##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
catena-Poly[bis[aqua(1,10-phenanthroline-κ²N,N')cobalt(II)]-
di-μ-4,4'-oxydibenzoato-1:2κ⁴O:O']
;
_chemical_name_common     ?
_chemical_formula_moiety     '2Co , 2C14 H8 O5 , 2C12 H8 N2 , 2H2 O'
_chemical_formula_sum     'C52 H36 Co2 N4 O12'
_chemical_formula_iupac     '[Co2 (C14 H8 O5)2 (C12 H8 N2)2 (H2 O)2]'
_chemical_formula_weight     1026.71
_chemical_melting_point     ?
_symmetry_cell_setting     Triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     7.7129(4)
_cell_length_b     11.5063(6)
_cell_length_c     13.3854(7)
_cell_angle_alpha     82.6140(10)
_cell_angle_beta     83.1650(10)
_cell_angle_gamma     72.7240(10)
_cell_volume     1120.80(10)
_cell_formula_units_Z     1
_cell_measurement_reflns_used     5331
_cell_measurement_theta_min     2.5
_cell_measurement_theta_max     28.3
_cell_measurement_temperature     295(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     red
_exptl_crystal_size_max     0.34
_exptl_crystal_size_mid     0.27
_exptl_crystal_size_min     0.23
_exptl_crystal_density_diffrn     1.521
_exptl_crystal_density_meas     'not measured'
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     526
_exptl_absorpt_coefficient_mu     0.813
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2002)'
_exptl_absorpt_correction_T_min     0.770
_exptl_absorpt_correction_T_max     0.835
_diffrn_ambient_temperature     295(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEX CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     9587
_diffrn_reflns_av_R_equivalents     0.014
_diffrn_reflns_av_sigmaI/netI     0.024
_diffrn_reflns_theta_min     1.9
_diffrn_reflns_theta_max     27.5
_diffrn_reflns_theta_full     27.5
_diffrn_measured_fraction_theta_max     0.96
_diffrn_measured_fraction_theta_full     0.96
_diffrn_reflns_limit_h_min     -10
_diffrn_reflns_limit_h_max     10
_diffrn_reflns_limit_k_min     -14
_diffrn_reflns_limit_k_max     14
_diffrn_reflns_limit_l_min     -17
_diffrn_reflns_limit_l_max     17
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_reflns_number_total     4919
_reflns_number_gt     4510
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.037
_refine_ls_R_factor_gt     0.034
_refine_ls_wR_factor_gt     0.090
_refine_ls_wR_factor_ref     0.092
_refine_ls_goodness_of_fit_ref     1.027
_refine_ls_restrained_S_all     1.027
_refine_ls_number_reflns     4919
_refine_ls_number_parameters     324
_refine_ls_number_restraints     2
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.0553P)²+0.3018P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.40
_refine_diff_density_min     -0.30
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Co' 'Co' 0.3494 0.9721
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 2002)'
_computing_cell_refinement     'SAINT (Bruker, 2002)'
_computing_data_reduction     SAINT
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEPII (Johnson, 1976)'
_computing_publication_material     SHELXL97
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Co1 0.68260(3) 0.38248(2) 0.98543(2) 0.02611(9) Uani d . 1 . . Co
    O1 0.6287(2) 0.34520(10)
                           0.84840(10)
                                     0.0349(3) Uani d . 1 . . O
    O2 0.8920(2) 0.30340(10)
                           0.75090(10)
                                     0.0445(3) Uani d . 1 . . O
    O3 0.3672(2) 0.1601(2) 0.48560(10)
                                     0.0525(4) Uani d . 1 . . O
    O4 0.2529(2) 0.29050(10)
                           0.02140(10)
                                     0.0395(3) Uani d . 1 . . O
    O5 0.4044(2) 0.42370(10)
                           0.03780(10)
                                     0.0280(2) Uani d . 1 . . O
    O1W 0.9417(2) 0.38620(10)
                            0.92000(10)
                                      0.0395(3) Uani d D 1 . . O
    N1 0.7753(2) 0.37030(10)
                           1.13040(10)
                                     0.0287(3) Uani d . 1 . . N
    N2 0.7385(2) 0.18970(10)
                           1.03520(10)
                                     0.0303(3) Uani d . 1 . . N
    C1 0.7856(3) 0.4619(2) 1.17760(10)
                                     0.0356(4) Uani d . 1 . . C
    C2 0.8546(3) 0.4440(2) 1.2723(2) 0.0436(5) Uani d . 1 . . C
    C3 0.9113(3) 0.3282(2) 1.3193(2) 0.0413(4) Uani d . 1 . . C
    C4 0.8998(2) 0.2290(2) 1.27220(10)
                                     0.0334(4) Uani d . 1 . . C
    C5 0.9545(3) 0.1043(2) 1.3155(2) 0.0409(4) Uani d . 1 . . C
    C6 0.9363(3) 0.0128(2) 1.2670(2) 0.0422(5) Uani d . 1 . . C
    C7 0.8616(2) 0.0373(2) 1.1711(2) 0.0356(4) Uani d . 1 . . C
    C8 0.8338(3) -0.0532(2) 1.1190(2) 0.0430(5) Uani d . 1 . . C
    C9 0.7588(3) -0.0213(2) 1.0285(2) 0.0456(5) Uani d . 1 . . C
    C10 0.7125(3) 0.1015(2) 0.9892(2) 0.0383(4) Uani d . 1 . . C
    C11 0.8109(2) 0.1581(2) 1.12570(10)
                                      0.0291(3) Uani d . 1 . . C
    C12 0.8301(2) 0.2551(2) 1.17710(10)
                                      0.0288(3) Uani d . 1 . . C
    C13 0.7282(2) 0.3078(2) 0.76980(10)
                                      0.0313(4) Uani d . 1 . . C
    C14 0.6345(2) 0.2670(2) 0.69430(10)
                                      0.0325(4) Uani d . 1 . . C
    C15 0.4624(3) 0.2520(2) 0.71820(10)
                                      0.0389(4) Uani d . 1 . . C
    C16 0.3719(3) 0.2190(2) 0.64760(10)
                                      0.0417(4) Uani d . 1 . . C
    C17 0.4580(3) 0.1990(2) 0.55220(10)
                                      0.0388(4) Uani d . 1 . . C
    C18 0.6315(3) 0.2100(2) 0.5275(2) 0.0508(5) Uani d . 1 . . C
    C19 0.7187(3) 0.2439(2) 0.59810(10)
                                      0.0448(5) Uani d . 1 . . C
    C20 0.3327(2) 0.3367(2) 0.07210(10)
                                      0.0263(3) Uani d . 1 . . C
    C21 0.3539(2) 0.2894(2) 0.18160(10)
                                      0.0270(3) Uani d . 1 . . C
    C22 0.3579(3) 0.1695(2) 0.21490(10)
                                      0.0323(4) Uani d . 1 . . C
    C23 0.3731(3) 0.1259(2) 0.31600(10)
                                      0.0361(4) Uani d . 1 . . C
    C24 0.3760(3) 0.2052(2) 0.38420(10)
                                      0.0364(4) Uani d . 1 . . C
    C25 0.3739(3) 0.3248(2) 0.35290(10)
                                      0.0414(5) Uani d . 1 . . C
    C26 0.3663(3) 0.3656(2) 0.25090(10)
                                      0.0351(4) Uani d . 1 . . C
    H1W1 0.950(4) 0.360(2) 0.8630(10)
                                    0.075(9) Uiso d D 1 . . H
    H1W2 1.040(2) 0.357(2) 0.947(2) 0.054(7) Uiso d D 1 . . H
    H1 0.7455 0.5412 1.1467 0.043 Uiso calc R 1 . . H
    H2 0.8617 0.5104 1.3030 0.052 Uiso calc R 1 . . H
    H3 0.9574 0.3152 1.3822 0.050 Uiso calc R 1 . . H
    H5 1.0033 0.0860 1.3778 0.049 Uiso calc R 1 . . H
    H6 0.9731 -0.0673 1.2966 0.051 Uiso calc R 1 . . H
    H8 0.8664 -0.1345 1.1461 0.052 Uiso calc R 1 . . H
    H9 0.7388 -0.0803 0.9936 0.055 Uiso calc R 1 . . H
    H10 0.6609 0.1224 0.9276 0.046 Uiso calc R 1 . . H
    H15 0.4060 0.2642 0.7829 0.047 Uiso calc R 1 . . H
    H16 0.2555 0.2105 0.6642 0.050 Uiso calc R 1 . . H
    H18 0.6894 0.1946 0.4635 0.061 Uiso calc R 1 . . H
    H19 0.8357 0.2515 0.5812 0.054 Uiso calc R 1 . . H
    H22 0.3502 0.1176 0.1688 0.039 Uiso calc R 1 . . H
    H23 0.3812 0.0445 0.3374 0.043 Uiso calc R 1 . . H
    H25 0.3776 0.3772 0.3995 0.050 Uiso calc R 1 . . H
    H26 0.3695 0.4450 0.2288 0.042 Uiso calc R 1 . . H
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Co1 O1 . 2.0530(10)
                      yes
    Co1 O5 1_556 2.1080(10)
                          yes
    Co1 O5 2_666 2.1220(10)
                          yes
    Co1 O1W . 2.0940(10)
                       yes
    Co1 N1 . 2.1210(10)
                      yes
    Co1 N2 . 2.1610(10)
                      yes
    O1 C13 . 1.268(2) no
    O2 C13 . 1.246(2) no
    O3 C17 . 1.386(2) no
    O3 C24 . 1.391(2) no
    O4 C20 . 1.228(2) no
    O5 C20 . 1.292(2) no
    N1 C1 . 1.322(2) no
    N1 C12 . 1.358(2) no
    N2 C10 . 1.326(2) no
    N2 C11 . 1.357(2) no
    C1 C2 . 1.401(3) no
    C2 C3 . 1.366(3) no
    C3 C4 . 1.403(3) no
    C4 C12 . 1.403(2) no
    C4 C5 . 1.434(3) no
    C5 C6 . 1.354(3) no
    C6 C7 . 1.431(3) no
    C7 C8 . 1.403(3) no
    C7 C11 . 1.404(2) no
    C8 C9 . 1.365(3) no
    C9 C10 . 1.398(3) no
    C11 C12 . 1.435(2) no
    C13 C14 . 1.504(2) no
    C14 C15 . 1.384(3) no
    C14 C19 . 1.392(3) no
    C15 C16 . 1.390(3) no
    C16 C17 . 1.380(3) no
    C17 C18 . 1.379(3) no
    C18 C19 . 1.379(3) no
    C20 C21 . 1.506(2) no
    C21 C26 . 1.385(2) no
    C21 C22 . 1.386(2) no
    C22 C23 . 1.388(2) no
    C23 C24 . 1.377(3) no
    C24 C25 . 1.382(3) no
    C25 C26 . 1.388(2) no
    O1W H1W1 . 0.850(10)
                       no
    O1W H1W2 . 0.840(10)
                       no
    C1 H1 . 0.93 no
    C2 H2 . 0.93 no
    C3 H3 . 0.93 no
    C5 H5 . 0.93 no
    C6 H6 . 0.93 no
    C8 H8 . 0.93 no
    C9 H9 . 0.93 no
    C10 H10 . 0.93 no
    C15 H15 . 0.93 no
    C16 H16 . 0.93 no
    C18 H18 . 0.93 no
    C19 H19 . 0.93 no
    C22 H22 . 0.93 no
    C23 H23 . 0.93 no
    C25 H25 . 0.93 no
    C26 H26 . 0.93 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Co1 O5 . 1_556 91.30(5) yes
    O1 Co1 O5 . 2_666 98.51(5) yes
    O1 Co1 O1W . . 88.10(5) yes
    O1 Co1 N1 . . 164.66(5) yes
    O1 Co1 N2 . . 88.34(5) yes
    O5 Co1 O5 1_556 2_666 77.47(5) yes
    O5 Co1 O1W 1_556 . 166.14(5) yes
    O5 Co1 N1 1_556 . 94.90(5) yes
    O5 Co1 N2 1_556 . 94.16(5) yes
    O5 Co1 O1W 2_666 . 88.92(5) yes
    O5 Co1 N1 2_666 . 96.53(5) yes
    O5 Co1 N2 2_666 . 169.23(5) yes
    O1W Co1 N1 . . 89.18(6) yes
    O1W Co1 N2 . . 99.66(6) yes
    N1 Co1 N2 . . 77.24(6) yes
    C13 O1 Co1 . . 133.60(10)
                            no
    C17 O3 C24 . . 119.1(2) no
    C20 O5 Co1 . 1_554 120.20(10)
                                no
    C20 O5 Co1 . 2_666 137.30(10)
                                no
    Co1 O5 Co1 1_554 2_666 102.53(5) no
    C1 N1 C12 . . 118.4(2) no
    C1 N1 Co1 . . 126.80(10)
                           no
    C12 N1 Co1 . . 114.90(10)
                            no
    C10 N2 C11 . . 117.7(2) no
    C10 N2 Co1 . . 128.80(10)
                            no
    C11 N2 Co1 . . 113.50(10)
                            no
    N1 C1 C2 . . 122.5(2) no
    C3 C2 C1 . . 119.3(2) no
    C2 C3 C4 . . 119.7(2) no
    C3 C4 C12 . . 117.1(2) no
    C3 C4 C5 . . 124.0(2) no
    C12 C4 C5 . . 118.9(2) no
    C6 C5 C4 . . 121.1(2) no
    C5 C6 C7 . . 121.1(2) no
    C8 C7 C11 . . 117.3(2) no
    C8 C7 C6 . . 123.7(2) no
    C11 C7 C6 . . 119.1(2) no
    C9 C8 C7 . . 119.7(2) no
    C8 C9 C10 . . 119.0(2) no
    N2 C10 C9 . . 123.3(2) no
    N2 C11 C7 . . 123.1(2) no
    N2 C11 C12 . . 117.20(10)
                            no
    C7 C11 C12 . . 119.8(2) no
    N1 C12 C4 . . 122.9(2) no
    N1 C12 C11 . . 117.1(2) no
    C4 C12 C11 . . 120.0(2) no
    O2 C13 O1 . . 125.8(2) no
    O2 C13 C14 . . 119.0(2) no
    O1 C13 C14 . . 115.2(2) no
    C15 C14 C19 . . 118.2(2) no
    C15 C14 C13 . . 121.1(2) no
    C19 C14 C13 . . 120.7(2) no
    C14 C15 C16 . . 121.5(2) no
    C17 C16 C15 . . 118.8(2) no
    C18 C17 C16 . . 120.8(2) no
    C18 C17 O3 . . 122.0(2) no
    C16 C17 O3 . . 117.1(2) no
    C17 C18 C19 . . 119.6(2) no
    C18 C19 C14 . . 121.0(2) no
    O4 C20 O5 . . 124.5(2) no
    O4 C20 C21 . . 119.3(2) no
    O5 C20 C21 . . 116.20(10)
                            no
    C26 C21 C22 . . 119.0(2) no
    C26 C21 C20 . . 120.5(2) no
    C22 C21 C20 . . 120.5(2) no
    C21 C22 C23 . . 120.9(2) no
    C24 C23 C22 . . 119.0(2) no
    C23 C24 C25 . . 121.2(2) no
    C23 C24 O3 . . 115.9(2) no
    C25 C24 O3 . . 122.7(2) no
    C24 C25 C26 . . 119.0(2) no
    C21 C26 C25 . . 120.8(2) no
    Co1 O1W H1W1 . . 105(2) no
    Co1 O1W H1W2 . . 126(2) no
    H1W1 O1W H1W2 . . 111(3) no
    N1 C1 H1 . . 118.7 no
    C2 C1 H1 . . 118.7 no
    C3 C2 H2 . . 120.3 no
    C1 C2 H2 . . 120.3 no
    C2 C3 H3 . . 120.1 no
    C4 C3 H3 . . 120.1 no
    C6 C5 H5 . . 119.5 no
    C4 C5 H5 . . 119.5 no
    C5 C6 H6 . . 119.4 no
    C7 C6 H6 . . 119.4 no
    C9 C8 H8 . . 120.1 no
    C7 C8 H8 . . 120.1 no
    C8 C9 H9 . . 120.5 no
    C10 C9 H9 . . 120.5 no
    N2 C10 H10 . . 118.4 no
    C9 C10 H10 . . 118.4 no
    C14 C15 H15 . . 119.3 no
    C16 C15 H15 . . 119.3 no
    C17 C16 H16 . . 120.6 no
    C15 C16 H16 . . 120.6 no
    C17 C18 H18 . . 120.2 no
    C19 C18 H18 . . 120.2 no
    C18 C19 H19 . . 119.5 no
    C14 C19 H19 . . 119.5 no
    C21 C22 H22 . . 119.5 no
    C23 C22 H22 . . 119.5 no
    C24 C23 H23 . . 120.5 no
    C22 C23 H23 . . 120.5 no
    C24 C25 H25 . . 120.5 no
    C26 C25 H25 . . 120.5 no
    C21 C26 H26 . . 119.6 no
    C25 C26 H26 . . 119.6 no
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O1W Co1 O1 C13 . . . . 16.7(2) no
    O5 Co1 O1 C13 1_556 . . . -177.2(2) no
    N1 Co1 O1 C13 . . . . -63.2(3) no
    O5 Co1 O1 C13 2_666 . . . 105.3(2) no
    N2 Co1 O1 C13 . . . . -83.0(2) no
    O1 Co1 N1 C1 . . . . 162.5(2) no
    O1W Co1 N1 C1 . . . . 82.8(2) no
    O5 Co1 N1 C1 1_556 . . . -84.0(2) no
    O5 Co1 N1 C1 2_666 . . . -6.1(2) no
    N2 Co1 N1 C1 . . . . -177.2(2) no
    O1 Co1 N1 C12 . . . . -16.9(3) no
    O1W Co1 N1 C12 . . . . -96.70(10)
                                    no
    O5 Co1 N1 C12 1_556 . . . 96.60(10)
                                      no
    O5 Co1 N1 C12 2_666 . . . 174.50(10)
                                       no
    N2 Co1 N1 C12 . . . . 3.40(10)
                                 no
    O1 Co1 N2 C10 . . . . -8.5(2) no
    O1W Co1 N2 C10 . . . . -96.2(2) no
    O5 Co1 N2 C10 1_556 . . . 82.7(2) no
    N1 Co1 N2 C10 . . . . 176.8(2) no
    O5 Co1 N2 C10 2_666 . . . 121.3(3) no
    O1 Co1 N2 C11 . . . . 171.10(10)
                                   no
    O1W Co1 N2 C11 . . . . 83.30(10)
                                   no
    O5 Co1 N2 C11 1_556 . . . -97.70(10)
                                       no
    N1 Co1 N2 C11 . . . . -3.60(10)
                                  no
    O5 Co1 N2 C11 2_666 . . . -59.1(3) no
    C12 N1 C1 C2 . . . . 1.5(3) no
    Co1 N1 C1 C2 . . . . -177.90(10)
                                   no
    N1 C1 C2 C3 . . . . -1.0(3) no
    C1 C2 C3 C4 . . . . 0.0(3) no
    C2 C3 C4 C12 . . . . 0.4(3) no
    C2 C3 C4 C5 . . . . -179.6(2) no
    C3 C4 C5 C6 . . . . 178.6(2) no
    C12 C4 C5 C6 . . . . -1.4(3) no
    C4 C5 C6 C7 . . . . -0.1(3) no
    C5 C6 C7 C8 . . . . -177.8(2) no
    C5 C6 C7 C11 . . . . 1.7(3) no
    C11 C7 C8 C9 . . . . -0.6(3) no
    C6 C7 C8 C9 . . . . 178.9(2) no
    C7 C8 C9 C10 . . . . 0.5(3) no
    C11 N2 C10 C9 . . . . -1.1(3) no
    Co1 N2 C10 C9 . . . . 178.4(2) no
    C8 C9 C10 N2 . . . . 0.3(3) no
    C10 N2 C11 C7 . . . . 1.1(3) no
    Co1 N2 C11 C7 . . . . -178.50(10)
                                    no
    C10 N2 C11 C12 . . . . -177.0(2) no
    Co1 N2 C11 C12 . . . . 3.4(2) no
    C8 C7 C11 N2 . . . . -0.3(3) no
    C6 C7 C11 N2 . . . . -179.8(2) no
    C8 C7 C11 C12 . . . . 177.8(2) no
    C6 C7 C11 C12 . . . . -1.7(3) no
    C1 N1 C12 C4 . . . . -1.1(3) no
    Co1 N1 C12 C4 . . . . 178.40(10)
                                   no
    C1 N1 C12 C11 . . . . 177.7(2) no
    Co1 N1 C12 C11 . . . . -2.8(2) no
    C3 C4 C12 N1 . . . . 0.1(3) no
    C5 C4 C12 N1 . . . . -179.9(2) no
    C3 C4 C12 C11 . . . . -178.6(2) no
    C5 C4 C12 C11 . . . . 1.3(3) no
    N2 C11 C12 N1 . . . . -0.4(2) no
    C7 C11 C12 N1 . . . . -178.6(2) no
    N2 C11 C12 C4 . . . . 178.4(2) no
    C7 C11 C12 C4 . . . . 0.2(2) no
    Co1 O1 C13 O2 . . . . -13.3(3) no
    Co1 O1 C13 C14 . . . . 167.30(10)
                                    no
    O2 C13 C14 C15 . . . . 169.8(2) no
    O1 C13 C14 C15 . . . . -10.7(2) no
    O2 C13 C14 C19 . . . . -10.5(3) no
    O1 C13 C14 C19 . . . . 169.0(2) no
    C19 C14 C15 C16 . . . . -2.2(3) no
    C13 C14 C15 C16 . . . . 177.4(2) no
    C14 C15 C16 C17 . . . . 1.1(3) no
    C15 C16 C17 C18 . . . . 0.8(3) no
    C15 C16 C17 O3 . . . . 176.8(2) no
    C24 O3 C17 C18 . . . . -42.6(3) no
    C24 O3 C17 C16 . . . . 141.5(2) no
    C16 C17 C18 C19 . . . . -1.4(3) no
    O3 C17 C18 C19 . . . . -177.2(2) no
    C17 C18 C19 C14 . . . . 0.1(4) no
    C15 C14 C19 C18 . . . . 1.6(3) no
    C13 C14 C19 C18 . . . . -178.1(2) no
    Co1 O5 C20 O4 1_554 . . . -94.4(2) no
    Co1 O5 C20 O4 2_666 . . . 85.1(2) no
    Co1 O5 C20 C21 1_554 . . . 84.4(2) no
    Co1 O5 C20 C21 2_666 . . . -96.0(2) no
    O4 C20 C21 C26 . . . . -151.5(2) no
    O5 C20 C21 C26 . . . . 29.7(2) no
    O4 C20 C21 C22 . . . . 27.3(2) no
    O5 C20 C21 C22 . . . . -151.6(2) no
    C26 C21 C22 C23 . . . . 0.3(3) no
    C20 C21 C22 C23 . . . . -178.5(2) no
    C21 C22 C23 C24 . . . . 2.9(3) no
    C22 C23 C24 C25 . . . . -3.5(3) no
    C22 C23 C24 O3 . . . . 171.8(2) no
    C17 O3 C24 C23 . . . . 147.1(2) no
    C17 O3 C24 C25 . . . . -37.7(3) no
    C23 C24 C25 C26 . . . . 0.9(3) no
    O3 C24 C25 C26 . . . . -174.1(2) no
    C22 C21 C26 C25 . . . . -3.0(3) no
    C20 C21 C26 C25 . . . . 175.8(2) no
    C24 C25 C26 C21 . . . . 2.4(3) no
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    O1W H1W1 O2 . 0.850(10)
                          1.86(2) 2.675(2) 161(3) yes
    O1W H1W2 O4 1_656 0.840(10)
                              1.930(10)
                                      2.764(2) 175(2) yes
data_global
_journal_date_recd_electronic     2005-01-10
_journal_date_accepted     2005-01-17
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2005
_journal_volume     61
_journal_issue      2
_journal_page_first     m344
_journal_page_last     m345
_journal_paper_category     EM
_publ_contact_author_name     'Hong-Ping, Xiao'
_publ_contact_author_address
;
School of Chemistry and Materials Science
Wenzhou Normal College
Wenzhou 325027
People's Republic of China
;
_publ_contact_author_email     'hp_xiao@wznc.zj.cn'
_publ_contact_author_fax     '86-577-88373113'
_publ_contact_author_phone     '86-577-88373111'
_publ_section_title
;\
catena-Poly[bis[aqua(1,10-phenanthroline-κ²N,N')cobalt(II)]-
di-μ-4,4'-oxydibenzoato-1:2κ⁴O:O']
;
loop_
    _publ_author_name
    _publ_author_address
    'Xiao, Hong-Ping'
;
School of Chemistry and Materials Science
Wenzhou Normal College
Wenzhou 325027
People's Republic of China
;
    'Li, Xin-Hua'
;
School of Chemistry and Materials Science
Wenzhou Normal College
Wenzhou 325027
People's Republic of China
;
    'Ng, Seik Weng'
;
Department of Chemistry
University of Malaya
50603 Kuala Lumpur
Malaysia
;
