##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
[5-Bromo-N-(2-pyridylethylsulfanylethyl)salicylideneiminato-
κ⁴N,N',O,S]copper(II) perchlorate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C16 H16 Br Cu N2 O S + , Cl O4 -'
_chemical_formula_sum     'C16 H16 Br Cl Cu N2 O5 S'
_chemical_formula_iupac     '[Cu (C16 H16 Br N2 O S)] Cl O4'
_chemical_formula_weight     527.27
_chemical_melting_point     ?
_symmetry_cell_setting     Monoclinic
_symmetry_space_group_name_H-M     'P 21/n'
_symmetry_space_group_name_Hall     '-P 2yn'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    'x+1/2, -y+1/2, z+1/2'
    '-x, -y, -z'
    '-x-1/2, y-1/2, -z-1/2'
_cell_length_a     9.9542(6)
_cell_length_b     8.8479(6)
_cell_length_c     21.2230(10)
_cell_angle_alpha     90.00
_cell_angle_beta     102.2630(10)
_cell_angle_gamma     90.00
_cell_volume     1826.5(2)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     5071
_cell_measurement_theta_min     2.5
_cell_measurement_theta_max     26.4
_cell_measurement_temperature     113(2)
_exptl_crystal_description     plate
_exptl_crystal_colour     blue
_exptl_crystal_size_max     0.45
_exptl_crystal_size_mid     0.43
_exptl_crystal_size_min     0.15
_exptl_crystal_density_diffrn     1.917
_exptl_crystal_density_meas     'not measured'
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1052
_exptl_absorpt_coefficient_mu     3.676
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2001)'
_exptl_absorpt_correction_T_min     0.145
_exptl_absorpt_correction_T_max     0.576
_exptl_special_details
;
A value of μ*2r of 1.40 was used during the data reduction.
;
_diffrn_ambient_temperature     113(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'medium-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Siemens P4 CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     9902
_diffrn_reflns_av_R_equivalents     0.057
_diffrn_reflns_av_sigmaI/netI     0.086
_diffrn_reflns_theta_min     2.5
_diffrn_reflns_theta_max     26.5
_diffrn_reflns_theta_full     26.5
_diffrn_measured_fraction_theta_max     0.96
_diffrn_measured_fraction_theta_full     0.96
_diffrn_reflns_limit_h_min     -12
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -11
_diffrn_reflns_limit_k_max     11
_diffrn_reflns_limit_l_min     -23
_diffrn_reflns_limit_l_max     26
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_reflns_number_total     3657
_reflns_number_gt     2645
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.078
_refine_ls_R_factor_gt     0.039
_refine_ls_wR_factor_gt     0.092
_refine_ls_wR_factor_ref     0.107
_refine_ls_goodness_of_fit_ref     0.99
_refine_ls_restrained_S_all     0.99
_refine_ls_number_reflns     3657
_refine_ls_number_parameters     244
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
               'calc w = 1/[σ²(Fo²)+(0.0558P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.72
_refine_diff_density_min     -1.49
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cu' 'Cu' 0.3201 1.2651
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Br' 'Br' -0.2901 2.4595
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 2001)'
_computing_cell_refinement     'SAINT (Bruker, 2001)'
_computing_data_reduction     SAINT
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEPII (Johnson, 1976)'
_computing_publication_material     SHELXL97
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Br1 1.08500(5) 0.36859(5) 0.63028(2) 0.0279(2) Uani d . 1 . . Br
    Cu1 0.42616(6) 0.76314(5) 0.56498(2) 0.0158(2) Uani d . 1 . . Cu
    S1 0.23320(10)
                 0.78280(10)
                           0.61047(5) 0.0192(2) Uani d . 1 . . S
    Cl1 1.01140(10)
                  0.81830(10)
                            0.78729(5) 0.0229(3) Uani d . 1 . . Cl
    O1 0.5502(3) 0.6743(3) 0.52140(10)
                                     0.0190(10)
                                              Uani d . 1 . . O
    O2 1.0530(5) 0.6669(3) 0.7809(2) 0.063(2) Uani d . 1 . . O
    O3 0.8659(4) 0.8309(4) 0.7706(2) 0.0480(10)
                                              Uani d . 1 . . O
    O4 1.0685(4) 0.9126(4) 0.7449(2) 0.0390(10)
                                              Uani d . 1 . . O
    O5 1.0603(4) 0.8677(3) 0.85240(10)
                                     0.0400(10)
                                              Uani d . 1 . . O
    N1 0.5311(4) 0.7268(3) 0.6496(2) 0.0180(10)
                                              Uani d . 1 . . N
    N2 0.3370(4) 0.8818(3) 0.4893(2) 0.0160(10)
                                              Uani d . 1 . . N
    C1 0.6616(5) 0.6016(4) 0.5484(2) 0.0140(10)
                                              Uani d . 1 . . C
    C2 0.7373(5) 0.5297(4) 0.5074(2) 0.0170(10)
                                              Uani d . 1 . . C
    C3 0.8583(5) 0.4593(4) 0.5314(2) 0.0180(10)
                                              Uani d . 1 . . C
    C4 0.9124(5) 0.4577(4) 0.5976(2) 0.0160(10)
                                              Uani d . 1 . . C
    C5 0.8403(5) 0.5226(4) 0.6390(2) 0.0170(10)
                                              Uani d . 1 . . C
    C6 0.7149(5) 0.5932(4) 0.6150(2) 0.0140(10)
                                              Uani d . 1 . . C
    C7 0.6451(5) 0.6562(4) 0.6621(2) 0.0180(10)
                                              Uani d . 1 . . C
    C8 0.4716(5) 0.7855(5) 0.7027(2) 0.0220(10)
                                              Uani d . 1 . . C
    C9 0.3234(5) 0.7412(5) 0.6915(2) 0.0260(10)
                                              Uani d . 1 . . C
    C10 0.2092(5) 0.9869(4) 0.6091(2) 0.0230(10)
                                               Uani d . 1 . . C
    C11 0.2928(5) 1.0659(4) 0.5671(2) 0.0200(10)
                                               Uani d . 1 . . C
    C12 0.2693(5) 1.0085(4) 0.4990(2) 0.0180(10)
                                               Uani d . 1 . . C
    C13 0.1853(5) 1.0807(4) 0.4483(2) 0.0240(10)
                                               Uani d . 1 . . C
    C14 0.1752(6) 1.0268(5) 0.3863(2) 0.0310(10)
                                               Uani d . 1 . . C
    C15 0.2485(5) 0.9010(5) 0.3769(2) 0.0280(10)
                                               Uani d . 1 . . C
    C16 0.3267(5) 0.8301(4) 0.4293(2) 0.0230(10)
                                               Uani d . 1 . . C
    H2 0.7024 0.5308 0.4621 0.021 Uiso calc R 1 . . H
    H3 0.9066 0.4109 0.5029 0.021 Uiso calc R 1 . . H
    H5 0.8762 0.5194 0.6842 0.021 Uiso calc R 1 . . H
    H7 0.6881 0.6439 0.7062 0.021 Uiso calc R 1 . . H
    H8a 0.4800 0.8970 0.7047 0.027 Uiso calc R 1 . . H
    H8b 0.5220 0.7435 0.7443 0.027 Uiso calc R 1 . . H
    H9a 0.2791 0.7959 0.7223 0.032 Uiso calc R 1 . . H
    H9b 0.3167 0.6316 0.6997 0.032 Uiso calc R 1 . . H
    H10a 0.1106 1.0100 0.5928 0.028 Uiso calc R 1 . . H
    H10b 0.2361 1.0265 0.6536 0.028 Uiso calc R 1 . . H
    H11a 0.2709 1.1751 0.5660 0.024 Uiso calc R 1 . . H
    H11b 0.3916 1.0547 0.5872 0.024 Uiso calc R 1 . . H
    H13 0.1344 1.1673 0.4558 0.029 Uiso calc R 1 . . H
    H14 0.1182 1.0764 0.3507 0.037 Uiso calc R 1 . . H
    H15 0.2450 0.8635 0.3347 0.033 Uiso calc R 1 . . H
    H16 0.3756 0.7412 0.4228 0.028 Uiso calc R 1 . . H
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_22
    _atom_site_aniso_U_33
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_23
    Br1 0.0269(3) 0.0348(2) 0.0216(2) 0.0148(2) 0.0047(2) 0.0037(2)
    Cu1 0.0209(4) 0.0167(2) 0.0095(2) 0.0049(2) 0.0027(2) -0.00014(17)
    S1 0.0247(7) 0.0169(4) 0.0167(5) 0.0002(4) 0.0060(4) -0.0019(4)
    Cl1 0.0334(8) 0.0180(4) 0.0151(5) -0.0016(4) 0.0002(5) 0.0007(3)
    O1 0.023(2) 0.0230(10)
                         0.0110(10)
                                  0.0080(10)
                                           0.0020(10)
                                                    0.0000(10)
    O2 0.120(5) 0.020(2) 0.041(2) 0.016(2) -0.005(2) -0.002(2)
    O3 0.029(3) 0.076(2) 0.036(2) -0.009(2) 0.000(2) -0.001(2)
    O4 0.049(3) 0.041(2) 0.029(2) -0.006(2) 0.014(2) 0.010(2)
    O5 0.061(3) 0.039(2) 0.014(2) 0.001(2) -0.007(2) -0.0040(10)
    N1 0.028(3) 0.017(2) 0.008(2) 0.005(2) 0.005(2) -0.0010(10)
    N2 0.019(2) 0.016(2) 0.013(2) -0.0010(10)
                                            0.004(2) 0.0010(10)
    C1 0.016(3) 0.011(2) 0.016(2) -0.002(2) 0.002(2) -0.0020(10)
    C2 0.024(3) 0.018(2) 0.010(2) -0.003(2) 0.003(2) -0.0010(10)
    C3 0.025(3) 0.013(2) 0.016(2) 0.000(2) 0.008(2) -0.0040(10)
    C4 0.016(3) 0.012(2) 0.018(2) 0.003(2) 0.001(2) 0.0020(10)
    C5 0.024(3) 0.018(2) 0.009(2) -0.001(2) 0.002(2) -0.0010(10)
    C6 0.021(3) 0.012(2) 0.012(2) 0.002(2) 0.006(2) -0.0020(10)
    C7 0.027(3) 0.014(2) 0.011(2) 0.001(2) 0.002(2) 0.0000(10)
    C8 0.030(3) 0.028(2) 0.009(2) 0.014(2) 0.004(2) -0.004(2)
    C9 0.037(4) 0.029(2) 0.015(2) 0.011(2) 0.011(2) 0.003(2)
    C10 0.028(3) 0.019(2) 0.023(2) 0.007(2) 0.007(2) -0.003(2)
    C11 0.025(3) 0.015(2) 0.019(2) 0.000(2) 0.001(2) -0.001(2)
    C12 0.022(3) 0.013(2) 0.019(2) -0.003(2) 0.004(2) 0.000(2)
    C13 0.027(3) 0.016(2) 0.028(2) 0.001(2) 0.003(2) 0.006(2)
    C14 0.037(4) 0.031(2) 0.020(2) -0.003(2) -0.004(2) 0.011(2)
    C15 0.038(3) 0.032(2) 0.011(2) -0.009(2) 0.001(2) 0.002(2)
    C16 0.033(3) 0.020(2) 0.017(2) -0.003(2) 0.006(2) -0.001(2)
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Br1 C4 . 1.884(4) no
    Cu1 N1 . 1.904(3) yes
    Cu1 N2 . 1.966(3) yes
    Cu1 O1 . 1.866(3) yes
    Cu1 S1 . 2.3320(10)
                      yes
    S1 C9 . 1.801(4) no
    S1 C10 . 1.821(4) no
    Cl1 O2 . 1.418(3) no
    Cl1 O3 . 1.420(4) no
    Cl1 O5 . 1.432(3) no
    Cl1 O4 . 1.431(3) no
    O1 C1 . 1.305(5) no
    N1 C7 . 1.272(6) no
    N1 C8 . 1.474(5) no
    N2 C16 . 1.337(5) no
    N2 C12 . 1.346(5) no
    C1 C6 . 1.403(5) no
    C1 C2 . 1.415(5) no
    C2 C3 . 1.356(6) no
    C3 C4 . 1.394(5) no
    C4 C5 . 1.372(5) no
    C5 C6 . 1.392(6) no
    C6 C7 . 1.445(5) no
    C8 C9 . 1.496(7) no
    C10 C11 . 1.514(6) no
    C11 C12 . 1.501(5) no
    C12 C13 . 1.372(6) no
    C13 C14 . 1.384(6) no
    C14 C15 . 1.368(7) no
    C15 C16 . 1.366(6) no
    C2 H2 . 0.95 no
    C3 H3 . 0.95 no
    C5 H5 . 0.95 no
    C7 H7 . 0.95 no
    C8 H8a . 0.99 no
    C8 H8b . 0.99 no
    C9 H9a . 0.99 no
    C9 H9b . 0.99 no
    C10 H10a . 0.99 no
    C10 H10b . 0.99 no
    C11 H11a . 0.99 no
    C11 H11b . 0.99 no
    C13 H13 . 0.95 no
    C14 H14 . 0.95 no
    C15 H15 . 0.95 no
    C16 H16 . 0.95 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N1 Cu1 O1 . . 96.20(10)
                          yes
    N1 Cu1 N2 . . 157.40(10)
                           yes
    N1 Cu1 S1 . . 87.50(10)
                          yes
    N2 Cu1 O1 . . 92.90(10)
                          yes
    N2 Cu1 S1 . . 91.70(10)
                          yes
    O1 Cu1 S1 . . 157.90(10)
                           yes
    C9 S1 C10 . . 104.8(2) no
    C9 S1 Cu1 . . 95.3(2) no
    C10 S1 Cu1 . . 100.6(2) no
    O2 Cl1 O3 . . 110.7(3) no
    O2 Cl1 O5 . . 109.6(2) no
    O3 Cl1 O5 . . 109.7(2) no
    O2 Cl1 O4 . . 109.1(2) no
    O3 Cl1 O4 . . 108.5(2) no
    O5 Cl1 O4 . . 109.3(2) no
    C1 O1 Cu1 . . 125.5(2) no
    C7 N1 C8 . . 120.0(3) no
    C7 N1 Cu1 . . 124.4(3) no
    C8 N1 Cu1 . . 115.6(3) no
    C16 N2 C12 . . 119.4(4) no
    C16 N2 Cu1 . . 121.7(3) no
    C12 N2 Cu1 . . 118.3(3) no
    O1 C1 C6 . . 124.9(3) no
    O1 C1 C2 . . 117.8(3) no
    C6 C1 C2 . . 117.3(4) no
    C3 C2 C1 . . 121.5(4) no
    C2 C3 C4 . . 120.3(4) no
    C5 C4 C3 . . 119.9(4) no
    C5 C4 Br1 . . 120.0(3) no
    C3 C4 Br1 . . 120.1(3) no
    C4 C5 C6 . . 120.3(4) no
    C5 C6 C1 . . 120.7(3) no
    C5 C6 C7 . . 116.5(3) no
    C1 C6 C7 . . 122.8(4) no
    N1 C7 C6 . . 125.8(4) no
    N1 C8 C9 . . 109.2(3) no
    C8 C9 S1 . . 111.9(3) no
    C11 C10 S1 . . 112.4(3) no
    C12 C11 C10 . . 114.7(3) no
    N2 C12 C13 . . 120.6(4) no
    N2 C12 C11 . . 116.6(4) no
    C13 C12 C11 . . 122.7(4) no
    C12 C13 C14 . . 119.6(4) no
    C15 C14 C13 . . 119.0(4) no
    C16 C15 C14 . . 119.0(4) no
    N2 C16 C15 . . 122.2(4) no
    C3 C2 H2 . . 119.3 no
    C1 C2 H2 . . 119.3 no
    C2 C3 H3 . . 119.8 no
    C4 C3 H3 . . 119.8 no
    C4 C5 H5 . . 119.9 no
    C6 C5 H5 . . 119.9 no
    N1 C7 H7 . . 117.1 no
    C6 C7 H7 . . 117.1 no
    N1 C8 H8a . . 109.8 no
    C9 C8 H8a . . 109.8 no
    N1 C8 H8b . . 109.8 no
    C9 C8 H8b . . 109.8 no
    H8a C8 H8b . . 108.3 no
    C8 C9 H9a . . 109.2 no
    S1 C9 H9a . . 109.2 no
    C8 C9 H9b . . 109.2 no
    S1 C9 H9b . . 109.2 no
    H9a C9 H9b . . 107.9 no
    C11 C10 H10a . . 109.1 no
    S1 C10 H10a . . 109.1 no
    C11 C10 H10b . . 109.1 no
    S1 C10 H10b . . 109.1 no
    H10a C10 H10b . . 107.9 no
    C12 C11 H11a . . 108.6 no
    C10 C11 H11a . . 108.6 no
    C12 C11 H11b . . 108.6 no
    C10 C11 H11b . . 108.6 no
    H11a C11 H11b . . 107.6 no
    C12 C13 H13 . . 120.2 no
    C14 C13 H13 . . 120.2 no
    C15 C14 H14 . . 120.5 no
    C13 C14 H14 . . 120.5 no
    C16 C15 H15 . . 120.5 no
    C14 C15 H15 . . 120.5 no
    N2 C16 H16 . . 118.9 no
    C15 C16 H16 . . 118.9 no
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O1 Cu1 S1 C9 . . . . 98.2(3) no
    N1 Cu1 S1 C9 . . . . -2.3(2) no
    N2 Cu1 S1 C9 . . . . -159.8(2) no
    O1 Cu1 S1 C10 . . . . -155.7(3) no
    N1 Cu1 S1 C10 . . . . 103.8(2) no
    N2 Cu1 S1 C10 . . . . -53.6(2) no
    N1 Cu1 O1 C1 . . . . 5.9(3) no
    N2 Cu1 O1 C1 . . . . 165.2(3) no
    S1 Cu1 O1 C1 . . . . -92.9(4) no
    O1 Cu1 N1 C7 . . . . -2.4(4) no
    N2 Cu1 N1 C7 . . . . -115.8(4) no
    S1 Cu1 N1 C7 . . . . 155.7(3) no
    O1 Cu1 N1 C8 . . . . 178.0(3) no
    N2 Cu1 N1 C8 . . . . 64.7(5) no
    S1 Cu1 N1 C8 . . . . -23.8(3) no
    O1 Cu1 N2 C16 . . . . 32.2(4) no
    N1 Cu1 N2 C16 . . . . 146.1(4) no
    S1 Cu1 N2 C16 . . . . -126.2(3) no
    O1 Cu1 N2 C12 . . . . -156.6(3) no
    N1 Cu1 N2 C12 . . . . -42.7(6) no
    S1 Cu1 N2 C12 . . . . 45.0(3) no
    Cu1 O1 C1 C6 . . . . -7.8(5) no
    Cu1 O1 C1 C2 . . . . 174.4(3) no
    O1 C1 C2 C3 . . . . 176.1(4) no
    C6 C1 C2 C3 . . . . -1.9(5) no
    C1 C2 C3 C4 . . . . -0.7(6) no
    C2 C3 C4 C5 . . . . 2.5(6) no
    C2 C3 C4 Br1 . . . . -176.8(3) no
    C3 C4 C5 C6 . . . . -1.4(6) no
    Br1 C4 C5 C6 . . . . 177.8(3) no
    C4 C5 C6 C1 . . . . -1.3(6) no
    C4 C5 C6 C7 . . . . 179.0(3) no
    O1 C1 C6 C5 . . . . -175.0(4) no
    C2 C1 C6 C5 . . . . 2.9(5) no
    O1 C1 C6 C7 . . . . 4.8(6) no
    C2 C1 C6 C7 . . . . -177.4(3) no
    C8 N1 C7 C6 . . . . -179.9(4) no
    Cu1 N1 C7 C6 . . . . 0.6(6) no
    C5 C6 C7 N1 . . . . 178.8(4) no
    C1 C6 C7 N1 . . . . -0.9(6) no
    C7 N1 C8 C9 . . . . -131.9(4) no
    Cu1 N1 C8 C9 . . . . 47.7(4) no
    N1 C8 C9 S1 . . . . -48.5(4) no
    C10 S1 C9 C8 . . . . -75.1(3) no
    Cu1 S1 C9 C8 . . . . 27.4(3) no
    C9 S1 C10 C11 . . . . 112.0(3) no
    Cu1 S1 C10 C11 . . . . 13.5(3) no
    S1 C10 C11 C12 . . . . 54.7(5) no
    C16 N2 C12 C13 . . . . 3.0(6) no
    Cu1 N2 C12 C13 . . . . -168.4(3) no
    C16 N2 C12 C11 . . . . -176.0(4) no
    Cu1 N2 C12 C11 . . . . 12.6(5) no
    C10 C11 C12 N2 . . . . -81.1(5) no
    C10 C11 C12 C13 . . . . 99.9(5) no
    N2 C12 C13 C14 . . . . -3.1(7) no
    C11 C12 C13 C14 . . . . 175.9(4) no
    C12 C13 C14 C15 . . . . 0.7(7) no
    C13 C14 C15 C16 . . . . 1.6(7) no
    C12 N2 C16 C15 . . . . -0.6(7) no
    Cu1 N2 C16 C15 . . . . 170.5(4) no
    C14 C15 C16 N2 . . . . -1.7(7) no
data_global
_journal_date_recd_electronic     2004-07-28
_journal_date_accepted     2004-08-05
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2004
_journal_volume     60
_journal_issue      9
_journal_page_first     m1259
_journal_page_last     m1260
_journal_paper_category     EM
_publ_contact_author_name     'Dr Seik Weng Ng'
_publ_contact_author_address
;
Department of Chemistry
University of Malaya
50603 Kuala Lumpur
Malaysia
;
_publ_contact_author_email     seikweng@um.edu.my
_publ_contact_author_fax     '03 7967 4193'
_publ_contact_author_phone     '03 7967 6778'
_publ_section_title
;
[5-Bromo-N-(2-pyridylethylsulfanylethyl)salicylideneiminato-
κ⁴N,N',O,S]copper(II) perchlorate
;
loop_
    _publ_author_name
    _publ_author_address
    'Saghatforoush, Lotf A.'
;
Department of Chemistry
Payame Noor University
Khoy
Iran
;
    'Hossaini Sadr, Moayad '
;
Department of Chemistry
Tarbiat Moallem University of Azarbaijan
Tabriz
Iran
;
    'Lewis, William'
;
Department of Chemistry
University of Canterbury
Christchurch
New Zealand
;
    'Wikaira, Jan'
;
Department of Chemistry
University of Canterbury
Christchurch
New Zealand
;
    'Robinson, Ward T.'
;
Department of Chemistry
University of Canterbury
Christchurch
New Zealand
;
    'Ng, Seik Weng'
;
Department of Chemistry
University of Malaya
50603 Kuala Lumpur
Malaysia
;
