C2 . . . . 174.4(2) no
    N1 C1 C2 C3 . . . . -1.0(3) no
    C1 C2 C3 C4 . . . . 0.9(3) no
    C1 C2 C3 C6 . . . . -178.9(2) no
    C2 C3 C4 C5 . . . . -0.2(3) no
    C6 C3 C4 C5 . . . . 179.6(2) no
    C1 N1 C5 C4 . . . . 0.6(3) no
    Mn1 N1 C5 C4 . . . . -173.5(2) no
    C3 C4 C5 N1 . . . . -0.6(4) no
    C4 C3 C6 C10 . . . . 151.7(2) no
    C2 C3 C6 C10 . . . . -28.6(3) no
    C4 C3 C6 C7 . . . . -28.7(3) no
    C2 C3 C6 C7 . . . . 151.1(2) no
    C10 C6 C7 C8 . . . . 0.2(3) no
    C3 C6 C7 C8 . . . . -179.4(2) no
    C9 N2 C8 C7 . . . . 0.5(3) no
    C6 C7 C8 N2 . . . . -0.7(3) no
    C8 N2 C9 C10 . . . . 0.1(3) no
    N2 C9 C10 C6 . . . . -0.6(3) no
    C7 C6 C10 C9 . . . . 0.3(3) no
    C3 C6 C10 C9 . . . . 180.0(2) no
    C15 N3 C11 C12 . . . . -1.4(3) no
    Mn1 N3 C11 C12 . . . . -179.80(10)
                                     no
    N3 C11 C12 C13 . . . . 1.4(3) no
    C11 C12 C13 C14 . . . . 0.0(3) no
    C11 C12 C13 C16 . . . . -179.9(2) no
    C12 C13 C14 C15 . . . . -1.3(3) no
    C16 C13 C14 C15 . . . . 178.6(2) no
    C11 N3 C15 C14 . . . . -0.1(3) no
    Mn1 N3 C15 C14 . . . . 178.40(10)
                                    no
    C13 C14 C15 N3 . . . . 1.4(3) no
    C14 C13 C16 C20 . . . . 35.4(3) no
    C12 C13 C16 C20 . . . . -144.7(2) no
    C14 C13 C16 C17 . . . . -145.4(2) no
    C12 C13 C16 C17 . . . . 34.5(3) no
    C20 C16 C17 C18 . . . . 0.8(3) no
    C13 C16 C17 C18 . . . . -178.4(2) no
    C19 N4 C18 C17 . . . . -3.5(3) no
    Mn2 N4 C18 C17 2_745 . . . 166.00(10)
                                        no
    C16 C17 C18 N4 . . . . 2.1(3) no
    C18 N4 C19 C20 . . . . 2.2(3) no
    Mn2 N4 C19 C20 2_745 . . . -167.5(2) no
    N4 C19 C20 C16 . . . . 0.6(3) no
    C17 C16 C20 C19 . . . . -2.0(3) no
    C13 C16 C20 C19 . . . . 177.2(2) no
    C25 N5 C21 C22 . . . . 2.5(3) no
    Mn2 N5 C21 C22 . . . . -167.1(2) no
    N5 C21 C22 C23 . . . . -1.0(3) no
    C21 C22 C23 C24 . . . . -1.7(3) no
    C21 C22 C23 C26 . . . . 178.1(2) no
    C22 C23 C24 C25 . . . . 2.8(3) no
    C26 C23 C24 C25 . . . . -177.0(2) no
    C21 N5 C25 C24 . . . . -1.3(3) no
    Mn2 N5 C25 C24 . . . . 168.7(2) no
    C23 C24 C25 N5 . . . . -1.4(3) no
    C22 C23 C26 C27 . . . . 139.7(2) no
    C24 C23 C26 C27 . . . . -40.5(3) no
    C22 C23 C26 C30 . . . . -41.1(3) no
    C24 C23 C26 C30 . . . . 138.7(2) no
    C30 C26 C27 C28 . . . . 2.2(3) no
    C23 C26 C27 C28 . . . . -178.6(2) no
    C29 N6 C28 C27 . . . . -0.3(3) no
    Mn3 N6 C28 C27 2_646 . . . 172.6(2) no
    C26 C27 C28 N6 . . . . -1.6(3) no
    C28 N6 C29 C30 . . . . 1.5(3) no
    Mn3 N6 C29 C30 2_646 . . . -171.30(10)
                                         no
    N6 C29 C30 C26 . . . . -0.8(3) no
    C27 C26 C30 C29 . . . . -1.1(3) no
    C23 C26 C30 C29 . . . . 179.8(2) no
    C35 N7 C31 C32 . . . . -2.4(3) no
    Mn3 N7 C31 C32 . . . . 162.1(2) no
    N7 C31 C32 C33 . . . . 0.3(3) no
    C31 C32 C33 C34 . . . . 1.9(3) no
    C31 C32 C33 C36 . . . . -178.5(2) no
    C32 C33 C34 C35 . . . . -2.0(3) no
    C36 C33 C34 C35 . . . . 178.5(2) no
    C32 C33 C36 C37 . . . . -146.9(2) no
    C34 C33 C36 C37 . . . . 32.7(3) no
    C32 C33 C36 C40 . . . . 33.6(3) no
    C34 C33 C36 C40 . . . . -146.9(2) no
    C31 N7 C35 C34 . . . . 2.3(3) no
    Mn3 N7 C35 C34 . . . . -162.3(2) no
    C33 C34 C35 N7 . . . . -0.2(3) no
    C40 C36 C37 C38 . . . . -1.4(3) no
    C33 C36 C37 C38 . . . . 179.1(2) no
    C39 N8 C38 C37 . . . . -0.1(3) no
    C36 C37 C38 N8 . . . . 1.1(3) no
    C38 N8 C39 C40 . . . . -0.6(3) no
    N8 C39 C40 C36 . . . . 0.2(3) no
    C37 C36 C40 C39 . . . . 0.8(3) no
    C33 C36 C40 C39 . . . . -179.7(2) no
    Mn2 O2 C41 O1 . . . . 174.90(10)
                                   no
    Mn2 O2 C41 C42 . . . . -3.7(2) no
    Mn1 O1 C41 O2 . . . . -167.80(10)
                                    no
    Mn1 O1 C41 C42 . . . . 10.8(2) no
    Mn2 O4 C42 O3 . . . . -172.30(10)
                                    no
    Mn2 O4 C42 C41 . . . . 6.0(2) no
    Mn1 O3 C42 O4 . . . . 170.20(10)
                                   no
    Mn1 O3 C42 C41 . . . . -8.1(2) no
    O2 C41 C42 O4 . . . . -1.7(2) no
    O1 C41 C42 O4 . . . . 179.60(10)
                                   no
    O2 C41 C42 O3 . . . . 176.70(10)
                                   no
    O1 C41 C42 O3 . . . . -1.9(2) no
    Mn2 O5 C43 O6 . . . . 164.90(10)
                                   no
    Mn2 O5 C43 C44 . . . . -13.7(2) no
    Mn3 O6 C43 O5 . . . . -171.50(10)
                                    no
    Mn3 O6 C43 C44 . . . . 7.2(2) no
    Mn3 O8 C44 O7 . . . . 167.50(10)
                                   no
    Mn3 O8 C44 C43 . . . . -11.5(2) no
    Mn2 O7 C44 O8 . . . . -169.20(10)
                                    no
    Mn2 O7 C44 C43 . . . . 9.8(2) no
    O5 C43 C44 O8 . . . . -178.10(10)
                                    no
    O6 C43 C44 O8 . . . . 3.2(2) no
    O5 C43 C44 O7 . . . . 2.9(2) no
    O6 C43 C44 O7 . . . . -175.90(10)
                                    no
    Mn3 O9 C45 O10 . . . . 179.20(10)
                                    no
    Mn3 O9 C45 C46 . . . . -0.9(2) no
    Mn1 O10 C45 O9 1_565 . . . 175.00(10)
                                        no
    Mn1 O10 C45 C46 1_565 . . . -5.0(2) no
    Mn3 O11 C46 O12 . . . . -173.70(10)
                                      no
    Mn3 O11 C46 C45 . . . . 5.4(2) no
    Mn1 O12 C46 O11 1_565 . . . -170.10(10)
                                          no
    Mn1 O12 C46 C45 1_565 . . . 10.8(2) no
    O9 C45 C46 O11 . . . . -3.2(2) no
    O10 C45 C46 O11 . . . . 176.80(10)
                                     no
    O9 C45 C46 O12 . . . . 176.00(10)
                                    no
    O10 C45 C46 O12 . . . . -4.1(2) no
data_global
_journal_date_recd_electronic     2005-04-06
_journal_date_accepted     2005-04-13
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2005
_journal_volume     61
_journal_issue      5
_journal_page_first     m916
_journal_page_last     m918
_journal_paper_category     EM
_publ_contact_author_name     'Dr Ming-Hua Zeng'
_publ_contact_author_address
;
Department of Chemistry
Guangxi Normal Univerity
Guilin 541000
Guangxi
People's Republic of China
;
_publ_contact_author_email     zmhzsu@163.com
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;\
catena-Poly[tris(μ₂-oxalato-κ⁴O,O':\
O''O''')bis(μ₂-4,4'-bipyridyl-
κ²N,N')bis(4,4'-bipyridyl-κN)trimanganese(II)]\

;
loop_
    _publ_author_name
    _publ_author_address
    'Zhu, Li-Hong'
;
Department of Chemistry,
Guangxi Normal University
Guilin 541000
Guangxi
People's Republic of China
and Department of Chemistry
Huanggang Normal College
Huangzhou 441000
Hubei
People's Republic of China
;
    'Zeng, Ming-Hua'
;
Department of Chemistry
Guangxi Normal University
Guilin 541000
Guangxi
People's Republic of China
;
    'Ng, Seik Weng'
;
Department of Chemistry
University of Malaya
50603 Kuala Lumpur
Malaysia
;
