##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
catena-poly[[caesium(I)-μ-18-crown-6-caesium(I)-di-μ-2-amidopyridine]
toluene]
;
_chemical_name_common     ?
_chemical_formula_moiety     'C29 H42 Cs2 N4 O6'
_chemical_formula_sum     'C29 H42 Cs2 N4 O6'
_chemical_formula_iupac     '[Cs2 (C5 H5 N2)2 (C12 H24 O6)], C7 H8'
_chemical_formula_weight     808.49
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'C m'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    'x, -y, z'
    'x+1/2, y+1/2, z'
    'x+1/2, -y+1/2, z'
_cell_length_a     13.0109(10)
_cell_length_b     17.3720(14)
_cell_length_c     7.8427(6)
_cell_angle_alpha     90.00
_cell_angle_beta     107.979(2)
_cell_angle_gamma     90.00
_cell_volume     1686.1(2)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     5667
_cell_measurement_theta_min     2.35
_cell_measurement_theta_max     28.43
_cell_measurement_temperature     160(2)
_exptl_crystal_description     needle
_exptl_crystal_colour     yellow
_exptl_crystal_size_max     1.30
_exptl_crystal_size_mid     0.22
_exptl_crystal_size_min     0.12
_exptl_crystal_density_diffrn     1.592
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     804
_exptl_absorpt_coefficient_mu     2.205
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 2002)'
_exptl_absorpt_correction_T_min     0.478
_exptl_absorpt_correction_T_max     0.768
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     160(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART 1K CCD'
_diffrn_measurement_method     'thin-slice ω'
_diffrn_detector_area_resol_mean     8.192
_diffrn_reflns_number     7390
_diffrn_reflns_av_R_equivalents     0.0250
_diffrn_reflns_av_sigmaI/netI     0.0416
_diffrn_reflns_theta_min     2.02
_diffrn_reflns_theta_max     28.51
_diffrn_reflns_theta_full     26.00
_diffrn_measured_fraction_theta_max     0.940
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -17
_diffrn_reflns_limit_h_max     16
_diffrn_reflns_limit_k_min     -22
_diffrn_reflns_limit_k_max     23
_diffrn_reflns_limit_l_min     -10
_diffrn_reflns_limit_l_max     10
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
;
_reflns_number_total     3879
_reflns_number_gt     2911
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0420
_refine_ls_R_factor_gt     0.0284
_refine_ls_wR_factor_gt     0.0600
_refine_ls_wR_factor_ref     0.0650
_refine_ls_goodness_of_fit_ref     0.935
_refine_ls_restrained_S_all     1.003
_refine_ls_number_reflns     3879
_refine_ls_number_parameters     201
_refine_ls_number_restraints     65
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                    'w = 1/[σ²(Fo²)+(0.03P)²] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.038
_refine_ls_shift/su_mean     0.005
_refine_diff_density_max     0.814
_refine_diff_density_min     -0.531
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
_refine_ls_abs_structure_details     'Flack (1983)'
_refine_ls_abs_structure_Flack     0.46(4)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cs' 'Cs' -0.3680 2.1192
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 2001)'
_computing_cell_refinement     'SAINT (Bruker, 2001)'
_computing_data_reduction     'SAINT'
_computing_structure_solution     'SHELXTL (Sheldrick, 2001)'
_computing_structure_refinement     SHELXTL
_computing_molecular_graphics     SHELXTL
_computing_publication_material     'SHELXTL and local programs'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Cs1 0.54337(3) 0.5000 0.55808(5) 0.0412(3) Uani d S 1 . . Cs
    Cs2 0.53181(3) 0.5000 1.04501(4) 0.0398(2) Uani d S 1 . . Cs
    N1 0.5867(9) 0.6431(5) 0.3252(12) 0.056(2) Uani d U 1 . . N
    N2 0.4028(4) 0.6085(3) 0.2416(6) 0.0515(12) Uani d U 1 . . N
    H2N 0.322(4) 0.635(3) 0.191(6) 0.037(13) Uiso d . 1 . . H
    C1 0.6594(6) 0.6920(4) 0.3401(8) 0.0607(17) Uani d DU 1 . . C
    H1 0.7316 0.6754 0.3591 0.073 Uiso calc R 1 . . H
    C2 0.6372(10) 0.7678(5) 0.3297(17) 0.077(2) Uani d DU 1 . . C
    H2 0.6950 0.8033 0.3462 0.092 Uiso calc R 1 . . H
    C3 0.5353(13) 0.7953(3) 0.296(2) 0.0702(15) Uani d DU 1 . . C
    H3 0.5223 0.8491 0.2859 0.084 Uiso calc R 1 . . H
    C4 0.4519(10) 0.7457(5) 0.2780(14) 0.077(3) Uani d DU 1 . . C
    H4 0.3803 0.7633 0.2608 0.092 Uiso calc R 1 . . H
    C5 0.4802(9) 0.6582(6) 0.2867(13) 0.051(2) Uani d DU 1 . . C
    O1 0.7602(10) 0.5000 0.9015(16) 0.081(4) Uani d SDU 1 . . O
    O2 0.6388(8) 0.6418(4) 0.8835(12) 0.074(2) Uani d DU 1 . . O
    O3 0.4197(7) 0.6345(4) 0.7223(9) 0.0673(19) Uani d DU 1 . . O
    O4 0.3166(8) 0.5000 0.7064(15) 0.076(3) Uani d SDU 1 . . O
    C6 0.8016(9) 0.5711(7) 0.9845(16) 0.091(3) Uani d DU 1 . . C
    H6A 0.8804 0.5728 1.0038 0.109 Uiso calc R 1 . . H
    H6B 0.7901 0.5736 1.1034 0.109 Uiso calc R 1 . . H
    C7 0.7501(10) 0.6398(7) 0.8767(16) 0.097(3) Uani d DU 1 . . C
    H7A 0.7890 0.6874 0.9286 0.117 Uiso calc R 1 . . H
    H7B 0.7508 0.6348 0.7513 0.117 Uiso calc R 1 . . H
    C8 0.6008(13) 0.7062(5) 0.7947(13) 0.099(3) Uani d DU 1 . . C
    H8A 0.6020 0.7046 0.6692 0.118 Uiso calc R 1 . . H
    H8B 0.6395 0.7525 0.8556 0.118 Uiso calc R 1 . . H
    C9 0.4897(13) 0.7008(6) 0.8073(16) 0.109(4) Uani d DU 1 . . C
    H9A 0.4954 0.7009 0.9361 0.131 Uiso calc R 1 . . H
    H9B 0.4511 0.7486 0.7549 0.131 Uiso calc R 1 . . H
    C10 0.3123(10) 0.6290(9) 0.716(2) 0.122(4) Uani d DU 1 . . C
    H10A 0.2738 0.6767 0.6635 0.146 Uiso calc R 1 . . H
    H10B 0.3083 0.6242 0.8400 0.146 Uiso calc R 1 . . H
    C11 0.2592(11) 0.5630(8) 0.6108(18) 0.114(4) Uani d DU 1 . . C
    H11A 0.1819 0.5606 0.6037 0.137 Uiso calc R 1 . . H
    H11B 0.2649 0.5650 0.4879 0.137 Uiso calc R 1 . . H
    C12 0.5908(8) 1.0000 0.9116(16) 0.072(3) Uani d SU 1 . . C
    C13 0.5411(14) 0.9324(4) 0.826(2) 0.081(3) Uani d U 1 . . C
    H13 0.5612 0.8844 0.8855 0.097 Uiso calc R 1 . . H
    C14 0.4648(7) 0.9335(5) 0.6611(12) 0.094(3) Uani d U 1 . . C
    H14 0.4398 0.8850 0.6088 0.113 Uiso calc R 1 . . H
    C15 0.4190(12) 1.0000 0.559(3) 0.096(5) Uani d SU 1 . . C
    H15 0.3669 1.0000 0.4437 0.115 Uiso calc SR 1 . . H
    C16 0.6800(16) 1.0000 1.069(2) 0.155(9) Uani d SU 1 . . C
    H16A 0.7024 1.0531 1.1033 0.232 Uiso calc PR 0.25 . . H
    H16B 0.7400 0.9716 1.0483 0.232 Uiso calc PR 0.25 . . H
    H16C 0.6594 0.9752 1.1664 0.232 Uiso calc PR 0.25 . . H
    H16D 0.6988 0.9469 1.1087 0.232 Uiso calc PR 0.25 . . H
    H16E 0.6612 1.0284 1.1637 0.232 Uiso calc PR 0.25 . . H
    H16F 0.7418 1.0248 1.0456 0.232 Uiso calc PR 0.25 . . H
_geom_special_details
;
 ?
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Cs1 N1 . 3.235(9) yes
    Cs1 N1 2_565 3.235(9) no
    Cs1 N2 . 3.202(5) yes
    Cs1 N2 2_565 3.202(5) no
    Cs1 O1 . 3.243(12) yes
    Cs1 O2 . 3.488(8) yes
    Cs1 O2 2_565 3.488(8) no
    Cs1 O3 . 3.315(6) yes
    Cs1 O3 2_565 3.315(6) no
    Cs1 O4 . 3.490(10) yes
    Cs2 N1 1_556 3.247(9) yes
    Cs2 N1 2_566 3.247(9) no
    Cs2 N2 2_566 3.216(5) no
    Cs2 N2 1_556 3.216(5) yes
    Cs2 O1 . 3.487(13) yes
    Cs2 O2 . 3.272(8) yes
    Cs2 O2 2_565 3.272(8) no
    Cs2 O3 . 3.423(6) yes
    Cs2 O3 2_565 3.423(6) no
    Cs2 O4 . 3.210(10) yes
    N1 Cs2 1_554 3.247(9) no
    N1 C1 . 1.250(11) no
    N1 C5 . 1.350(8) no
    N2 Cs2 1_554 3.216(5) no
    N2 H2N . 1.11(5) no
    N2 C5 . 1.289(10) no
    C1 H1 . 0.950 no
    C1 C2 . 1.344(10) no
    C2 H2 . 0.950 no
    C2 C3 . 1.358(11) no
    C3 H3 . 0.950 no
    C3 C4 . 1.357(10) no
    C4 H4 . 0.950 no
    C4 C5 . 1.562(11) no
    O1 C6 . 1.422(9) no
    O1 C6 2_565 1.422(9) no
    O2 C7 . 1.465(10) no
    O2 C8 . 1.330(9) no
    O3 C9 . 1.492(11) no
    O3 C10 . 1.387(11) no
    O4 C11 . 1.404(10) no
    O4 C11 2_565 1.404(10) no
    C6 H6A . 0.990 no
    C6 H6B . 0.990 no
    C6 C7 . 1.496(10) no
    C7 H7A . 0.990 no
    C7 H7B . 0.990 no
    C8 H8A . 0.990 no
    C8 H8B . 0.990 no
    C8 C9 . 1.483(9) no
    C9 H9A . 0.990 no
    C9 H9B . 0.990 no
    C10 H10A . 0.990 no
    C10 H10B . 0.990 no
    C10 C11 . 1.458(12) no
    C11 H11A . 0.990 no
    C11 H11B . 0.990 no
    C12 C13 . 1.406(10) no
    C12 C13 2_575 1.406(10) no
    C12 C16 . 1.41(2) no
    C13 H13 . 0.950 no
    C13 C14 . 1.368(16) no
    C14 H14 . 0.950 no
    C14 C15 . 1.426(14) no
    C15 C14 2_575 1.426(14) no
    C15 H15 . 0.950 no
    C16 H16A . 0.980 no
    C16 H16B . 0.980 no
    C16 H16C . 0.980 no
    C16 H16D . 0.980 no
    C16 H16E . 0.980 no
    C16 H16F . 0.980 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N1 Cs1 N1 . 2_565 100.4(3) yes
    N1 Cs1 N2 . . 42.9(2) yes
    N1 Cs1 N2 2_565 2_565 42.9(2) no
    N1 Cs1 N2 2_565 . 99.90(18) no
    N1 Cs1 N2 . 2_565 99.90(18) no
    N1 Cs1 O1 . . 102.1(2) no
    N1 Cs1 O1 2_565 . 102.1(2) no
    N1 Cs1 O2 . . 77.6(2) no
    N1 Cs1 O2 2_565 . 150.6(2) no
    N1 Cs1 O2 2_565 2_565 77.6(2) no
    N1 Cs1 O2 . 2_565 150.6(2) no
    N1 Cs1 O3 . . 82.4(2) no
    N1 Cs1 O3 2_565 2_565 82.4(2) no
    N1 Cs1 O3 . 2_565 162.0(2) no
    N1 Cs1 O3 2_565 . 162.0(2) no
    N1 Cs1 O4 . . 120.1(2) no
    N1 Cs1 O4 2_565 . 120.1(2) no
    N2 Cs1 N2 . 2_565 72.11(17) yes
    N2 Cs1 O1 . . 141.79(11) no
    N2 Cs1 O1 2_565 . 141.79(11) no
    N2 Cs1 O2 . . 98.08(15) no
    N2 Cs1 O2 2_565 . 166.39(17) no
    N2 Cs1 O2 2_565 2_565 98.08(16) no
    N2 Cs1 O2 . 2_565 166.39(17) no
    N2 Cs1 O3 . . 69.92(14) no
    N2 Cs1 O3 2_565 2_565 69.92(15) no
    N2 Cs1 O3 . 2_565 119.11(19) no
    N2 Cs1 O3 2_565 . 119.11(19) no
    N2 Cs1 O4 . . 85.36(17) no
    N2 Cs1 O4 2_565 . 85.36(17) no
    O1 Cs1 O2 . . 50.99(17) yes
    O1 Cs1 O2 . 2_565 50.99(17) no
    O1 Cs1 O3 . . 94.6(2) no
    O1 Cs1 O3 . 2_565 94.6(2) no
    O1 Cs1 O4 . . 109.3(3) no
    O2 Cs1 O2 . 2_565 89.9(3) no
    O2 Cs1 O3 . . 47.45(14) yes
    O2 Cs1 O3 . 2_565 108.6(2) no
    O2 Cs1 O3 2_565 2_565 47.45(14) no
    O2 Cs1 O3 2_565 . 108.6(2) no
    O2 Cs1 O4 . . 84.4(2) no
    O2 Cs1 O4 2_565 . 84.4(2) no
    O3 Cs1 O3 . 2_565 89.7(3) no
    O3 Cs1 O4 . . 46.27(17) yes
    O3 Cs1 O4 2_565 . 46.27(17) no
    N1 Cs2 N1 1_556 2_566 99.9(3) yes
    N1 Cs2 N2 1_556 2_566 99.34(19) no
    N1 Cs2 N2 1_556 1_556 42.7(2) yes
    N1 Cs2 N2 2_566 2_566 42.7(2) no
    N1 Cs2 N2 2_566 1_556 99.34(19) no
    N1 Cs2 O1 1_556 . 100.8(2) no
    N1 Cs2 O1 2_566 . 100.8(2) no
    N1 Cs2 O2 1_556 . 69.8(2) no
    N1 Cs2 O2 2_566 . 143.8(2) no
    N1 Cs2 O2 1_556 2_565 143.8(2) no
    N1 Cs2 O2 2_566 2_565 69.8(2) no
    N1 Cs2 O3 1_556 2_565 167.8(2) no
    N1 Cs2 O3 2_566 2_565 86.1(2) no
    N1 Cs2 O3 1_556 . 86.1(2) no
    N1 Cs2 O3 2_566 . 167.8(2) no
    N1 Cs2 O4 1_556 . 120.9(2) no
    N1 Cs2 O4 2_566 . 120.9(2) no
    N2 Cs2 N2 2_566 1_556 71.75(18) yes
    N2 Cs2 O1 2_566 . 141.03(11) no
    N2 Cs2 O1 1_556 . 141.03(12) no
    N2 Cs2 O2 2_566 . 167.02(16) no
    N2 Cs2 O2 1_556 . 95.27(18) no
    N2 Cs2 O2 2_566 2_565 95.27(18) no
    N2 Cs2 O2 1_556 2_565 167.02(16) no
    N2 Cs2 O3 2_566 2_565 77.76(14) no
    N2 Cs2 O3 1_556 2_565 126.04(19) no
    N2 Cs2 O3 2_566 . 126.04(19) no
    N2 Cs2 O3 1_556 . 77.76(14) no
    N2 Cs2 O4 2_566 . 86.87(18) no
    N2 Cs2 O4 1_556 . 86.87(17) no
    O1 Cs2 O2 . . 50.80(16) yes
    O1 Cs2 O2 . 2_565 50.80(16) no
    O1 Cs2 O3 . . 88.4(2) no
    O1 Cs2 O3 . 2_565 88.4(2) no
    O1 Cs2 O4 . . 110.2(3) no
    O2 Cs2 O2 . 2_565 97.7(3) no
    O2 Cs2 O3 . . 48.29(15) yes
    O2 Cs2 O3 . 2_565 111.3(2) no
    O2 Cs2 O3 2_565 2_565 48.29(15) no
    O2 Cs2 O3 2_565 . 111.3(2) no
    O2 Cs2 O4 . . 92.7(2) no
    O2 Cs2 O4 2_565 . 92.7(2) no
    O3 Cs2 O3 . 2_565 86.1(3) no
    O3 Cs2 O4 . . 47.51(17) yes
    O3 Cs2 O4 2_565 . 47.51(17) no
    Cs1 N1 Cs2 . 1_554 75.75(19) yes
    Cs1 N1 C1 . . 136.8(7) no
    Cs1 N1 C5 . . 86.0(6) no
    Cs2 N1 C1 1_554 . 125.9(7) no
    Cs2 N1 C5 1_554 . 90.1(6) no
    C1 N1 C5 . . 125.7(11) no
    Cs1 N2 Cs2 . 1_554 76.64(11) yes
    Cs1 N2 H2N . . 141(3) no
    Cs1 N2 C5 . . 88.3(6) no
    Cs2 N2 H2N 1_554 . 131(2) no
    Cs2 N2 C5 1_554 . 92.6(6) no
    H2N N2 C5 . . 114(3) no
    N1 C1 H1 . . 119.4 no
    N1 C1 C2 . . 121.2(10) no
    H1 C1 C2 . . 119.4 no
    C1 C2 H2 . . 118.8 no
    C1 C2 C3 . . 122.3(9) no
    H2 C2 C3 . . 118.8 no
    C2 C3 H3 . . 120.0 no
    C2 C3 C4 . . 119.9(6) no
    H3 C3 C4 . . 120.0 no
    C3 C4 H4 . . 121.8 no
    C3 C4 C5 . . 116.3(8) no
    H4 C4 C5 . . 121.8 no
    N1 C5 N2 . . 126.3(11) no
    N1 C5 C4 . . 114.3(9) no
    N2 C5 C4 . . 119.1(10) no
    Cs1 O1 Cs2 . . 70.0(2) yes
    Cs1 O1 C6 . . 119.3(6) no
    Cs1 O1 C6 . 2_565 119.3(6) no
    Cs2 O1 C6 . . 95.3(7) no
    Cs2 O1 C6 . 2_565 95.3(7) no
    C6 O1 C6 . 2_565 120.5(13) no
    Cs1 O2 Cs2 . . 69.72(16) yes
    Cs1 O2 C7 . . 95.1(6) no
    Cs1 O2 C8 . . 102.7(7) no
    Cs2 O2 C7 . . 122.6(6) no
    Cs2 O2 C8 . . 134.6(9) no
    C7 O2 C8 . . 102.3(11) no
    Cs1 O3 Cs2 . . 70.05(12) yes
    Cs1 O3 C9 . . 114.6(8) no
    Cs1 O3 C10 . . 122.9(8) no
    Cs2 O3 C9 . . 97.8(6) no
    Cs2 O3 C10 . . 99.9(8) no
    C9 O3 C10 . . 122.5(10) no
    Cs1 O4 Cs2 . . 70.38(19) yes
    Cs1 O4 C11 . . 100.8(7) no
    Cs1 O4 C11 . 2_565 100.8(7) no
    Cs2 O4 C11 . . 128.8(7) no
    Cs2 O4 C11 . 2_565 128.8(7) no
    C11 O4 C11 . 2_565 102.4(14) no
    O1 C6 H6A . . 109.0 no
    O1 C6 H6B . . 108.9 no
    O1 C6 C7 . . 113.2(8) no
    H6A C6 H6B . . 107.8 no
    H6A C6 C7 . . 108.9 no
    H6B C6 C7 . . 109.0 no
    O2 C7 C6 . . 105.9(8) no
    O2 C7 H7A . . 110.6 no
    O2 C7 H7B . . 110.6 no
    C6 C7 H7A . . 110.6 no
    C6 C7 H7B . . 110.5 no
    H7A C7 H7B . . 108.7 no
    O2 C8 H8A . . 112.3 no
    O2 C8 H8B . . 112.3 no
    O2 C8 C9 . . 97.2(10) no
    H8A C8 H8B . . 109.9 no
    H8A C8 C9 . . 112.3 no
    H8B C8 C9 . . 112.3 no
    Cs2 C9 O3 . . 60.1(5) no
    Cs2 C9 C8 . . 95.2(7) no
    Cs2 C9 H9A . . 63.8 no
    Cs2 C9 H9B . . 157.3 no
    O3 C9 C8 . . 119.5(11) no
    O3 C9 H9A . . 107.5 no
    O3 C9 H9B . . 107.5 no
    C8 C9 H9A . . 107.5 no
    C8 C9 H9B . . 107.5 no
    H9A C9 H9B . . 107.0 no
    O3 C10 H10A . . 109.3 no
    O3 C10 H10B . . 109.3 no
    O3 C10 C11 . . 111.7(11) no
    H10A C10 H10B . . 108.0 no
    H10A C10 C11 . . 109.3 no
    H10B C10 C11 . . 109.3 no
    O4 C11 C10 . . 103.3(10) no
    O4 C11 H11A . . 111.1 no
    O4 C11 H11B . . 111.1 no
    C10 C11 H11A . . 111.1 no
    C10 C11 H11B . . 111.1 no
    H11A C11 H11B . . 109.1 no
    C13 C12 C13 . 2_575 113.3(14) no
    C13 C12 C16 . . 123.3(7) no
    C13 C12 C16 2_575 . 123.3(7) no
    C12 C13 H13 . . 119.0 no
    C12 C13 C14 . . 122.1(10) no
    H13 C13 C14 . . 119.0 no
    C13 C14 H14 . . 116.7 no
    C13 C14 C15 . . 126.7(11) no
    H14 C14 C15 . . 116.7 no
    C14 C15 C14 . 2_575 108.2(16) no
    C14 C15 H15 . . 125.9 no
    C14 C15 H15 2_575 . 125.9 no
    C12 C16 H16A . . 109.5 no
    C12 C16 H16B . . 109.5 no
    C12 C16 H16C . . 109.5 no
    C12 C16 H16D . . 109.5 no
    C12 C16 H16E . . 109.5 no
    C12 C16 H16F . . 109.5 no
    H16A C16 H16B . . 109.5 no
    H16A C16 H16C . . 109.5 no
    H16B C16 H16C . . 109.5 no
    H16D C16 H16E . . 109.5 no
    H16D C16 H16F . . 109.5 no
    H16E C16 H16F . . 109.5 no
data_global
_journal_date_recd_electronic     2003-10-15
_journal_date_accepted     2003-10-20
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2003
_journal_volume     59
_journal_issue     11
_journal_page_first     m1062
_journal_page_last     m1064
_journal_paper_category     EM
_publ_contact_author_name     'Prof. W. Clegg'
_publ_contact_author_address
;
School of Natural Sciences (Chemistry)
University of Newcastle
Newcastle upon Tyne
NE1 7RU
;
_publ_contact_author_email     w.clegg@ncl.ac.uk
_publ_contact_author_fax     '0191 222 6929'
_publ_contact_author_phone     '0191 222 6649'
_publ_section_title
;
Polymeric (18-crown-6)bis(2-amidopyridinecaesium) toluene solvate
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Liddle, Stephen T.' .
;
School of Natural Sciences (Chemistry)
University of Newcastle upon Tyne
Newcastle upon Tyne NE1 7RU
England
;
    'Clegg, William' .
;
School of Natural Sciences (Chemistry)
University of Newcastle upon Tyne
Newcastle upon Tyne NE1 7RU
England
;
