##############################################################################
###                                                                        ###
###        Electronic paper (Acta Crystallographica Section E)             ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section E. It conforms to the requirements of Notes      #
# for Authors for Section E, and has been peer reviewed under the auspices   #
# of the IUCr Commission on Journals.                                        #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
                                             
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
[Bis(diphenylphosphino)methane-2\k^2^P,P']-\m-carbonyl-1:2\kC-carbonyl-1\kC-
[1(η⁵)-cyclopentadienyl](μ-phenylvinylidene-1:2κ²C)manganeseplatinum-
(Mn---Pt) diethyl ether solvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C40 H33 Mn O2 P2 Pt, C4 H10 O'
_chemical_formula_sum     'C44 H43 Mn O3 P2 Pt'
_chemical_formula_iupac
                         '[Mn Pt (C5 H5) (C8 H6) (C25 H22 P2) (C O)2], C4 H10 O'
_chemical_formula_weight     931.75
_chemical_melting_point     ?
_symmetry_cell_setting     Orthorhombic
_symmetry_space_group_name_H-M     'P b c a'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, -y, z+1/2'
    '-x, y+1/2, -z+1/2'
    'x+1/2, -y+1/2, -z'
    '-x, -y, -z'
    'x-1/2, y, -z-1/2'
    'x, -y-1/2, z-1/2'
    '-x-1/2, y-1/2, z'
_cell_length_a     18.3417(18)
_cell_length_b     18.3164(18)
_cell_length_c     23.547(2)
_cell_angle_alpha     90.00
_cell_angle_beta     90.00
_cell_angle_gamma     90.00
_cell_volume     7910.7(14)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     932
_cell_measurement_theta_min     2
_cell_measurement_theta_max     24
_cell_measurement_temperature     110(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     orange
_exptl_crystal_size_max      .4
_exptl_crystal_size_mid      .2
_exptl_crystal_size_min      .2
_exptl_crystal_density_diffrn     1.565
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     3712
_exptl_absorpt_coefficient_mu     3.97
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1998)'
_exptl_absorpt_correction_T_min      .443
_exptl_absorpt_correction_T_max      .694
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     110(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength      .71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'CCD area detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     55551
_diffrn_reflns_av_R_equivalents      .070
_diffrn_reflns_av_sigmaI/netI      .082
_diffrn_reflns_theta_min     1.7
_diffrn_reflns_theta_max     28.1
_diffrn_reflns_theta_full     28.1
_diffrn_measured_fraction_theta_max      .993
_diffrn_measured_fraction_theta_full      .993
_diffrn_reflns_limit_h_min     -24
_diffrn_reflns_limit_h_max     23
_diffrn_reflns_limit_k_min     -24
_diffrn_reflns_limit_k_max     11
_diffrn_reflns_limit_l_min     -31
_diffrn_reflns_limit_l_max     31
_diffrn_standards_number     0
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     0
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     9557
_reflns_number_gt     5404
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all      .092
_refine_ls_R_factor_gt      .054
_refine_ls_wR_factor_ref      .129
_refine_ls_goodness_of_fit_ref      .97
_refine_ls_restrained_S_all      .97
_refine_ls_number_reflns     9557
_refine_ls_number_parameters     455
_refine_ls_number_restraints     8
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
               'calc w = 1/[σ²(Fo²)+(0.06P)²] where P = (Fo²+2Fc²)/3'
_refine_ls_shift/su_max      .001
_refine_ls_shift/su_mean      .000
_refine_diff_density_max     1.91
_refine_diff_density_min     -1.67
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C'  .0033  .0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H'  .0000  .0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O'  .0106  .0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P'  .1023  .0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Mn' 'Mn'  .3368  .7283
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 1998)'
_computing_cell_refinement     'SAINT-Plus (Bruker, 1998)'
_computing_data_reduction     'SAINT-Plus'
_computing_structure_solution     'SHELXTL (Sheldrick, 1998)'
_computing_structure_refinement     'SHELXTL'
_computing_molecular_graphics     'SHELXTL'
_computing_publication_material     'SHELXTL'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Pt1  .044444(12)  .367216(14)  -.326505(10)  .02265(9) Uani d . 1 . . Pt
    Mn1  -.01953(5)  .38471(6)  -.42442(4)  .0274(2) Uani d . 1 . . Mn
    P1  .16410(9)  .37428(10)  -.29358(7)  .0242(4) Uani d . 1 . . P
    P2  .04716(9)  .31278(9)  -.23948(7)  .0233(4) Uani d . 1 . . P
    O3  .1075(2)  .4804(3)  -.4095(2)  .0408(13) Uani d . 1 . . O
    O4  -.1138(3)  .5129(3)  -.4137(2)  .0384(12) Uani d . 1 . . O
    C1  -.0544(3)  .3415(4)  -.3551(3)  .0261(15) Uani d . 1 . . C
    C2  -.1100(3)  .3015(3)  -.3324(3)  .0248(14) Uani d . 1 . . C
    H2A  -.1034  .2841  -.2948  .030 Uiso calc R 1 . . H
    C3  .0602(4)  .4371(4)  -.4022(3)  .0329(17) Uani d . 1 . . C
    C4  -.0762(4)  .4626(4)  -.4161(3)  .0308(16) Uani d . 1 . . C
    C5  -.1790(3)  .2829(4)  -.3605(3)  .0253(15) Uani d . 1 . . C
    C6  -.2163(3)  .3290(4)  -.3968(3)  .0307(16) Uani d . 1 . . C
    H6A  -.1977  .3768  -.4029  .037 Uiso calc R 1 . . H
    C7  -.2799(4)  .3084(4)  -.4246(3)  .0382(18) Uani d . 1 . . C
    H7A  -.3030  .3413  -.4501  .046 Uiso calc R 1 . . H
    C8  -.3098(4)  .2393(4)  -.4153(3)  .0373(19) Uani d . 1 . . C
    H8A  -.3536  .2248  -.4337  .045 Uiso calc R 1 . . H
    C9  -.2739(4)  .1923(4)  -.3784(3)  .0355(17) Uani d . 1 . . C
    H9A  -.2933  .1449  -.3719  .043 Uiso calc R 1 . . H
    C10  -.2107(3)  .2130(4)  -.3508(3)  .0308(16) Uani d . 1 . . C
    H10A  -.1881  .1802  -.3250  .037 Uiso calc R 1 . . H
    C11  -.0239(4)  .3875(4)  -.5146(3)  .0408(19) Uani d . 1 . . C
    H11A  -.0310  .4325  -.5380  .049 Uiso calc R 1 . . H
    C12  -.0801(4)  .3434(5)  -.4936(3)  .047(2) Uani d . 1 . . C
    H12A  -.1336  .3500  -.5003  .057 Uiso calc R 1 . . H
    C13  -.0467(4)  .2844(4)  -.4656(3)  .0407(19) Uani d . 1 . . C
    H13A  -.0729  .2425  -.4475  .049 Uiso calc R 1 . . H
    C14  .0297(4)  .2925(4)  -.4686(3)  .042(2) Uani d . 1 . . C
    H14A  .0673  .2582  -.4533  .050 Uiso calc R 1 . . H
    C15  .0425(4)  .3591(4)  -.4991(3)  .0365(17) Uani d . 1 . . C
    H15A  .0913  .3797  -.5092  .044 Uiso calc R 1 . . H
    C16  .1459(3)  .3207(4)  -.2284(3)  .0302(16) Uani d . 1 . . C
    H16A  .1708  .2727  -.2286  .036 Uiso calc R 1 . . H
    H16B  .1583  .3478  -.1933  .036 Uiso calc R 1 . . H
    C17  .2152(3)  .4545(4)  -.2706(3)  .0267(15) Uani d . 1 . . C
    C18  .2718(4)  .4482(4)  -.2319(3)  .0342(17) Uani d . 1 . . C
    H18A  .2810  .4025  -.2142  .041 Uiso calc R 1 . . H
    C19  .3151(4)  .5077(4)  -.2188(3)  .0384(18) Uani d . 1 . . C
    H19A  .3544  .5027  -.1928  .046 Uiso calc R 1 . . H
    C20  .3005(4)  .5750(4)  -.2441(3)  .043(2) Uani d . 1 . . C
    H20A  .3302  .6161  -.2358  .052 Uiso calc R 1 . . H
    C21  .2445(4)  .5814(4)  -.2801(4)  .045(2) Uani d . 1 . . C
    H21A  .2339  .6278  -.2962  .054 Uiso calc R 1 . . H
    C22  .2008(4)  .5213(4)  -.2948(3)  .0401(19) Uani d . 1 . . C
    H22A  .1620  .5267  -.3211  .048 Uiso calc R 1 . . H
    C23  .2321(3)  .3227(3)  -.3333(3)  .0256(15) Uani d . 1 . . C
    C24  .2859(3)  .2822(4)  -.3060(3)  .0324(17) Uani d . 1 . . C
    H24A  .2862  .2785  -.2658  .039 Uiso calc R 1 . . H
    C25  .3386(4)  .2477(4)  -.3377(3)  .0365(18) Uani d . 1 . . C
    H25A  .3745  .2191  -.3190  .044 Uiso calc R 1 . . H
    C26  .3404(4)  .2536(4)  -.3953(4)  .044(2) Uani d . 1 . . C
    H26A  .3777  .2300  -.4164  .053 Uiso calc R 1 . . H
    C27  .2872(4)  .2945(5)  -.4230(3)  .049(2) Uani d . 1 . . C
    H27A  .2881  .2984  -.4632  .058 Uiso calc R 1 . . H
    C28  .2331(4)  .3293(4)  -.3923(3)  .0370(18) Uani d . 1 . . C
    H28A  .1970  .3574  -.4112  .044 Uiso calc R 1 . . H
    C29  .0043(3)  .3587(3)  -.1806(3)  .0270(15) Uani d . 1 . . C
    C30  -.0548(3)  .3999(3)  -.1862(3)  .0342(14) Uani d . 1 . . C
    H30A  -.0725  .4031  -.2241  .041 Uiso calc R 1 . . H
    C31  -.0941(4)  .4375(4)  -.1487(4)  .045(2) Uani d . 1 . . C
    H31A  -.1369  .4638  -.1586  .054 Uiso calc R 1 . . H
    C32  -.0670(4)  .4349(5)  -.0937(3)  .048(2) Uani d . 1 . . C
    H32A  -.0911  .4604  -.0640  .057 Uiso calc R 1 . . H
    C33  -.0026(5)  .3936(5)  -.0821(3)  .047(2) Uani d . 1 . . C
    H33A  .0167  .3914  -.0446  .056 Uiso calc R 1 . . H
    C34  .0311(4)  .3571(5)  -.1259(3)  .047(2) Uani d . 1 . . C
    H34A  .0741  .3299  -.1183  .056 Uiso calc R 1 . . H
    C35  .0256(3)  .2158(4)  -.2325(3)  .0289(16) Uani d . 1 . . C
    C36  .0183(4)  .1813(4)  -.1802(3)  .0321(16) Uani d . 1 . . C
    H36A  .0238  .2082  -.1460  .039 Uiso calc R 1 . . H
    C37  .0028(4)  .1072(4)  -.1783(4)  .046(2) Uani d . 1 . . C
    H37A  -.0017  .0835  -.1426  .055 Uiso calc R 1 . . H
    C38  -.0061(4)  .0676(4)  -.2273(4)  .043(2) Uani d . 1 . . C
    H38A  -.0169  .0170  -.2252  .052 Uiso calc R 1 . . H
    C39  .0006(4)  .1006(4)  -.2791(4)  .048(2) Uani d . 1 . . C
    H39A  -.0055  .0731  -.3129  .057 Uiso calc R 1 . . H
    C40  .0165(4)  .1757(4)  -.2819(3)  .0322(16) Uani d . 1 . . C
    H40A  .0210  .1990  -.3178  .039 Uiso calc R 1 . . H
    O1S  -.3286(6)  .4488(6)  -.5138(5)  .059(3) Uiso d PD  .60 A 1 O
    C1S  -.2886(14)  .4251(18)  -.5619(12)  .096(12) Uiso d PD  .60 A 1 C
    H1SA  -.2425  .4009  -.5509  .115 Uiso calc PR  .60 A 1 H
    H1SB  -.2779  .4660  -.5881  .115 Uiso calc PR  .60 A 1 H
    C2S  -.3444(10)  .3697(9)  -.5883(7)  .078(5) Uiso d PD  .60 A 1 C
    H2SA  -.3224  .3460  -.6215  .117 Uiso calc PR  .60 A 1 H
    H2SB  -.3886  .3958  -.6000  .117 Uiso calc PR  .60 A 1 H
    H2SC  -.3570  .3325  -.5600  .117 Uiso calc PR  .60 A 1 H
    C3S  -.2884(10)  .5037(10)  -.4830(8)  .079(5) Uiso d PD  .60 A 1 C
    H3SA  -.2809  .5471  -.5074  .095 Uiso calc PR  .60 A 1 H
    H3SB  -.2400  .4844  -.4721  .095 Uiso calc PR  .60 A 1 H
    C4S  -.3317(16)  .5252(18)  -.4294(11)  .145(12) Uiso d PD  .60 A 1 C
    H4SA  -.3038  .5610  -.4074  .218 Uiso calc PR  .60 A 1 H
    H4SB  -.3404  .4817  -.4061  .218 Uiso calc PR  .60 A 1 H
    H4SC  -.3785  .5466  -.4406  .218 Uiso calc PR  .60 A 1 H
    O1S'  -.3303(8)  .4741(9)  -.4902(7)  .060(5) Uiso d PD  .40 B 2 O
    C1S'  -.2659(12)  .4717(14)  -.5268(10)  .074(7) Uiso d PD  .40 B 2 C
    H1SC  -.2213  .4571  -.5060  .089 Uiso calc PR  .40 B 2 H
    H1SD  -.2575  .5183  -.5471  .089 Uiso calc PR  .40 B 2 H
    C2S'  -.295(2)  .411(2)  -.5662(17)  .083(16) Uiso d PD  .40 B 2 C
    H2SD  -.2584  .3998  -.5954  .124 Uiso calc PR  .40 B 2 H
    H2SE  -.3401  .4270  -.5844  .124 Uiso calc PR  .40 B 2 H
    H2SF  -.3045  .3666  -.5438  .124 Uiso calc PR  .40 B 2 H
    C3S'  -.3145(13)  .5298(13)  -.4506(11)  .054(6) Uiso d PD  .40 B 2 C
    H3SC  -.3067  .5764  -.4710  .065 Uiso calc PR  .40 B 2 H
    H3SD  -.2690  .5177  -.4301  .065 Uiso calc PR  .40 B 2 H
    C4S'  -.3766(18)  .539(2)  -.4082(14)  .139(15) Uiso d PD  .40 B 2 C
    H4SD  -.3644  .5774  -.3811  .208 Uiso calc PR  .40 B 2 H
    H4SE  -.3839  .4927  -.3877  .208 Uiso calc PR  .40 B 2 H
    H4SF  -.4214  .5516  -.4285  .208 Uiso calc PR  .40 B 2 H
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Pt1 Mn1 . 2.6068(10) y
    Pt1 P1 . 2.3312(16) y
    Pt1 P2 . 2.2796(17) y
    Pt1 C1 . 1.991(6) y
    Pt1 C3 . 2.212(7) y
    Mn1 C1 . 1.924(7) y
    Mn1 C3 . 1.826(7) y
    Mn1 C4 . 1.775(8) y
    Mn1 C11 . 2.126(7) y
    Mn1 C12 . 2.112(7) y
    Mn1 C13 . 2.137(7) y
    Mn1 C14 . 2.178(7) y
    Mn1 C15 . 2.146(7) y
    P2 C29 . 1.801(7) n
    P2 C35 . 1.827(7) n
    P2 C16 . 1.835(6) n
    P1 C23 . 1.822(6) n
    P1 C17 . 1.825(7) n
    P1 C16 . 1.852(7) n
    O3 C3 . 1.189(8) y
    O4 C4 . 1.153(8) y
    C1 C2 . 1.363(9) y
    C2 C5 . 1.469(9) y
    C5 C6 . 1.383(9) n
    C5 C10 . 1.424(9) n
    C6 C7 . 1.390(9) n
    C7 C8 . 1.397(10) n
    C8 C9 . 1.388(10) n
    C9 C10 . 1.382(9) n
    C11 C15 . 1.373(10) n
    C11 C12 . 1.401(11) n
    C12 C13 . 1.407(11) n
    C13 C14 . 1.410(10) n
    C14 C15 . 1.435(10) n
    C17 C22 . 1.374(9) n
    C17 C18 . 1.386(9) n
    C18 C19 . 1.382(9) n
    C19 C20 . 1.395(10) n
    C20 C21 . 1.337(10) n
    C21 C22 . 1.404(10) n
    C23 C24 . 1.392(9) n
    C23 C28 . 1.395(9) n
    C24 C25 . 1.376(9) n
    C25 C26 . 1.359(10) n
    C26 C27 . 1.391(11) n
    C27 C28 . 1.384(10) n
    C29 C30 . 1.329(8) n
    C29 C34 . 1.379(10) n
    C30 C31 . 1.333(9) n
    C31 C32 . 1.386(11) n
    C32 C33 . 1.429(11) n
    C33 C34 . 1.378(10) n
    C35 C40 . 1.386(9) n
    C35 C36 . 1.391(9) n
    C36 C37 . 1.386(11) n
    C37 C38 . 1.372(11) n
    C38 C39 . 1.366(11) n
    C39 C40 . 1.408(10) n
    O1S C1S . 1.418(18) n
    O1S C3S . 1.442(14) n
    C1S C2S . 1.570(17) n
    C3S C4S . 1.543(17) n
    O1S' C3S' . 1.412(17) n
    O1S' C1S' . 1.464(17) n
    C1S' C2S' . 1.548(19) n
    C3S' C4S' . 1.524(19) n
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C1 Pt1 C3 . . 89.1(3) y
    C1 Pt1 P2 . . 102.7(2) y
    C3 Pt1 P2 . . 166.9(2) y
    C1 Pt1 P1 . . 169.4(2) y
    C3 Pt1 P1 . . 96.47(19) y
    P2 Pt1 P1 . . 72.83(6) y
    C1 Pt1 Mn1 . . 47.17(19) y
    C3 Pt1 Mn1 . . 43.57(19) y
    P2 Pt1 Mn1 . . 149.17(5) y
    P1 Pt1 Mn1 . . 135.32(5) y
    C4 Mn1 C3 . . 90.8(3) y
    C4 Mn1 C1 . . 92.4(3) y
    C3 Mn1 C1 . . 103.8(3) y
    C4 Mn1 C12 . . 93.7(3) n
    C3 Mn1 C12 . . 146.2(3) n
    C1 Mn1 C12 . . 109.4(3) n
    C4 Mn1 C11 . . 94.0(3) n
    C3 Mn1 C11 . . 107.7(3) n
    C1 Mn1 C11 . . 147.7(3) n
    C12 Mn1 C11 . . 38.6(3) n
    C4 Mn1 C13 . . 127.2(3) n
    C3 Mn1 C13 . . 140.3(3) n
    C1 Mn1 C13 . . 87.3(3) n
    C12 Mn1 C13 . . 38.7(3) n
    C11 Mn1 C13 . . 63.8(3) n
    C4 Mn1 C15 . . 125.2(3) n
    C3 Mn1 C15 . . 85.7(3) n
    C1 Mn1 C15 . . 141.4(3) n
    C12 Mn1 C15 . . 64.5(3) n
    C11 Mn1 C15 . . 37.5(3) n
    C13 Mn1 C15 . . 64.2(3) n
    C4 Mn1 C14 . . 156.6(3) n
    C3 Mn1 C14 . . 102.3(3) n
    C1 Mn1 C14 . . 102.9(3) n
    C12 Mn1 C14 . . 64.7(3) n
    C11 Mn1 C14 . . 63.7(3) n
    C13 Mn1 C14 . . 38.1(3) n
    C15 Mn1 C14 . . 38.8(3) n
    C4 Mn1 Pt1 . . 105.3(2) n
    C3 Mn1 Pt1 . . 56.6(2) n
    C1 Mn1 Pt1 . . 49.35(19) n
    C12 Mn1 Pt1 . . 151.0(3) n
    C11 Mn1 Pt1 . . 154.6(2) n
    C13 Mn1 Pt1 . . 113.6(2) n
    C15 Mn1 Pt1 . . 117.3(2) n
    C14 Mn1 Pt1 . . 98.1(2) n
    C29 P2 C35 . . 106.9(3) n
    C29 P2 C16 . . 106.5(3) n
    C35 P2 C16 . . 106.1(3) n
    C29 P2 Pt1 . . 118.6(2) n
    C35 P2 Pt1 . . 120.1(2) n
    C16 P2 Pt1 . . 96.6(2) n
    C23 P1 C17 . . 102.6(3) n
    C23 P1 C16 . . 105.9(3) n
    C17 P1 C16 . . 105.9(3) n
    C23 P1 Pt1 . . 116.4(2) n
    C17 P1 Pt1 . . 128.8(2) n
    C16 P1 Pt1 . . 94.4(2) n
    C2 C1 Mn1 . . 143.2(5) y
    C2 C1 Pt1 . . 132.5(5) y
    Mn1 C1 Pt1 . . 83.5(2) y
    C1 C2 C5 . . 126.5(6) y
    O3 C3 Mn1 . . 153.4(6) y
    O3 C3 Pt1 . . 126.7(5) y
    Mn1 C3 Pt1 . . 79.8(3) y
    O4 C4 Mn1 . . 176.3(6) y
    C6 C5 C10 . . 116.6(6) n
    C6 C5 C2 . . 124.2(6) n
    C10 C5 C2 . . 119.3(6) n
    C5 C6 C7 . . 122.6(7) n
    C6 C7 C8 . . 120.1(7) n
    C9 C8 C7 . . 118.2(6) n
    C10 C9 C8 . . 121.5(7) n
    C9 C10 C5 . . 120.9(7) n
    C15 C11 C12 . . 109.9(7) n
    C15 C11 Mn1 . . 72.0(4) n
    C12 C11 Mn1 . . 70.1(4) n
    C11 C12 C13 . . 106.7(7) n
    C11 C12 Mn1 . . 71.3(4) n
    C13 C12 Mn1 . . 71.6(4) n
    C12 C13 C14 . . 109.1(7) n
    C12 C13 Mn1 . . 69.7(4) n
    C14 C13 Mn1 . . 72.5(4) n
    C13 C14 C15 . . 106.1(7) n
    C13 C14 Mn1 . . 69.3(4) n
    C15 C14 Mn1 . . 69.4(4) n
    C11 C15 C14 . . 108.0(7) n
    C11 C15 Mn1 . . 70.5(4) n
    C14 C15 Mn1 . . 71.8(4) n
    P2 C16 P1 . . 95.9(3) y
    C22 C17 C18 . . 119.3(6) n
    C22 C17 P1 . . 119.7(5) n
    C18 C17 P1 . . 120.8(5) n
    C19 C18 C17 . . 120.8(7) n
    C18 C19 C20 . . 119.4(7) n
    C21 C20 C19 . . 119.7(7) n
    C20 C21 C22 . . 121.7(7) n
    C17 C22 C21 . . 119.1(7) n
    C24 C23 C28 . . 119.8(6) n
    C24 C23 P1 . . 121.6(5) n
    C28 C23 P1 . . 118.4(5) n
    C25 C24 C23 . . 119.5(7) n
    C26 C25 C24 . . 121.4(7) n
    C25 C26 C27 . . 119.6(7) n
    C28 C27 C26 . . 120.3(8) n
    C27 C28 C23 . . 119.4(7) n
    C30 C29 C34 . . 113.3(6) n
    C30 C29 P2 . . 123.1(5) n
    C34 C29 P2 . . 123.6(5) n
    C29 C30 C31 . . 132.0(7) n
    C30 C31 C32 . . 114.0(7) n
    C31 C32 C33 . . 119.6(7) n
    C34 C33 C32 . . 118.9(7) n
    C33 C34 C29 . . 122.0(7) n
    C40 C35 C36 . . 119.4(6) n
    C40 C35 P2 . . 117.8(5) n
    C36 C35 P2 . . 122.9(5) n
    C37 C36 C35 . . 119.6(7) n
    C38 C37 C36 . . 121.0(7) n
    C39 C38 C37 . . 120.4(7) n
    C38 C39 C40 . . 119.6(8) n
    C35 C40 C39 . . 120.2(7) n
    C1S O1S C3S . . 110.5(13) n
    O1S C1S C2S . . 100.3(15) n
    O1S C3S C4S . . 109.0(17) n
    C3S' O1S' C1S' . . 104.1(17) n
    O1S' C1S' C2S' . . 96(2) n
    O1S' C3S' C4S' . . 111(2) n
data_global
_journal_date_recd_electronic     2001-10-10
_journal_date_accepted     2001-10-16
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2001
_journal_volume     57
_journal_issue     11
_journal_page_first     m541
_journal_page_last     m542
_journal_paper_category     EM
_publ_contact_author_name     'Fedor M. Dolgushin'
_publ_contact_author_address
;
A. N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences
Vavilov St. 28
Moscow 119991
Russian Federation
;
_publ_contact_author_email     fedya@xrlab.ineos.ac.ru
_publ_contact_author_fax     ' 7(095)135-50-85'
_publ_contact_author_phone     ' 7(095)135-92-14'
_publ_section_title
;
The binuclear μ-phenylvinylidene complex
(η⁵-C₅H₅)(CO)(μ-CO)MnPt(μ-C=CHPh)(η²-Ph₂PCH₂PPh₂).Et₂O
;
loop_
    _publ_author_name
    _publ_author_address
    'Dolgushin, Fedor M.'
;
A. N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences
Vavilov St. 28
Moscow 119991
Russian Federation
;
    'Deykhina, Nina A.'
;
Institute of Chemistry and Chemical Technology
Russian Academy of Sciences
Siberian Branch
Karl Marx St. 42
Krasnoyarsk 660049
Russian Federation
;
    'Pogrebnyakov, Dmitry A.'
;
Institute of Chemistry and Chemical Technology
Russian Academy of Sciences
Siberian Branch
Karl Marx St. 42
Krasnoyarsk 660049
Russian Federation
;
    'Antonova, Alla B.'
;
Institute of Chemistry and Chemical Technology
Russian Academy of Sciences
Siberian Branch
Karl Marx St. 42
Krasnoyarsk 660049
Russian Federation
;
