##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Bis(butane-2,3-dione monooxime benzoylhydrazone-κ³O,N,N')nickel(II) sulfate
salicylhydroxamic acid
;
_chemical_name_common     ?
_chemical_formula_moiety     'C22 H26 N6 O4 Ni 2+, S O4 2-, C7 H7 N O3'
_chemical_formula_sum     'C29 H33 N7 Ni O11 S'
_chemical_formula_iupac     '[Ni (C11 H13 N3 O2)2] S O4, C7 H7 N O3'
_chemical_formula_weight     746.39
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/c'
_symmetry_space_group_name_Hall     '-P 2ybc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     7.986(2)
_cell_length_b     23.781(5)
_cell_length_c     17.868(4)
_cell_angle_alpha     90.00
_cell_angle_beta     102.82(3)
_cell_angle_gamma     90.00
_cell_volume     3309.0(10)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     21088
_cell_measurement_theta_min     3.1
_cell_measurement_theta_max     27.4
_cell_measurement_temperature     295(2)
_exptl_crystal_description     Prism
_exptl_crystal_colour     Yellow
_exptl_crystal_size_max     0.39
_exptl_crystal_size_mid     0.27
_exptl_crystal_size_min     0.20
_exptl_crystal_density_diffrn     1.498
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1552
_exptl_absorpt_coefficient_mu     0.719
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(ABSCOR; Higashi, 1995)'
_exptl_absorpt_correction_T_min     0.591
_exptl_absorpt_correction_T_max     0.870
_diffrn_ambient_temperature     295(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Rigaku R-AXIS RAPID'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     29244
_diffrn_reflns_av_R_equivalents     0.0689
_diffrn_reflns_av_sigmaI/netI     0.0575
_diffrn_reflns_theta_min     3.10
_diffrn_reflns_theta_max     27.45
_diffrn_reflns_theta_full     27.5
_diffrn_measured_fraction_theta_max     0.99
_diffrn_measured_fraction_theta_full     0.99
_diffrn_reflns_limit_h_min     -9
_diffrn_reflns_limit_h_max     10
_diffrn_reflns_limit_k_min     -30
_diffrn_reflns_limit_k_max     30
_diffrn_reflns_limit_l_min     -23
_diffrn_reflns_limit_l_max     23
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_reflns_number_total     7483
_reflns_number_gt     4963
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.1010
_refine_ls_R_factor_gt     0.0592
_refine_ls_wR_factor_gt     0.1354
_refine_ls_wR_factor_ref     0.1519
_refine_ls_goodness_of_fit_ref     1.018
_refine_ls_restrained_S_all     1.018
_refine_ls_number_reflns     7483
_refine_ls_number_parameters     450
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
     'calc  w= 1/[σ²(Fo²)+(0.0767P)²+1.6714P] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.19
_refine_diff_density_min     -0.33
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ni' 'Ni' 0.3393 1.1124
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'RAPID-AUTO (Rigaku, 1998)'
_computing_cell_refinement     RAPID-AUTO
_computing_data_reduction     'CrystalStructure (Rigaku/MSC, 2002)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEPII (Johnson, 1976)'
_computing_publication_material     SHELXL97
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Ni1 0.80605(5) 0.842363(19) 0.82195(2) 0.03235(14) Uani d . 1 . . Ni
    S1 0.70492(13) 0.69756(4) 0.60396(5) 0.0433(2) Uani d . 1 . . S
    O1 0.9615(4) 0.72360(12) 0.78399(16) 0.0552(7) Uani d . 1 . . O
    H2o 0.9087 0.7324 0.7408 0.083 Uiso calc R 1 . . H
    O2 0.7425(3) 0.92181(10) 0.86001(13) 0.0414(6) Uani d . 1 . . O
    O3 0.4907(4) 0.78890(14) 0.87745(15) 0.0576(8) Uani d . 1 . . O
    H3o 0.5515 0.7964 0.9196 0.086 Uiso calc R 1 . . H
    O4 0.9934(3) 0.87913(11) 0.77353(13) 0.0409(6) Uani d . 1 . . O
    O5 0.8195(4) 0.81190(13) 0.49856(17) 0.0613(8) Uani d . 1 . . O
    H5o 0.7810 0.7852 0.5184 0.092 Uiso calc R 1 . . H
    O6 0.6192(4) 0.90135(13) 0.50373(15) 0.0579(8) Uani d . 1 . . O
    O7 0.5894(4) 0.83629(14) 0.28513(16) 0.0653(9) Uani d . 1 . . O
    H7O 0.5827 0.8326 0.2389 0.098 Uiso calc R 1 . . H
    O8 0.8144(4) 0.74344(12) 0.64345(16) 0.0593(8) Uani d . 1 . . O
    O9 0.5561(4) 0.69058(13) 0.63923(16) 0.0598(8) Uani d . 1 . . O
    O10 0.6483(4) 0.71460(13) 0.52294(15) 0.0625(8) Uani d . 1 . . O
    O11 0.8026(4) 0.64516(11) 0.60894(15) 0.0535(7) Uani d . 1 . . O
    N1 0.9428(4) 0.76494(12) 0.83487(17) 0.0387(7) Uani d . 1 . . N
    N2 0.9165(3) 0.84054(12) 0.93217(15) 0.0335(6) Uani d . 1 . . N
    N3 0.8789(4) 0.88534(12) 0.97441(15) 0.0367(7) Uani d . 1 . . N
    H3n 0.9106 0.8871 1.0236 0.044 Uiso calc R 1 . . H
    N4 0.5653(4) 0.80900(13) 0.82131(17) 0.0390(7) Uani d . 1 . . N
    N5 0.6905(4) 0.84761(12) 0.71125(16) 0.0347(6) Uani d . 1 . . N
    N6 0.7862(4) 0.87300(12) 0.66524(16) 0.0368(7) Uani d . 1 . . N
    H6n 0.7479 0.8786 0.6169 0.044 Uiso calc R 1 . . H
    N7 0.6970(5) 0.83044(15) 0.4353(2) 0.0569(9) Uani d . 1 . . N
    H7n 0.6811 0.8126 0.3924 0.068 Uiso calc R 1 . . H
    C1 1.1585(6) 0.70861(19) 0.9246(3) 0.0616(12) Uani d . 1 . . C
    H1a 1.1283 0.6884 0.9662 0.092 Uiso calc R 1 . . H
    H1b 1.2743 0.7221 0.9403 0.092 Uiso calc R 1 . . H
    H1c 1.1495 0.6840 0.8813 0.092 Uiso calc R 1 . . H
    C2 1.0395(5) 0.75728(16) 0.9030(2) 0.0399(8) Uani d . 1 . . C
    C3 1.0222(4) 0.80126(16) 0.9607(2) 0.0384(8) Uani d . 1 . . C
    C4 1.1218(5) 0.79780(19) 1.0409(2) 0.0531(10) Uani d . 1 . . C
    H4a 1.1037 0.8313 1.0680 0.080 Uiso calc R 1 . . H
    H4b 1.2417 0.7941 1.0413 0.080 Uiso calc R 1 . . H
    H4c 1.0846 0.7657 1.0655 0.080 Uiso calc R 1 . . H
    C5 0.7871(4) 0.92659(15) 0.93114(19) 0.0352(8) Uani d . 1 . . C
    C6 0.7506(4) 0.97796(14) 0.9718(2) 0.0370(8) Uani d . 1 . . C
    C7 0.8331(5) 0.98884(17) 1.0475(2) 0.0474(9) Uani d . 1 . . C
    H7 0.9094 0.9627 1.0748 0.057 Uiso calc R 1 . . H
    C8 0.8014(6) 1.0387(2) 1.0821(3) 0.0631(13) Uani d . 1 . . C
    H8 0.8573 1.0459 1.1326 0.076 Uiso calc R 1 . . H
    C9 0.6888(7) 1.0773(2) 1.0425(3) 0.0698(15) Uani d . 1 . . C
    H9 0.6679 1.1105 1.0663 0.084 Uiso calc R 1 . . H
    C10 0.6065(6) 1.06710(19) 0.9676(3) 0.0665(13) Uani d . 1 . . C
    H10 0.5297 1.0934 0.9409 0.080 Uiso calc R 1 . . H
    C11 0.6380(5) 1.01742(16) 0.9316(2) 0.0503(10) Uani d . 1 . . C
    H11 0.5835 1.0108 0.8808 0.060 Uiso calc R 1 . . H
    C12 0.2960(5) 0.7763(2) 0.7368(2) 0.0572(11) Uani d . 1 . . C
    H12a 0.2646 0.7682 0.7845 0.086 Uiso calc R 1 . . H
    H12b 0.3004 0.7419 0.7092 0.086 Uiso calc R 1 . . H
    H12c 0.2123 0.8010 0.7067 0.086 Uiso calc R 1 . . H
    C13 0.4678(5) 0.80388(16) 0.7524(2) 0.0421(9) Uani d . 1 . . C
    C14 0.5403(5) 0.82797(16) 0.6884(2) 0.0414(9) Uani d . 1 . . C
    C15 0.4409(5) 0.82622(19) 0.6079(2) 0.0516(10) Uani d . 1 . . C
    H15A 0.4912 0.8516 0.5773 0.077 Uiso calc R 1 . . H
    H15B 0.3244 0.8372 0.6060 0.077 Uiso calc R 1 . . H
    H15C 0.4426 0.7887 0.5882 0.077 Uiso calc R 1 . . H
    C16 0.9456(5) 0.88822(14) 0.7031(2) 0.0363(8) Uani d . 1 . . C
    C17 1.0642(5) 0.91610(15) 0.6611(2) 0.0401(8) Uani d . 1 . . C
    C18 1.0251(5) 0.9233(2) 0.5823(2) 0.0554(11) Uani d . 1 . . C
    H18 0.9217 0.9099 0.5531 0.067 Uiso calc R 1 . . H
    C19 1.1408(6) 0.9509(2) 0.5465(3) 0.0667(13) Uani d . 1 . . C
    H19 1.1139 0.9559 0.4936 0.080 Uiso calc R 1 . . H
    C20 1.2941(7) 0.9704(2) 0.5893(3) 0.0688(14) Uani d . 1 . . C
    H20 1.3710 0.9886 0.5653 0.083 Uiso calc R 1 . . H
    C21 1.3341(7) 0.9632(2) 0.6679(3) 0.0807(17) Uani d . 1 . . C
    H21 1.4373 0.9769 0.6969 0.097 Uiso calc R 1 . . H
    C22 1.2211(6) 0.9356(2) 0.7036(3) 0.0650(13) Uani d . 1 . . C
    H22 1.2499 0.9300 0.7564 0.078 Uiso calc R 1 . . H
    C23 0.4775(5) 0.89414(16) 0.3718(2) 0.0435(9) Uani d . 1 . . C
    C24 0.4704(5) 0.87402(18) 0.2968(2) 0.0498(10) Uani d . 1 . . C
    C25 0.3429(7) 0.8931(2) 0.2365(3) 0.0751(15) Uani d . 1 . . C
    H25 0.3396 0.8806 0.1869 0.090 Uiso calc R 1 . . H
    C26 0.2213(8) 0.9305(3) 0.2494(3) 0.095(2) Uani d . 1 . . C
    H26 0.1348 0.9424 0.2086 0.114 Uiso calc R 1 . . H
    C27 0.2260(7) 0.9505(2) 0.3221(3) 0.0843(17) Uani d . 1 . . C
    H27 0.1434 0.9758 0.3305 0.101 Uiso calc R 1 . . H
    C28 0.3534(6) 0.9328(2) 0.3820(3) 0.0594(11) Uani d . 1 . . C
    H28 0.3572 0.9470 0.4309 0.071 Uiso calc R 1 . . H
    C29 0.6044(5) 0.87626(17) 0.4420(2) 0.0437(9) Uani d . 1 . . C
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ni1 O2 . 2.108(2) yes
    Ni1 O4 . 2.080(2) yes
    Ni1 N1 . 2.127(3) yes
    Ni1 N2 . 1.972(3) yes
    Ni1 N5 . 1.992(3) yes
    Ni1 N4 . 2.078(3) yes
    S1 O8 . 1.476(3) yes
    S1 O9 . 1.473(3) yes
    S1 O10 . 1.474(3) yes
    S1 O11 . 1.462(3) yes
    O1 N1 . 1.369(4) no
    O1 H2o . 0.8200 no
    O2 C5 . 1.247(4) no
    O3 N4 . 1.362(4) no
    O3 H3o . 0.8200 no
    O4 C16 . 1.250(4) no
    O5 N7 . 1.392(4) no
    O5 H5o . 0.8200 no
    O6 C29 . 1.236(4) no
    O7 C24 . 1.357(5) no
    O7 H7O . 0.8200 no
    N1 C2 . 1.302(5) no
    N2 C3 . 1.286(4) no
    N2 N3 . 1.377(4) no
    N3 C5 . 1.359(4) no
    N3 H3n . 0.8600 no
    N4 C13 . 1.308(5) no
    N5 C14 . 1.267(5) no
    N5 N6 . 1.379(4) no
    N6 C16 . 1.352(5) no
    N6 H6n . 0.8600 no
    N7 C29 . 1.337(5) no
    N7 H7n . 0.8600 no
    C1 C2 . 1.493(5) no
    C1 H1a . 0.9600 no
    C1 H1b . 0.9600 no
    C1 H1c . 0.9600 no
    C2 C3 . 1.497(5) no
    C3 C4 . 1.479(5) no
    C4 H4a . 0.9600 no
    C4 H4b . 0.9600 no
    C4 H4c . 0.9600 no
    C5 C6 . 1.483(5) no
    C6 C11 . 1.385(5) no
    C6 C7 . 1.390(5) no
    C7 C8 . 1.386(6) no
    C7 H7 . 0.9300 no
    C8 C9 . 1.367(7) no
    C8 H8 . 0.9300 no
    C9 C10 . 1.376(7) no
    C9 H9 . 0.9300 no
    C10 C11 . 1.394(6) no
    C10 H10 . 0.9300 no
    C11 H11 . 0.9300 no
    C12 C13 . 1.490(5) no
    C12 H12a . 0.9600 no
    C12 H12b . 0.9600 no
    C12 H12c . 0.9600 no
    C13 C14 . 1.504(5) no
    C14 C15 . 1.482(5) no
    C15 H15a . 0.9600 no
    C15 H15b . 0.9600 no
    C15 H15c . 0.9600 no
    C16 C17 . 1.488(5) no
    C17 C18 . 1.383(5) no
    C17 C22 . 1.393(6) no
    C18 C19 . 1.398(6) no
    C18 H18 . 0.9300 no
    C19 C20 . 1.372(7) no
    C19 H19 . 0.9300 no
    C20 C21 . 1.381(7) no
    C20 H20 . 0.9300 no
    C21 C22 . 1.380(6) no
    C21 H21 . 0.9300 no
    C22 H22 . 0.9300 no
    C23 C28 . 1.393(6) no
    C23 C24 . 1.411(5) no
    C23 C29 . 1.490(5) no
    C24 C25 . 1.385(6) no
    C25 C26 . 1.372(7) no
    C25 H25 . 0.9300 no
    C26 C27 . 1.376(7) no
    C26 H26 . 0.9300 no
    C27 C28 . 1.369(7) no
    C27 H27 . 0.9300 no
    C28 H28 . 0.9300 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O2 Ni1 O4 . . 90.30(10)
                          yes
    O2 Ni1 N1 . . 153.60(10)
                           yes
    O2 Ni1 N2 . . 77.50(10)
                          yes
    O2 Ni1 N4 . . 93.20(10)
                          yes
    O2 Ni1 N5 . . 99.90(10)
                          yes
    O4 Ni1 N1 . . 90.60(10)
                          yes
    O4 Ni1 N2 . . 102.80(10)
                           yes
    O4 Ni1 N4 . . 155.30(10)
                           yes
    O4 Ni1 N5 . . 77.20(10)
                          yes
    N1 Ni1 N2 . . 76.60(10)
                          yes
    N1 Ni1 N4 . . 97.00(10)
                          yes
    N1 Ni1 N5 . . 106.00(10)
                           yes
    N2 Ni1 N4 . . 101.90(10)
                           yes
    N2 Ni1 N5 . . 177.50(10)
                           yes
    N4 Ni1 N5 . . 78.10(10)
                          yes
    O8 S1 O9 . . 109.1(2) yes
    O8 S1 O10 . . 106.6(2) yes
    O8 S1 O11 . . 110.5(2) yes
    O9 S1 O10 . . 110.5(2) yes
    O9 S1 O11 . . 110.4(2) yes
    O10 S1 O11 . . 109.7(2) no
    N1 O1 H2o . . 109.5 no
    C5 O2 Ni1 . . 112.1(2) no
    N4 O3 H3o . . 109.5 no
    C16 O4 Ni1 . . 113.9(2) no
    N7 O5 H5o . . 109.5 no
    C24 O7 H7O . . 109.5 no
    C2 N1 O1 . . 113.0(3) no
    C2 N1 Ni1 . . 114.0(2) no
    O1 N1 Ni1 . . 132.7(2) no
    C3 N2 N3 . . 123.3(3) no
    C3 N2 Ni1 . . 121.4(2) no
    N3 N2 Ni1 . . 115.3(2) no
    C5 N3 N2 . . 113.7(3) no
    C5 N3 H3n . . 123.1 no
    N2 N3 H3n . . 123.1 no
    C13 N4 O3 . . 113.2(3) no
    C13 N4 Ni1 . . 113.4(2) no
    O3 N4 Ni1 . . 133.3(2) no
    C14 N5 N6 . . 125.4(3) no
    C14 N5 Ni1 . . 119.5(2) no
    N6 N5 Ni1 . . 115.1(2) no
    C16 N6 N5 . . 113.8(3) no
    C16 N6 H6n . . 123.1 no
    N5 N6 H6n . . 123.1 no
    C29 N7 O5 . . 119.2(3) no
    C29 N7 H7n . . 120.4 no
    O5 N7 H7n . . 120.4 no
    C2 C1 H1a . . 109.5 no
    C2 C1 H1b . . 109.5 no
    H1a C1 H1b . . 109.5 no
    C2 C1 H1c . . 109.5 no
    H1a C1 H1c . . 109.5 no
    H1b C1 H1c . . 109.5 no
    N1 C2 C1 . . 124.2(3) no
    N1 C2 C3 . . 114.8(3) no
    C1 C2 C3 . . 121.0(3) no
    N2 C3 C4 . . 126.1(3) no
    N2 C3 C2 . . 112.8(3) no
    C4 C3 C2 . . 121.1(3) no
    C3 C4 H4a . . 109.5 no
    C3 C4 H4b . . 109.5 no
    H4a C4 H4b . . 109.5 no
    C3 C4 H4c . . 109.5 no
    H4a C4 H4c . . 109.5 no
    H4b C4 H4c . . 109.5 no
    O2 C5 N3 . . 120.7(3) no
    O2 C5 C6 . . 122.1(3) no
    N3 C5 C6 . . 117.1(3) no
    C11 C6 C7 . . 119.4(4) no
    C11 C6 C5 . . 118.7(3) no
    C7 C6 C5 . . 121.8(3) no
    C8 C7 C6 . . 119.9(4) no
    C8 C7 H7 . . 120.0 no
    C6 C7 H7 . . 120.0 no
    C9 C8 C7 . . 120.5(5) no
    C9 C8 H8 . . 119.7 no
    C7 C8 H8 . . 119.7 no
    C8 C9 C10 . . 120.1(4) no
    C8 C9 H9 . . 119.9 no
    C10 C9 H9 . . 119.9 no
    C9 C10 C11 . . 120.1(5) no
    C9 C10 H10 . . 119.9 no
    C11 C10 H10 . . 119.9 no
    C6 C11 C10 . . 119.9(4) no
    C6 C11 H11 . . 120.1 no
    C10 C11 H11 . . 120.1 no
    C13 C12 H12a . . 109.5 no
    C13 C12 H12b . . 109.5 no
    H12a C12 H12b . . 109.5 no
    C13 C12 H12c . . 109.5 no
    H12a C12 H12c . . 109.5 no
    H12b C12 H12c . . 109.5 no
    N4 C13 C12 . . 123.2(3) no
    N4 C13 C14 . . 115.5(3) no
    C12 C13 C14 . . 121.3(3) no
    N5 C14 C15 . . 126.0(3) no
    N5 C14 C13 . . 113.1(3) no
    C15 C14 C13 . . 120.9(3) no
    C14 C15 H15a . . 109.5 no
    C14 C15 H15b . . 109.5 no
    H15a C15 H15b . . 109.5 no
    C14 C15 H15c . . 109.5 no
    H15a C15 H15c . . 109.5 no
    H15b C15 H15c . . 109.5 no
    O4 C16 N6 . . 120.0(3) no
    O4 C16 C17 . . 119.9(3) no
    N6 C16 C17 . . 120.1(3) no
    C18 C17 C22 . . 119.0(4) no
    C18 C17 C16 . . 122.9(4) no
    C22 C17 C16 . . 118.0(3) no
    C17 C18 C19 . . 120.1(4) no
    C17 C18 H18 . . 120.0 no
    C19 C18 H18 . . 120.0 no
    C20 C19 C18 . . 120.2(4) no
    C20 C19 H19 . . 119.9 no
    C18 C19 H19 . . 119.9 no
    C19 C20 C21 . . 120.0(4) no
    C19 C20 H20 . . 120.0 no
    C21 C20 H20 . . 120.0 no
    C22 C21 C20 . . 120.1(5) no
    C22 C21 H21 . . 120.0 no
    C20 C21 H21 . . 120.0 no
    C21 C22 C17 . . 120.6(4) no
    C21 C22 H22 . . 119.7 no
    C17 C22 H22 . . 119.7 no
    C28 C23 C24 . . 117.9(4) no
    C28 C23 C29 . . 116.6(3) no
    C24 C23 C29 . . 125.4(4) no
    O7 C24 C25 . . 121.1(4) no
    O7 C24 C23 . . 119.2(4) no
    C25 C24 C23 . . 119.6(4) no
    C26 C25 C24 . . 120.5(4) no
    C26 C25 H25 . . 119.7 no
    C24 C25 H25 . . 119.7 no
    C25 C26 C27 . . 120.6(5) no
    C25 C26 H26 . . 119.7 no
    C27 C26 H26 . . 119.7 no
    C28 C27 C26 . . 119.5(5) no
    C28 C27 H27 . . 120.3 no
    C26 C27 H27 . . 120.3 no
    C27 C28 C23 . . 121.8(4) no
    C27 C28 H28 . . 119.1 no
    C23 C28 H28 . . 119.1 no
    O6 C29 N7 . . 121.9(4) no
    O6 C29 C23 . . 121.7(4) no
    N7 C29 C23 . . 116.3(3) no
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    O1 H2o O8 . 0.82 1.76 2.569(4) 171 yes
    O3 H3o O10 4_576 0.82 1.86 2.626(4) 156 yes
    N3 H3n O11 4_576 0.86 2.06 2.707(4) 132 yes
    N6 H6n O6 . 0.86 2.13 2.975(4) 170 yes
    O5 H5o O10 . 0.82 2.00 2.771(4) 157 yes
    O7 H7o O9 4_575 0.82 1.83 2.639(4) 168 yes
    N7 H7n O7 . 0.86 1.98 2.634(5) 132 yes
data_global
_journal_data_validation_number     ?
_journal_date_recd_electronic     2004-10-21
_journal_date_accepted     2004-10-25
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2004
_journal_volume     60
_journal_issue     12
_journal_page_first     m1750
_journal_page_last     m1751
_journal_paper_category     EM
_publ_contact_author_name     'Dr Seik Weng Ng'
_publ_contact_author_address
;
 Department of Chemistry
 University of Malaya
 50603 Kuala Lumpur
 Malaysia
;
_publ_contact_author_email     seikweng@um.edu.my
_publ_contact_author_fax     '603 7967 6778'
_publ_contact_author_phone     '603 7967 4193'
_publ_section_title
;
Bis(butane-2,3-dione monooxime benzoylhydrazone-κ³O,N,N')nickel(II) sulfate
salicylhydroxamic acid
;
loop_
    _publ_author_name
    _publ_author_address
    'Gao, Shan'
;
College of Chemistry and Chemical Technology
Heilongjiang University
Harbin 150080
People's Republic of China
;
    'Huo, Li-Hua'
;
College of Chemistry and Chemical Technology
Heilongjiang University
Harbin 150080
People's Republic of China
;
    'Zhao, Hui'
;
College of Chemistry and Chemical Technology
Heilongjiang University
Harbin 150080
People's Republic of China
;
    'Ng, Seik Weng'
;
Department of Chemistry
University of Malaya
Kuala Lumpur 50603
Malaysia
;
