##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
hydridodichlorotris(methyldiphenylphosphine)rhodium(III)
dichloromethane trisolvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C39 H40 Cl2 P3 Rh , 3 C H2 Cl2'
_chemical_formula_sum     'C42 H46 Cl8 P3 Rh'
_chemical_formula_iupac     '[Rh H Cl2 (C13 H13 P)3], 3C H2 Cl2'
_chemical_formula_weight     1030.21
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/n'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     12.5494(8)
_cell_length_b     18.3233(12)
_cell_length_c     20.0687(13)
_cell_angle_alpha     90.00
_cell_angle_beta     92.063(2)
_cell_angle_gamma     90.00
_cell_volume     4611.7(5)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     16248
_cell_measurement_theta_min     2.2
_cell_measurement_theta_max     28.4
_cell_measurement_temperature     160(2)
_exptl_crystal_description     block
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.50
_exptl_crystal_size_mid     0.32
_exptl_crystal_size_min     0.30
_exptl_crystal_density_diffrn     1.484
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     2096
_exptl_absorpt_coefficient_mu     0.968
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(XPREP in SHELXTL; Sheldrick, 1997)'
_exptl_absorpt_correction_T_min     0.642
_exptl_absorpt_correction_T_max     0.876
_exptl_special_details
;
;
_diffrn_ambient_temperature     160(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Siemens SMART CCD'
_diffrn_measurement_method     'ω rotation with narrow frames'
_diffrn_detector_area_resol_mean     8.192
_diffrn_reflns_number     27485
_diffrn_reflns_av_R_equivalents     0.0409
_diffrn_reflns_av_sigmaI/netI     0.0360
_diffrn_reflns_theta_min     1.5
_diffrn_reflns_theta_max     28.4
_diffrn_reflns_theta_full     26.00
_diffrn_measured_fraction_theta_max     0.898
_diffrn_measured_fraction_theta_full     0.994
_diffrn_reflns_limit_h_min     -16
_diffrn_reflns_limit_h_max     11
_diffrn_reflns_limit_k_min     -23
_diffrn_reflns_limit_k_max     24
_diffrn_reflns_limit_l_min     -26
_diffrn_reflns_limit_l_max     26
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
;
_reflns_number_total     10376
_reflns_number_gt     8288
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0640
_refine_ls_R_factor_gt     0.0440
_refine_ls_wR_factor_gt     0.1024
_refine_ls_wR_factor_ref     0.1180
_refine_ls_goodness_of_fit_ref     1.113
_refine_ls_restrained_S_all     1.113
_refine_ls_number_reflns     10376
_refine_ls_number_parameters     493
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'w = 1/[σ²(Fo²)+(0.0449P)²+10.9692P] where P = (Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     1.019
_refine_diff_density_min     -1.512
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Rh' 'Rh' -1.1178 0.9187
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Siemens, 1994)'
_computing_cell_refinement     'local programs'
_computing_data_reduction     'SAINT (Siemens, 1994)'
_computing_structure_solution     'SHELXTL (Sheldrick, 1997)'
_computing_structure_refinement     SHELXTL
_computing_molecular_graphics     SHELXTL
_computing_publication_material     'SHELXTL and local programs'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Rh 0.51389(2) 0.229024(13) 0.729752(12) 0.01714(7) Uani d . 1 . . Rh
    H1 0.594(3) 0.242(2) 0.6746(19) 0.025 Uiso d . 1 . . H
    Cl1 0.39325(7) 0.20623(5) 0.82468(4) 0.02745(18) Uani d . 1 . . Cl
    Cl2 0.54299(7) 0.35538(4) 0.76159(4) 0.02479(17) Uani d . 1 . . Cl
    P1 0.66312(7) 0.20692(5) 0.80172(4) 0.01958(17) Uani d . 1 . . P
    C1 0.7910(3) 0.24474(19) 0.77800(17) 0.0233(7) Uani d . 1 . . C
    C2 0.8799(3) 0.2394(2) 0.82212(19) 0.0321(8) Uani d . 1 . . C
    H2 0.8737 0.2146 0.8634 0.038 Uiso calc R 1 . . H
    C3 0.9767(3) 0.2699(3) 0.8060(2) 0.0397(10) Uani d . 1 . . C
    H3 1.0367 0.2657 0.8360 0.048 Uiso calc R 1 . . H
    C4 0.9855(3) 0.3066(2) 0.7463(2) 0.0397(10) Uani d . 1 . . C
    H4 1.0519 0.3275 0.7354 0.048 Uiso calc R 1 . . H
    C5 0.8988(3) 0.3129(2) 0.7026(2) 0.0363(9) Uani d . 1 . . C
    H5 0.9054 0.3382 0.6616 0.044 Uiso calc R 1 . . H
    C6 0.8017(3) 0.2823(2) 0.71856(19) 0.0286(8) Uani d . 1 . . C
    H6 0.7420 0.2871 0.6884 0.034 Uiso calc R 1 . . H
    C7 0.6943(3) 0.11327(19) 0.82669(17) 0.0251(7) Uani d . 1 . . C
    C8 0.7895(3) 0.0780(2) 0.81223(18) 0.0312(8) Uani d . 1 . . C
    H8 0.8411 0.1027 0.7871 0.037 Uiso calc R 1 . . H
    C9 0.8097(4) 0.0074(2) 0.8341(2) 0.0423(11) Uani d . 1 . . C
    H9 0.8743 -0.0163 0.8238 0.051 Uiso calc R 1 . . H
    C10 0.7346(4) -0.0283(2) 0.8713(2) 0.0496(13) Uani d . 1 . . C
    H10 0.7488 -0.0763 0.8873 0.060 Uiso calc R 1 . . H
    C11 0.6402(4) 0.0047(2) 0.8852(2) 0.0447(11) Uani d . 1 . . C
    H11 0.5888 -0.0207 0.9099 0.054 Uiso calc R 1 . . H
    C12 0.6191(3) 0.0758(2) 0.86312(19) 0.0326(8) Uani d . 1 . . C
    H12 0.5535 0.0986 0.8729 0.039 Uiso calc R 1 . . H
    C13 0.6449(3) 0.2497(2) 0.88283(17) 0.0273(7) Uani d . 1 . . C
    H13A 0.7072 0.2396 0.9122 0.041 Uiso calc R 1 . . H
    H13B 0.5809 0.2298 0.9027 0.041 Uiso calc R 1 . . H
    H13C 0.6369 0.3025 0.8770 0.041 Uiso calc R 1 . . H
    P2 0.50594(7) 0.11729(5) 0.68241(4) 0.01970(17) Uani d . 1 . . P
    C14 0.6319(3) 0.06878(19) 0.67598(16) 0.0218(7) Uani d . 1 . . C
    C15 0.7156(3) 0.1046(2) 0.64554(19) 0.0307(8) Uani d . 1 . . C
    H15 0.7084 0.1546 0.6335 0.037 Uiso calc R 1 . . H
    C16 0.8089(3) 0.0676(3) 0.6328(2) 0.0412(10) Uani d . 1 . . C
    H16 0.8653 0.0920 0.6117 0.049 Uiso calc R 1 . . H
    C17 0.8198(4) -0.0051(2) 0.6508(2) 0.0405(10) Uani d . 1 . . C
    H17 0.8836 -0.0305 0.6417 0.049 Uiso calc R 1 . . H
    C18 0.7389(3) -0.0402(2) 0.6816(2) 0.0355(9) Uani d . 1 . . C
    H18 0.7474 -0.0898 0.6945 0.043 Uiso calc R 1 . . H
    C19 0.6445(3) -0.00402(19) 0.69412(17) 0.0269(7) Uani d . 1 . . C
    H19 0.5885 -0.0290 0.7151 0.032 Uiso calc R 1 . . H
    C20 0.4678(3) 0.1160(2) 0.59302(18) 0.0262(7) Uani d . 1 . . C
    C21 0.4086(3) 0.0594(2) 0.5645(2) 0.0349(9) Uani d . 1 . . C
    H21 0.3824 0.0215 0.5918 0.042 Uiso calc R 1 . . H
    C22 0.3875(4) 0.0581(2) 0.4955(2) 0.0431(11) Uani d . 1 . . C
    H22 0.3462 0.0196 0.4763 0.052 Uiso calc R 1 . . H
    C23 0.4260(4) 0.1123(3) 0.4554(2) 0.0439(11) Uani d . 1 . . C
    H23 0.4111 0.1112 0.4086 0.053 Uiso calc R 1 . . H
    C24 0.4864(3) 0.1682(3) 0.48329(19) 0.0389(10) Uani d . 1 . . C
    H24 0.5133 0.2056 0.4557 0.047 Uiso calc R 1 . . H
    C25 0.5079(3) 0.1699(2) 0.55168(18) 0.0288(8) Uani d . 1 . . C
    H25 0.5504 0.2081 0.5705 0.035 Uiso calc R 1 . . H
    C26 0.4166(3) 0.0546(2) 0.72142(19) 0.0298(8) Uani d . 1 . . C
    H26A 0.4376 0.0493 0.7687 0.045 Uiso calc R 1 . . H
    H26B 0.4201 0.0069 0.6994 0.045 Uiso calc R 1 . . H
    H26C 0.3436 0.0734 0.7173 0.045 Uiso calc R 1 . . H
    P3 0.36572(7) 0.27458(5) 0.66785(4) 0.02050(17) Uani d . 1 . . P
    C27 0.3948(3) 0.32810(19) 0.59398(17) 0.0245(7) Uani d . 1 . . C
    C28 0.3132(3) 0.3495(2) 0.54909(19) 0.0304(8) Uani d . 1 . . C
    H28 0.2416 0.3358 0.5567 0.037 Uiso calc R 1 . . H
    C29 0.3363(3) 0.3910(2) 0.49305(19) 0.0365(9) Uani d . 1 . . C
    H29 0.2806 0.4042 0.4621 0.044 Uiso calc R 1 . . H
    C30 0.4390(4) 0.4128(2) 0.4823(2) 0.0391(9) Uani d . 1 . . C
    H30 0.4545 0.4405 0.4438 0.047 Uiso calc R 1 . . H
    C31 0.5201(3) 0.3941(2) 0.5280(2) 0.0363(9) Uani d . 1 . . C
    H31 0.5910 0.4101 0.5214 0.044 Uiso calc R 1 . . H
    C32 0.4976(3) 0.3520(2) 0.58337(18) 0.0289(8) Uani d . 1 . . C
    H32 0.5535 0.3394 0.6144 0.035 Uiso calc R 1 . . H
    C33 0.2596(3) 0.21112(19) 0.64167(19) 0.0269(7) Uani d . 1 . . C
    C34 0.2413(3) 0.1891(2) 0.5752(2) 0.0335(8) Uani d . 1 . . C
    H34 0.2842 0.2081 0.5413 0.040 Uiso calc R 1 . . H
    C35 0.1602(3) 0.1395(3) 0.5589(3) 0.0450(11) Uani d . 1 . . C
    H35 0.1474 0.1253 0.5138 0.054 Uiso calc R 1 . . H
    C36 0.0984(3) 0.1109(3) 0.6084(3) 0.0499(12) Uani d . 1 . . C
    H36 0.0441 0.0764 0.5973 0.060 Uiso calc R 1 . . H
    C37 0.1157(3) 0.1325(3) 0.6738(3) 0.0486(12) Uani d . 1 . . C
    H37 0.0724 0.1132 0.7074 0.058 Uiso calc R 1 . . H
    C38 0.1959(3) 0.1821(2) 0.6907(2) 0.0372(9) Uani d . 1 . . C
    H38 0.2074 0.1964 0.7359 0.045 Uiso calc R 1 . . H
    C39 0.2896(3) 0.3399(2) 0.71577(19) 0.0280(7) Uani d . 1 . . C
    H39A 0.2683 0.3171 0.7574 0.042 Uiso calc R 1 . . H
    H39B 0.2258 0.3548 0.6896 0.042 Uiso calc R 1 . . H
    H39C 0.3338 0.3828 0.7260 0.042 Uiso calc R 1 . . H
    C40 0.8530(3) 0.1008(3) 0.3812(2) 0.0417(10) Uani d . 1 . . C
    H40A 0.8844 0.1429 0.3580 0.050 Uiso calc R 1 . . H
    H40B 0.8518 0.0587 0.3503 0.050 Uiso calc R 1 . . H
    Cl3 0.93320(11) 0.07929(7) 0.45250(6) 0.0552(3) Uani d . 1 . . Cl
    Cl4 0.72200(10) 0.12220(7) 0.40219(8) 0.0614(4) Uani d . 1 . . Cl
    C41 0.9013(4) 0.2684(3) 0.5054(3) 0.0530(13) Uani d . 1 . . C
    H41A 0.9024 0.2558 0.4574 0.064 Uiso calc R 1 . . H
    H41B 0.9295 0.2260 0.5311 0.064 Uiso calc R 1 . . H
    Cl5 0.98438(12) 0.34426(8) 0.52105(7) 0.0608(4) Uani d . 1 . . Cl
    Cl6 0.76911(12) 0.28492(8) 0.52718(7) 0.0624(4) Uani d . 1 . . Cl
    C42 0.2668(6) 0.0515(4) 0.9049(4) 0.103(3) Uani d . 1 . . C
    H42A 0.2963 0.1000 0.8939 0.123 Uiso calc R 1 . . H
    H42B 0.2445 0.0531 0.9517 0.123 Uiso calc R 1 . . H
    Cl7 0.35908(15) -0.00962(10) 0.89810(9) 0.0852(5) Uani d . 1 . . Cl
    Cl8 0.14466(19) 0.03221(11) 0.84745(12) 0.1052(7) Uani d . 1 . . Cl
_geom_special_details
;
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Rh H1 . 1.54(4) yes
    Rh Cl1 . 2.5107(8) yes
    Rh Cl2 . 2.4260(8) yes
    Rh P1 . 2.3585(9) yes
    Rh P2 . 2.2577(9) yes
    Rh P3 . 2.3518(9) yes
    P1 C1 . 1.827(3) ?
    P1 C7 . 1.826(4) ?
    P1 C13 . 1.828(4) ?
    C1 C2 . 1.403(5) ?
    C1 C6 . 1.388(5) ?
    C2 H2 . 0.950 ?
    C2 C3 . 1.386(6) ?
    C3 H3 . 0.950 ?
    C3 C4 . 1.381(6) ?
    C4 H4 . 0.950 ?
    C4 C5 . 1.379(6) ?
    C5 H5 . 0.950 ?
    C5 C6 . 1.389(5) ?
    C6 H6 . 0.950 ?
    C7 C8 . 1.398(5) ?
    C7 C12 . 1.395(5) ?
    C8 H8 . 0.950 ?
    C8 C9 . 1.387(6) ?
    C9 H9 . 0.950 ?
    C9 C10 . 1.387(7) ?
    C10 H10 . 0.950 ?
    C10 C11 . 1.368(7) ?
    C11 H11 . 0.950 ?
    C11 C12 . 1.398(6) ?
    C12 H12 . 0.950 ?
    C13 H13A . 0.980 ?
    C13 H13B . 0.980 ?
    C13 H13C . 0.980 ?
    P2 C14 . 1.822(3) ?
    P2 C20 . 1.840(4) ?
    P2 C26 . 1.804(4) ?
    C14 C15 . 1.398(5) ?
    C14 C19 . 1.390(5) ?
    C15 H15 . 0.950 ?
    C15 C16 . 1.385(5) ?
    C16 H16 . 0.950 ?
    C16 C17 . 1.385(6) ?
    C17 H17 . 0.950 ?
    C17 C18 . 1.369(6) ?
    C18 H18 . 0.950 ?
    C18 C19 . 1.388(5) ?
    C19 H19 . 0.950 ?
    C20 C21 . 1.387(5) ?
    C20 C25 . 1.395(5) ?
    C21 H21 . 0.950 ?
    C21 C22 . 1.401(6) ?
    C22 H22 . 0.950 ?
    C22 C23 . 1.377(7) ?
    C23 H23 . 0.950 ?
    C23 C24 . 1.381(6) ?
    C24 H24 . 0.950 ?
    C24 C25 . 1.390(5) ?
    C25 H25 . 0.950 ?
    C26 H26A . 0.980 ?
    C26 H26B . 0.980 ?
    C26 H26C . 0.980 ?
    P3 C27 . 1.825(4) ?
    P3 C33 . 1.831(4) ?
    P3 C39 . 1.826(4) ?
    C27 C28 . 1.395(5) ?
    C27 C32 . 1.386(5) ?
    C28 H28 . 0.950 ?
    C28 C29 . 1.396(6) ?
    C29 H29 . 0.950 ?
    C29 C30 . 1.374(6) ?
    C30 H30 . 0.950 ?
    C30 C31 . 1.387(6) ?
    C31 H31 . 0.950 ?
    C31 C32 . 1.390(5) ?
    C32 H32 . 0.950 ?
    C33 C34 . 1.404(5) ?
    C33 C38 . 1.395(6) ?
    C34 H34 . 0.950 ?
    C34 C35 . 1.395(6) ?
    C35 H35 . 0.950 ?
    C35 C36 . 1.384(7) ?
    C36 H36 . 0.950 ?
    C36 C37 . 1.380(7) ?
    C37 H37 . 0.950 ?
    C37 C38 . 1.390(6) ?
    C38 H38 . 0.950 ?
    C39 H39A . 0.980 ?
    C39 H39B . 0.980 ?
    C39 H39C . 0.980 ?
    C40 H40A . 0.990 ?
    C40 H40B . 0.990 ?
    C40 Cl3 . 1.764(4) ?
    C40 Cl4 . 1.756(4) ?
    C41 H41A . 0.990 ?
    C41 H41B . 0.990 ?
    C41 Cl5 . 1.759(5) ?
    C41 Cl6 . 1.757(5) ?
    C42 H42A . 0.990 ?
    C42 H42B . 0.990 ?
    C42 Cl7 . 1.621(9) ?
    C42 Cl8 . 1.918(9) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    H1 Rh Cl1 . . 176.3(14) yes
    H1 Rh Cl2 . . 86.8(14) yes
    H1 Rh P1 . . 86.6(14) yes
    H1 Rh P2 . . 81.9(14) yes
    H1 Rh P3 . . 95.2(14) yes
    Cl1 Rh Cl2 . . 92.75(3) yes
    Cl1 Rh P1 . . 89.66(3) yes
    Cl1 Rh P2 . . 98.61(3) yes
    Cl1 Rh P3 . . 88.45(3) yes
    Cl2 Rh P1 . . 83.91(3) yes
    Cl2 Rh P2 . . 168.58(3) yes
    Cl2 Rh P3 . . 84.78(3) yes
    P1 Rh P2 . . 97.13(3) yes
    P1 Rh P3 . . 168.43(3) yes
    P2 Rh P3 . . 94.44(3) yes
    Rh P1 C1 . . 117.45(12) ?
    Rh P1 C7 . . 119.13(12) ?
    Rh P1 C13 . . 110.48(13) ?
    C1 P1 C7 . . 104.27(17) ?
    C1 P1 C13 . . 102.04(16) ?
    C7 P1 C13 . . 100.99(17) ?
    P1 C1 C2 . . 119.7(3) ?
    P1 C1 C6 . . 121.7(3) ?
    C2 C1 C6 . . 118.5(3) ?
    C1 C2 H2 . . 119.7 ?
    C1 C2 C3 . . 120.6(4) ?
    H2 C2 C3 . . 119.7 ?
    C2 C3 H3 . . 120.1 ?
    C2 C3 C4 . . 119.8(4) ?
    H3 C3 C4 . . 120.1 ?
    C3 C4 H4 . . 119.8 ?
    C3 C4 C5 . . 120.5(4) ?
    H4 C4 C5 . . 119.8 ?
    C4 C5 H5 . . 120.1 ?
    C4 C5 C6 . . 119.8(4) ?
    H5 C5 C6 . . 120.1 ?
    C1 C6 C5 . . 120.8(4) ?
    C1 C6 H6 . . 119.6 ?
    C5 C6 H6 . . 119.6 ?
    P1 C7 C8 . . 123.6(3) ?
    P1 C7 C12 . . 117.6(3) ?
    C8 C7 C12 . . 118.7(3) ?
    C7 C8 H8 . . 119.6 ?
    C7 C8 C9 . . 120.9(4) ?
    H8 C8 C9 . . 119.6 ?
    C8 C9 H9 . . 120.3 ?
    C8 C9 C10 . . 119.4(4) ?
    H9 C9 C10 . . 120.3 ?
    C9 C10 H10 . . 119.7 ?
    C9 C10 C11 . . 120.7(4) ?
    H10 C10 C11 . . 119.7 ?
    C10 C11 H11 . . 119.9 ?
    C10 C11 C12 . . 120.3(4) ?
    H11 C11 C12 . . 119.9 ?
    C7 C12 C11 . . 120.0(4) ?
    C7 C12 H12 . . 120.0 ?
    C11 C12 H12 . . 120.0 ?
    P1 C13 H13A . . 109.5 ?
    P1 C13 H13B . . 109.5 ?
    P1 C13 H13C . . 109.5 ?
    H13A C13 H13B . . 109.5 ?
    H13A C13 H13C . . 109.5 ?
    H13B C13 H13C . . 109.5 ?
    Rh P2 C14 . . 116.55(11) ?
    Rh P2 C20 . . 115.36(12) ?
    Rh P2 C26 . . 114.45(13) ?
    C14 P2 C20 . . 96.89(15) ?
    C14 P2 C26 . . 105.91(17) ?
    C20 P2 C26 . . 105.72(18) ?
    P2 C14 C15 . . 118.0(3) ?
    P2 C14 C19 . . 122.7(3) ?
    C15 C14 C19 . . 119.0(3) ?
    C14 C15 H15 . . 119.9 ?
    C14 C15 C16 . . 120.3(4) ?
    H15 C15 C16 . . 119.9 ?
    C15 C16 H16 . . 120.0 ?
    C15 C16 C17 . . 119.9(4) ?
    H16 C16 C17 . . 120.0 ?
    C16 C17 H17 . . 119.9 ?
    C16 C17 C18 . . 120.1(4) ?
    H17 C17 C18 . . 119.9 ?
    C17 C18 H18 . . 119.7 ?
    C17 C18 C19 . . 120.6(4) ?
    H18 C18 C19 . . 119.7 ?
    C14 C19 C18 . . 120.0(4) ?
    C14 C19 H19 . . 120.0 ?
    C18 C19 H19 . . 120.0 ?
    P2 C20 C21 . . 121.9(3) ?
    P2 C20 C25 . . 118.9(3) ?
    C21 C20 C25 . . 118.9(3) ?
    C20 C21 H21 . . 120.0 ?
    C20 C21 C22 . . 120.0(4) ?
    H21 C21 C22 . . 120.0 ?
    C21 C22 H22 . . 119.7 ?
    C21 C22 C23 . . 120.6(4) ?
    H22 C22 C23 . . 119.7 ?
    C22 C23 H23 . . 120.1 ?
    C22 C23 C24 . . 119.8(4) ?
    H23 C23 C24 . . 120.1 ?
    C23 C24 H24 . . 120.0 ?
    C23 C24 C25 . . 120.1(4) ?
    H24 C24 C25 . . 120.0 ?
    C20 C25 C24 . . 120.7(4) ?
    C20 C25 H25 . . 119.7 ?
    C24 C25 H25 . . 119.7 ?
    P2 C26 H26A . . 109.5 ?
    P2 C26 H26B . . 109.5 ?
    P2 C26 H26C . . 109.5 ?
    H26A C26 H26B . . 109.5 ?
    H26A C26 H26C . . 109.5 ?
    H26B C26 H26C . . 109.5 ?
    Rh P3 C27 . . 116.26(12) ?
    Rh P3 C33 . . 118.65(12) ?
    Rh P3 C39 . . 111.90(12) ?
    C27 P3 C33 . . 105.82(17) ?
    C27 P3 C39 . . 101.49(17) ?
    C33 P3 C39 . . 100.27(17) ?
    P3 C27 C28 . . 120.8(3) ?
    P3 C27 C32 . . 120.6(3) ?
    C28 C27 C32 . . 118.5(3) ?
    C27 C28 H28 . . 119.9 ?
    C27 C28 C29 . . 120.3(4) ?
    H28 C28 C29 . . 119.9 ?
    C28 C29 H29 . . 119.8 ?
    C28 C29 C30 . . 120.5(4) ?
    H29 C29 C30 . . 119.8 ?
    C29 C30 H30 . . 120.2 ?
    C29 C30 C31 . . 119.7(4) ?
    H30 C30 C31 . . 120.2 ?
    C30 C31 H31 . . 120.0 ?
    C30 C31 C32 . . 120.0(4) ?
    H31 C31 C32 . . 120.0 ?
    C27 C32 C31 . . 121.0(3) ?
    C27 C32 H32 . . 119.5 ?
    C31 C32 H32 . . 119.5 ?
    P3 C33 C34 . . 123.2(3) ?
    P3 C33 C38 . . 117.9(3) ?
    C34 C33 C38 . . 118.8(4) ?
    C33 C34 H34 . . 119.9 ?
    C33 C34 C35 . . 120.2(4) ?
    H34 C34 C35 . . 119.9 ?
    C34 C35 H35 . . 120.0 ?
    C34 C35 C36 . . 120.0(4) ?
    H35 C35 C36 . . 120.0 ?
    C35 C36 H36 . . 120.0 ?
    C35 C36 C37 . . 120.1(4) ?
    H36 C36 C37 . . 120.0 ?
    C36 C37 H37 . . 119.7 ?
    C36 C37 C38 . . 120.5(4) ?
    H37 C37 C38 . . 119.7 ?
    C33 C38 C37 . . 120.3(4) ?
    C33 C38 H38 . . 119.9 ?
    C37 C38 H38 . . 119.9 ?
    P3 C39 H39A . . 109.5 ?
    P3 C39 H39B . . 109.5 ?
    P3 C39 H39C . . 109.5 ?
    H39A C39 H39B . . 109.5 ?
    H39A C39 H39C . . 109.5 ?
    H39B C39 H39C . . 109.5 ?
    H40A C40 H40B . . 108.0 ?
    H40A C40 Cl3 . . 109.3 ?
    H40A C40 Cl4 . . 109.3 ?
    H40B C40 Cl3 . . 109.3 ?
    H40B C40 Cl4 . . 109.3 ?
    Cl3 C40 Cl4 . . 111.6(2) ?
    H41A C41 H41B . . 107.9 ?
    H41A C41 Cl5 . . 109.2 ?
    H41A C41 Cl6 . . 109.2 ?
    H41B C41 Cl5 . . 109.2 ?
    H41B C41 Cl6 . . 109.2 ?
    Cl5 C41 Cl6 . . 112.2(3) ?
    H42A C42 H42B . . 107.9 ?
    H42A C42 Cl7 . . 109.1 ?
    H42A C42 Cl8 . . 109.1 ?
    H42B C42 Cl7 . . 109.1 ?
    H42B C42 Cl8 . . 109.1 ?
    Cl7 C42 Cl8 . . 112.3(3) ?
data_global
_journal_date_recd_electronic     2002-07-08
_journal_date_accepted     2002-07-09
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2002
_journal_volume     58
_journal_issue      8
_journal_page_first     m408
_journal_page_last     m409
_journal_paper_category     EM
_publ_contact_author_name     'Professor W. Clegg'
_publ_contact_author_address
;
Department of Chemistry
Bedson Building
University of Newcastle
Newcastle upon Tyne NE1 7RU
England
;
_publ_contact_author_email     w.clegg@ncl.ac.uk
_publ_contact_author_fax     '0191 222 6929'
_publ_contact_author_phone     '0191 222 6649'
_publ_section_title
;
Hydridodichlorotris(methyldiphenylphosphine)rhodium(III)
dichloromethane trisolvate
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Clegg, William' .
; Department of Chemistry
  University of Newcastle upon Tyne
  Newcastle upon Tyne NE1 7RU
  England
;
    'Scott, Andrew J.' .
; Department of Chemistry
  University of Newcastle upon Tyne
  Newcastle upon Tyne NE1 7RU
  England
;
    'Norman, Nicholas C.' .
; School of Chemistry
  University of Bristol
  Cantock's Close
  Bristol BS8 1TS
  England
;
    'Robins, Edward G.' .
; School of Chemistry
  University of Bristol
  Cantock's Close
  Bristol BS8 1TS
  England
;
    'Whittell, George R.' .
; School of Chemistry
  University of Bristol
  Cantock's Close
  Bristol BS8 1TS
  England
;
