##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
 Bis(1,10-phenanthroline)diazidonickel(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C24 H16 N10 Ni'
_chemical_formula_sum     'C24 H16 N10 Ni'
_chemical_formula_weight     503.18
_chemical_melting_point     ?
_symmetry_cell_setting     Triclinic
_symmetry_space_group_name_H-M     'P -1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     8.2000(10)
_cell_length_b     11.002(2)
_cell_length_c     12.408(2)
_cell_angle_alpha     82.28(2)
_cell_angle_beta     82.26(2)
_cell_angle_gamma     72.570(10)
_cell_volume     1053.0(3)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     30
_cell_measurement_theta_min     3.0
_cell_measurement_theta_max     14.4
_cell_measurement_temperature     298(2)
_exptl_crystal_description     Prism
_exptl_crystal_colour     Green
_exptl_crystal_size_max     0.48
_exptl_crystal_size_mid     0.34
_exptl_crystal_size_min     0.30
_exptl_crystal_density_diffrn     1.587
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     516
_exptl_absorpt_coefficient_mu     0.96
_exptl_absorpt_correction_type     Empirical
_exptl_absorpt_process_details     'ψ scan (North et al., 1968)'
_exptl_absorpt_correction_T_min     0.656
_exptl_absorpt_correction_T_max     0.762
_diffrn_ambient_temperature     298(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Siemens P4 four-circle diffractometer'
_diffrn_measurement_method     'ω scan'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     3984
_diffrn_reflns_av_R_equivalents     0.012
_diffrn_reflns_av_sigmaI/netI     0.023
_diffrn_reflns_theta_min     1.7
_diffrn_reflns_theta_max     25.0
_diffrn_reflns_theta_full     25.0
_diffrn_measured_fraction_theta_max     0.999
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     0
_diffrn_reflns_limit_h_max     9
_diffrn_reflns_limit_k_min     -12
_diffrn_reflns_limit_k_max     13
_diffrn_reflns_limit_l_min     -14
_diffrn_reflns_limit_l_max     14
_diffrn_standards_number     3
_diffrn_standards_interval_count     97
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     2.6
_reflns_number_total     3697
_reflns_number_gt     3277
_reflns_threshold_expression     'I>2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.032
_refine_ls_R_factor_gt     0.027
_refine_ls_wR_factor_gt     0.071
_refine_ls_wR_factor_ref     0.072
_refine_ls_goodness_of_fit_ref     1.03
_refine_ls_restrained_S_all     1.03
_refine_ls_number_reflns     3697
_refine_ls_number_parameters     316
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
     'calc w = 1/[σ²(Fo²)+(0.0404P)²+0.2944P] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     '<0.001'
_refine_ls_shift/su_mean     '<0.001'
_refine_diff_density_max     0.24
_refine_diff_density_min     -0.30
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ni' 'Ni' 0.3393 1.1124
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'XSCANS (Siemens, 1990)'
_computing_cell_refinement     'Siemens software PLEASE SPECIFY (Siemens, 1990)'
_computing_data_reduction     'Siemens software'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'ORTEP-II (Johnson, 1976)'
_computing_publication_material     'SHELXL97 (Sheldrick, 1997)'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Ni1 0.48265(3) 0.28823(2) 0.23492(2) 0.02710(10)
                                                   Uani d . 1 . . Ni
    N1 0.6351(3) 0.4097(2) 0.1853(2) 0.0427(4) Uani d . 1 . . N
    N2 0.7839(3) 0.3741(2) 0.1600(2) 0.0479(5) Uani d . 1 . . N
    N3 0.9284(4) 0.3436(3) 0.1339(3) 0.1150(10)
                                              Uani d . 1 . . N
    N4 0.6984(2) 0.1301(2) 0.2538(2) 0.0433(5) Uani d . 1 . . N
    N5 0.7032(2) 0.0339(2) 0.30890(10)
                                     0.0372(4) Uani d . 1 . . N
    N6 0.7137(3) -0.0632(2) 0.3617(2) 0.0674(7) Uani d . 1 . . N
    N7 0.4621(2) 0.2553(2) 0.07670(10)
                                     0.0300(4) Uani d . 1 . . N
    N8 0.3272(2) 0.1624(2) 0.26590(10)
                                     0.0310(4) Uani d . 1 . . N
    N9 0.4475(2) 0.3285(2) 0.39810(10)
                                     0.0299(4) Uani d . 1 . . N
    N10 0.2663(2) 0.4518(2) 0.23170(10)
                                      0.0302(4) Uani d . 1 . . N
    C1 0.5289(3) 0.3040(2) -0.0164(2) 0.0380(5) Uani d . 1 . . C
    C2 0.5069(3) 0.2752(2) -0.1182(2) 0.0429(5) Uani d . 1 . . C
    C3 0.4149(3) 0.1918(2) -0.1245(2) 0.0414(5) Uani d . 1 . . C
    C4 0.3404(3) 0.1390(2) -0.0278(2) 0.0356(5) Uani d . 1 . . C
    C5 0.2423(3) 0.0502(2) -0.0249(2) 0.0450(6) Uani d . 1 . . C
    C6 0.1745(3) 0.0035(2) 0.0712(2) 0.0468(6) Uani d . 1 . . C
    C7 0.1976(3) 0.0389(2) 0.1735(2) 0.0375(5) Uani d . 1 . . C
    C8 0.1328(3) -0.0081(2) 0.2757(2) 0.0486(6) Uani d . 1 . . C
    C9 0.1687(3) 0.0279(2) 0.3686(2) 0.0487(6) Uani d . 1 . . C
    C10 0.2668(3) 0.1128(2) 0.3609(2) 0.0391(5) Uani d . 1 . . C
    C11 0.2949(2) 0.1247(2) 0.1735(2) 0.0298(4) Uani d . 1 . . C
    C12 0.3677(2) 0.1747(2) 0.0713(2) 0.0290(4) Uani d . 1 . . C
    C13 0.5355(3) 0.2639(2) 0.4804(2) 0.0367(5) Uani d . 1 . . C
    C14 0.5008(3) 0.3021(2) 0.5854(2) 0.0414(5) Uani d . 1 . . C
    C15 0.3731(3) 0.4108(2) 0.6069(2) 0.0417(5) Uani d . 1 . . C
    C16 0.2767(3) 0.4818(2) 0.5221(2) 0.0357(5) Uani d . 1 . . C
    C17 0.1401(3) 0.5981(2) 0.5356(2) 0.0456(6) Uani d . 1 . . C
    C18 0.0521(3) 0.6621(2) 0.4509(2) 0.0452(6) Uani d . 1 . . C
    C19 0.0901(3) 0.6159(2) 0.3448(2) 0.0368(5) Uani d . 1 . . C
    C20 -0.0007(3) 0.6767(2) 0.2549(2) 0.0468(6) Uani d . 1 . . C
    C21 0.0425(3) 0.6250(2) 0.1579(2) 0.0481(6) Uani d . 1 . . C
    C22 0.1768(3) 0.5117(2) 0.1493(2) 0.0393(5) Uani d . 1 . . C
    C23 0.2230(2) 0.5031(2) 0.3289(2) 0.0299(4) Uani d . 1 . . C
    C24 0.3186(2) 0.4359(2) 0.4187(2) 0.0296(4) Uani d . 1 . . C
    H1 0.5933 0.3599 -0.0133 0.046 Uiso calc R 1 . . H
    H2 0.5544 0.3125 -0.1816 0.051 Uiso calc R 1 . . H
    H3 0.4016 0.1701 -0.1920 0.050 Uiso calc R 1 . . H
    H5 0.2253 0.0245 -0.0899 0.054 Uiso calc R 1 . . H
    H6 0.1107 -0.0535 0.0708 0.056 Uiso calc R 1 . . H
    H8 0.0654 -0.0635 0.2801 0.058 Uiso calc R 1 . . H
    H9 0.1279 -0.0041 0.4367 0.058 Uiso calc R 1 . . H
    H10 0.2911 0.1358 0.4250 0.047 Uiso calc R 1 . . H
    H13 0.6241 0.1900 0.4672 0.044 Uiso calc R 1 . . H
    H14 0.5646 0.2535 0.6409 0.050 Uiso calc R 1 . . H
    H15 0.3502 0.4377 0.6768 0.050 Uiso calc R 1 . . H
    H17 0.1120 0.6297 0.6036 0.055 Uiso calc R 1 . . H
    H18 -0.0348 0.7376 0.4615 0.054 Uiso calc R 1 . . H
    H20 -0.0898 0.7519 0.2616 0.056 Uiso calc R 1 . . H
    H21 -0.0166 0.6645 0.0977 0.058 Uiso calc R 1 . . H
    H22 0.2043 0.4769 0.0826 0.047 Uiso calc R 1 . . H
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ni1 N1 . 2.073(2) yes
    Ni1 N4 . 2.091(2) yes
    Ni1 N7 . 2.081(2) yes
    Ni1 N8 . 2.115(2) yes
    Ni1 N9 . 2.094(2) yes
    Ni1 N10 . 2.115(2) yes
    N1 N2 . 1.177(3) yes
    N2 N3 . 1.144(3) yes
    N4 N5 . 1.174(3) yes
    N5 N6 . 1.162(3) yes
    N7 C1 . 1.326(3) no
    N7 C12 . 1.353(3) no
    N8 C10 . 1.328(3) no
    N8 C11 . 1.354(3) no
    N9 C13 . 1.329(3) no
    N9 C24 . 1.356(2) no
    N10 C22 . 1.323(3) no
    N10 C23 . 1.359(2) no
    C1 C2 . 1.391(3) no
    C2 C3 . 1.366(3) no
    C3 C4 . 1.406(3) no
    C4 C12 . 1.404(3) no
    C4 C5 . 1.434(3) no
    C5 C6 . 1.350(3) no
    C6 C7 . 1.427(3) no
    C7 C8 . 1.402(3) no
    C7 C11 . 1.407(3) no
    C8 C9 . 1.362(3) no
    C9 C10 . 1.390(3) no
    C11 C12 . 1.439(3) no
    C13 C14 . 1.389(3) no
    C14 C15 . 1.364(3) no
    C15 C16 . 1.405(3) no
    C16 C24 . 1.404(3) no
    C16 C17 . 1.439(3) no
    C17 C18 . 1.349(3) no
    C18 C19 . 1.436(3) no
    C19 C23 . 1.402(3) no
    C19 C20 . 1.405(3) no
    C20 C21 . 1.359(3) no
    C21 C22 . 1.400(3) no
    C23 C24 . 1.439(3) no
    C1 H1 . 0.9300 no
    C2 H2 . 0.9300 no
    C3 H3 . 0.9300 no
    C5 H5 . 0.9300 no
    C6 H6 . 0.9300 no
    C8 H8 . 0.9300 no
    C9 H9 . 0.9300 no
    C10 H10 . 0.9300 no
    C13 H13 . 0.9300 no
    C14 H14 . 0.9300 no
    C15 H15 . 0.9300 no
    C17 H17 . 0.9300 no
    C18 H18 . 0.9300 no
    C20 H20 . 0.9300 no
    C21 H21 . 0.9300 no
    C22 H22 . 0.9300 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N1 Ni1 N4 . . 91.60(10)
                          yes
    N1 Ni1 N7 . . 94.30(10)
                          yes
    N1 Ni1 N8 . . 173.30(10)
                           yes
    N1 Ni1 N9 . . 93.60(10)
                          yes
    N1 Ni1 N10 . . 87.90(10)
                           yes
    N4 Ni1 N7 . . 93.40(10)
                          yes
    N4 Ni1 N8 . . 88.80(10)
                          yes
    N4 Ni1 N9 . . 95.30(10)
                          yes
    N4 Ni1 N10 . . 174.30(10)
                            yes
    N7 Ni1 N8 . . 78.90(10)
                          yes
    N7 Ni1 N9 . . 168.00(10)
                           yes
    N7 Ni1 N10 . . 92.30(10)
                           yes
    N8 Ni1 N9 . . 93.00(10)
                          yes
    N8 Ni1 N10 . . 92.30(10)
                           yes
    N9 Ni1 N10 . . 79.00(10)
                           yes
    N2 N1 Ni1 . . 123.90(10)
                           yes
    N1 N2 N3 . . 177.8(3) yes
    N5 N4 Ni1 . . 126.6(2) yes
    N4 N5 N6 . . 177.6(2) yes
    C1 N7 C12 . . 118.1(2) no
    C1 N7 Ni1 . . 127.80(10)
                           no
    C12 N7 Ni1 . . 114.20(10)
                            no
    C10 N8 C11 . . 117.8(2) no
    C10 N8 Ni1 . . 129.3(2) no
    C11 N8 Ni1 . . 112.90(10)
                            no
    C13 N9 C24 . . 117.9(2) no
    C13 N9 Ni1 . . 128.40(10)
                            no
    C24 N9 Ni1 . . 113.70(10)
                            no
    C22 N10 C23 . . 117.7(2) no
    C22 N10 Ni1 . . 129.50(10)
                             no
    C23 N10 Ni1 . . 112.70(10)
                             no
    N7 C1 C2 . . 122.9(2) no
    C3 C2 C1 . . 119.5(2) no
    C2 C3 C4 . . 119.4(2) no
    C3 C4 C12 . . 117.2(2) no
    C3 C4 C5 . . 123.9(2) no
    C12 C4 C5 . . 118.8(2) no
    C6 C5 C4 . . 120.7(2) no
    C5 C6 C7 . . 122.1(2) no
    C8 C7 C11 . . 116.8(2) no
    C8 C7 C6 . . 124.6(2) no
    C11 C7 C6 . . 118.6(2) no
    C9 C8 C7 . . 119.7(2) no
    C8 C9 C10 . . 119.6(2) no
    N8 C10 C9 . . 122.8(2) no
    N8 C11 C7 . . 123.3(2) no
    N8 C11 C12 . . 117.1(2) no
    C7 C11 C12 . . 119.6(2) no
    N7 C12 C4 . . 122.9(2) no
    N7 C12 C11 . . 116.9(2) no
    C4 C12 C11 . . 120.2(2) no
    N9 C13 C14 . . 122.8(2) no
    C15 C14 C13 . . 119.9(2) no
    C14 C15 C16 . . 119.1(2) no
    C15 C16 C24 . . 117.4(2) no
    C15 C16 C17 . . 123.7(2) no
    C24 C16 C17 . . 118.9(2) no
    C18 C17 C16 . . 121.0(2) no
    C17 C18 C19 . . 121.3(2) no
    C23 C19 C20 . . 117.2(2) no
    C23 C19 C18 . . 119.1(2) no
    C20 C19 C18 . . 123.6(2) no
    C21 C20 C19 . . 119.5(2) no
    C20 C21 C22 . . 119.4(2) no
    N10 C22 C21 . . 123.0(2) no
    N10 C23 C19 . . 123.1(2) no
    N10 C23 C24 . . 117.3(2) no
    C19 C23 C24 . . 119.6(2) no
    N9 C24 C16 . . 122.9(2) no
    N9 C24 C23 . . 117.0(2) no
    C16 C24 C23 . . 120.1(2) no
    N7 C1 H1 . . 118.5 no
    C2 C1 H1 . . 118.5 no
    C3 C2 H2 . . 120.3 no
    C1 C2 H2 . . 120.3 no
    C2 C3 H3 . . 120.3 no
    C4 C3 H3 . . 120.3 no
    C6 C5 H5 . . 119.7 no
    C4 C5 H5 . . 119.7 no
    C5 C6 H6 . . 119.0 no
    C7 C6 H6 . . 119.0 no
    C9 C8 H8 . . 120.1 no
    C7 C8 H8 . . 120.1 no
    C8 C9 H9 . . 120.2 no
    C10 C9 H9 . . 120.2 no
    N8 C10 H10 . . 118.6 no
    C9 C10 H10 . . 118.6 no
    N9 C13 H13 . . 118.6 no
    C14 C13 H13 . . 118.6 no
    C15 C14 H14 . . 120.0 no
    C13 C14 H14 . . 120.0 no
    C14 C15 H15 . . 120.5 no
    C16 C15 H15 . . 120.5 no
    C18 C17 H17 . . 119.5 no
    C16 C17 H17 . . 119.5 no
    C17 C18 H18 . . 119.3 no
    C19 C18 H18 . . 119.3 no
    C21 C20 H20 . . 120.2 no
    C19 C20 H20 . . 120.2 no
    C20 C21 H21 . . 120.3 no
    C22 C21 H21 . . 120.3 no
    N10 C22 H22 . . 118.5 no
    C21 C22 H22 . . 118.5 no
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    N7 Ni1 N1 N2 . . . . -80.2(2) no
    N4 Ni1 N1 N2 . . . . 13.4(2) no
    N9 Ni1 N1 N2 . . . . 108.8(2) no
    N10 Ni1 N1 N2 . . . . -172.3(2) no
    N1 Ni1 N4 N5 . . . . 157.5(2) no
    N7 Ni1 N4 N5 . . . . -108.1(2) no
    N9 Ni1 N4 N5 . . . . 63.7(2) no
    N8 Ni1 N4 N5 . . . . -29.2(2) no
    N1 Ni1 N7 C1 . . . . -0.9(2) no
    N4 Ni1 N7 C1 . . . . -92.8(2) no
    N9 Ni1 N7 C1 . . . . 130.5(3) no
    N8 Ni1 N7 C1 . . . . 179.1(2) no
    N10 Ni1 N7 C1 . . . . 87.2(2) no
    N1 Ni1 N7 C12 . . . . 179.50(10)
                                   no
    N4 Ni1 N7 C12 . . . . 87.60(10)
                                  no
    N9 Ni1 N7 C12 . . . . -49.1(3) no
    N8 Ni1 N7 C12 . . . . -0.50(10)
                                  no
    N10 Ni1 N7 C12 . . . . -92.40(10)
                                    no
    N7 Ni1 N8 C10 . . . . 176.9(2) no
    N4 Ni1 N8 C10 . . . . 83.2(2) no
    N9 Ni1 N8 C10 . . . . -12.10(10)
                                   no
    N10 Ni1 N8 C10 . . . . -91.2(2) no
    N7 Ni1 N8 C11 . . . . 0.50(10)
                                 no
    N4 Ni1 N8 C11 . . . . -93.30(10)
                                   no
    N9 Ni1 N8 C11 . . . . 171.50(10)
                                   no
    N10 Ni1 N8 C11 . . . . 92.40(10)
                                   no
    N1 Ni1 N9 C13 . . . . -95.1(2) no
    N7 Ni1 N9 C13 . . . . 133.4(3) no
    N4 Ni1 N9 C13 . . . . -3.2(2) no
    N8 Ni1 N9 C13 . . . . 85.9(2) no
    N10 Ni1 N9 C13 . . . . 177.7(2) no
    N1 Ni1 N9 C24 . . . . 84.00(10)
                                  no
    N7 Ni1 N9 C24 . . . . -47.4(4) no
    N4 Ni1 N9 C24 . . . . 176.00(10)
                                   no
    N8 Ni1 N9 C24 . . . . -95.00(10)
                                   no
    N10 Ni1 N9 C24 . . . . -3.20(10)
                                   no
    N1 Ni1 N10 C22 . . . . 86.4(2) no
    N7 Ni1 N10 C22 . . . . -7.9(2) no
    N9 Ni1 N10 C22 . . . . -179.5(2) no
    N8 Ni1 N10 C22 . . . . -86.9(2) no
    N1 Ni1 N10 C23 . . . . -90.00(10)
                                    no
    N7 Ni1 N10 C23 . . . . 175.80(10)
                                    no
    N9 Ni1 N10 C23 . . . . 4.10(10)
                                  no
    N8 Ni1 N10 C23 . . . . 96.70(10)
                                   no
    C12 N7 C1 C2 . . . . -0.4(3) no
    Ni1 N7 C1 C2 . . . . 180.0(2) no
    N7 C1 C2 C3 . . . . -1.0(3) no
    C1 C2 C3 C4 . . . . 1.6(3) no
    C2 C3 C4 C12 . . . . -0.8(3) no
    C2 C3 C4 C5 . . . . -179.7(2) no
    C3 C4 C5 C6 . . . . -180.0(2) no
    C12 C4 C5 C6 . . . . 1.3(3) no
    C4 C5 C6 C7 . . . . -0.5(3) no
    C5 C6 C7 C8 . . . . -178.9(2) no
    C5 C6 C7 C11 . . . . -0.3(3) no
    C11 C7 C8 C9 . . . . -1.5(3) no
    C6 C7 C8 C9 . . . . 177.2(2) no
    C7 C8 C9 C10 . . . . 1.2(3) no
    C11 N8 C10 C9 . . . . -2.0(3) no
    Ni1 N8 C10 C9 . . . . -178.3(2) no
    C8 C9 C10 N8 . . . . 0.6(3) no
    C10 N8 C11 C7 . . . . 1.7(3) no
    Ni1 N8 C11 C7 . . . . 178.6(2) no
    C10 N8 C11 C12 . . . . -177.3(2) no
    Ni1 N8 C11 C12 . . . . -0.4(2) no
    C8 C7 C11 N8 . . . . 0.0(3) no
    C6 C7 C11 N8 . . . . -178.7(2) no
    C8 C7 C11 C12 . . . . 178.9(2) no
    C6 C7 C11 C12 . . . . 0.2(3) no
    C1 N7 C12 C4 . . . . 1.2(3) no
    Ni1 N7 C12 C4 . . . . -179.20(10)
                                    no
    C1 N7 C12 C11 . . . . -179.2(2) no
    Ni1 N7 C12 C11 . . . . 0.5(2) no
    C3 C4 C12 N7 . . . . -0.6(3) no
    C5 C4 C12 N7 . . . . 178.3(2) no
    C3 C4 C12 C11 . . . . 179.8(2) no
    C5 C4 C12 C11 . . . . -1.3(3) no
    N8 C11 C12 N7 . . . . -0.1(3) no
    C7 C11 C12 N7 . . . . -179.1(2) no
    N8 C11 C12 C4 . . . . 179.6(2) no
    C7 C11 C12 C4 . . . . 0.6(3) no
    C24 N9 C13 C14 . . . . -0.1(3) no
    Ni1 N9 C13 C14 . . . . 179.0(2) no
    N9 C13 C14 C15 . . . . -0.8(3) no
    C13 C14 C15 C16 . . . . 0.9(3) no
    C14 C15 C16 C24 . . . . -0.2(3) no
    C14 C15 C16 C17 . . . . -179.6(2) no
    C15 C16 C17 C18 . . . . 180.0(2) no
    C24 C16 C17 C18 . . . . 0.5(3) no
    C16 C17 C18 C19 . . . . 0.7(4) no
    C17 C18 C19 C23 . . . . -1.0(3) no
    C17 C18 C19 C20 . . . . 178.1(2) no
    C23 C19 C20 C21 . . . . 0.1(3) no
    C18 C19 C20 C21 . . . . -179.0(2) no
    C19 C20 C21 C22 . . . . 0.1(4) no
    C23 N10 C22 C21 . . . . 0.7(3) no
    Ni1 N10 C22 C21 . . . . -175.5(2) no
    C20 C21 C22 N10 . . . . -0.6(4) no
    C22 N10 C23 C19 . . . . -0.5(3) no
    Ni1 N10 C23 C19 . . . . 176.3(2) no
    C22 N10 C23 C24 . . . . 178.7(2) no
    Ni1 N10 C23 C24 . . . . -4.5(2) no
    C20 C19 C23 N10 . . . . 0.1(3) no
    C18 C19 C23 N10 . . . . 179.2(2) no
    C20 C19 C23 C24 . . . . -179.1(2) no
    C18 C19 C23 C24 . . . . 0.0(3) no
    C13 N9 C24 C16 . . . . 1.0(3) no
    Ni1 N9 C24 C16 . . . . -178.3(2) no
    C13 N9 C24 C23 . . . . -178.9(2) no
    Ni1 N9 C24 C23 . . . . 1.8(2) no
    C15 C16 C24 N9 . . . . -0.8(3) no
    C17 C16 C24 N9 . . . . 178.7(2) no
    C15 C16 C24 C23 . . . . 179.1(2) no
    C17 C16 C24 C23 . . . . -1.4(3) no
    N10 C23 C24 N9 . . . . 1.8(3) no
    C19 C23 C24 N9 . . . . -178.9(2) no
    N10 C23 C24 C16 . . . . -178.1(2) no
    C19 C23 C24 C16 . . . . 1.2(3) no
data_ya6136
_journal_date_recd_electronic     2002-08-27
_journal_date_accepted     2002-09-09
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2002
_journal_volume     58
_journal_issue     10
_journal_page_first     m545
_journal_page_last     m547
_journal_paper_category     EM
_publ_contact_author
;
     Prof. Ya-Qian Cheng
     Department of Chemistry and Material Science
     Wenzhou Normal College
     Wenzhou, 325027
     China
;
_publ_contact_author_email     hu403cn@yahoo.com.cn
_publ_contact_author_fax     '86 577 8833 9081'
_publ_contact_author_phone     '86 577 8837 3111'
_publ_section_title
;
 Bis(1,10-phenanthroline)diazidonickel(II)
;
loop_
    _publ_author_name
    _publ_author_address
    'Cheng, Ya-Qian'
;
      Department of Chemistry and Material Science
      Wenzhou Normal College
      Wenzhou 325027
      People's Republic of China
;
    'Liu, Ai-Li'
;
      Department of Chemistry and Material Science
      Wenzhou Normal College
      Wenzhou 325027
      People's Republic of China
;
    'Hu, Mao-Lin'
;
     Department of Chemistry and Material Science
     Wenzhou Normal College
     Wenzhou 325027
     People's Republic of China
;
    'Ng, Seik Weng'
;
     Department of Chemistry
     University of Malaya
     50603 Kuala Lumpur
     Malaysia
;
