##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Bis[μ-bis(diphenylphosphino)amine-\kP:P']bis[acetonitrilesiliver(I)]
tris(cis-1,2-dicyanoethylene 1,2-dithiolate)molybdenate(IV)
;
_chemical_name_common     'C64 H48 Ag2 Mo N10 P4 S6'
_chemical_formula_moiety     ?
_chemical_formula_sum     'C64 H48 Ag2 Mo N10 P4 S6'
_chemical_formula_iupac     '[Ag2 (C24 H21 N2 P2)2 (C2 H3 N)2] [Mo (C4 N2 S2)3]'
_chemical_formula_weight     1585.1
_chemical_melting_point     ?
_symmetry_cell_setting     Orthorhombic
_symmetry_space_group_name_H-M     'P b c n'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, -y+1/2, z+1/2'
    '-x, y, -z+1/2'
    'x+1/2, -y+1/2, -z'
    '-x, -y, -z'
    'x-1/2, y-1/2, -z-1/2'
    'x, -y, z-1/2'
    '-x-1/2, y-1/2, z'
_cell_length_a     17.181(3)
_cell_length_b     15.313(3)
_cell_length_c     26.386(5)
_cell_angle_alpha     90.00
_cell_angle_beta     90.00
_cell_angle_gamma     90.00
_cell_volume     6942(2)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     5955
_cell_measurement_theta_min     1.54
_cell_measurement_theta_max     25.07
_cell_measurement_temperature     293(2)
_exptl_crystal_description     'prism'
_exptl_crystal_colour     'dark-green'
_exptl_crystal_size_max     .36
_exptl_crystal_size_mid     .34
_exptl_crystal_size_min     .28
_exptl_crystal_density_diffrn     1.517
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     3176
_exptl_absorpt_coefficient_mu     1.055
_exptl_absorpt_correction_type     empirical
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min     .7293
_exptl_absorpt_correction_T_max     1.0000
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Siemens SMART CCD'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     19737
_diffrn_reflns_av_R_equivalents     0.0798
_diffrn_reflns_av_sigmaI/netI     0.0709
_diffrn_reflns_theta_min     1.54
_diffrn_reflns_theta_max     25.07
_diffrn_reflns_theta_full     25.07
_diffrn_measured_fraction_theta_max     0.995
_diffrn_measured_fraction_theta_full     0.995
_diffrn_reflns_limit_h_min     -13
_diffrn_reflns_limit_h_max     20
_diffrn_reflns_limit_k_min     -18
_diffrn_reflns_limit_k_max     17
_diffrn_reflns_limit_l_min     -31
_diffrn_reflns_limit_l_max     21
_diffrn_standards_number     none
_diffrn_standards_interval_count     none
_diffrn_standards_interval_time     none
_diffrn_standards_decay_%     none
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     6143
_reflns_number_gt     3749
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.1322
_refine_ls_R_factor_gt     0.0630
_refine_ls_wR_factor_gt     0.1092
_refine_ls_wR_factor_ref     0.1350
_refine_ls_goodness_of_fit_ref     1.165
_refine_ls_restrained_S_all     1.165
_refine_ls_number_reflns     6143
_refine_ls_number_parameters     393
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
    'calc w = 1/[σ²(Fo²)+(0.0205P)²+30.6018P] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.404
_refine_diff_density_min     -0.547
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Mo' 'Mo' -1.6832 0.6857
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ag' 'Ag' -0.8971 1.1015
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Siemens, 1994)'
_computing_cell_refinement     'SMART and SAINT (Siemens, 1994)'
_computing_data_reduction     'XPREP (Siemens, 1994)'
_computing_structure_solution     'SHELXTL (Siemens, 1994)'
_computing_structure_refinement     'SHELXTL'
_computing_molecular_graphics     'SHELXTL'
_computing_publication_material     'SHELXTL'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Mo 0.5000 0.96380(5) 0.7500 0.0401(2) Uani d S 1 . . Mo
    Ag 0.49209(4) 0.58946(4) 0.52007(2) 0.0545(2) Uani d . 1 . . Ag
    P1 0.48015(11) 0.52739(12) 0.60463(7) 0.0439(5) Uani d . 1 . . P
    P2 0.44075(11) 0.35718(12) 0.55482(7) 0.0436(5) Uani d . 1 . . P
    N 0.4472(3) 0.4243(4) 0.6054(2) 0.0460(15) Uani d . 1 . . N
    H0A 0.4322 0.4038 0.6341 0.055 Uiso calc R 1 . . H
    N1 0.3565(5) 0.5771(6) 0.4914(4) 0.097(3) Uani d . 1 . . N
    C1 0.2946(7) 0.5602(7) 0.4839(5) 0.091(3) Uani d . 1 . . C
    C2 0.2135(7) 0.5395(8) 0.4760(6) 0.159(7) Uani d . 1 . . C
    H2A 0.1897 0.5256 0.5079 0.191 Uiso calc R 1 . . H
    H2B 0.2094 0.4902 0.4536 0.191 Uiso calc R 1 . . H
    H2C 0.1876 0.5888 0.4612 0.191 Uiso calc R 1 . . H
    C11 0.4107(5) 0.5851(5) 0.6438(3) 0.052(2) Uani d . 1 . . C
    C12 0.3324(6) 0.5746(7) 0.6346(4) 0.087(3) Uani d . 1 . . C
    H12A 0.3161 0.5359 0.6095 0.104 Uiso calc R 1 . . H
    C13 0.2771(7) 0.6212(10) 0.6623(5) 0.119(5) Uani d . 1 . . C
    H13A 0.2244 0.6126 0.6562 0.143 Uiso calc R 1 . . H
    C14 0.3007(10) 0.6797(9) 0.6984(6) 0.118(5) Uani d . 1 . . C
    H14A 0.2642 0.7122 0.7162 0.142 Uiso calc R 1 . . H
    C15 0.3764(9) 0.6897(7) 0.7078(5) 0.105(4) Uani d . 1 . . C
    H15A 0.3921 0.7292 0.7326 0.126 Uiso calc R 1 . . H
    C16 0.4320(6) 0.6429(6) 0.6817(4) 0.079(3) Uani d . 1 . . C
    H16A 0.4843 0.6502 0.6896 0.095 Uiso calc R 1 . . H
    C21 0.5683(4) 0.5276(5) 0.6421(3) 0.0471(19) Uani d . 1 . . C
    C22 0.5783(6) 0.4803(7) 0.6855(4) 0.086(3) Uani d . 1 . . C
    H22A 0.5382 0.4446 0.6969 0.103 Uiso calc R 1 . . H
    C23 0.6468(7) 0.4846(7) 0.7125(4) 0.100(4) Uani d . 1 . . C
    H23A 0.6524 0.4515 0.7418 0.120 Uiso calc R 1 . . H
    C24 0.7055(6) 0.5358(7) 0.6973(4) 0.082(3) Uani d . 1 . . C
    H24A 0.7513 0.5389 0.7159 0.098 Uiso calc R 1 . . H
    C25 0.6969(6) 0.5828(8) 0.6544(5) 0.110(4) Uani d . 1 . . C
    H25A 0.7373 0.6185 0.6435 0.132 Uiso calc R 1 . . H
    C26 0.6297(5) 0.5789(7) 0.6268(4) 0.087(3) Uani d . 1 . . C
    H26A 0.6254 0.6115 0.5972 0.105 Uiso calc R 1 . . H
    C31 0.3376(4) 0.3330(5) 0.5479(3) 0.0465(19) Uani d . 1 . . C
    C32 0.2858(5) 0.3376(7) 0.5874(4) 0.079(3) Uani d . 1 . . C
    H32A 0.3034 0.3517 0.6197 0.095 Uiso calc R 1 . . H
    C33 0.2063(6) 0.3209(8) 0.5792(4) 0.097(4) Uani d . 1 . . C
    H33A 0.1712 0.3248 0.6059 0.117 Uiso calc R 1 . . H
    C34 0.1808(6) 0.2989(7) 0.5319(4) 0.084(3) Uani d . 1 . . C
    H34A 0.1282 0.2883 0.5264 0.100 Uiso calc R 1 . . H
    C35 0.2317(5) 0.2924(6) 0.4930(4) 0.076(3) Uani d . 1 . . C
    H35A 0.2140 0.2758 0.4611 0.091 Uiso calc R 1 . . H
    C36 0.3098(5) 0.3104(5) 0.5002(3) 0.062(2) Uani d . 1 . . C
    H36A 0.3440 0.3074 0.4730 0.075 Uiso calc R 1 . . H
    C41 0.4824(4) 0.2560(5) 0.5783(3) 0.0473(19) Uani d . 1 . . C
    C42 0.5525(5) 0.2589(6) 0.6039(4) 0.070(3) Uani d . 1 . . C
    H42A 0.5766 0.3124 0.6097 0.084 Uiso calc R 1 . . H
    C43 0.5873(6) 0.1828(7) 0.6210(4) 0.082(3) Uani d . 1 . . C
    H43A 0.6340 0.1859 0.6388 0.099 Uiso calc R 1 . . H
    C44 0.5542(7) 0.1040(7) 0.6121(4) 0.091(4) Uani d . 1 . . C
    H44A 0.5778 0.0531 0.6236 0.109 Uiso calc R 1 . . H
    C45 0.4866(8) 0.1004(6) 0.5865(5) 0.110(4) Uani d . 1 . . C
    H45A 0.4642 0.0462 0.5799 0.132 Uiso calc R 1 . . H
    C46 0.4495(6) 0.1753(6) 0.5696(4) 0.087(3) Uani d . 1 . . C
    H46A 0.4024 0.1712 0.5524 0.105 Uiso calc R 1 . . H
    S1 0.57730(12) 1.08156(13) 0.78096(8) 0.0533(5) Uani d . 1 . . S
    N2 0.5943(4) 1.3207(5) 0.7971(3) 0.069(2) Uani d . 1 . . N
    C51 0.5328(4) 1.1784(4) 0.7640(3) 0.0461(19) Uani d . 1 . . C
    C52 0.5678(5) 1.2580(5) 0.7814(3) 0.0494(19) Uani d . 1 . . C
    S2 0.62374(11) 0.91214(14) 0.72242(8) 0.0563(5) Uani d . 1 . . S
    S3 0.45993(12) 0.89637(13) 0.67281(8) 0.0550(5) Uani d . 1 . . S
    N3 0.7362(5) 0.7991(6) 0.6239(4) 0.106(3) Uani d . 1 . . N
    N4 0.5176(5) 0.7643(5) 0.5621(3) 0.083(2) Uani d . 1 . . N
    C53 0.6114(5) 0.8581(5) 0.6654(3) 0.056(2) Uani d . 1 . . C
    C54 0.6799(5) 0.8233(6) 0.6427(3) 0.070(3) Uani d . 1 . . C
    C55 0.5405(5) 0.8497(5) 0.6444(3) 0.053(2) Uani d . 1 . . C
    C56 0.5279(5) 0.8024(6) 0.5980(3) 0.066(2) Uani d . 1 . . C
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Mo S2 3_656 2.382(2) ?
    Mo S2 . 2.382(2) yes
    Mo S1 . 2.384(2) yes
    Mo S1 3_656 2.384(2) ?
    Mo S3 . 2.385(2) yes
    Mo S3 3_656 2.385(2) ?
    Ag P2 5_666 2.430(2) ?
    Ag P1 . 2.434(2) yes
    Ag N1 . 2.457(9) yes
    Ag Ag 5_666 2.9501(13) yes
    P1 N . 1.677(6) yes
    P1 C21 . 1.808(8) ?
    P1 C11 . 1.809(8) ?
    P2 N . 1.688(6) yes
    P2 C41 . 1.816(7) ?
    P2 C31 . 1.820(8) ?
    P2 Ag 5_666 2.430(2) yes
    N H0A . 0.8600 ?
    N1 C1 . 1.111(13) yes
    C1 C2 . 1.445(15) ?
    C2 H2A . 0.9600 ?
    C2 H2B . 0.9600 ?
    C2 H2C . 0.9600 ?
    C11 C12 . 1.377(12) ?
    C11 C16 . 1.384(11) ?
    C12 C13 . 1.394(14) ?
    C12 H12A . 0.9300 ?
    C13 C14 . 1.369(17) ?
    C13 H13A . 0.9300 ?
    C14 C15 . 1.332(17) ?
    C14 H14A . 0.9300 ?
    C15 C16 . 1.379(13) ?
    C15 H15A . 0.9300 ?
    C16 H16A . 0.9300 ?
    C21 C22 . 1.365(11) ?
    C21 C26 . 1.376(11) ?
    C22 C23 . 1.379(13) ?
    C22 H22A . 0.9300 ?
    C23 C24 . 1.338(13) ?
    C23 H23A . 0.9300 ?
    C24 C25 . 1.348(14) ?
    C24 H24A . 0.9300 ?
    C25 C26 . 1.367(13) ?
    C25 H25A . 0.9300 ?
    C26 H26A . 0.9300 ?
    C31 C32 . 1.373(10) ?
    C31 C36 . 1.388(10) ?
    C32 C33 . 1.406(12) ?
    C32 H32A . 0.9300 ?
    C33 C34 . 1.366(13) ?
    C33 H33A . 0.9300 ?
    C34 C35 . 1.350(12) ?
    C34 H34A . 0.9300 ?
    C35 C36 . 1.384(11) ?
    C35 H35A . 0.9300 ?
    C36 H36A . 0.9300 ?
    C41 C46 . 1.378(11) ?
    C41 C42 . 1.381(11) ?
    C42 C43 . 1.385(12) ?
    C42 H42A . 0.9300 ?
    C43 C44 . 1.355(13) ?
    C43 H43A . 0.9300 ?
    C44 C45 . 1.346(14) ?
    C44 H44A . 0.9300 ?
    C45 C46 . 1.386(13) ?
    C45 H45A . 0.9300 ?
    C46 H46A . 0.9300 ?
    S1 C51 . 1.727(7) ?
    N2 C52 . 1.140(9) ?
    C51 C51 3_656 1.349(14) ?
    C51 C52 . 1.434(10) ?
    S2 C53 . 1.730(9) ?
    S3 C55 . 1.730(8) ?
    N3 C54 . 1.149(10) ?
    N4 C56 . 1.127(10) ?
    C53 C55 . 1.345(10) ?
    C53 C54 . 1.423(11) ?
    C55 C56 . 1.437(11) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    S2 Mo S2 3_656 . 141.21(11) yes
    S2 Mo S1 3_656 . 130.07(8) yes
    S2 Mo S1 . . 81.88(7) yes
    S2 Mo S1 3_656 3_656 81.88(7) ?
    S2 Mo S1 . 3_656 130.07(8) yes
    S1 Mo S1 . 3_656 81.70(10) yes
    S2 Mo S3 3_656 . 81.93(8) yes
    S2 Mo S3 . . 81.54(7) yes
    S1 Mo S3 . . 141.35(8) yes
    S1 Mo S3 3_656 . 82.77(7) yes
    S2 Mo S3 3_656 3_656 81.54(7) yes
    S2 Mo S3 . 3_656 81.93(8) ?
    S1 Mo S3 . 3_656 82.77(7) ?
    S1 Mo S3 3_656 3_656 141.35(8) ?
    S3 Mo S3 . 3_656 128.69(11) yes
    P2 Ag P1 5_666 . 156.48(7) yes
    P2 Ag N1 5_666 . 103.0(2) yes
    P1 Ag N1 . . 99.9(2) yes
    P2 Ag Ag 5_666 5_666 88.65(5) yes
    P1 Ag Ag . 5_666 88.52(5) yes
    N1 Ag Ag . 5_666 84.5(2) yes
    N P1 C21 . . 106.1(3) ?
    N P1 C11 . . 103.3(3) ?
    C21 P1 C11 . . 103.8(4) ?
    N P1 Ag . . 114.0(2) yes
    C21 P1 Ag . . 115.5(3) yes
    C11 P1 Ag . . 112.9(3) yes
    N P2 C41 . . 102.9(3) ?
    N P2 C31 . . 105.5(3) ?
    C41 P2 C31 . . 104.2(4) ?
    N P2 Ag . 5_666 114.0(2) yes
    C41 P2 Ag . 5_666 112.2(2) yes
    C31 P2 Ag . 5_666 116.7(3) yes
    P1 N P2 . . 125.9(3) yes
    P1 N H0A . . 117.1 ?
    P2 N H0A . . 117.1 ?
    C1 N1 Ag . . 168.3(10) yes
    N1 C1 C2 . . 178.0(15) ?
    C1 C2 H2A . . 109.5 ?
    C1 C2 H2B . . 109.5 ?
    H2A C2 H2B . . 109.5 ?
    C1 C2 H2C . . 109.5 ?
    H2A C2 H2C . . 109.5 ?
    H2B C2 H2C . . 109.5 ?
    C12 C11 C16 . . 117.4(8) ?
    C12 C11 P1 . . 119.1(7) ?
    C16 C11 P1 . . 123.4(7) ?
    C11 C12 C13 . . 120.8(11) ?
    C11 C12 H12A . . 119.6 ?
    C13 C12 H12A . . 119.6 ?
    C14 C13 C12 . . 119.9(13) ?
    C14 C13 H13A . . 120.1 ?
    C12 C13 H13A . . 120.1 ?
    C15 C14 C13 . . 119.7(13) ?
    C15 C14 H14A . . 120.2 ?
    C13 C14 H14A . . 120.2 ?
    C14 C15 C16 . . 121.4(13) ?
    C14 C15 H15A . . 119.3 ?
    C16 C15 H15A . . 119.3 ?
    C15 C16 C11 . . 120.7(11) ?
    C15 C16 H16A . . 119.6 ?
    C11 C16 H16A . . 119.6 ?
    C22 C21 C26 . . 116.9(8) ?
    C22 C21 P1 . . 124.3(7) ?
    C26 C21 P1 . . 118.8(6) ?
    C21 C22 C23 . . 121.1(9) ?
    C21 C22 H22A . . 119.5 ?
    C23 C22 H22A . . 119.5 ?
    C24 C23 C22 . . 121.0(10) ?
    C24 C23 H23A . . 119.5 ?
    C22 C23 H23A . . 119.5 ?
    C23 C24 C25 . . 118.9(10) ?
    C23 C24 H24A . . 120.6 ?
    C25 C24 H24A . . 120.6 ?
    C24 C25 C26 . . 121.1(10) ?
    C24 C25 H25A . . 119.5 ?
    C26 C25 H25A . . 119.5 ?
    C25 C26 C21 . . 121.1(10) ?
    C25 C26 H26A . . 119.5 ?
    C21 C26 H26A . . 119.5 ?
    C32 C31 C36 . . 118.5(7) ?
    C32 C31 P2 . . 123.0(6) ?
    C36 C31 P2 . . 118.5(6) ?
    C31 C32 C33 . . 120.2(9) ?
    C31 C32 H32A . . 119.9 ?
    C33 C32 H32A . . 119.9 ?
    C34 C33 C32 . . 119.8(9) ?
    C34 C33 H33A . . 120.1 ?
    C32 C33 H33A . . 120.1 ?
    C35 C34 C33 . . 120.3(9) ?
    C35 C34 H34A . . 119.8 ?
    C33 C34 H34A . . 119.8 ?
    C34 C35 C36 . . 120.6(9) ?
    C34 C35 H35A . . 119.7 ?
    C36 C35 H35A . . 119.7 ?
    C35 C36 C31 . . 120.5(8) ?
    C35 C36 H36A . . 119.7 ?
    C31 C36 H36A . . 119.7 ?
    C46 C41 C42 . . 118.0(8) ?
    C46 C41 P2 . . 123.1(7) ?
    C42 C41 P2 . . 118.9(6) ?
    C41 C42 C43 . . 120.5(9) ?
    C41 C42 H42A . . 119.7 ?
    C43 C42 H42A . . 119.7 ?
    C44 C43 C42 . . 120.8(10) ?
    C44 C43 H43A . . 119.6 ?
    C42 C43 H43A . . 119.6 ?
    C45 C44 C43 . . 119.1(10) ?
    C45 C44 H44A . . 120.4 ?
    C43 C44 H44A . . 120.4 ?
    C44 C45 C46 . . 121.6(10) ?
    C44 C45 H45A . . 119.2 ?
    C46 C45 H45A . . 119.2 ?
    C41 C46 C45 . . 120.0(10) ?
    C41 C46 H46A . . 120.0 ?
    C45 C46 H46A . . 120.0 ?
    C51 S1 Mo . . 108.3(2) ?
    C51 C51 C52 3_656 . 121.7(4) ?
    C51 C51 S1 3_656 . 120.8(2) ?
    C52 C51 S1 . . 117.5(5) ?
    N2 C52 C51 . . 177.3(9) ?
    C53 S2 Mo . . 108.4(3) ?
    C55 S3 Mo . . 108.6(3) ?
    C55 C53 C54 . . 122.6(8) ?
    C55 C53 S2 . . 121.1(6) ?
    C54 C53 S2 . . 116.3(7) ?
    N3 C54 C53 . . 176.8(11) ?
    C53 C55 C56 . . 122.5(8) ?
    C53 C55 S3 . . 120.4(6) ?
    C56 C55 S3 . . 117.2(6) ?
    N4 C56 C55 . . 178.9(11) ?
data_global
_journal_date_recd_electronic     2002-09-25
_journal_date_accepted     2002-10-07
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2002
_journal_volume     58
_journal_issue     11
_journal_page_first     m631
_journal_page_last     m633
_journal_paper_category     EM
_publ_contact_author_name     'Zhongning Chen'
_publ_contact_author_address
;
State Key Laboratory of Structural Chemistry
Fujian Institute of Research on the Structure of Matter
Fuzhou
Fujian 350002
People's Republic of China
;
_publ_contact_author_email     'cjl@ms.fjirsm.ac.cn'
_publ_contact_author_fax     '+86-591-3792346'
_publ_contact_author_phone     '+86-591-3792346'
_publ_section_title
;
Bis[μ-bis(diphenylphosphino)amine-\kP:P']bis[acetonitrilesiliver(I)]
tris(cis-1,2-dicyanoethylene 1,2-dithiolate)molybdenate(IV)
;
loop_
    _publ_author_name
    _publ_author_address
    'Xu, Hong-Wu'
;
State Key Laboratory of Structural Chemistry
Fujian Institute of Research on the Structure of Matter
Fuzhou
Fujian 350002
People's Republic of China
;
    'Chen, Zhong-Ning'
;
State Key Laboratory of Structural Chemistry
Fujian Institute of Research on the Structure of Matter
Fuzhou
Fujian 350002
People's Republic of China
;
    'Wu, Ji-Gui'
;
Department of Chemistry
Lanzhou University
Lanzhou 730000
People's Republic of China
;
