##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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data_global
_audit_creation_method     SHELXL-97
_journal_date_recd_electronic     2004-04-13
_journal_date_accepted     2004-04-14
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2004
_journal_volume     60
_journal_issue      5
_journal_page_first     m601
_journal_page_last     m602
_journal_paper_category     EM
_publ_contact_author
;
'Buyukgungor, Orhan'
Department of Physics
Ondokuz Mayis University
TR-55139
Samsun
Turkey
;
_publ_contact_author_email     orhanb@omu.edu.tr
_publ_section_title
;
Chloro[(N,N-dimethylamino)methylphenyl-
κ²C²,N](triphenylstibine)palladium(II)
;
loop_
    _publ_author_name
    _publ_author_address
    'Ayfer Mentes'
;
Department of Chemistry
Zonguldak Karaelmas University
TR-67100 Zonguldak
Turkey
;
    'Büyükgüngör, Orhan'
;
Department of Physics
Ondokuz Mayıs University
TR-55139 Samsun
Turkey
;
data_I
_chemical_name_systematic
;
Chloro[(N,N-dimethylamino)methylphenyl-
κ²C²,N](triphenylstibine)palladium(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C27 H27 Cl N Pd Sb'
_chemical_formula_sum     'C27 H27 Cl N Pd Sb'
_chemical_formula_iupac     '[Pd Cl (C9 H12 N) (C18 H15 Sb)]'
_chemical_formula_weight     629.10
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     9.7455(7)
_cell_length_b     10.0846(7)
_cell_length_c     14.9766(10)
_cell_angle_alpha     81.475(6)
_cell_angle_beta     72.856(6)
_cell_angle_gamma     63.805(5)
_cell_volume     1261.76(15)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     17979
_cell_measurement_theta_min     2.25
_cell_measurement_theta_max     26.00
_cell_measurement_temperature     293
_exptl_crystal_description     'prism'
_exptl_crystal_colour     'yellow'
_exptl_crystal_size_max     0.29
_exptl_crystal_size_mid     0.27
_exptl_crystal_size_min     0.25
_exptl_crystal_density_diffrn     1.656
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     620
_exptl_absorpt_coefficient_mu     1.903
_exptl_absorpt_correction_type     integration
_exptl_absorpt_process_details     '(X-RED; Stoe & Cie, 2002)'
_exptl_absorpt_correction_T_min     0.637
_exptl_absorpt_correction_T_max     0.712
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     'plane graphite'
_diffrn_measurement_device_type     'Stoe IPDS-2'
_diffrn_measurement_device     '2-circle goniometer'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     6.67
_diffrn_reflns_number     27284
_diffrn_reflns_av_R_equivalents     0.0623
_diffrn_reflns_av_sigmaI/netI     0.0438
_diffrn_reflns_theta_min     2.25
_diffrn_reflns_theta_max     26.00
_diffrn_reflns_theta_full     26.00
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -12
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -12
_diffrn_reflns_limit_k_max     12
_diffrn_reflns_limit_l_min     -18
_diffrn_reflns_limit_l_max     18
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     '<2'
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     4954
_reflns_number_gt     3625
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0403
_refine_ls_R_factor_gt     0.0231
_refine_ls_wR_factor_gt     0.0422
_refine_ls_wR_factor_ref     0.0442
_refine_ls_goodness_of_fit_ref     0.853
_refine_ls_restrained_S_all     0.853
_refine_ls_number_reflns     4954
_refine_ls_number_parameters     280
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
             'calc w = 1/[σ²(Fo²)+(0.0187P)²] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.420
_refine_diff_density_min     -0.664
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pd' 'Pd' -0.9988 1.0072
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Sb' 'Sb' -0.5866 1.5461
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'X-AREA (Stoe & Cie, 2002)'
_computing_cell_refinement     'X-AREA'
_computing_data_reduction     'X-RED (Stoe & Cie, 2002)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material     'WinGX (Farrugia, 1999)'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    C1 0.6860(3) 0.3736(3) 0.14878(19) 0.0433(7) Uani d . 1 . . C
    C2 0.6779(4) 0.2629(3) 0.2134(2) 0.0567(8) Uani d . 1 . . C
    H2 0.6381 0.2841 0.2767 0.068 Uiso calc R 1 . . H
    C3 0.7280(4) 0.1216(4) 0.1853(3) 0.0686(10) Uani d . 1 . . C
    H3 0.7188 0.0483 0.2291 0.082 Uiso calc R 1 . . H
    C4 0.7919(4) 0.0892(4) 0.0916(3) 0.0749(11) Uani d . 1 . . C
    H4 0.8278 -0.0066 0.0722 0.090 Uiso calc R 1 . . H
    C5 0.8026(4) 0.1968(4) 0.0277(3) 0.0703(11) Uani d . 1 . . C
    H5 0.8469 0.1740 -0.0352 0.084 Uiso calc R 1 . . H
    C6 0.7483(3) 0.3407(4) 0.0551(2) 0.0533(8) Uani d . 1 . . C
    H6 0.7539 0.4144 0.0108 0.064 Uiso calc R 1 . . H
    C7 0.3475(3) 0.6491(3) 0.20986(18) 0.0449(7) Uani d . 1 . . C
    C8 0.3005(4) 0.5446(4) 0.1963(2) 0.0615(9) Uani d . 1 . . C
    H8 0.3759 0.4500 0.1781 0.074 Uiso calc R 1 . . H
    C9 0.1412(5) 0.5805(5) 0.2098(3) 0.0738(10) Uani d . 1 . . C
    H9 0.1099 0.5094 0.2015 0.089 Uiso calc R 1 . . H
    C10 0.0299(4) 0.7199(5) 0.2352(2) 0.0719(10) Uani d . 1 . . C
    H10 -0.0768 0.7439 0.2437 0.086 Uiso calc R 1 . . H
    C11 0.0761(4) 0.8249(4) 0.2483(2) 0.0668(9) Uani d . 1 . . C
    H11 0.0008 0.9202 0.2650 0.080 Uiso calc R 1 . . H
    C12 0.2334(4) 0.7887(4) 0.2367(2) 0.0573(8) Uani d . 1 . . C
    H12 0.2636 0.8594 0.2471 0.069 Uiso calc R 1 . . H
    C13 0.6548(3) 0.7004(3) 0.06794(18) 0.0431(7) Uani d . 1 . . C
    C14 0.5527(4) 0.7679(4) 0.0125(2) 0.0746(11) Uani d . 1 . . C
    H14 0.4523 0.7691 0.0321 0.090 Uiso calc R 1 . . H
    C15 0.5947(5) 0.8339(5) -0.0712(3) 0.0908(13) Uani d . 1 . . C
    H15 0.5227 0.8795 -0.1075 0.109 Uiso calc R 1 . . H
    C16 0.7397(5) 0.8331(4) -0.1013(2) 0.0741(10) Uani d . 1 . . C
    H16 0.7685 0.8776 -0.1582 0.089 Uiso calc R 1 . . H
    C17 0.8423(5) 0.7670(5) -0.0478(3) 0.0792(11) Uani d . 1 . . C
    H17 0.9424 0.7664 -0.0683 0.095 Uiso calc R 1 . . H
    C18 0.8018(4) 0.7003(4) 0.0365(2) 0.0653(9) Uani d . 1 . . C
    H18 0.8746 0.6549 0.0723 0.078 Uiso calc R 1 . . H
    C19 0.7702(4) 0.4544(3) 0.37671(19) 0.0462(7) Uani d . 1 . . C
    C20 0.8896(4) 0.3397(4) 0.3198(2) 0.0571(8) Uani d . 1 . . C
    H20 0.9022 0.3489 0.2555 0.069 Uiso calc R 1 . . H
    C21 0.9895(4) 0.2128(4) 0.3568(3) 0.0700(10) Uani d . 1 . . C
    H21 1.0678 0.1372 0.3175 0.084 Uiso calc R 1 . . H
    C22 0.9742(5) 0.1972(4) 0.4517(3) 0.0779(11) Uani d . 1 . . C
    H22 1.0406 0.1108 0.4765 0.094 Uiso calc R 1 . . H
    C23 0.8598(5) 0.3103(5) 0.5094(3) 0.0720(10) Uani d . 1 . . C
    H23 0.8501 0.3008 0.5734 0.086 Uiso calc R 1 . . H
    C24 0.7600(4) 0.4370(4) 0.4731(2) 0.0522(8) Uani d . 1 . . C
    C25 0.6380(4) 0.5640(4) 0.53249(19) 0.0595(9) Uani d . 1 . . C
    H25A 0.5389 0.5539 0.5536 0.071 Uiso calc R 1 . . H
    H25B 0.6717 0.5652 0.5871 0.071 Uiso calc R 1 . . H
    C26 0.4616(4) 0.8243(4) 0.5219(2) 0.0736(11) Uani d . 1 . . C
    H26A 0.3771 0.7976 0.5251 0.110 Uiso calc R 1 . . H
    H26B 0.4473 0.9138 0.4853 0.110 Uiso calc R 1 . . H
    H26C 0.4609 0.8394 0.5838 0.110 Uiso calc R 1 . . H
    C27 0.7467(5) 0.7442(5) 0.4725(2) 0.0798(12) Uani d . 1 . . C
    H27A 0.7321 0.8344 0.4367 0.120 Uiso calc R 1 . . H
    H27B 0.8455 0.6666 0.4431 0.120 Uiso calc R 1 . . H
    H27C 0.7475 0.7576 0.5345 0.120 Uiso calc R 1 . . H
    N1 0.6151(3) 0.7040(3) 0.47771(16) 0.0538(7) Uani d . 1 . . N
    Cl1 0.48678(13) 0.90841(9) 0.29638(7) 0.0758(3) Uani d . 1 . . Cl
    Pd1 0.62798(3) 0.65567(2) 0.340706(14) 0.04401(7) Uani d . 1 . . Pd
    Sb1 0.59187(2) 0.59349(2) 0.195711(12) 0.04138(6) Uani d . 1 . . Sb
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_22
    _atom_site_aniso_U_33
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_23
    C1 0.0435(17) 0.0457(17) 0.0416(15) -0.0148(14) -0.0173(13) -0.0035(13)
    C2 0.060(2) 0.053(2) 0.0534(18) -0.0191(17) -0.0166(16) -0.0049(15)
    C3 0.064(2) 0.051(2) 0.093(3) -0.0205(19) -0.032(2) 0.0023(19)
    C4 0.063(2) 0.057(2) 0.108(3) -0.012(2) -0.034(2) -0.029(2)
    C5 0.058(2) 0.080(3) 0.067(2) -0.014(2) -0.0151(18) -0.035(2)
    C6 0.0487(18) 0.064(2) 0.0477(17) -0.0185(17) -0.0157(14) -0.0113(15)
    C7 0.0486(17) 0.0517(18) 0.0350(14) -0.0223(16) -0.0112(13) 0.0023(12)
    C8 0.057(2) 0.061(2) 0.071(2) -0.0272(18) -0.0162(17) -0.0071(17)
    C9 0.066(2) 0.085(3) 0.086(3) -0.044(2) -0.023(2) 0.001(2)
    C10 0.051(2) 0.105(3) 0.057(2) -0.033(2) -0.0133(17) 0.004(2)
    C11 0.053(2) 0.074(2) 0.061(2) -0.0138(19) -0.0148(17) -0.0074(18)
    C12 0.060(2) 0.059(2) 0.0525(18) -0.0237(18) -0.0164(16) -0.0017(15)
    C13 0.0490(17) 0.0478(17) 0.0367(14) -0.0237(15) -0.0127(13) 0.0013(12)
    C14 0.056(2) 0.118(3) 0.058(2) -0.047(2) -0.0264(17) 0.034(2)
    C15 0.078(3) 0.133(4) 0.066(2) -0.051(3) -0.038(2) 0.043(2)
    C16 0.082(3) 0.086(3) 0.056(2) -0.046(2) -0.012(2) 0.0175(19)
    C17 0.060(2) 0.114(3) 0.073(2) -0.056(2) -0.008(2) 0.012(2)
    C18 0.052(2) 0.091(3) 0.058(2) -0.033(2) -0.0228(16) 0.0102(18)
    C19 0.0519(18) 0.0572(19) 0.0418(15) -0.0317(16) -0.0171(14) 0.0024(13)
    C20 0.059(2) 0.064(2) 0.0519(18) -0.0241(18) -0.0218(16) -0.0004(16)
    C21 0.063(2) 0.059(2) 0.086(3) -0.0170(19) -0.031(2) -0.0022(19)
    C22 0.083(3) 0.070(3) 0.099(3) -0.037(2) -0.057(3) 0.029(2)
    C23 0.084(3) 0.091(3) 0.057(2) -0.048(2) -0.037(2) 0.023(2)
    C24 0.060(2) 0.069(2) 0.0446(16) -0.0418(18) -0.0211(15) 0.0109(15)
    C25 0.075(2) 0.084(2) 0.0354(15) -0.048(2) -0.0155(15) 0.0028(16)
    C26 0.086(3) 0.078(3) 0.057(2) -0.041(2) 0.0007(19) -0.0228(19)
    C27 0.098(3) 0.117(3) 0.063(2) -0.079(3) -0.015(2) -0.013(2)
    N1 0.0681(18) 0.0703(18) 0.0410(13) -0.0453(16) -0.0101(12) -0.0082(12)
    Cl1 0.1052(8) 0.0513(5) 0.0795(6) -0.0330(5) -0.0388(6) 0.0044(4)
    Pd1 0.05447(16) 0.05074(16) 0.03456(12) -0.02807(13) -0.01235(11)
                                                                    -0.00206(10)
    Sb1 0.04822(13) 0.04562(13) 0.03285(10) -0.01994(10) -0.01412(9) -0.00007(8)
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 C2 . 1.378(4) ?
    C1 C6 . 1.380(4) ?
    C1 Sb1 . 2.130(3) ?
    C2 C3 . 1.375(4) ?
    C2 H2 . 0.9300 ?
    C3 C4 . 1.380(5) ?
    C3 H3 . 0.9300 ?
    C4 C5 . 1.355(5) ?
    C4 H4 . 0.9300 ?
    C5 C6 . 1.387(4) ?
    C5 H5 . 0.9300 ?
    C6 H6 . 0.9300 ?
    C7 C12 . 1.379(4) ?
    C7 C8 . 1.380(4) ?
    C7 Sb1 . 2.143(3) ?
    C8 C9 . 1.387(5) ?
    C8 H8 . 0.9300 ?
    C9 C10 . 1.366(5) ?
    C9 H9 . 0.9300 ?
    C10 C11 . 1.377(5) ?
    C10 H10 . 0.9300 ?
    C11 C12 . 1.371(5) ?
    C11 H11 . 0.9300 ?
    C12 H12 . 0.9300 ?
    C13 C14 . 1.365(4) ?
    C13 C18 . 1.369(4) ?
    C13 Sb1 . 2.117(3) ?
    C14 C15 . 1.369(5) ?
    C14 H14 . 0.9300 ?
    C15 C16 . 1.348(5) ?
    C15 H15 . 0.9300 ?
    C16 C17 . 1.345(5) ?
    C16 H16 . 0.9300 ?
    C17 C18 . 1.375(5) ?
    C17 H17 . 0.9300 ?
    C18 H18 . 0.9300 ?
    C19 C20 . 1.392(4) y
    C19 C24 . 1.407(4) y
    C19 Pd1 . 1.991(3) y
    C20 C21 . 1.380(5) ?
    C20 H20 . 0.9300 ?
    C21 C22 . 1.376(5) ?
    C21 H21 . 0.9300 ?
    C22 C23 . 1.375(5) ?
    C22 H22 . 0.9300 ?
    C23 C24 . 1.372(5) ?
    C23 H23 . 0.9300 ?
    C24 C25 . 1.488(4) ?
    C25 N1 . 1.484(4) y
    C25 H25A . 0.9700 ?
    C25 H25B . 0.9700 ?
    C26 N1 . 1.483(4) ?
    C26 H26A . 0.9600 ?
    C26 H26B . 0.9600 ?
    C26 H26C . 0.9600 ?
    C27 N1 . 1.485(4) ?
    C27 H27A . 0.9600 ?
    C27 H27B . 0.9600 ?
    C27 H27C . 0.9600 ?
    N1 Pd1 . 2.134(2) y
    Cl1 Pd1 . 2.4023(9) y
    Pd1 Sb1 . 2.5063(3) y
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C2 C1 C6 . . 119.3(3) ?
    C2 C1 Sb1 . . 119.0(2) ?
    C6 C1 Sb1 . . 121.6(2) ?
    C3 C2 C1 . . 120.7(3) ?
    C3 C2 H2 . . 119.6 ?
    C1 C2 H2 . . 119.6 ?
    C2 C3 C4 . . 119.5(4) ?
    C2 C3 H3 . . 120.2 ?
    C4 C3 H3 . . 120.2 ?
    C5 C4 C3 . . 120.1(3) ?
    C5 C4 H4 . . 119.9 ?
    C3 C4 H4 . . 119.9 ?
    C4 C5 C6 . . 120.8(3) ?
    C4 C5 H5 . . 119.6 ?
    C6 C5 H5 . . 119.6 ?
    C1 C6 C5 . . 119.5(3) ?
    C1 C6 H6 . . 120.3 ?
    C5 C6 H6 . . 120.3 ?
    C12 C7 C8 . . 118.8(3) ?
    C12 C7 Sb1 . . 120.3(2) ?
    C8 C7 Sb1 . . 120.8(2) ?
    C7 C8 C9 . . 120.1(3) ?
    C7 C8 H8 . . 120.0 ?
    C9 C8 H8 . . 120.0 ?
    C10 C9 C8 . . 120.3(3) ?
    C10 C9 H9 . . 119.8 ?
    C8 C9 H9 . . 119.8 ?
    C9 C10 C11 . . 119.8(3) ?
    C9 C10 H10 . . 120.1 ?
    C11 C10 H10 . . 120.1 ?
    C12 C11 C10 . . 119.9(3) ?
    C12 C11 H11 . . 120.1 ?
    C10 C11 H11 . . 120.1 ?
    C11 C12 C7 . . 121.1(3) ?
    C11 C12 H12 . . 119.5 ?
    C7 C12 H12 . . 119.5 ?
    C14 C13 C18 . . 117.5(3) ?
    C14 C13 Sb1 . . 121.5(2) ?
    C18 C13 Sb1 . . 121.0(2) ?
    C13 C14 C15 . . 121.5(3) ?
    C13 C14 H14 . . 119.2 ?
    C15 C14 H14 . . 119.2 ?
    C16 C15 C14 . . 120.3(3) ?
    C16 C15 H15 . . 119.8 ?
    C14 C15 H15 . . 119.8 ?
    C17 C16 C15 . . 119.2(3) ?
    C17 C16 H16 . . 120.4 ?
    C15 C16 H16 . . 120.4 ?
    C16 C17 C18 . . 121.2(3) ?
    C16 C17 H17 . . 119.4 ?
    C18 C17 H17 . . 119.4 ?
    C13 C18 C17 . . 120.3(3) ?
    C13 C18 H18 . . 119.9 ?
    C17 C18 H18 . . 119.9 ?
    C20 C19 C24 . . 116.9(3) ?
    C20 C19 Pd1 . . 129.2(2) ?
    C24 C19 Pd1 . . 113.2(2) ?
    C21 C20 C19 . . 121.3(3) ?
    C21 C20 H20 . . 119.3 ?
    C19 C20 H20 . . 119.3 ?
    C22 C21 C20 . . 120.4(4) ?
    C22 C21 H21 . . 119.8 ?
    C20 C21 H21 . . 119.8 ?
    C23 C22 C21 . . 119.5(3) ?
    C23 C22 H22 . . 120.2 ?
    C21 C22 H22 . . 120.2 ?
    C24 C23 C22 . . 120.4(3) ?
    C24 C23 H23 . . 119.8 ?
    C22 C23 H23 . . 119.8 ?
    C23 C24 C19 . . 121.3(3) ?
    C23 C24 C25 . . 122.3(3) ?
    C19 C24 C25 . . 116.4(3) ?
    N1 C25 C24 . . 109.5(2) ?
    N1 C25 H25A . . 109.8 ?
    C24 C25 H25A . . 109.8 ?
    N1 C25 H25B . . 109.8 ?
    C24 C25 H25B . . 109.8 ?
    H25A C25 H25B . . 108.2 ?
    N1 C26 H26A . . 109.5 ?
    N1 C26 H26B . . 109.5 ?
    H26A C26 H26B . . 109.5 ?
    N1 C26 H26C . . 109.5 ?
    H26A C26 H26C . . 109.5 ?
    H26B C26 H26C . . 109.5 ?
    N1 C27 H27A . . 109.5 ?
    N1 C27 H27B . . 109.5 ?
    H27A C27 H27B . . 109.5 ?
    N1 C27 H27C . . 109.5 ?
    H27A C27 H27C . . 109.5 ?
    H27B C27 H27C . . 109.5 ?
    C26 N1 C25 . . 110.3(3) ?
    C26 N1 C27 . . 109.9(3) ?
    C25 N1 C27 . . 109.6(3) ?
    C26 N1 Pd1 . . 112.9(2) ?
    C25 N1 Pd1 . . 105.15(16) ?
    C27 N1 Pd1 . . 108.91(19) ?
    C19 Pd1 N1 . . 81.97(11) y
    C19 Pd1 Cl1 . . 171.69(8) y
    N1 Pd1 Cl1 . . 95.20(8) y
    C19 Pd1 Sb1 . . 99.16(7) y
    N1 Pd1 Sb1 . . 168.34(7) y
    Cl1 Pd1 Sb1 . . 85.20(2) y
    C13 Sb1 C1 . . 99.88(11) ?
    C13 Sb1 C7 . . 102.58(11) ?
    C1 Sb1 C7 . . 97.50(11) ?
    C13 Sb1 Pd1 . . 118.89(7) ?
    C1 Sb1 Pd1 . . 123.52(7) ?
    C7 Sb1 Pd1 . . 110.74(7) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C6 C1 C2 C3 . . . . -1.4(5) ?
    Sb1 C1 C2 C3 . . . . 175.8(2) ?
    C1 C2 C3 C4 . . . . 2.2(5) ?
    C2 C3 C4 C5 . . . . -1.2(5) ?
    C3 C4 C5 C6 . . . . -0.7(6) ?
    C2 C1 C6 C5 . . . . -0.4(4) ?
    Sb1 C1 C6 C5 . . . . -177.5(2) ?
    C4 C5 C6 C1 . . . . 1.5(5) ?
    C12 C7 C8 C9 . . . . -0.1(5) ?
    Sb1 C7 C8 C9 . . . . 177.1(3) ?
    C7 C8 C9 C10 . . . . 1.0(5) ?
    C8 C9 C10 C11 . . . . -0.6(5) ?
    C9 C10 C11 C12 . . . . -0.6(5) ?
    C10 C11 C12 C7 . . . . 1.5(5) ?
    C8 C7 C12 C11 . . . . -1.2(5) ?
    Sb1 C7 C12 C11 . . . . -178.4(2) ?
    C18 C13 C14 C15 . . . . -0.3(6) ?
    Sb1 C13 C14 C15 . . . . -178.4(3) ?
    C13 C14 C15 C16 . . . . 0.3(7) ?
    C14 C15 C16 C17 . . . . -0.2(7) ?
    C15 C16 C17 C18 . . . . 0.2(6) ?
    C14 C13 C18 C17 . . . . 0.3(5) ?
    Sb1 C13 C18 C17 . . . . 178.3(3) ?
    C16 C17 C18 C13 . . . . -0.2(6) ?
    C24 C19 C20 C21 . . . . 2.2(5) ?
    Pd1 C19 C20 C21 . . . . 172.2(3) ?
    C19 C20 C21 C22 . . . . -0.6(5) ?
    C20 C21 C22 C23 . . . . -1.0(6) ?
    C21 C22 C23 C24 . . . . 1.0(6) ?
    C22 C23 C24 C19 . . . . 0.7(5) ?
    C22 C23 C24 C25 . . . . -178.0(3) ?
    C20 C19 C24 C23 . . . . -2.3(4) ?
    Pd1 C19 C24 C23 . . . . -173.9(2) ?
    C20 C19 C24 C25 . . . . 176.5(3) ?
    Pd1 C19 C24 C25 . . . . 4.9(3) ?
    C23 C24 C25 N1 . . . . 147.9(3) ?
    C19 C24 C25 N1 . . . . -30.9(4) ?
    C24 C25 N1 C26 . . . . 160.9(2) ?
    C24 C25 N1 C27 . . . . -78.1(3) ?
    C24 C25 N1 Pd1 . . . . 38.8(3) ?
    C20 C19 Pd1 N1 . . . . -156.1(3) ?
    C24 C19 Pd1 N1 . . . . 14.2(2) ?
    C20 C19 Pd1 Sb1 . . . . 35.6(3) ?
    C24 C19 Pd1 Sb1 . . . . -154.1(2) ?
    C26 N1 Pd1 C19 . . . . -149.8(2) ?
    C25 N1 Pd1 C19 . . . . -29.5(2) ?
    C27 N1 Pd1 C19 . . . . 87.8(2) ?
    C26 N1 Pd1 Cl1 . . . . 38.1(2) ?
    C25 N1 Pd1 Cl1 . . . . 158.33(19) ?
    C27 N1 Pd1 Cl1 . . . . -84.3(2) ?
    C26 N1 Pd1 Sb1 . . . . -53.4(5) ?
    C25 N1 Pd1 Sb1 . . . . 66.9(5) ?
    C27 N1 Pd1 Sb1 . . . . -175.8(3) ?
    C14 C13 Sb1 C1 . . . . 93.4(3) ?
    C18 C13 Sb1 C1 . . . . -84.6(3) ?
    C14 C13 Sb1 C7 . . . . -6.6(3) ?
    C18 C13 Sb1 C7 . . . . 175.4(2) ?
    C14 C13 Sb1 Pd1 . . . . -129.1(3) ?
    C18 C13 Sb1 Pd1 . . . . 52.9(3) ?
    C2 C1 Sb1 C13 . . . . 176.3(2) ?
    C6 C1 Sb1 C13 . . . . -6.6(3) ?
    C2 C1 Sb1 C7 . . . . -79.4(2) ?
    C6 C1 Sb1 C7 . . . . 97.7(2) ?
    C2 C1 Sb1 Pd1 . . . . 41.6(3) ?
    C6 C1 Sb1 Pd1 . . . . -141.3(2) ?
    C12 C7 Sb1 C13 . . . . -75.8(2) ?
    C8 C7 Sb1 C13 . . . . 107.0(2) ?
    C12 C7 Sb1 C1 . . . . -177.7(2) ?
    C8 C7 Sb1 C1 . . . . 5.1(3) ?
    C12 C7 Sb1 Pd1 . . . . 52.1(2) ?
    C8 C7 Sb1 Pd1 . . . . -125.1(2) ?
    C19 Pd1 Sb1 C13 . . . . -122.51(12) ?
    N1 Pd1 Sb1 C13 . . . . 142.8(4) ?
    Cl1 Pd1 Sb1 C13 . . . . 50.36(9) ?
    C19 Pd1 Sb1 C1 . . . . 4.41(12) ?
    N1 Pd1 Sb1 C1 . . . . -90.2(4) ?
    Cl1 Pd1 Sb1 C1 . . . . 177.28(10) ?
    C19 Pd1 Sb1 C7 . . . . 119.14(12) ?
    N1 Pd1 Sb1 C7 . . . . 24.5(4) ?
    Cl1 Pd1 Sb1 C7 . . . . -67.99(9) ?
