##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
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#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
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#                                                                            #
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data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
μ₃-Chloro-tri-μ-chloro- 1Κ²Cl,2Κ²Cl,3Κ²Cl-triangulo-μ₃
-sulfidohexakis(triphenylphosphine)triruthenium(II)--tetrahydrofuran--water
(1/1.25/0.75)
;
_chemical_name_common
;
'μ₃-Chloro-tri-μ-chloro-μ₃-
sulfidohexakis (triphenylphospine)triruthenium(II)
;
_chemical_formula_moiety     'C108H90Cl4P6Ru3S, 1.25C4H8O, 0.75H2O'
_chemical_formula_sum     'C113 H100 Cl4 O2 P6 Ru3 S'
_chemical_formula_iupac     '[Ru3 Cl4 S (C18 H15 P1)6], 1.25C4 H8 O, 0.75 H2 O'
_chemical_formula_weight     2152.82
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     14.183(4)
_cell_length_b     14.699(5)
_cell_length_c     25.814(9)
_cell_angle_alpha     91.904(11)
_cell_angle_beta     92.328(11)
_cell_angle_gamma     102.784(11)
_cell_volume     5239(3)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     1021
_cell_measurement_theta_min     2.3
_cell_measurement_theta_max     19.4
_cell_measurement_temperature     123(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     red
_exptl_crystal_size_max     0.080
_exptl_crystal_size_mid     0.030
_exptl_crystal_size_min     0.015
_exptl_crystal_density_diffrn     1.365
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     2200
_exptl_absorpt_coefficient_mu     0.365
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Blessings, 1995; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min     0.987
_exptl_absorpt_correction_T_max     0.995
_exptl_special_details
;
Data were collected with a 360° φ scan using 0.3° increments.
A multi-scan
empirical correction for absorption, decay and any beam inhomogeneity
determined
with SADABS (Sheldrick, 1996; Blessing, 1995) was applied to the data. The data
integration and reduction were undertaken with SAINT and XPREP (Bruker, 2001)
and subsequent computations were carried out with the TEXSAN (Molecular
Structure Corporation, 1995), WinGX (Farrugia, 1999) and Xtal3.6 (Hall et al.,
1999) graphical user interfaces. The data reduction included the application of
Lorentz and polarization corrections. The structure was solved in the space
group P\=1 by direct methods with SHELXS97 (Sheldrick, 1997), and extended and
refined with SHELXL97 (Sheldrick, 1997).
;
_diffrn_ambient_temperature     123(2)
_diffrn_radiation_type     synchrotron
_diffrn_radiation_wavelength     0.55940
_diffrn_radiation_source     'ChemMatCARS, APS, Argonne National Lab, USA'
_diffrn_radiation_monochromator     'Double Diamond 111'
_diffrn_measurement_device_type
;
SMART 6000 detector mounted on a Bruker Kappa Platform
;
_diffrn_measurement_method     φ
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     109758
_diffrn_reflns_av_R_equivalents     0.049
_diffrn_reflns_av_sigmaI/netI     0.030
_diffrn_reflns_theta_min     1.3
_diffrn_reflns_theta_max     19.0
_diffrn_reflns_theta_full     19.0
_diffrn_measured_fraction_theta_max     0.870
_diffrn_measured_fraction_theta_full     0.870
_diffrn_reflns_limit_h_min     -14
_diffrn_reflns_limit_h_max     14
_diffrn_reflns_limit_k_min     -16
_diffrn_reflns_limit_k_max     16
_diffrn_reflns_limit_l_min     -29
_diffrn_reflns_limit_l_max     29
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     0
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     15139
_reflns_number_gt     12160
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.116
_refine_ls_R_factor_gt     0.089
_refine_ls_wR_factor_gt     0.223
_refine_ls_wR_factor_ref     0.243
_refine_ls_goodness_of_fit_ref     1.42
_refine_ls_restrained_S_all     1.42
_refine_ls_number_reflns     15139
_refine_ls_number_parameters     1156
_refine_ls_number_restraints     30
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
            'calc w = 1/[σ²(Fo²)+(0.06P)²+6P] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.38
_refine_diff_density_min     -1.25
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0015 0.0009
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.0998 0.0984
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0056 0.0036
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.0667 0.0580
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ru' 'Ru' -5.3630 3.6506
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.0826 0.0763
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART--KAPPA (Bruker, 2001)'
_computing_cell_refinement     'SAINT (Bruker, 2001)'
_computing_data_reduction     'SAINT and XPREP (Bruker, 2001)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics
;
TEXSAN for Windows (Molecular Structure Corporation, 1997),
Xtal3.6 (Hall et al., 1999),
ORTEPII (Johnson, 1976) and WinGX (Farrugia, 1999)
;
_computing_publication_material     ?
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Ru1 0.89559(7) 0.62445(6) 0.20081(3) 0.0232(2) Uani d . 1 . . Ru
    Ru2 0.80558(7) 0.39975(6) 0.21930(3) 0.0234(2) Uani d . 1 . . Ru
    Ru3 0.72397(7) 0.56132(6) 0.28474(3) 0.0240(2) Uani d . 1 . . Ru
    Cl1 0.93095(15) 0.48085(14) 0.16220(7) 0.0150(4) Uani d . 1 . . Cl
    Cl2 0.69038(16) 0.39337(15) 0.28507(8) 0.0196(5) Uani d . 1 . . Cl
    Cl3 0.81337(17) 0.71697(14) 0.25731(7) 0.0187(5) Uani d . 1 . . Cl
    Cl4 0.89304(16) 0.53285(14) 0.28059(7) 0.0161(4) Uani d . 1 . . Cl
    S1 0.73580(16) 0.52788(14) 0.19423(7) 0.0133(4) Uani d . 1 . . S
    P1 1.06235(17) 0.69304(15) 0.21911(8) 0.0146(5) Uani d . 1 . . P
    P2 0.87108(17) 0.71042(15) 0.13116(8) 0.0139(5) Uani d . 1 . . P
    P3 0.88843(17) 0.29634(15) 0.26054(8) 0.0162(5) Uani d . 1 . . P
    P4 0.72402(17) 0.29389(15) 0.15516(8) 0.0136(5) Uani d . 1 . . P
    P5 0.74561(18) 0.60469(17) 0.37448(8) 0.0181(5) Uani d . 1 . . P
    P6 0.56313(17) 0.56460(16) 0.27658(8) 0.0161(5) Uani d . 1 . . P
    C1 1.0994(7) 0.8097(6) 0.2528(3) 0.021(2) Uani d . 1 . . C
    C2 1.0460(8) 0.8271(7) 0.2949(4) 0.030(2) Uani d . 1 . . C
    H2 0.9946 0.7796 0.3057 0.036 Uiso calc R 1 . . H
    C3 1.0688(9) 0.9161(8) 0.3214(4) 0.042(3) Uani d . 1 . . C
    H3 1.0313 0.9286 0.3493 0.050 Uiso calc R 1 . . H
    C4 1.1444(10) 0.9836(8) 0.3069(5) 0.045(3) Uani d . 1 . . C
    H4 1.1615 1.0416 0.3261 0.054 Uiso calc R 1 . . H
    C5 1.1960(10) 0.9684(7) 0.2649(5) 0.044(3) Uani d . 1 . . C
    H5 1.2467 1.0168 0.2542 0.052 Uiso calc R 1 . . H
    C6 1.1739(8) 0.8816(6) 0.2378(4) 0.028(2) Uani d . 1 . . C
    H6 1.2101 0.8714 0.2088 0.033 Uiso calc R 1 . . H
    C7 1.1491(7) 0.7020(6) 0.1668(3) 0.019(2) Uani d . 1 . . C
    C8 1.2485(7) 0.7227(7) 0.1793(4) 0.025(2) Uani d . 1 . . C
    H8 1.2709 0.7318 0.2147 0.031 Uiso calc R 1 . . H
    C9 1.3150(8) 0.7302(7) 0.1410(4) 0.033(2) Uani d . 1 . . C
    H9 1.3824 0.7466 0.1501 0.039 Uiso calc R 1 . . H
    C10 1.2830(9) 0.7137(8) 0.0895(4) 0.039(3) Uani d . 1 . . C
    H10 1.3286 0.7179 0.0632 0.047 Uiso calc R 1 . . H
    C11 1.1856(8) 0.6911(7) 0.0762(3) 0.027(2) Uani d . 1 . . C
    H11 1.1638 0.6796 0.0408 0.033 Uiso calc R 1 . . H
    C12 1.1187(8) 0.6852(6) 0.1149(3) 0.023(2) Uani d . 1 . . C
    H12 1.0514 0.6695 0.1055 0.028 Uiso calc R 1 . . H
    C13 1.1240(7) 0.6233(6) 0.2623(3) 0.020(2) Uani d . 1 . . C
    C14 1.1548(7) 0.6505(7) 0.3138(3) 0.022(2) Uani d . 1 . . C
    H14 1.1393 0.7046 0.3293 0.026 Uiso calc R 1 . . H
    C15 1.2077(7) 0.5991(7) 0.3423(4) 0.028(2) Uani d . 1 . . C
    H15 1.2273 0.6176 0.3774 0.033 Uiso calc R 1 . . H
    C16 1.2321(8) 0.5214(7) 0.3203(4) 0.030(2) Uani d U 1 . . C
    H16 1.2707 0.4879 0.3396 0.036 Uiso calc R 1 . . H
    C17 1.2000(8) 0.4925(7) 0.2697(4) 0.031(2) Uani d . 1 . . C
    H17 1.2149 0.4376 0.2549 0.037 Uiso calc R 1 . . H
    C18 1.1470(7) 0.5419(6) 0.2406(4) 0.021(2) Uani d . 1 . . C
    H18 1.1258 0.5213 0.2059 0.025 Uiso calc R 1 . . H
    C19 0.7548(7) 0.7470(6) 0.1282(3) 0.0147(18) Uani d U 1 . . C
    C20 0.6693(7) 0.6779(6) 0.1168(3) 0.0177(19) Uani d . 1 . . C
    H20 0.6718 0.6139 0.1145 0.021 Uiso calc R 1 . . H
    C21 0.5821(7) 0.7036(7) 0.1089(3) 0.023(2) Uani d . 1 . . C
    H21 0.5247 0.6568 0.1016 0.027 Uiso calc R 1 . . H
    C22 0.5772(8) 0.7964(7) 0.1114(4) 0.029(2) Uani d . 1 . . C
    H22 0.5172 0.8135 0.1046 0.035 Uiso calc R 1 . . H
    C23 0.6607(9) 0.8649(7) 0.1240(5) 0.038(3) Uani d . 1 . . C
    H23 0.6576 0.9288 0.1264 0.046 Uiso calc R 1 . . H
    C24 0.7477(7) 0.8401(6) 0.1329(4) 0.026(2) Uani d . 1 . . C
    H24 0.8039 0.8870 0.1424 0.032 Uiso calc R 1 . . H
    C25 0.9549(7) 0.8244(6) 0.1273(3) 0.0179(19) Uani d U 1 . . C
    C26 0.9705(8) 0.8857(6) 0.1710(4) 0.025(2) Uani d . 1 . . C
    H26 0.9396 0.8656 0.2019 0.030 Uiso calc R 1 . . H
    C27 1.0299(8) 0.9756(6) 0.1710(4) 0.030(2) Uani d . 1 . . C
    H27 1.0367 1.0167 0.2008 0.036 Uiso calc R 1 . . H
    C28 1.0789(8) 1.0035(7) 0.1265(4) 0.034(3) Uani d . 1 . . C
    H28 1.1215 1.0632 0.1262 0.041 Uiso calc R 1 . . H
    C29 1.0655(8) 0.9436(7) 0.0824(4) 0.033(2) Uani d . 1 . . C
    H29 1.0982 0.9631 0.0520 0.040 Uiso calc R 1 . . H
    C30 1.0041(7) 0.8553(6) 0.0829(4) 0.023(2) Uani d . 1 . . C
    H30 0.9956 0.8152 0.0527 0.028 Uiso calc R 1 . . H
    C31 0.8648(7) 0.6649(6) 0.0620(3) 0.0177(19) Uani d . 1 . . C
    C32 0.8245(6) 0.7113(6) 0.0232(3) 0.0158(18) Uani d . 1 . . C
    H32 0.8005 0.7649 0.0320 0.019 Uiso calc R 1 . . H
    C33 0.8195(7) 0.6789(6) -0.0283(3) 0.021(2) Uani d . 1 . . C
    H33 0.7928 0.7113 -0.0543 0.025 Uiso calc R 1 . . H
    C34 0.8526(7) 0.6008(7) -0.0423(3) 0.024(2) Uani d . 1 . . C
    H34 0.8480 0.5789 -0.0776 0.028 Uiso calc R 1 . . H
    C35 0.8929(7) 0.5543(6) -0.0040(3) 0.021(2) Uani d . 1 . . C
    H35 0.9157 0.5001 -0.0133 0.026 Uiso calc R 1 . . H
    C36 0.9000(6) 0.5866(6) 0.0477(3) 0.0149(18) Uani d . 1 . . C
    H36 0.9291 0.5553 0.0734 0.018 Uiso calc R 1 . . H
    C37 1.0080(7) 0.2850(6) 0.2398(3) 0.0168(18) Uani d U 1 . . C
    C38 1.0290(7) 0.2962(6) 0.1885(3) 0.021(2) Uani d . 1 . . C
    H38 0.9849 0.3158 0.1650 0.025 Uiso calc R 1 . . H
    C39 1.1163(8) 0.2785(7) 0.1710(4) 0.029(2) Uani d . 1 . . C
    H39 1.1307 0.2862 0.1356 0.035 Uiso calc R 1 . . H
    C40 1.1812(8) 0.2498(7) 0.2048(4) 0.030(2) Uani d . 1 . . C
    H40 1.2401 0.2385 0.1927 0.036 Uiso calc R 1 . . H
    C41 1.1597(8) 0.2379(7) 0.2558(4) 0.033(2) Uani d . 1 . . C
    H41 1.2035 0.2171 0.2789 0.040 Uiso calc R 1 . . H
    C42 1.0746(8) 0.2560(7) 0.2737(4) 0.027(2) Uani d . 1 . . C
    H42 1.0612 0.2488 0.3093 0.032 Uiso calc R 1 . . H
    C43 0.8296(7) 0.1710(6) 0.2662(3) 0.021(2) Uani d . 1 . . C
    C44 0.8805(8) 0.0994(7) 0.2634(4) 0.030(2) Uani d . 1 . . C
    H44 0.9477 0.1151 0.2574 0.036 Uiso calc R 1 . . H
    C45 0.8358(9) 0.0062(7) 0.2690(4) 0.036(3) Uani d . 1 . . C
    H45 0.8720 -0.0409 0.2670 0.044 Uiso calc R 1 . . H
    C46 0.7382(10) -0.0171(7) 0.2776(5) 0.042(3) Uani d . 1 . . C
    H46 0.7063 -0.0803 0.2818 0.050 Uiso calc R 1 . . H
    C47 0.6867(9) 0.0543(7) 0.2802(4) 0.036(3) Uani d U 1 . . C
    H47 0.6194 0.0391 0.2860 0.043 Uiso calc R 1 . . H
    C48 0.7328(7) 0.1465(7) 0.2745(4) 0.027(2) Uani d . 1 . . C
    H48 0.6966 0.1936 0.2764 0.032 Uiso calc R 1 . . H
    C49 0.9155(8) 0.3285(7) 0.3308(3) 0.024(2) Uani d . 1 . . C
    C50 1.0007(8) 0.3934(7) 0.3472(4) 0.028(2) Uani d . 1 . . C
    H50 1.0425 0.4233 0.3220 0.034 Uiso calc R 1 . . H
    C51 1.0246(9) 0.4144(9) 0.3991(4) 0.044(3) Uani d . 1 . . C
    H51 1.0848 0.4550 0.4095 0.053 Uiso calc R 1 . . H
    C52 0.9603(10) 0.3760(10) 0.4365(4) 0.049(3) Uani d . 1 . . C
    H52 0.9761 0.3917 0.4723 0.058 Uiso calc R 1 . . H
    C53 0.8754(10) 0.3164(9) 0.4214(4) 0.046(3) Uani d . 1 . . C
    H53 0.8312 0.2915 0.4467 0.055 Uiso calc R 1 . . H
    C54 0.8526(8) 0.2914(8) 0.3693(4) 0.033(2) Uani d . 1 . . C
    H54 0.7935 0.2485 0.3595 0.039 Uiso calc R 1 . . H
    C55 0.8031(7) 0.2337(6) 0.1188(3) 0.0179(19) Uani d . 1 . . C
    C56 0.8531(7) 0.2781(6) 0.0778(3) 0.0173(18) Uani d . 1 . . C
    H56 0.8422 0.3363 0.0672 0.021 Uiso calc R 1 . . H
    C57 0.9189(7) 0.2369(7) 0.0525(3) 0.024(2) Uani d . 1 . . C
    H57 0.9531 0.2678 0.0249 0.029 Uiso calc R 1 . . H
    C58 0.9354(8) 0.1510(6) 0.0669(3) 0.025(2) Uani d . 1 . . C
    H58 0.9797 0.1229 0.0491 0.030 Uiso calc R 1 . . H
    C59 0.8857(7) 0.1075(6) 0.1077(4) 0.023(2) Uani d . 1 . . C
    H59 0.8952 0.0484 0.1177 0.028 Uiso calc R 1 . . H
    C60 0.8225(7) 0.1495(6) 0.1342(3) 0.020(2) Uani d . 1 . . C
    H60 0.7919 0.1204 0.1633 0.024 Uiso calc R 1 . . H
    C61 0.6217(7) 0.1973(6) 0.1701(3) 0.0188(19) Uani d . 1 . . C
    C62 0.6008(8) 0.1097(7) 0.1437(4) 0.029(2) Uani d . 1 . . C
    H62 0.6436 0.0962 0.1187 0.034 Uiso calc R 1 . . H
    C63 0.5171(9) 0.0411(7) 0.1536(5) 0.040(3) Uani d . 1 . . C
    H63 0.5041 -0.0180 0.1354 0.048 Uiso calc R 1 . . H
    C64 0.4557(9) 0.0600(8) 0.1893(5) 0.041(3) Uani d . 1 . . C
    H64 0.4005 0.0133 0.1967 0.050 Uiso calc R 1 . . H
    C65 0.4727(8) 0.1471(7) 0.2151(4) 0.032(2) Uani d . 1 . . C
    H65 0.4277 0.1612 0.2387 0.038 Uiso calc R 1 . . H
    C66 0.5578(8) 0.2144(7) 0.2060(4) 0.026(2) Uani d . 1 . . C
    H66 0.5712 0.2726 0.2250 0.031 Uiso calc R 1 . . H
    C67 0.6649(7) 0.3387(6) 0.0983(3) 0.0152(18) Uani d . 1 . . C
    C68 0.5875(7) 0.2819(6) 0.0688(3) 0.022(2) Uani d . 1 . . C
    H68 0.5627 0.2195 0.0781 0.027 Uiso calc R 1 . . H
    C69 0.5465(8) 0.3170(7) 0.0253(3) 0.027(2) Uani d . 1 . . C
    H69 0.4932 0.2784 0.0060 0.033 Uiso calc R 1 . . H
    C70 0.5827(7) 0.4066(7) 0.0105(3) 0.025(2) Uani d . 1 . . C
    H70 0.5532 0.4301 -0.0183 0.030 Uiso calc R 1 . . H
    C71 0.6631(8) 0.4630(7) 0.0379(3) 0.023(2) Uani d . 1 . . C
    H71 0.6898 0.5242 0.0271 0.027 Uiso calc R 1 . . H
    C72 0.7032(7) 0.4283(6) 0.0810(3) 0.0180(19) Uani d . 1 . . C
    H72 0.7581 0.4664 0.0993 0.022 Uiso calc R 1 . . H
    C73 0.7233(7) 0.5150(7) 0.4236(3) 0.022(2) Uani d . 1 . . C
    C74 0.6567(7) 0.4320(7) 0.4127(3) 0.025(2) Uani d . 1 . . C
    H74 0.6250 0.4206 0.3793 0.029 Uiso calc R 1 . . H
    C75 0.6345(8) 0.3639(7) 0.4502(4) 0.029(2) Uani d . 1 . . C
    H75 0.5884 0.3073 0.4418 0.035 Uiso calc R 1 . . H
    C76 0.6800(9) 0.3793(8) 0.4997(4) 0.038(3) Uani d . 1 . . C
    H76 0.6659 0.3334 0.5250 0.045 Uiso calc R 1 . . H
    C77 0.7461(8) 0.4625(8) 0.5112(4) 0.034(3) Uani d . 1 . . C
    H77 0.7768 0.4743 0.5449 0.040 Uiso calc R 1 . . H
    C78 0.7684(8) 0.5297(8) 0.4738(3) 0.031(2) Uani d . 1 . . C
    H78 0.8147 0.5862 0.4823 0.038 Uiso calc R 1 . . H
    C79 0.8685(8) 0.6668(8) 0.3966(3) 0.033(3) Uani d . 1 . . C
    C80 0.9387(8) 0.6126(9) 0.4014(4) 0.036(3) Uani d . 1 . . C
    H80 0.9228 0.5484 0.3906 0.043 Uiso calc R 1 . . H
    C81 1.0321(9) 0.6534(11) 0.4219(4) 0.050(4) Uani d . 1 . . C
    H81 1.0791 0.6166 0.4256 0.061 Uiso calc R 1 . . H
    C82 1.0562(10) 0.7480(13) 0.4371(4) 0.061(5) Uani d . 1 . . C
    H82 1.1193 0.7756 0.4512 0.074 Uiso calc R 1 . . H
    C83 0.9885(11) 0.8012(11) 0.4314(5) 0.058(4) Uani d . 1 . . C
    H83 1.0055 0.8657 0.4415 0.070 Uiso calc R 1 . . H
    C84 0.8959(9) 0.7623(9) 0.4112(4) 0.044(3) Uani d . 1 . . C
    H84 0.8504 0.8006 0.4072 0.052 Uiso calc R 1 . . H
    C85 0.6812(8) 0.6903(7) 0.4011(3) 0.026(2) Uani d . 1 . . C
    C86 0.6401(9) 0.6847(8) 0.4491(4) 0.034(3) Uani d . 1 . . C
    H86 0.6423 0.6330 0.4699 0.041 Uiso calc R 1 . . H
    C87 0.5952(10) 0.7546(9) 0.4673(4) 0.046(3) Uani d . 1 . . C
    H87 0.5671 0.7499 0.5002 0.055 Uiso calc R 1 . . H
    C88 0.5918(11) 0.8302(9) 0.4376(5) 0.053(4) Uani d . 1 . . C
    H88 0.5606 0.8771 0.4498 0.063 Uiso calc R 1 . . H
    C89 0.6340(10) 0.8379(8) 0.3897(4) 0.044(3) Uani d . 1 . . C
    H89 0.6327 0.8905 0.3695 0.053 Uiso calc R 1 . . H
    C90 0.6781(8) 0.7684(7) 0.3716(4) 0.033(2) Uani d . 1 . . C
    H90 0.7066 0.7737 0.3389 0.039 Uiso calc R 1 . . H
    C91 0.4889(7) 0.4915(7) 0.3238(3) 0.020(2) Uani d . 1 . . C
    C92 0.4433(8) 0.3976(6) 0.3104(4) 0.024(2) Uani d . 1 . . C
    H92 0.4459 0.3734 0.2760 0.029 Uiso calc R 1 . . H
    C93 0.3941(9) 0.3395(8) 0.3476(4) 0.038(3) Uani d . 1 . . C
    H93 0.3653 0.2758 0.3388 0.046 Uiso calc R 1 . . H
    C94 0.3881(9) 0.3767(9) 0.3979(4) 0.039(3) Uani d . 1 . . C
    H94 0.3537 0.3383 0.4230 0.047 Uiso calc R 1 . . H
    C95 0.4307(8) 0.4664(9) 0.4110(4) 0.037(3) Uani d . 1 . . C
    H95 0.4268 0.4904 0.4452 0.045 Uiso calc R 1 . . H
    C96 0.4812(7) 0.5253(7) 0.3739(3) 0.022(2) Uani d . 1 . . C
    H96 0.5102 0.5885 0.3836 0.027 Uiso calc R 1 . . H
    C97 0.5264(7) 0.6764(6) 0.2804(3) 0.020(2) Uani d . 1 . . C
    C98 0.4472(8) 0.6919(7) 0.3081(4) 0.033(2) Uani d . 1 . . C
    H98 0.4158 0.6458 0.3304 0.040 Uiso calc R 1 . . H
    C99 0.4152(9) 0.7731(8) 0.3032(5) 0.043(3) Uani d . 1 . . C
    H99 0.3614 0.7819 0.3220 0.052 Uiso calc R 1 . . H
    C100 0.4604(9) 0.8429(7) 0.2712(5) 0.041(3) Uani d . 1 . . C
    H100 0.4397 0.8999 0.2690 0.049 Uiso calc R 1 . . H
    C101 0.5346(9) 0.8272(7) 0.2434(4) 0.033(3) Uani d . 1 . . C
    H101 0.5636 0.8726 0.2201 0.040 Uiso calc R 1 . . H
    C102 0.5694(7) 0.7469(7) 0.2480(4) 0.025(2) Uani d . 1 . . C
    H102 0.6232 0.7394 0.2288 0.030 Uiso calc R 1 . . H
    C103 0.4918(7) 0.5158(6) 0.2156(3) 0.0183(19) Uani d . 1 . . C
    C104 0.4128(8) 0.5498(7) 0.1987(4) 0.028(2) Uani d . 1 . . C
    H104 0.3973 0.6016 0.2166 0.034 Uiso calc R 1 . . H
    C105 0.3555(9) 0.5074(7) 0.1548(4) 0.035(3) Uani d . 1 . . C
    H105 0.3005 0.5300 0.1437 0.042 Uiso calc R 1 . . H
    C106 0.3785(8) 0.4339(8) 0.1280(4) 0.035(3) Uani d . 1 . . C
    H106 0.3406 0.4068 0.0978 0.042 Uiso calc R 1 . . H
    C107 0.4557(8) 0.3994(9) 0.1445(4) 0.040(3) Uani d . 1 . . C
    H107 0.4701 0.3473 0.1264 0.048 Uiso calc R 1 . . H
    C108 0.5138(8) 0.4400(7) 0.1878(4) 0.031(2) Uani d . 1 . . C
    H108 0.5682 0.4163 0.1985 0.037 Uiso calc R 1 . . H
    O1 0.2577(14) 0.1076(12) 0.0451(7) 0.065(5) Uiso d PG 0.50 . . O
    C109 0.247(2) 0.0571(18) -0.0036(7) 0.103(13) Uiso d PG 0.50 . . C
    H10A 0.2620 0.1006 -0.0320 0.123 Uiso calc PR 0.50 . . H
    H10B 0.1794 0.0207 -0.0095 0.123 Uiso calc PR 0.50 . . H
    C110 0.315(3) -0.0060(19) -0.0017(9) 0.115(15) Uiso d PG 0.50 . . C
    H11A 0.3770 0.0234 -0.0163 0.137 Uiso calc PR 0.50 . . H
    H11B 0.2869 -0.0656 -0.0213 0.137 Uiso calc PR 0.50 . . H
    C111 0.327(2) -0.0211(17) 0.0546(11) 0.092(11) Uiso d PG 0.50 . . C
    H11C 0.2772 -0.0745 0.0654 0.110 Uiso calc PR 0.50 . . H
    H11D 0.3920 -0.0328 0.0632 0.110 Uiso calc PR 0.50 . . H
    C112 0.3160(19) 0.0673(17) 0.0798(7) 0.099(12) Uiso d PG 0.50 . . C
    H11E 0.2844 0.0552 0.1132 0.119 Uiso calc PR 0.50 . . H
    H11F 0.3801 0.1101 0.0868 0.119 Uiso calc PR 0.50 . . H
    O2 0.139(2) 0.2160(17) 0.4205(12) 0.056(9) Uiso d PG 0.25 . . O
    C113 0.041(2) 0.170(2) 0.4264(15) 0.060(15) Uiso d PG 0.25 . . C
    H11G 0.0017 0.1734 0.3945 0.072 Uiso calc PR 0.25 . . H
    H11H 0.0144 0.1992 0.4557 0.072 Uiso calc PR 0.25 . . H
    C114 0.041(2) 0.0714(19) 0.4367(14) 0.036(10) Uiso d PG 0.25 . . C
    H11I 0.0294 0.0322 0.4042 0.044 Uiso calc PR 0.25 . . H
    H11J -0.0096 0.0460 0.4611 0.044 Uiso calc PR 0.25 . . H
    C115 0.139(3) 0.076(2) 0.4603(15) 0.054(13) Uiso d PG 0.25 . . C
    H11K 0.1411 0.0868 0.4984 0.065 Uiso calc PR 0.25 . . H
    H11L 0.1608 0.0174 0.4524 0.065 Uiso calc PR 0.25 . . H
    C116 0.2005(18) 0.156(2) 0.4355(17) 0.073(18) Uiso d PG 0.25 . . C
    H11M 0.2530 0.1889 0.4602 0.087 Uiso calc PR 0.25 . . H
    H11N 0.2301 0.1336 0.4048 0.087 Uiso calc PR 0.25 . . H
    O3 0.512(3) 0.140(2) 0.3667(13) 0.062(10) Uiso d PG 0.25 . . O
    C117 0.550(3) 0.103(3) 0.4113(17) 0.12(3) Uiso d PG 0.25 . . C
    H11O 0.5780 0.1533 0.4372 0.144 Uiso calc PR 0.25 . . H
    H11P 0.6005 0.0696 0.4016 0.144 Uiso calc PR 0.25 . . H
    C118 0.468(4) 0.037(4) 0.4330(15) 0.08(2) Uiso d PG 0.25 . . C
    H11Q 0.4377 0.0683 0.4602 0.101 Uiso calc PR 0.25 . . H
    H11R 0.4893 -0.0168 0.4479 0.101 Uiso calc PR 0.25 . . H
    C119 0.399(3) 0.006(3) 0.387(2) 0.12(3) Uiso d PG 0.25 . . C
    H11S 0.4138 -0.0488 0.3687 0.142 Uiso calc PR 0.25 . . H
    H11T 0.3315 -0.0098 0.3980 0.142 Uiso calc PR 0.25 . . H
    C120 0.416(3) 0.088(3) 0.3546(15) 0.055(13) Uiso d PG 0.25 . . C
    H12A 0.4078 0.0680 0.3174 0.066 Uiso calc PR 0.25 . . H
    H12B 0.3690 0.1273 0.3620 0.066 Uiso calc PR 0.25 . . H
    O4 0.425(2) 0.0651(16) 0.0081(12) 0.053 Uiso d PG 0.25 . . O
    C121 0.336(3) 0.058(2) 0.0325(15) 0.09(2) Uiso d PG 0.25 . . C
    H12C 0.3048 0.1090 0.0214 0.106 Uiso calc PR 0.25 . . H
    H12D 0.3472 0.0641 0.0707 0.106 Uiso calc PR 0.25 . . H
    C122 0.2741(19) -0.034(2) 0.0167(17) 0.054 Uiso d PG 0.25 . . C
    H12E 0.2319 -0.0293 -0.0142 0.065 Uiso calc PR 0.25 . . H
    H12F 0.2332 -0.0597 0.0452 0.065 Uiso calc PR 0.25 . . H
    C123 0.345(2) -0.0917(15) 0.0045(13) 0.031(9) Uiso d PG 0.25 . . C
    H12G 0.3640 -0.1214 0.0359 0.037 Uiso calc PR 0.25 . . H
    H12H 0.3173 -0.1409 -0.0225 0.037 Uiso calc PR 0.25 . . H
    C124 0.428(2) -0.024(2) -0.0145(13) 0.050 Uiso d PG 0.25 . . C
    H12I 0.4893 -0.0413 -0.0041 0.060 Uiso calc PR 0.25 . . H
    H12J 0.4228 -0.0229 -0.0528 0.060 Uiso calc PR 0.25 . . H
    O5 -0.091(3) -0.012(2) 0.4486(13) 0.036(9) Uiso d P 0.20 . . O
    O6 0.383(4) -0.014(3) -0.0224(18) 0.057(12) Uiso d P 0.20 . . O
    O7 0.031(4) 0.138(4) 0.404(2) 0.040(13) Uiso d P 0.15 . . O
    O8 0.213(3) 0.169(3) 0.4069(16) 0.048(10) Uiso d P 0.20 . . O
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ru1 P2 . 2.290(2) ?
    Ru1 P1 . 2.378(3) ?
    Ru1 S1 . 2.389(2) ?
    Ru1 Cl3 . 2.459(2) ?
    Ru1 Cl1 . 2.464(2) ?
    Ru1 Cl4 . 2.495(2) ?
    Ru2 P4 . 2.319(2) ?
    Ru2 P3 . 2.371(2) ?
    Ru2 Cl2 . 2.394(2) ?
    Ru2 S1 . 2.408(2) ?
    Ru2 Cl1 . 2.479(2) ?
    Ru2 Cl4 . 2.536(2) ?
    Ru3 P6 . 2.294(3) ?
    Ru3 P5 . 2.372(2) ?
    Ru3 S1 . 2.392(2) ?
    Ru3 Cl2 . 2.409(2) ?
    Ru3 Cl3 . 2.498(2) ?
    Ru3 Cl4 . 2.530(2) ?
    P1 C7 . 1.851(9) ?
    P1 C1 . 1.854(9) ?
    P1 C13 . 1.859(9) ?
    P2 C25 . 1.836(9) ?
    P2 C19 . 1.844(9) ?
    P2 C31 . 1.877(8) ?
    P3 C37 . 1.839(9) ?
    P3 C43 . 1.860(9) ?
    P3 C49 . 1.862(9) ?
    P4 C55 . 1.842(9) ?
    P4 C61 . 1.855(9) ?
    P4 C67 . 1.871(9) ?
    P5 C79 . 1.838(11) ?
    P5 C85 . 1.843(10) ?
    P5 C73 . 1.846(9) ?
    P6 C97 . 1.832(9) ?
    P6 C91 . 1.855(9) ?
    P6 C103 . 1.869(8) ?
    C1 C6 . 1.396(14) ?
    C1 C2 . 1.398(14) ?
    C2 C3 . 1.420(15) ?
    C2 H2 . 0.9500 ?
    C3 C4 . 1.363(17) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.372(17) ?
    C4 H4 . 0.9500 ?
    C5 C6 . 1.401(14) ?
    C5 H5 . 0.9500 ?
    C6 H6 . 0.9500 ?
    C7 C12 . 1.389(13) ?
    C7 C8 . 1.398(14) ?
    C8 C9 . 1.383(15) ?
    C8 H8 . 0.9500 ?
    C9 C10 . 1.384(16) ?
    C9 H9 . 0.9500 ?
    C10 C11 . 1.374(17) ?
    C10 H10 . 0.9500 ?
    C11 C12 . 1.396(14) ?
    C11 H11 . 0.9500 ?
    C12 H12 . 0.9500 ?
    C13 C14 . 1.400(13) ?
    C13 C18 . 1.412(13) ?
    C14 C15 . 1.386(14) ?
    C14 H14 . 0.9500 ?
    C15 C16 . 1.376(15) ?
    C15 H15 . 0.9500 ?
    C16 C17 . 1.388(15) ?
    C16 H16 . 0.9500 ?
    C17 C18 . 1.374(13) ?
    C17 H17 . 0.9500 ?
    C18 H18 . 0.9500 ?
    C19 C24 . 1.395(12) ?
    C19 C20 . 1.412(13) ?
    C20 C21 . 1.379(14) ?
    C20 H20 . 0.9500 ?
    C21 C22 . 1.381(14) ?
    C21 H21 . 0.9500 ?
    C22 C23 . 1.394(16) ?
    C22 H22 . 0.9500 ?
    C23 C24 . 1.374(16) ?
    C23 H23 . 0.9500 ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.399(13) ?
    C25 C30 . 1.402(13) ?
    C26 C27 . 1.401(14) ?
    C26 H26 . 0.9500 ?
    C27 C28 . 1.394(16) ?
    C27 H27 . 0.9500 ?
    C28 C29 . 1.395(15) ?
    C28 H28 . 0.9500 ?
    C29 C30 . 1.395(13) ?
    C29 H29 . 0.9500 ?
    C30 H30 . 0.9500 ?
    C31 C36 . 1.397(12) ?
    C31 C32 . 1.403(12) ?
    C32 C33 . 1.389(12) ?
    C32 H32 . 0.9500 ?
    C33 C34 . 1.376(14) ?
    C33 H33 . 0.9500 ?
    C34 C35 . 1.394(13) ?
    C34 H34 . 0.9500 ?
    C35 C36 . 1.396(12) ?
    C35 H35 . 0.9500 ?
    C36 H36 . 0.9500 ?
    C37 C38 . 1.376(12) ?
    C37 C42 . 1.407(13) ?
    C38 C39 . 1.408(14) ?
    C38 H38 . 0.9500 ?
    C39 C40 . 1.383(15) ?
    C39 H39 . 0.9500 ?
    C40 C41 . 1.372(15) ?
    C40 H40 . 0.9500 ?
    C41 C42 . 1.387(16) ?
    C41 H41 . 0.9500 ?
    C42 H42 . 0.9500 ?
    C43 C48 . 1.368(14) ?
    C43 C44 . 1.404(14) ?
    C44 C45 . 1.392(15) ?
    C44 H44 . 0.9500 ?
    C45 C46 . 1.379(17) ?
    C45 H45 . 0.9500 ?
    C46 C47 . 1.407(17) ?
    C46 H46 . 0.9500 ?
    C47 C48 . 1.384(14) ?
    C47 H47 . 0.9500 ?
    C48 H48 . 0.9500 ?
    C49 C50 . 1.403(14) ?
    C49 C54 . 1.404(14) ?
    C50 C51 . 1.376(14) ?
    C50 H50 . 0.9500 ?
    C51 C52 . 1.401(17) ?
    C51 H51 . 0.9500 ?
    C52 C53 . 1.357(18) ?
    C52 H52 . 0.9500 ?
    C53 C54 . 1.389(15) ?
    C53 H53 . 0.9500 ?
    C54 H54 . 0.9500 ?
    C55 C60 . 1.392(12) ?
    C55 C56 . 1.397(12) ?
    C56 C57 . 1.393(13) ?
    C56 H56 . 0.9500 ?
    C57 C58 . 1.393(13) ?
    C57 H57 . 0.9500 ?
    C58 C59 . 1.388(14) ?
    C58 H58 . 0.9500 ?
    C59 C60 . 1.385(13) ?
    C59 H59 . 0.9500 ?
    C60 H60 . 0.9500 ?
    C61 C66 . 1.377(14) ?
    C61 C62 . 1.402(13) ?
    C62 C63 . 1.416(15) ?
    C62 H62 . 0.9500 ?
    C63 C64 . 1.356(17) ?
    C63 H63 . 0.9500 ?
    C64 C65 . 1.391(15) ?
    C64 H64 . 0.9500 ?
    C65 C66 . 1.415(14) ?
    C65 H65 . 0.9500 ?
    C66 H66 . 0.9500 ?
    C67 C68 . 1.402(13) ?
    C67 C72 . 1.404(12) ?
    C68 C69 . 1.408(13) ?
    C68 H68 . 0.9500 ?
    C69 C70 . 1.376(14) ?
    C69 H69 . 0.9500 ?
    C70 C71 . 1.401(14) ?
    C70 H70 . 0.9500 ?
    C71 C72 . 1.393(13) ?
    C71 H71 . 0.9500 ?
    C72 H72 . 0.9500 ?
    C73 C74 . 1.380(14) ?
    C73 C78 . 1.409(13) ?
    C74 C75 . 1.410(13) ?
    C74 H74 . 0.9500 ?
    C75 C76 . 1.396(15) ?
    C75 H75 . 0.9500 ?
    C76 C77 . 1.381(16) ?
    C76 H76 . 0.9500 ?
    C77 C78 . 1.399(14) ?
    C77 H77 . 0.9500 ?
    C78 H78 . 0.9500 ?
    C79 C84 . 1.406(16) ?
    C79 C80 . 1.411(17) ?
    C80 C81 . 1.402(16) ?
    C80 H80 . 0.9500 ?
    C81 C82 . 1.39(2) ?
    C81 H81 . 0.9500 ?
    C82 C83 . 1.37(2) ?
    C82 H82 . 0.9500 ?
    C83 C84 . 1.384(18) ?
    C83 H83 . 0.9500 ?
    C84 H84 . 0.9500 ?
    C85 C86 . 1.388(14) ?
    C85 C90 . 1.407(15) ?
    C86 C87 . 1.400(17) ?
    C86 H86 . 0.9500 ?
    C87 C88 . 1.381(18) ?
    C87 H87 . 0.9500 ?
    C88 C89 . 1.394(17) ?
    C88 H88 . 0.9500 ?
    C89 C90 . 1.388(15) ?
    C89 H89 . 0.9500 ?
    C90 H90 . 0.9500 ?
    C91 C96 . 1.388(13) ?
    C91 C92 . 1.414(13) ?
    C92 C93 . 1.410(14) ?
    C92 H92 . 0.9500 ?
    C93 C94 . 1.405(17) ?
    C93 H93 . 0.9500 ?
    C94 C95 . 1.349(17) ?
    C94 H94 . 0.9500 ?
    C95 C96 . 1.419(14) ?
    C95 H95 . 0.9500 ?
    C96 H96 . 0.9500 ?
    C97 C102 . 1.401(13) ?
    C97 C98 . 1.412(14) ?
    C98 C99 . 1.375(16) ?
    C98 H98 . 0.9500 ?
    C99 C100 . 1.399(17) ?
    C99 H99 . 0.9500 ?
    C100 C101 . 1.354(17) ?
    C100 H100 . 0.9500 ?
    C101 C102 . 1.383(15) ?
    C101 H101 . 0.9500 ?
    C102 H102 . 0.9500 ?
    C103 C104 . 1.385(14) ?
    C103 C108 . 1.404(14) ?
    C104 C105 . 1.409(14) ?
    C104 H104 . 0.9500 ?
    C105 C106 . 1.371(16) ?
    C105 H105 . 0.9500 ?
    C106 C107 . 1.364(17) ?
    C106 H106 . 0.9500 ?
    C107 C108 . 1.394(14) ?
    C107 H107 . 0.9500 ?
    C108 H108 . 0.9500 ?
    O1 C112 . 1.4233 ?
    O1 C109 . 1.4234 ?
    C109 C110 . 1.4766 ?
    C109 H10A . 0.9900 ?
    C109 H10B . 0.9900 ?
    C110 C111 . 1.4888 ?
    C110 H11A . 0.9900 ?
    C110 H11B . 0.9900 ?
    C111 C112 . 1.4766 ?
    C111 H11C . 0.9900 ?
    C111 H11D . 0.9900 ?
    C112 H11E . 0.9900 ?
    C112 H11F . 0.9900 ?
    O2 C116 . 1.4233 ?
    O2 C113 . 1.4234 ?
    C113 C114 . 1.4766 ?
    C113 H11G . 0.9900 ?
    C113 H11H . 0.9900 ?
    C114 C115 . 1.4889 ?
    C114 H11I . 0.9900 ?
    C114 H11J . 0.9900 ?
    C115 C116 . 1.4766 ?
    C115 H11K . 0.9900 ?
    C115 H11L . 0.9900 ?
    C116 H11M . 0.9900 ?
    C116 H11N . 0.9900 ?
    O3 C117 . 1.4233 ?
    O3 C120 . 1.4233 ?
    C117 C118 . 1.4766 ?
    C117 H11O . 0.9900 ?
    C117 H11P . 0.9900 ?
    C118 C119 . 1.4888 ?
    C118 H11Q . 0.9900 ?
    C118 H11R . 0.9900 ?
    C119 C120 . 1.4766 ?
    C119 H11S . 0.9900 ?
    C119 H11T . 0.9900 ?
    C120 H12A . 0.9900 ?
    C120 H12B . 0.9900 ?
    O4 C121 . 1.4233 ?
    O4 C124 . 1.4234 ?
    C121 C122 . 1.4766 ?
    C121 H12C . 0.9900 ?
    C121 H12D . 0.9900 ?
    C122 C123 . 1.4889 ?
    C122 H12E . 0.9900 ?
    C122 H12F . 0.9900 ?
    C123 C124 . 1.4767 ?
    C123 H12G . 0.9900 ?
    C123 H12H . 0.9900 ?
    C124 H12I . 0.9900 ?
    C124 H12J . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    P2 Ru1 P1 . . 98.04(8) ?
    P2 Ru1 S1 . . 94.42(8) ?
    P1 Ru1 S1 . . 166.94(8) ?
    P2 Ru1 Cl3 . . 91.14(8) ?
    P1 Ru1 Cl3 . . 103.22(8) ?
    S1 Ru1 Cl3 . . 80.36(8) ?
    P2 Ru1 Cl1 . . 104.52(8) ?
    P1 Ru1 Cl1 . . 92.62(8) ?
    S1 Ru1 Cl1 . . 80.41(8) ?
    Cl3 Ru1 Cl1 . . 156.01(8) ?
    P2 Ru1 Cl4 . . 169.92(9) ?
    P1 Ru1 Cl4 . . 90.02(8) ?
    S1 Ru1 Cl4 . . 78.03(7) ?
    Cl3 Ru1 Cl4 . . 81.09(8) ?
    Cl1 Ru1 Cl4 . . 81.01(7) ?
    P4 Ru2 P3 . . 96.70(9) ?
    P4 Ru2 Cl2 . . 103.64(9) ?
    P3 Ru2 Cl2 . . 94.21(8) ?
    P4 Ru2 S1 . . 96.17(8) ?
    P3 Ru2 S1 . . 166.98(8) ?
    Cl2 Ru2 S1 . . 80.82(8) ?
    P4 Ru2 Cl1 . . 95.14(8) ?
    P3 Ru2 Cl1 . . 101.06(8) ?
    Cl2 Ru2 Cl1 . . 154.22(8) ?
    S1 Ru2 Cl1 . . 79.73(8) ?
    P4 Ru2 Cl4 . . 172.04(8) ?
    P3 Ru2 Cl4 . . 90.39(8) ?
    Cl2 Ru2 Cl4 . . 79.33(8) ?
    S1 Ru2 Cl4 . . 76.90(8) ?
    Cl1 Ru2 Cl4 . . 79.90(7) ?
    P6 Ru3 P5 . . 96.56(9) ?
    P6 Ru3 S1 . . 93.96(8) ?
    P5 Ru3 S1 . . 168.78(9) ?
    P6 Ru3 Cl2 . . 93.07(9) ?
    P5 Ru3 Cl2 . . 102.44(8) ?
    S1 Ru3 Cl2 . . 80.84(7) ?
    P6 Ru3 Cl3 . . 105.48(8) ?
    P5 Ru3 Cl3 . . 93.86(8) ?
    S1 Ru3 Cl3 . . 79.52(7) ?
    Cl2 Ru3 Cl3 . . 153.75(8) ?
    P6 Ru3 Cl4 . . 169.07(8) ?
    P5 Ru3 Cl4 . . 92.66(8) ?
    S1 Ru3 Cl4 . . 77.31(7) ?
    Cl2 Ru3 Cl4 . . 79.18(8) ?
    Cl3 Ru3 Cl4 . . 79.65(8) ?
    Ru1 Cl1 Ru2 . . 84.55(7) ?
    Ru2 Cl2 Ru3 . . 87.07(7) ?
    Ru1 Cl3 Ru3 . . 84.20(7) ?
    Ru1 Cl4 Ru3 . . 82.81(7) ?
    Ru1 Cl4 Ru2 . . 82.73(7) ?
    Ru3 Cl4 Ru2 . . 81.55(7) ?
    Ru1 S1 Ru3 . . 88.06(7) ?
    Ru1 S1 Ru2 . . 87.74(8) ?
    Ru3 S1 Ru2 . . 87.13(7) ?
    C7 P1 C1 . . 102.2(4) ?
    C7 P1 C13 . . 96.2(4) ?
    C1 P1 C13 . . 100.5(4) ?
    C7 P1 Ru1 . . 120.1(3) ?
    C1 P1 Ru1 . . 120.2(3) ?
    C13 P1 Ru1 . . 113.4(3) ?
    C25 P2 C19 . . 99.8(4) ?
    C25 P2 C31 . . 101.0(4) ?
    C19 P2 C31 . . 96.6(4) ?
    C25 P2 Ru1 . . 116.4(3) ?
    C19 P2 Ru1 . . 115.3(3) ?
    C31 P2 Ru1 . . 123.5(3) ?
    C37 P3 C43 . . 99.9(4) ?
    C37 P3 C49 . . 101.1(4) ?
    C43 P3 C49 . . 98.6(4) ?
    C37 P3 Ru2 . . 120.6(3) ?
    C43 P3 Ru2 . . 121.1(3) ?
    C49 P3 Ru2 . . 111.8(3) ?
    C55 P4 C61 . . 103.0(4) ?
    C55 P4 C67 . . 97.7(4) ?
    C61 P4 C67 . . 98.0(4) ?
    C55 P4 Ru2 . . 113.9(3) ?
    C61 P4 Ru2 . . 121.5(3) ?
    C67 P4 Ru2 . . 118.8(3) ?
    C79 P5 C85 . . 97.1(5) ?
    C79 P5 C73 . . 99.4(5) ?
    C85 P5 C73 . . 100.9(4) ?
    C79 P5 Ru3 . . 115.6(3) ?
    C85 P5 Ru3 . . 119.1(3) ?
    C73 P5 Ru3 . . 120.5(3) ?
    C97 P6 C91 . . 104.9(4) ?
    C97 P6 C103 . . 97.8(4) ?
    C91 P6 C103 . . 98.9(4) ?
    C97 P6 Ru3 . . 120.0(3) ?
    C91 P6 Ru3 . . 112.9(3) ?
    C103 P6 Ru3 . . 119.3(3) ?
    C6 C1 C2 . . 118.3(9) ?
    C6 C1 P1 . . 124.6(7) ?
    C2 C1 P1 . . 117.0(7) ?
    C1 C2 C3 . . 119.8(10) ?
    C1 C2 H2 . . 120.1 ?
    C3 C2 H2 . . 120.1 ?
    C4 C3 C2 . . 120.3(11) ?
    C4 C3 H3 . . 119.8 ?
    C2 C3 H3 . . 119.8 ?
    C3 C4 C5 . . 120.6(10) ?
    C3 C4 H4 . . 119.7 ?
    C5 C4 H4 . . 119.7 ?
    C4 C5 C6 . . 120.0(11) ?
    C4 C5 H5 . . 120.0 ?
    C6 C5 H5 . . 120.0 ?
    C1 C6 C5 . . 120.9(10) ?
    C1 C6 H6 . . 119.5 ?
    C5 C6 H6 . . 119.5 ?
    C12 C7 C8 . . 118.0(8) ?
    C12 C7 P1 . . 122.1(8) ?
    C8 C7 P1 . . 119.9(7) ?
    C9 C8 C7 . . 121.2(9) ?
    C9 C8 H8 . . 119.4 ?
    C7 C8 H8 . . 119.4 ?
    C8 C9 C10 . . 119.8(11) ?
    C8 C9 H9 . . 120.1 ?
    C10 C9 H9 . . 120.1 ?
    C11 C10 C9 . . 120.3(9) ?
    C11 C10 H10 . . 119.9 ?
    C9 C10 H10 . . 119.9 ?
    C10 C11 C12 . . 119.8(9) ?
    C10 C11 H11 . . 120.1 ?
    C12 C11 H11 . . 120.1 ?
    C7 C12 C11 . . 121.0(10) ?
    C7 C12 H12 . . 119.5 ?
    C11 C12 H12 . . 119.5 ?
    C14 C13 C18 . . 118.5(9) ?
    C14 C13 P1 . . 123.6(7) ?
    C18 C13 P1 . . 117.8(7) ?
    C15 C14 C13 . . 120.3(9) ?
    C15 C14 H14 . . 119.8 ?
    C13 C14 H14 . . 119.8 ?
    C16 C15 C14 . . 120.7(9) ?
    C16 C15 H15 . . 119.6 ?
    C14 C15 H15 . . 119.6 ?
    C15 C16 C17 . . 119.4(9) ?
    C15 C16 H16 . . 120.3 ?
    C17 C16 H16 . . 120.3 ?
    C18 C17 C16 . . 121.0(10) ?
    C18 C17 H17 . . 119.5 ?
    C16 C17 H17 . . 119.5 ?
    C17 C18 C13 . . 119.9(9) ?
    C17 C18 H18 . . 120.0 ?
    C13 C18 H18 . . 120.0 ?
    C24 C19 C20 . . 118.3(9) ?
    C24 C19 P2 . . 123.3(7) ?
    C20 C19 P2 . . 118.2(6) ?
    C21 C20 C19 . . 119.9(8) ?
    C21 C20 H20 . . 120.0 ?
    C19 C20 H20 . . 120.0 ?
    C20 C21 C22 . . 120.9(9) ?
    C20 C21 H21 . . 119.6 ?
    C22 C21 H21 . . 119.6 ?
    C21 C22 C23 . . 119.6(10) ?
    C21 C22 H22 . . 120.2 ?
    C23 C22 H22 . . 120.2 ?
    C24 C23 C22 . . 120.0(10) ?
    C24 C23 H23 . . 120.0 ?
    C22 C23 H23 . . 120.0 ?
    C23 C24 C19 . . 121.1(9) ?
    C23 C24 H24 . . 119.4 ?
    C19 C24 H24 . . 119.4 ?
    C26 C25 C30 . . 117.2(8) ?
    C26 C25 P2 . . 118.6(7) ?
    C30 C25 P2 . . 124.2(7) ?
    C25 C26 C27 . . 122.6(9) ?
    C25 C26 H26 . . 118.7 ?
    C27 C26 H26 . . 118.7 ?
    C28 C27 C26 . . 118.7(9) ?
    C28 C27 H27 . . 120.6 ?
    C26 C27 H27 . . 120.6 ?
    C27 C28 C29 . . 120.0(9) ?
    C27 C28 H28 . . 120.0 ?
    C29 C28 H28 . . 120.0 ?
    C30 C29 C28 . . 120.3(10) ?
    C30 C29 H29 . . 119.9 ?
    C28 C29 H29 . . 119.9 ?
    C29 C30 C25 . . 121.2(9) ?
    C29 C30 H30 . . 119.4 ?
    C25 C30 H30 . . 119.4 ?
    C36 C31 C32 . . 118.6(7) ?
    C36 C31 P2 . . 122.1(7) ?
    C32 C31 P2 . . 119.3(7) ?
    C33 C32 C31 . . 120.1(8) ?
    C33 C32 H32 . . 119.9 ?
    C31 C32 H32 . . 119.9 ?
    C34 C33 C32 . . 121.4(8) ?
    C34 C33 H33 . . 119.3 ?
    C32 C33 H33 . . 119.3 ?
    C33 C34 C35 . . 118.9(8) ?
    C33 C34 H34 . . 120.5 ?
    C35 C34 H34 . . 120.5 ?
    C34 C35 C36 . . 120.6(8) ?
    C34 C35 H35 . . 119.7 ?
    C36 C35 H35 . . 119.7 ?
    C35 C36 C31 . . 120.3(8) ?
    C35 C36 H36 . . 119.8 ?
    C31 C36 H36 . . 119.8 ?
    C38 C37 C42 . . 119.0(9) ?
    C38 C37 P3 . . 119.1(7) ?
    C42 C37 P3 . . 121.6(7) ?
    C37 C38 C39 . . 119.7(9) ?
    C37 C38 H38 . . 120.1 ?
    C39 C38 H38 . . 120.1 ?
    C40 C39 C38 . . 120.8(9) ?
    C40 C39 H39 . . 119.6 ?
    C38 C39 H39 . . 119.6 ?
    C41 C40 C39 . . 119.5(10) ?
    C41 C40 H40 . . 120.3 ?
    C39 C40 H40 . . 120.3 ?
    C40 C41 C42 . . 120.4(9) ?
    C40 C41 H41 . . 119.8 ?
    C42 C41 H41 . . 119.8 ?
    C41 C42 C37 . . 120.6(9) ?
    C41 C42 H42 . . 119.7 ?
    C37 C42 H42 . . 119.7 ?
    C48 C43 C44 . . 117.7(9) ?
    C48 C43 P3 . . 119.3(7) ?
    C44 C43 P3 . . 123.0(8) ?
    C45 C44 C43 . . 122.2(11) ?
    C45 C44 H44 . . 118.9 ?
    C43 C44 H44 . . 118.9 ?
    C46 C45 C44 . . 119.3(11) ?
    C46 C45 H45 . . 120.4 ?
    C44 C45 H45 . . 120.4 ?
    C45 C46 C47 . . 118.9(10) ?
    C45 C46 H46 . . 120.6 ?
    C47 C46 H46 . . 120.6 ?
    C48 C47 C46 . . 120.8(11) ?
    C48 C47 H47 . . 119.6 ?
    C46 C47 H47 . . 119.6 ?
    C43 C48 C47 . . 121.2(10) ?
    C43 C48 H48 . . 119.4 ?
    C47 C48 H48 . . 119.4 ?
    C50 C49 C54 . . 117.2(9) ?
    C50 C49 P3 . . 120.2(7) ?
    C54 C49 P3 . . 122.6(8) ?
    C51 C50 C49 . . 121.2(9) ?
    C51 C50 H50 . . 119.4 ?
    C49 C50 H50 . . 119.4 ?
    C50 C51 C52 . . 120.1(11) ?
    C50 C51 H51 . . 120.0 ?
    C52 C51 H51 . . 120.0 ?
    C53 C52 C51 . . 119.7(10) ?
    C53 C52 H52 . . 120.2 ?
    C51 C52 H52 . . 120.2 ?
    C52 C53 C54 . . 120.6(11) ?
    C52 C53 H53 . . 119.7 ?
    C54 C53 H53 . . 119.7 ?
    C53 C54 C49 . . 121.1(11) ?
    C53 C54 H54 . . 119.5 ?
    C49 C54 H54 . . 119.5 ?
    C60 C55 C56 . . 118.5(9) ?
    C60 C55 P4 . . 122.0(7) ?
    C56 C55 P4 . . 119.1(7) ?
    C57 C56 C55 . . 119.9(8) ?
    C57 C56 H56 . . 120.0 ?
    C55 C56 H56 . . 120.0 ?
    C58 C57 C56 . . 121.2(8) ?
    C58 C57 H57 . . 119.4 ?
    C56 C57 H57 . . 119.4 ?
    C59 C58 C57 . . 118.6(9) ?
    C59 C58 H58 . . 120.7 ?
    C57 C58 H58 . . 120.7 ?
    C60 C59 C58 . . 120.5(8) ?
    C60 C59 H59 . . 119.7 ?
    C58 C59 H59 . . 119.7 ?
    C59 C60 C55 . . 121.2(8) ?
    C59 C60 H60 . . 119.4 ?
    C55 C60 H60 . . 119.4 ?
    C66 C61 C62 . . 117.7(9) ?
    C66 C61 P4 . . 118.5(7) ?
    C62 C61 P4 . . 123.6(7) ?
    C61 C62 C63 . . 121.3(10) ?
    C61 C62 H62 . . 119.4 ?
    C63 C62 H62 . . 119.4 ?
    C64 C63 C62 . . 119.7(10) ?
    C64 C63 H63 . . 120.2 ?
    C62 C63 H63 . . 120.2 ?
    C63 C64 C65 . . 120.6(10) ?
    C63 C64 H64 . . 119.7 ?
    C65 C64 H64 . . 119.7 ?
    C64 C65 C66 . . 119.3(10) ?
    C64 C65 H65 . . 120.3 ?
    C66 C65 H65 . . 120.3 ?
    C61 C66 C65 . . 121.4(9) ?
    C61 C66 H66 . . 119.3 ?
    C65 C66 H66 . . 119.3 ?
    C68 C67 C72 . . 117.8(8) ?
    C68 C67 P4 . . 121.7(7) ?
    C72 C67 P4 . . 120.2(7) ?
    C67 C68 C69 . . 120.2(9) ?
    C67 C68 H68 . . 119.9 ?
    C69 C68 H68 . . 119.9 ?
    C70 C69 C68 . . 120.8(9) ?
    C70 C69 H69 . . 119.6 ?
    C68 C69 H69 . . 119.6 ?
    C69 C70 C71 . . 120.0(9) ?
    C69 C70 H70 . . 120.0 ?
    C71 C70 H70 . . 120.0 ?
    C72 C71 C70 . . 119.1(9) ?
    C72 C71 H71 . . 120.5 ?
    C70 C71 H71 . . 120.5 ?
    C71 C72 C67 . . 122.0(9) ?
    C71 C72 H72 . . 119.0 ?
    C67 C72 H72 . . 119.0 ?
    C74 C73 C78 . . 117.7(9) ?
    C74 C73 P5 . . 120.0(7) ?
    C78 C73 P5 . . 122.2(8) ?
    C73 C74 C75 . . 121.4(9) ?
    C73 C74 H74 . . 119.3 ?
    C75 C74 H74 . . 119.3 ?
    C76 C75 C74 . . 120.2(10) ?
    C76 C75 H75 . . 119.9 ?
    C74 C75 H75 . . 119.9 ?
    C77 C76 C75 . . 118.8(9) ?
    C77 C76 H76 . . 120.6 ?
    C75 C76 H76 . . 120.6 ?
    C76 C77 C78 . . 120.8(9) ?
    C76 C77 H77 . . 119.6 ?
    C78 C77 H77 . . 119.6 ?
    C77 C78 C73 . . 121.0(10) ?
    C77 C78 H78 . . 119.5 ?
    C73 C78 H78 . . 119.5 ?
    C84 C79 C80 . . 118.3(10) ?
    C84 C79 P5 . . 125.0(9) ?
    C80 C79 P5 . . 116.7(9) ?
    C81 C80 C79 . . 120.1(12) ?
    C81 C80 H80 . . 119.9 ?
    C79 C80 H80 . . 119.9 ?
    C82 C81 C80 . . 120.0(13) ?
    C82 C81 H81 . . 120.0 ?
    C80 C81 H81 . . 120.0 ?
    C83 C82 C81 . . 119.8(12) ?
    C83 C82 H82 . . 120.1 ?
    C81 C82 H82 . . 120.1 ?
    C82 C83 C84 . . 121.1(14) ?
    C82 C83 H83 . . 119.5 ?
    C84 C83 H83 . . 119.5 ?
    C83 C84 C79 . . 120.6(14) ?
    C83 C84 H84 . . 119.7 ?
    C79 C84 H84 . . 119.7 ?
    C86 C85 C90 . . 118.5(10) ?
    C86 C85 P5 . . 124.3(8) ?
    C90 C85 P5 . . 117.2(7) ?
    C85 C86 C87 . . 120.7(10) ?
    C85 C86 H86 . . 119.7 ?
    C87 C86 H86 . . 119.7 ?
    C88 C87 C86 . . 120.1(10) ?
    C88 C87 H87 . . 119.9 ?
    C86 C87 H87 . . 119.9 ?
    C87 C88 C89 . . 120.1(11) ?
    C87 C88 H88 . . 120.0 ?
    C89 C88 H88 . . 120.0 ?
    C90 C89 C88 . . 119.7(11) ?
    C90 C89 H89 . . 120.1 ?
    C88 C89 H89 . . 120.1 ?
    C89 C90 C85 . . 120.9(10) ?
    C89 C90 H90 . . 119.6 ?
    C85 C90 H90 . . 119.6 ?
    C96 C91 C92 . . 118.2(8) ?
    C96 C91 P6 . . 121.3(7) ?
    C92 C91 P6 . . 120.4(7) ?
    C93 C92 C91 . . 120.5(9) ?
    C93 C92 H92 . . 119.7 ?
    C91 C92 H92 . . 119.7 ?
    C94 C93 C92 . . 119.3(10) ?
    C94 C93 H93 . . 120.4 ?
    C92 C93 H93 . . 120.4 ?
    C95 C94 C93 . . 120.6(10) ?
    C95 C94 H94 . . 119.7 ?
    C93 C94 H94 . . 119.7 ?
    C94 C95 C96 . . 120.6(9) ?
    C94 C95 H95 . . 119.7 ?
    C96 C95 H95 . . 119.7 ?
    C91 C96 C95 . . 120.8(9) ?
    C91 C96 H96 . . 119.6 ?
    C95 C96 H96 . . 119.6 ?
    C102 C97 C98 . . 116.9(9) ?
    C102 C97 P6 . . 118.4(7) ?
    C98 C97 P6 . . 123.9(7) ?
    C99 C98 C97 . . 120.6(10) ?
    C99 C98 H98 . . 119.7 ?
    C97 C98 H98 . . 119.7 ?
    C98 C99 C100 . . 121.2(12) ?
    C98 C99 H99 . . 119.4 ?
    C100 C99 H99 . . 119.4 ?
    C101 C100 C99 . . 118.2(10) ?
    C101 C100 H100 . . 120.9 ?
    C99 C100 H100 . . 120.9 ?
    C100 C101 C102 . . 122.0(10) ?
    C100 C101 H101 . . 119.0 ?
    C102 C101 H101 . . 119.0 ?
    C101 C102 C97 . . 120.9(10) ?
    C101 C102 H102 . . 119.5 ?
    C97 C102 H102 . . 119.5 ?
    C104 C103 C108 . . 118.8(8) ?
    C104 C103 P6 . . 120.7(7) ?
    C108 C103 P6 . . 120.4(8) ?
    C103 C104 C105 . . 119.9(10) ?
    C103 C104 H104 . . 120.1 ?
    C105 C104 H104 . . 120.1 ?
    C106 C105 C104 . . 120.5(11) ?
    C106 C105 H105 . . 119.8 ?
    C104 C105 H105 . . 119.8 ?
    C107 C106 C105 . . 120.0(10) ?
    C107 C106 H106 . . 120.0 ?
    C105 C106 H106 . . 120.0 ?
    C106 C107 C108 . . 120.8(11) ?
    C106 C107 H107 . . 119.6 ?
    C108 C107 H107 . . 119.6 ?
    C107 C108 C103 . . 120.0(11) ?
    C107 C108 H108 . . 120.0 ?
    C103 C108 H108 . . 120.0 ?
    C112 O1 C109 . . 108.8 ?
    O1 C109 C110 . . 107.1 ?
    O1 C109 H10A . . 110.3 ?
    C110 C109 H10A . . 110.3 ?
    O1 C109 H10B . . 110.3 ?
    C110 C109 H10B . . 110.3 ?
    H10A C109 H10B . . 108.6 ?
    C109 C110 C111 . . 103.6 ?
    C109 C110 H11A . . 111.0 ?
    C111 C110 H11A . . 111.0 ?
    C109 C110 H11B . . 111.0 ?
    C111 C110 H11B . . 111.0 ?
    H11A C110 H11B . . 109.0 ?
    C112 C111 C110 . . 103.6 ?
    C112 C111 H11C . . 111.0 ?
    C110 C111 H11C . . 111.0 ?
    C112 C111 H11D . . 111.0 ?
    C110 C111 H11D . . 111.0 ?
    H11C C111 H11D . . 109.0 ?
    O1 C112 C111 . . 107.1 ?
    O1 C112 H11E . . 110.3 ?
    C111 C112 H11E . . 110.3 ?
    O1 C112 H11F . . 110.3 ?
    C111 C112 H11F . . 110.3 ?
    H11E C112 H11F . . 108.5 ?
    C116 O2 C113 . . 108.8 ?
    O2 C113 C114 . . 107.1 ?
    O2 C113 H11G . . 110.3 ?
    C114 C113 H11G . . 110.3 ?
    O2 C113 H11H . . 110.3 ?
    C114 C113 H11H . . 110.3 ?
    H11G C113 H11H . . 108.6 ?
    C113 C114 C115 . . 103.6 ?
    C113 C114 H11I . . 111.0 ?
    C115 C114 H11I . . 111.0 ?
    C113 C114 H11J . . 111.0 ?
    C115 C114 H11J . . 111.0 ?
    H11I C114 H11J . . 109.0 ?
    C116 C115 C114 . . 103.6 ?
    C116 C115 H11K . . 111.0 ?
    C114 C115 H11K . . 111.0 ?
    C116 C115 H11L . . 111.0 ?
    C114 C115 H11L . . 111.0 ?
    H11K C115 H11L . . 109.0 ?
    O2 C116 C115 . . 107.1 ?
    O2 C116 H11M . . 110.3 ?
    C115 C116 H11M . . 110.3 ?
    O2 C116 H11N . . 110.3 ?
    C115 C116 H11N . . 110.3 ?
    H11M C116 H11N . . 108.6 ?
    C117 O3 C120 . . 108.8 ?
    O3 C117 C118 . . 107.1 ?
    O3 C117 H11O . . 110.3 ?
    C118 C117 H11O . . 110.3 ?
    O3 C117 H11P . . 110.3 ?
    C118 C117 H11P . . 110.3 ?
    H11O C117 H11P . . 108.6 ?
    C117 C118 C119 . . 103.6 ?
    C117 C118 H11Q . . 111.0 ?
    C119 C118 H11Q . . 111.0 ?
    C117 C118 H11R . . 111.0 ?
    C119 C118 H11R . . 111.0 ?
    H11Q C118 H11R . . 109.0 ?
    C120 C119 C118 . . 103.6 ?
    C120 C119 H11S . . 111.0 ?
    C118 C119 H11S . . 111.0 ?
    C120 C119 H11T . . 111.0 ?
    C118 C119 H11T . . 111.0 ?
    H11S C119 H11T . . 109.0 ?
    O3 C120 C119 . . 107.1 ?
    O3 C120 H12A . . 110.3 ?
    C119 C120 H12A . . 110.3 ?
    O3 C120 H12B . . 110.3 ?
    C119 C120 H12B . . 110.3 ?
    H12A C120 H12B . . 108.6 ?
    C121 O4 C124 . . 108.8 ?
    O4 C121 C122 . . 107.1 ?
    O4 C121 H12C . . 110.3 ?
    C122 C121 H12C . . 110.3 ?
    O4 C121 H12D . . 110.3 ?
    C122 C121 H12D . . 110.3 ?
    H12C C121 H12D . . 108.6 ?
    C121 C122 C123 . . 103.6 ?
    C121 C122 H12E . . 111.0 ?
    C123 C122 H12E . . 111.0 ?
    C121 C122 H12F . . 111.0 ?
    C123 C122 H12F . . 111.0 ?
    H12E C122 H12F . . 109.0 ?
    C124 C123 C122 . . 103.6 ?
    C124 C123 H12G . . 111.0 ?
    C122 C123 H12G . . 111.0 ?
    C124 C123 H12H . . 111.0 ?
    C122 C123 H12H . . 111.0 ?
    H12G C123 H12H . . 109.0 ?
    O4 C124 C123 . . 107.1 ?
    O4 C124 H12I . . 110.3 ?
    C123 C124 H12I . . 110.3 ?
    O4 C124 H12J . . 110.3 ?
    C123 C124 H12J . . 110.3 ?
    H12I C124 H12J . . 108.6 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    P2 Ru1 Cl1 Ru2 . . . . -129.90(8) ?
    P1 Ru1 Cl1 Ru2 . . . . 131.10(7) ?
    S1 Ru1 Cl1 Ru2 . . . . -37.78(7) ?
    Cl3 Ru1 Cl1 Ru2 . . . . -0.7(2) ?
    Cl4 Ru1 Cl1 Ru2 . . . . 41.49(7) ?
    P4 Ru2 Cl1 Ru1 . . . . 132.88(8) ?
    P3 Ru2 Cl1 Ru1 . . . . -129.25(8) ?
    Cl2 Ru2 Cl1 Ru1 . . . . -4.1(2) ?
    S1 Ru2 Cl1 Ru1 . . . . 37.53(7) ?
    Cl4 Ru2 Cl1 Ru1 . . . . -40.84(7) ?
    P4 Ru2 Cl2 Ru3 . . . . -129.97(8) ?
    P3 Ru2 Cl2 Ru3 . . . . 132.08(8) ?
    S1 Ru2 Cl2 Ru3 . . . . -35.80(7) ?
    Cl1 Ru2 Cl2 Ru3 . . . . 5.6(2) ?
    Cl4 Ru2 Cl2 Ru3 . . . . 42.48(7) ?
    P6 Ru3 Cl2 Ru2 . . . . 129.60(8) ?
    P5 Ru3 Cl2 Ru2 . . . . -132.99(8) ?
    S1 Ru3 Cl2 Ru2 . . . . 36.08(7) ?
    Cl3 Ru3 Cl2 Ru2 . . . . -5.9(2) ?
    Cl4 Ru3 Cl2 Ru2 . . . . -42.63(7) ?
    P2 Ru1 Cl3 Ru3 . . . . 131.97(8) ?
    P1 Ru1 Cl3 Ru3 . . . . -129.50(7) ?
    S1 Ru1 Cl3 Ru3 . . . . 37.68(7) ?
    Cl1 Ru1 Cl3 Ru3 . . . . 0.5(2) ?
    Cl4 Ru1 Cl3 Ru3 . . . . -41.59(7) ?
    P6 Ru3 Cl3 Ru1 . . . . -128.99(8) ?
    P5 Ru3 Cl3 Ru1 . . . . 133.11(8) ?
    S1 Ru3 Cl3 Ru1 . . . . -37.75(7) ?
    Cl2 Ru3 Cl3 Ru1 . . . . 4.4(2) ?
    Cl4 Ru3 Cl3 Ru1 . . . . 41.11(7) ?
    P2 Ru1 Cl4 Ru3 . . . . 1.2(5) ?
    P1 Ru1 Cl4 Ru3 . . . . 144.48(7) ?
    S1 Ru1 Cl4 Ru3 . . . . -40.86(7) ?
    Cl3 Ru1 Cl4 Ru3 . . . . 41.09(7) ?
    Cl1 Ru1 Cl4 Ru3 . . . . -122.88(7) ?
    P2 Ru1 Cl4 Ru2 . . . . 83.5(5) ?
    P1 Ru1 Cl4 Ru2 . . . . -133.18(8) ?
    S1 Ru1 Cl4 Ru2 . . . . 41.48(7) ?
    Cl3 Ru1 Cl4 Ru2 . . . . 123.43(8) ?
    Cl1 Ru1 Cl4 Ru2 . . . . -40.54(7) ?
    P6 Ru3 Cl4 Ru1 . . . . 78.5(4) ?
    P5 Ru3 Cl4 Ru1 . . . . -133.96(8) ?
    S1 Ru3 Cl4 Ru1 . . . . 40.95(7) ?
    Cl2 Ru3 Cl4 Ru1 . . . . 123.88(7) ?
    Cl3 Ru3 Cl4 Ru1 . . . . -40.52(6) ?
    P6 Ru3 Cl4 Ru2 . . . . -5.2(4) ?
    P5 Ru3 Cl4 Ru2 . . . . 142.37(7) ?
    S1 Ru3 Cl4 Ru2 . . . . -42.73(6) ?
    Cl2 Ru3 Cl4 Ru2 . . . . 40.20(6) ?
    Cl3 Ru3 Cl4 Ru2 . . . . -124.19(7) ?
    P4 Ru2 Cl4 Ru1 . . . . -11.5(6) ?
    P3 Ru2 Cl4 Ru1 . . . . 141.55(8) ?
    Cl2 Ru2 Cl4 Ru1 . . . . -124.25(8) ?
    S1 Ru2 Cl4 Ru1 . . . . -41.30(7) ?
    Cl1 Ru2 Cl4 Ru1 . . . . 40.39(7) ?
    P4 Ru2 Cl4 Ru3 . . . . 72.2(6) ?
    P3 Ru2 Cl4 Ru3 . . . . -134.69(7) ?
    Cl2 Ru2 Cl4 Ru3 . . . . -40.49(7) ?
    S1 Ru2 Cl4 Ru3 . . . . 42.46(7) ?
    Cl1 Ru2 Cl4 Ru3 . . . . 124.15(7) ?
    P2 Ru1 S1 Ru3 . . . . -129.87(8) ?
    P1 Ru1 S1 Ru3 . . . . 67.7(4) ?
    Cl3 Ru1 S1 Ru3 . . . . -39.46(7) ?
    Cl1 Ru1 S1 Ru3 . . . . 126.13(7) ?
    Cl4 Ru1 S1 Ru3 . . . . 43.38(7) ?
    P2 Ru1 S1 Ru2 . . . . 142.93(7) ?
    P1 Ru1 S1 Ru2 . . . . -19.5(4) ?
    Cl3 Ru1 S1 Ru2 . . . . -126.66(8) ?
    Cl1 Ru1 S1 Ru2 . . . . 38.93(7) ?
    Cl4 Ru1 S1 Ru2 . . . . -43.82(7) ?
    P6 Ru3 S1 Ru1 . . . . 143.86(8) ?
    P5 Ru3 S1 Ru1 . . . . -15.7(5) ?
    Cl2 Ru3 S1 Ru1 . . . . -123.66(8) ?
    Cl3 Ru3 S1 Ru1 . . . . 38.84(7) ?
    Cl4 Ru3 S1 Ru1 . . . . -42.79(7) ?
    P6 Ru3 S1 Ru2 . . . . -128.30(8) ?
    P5 Ru3 S1 Ru2 . . . . 72.2(5) ?
    Cl2 Ru3 S1 Ru2 . . . . -35.83(8) ?
    Cl3 Ru3 S1 Ru2 . . . . 126.67(8) ?
    Cl4 Ru3 S1 Ru2 . . . . 45.04(7) ?
    P4 Ru2 S1 Ru1 . . . . -132.86(8) ?
    P3 Ru2 S1 Ru1 . . . . 55.9(4) ?
    Cl2 Ru2 S1 Ru1 . . . . 124.26(8) ?
    Cl1 Ru2 S1 Ru1 . . . . -38.73(7) ?
    Cl4 Ru2 S1 Ru1 . . . . 43.18(7) ?
    P4 Ru2 S1 Ru3 . . . . 138.97(8) ?
    P3 Ru2 S1 Ru3 . . . . -32.2(4) ?
    Cl2 Ru2 S1 Ru3 . . . . 36.09(7) ?
    Cl1 Ru2 S1 Ru3 . . . . -126.90(8) ?
    Cl4 Ru2 S1 Ru3 . . . . -44.99(7) ?
    P2 Ru1 P1 C7 . . . . -51.4(3) ?
    S1 Ru1 P1 C7 . . . . 110.9(5) ?
    Cl3 Ru1 P1 C7 . . . . -144.5(3) ?
    Cl1 Ru1 P1 C7 . . . . 53.6(3) ?
    Cl4 Ru1 P1 C7 . . . . 134.6(3) ?
    P2 Ru1 P1 C1 . . . . 76.9(3) ?
    S1 Ru1 P1 C1 . . . . -120.7(4) ?
    Cl3 Ru1 P1 C1 . . . . -16.2(3) ?
    Cl1 Ru1 P1 C1 . . . . -178.0(3) ?
    Cl4 Ru1 P1 C1 . . . . -97.0(3) ?
    P2 Ru1 P1 C13 . . . . -164.2(3) ?
    S1 Ru1 P1 C13 . . . . -1.8(5) ?
    Cl3 Ru1 P1 C13 . . . . 102.7(3) ?
    Cl1 Ru1 P1 C13 . . . . -59.1(3) ?
    Cl4 Ru1 P1 C13 . . . . 21.9(3) ?
    P1 Ru1 P2 C25 . . . . -23.7(3) ?
    S1 Ru1 P2 C25 . . . . 160.3(3) ?
    Cl3 Ru1 P2 C25 . . . . 79.9(3) ?
    Cl1 Ru1 P2 C25 . . . . -118.5(3) ?
    Cl4 Ru1 P2 C25 . . . . 119.2(5) ?
    P1 Ru1 P2 C19 . . . . -140.1(3) ?
    S1 Ru1 P2 C19 . . . . 43.8(3) ?
    Cl3 Ru1 P2 C19 . . . . -36.6(3) ?
    Cl1 Ru1 P2 C19 . . . . 125.0(3) ?
    Cl4 Ru1 P2 C19 . . . . 2.7(6) ?
    P1 Ru1 P2 C31 . . . . 102.1(4) ?
    S1 Ru1 P2 C31 . . . . -74.0(4) ?
    Cl3 Ru1 P2 C31 . . . . -154.4(4) ?
    Cl1 Ru1 P2 C31 . . . . 7.3(4) ?
    Cl4 Ru1 P2 C31 . . . . -115.1(6) ?
    P4 Ru2 P3 C37 . . . . 89.5(3) ?
    Cl2 Ru2 P3 C37 . . . . -166.2(3) ?
    S1 Ru2 P3 C37 . . . . -99.3(5) ?
    Cl1 Ru2 P3 C37 . . . . -7.1(3) ?
    Cl4 Ru2 P3 C37 . . . . -86.9(3) ?
    P4 Ru2 P3 C43 . . . . -36.5(3) ?
    Cl2 Ru2 P3 C43 . . . . 67.8(3) ?
    S1 Ru2 P3 C43 . . . . 134.7(5) ?
    Cl1 Ru2 P3 C43 . . . . -133.1(3) ?
    Cl4 Ru2 P3 C43 . . . . 147.1(3) ?
    P4 Ru2 P3 C49 . . . . -151.9(4) ?
    Cl2 Ru2 P3 C49 . . . . -47.6(4) ?
    S1 Ru2 P3 C49 . . . . 19.3(6) ?
    Cl1 Ru2 P3 C49 . . . . 111.5(4) ?
    Cl4 Ru2 P3 C49 . . . . 31.7(4) ?
    P3 Ru2 P4 C55 . . . . -51.7(3) ?
    Cl2 Ru2 P4 C55 . . . . -147.7(3) ?
    S1 Ru2 P4 C55 . . . . 130.3(3) ?
    Cl1 Ru2 P4 C55 . . . . 50.1(3) ?
    Cl4 Ru2 P4 C55 . . . . 101.2(7) ?
    P3 Ru2 P4 C61 . . . . 72.4(4) ?
    Cl2 Ru2 P4 C61 . . . . -23.6(4) ?
    S1 Ru2 P4 C61 . . . . -105.6(4) ?
    Cl1 Ru2 P4 C61 . . . . 174.2(4) ?
    Cl4 Ru2 P4 C61 . . . . -134.7(7) ?
    P3 Ru2 P4 C67 . . . . -165.9(3) ?
    Cl2 Ru2 P4 C67 . . . . 98.1(3) ?
    S1 Ru2 P4 C67 . . . . 16.1(3) ?
    Cl1 Ru2 P4 C67 . . . . -64.1(3) ?
    Cl4 Ru2 P4 C67 . . . . -13.0(8) ?
    P6 Ru3 P5 C79 . . . . -151.8(4) ?
    S1 Ru3 P5 C79 . . . . 7.7(7) ?
    Cl2 Ru3 P5 C79 . . . . 113.6(4) ?
    Cl3 Ru3 P5 C79 . . . . -45.7(4) ?
    Cl4 Ru3 P5 C79 . . . . 34.1(4) ?
    P6 Ru3 P5 C85 . . . . -36.7(4) ?
    S1 Ru3 P5 C85 . . . . 122.8(5) ?
    Cl2 Ru3 P5 C85 . . . . -131.3(4) ?
    Cl3 Ru3 P5 C85 . . . . 69.4(4) ?
    Cl4 Ru3 P5 C85 . . . . 149.2(4) ?
    P6 Ru3 P5 C73 . . . . 88.8(4) ?
    S1 Ru3 P5 C73 . . . . -111.8(6) ?
    Cl2 Ru3 P5 C73 . . . . -5.8(4) ?
    Cl3 Ru3 P5 C73 . . . . -165.1(4) ?
    Cl4 Ru3 P5 C73 . . . . -85.3(4) ?
    P5 Ru3 P6 C97 . . . . 70.6(3) ?
    S1 Ru3 P6 C97 . . . . -105.5(3) ?
    Cl2 Ru3 P6 C97 . . . . 173.5(3) ?
    Cl3 Ru3 P6 C97 . . . . -25.3(3) ?
    Cl4 Ru3 P6 C97 . . . . -142.1(5) ?
    P5 Ru3 P6 C91 . . . . -53.9(3) ?
    S1 Ru3 P6 C91 . . . . 130.1(3) ?
    Cl2 Ru3 P6 C91 . . . . 49.1(3) ?
    Cl3 Ru3 P6 C91 . . . . -149.7(3) ?
    Cl4 Ru3 P6 C91 . . . . 93.5(5) ?
    P5 Ru3 P6 C103 . . . . -169.3(3) ?
    S1 Ru3 P6 C103 . . . . 14.6(3) ?
    Cl2 Ru3 P6 C103 . . . . -66.4(3) ?
    Cl3 Ru3 P6 C103 . . . . 94.9(3) ?
    Cl4 Ru3 P6 C103 . . . . -22.0(6) ?
    C7 P1 C1 C6 . . . . 1.5(10) ?
    C13 P1 C1 C6 . . . . 100.2(9) ?
    Ru1 P1 C1 C6 . . . . -134.6(8) ?
    C7 P1 C1 C2 . . . . 179.0(8) ?
    C13 P1 C1 C2 . . . . -82.3(8) ?
    Ru1 P1 C1 C2 . . . . 42.9(9) ?
    C6 C1 C2 C3 . . . . -0.5(15) ?
    P1 C1 C2 C3 . . . . -178.1(8) ?
    C1 C2 C3 C4 . . . . -2.0(18) ?
    C2 C3 C4 C5 . . . . 4(2) ?
    C3 C4 C5 C6 . . . . -3(2) ?
    C2 C1 C6 C5 . . . . 1.3(16) ?
    P1 C1 C6 C5 . . . . 178.8(8) ?
    C4 C5 C6 C1 . . . . 0.3(18) ?
    C1 P1 C7 C12 . . . . -124.4(7) ?
    C13 P1 C7 C12 . . . . 133.4(8) ?
    Ru1 P1 C7 C12 . . . . 11.7(9) ?
    C1 P1 C7 C8 . . . . 58.0(8) ?
    C13 P1 C7 C8 . . . . -44.2(8) ?
    Ru1 P1 C7 C8 . . . . -165.9(6) ?
    C12 C7 C8 C9 . . . . 2.6(14) ?
    P1 C7 C8 C9 . . . . -179.7(8) ?
    C7 C8 C9 C10 . . . . -2.4(15) ?
    C8 C9 C10 C11 . . . . 0.9(16) ?
    C9 C10 C11 C12 . . . . 0.2(16) ?
    C8 C7 C12 C11 . . . . -1.5(13) ?
    P1 C7 C12 C11 . . . . -179.1(7) ?
    C10 C11 C12 C7 . . . . 0.1(15) ?
    C7 P1 C13 C14 . . . . 124.1(8) ?
    C1 P1 C13 C14 . . . . 20.4(9) ?
    Ru1 P1 C13 C14 . . . . -109.2(8) ?
    C7 P1 C13 C18 . . . . -51.2(8) ?
    C1 P1 C13 C18 . . . . -154.9(8) ?
    Ru1 P1 C13 C18 . . . . 75.5(8) ?
    C18 C13 C14 C15 . . . . 0.9(14) ?
    P1 C13 C14 C15 . . . . -174.4(8) ?
    C13 C14 C15 C16 . . . . 1.0(15) ?
    C14 C15 C16 C17 . . . . -2.6(16) ?
    C15 C16 C17 C18 . . . . 2.2(16) ?
    C16 C17 C18 C13 . . . . -0.3(16) ?
    C14 C13 C18 C17 . . . . -1.2(14) ?
    P1 C13 C18 C17 . . . . 174.3(8) ?
    C25 P2 C19 C24 . . . . -11.0(8) ?
    C31 P2 C19 C24 . . . . -113.5(8) ?
    Ru1 P2 C19 C24 . . . . 114.5(7) ?
    C25 P2 C19 C20 . . . . 164.1(6) ?
    C31 P2 C19 C20 . . . . 61.6(7) ?
    Ru1 P2 C19 C20 . . . . -70.4(7) ?
    C24 C19 C20 C21 . . . . 2.1(12) ?
    P2 C19 C20 C21 . . . . -173.2(6) ?
    C19 C20 C21 C22 . . . . 0.8(13) ?
    C20 C21 C22 C23 . . . . -2.5(14) ?
    C21 C22 C23 C24 . . . . 1.2(16) ?
    C22 C23 C24 C19 . . . . 1.8(17) ?
    C20 C19 C24 C23 . . . . -3.4(14) ?
    P2 C19 C24 C23 . . . . 171.7(8) ?
    C19 P2 C25 C26 . . . . 74.3(8) ?
    C31 P2 C25 C26 . . . . 173.1(8) ?
    Ru1 P2 C25 C26 . . . . -50.5(8) ?
    C19 P2 C25 C30 . . . . -105.0(9) ?
    C31 P2 C25 C30 . . . . -6.2(9) ?
    Ru1 P2 C25 C30 . . . . 130.2(8) ?
    C30 C25 C26 C27 . . . . 2.0(15) ?
    P2 C25 C26 C27 . . . . -177.3(8) ?
    C25 C26 C27 C28 . . . . -3.0(16) ?
    C26 C27 C28 C29 . . . . 2.4(16) ?
    C27 C28 C29 C30 . . . . -0.9(17) ?
    C28 C29 C30 C25 . . . . -0.1(16) ?
    C26 C25 C30 C29 . . . . -0.5(15) ?
    P2 C25 C30 C29 . . . . 178.8(8) ?
    C25 P2 C31 C36 . . . . 114.5(8) ?
    C19 P2 C31 C36 . . . . -144.1(8) ?
    Ru1 P2 C31 C36 . . . . -17.8(9) ?
    C25 P2 C31 C32 . . . . -64.8(8) ?
    C19 P2 C31 C32 . . . . 36.7(8) ?
    Ru1 P2 C31 C32 . . . . 163.0(6) ?
    C36 C31 C32 C33 . . . . 0.5(14) ?
    P2 C31 C32 C33 . . . . 179.7(7) ?
    C31 C32 C33 C34 . . . . 0.7(14) ?
    C32 C33 C34 C35 . . . . -0.8(15) ?
    C33 C34 C35 C36 . . . . -0.3(15) ?
    C34 C35 C36 C31 . . . . 1.5(14) ?
    C32 C31 C36 C35 . . . . -1.6(14) ?
    P2 C31 C36 C35 . . . . 179.2(7) ?
    C43 P3 C37 C38 . . . . 103.3(7) ?
    C49 P3 C37 C38 . . . . -155.8(7) ?
    Ru2 P3 C37 C38 . . . . -32.0(8) ?
    C43 P3 C37 C42 . . . . -70.2(8) ?
    C49 P3 C37 C42 . . . . 30.7(8) ?
    Ru2 P3 C37 C42 . . . . 154.5(6) ?
    C42 C37 C38 C39 . . . . 0.1(13) ?
    P3 C37 C38 C39 . . . . -173.6(7) ?
    C37 C38 C39 C40 . . . . 0.1(14) ?
    C38 C39 C40 C41 . . . . 0.5(15) ?
    C39 C40 C41 C42 . . . . -1.2(16) ?
    C40 C41 C42 C37 . . . . 1.4(15) ?
    C38 C37 C42 C41 . . . . -0.8(14) ?
    P3 C37 C42 C41 . . . . 172.7(7) ?
    C37 P3 C43 C48 . . . . -171.5(7) ?
    C49 P3 C43 C48 . . . . 85.6(8) ?
    Ru2 P3 C43 C48 . . . . -36.4(8) ?
    C37 P3 C43 C44 . . . . 10.0(8) ?
    C49 P3 C43 C44 . . . . -93.0(8) ?
    Ru2 P3 C43 C44 . . . . 145.0(7) ?
    C48 C43 C44 C45 . . . . -0.3(14) ?
    P3 C43 C44 C45 . . . . 178.3(8) ?
    C43 C44 C45 C46 . . . . 0.0(16) ?
    C44 C45 C46 C47 . . . . 0.3(17) ?
    C45 C46 C47 C48 . . . . -0.3(17) ?
    C44 C43 C48 C47 . . . . 0.3(14) ?
    P3 C43 C48 C47 . . . . -178.4(8) ?
    C46 C47 C48 C43 . . . . 0.0(16) ?
    C37 P3 C49 C50 . . . . 42.4(9) ?
    C43 P3 C49 C50 . . . . 144.3(9) ?
    Ru2 P3 C49 C50 . . . . -87.2(9) ?
    C37 P3 C49 C54 . . . . -138.8(9) ?
    C43 P3 C49 C54 . . . . -36.9(10) ?
    Ru2 P3 C49 C54 . . . . 91.6(9) ?
    C54 C49 C50 C51 . . . . 4.6(16) ?
    P3 C49 C50 C51 . . . . -176.5(9) ?
    C49 C50 C51 C52 . . . . -4.6(19) ?
    C50 C51 C52 C53 . . . . 2(2) ?
    C51 C52 C53 C54 . . . . 1(2) ?
    C52 C53 C54 C49 . . . . -1.3(19) ?
    C50 C49 C54 C53 . . . . -1.7(17) ?
    P3 C49 C54 C53 . . . . 179.5(9) ?
    C61 P4 C55 C60 . . . . -43.0(9) ?
    C67 P4 C55 C60 . . . . -143.1(8) ?
    Ru2 P4 C55 C60 . . . . 90.6(8) ?
    C61 P4 C55 C56 . . . . 143.7(7) ?
    C67 P4 C55 C56 . . . . 43.6(8) ?
    Ru2 P4 C55 C56 . . . . -82.7(7) ?
    C60 C55 C56 C57 . . . . 1.5(14) ?
    P4 C55 C56 C57 . . . . 175.1(7) ?
    C55 C56 C57 C58 . . . . 0.7(14) ?
    C56 C57 C58 C59 . . . . -0.9(15) ?
    C57 C58 C59 C60 . . . . -1.2(15) ?
    C58 C59 C60 C55 . . . . 3.5(15) ?
    C56 C55 C60 C59 . . . . -3.6(14) ?
    P4 C55 C60 C59 . . . . -176.9(7) ?
    C55 P4 C61 C66 . . . . 167.2(8) ?
    C67 P4 C61 C66 . . . . -92.9(8) ?
    Ru2 P4 C61 C66 . . . . 38.2(9) ?
    C55 P4 C61 C62 . . . . -18.4(9) ?
    C67 P4 C61 C62 . . . . 81.5(8) ?
    Ru2 P4 C61 C62 . . . . -147.3(7) ?
    C66 C61 C62 C63 . . . . -0.1(15) ?
    P4 C61 C62 C63 . . . . -174.7(8) ?
    C61 C62 C63 C64 . . . . 0.1(18) ?
    C62 C63 C64 C65 . . . . 1.8(19) ?
    C63 C64 C65 C66 . . . . -3.4(18) ?
    C62 C61 C66 C65 . . . . -1.6(14) ?
    P4 C61 C66 C65 . . . . 173.2(8) ?
    C64 C65 C66 C61 . . . . 3.4(16) ?
    C55 P4 C67 C68 . . . . 81.0(8) ?
    C61 P4 C67 C68 . . . . -23.4(8) ?
    Ru2 P4 C67 C68 . . . . -156.4(7) ?
    C55 P4 C67 C72 . . . . -93.0(7) ?
    C61 P4 C67 C72 . . . . 162.6(7) ?
    Ru2 P4 C67 C72 . . . . 29.7(8) ?
    C72 C67 C68 C69 . . . . -4.1(14) ?
    P4 C67 C68 C69 . . . . -178.2(7) ?
    C67 C68 C69 C70 . . . . 1.3(15) ?
    C68 C69 C70 C71 . . . . 1.9(15) ?
    C69 C70 C71 C72 . . . . -2.2(14) ?
    C70 C71 C72 C67 . . . . -0.7(14) ?
    C68 C67 C72 C71 . . . . 3.8(13) ?
    P4 C67 C72 C71 . . . . 178.0(7) ?
    C79 P5 C73 C74 . . . . -156.0(9) ?
    C85 P5 C73 C74 . . . . 104.8(9) ?
    Ru3 P5 C73 C74 . . . . -28.8(10) ?
    C79 P5 C73 C78 . . . . 27.6(10) ?
    C85 P5 C73 C78 . . . . -71.6(9) ?
    Ru3 P5 C73 C78 . . . . 154.8(7) ?
    C78 C73 C74 C75 . . . . -0.3(15) ?
    P5 C73 C74 C75 . . . . -176.9(8) ?
    C73 C74 C75 C76 . . . . 0.1(16) ?
    C74 C75 C76 C77 . . . . 0.6(17) ?
    C75 C76 C77 C78 . . . . -1.0(18) ?
    C76 C77 C78 C73 . . . . 0.8(17) ?
    C74 C73 C78 C77 . . . . -0.1(16) ?
    P5 C73 C78 C77 . . . . 176.4(8) ?
    C85 P5 C79 C84 . . . . -19.3(9) ?
    C73 P5 C79 C84 . . . . -121.6(9) ?
    Ru3 P5 C79 C84 . . . . 107.9(8) ?
    C85 P5 C79 C80 . . . . 157.7(7) ?
    C73 P5 C79 C80 . . . . 55.4(8) ?
    Ru3 P5 C79 C80 . . . . -75.2(8) ?
    C84 C79 C80 C81 . . . . 2.3(14) ?
    P5 C79 C80 C81 . . . . -174.9(7) ?
    C79 C80 C81 C82 . . . . -1.0(15) ?
    C80 C81 C82 C83 . . . . -0.5(17) ?
    C81 C82 C83 C84 . . . . 0.5(19) ?
    C82 C83 C84 C79 . . . . 0.8(18) ?
    C80 C79 C84 C83 . . . . -2.2(15) ?
    P5 C79 C84 C83 . . . . 174.7(9) ?
    C79 P5 C85 C86 . . . . -94.5(9) ?
    C73 P5 C85 C86 . . . . 6.5(10) ?
    Ru3 P5 C85 C86 . . . . 140.9(8) ?
    C79 P5 C85 C90 . . . . 82.3(8) ?
    C73 P5 C85 C90 . . . . -176.7(8) ?
    Ru3 P5 C85 C90 . . . . -42.3(9) ?
    C90 C85 C86 C87 . . . . 1.0(17) ?
    P5 C85 C86 C87 . . . . 177.8(9) ?
    C85 C86 C87 C88 . . . . 0(2) ?
    C86 C87 C88 C89 . . . . -1(2) ?
    C87 C88 C89 C90 . . . . 1(2) ?
    C88 C89 C90 C85 . . . . 0(2) ?
    C86 C85 C90 C89 . . . . -0.7(16) ?
    P5 C85 C90 C89 . . . . -177.8(10) ?
    C97 P6 C91 C96 . . . . -48.6(9) ?
    C103 P6 C91 C96 . . . . -149.1(8) ?
    Ru3 P6 C91 C96 . . . . 83.8(8) ?
    C97 P6 C91 C92 . . . . 135.3(8) ?
    C103 P6 C91 C92 . . . . 34.8(9) ?
    Ru3 P6 C91 C92 . . . . -92.3(8) ?
    C96 C91 C92 C93 . . . . -1.9(15) ?
    P6 C91 C92 C93 . . . . 174.3(8) ?
    C91 C92 C93 C94 . . . . 2.0(16) ?
    C92 C93 C94 C95 . . . . -1.5(17) ?
    C93 C94 C95 C96 . . . . 0.9(18) ?
    C92 C91 C96 C95 . . . . 1.2(15) ?
    P6 C91 C96 C95 . . . . -174.9(8) ?
    C94 C95 C96 C91 . . . . -0.8(17) ?
    C91 P6 C97 C102 . . . . -178.9(7) ?
    C103 P6 C97 C102 . . . . -77.5(8) ?
    Ru3 P6 C97 C102 . . . . 52.9(8) ?
    C91 P6 C97 C98 . . . . -8.8(9) ?
    C103 P6 C97 C98 . . . . 92.6(9) ?
    Ru3 P6 C97 C98 . . . . -137.0(8) ?
    C102 C97 C98 C99 . . . . -0.3(15) ?
    P6 C97 C98 C99 . . . . -170.6(9) ?
    C97 C98 C99 C100 . . . . -0.7(19) ?
    C98 C99 C100 C101 . . . . 2.5(19) ?
    C99 C100 C101 C102 . . . . -3.4(17) ?
    C100 C101 C102 C97 . . . . 2.5(16) ?
    C98 C97 C102 C101 . . . . -0.6(14) ?
    P6 C97 C102 C101 . . . . 170.3(8) ?
    C97 P6 C103 C104 . . . . -20.8(8) ?
    C91 P6 C103 C104 . . . . 85.7(8) ?
    Ru3 P6 C103 C104 . . . . -151.6(7) ?
    C97 P6 C103 C108 . . . . 163.2(8) ?
    C91 P6 C103 C108 . . . . -90.3(8) ?
    Ru3 P6 C103 C108 . . . . 32.3(9) ?
    C108 C103 C104 C105 . . . . 0.9(15) ?
    P6 C103 C104 C105 . . . . -175.2(8) ?
    C103 C104 C105 C106 . . . . -1.4(16) ?
    C104 C105 C106 C107 . . . . 1.9(17) ?
    C105 C106 C107 C108 . . . . -1.9(18) ?
    C106 C107 C108 C103 . . . . 1.4(17) ?
    C104 C103 C108 C107 . . . . -0.9(15) ?
    P6 C103 C108 C107 . . . . 175.2(8) ?
    C112 O1 C109 C110 . . . . -10.1 ?
    O1 C109 C110 C111 . . . . 25.8 ?
    C109 C110 C111 C112 . . . . -31.1 ?
    C109 O1 C112 C111 . . . . -10.1 ?
    C110 C111 C112 O1 . . . . 25.8 ?
    C116 O2 C113 C114 . . . . -10.1 ?
    O2 C113 C114 C115 . . . . 25.8 ?
    C113 C114 C115 C116 . . . . -31.1 ?
    C113 O2 C116 C115 . . . . -10.1 ?
    C114 C115 C116 O2 . . . . 25.8 ?
    C120 O3 C117 C118 . . . . -10.1 ?
    O3 C117 C118 C119 . . . . 25.8 ?
    C117 C118 C119 C120 . . . . -31.1 ?
    C117 O3 C120 C119 . . . . -10.1 ?
    C118 C119 C120 O3 . . . . 25.8 ?
    C124 O4 C121 C122 . . . . -10.1 ?
    O4 C121 C122 C123 . . . . 25.8 ?
    C121 C122 C123 C124 . . . . -31.1 ?
    C121 O4 C124 C123 . . . . -10.1 ?
    C122 C123 C124 O4 . . . . 25.8 ?
data_global
_journal_date_recd_electronic     2003-03-07
_journal_date_accepted     2003-03-21
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2003
_journal_volume     59
_journal_issue      4
_journal_page_first     m218
_journal_page_last     m219
_journal_paper_category     EM
_publ_contact_author_name     'Peter Turner'
_publ_contact_author_address
;
Crystal Structure Analysis Facility
School of Chemistry
University of Sydney
Camperdown
NSW 2006
Australia
;
_publ_contact_author_email     p.turner@chem.usyd.edu.au
_publ_contact_author_fax     '61 2 9351 3329'
_publ_contact_author_phone     '61 2 9351 4270'
_publ_section_title
;
A synchrotron study of μ₃-chloro-tri-μ-chloro-μ₃-
sulfido-hexakis(triphenylphospine)triruthenium(II)--tetrahydrofuran--water
(1/1.25/0.75)
;
loop_
    _publ_author_name
    _publ_author_address
    'Vicki-Anne Tolhurst'
;
School of Chemistry
The Univeristy of Tasmania,
Private Bag 75,
Hobart, Tasmania 7001,
Australia
;
    'David Cookson'
;
ChemMatCARS
Advanced Photon Source,
Argonne National Laboratory,
Argonne, Illinois 60439,
USA
;
    'Peter Turner'
;
Crystal Structure Analysis Facility
School of Chemistry,
The University of Sydney,
Camperdown, NSW 2006,
Australia
;
