##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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#                                                                            #
#            Copyright International Union of Crystallography                #
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##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
μ-Chloro-μ-hydrido-bis[chloro(η⁶-p-cymene)ruthenium(II)](Ru---Ru)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C20 H29 Cl3 Ru2'
_chemical_formula_sum     'C20 H29 Cl3 Ru2'
_chemical_formula_iupac     '[Ru2 (C10 H14) Cl4 H]'
_chemical_formula_weight     577.92
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'C 2/c'
_symmetry_space_group_name_Hall     '-C 2yc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y, -z+1/2'
    'x+1/2, y+1/2, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y, z-1/2'
    '-x+1/2, -y+1/2, -z'
    'x+1/2, -y+1/2, z-1/2'
_cell_length_a     14.782(3)
_cell_length_b     17.431(3)
_cell_length_c     10.425(2)
_cell_angle_alpha     90.00
_cell_angle_beta     124.16(3)
_cell_angle_gamma     90.00
_cell_volume     2222.7(11)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     8000
_cell_measurement_theta_min     1.95
_cell_measurement_theta_max     25.90
_cell_measurement_temperature     153(2)
_exptl_crystal_description     block
_exptl_crystal_colour     orange
_exptl_crystal_size_max     0.36
_exptl_crystal_size_mid     0.22
_exptl_crystal_size_min     0.14
_exptl_crystal_density_diffrn     1.727
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1152
_exptl_absorpt_coefficient_mu     1.721
_exptl_absorpt_correction_type     'multi-scan'
_exptl_absorpt_process_details     '(Blessing, 1995)'
_exptl_absorpt_correction_T_min     0.500
_exptl_absorpt_correction_T_max     0.786
_exptl_special_details
;
A crystal was mounted at 153K on a Stoe Image Plate Diffraction
System (Stoe & Cie, 2000) using MoKα graphite monochromated
radiation.  Image plate distance 70mm, φ oscillation scans
0 - 200°, step Δφ = 1.3°, 4 minutes per frame.
;
_diffrn_ambient_temperature     153(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Stoe IPDS'
_diffrn_measurement_method     'phi oscillation'
_diffrn_detector_area_resol_mean     7
_diffrn_reflns_number     8650
_diffrn_reflns_av_R_equivalents     0.0402
_diffrn_reflns_av_sigmaI/netI     0.0328
_diffrn_reflns_theta_min     2.03
_diffrn_reflns_theta_max     25.92
_diffrn_reflns_theta_full     25.92
_diffrn_measured_fraction_theta_max     0.997
_diffrn_measured_fraction_theta_full     0.997
_diffrn_reflns_limit_h_min     -18
_diffrn_reflns_limit_h_max     18
_diffrn_reflns_limit_k_min     -21
_diffrn_reflns_limit_k_max     21
_diffrn_reflns_limit_l_min     -12
_diffrn_reflns_limit_l_max     12
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     2163
_reflns_number_gt     1749
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0308
_refine_ls_R_factor_gt     0.0216
_refine_ls_wR_factor_gt     0.0473
_refine_ls_wR_factor_ref     0.0487
_refine_ls_goodness_of_fit_ref     0.919
_refine_ls_restrained_S_all     0.919
_refine_ls_number_reflns     2163
_refine_ls_number_parameters     119
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
             'calc w = 1/[σ²(Fo²)+(0.0296P)²] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.437
_refine_diff_density_min     -0.546
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ru' 'Ru' -1.2594 0.8363
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'EXPOSE in IPDS Software (Stoe & Cie, 2000)'
_computing_cell_refinement     'CELL in IPDS Software'
_computing_data_reduction     'INTEGRATE in IPDS Software'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material     SHELXL97
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    C1 0.3847(2) 0.78352(15) 0.9196(3) 0.0263(6) Uani d . 1 . . C
    C2 0.3847(2) 0.85723(15) 0.9801(3) 0.0259(6) Uani d . 1 . . C
    H2 0.4188 0.8630 1.0864 0.031 Uiso calc R 1 . . H
    C3 0.3345(2) 0.92090(15) 0.8831(3) 0.0252(6) Uani d . 1 . . C
    H3 0.3359 0.9682 0.9255 0.030 Uiso calc R 1 . . H
    C4 0.2816(2) 0.91355(15) 0.7203(3) 0.0248(6) Uani d . 1 . . C
    C5 0.2793(2) 0.84124(16) 0.6584(3) 0.0272(6) Uani d . 1 . . C
    H5 0.2441 0.8354 0.5519 0.033 Uiso calc R 1 . . H
    C6 0.3305(2) 0.77736(15) 0.7578(3) 0.0276(6) Uani d . 1 . . C
    H6 0.3283 0.7300 0.7149 0.033 Uiso calc R 1 . . H
    C7 0.4418(2) 0.71652(16) 1.0281(4) 0.0340(7) Uani d . 1 . . C
    H7 0.5035 0.7366 1.1268 0.041 Uiso calc R 1 . . H
    C8 0.4861(3) 0.6584(2) 0.9682(5) 0.0550(10) Uani d . 1 . . C
    H8A 0.4263 0.6330 0.8787 0.083 Uiso calc R 1 . . H
    H8B 0.5297 0.6212 1.0475 0.083 Uiso calc R 1 . . H
    H8C 0.5302 0.6841 0.9405 0.083 Uiso calc R 1 . . H
    C9 0.3621(2) 0.67815(17) 1.0585(4) 0.0382(7) Uani d . 1 . . C
    H9A 0.3412 0.7143 1.1068 0.057 Uiso calc R 1 . . H
    H9B 0.3970 0.6348 1.1256 0.057 Uiso calc R 1 . . H
    H9C 0.2983 0.6614 0.9620 0.057 Uiso calc R 1 . . H
    C10 0.2327(2) 0.98243(17) 0.6166(4) 0.0359(7) Uani d . 1 . . C
    H10A 0.2270 0.9730 0.5216 0.054 Uiso calc R 1 . . H
    H10B 0.2785 1.0263 0.6676 0.054 Uiso calc R 1 . . H
    H10C 0.1613 0.9921 0.5944 0.054 Uiso calc R 1 . . H
    Cl1 0.63021(5) 0.86511(4) 1.07444(7) 0.02769(14) Uani d . 1 . . Cl
    Cl2 0.5000 0.97755(5) 0.7500 0.02193(18) Uani d S 1 . . Cl
    Ru1 0.448829(15) 0.869002(11) 0.83789(2) 0.01906(7) Uani d . 1 . . Ru
    H1 0.5000 0.820(2) 0.7500 0.024(10) Uiso d S 1 . . H
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 C6 . 1.407(4) ?
    C1 C2 . 1.432(4) ?
    C1 C7 . 1.511(4) ?
    C1 Ru1 . 2.180(3) ?
    C2 C3 . 1.401(4) ?
    C2 Ru1 . 2.173(2) ?
    C2 H2 . 0.9300 ?
    C3 C4 . 1.421(4) ?
    C3 Ru1 . 2.189(2) ?
    C3 H3 . 0.9300 ?
    C4 C5 . 1.408(4) ?
    C4 C10 . 1.502(4) ?
    C4 Ru1 . 2.194(3) ?
    C5 C6 . 1.416(4) ?
    C5 Ru1 . 2.179(3) ?
    C5 H5 . 0.9300 ?
    C6 Ru1 . 2.160(3) ?
    C6 H6 . 0.9300 ?
    C7 C8 . 1.518(4) ?
    C7 C9 . 1.534(4) ?
    C7 H7 . 0.9800 ?
    C8 H8A . 0.9600 ?
    C8 H8B . 0.9600 ?
    C8 H8C . 0.9600 ?
    C9 H9A . 0.9600 ?
    C9 H9B . 0.9600 ?
    C9 H9C . 0.9600 ?
    C10 H10A . 0.9600 ?
    C10 H10B . 0.9600 ?
    C10 H10C . 0.9600 ?
    Cl1 Ru1 . 2.4185(14) yes
    Cl2 Ru1 2_656 2.4021(7) ?
    Cl2 Ru1 . 2.4021(7) yes
    Ru1 Ru1 2_656 2.9598(7) yes
    Ru1 H1 . 1.711(18) yes
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C6 C1 C2 . . 117.1(2) ?
    C6 C1 C7 . . 122.8(3) ?
    C2 C1 C7 . . 120.1(2) ?
    C6 C1 Ru1 . . 70.33(15) ?
    C2 C1 Ru1 . . 70.53(14) ?
    C7 C1 Ru1 . . 129.64(18) ?
    C3 C2 C1 . . 121.6(2) ?
    C3 C2 Ru1 . . 71.90(14) ?
    C1 C2 Ru1 . . 71.06(14) ?
    C3 C2 H2 . . 119.2 ?
    C1 C2 H2 . . 119.2 ?
    Ru1 C2 H2 . . 130.6 ?
    C2 C3 C4 . . 120.3(2) ?
    C2 C3 Ru1 . . 70.64(14) ?
    C4 C3 Ru1 . . 71.28(14) ?
    C2 C3 H3 . . 119.9 ?
    C4 C3 H3 . . 119.9 ?
    Ru1 C3 H3 . . 130.9 ?
    C5 C4 C3 . . 118.9(2) ?
    C5 C4 C10 . . 120.5(2) ?
    C3 C4 C10 . . 120.5(2) ?
    C5 C4 Ru1 . . 70.63(15) ?
    C3 C4 Ru1 . . 70.89(14) ?
    C10 C4 Ru1 . . 128.40(18) ?
    C4 C5 C6 . . 120.2(2) ?
    C4 C5 Ru1 . . 71.81(15) ?
    C6 C5 Ru1 . . 70.24(15) ?
    C4 C5 H5 . . 119.9 ?
    C6 C5 H5 . . 119.9 ?
    Ru1 C5 H5 . . 130.7 ?
    C1 C6 C5 . . 121.8(2) ?
    C1 C6 Ru1 . . 71.83(15) ?
    C5 C6 Ru1 . . 71.67(15) ?
    C1 C6 H6 . . 119.1 ?
    C5 C6 H6 . . 119.1 ?
    Ru1 C6 H6 . . 130.1 ?
    C1 C7 C8 . . 113.4(3) ?
    C1 C7 C9 . . 108.7(2) ?
    C8 C7 C9 . . 110.6(3) ?
    C1 C7 H7 . . 108.0 ?
    C8 C7 H7 . . 108.0 ?
    C9 C7 H7 . . 108.0 ?
    C7 C8 H8A . . 109.5 ?
    C7 C8 H8B . . 109.5 ?
    H8A C8 H8B . . 109.5 ?
    C7 C8 H8C . . 109.5 ?
    H8A C8 H8C . . 109.5 ?
    H8B C8 H8C . . 109.5 ?
    C7 C9 H9A . . 109.5 ?
    C7 C9 H9B . . 109.5 ?
    H9A C9 H9B . . 109.5 ?
    C7 C9 H9C . . 109.5 ?
    H9A C9 H9C . . 109.5 ?
    H9B C9 H9C . . 109.5 ?
    C4 C10 H10A . . 109.5 ?
    C4 C10 H10B . . 109.5 ?
    H10A C10 H10B . . 109.5 ?
    C4 C10 H10C . . 109.5 ?
    H10A C10 H10C . . 109.5 ?
    H10B C10 H10C . . 109.5 ?
    Ru1 Cl2 Ru1 2_656 . 76.06(3) yes
    C6 Ru1 C2 . . 67.99(10) ?
    C6 Ru1 C5 . . 38.09(10) ?
    C2 Ru1 C5 . . 80.38(10) ?
    C6 Ru1 C1 . . 37.84(10) ?
    C2 Ru1 C1 . . 38.41(10) ?
    C5 Ru1 C1 . . 68.96(10) ?
    C6 Ru1 C3 . . 80.43(10) ?
    C2 Ru1 C3 . . 37.47(10) ?
    C5 Ru1 C3 . . 67.80(10) ?
    C1 Ru1 C3 . . 68.94(10) ?
    C6 Ru1 C4 . . 68.42(10) ?
    C2 Ru1 C4 . . 68.17(10) ?
    C5 Ru1 C4 . . 37.56(10) ?
    C1 Ru1 C4 . . 81.92(10) ?
    C3 Ru1 C4 . . 37.83(10) ?
    C6 Ru1 Cl2 . . 142.64(8) ?
    C2 Ru1 Cl2 . . 133.35(7) ?
    C5 Ru1 Cl2 . . 107.69(8) ?
    C1 Ru1 Cl2 . . 170.65(7) ?
    C3 Ru1 Cl2 . . 101.72(7) ?
    C4 Ru1 Cl2 . . 90.31(7) ?
    C6 Ru1 Cl1 . . 124.52(8) ?
    C2 Ru1 Cl1 . . 87.72(8) ?
    C5 Ru1 Cl1 . . 162.02(8) ?
    C1 Ru1 Cl1 . . 93.37(7) ?
    C3 Ru1 Cl1 . . 109.87(8) ?
    C4 Ru1 Cl1 . . 146.70(7) ?
    Cl2 Ru1 Cl1 . . 90.28(2) yes
    C6 Ru1 Ru1 . 2_656 110.17(7) ?
    C2 Ru1 Ru1 . 2_656 173.41(7) ?
    C5 Ru1 Ru1 . 2_656 102.08(7) ?
    C1 Ru1 Ru1 . 2_656 136.68(7) ?
    C3 Ru1 Ru1 . 2_656 149.12(7) ?
    C4 Ru1 Ru1 . 2_656 117.47(7) ?
    Cl2 Ru1 Ru1 . 2_656 51.969(14) ?
    Cl1 Ru1 Ru1 . 2_656 88.39(3) ?
    C6 Ru1 H1 . . 85.8(8) ?
    C2 Ru1 H1 . . 144.3(10) ?
    C5 Ru1 H1 . . 94.0(3) ?
    C1 Ru1 H1 . . 106.6(10) ?
    C3 Ru1 H1 . . 161.7(3) ?
    C4 Ru1 H1 . . 125.22(12) ?
    Cl2 Ru1 H1 . . 82.1(10) yes
    Cl1 Ru1 H1 . . 87.80(3) yes
    Ru1 Ru1 H1 2_656 . 30.1(10) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C6 C1 C2 C3 . . . . -1.0(4) ?
    C7 C1 C2 C3 . . . . 178.6(2) ?
    Ru1 C1 C2 C3 . . . . 53.4(2) ?
    C6 C1 C2 Ru1 . . . . -54.4(2) ?
    C7 C1 C2 Ru1 . . . . 125.2(2) ?
    C1 C2 C3 C4 . . . . 0.2(4) ?
    Ru1 C2 C3 C4 . . . . 53.2(2) ?
    C1 C2 C3 Ru1 . . . . -53.0(2) ?
    C2 C3 C4 C5 . . . . 0.8(3) ?
    Ru1 C3 C4 C5 . . . . 53.7(2) ?
    C2 C3 C4 C10 . . . . -176.9(2) ?
    Ru1 C3 C4 C10 . . . . -124.0(2) ?
    C2 C3 C4 Ru1 . . . . -52.9(2) ?
    C3 C4 C5 C6 . . . . -0.9(4) ?
    C10 C4 C5 C6 . . . . 176.7(2) ?
    Ru1 C4 C5 C6 . . . . 52.9(2) ?
    C3 C4 C5 Ru1 . . . . -53.8(2) ?
    C10 C4 C5 Ru1 . . . . 123.9(2) ?
    C2 C1 C6 C5 . . . . 0.9(4) ?
    C7 C1 C6 C5 . . . . -178.7(2) ?
    Ru1 C1 C6 C5 . . . . -53.6(2) ?
    C2 C1 C6 Ru1 . . . . 54.5(2) ?
    C7 C1 C6 Ru1 . . . . -125.1(2) ?
    C4 C5 C6 C1 . . . . 0.1(4) ?
    Ru1 C5 C6 C1 . . . . 53.7(2) ?
    C4 C5 C6 Ru1 . . . . -53.6(2) ?
    C6 C1 C7 C8 . . . . 29.5(4) ?
    C2 C1 C7 C8 . . . . -150.1(3) ?
    Ru1 C1 C7 C8 . . . . -61.3(3) ?
    C6 C1 C7 C9 . . . . -93.9(3) ?
    C2 C1 C7 C9 . . . . 86.5(3) ?
    Ru1 C1 C7 C9 . . . . 175.3(2) ?
    C1 C6 Ru1 C2 . . . . -30.98(15) ?
    C5 C6 Ru1 C2 . . . . 102.92(17) ?
    C1 C6 Ru1 C5 . . . . -133.9(2) ?
    C5 C6 Ru1 C1 . . . . 133.9(2) ?
    C1 C6 Ru1 C3 . . . . -67.85(16) ?
    C5 C6 Ru1 C3 . . . . 66.05(16) ?
    C1 C6 Ru1 C4 . . . . -105.23(17) ?
    C5 C6 Ru1 C4 . . . . 28.68(15) ?
    C1 C6 Ru1 Cl2 . . . . -164.67(12) ?
    C5 C6 Ru1 Cl2 . . . . -30.8(2) ?
    C1 C6 Ru1 Cl1 . . . . 39.75(18) ?
    C5 C6 Ru1 Cl1 . . . . 173.65(12) ?
    C1 C6 Ru1 Ru1 . . . 2_656 142.24(14) ?
    C5 C6 Ru1 Ru1 . . . 2_656 -83.86(15) ?
    C3 C2 Ru1 C6 . . . . -103.45(17) ?
    C1 C2 Ru1 C6 . . . . 30.55(15) ?
    C3 C2 Ru1 C5 . . . . -65.87(16) ?
    C1 C2 Ru1 C5 . . . . 68.13(16) ?
    C3 C2 Ru1 C1 . . . . -134.0(2) ?
    C1 C2 Ru1 C3 . . . . 134.0(2) ?
    C3 C2 Ru1 C4 . . . . -28.83(15) ?
    C1 C2 Ru1 C4 . . . . 105.17(17) ?
    C3 C2 Ru1 Cl2 . . . . 39.44(19) ?
    C1 C2 Ru1 Cl2 . . . . 173.44(12) ?
    C3 C2 Ru1 Cl1 . . . . 127.67(15) ?
    C1 C2 Ru1 Cl1 . . . . -98.33(15) ?
    C4 C5 Ru1 C6 . . . . 132.9(2) ?
    C4 C5 Ru1 C2 . . . . 66.51(16) ?
    C6 C5 Ru1 C2 . . . . -66.42(16) ?
    C4 C5 Ru1 C1 . . . . 104.67(17) ?
    C6 C5 Ru1 C1 . . . . -28.27(15) ?
    C4 C5 Ru1 C3 . . . . 29.67(15) ?
    C6 C5 Ru1 C3 . . . . -103.26(17) ?
    C6 C5 Ru1 C4 . . . . -132.9(2) ?
    C4 C5 Ru1 Cl2 . . . . -66.08(15) ?
    C6 C5 Ru1 Cl2 . . . . 160.99(13) ?
    C4 C5 Ru1 Cl1 . . . . 115.8(2) ?
    C6 C5 Ru1 Cl1 . . . . -17.2(3) ?
    C4 C5 Ru1 Ru1 . . . 2_656 -119.70(14) ?
    C6 C5 Ru1 Ru1 . . . 2_656 107.36(14) ?
    C2 C1 Ru1 C6 . . . . -129.8(2) ?
    C7 C1 Ru1 C6 . . . . 116.7(3) ?
    C6 C1 Ru1 C2 . . . . 129.8(2) ?
    C7 C1 Ru1 C2 . . . . -113.5(3) ?
    C6 C1 Ru1 C5 . . . . 28.44(15) ?
    C2 C1 Ru1 C5 . . . . -101.37(17) ?
    C7 C1 Ru1 C5 . . . . 145.2(3) ?
    C6 C1 Ru1 C3 . . . . 101.84(17) ?
    C2 C1 Ru1 C3 . . . . -27.96(15) ?
    C7 C1 Ru1 C3 . . . . -141.4(3) ?
    C6 C1 Ru1 C4 . . . . 65.00(16) ?
    C2 C1 Ru1 C4 . . . . -64.81(16) ?
    C7 C1 Ru1 C4 . . . . -178.3(3) ?
    C6 C1 Ru1 Cl1 . . . . -148.15(15) ?
    C2 C1 Ru1 Cl1 . . . . 82.04(15) ?
    C7 C1 Ru1 Cl1 . . . . -31.4(3) ?
    C6 C1 Ru1 Ru1 . . . 2_656 -56.92(19) ?
    C2 C1 Ru1 Ru1 . . . 2_656 173.28(12) ?
    C7 C1 Ru1 Ru1 . . . 2_656 59.8(3) ?
    C2 C3 Ru1 C6 . . . . 66.13(16) ?
    C4 C3 Ru1 C6 . . . . -66.99(16) ?
    C4 C3 Ru1 C2 . . . . -133.1(2) ?
    C2 C3 Ru1 C5 . . . . 103.64(17) ?
    C4 C3 Ru1 C5 . . . . -29.48(16) ?
    C2 C3 Ru1 C1 . . . . 28.62(15) ?
    C4 C3 Ru1 C1 . . . . -104.50(17) ?
    C2 C3 Ru1 C4 . . . . 133.1(2) ?
    C2 C3 Ru1 Cl2 . . . . -151.85(14) ?
    C4 C3 Ru1 Cl2 . . . . 75.03(15) ?
    C2 C3 Ru1 Cl1 . . . . -57.25(16) ?
    C4 C3 Ru1 Cl1 . . . . 169.63(13) ?
    C2 C3 Ru1 Ru1 . . . 2_656 179.65(12) ?
    C4 C3 Ru1 Ru1 . . . 2_656 46.5(2) ?
    C5 C4 Ru1 C6 . . . . -29.06(16) ?
    C3 C4 Ru1 C6 . . . . 102.57(17) ?
    C10 C4 Ru1 C6 . . . . -143.2(3) ?
    C5 C4 Ru1 C2 . . . . -103.05(17) ?
    C3 C4 Ru1 C2 . . . . 28.58(15) ?
    C10 C4 Ru1 C2 . . . . 142.8(3) ?
    C3 C4 Ru1 C5 . . . . 131.6(2) ?
    C10 C4 Ru1 C5 . . . . -114.1(3) ?
    C5 C4 Ru1 C1 . . . . -65.78(16) ?
    C3 C4 Ru1 C1 . . . . 65.85(16) ?
    C10 C4 Ru1 C1 . . . . -179.9(3) ?
    C5 C4 Ru1 C3 . . . . -131.6(2) ?
    C10 C4 Ru1 C3 . . . . 114.2(3) ?
    C5 C4 Ru1 Cl2 . . . . 119.44(15) ?
    C3 C4 Ru1 Cl2 . . . . -108.93(14) ?
    C10 C4 Ru1 Cl2 . . . . 5.3(2) ?
    C5 C4 Ru1 Cl1 . . . . -149.58(13) ?
    C3 C4 Ru1 Cl1 . . . . -18.0(2) ?
    C10 C4 Ru1 Cl1 . . . . 96.3(3) ?
    C5 C4 Ru1 Ru1 . . . 2_656 73.20(16) ?
    C3 C4 Ru1 Ru1 . . . 2_656 -155.17(13) ?
    C10 C4 Ru1 Ru1 . . . 2_656 -40.9(3) ?
    Ru1 Cl2 Ru1 C6 2_656 . . . -72.35(12) ?
    Ru1 Cl2 Ru1 C2 2_656 . . . 174.87(10) ?
    Ru1 Cl2 Ru1 C5 2_656 . . . -91.69(8) ?
    Ru1 Cl2 Ru1 C3 2_656 . . . -161.89(7) ?
    Ru1 Cl2 Ru1 C4 2_656 . . . -125.55(7) ?
    Ru1 Cl2 Ru1 Cl1 2_656 . . . 87.74(2) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C3 H3 Cl1 5_677 0.93 2.95 3.758(3) 146
    C10 H10B Cl1 5_677 0.96 2.93 3.770(3) 147
    C6 H6 Cl1 8_465 0.93 2.94 3.498(3) 120
data_global
_journal_date_recd_electronic     2004-10-04
_journal_date_accepted     2004-10-13
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2004
_journal_volume     60
_journal_issue     11
_journal_page_first     m1666
_journal_page_last     m1668
_journal_paper_category     EM
_publ_contact_author
;
      Süss-Fink, Georg
      Institut de Chimie,
      Université de Neuchâtel,
      Case postale 2,
      CH-2007 Neuchâtel,
      Switzerland
;
_publ_contact_author_email     bruno.therrien@unine.ch
_publ_contact_author_fax     '+41 32 718 2511'
_publ_contact_author_phone     '+41 32 718 2499'
_publ_section_title
;
μ-Chloro-μ-hydrido-bis[chloro(η⁶-p-cymene)ruthenium(II)](Ru---Ru)
;
loop_
    _publ_author_name
    _publ_author_address
    'Therrien, Bruno'
;
      Institut de Chimie,
      Université de Neuchâtel,
      Case postale 2,
      CH-2007 Neuchâtel,
      Switzerland
;
    'Frein,  Stéphane'
;
      Institut de Chimie,
      Université de Neuchâtel,
      Case postale 2,
      CH-2007 Neuchâtel,
      Switzerland
;
    'Süss-Fink, Georg'
;
      Institut de Chimie,
      Université de Neuchâtel,
      Case postale 2,
      CH-2007 Neuchâtel,
      Switzerland
;
