##############################################################################
###                                                                        ###
###           Full Paper (Acta Crystallographica Section C)                ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section C. It conforms to the editorial and technical    #
# requirements of Notes for Authors for Section C, and has been peer         #
# reviewed under the auspices of the IUCr Commission on Journals.            #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.0.1.  #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     SHELXL
_chemical_name_systematic
;
trans-[hydrotetrakis(trimethylphosphine)Rhodiumchloride/bromide]
[(tetrabromobenzene-1,2-diolato)borate] dichloromethane solvate
;
_chemical_name_common     ?
_chemical_formula_moiety
                         'C12 H37  Br0.27 Cl0.73  P4 Rh, C12 BBr8 O4 , CH2 Cl2 '
_chemical_formula_sum     'C25 H39 B Br8.27 Cl2.73 O4 P4 Rh'
_chemical_formula_analytical     ?
_chemical_formula_iupac
                      '[Rh  Cl0.73 Br0.27 H(C3 H9 P)4 ](C12 BBr8 O4 ), CH2 Cl2 '
_chemical_formula_weight     1398.57
_chemical_melting_point     ?
_symmetry_cell_setting     orthorhombic
_symmetry_space_group_name_H-M     P212121
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, -y, z+1/2'
    '-x, y+1/2, -z+1/2'
    'x+1/2, -y+1/2, -z'
_cell_length_a     13.0140(9)
_cell_length_b     16.3990(15)
_cell_length_c     20.726(3)
_cell_angle_alpha     90.000(8)
_cell_angle_beta     90.000(10)
_cell_angle_gamma     90.000(9)
_cell_volume     4423.3(8)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     462
_cell_measurement_theta_min     5
_cell_measurement_theta_max     25
_cell_measurement_temperature     173(2)
_exptl_crystal_description     rhomb
_exptl_crystal_colour     'pale yellow'
_exptl_crystal_size_max      .80
_exptl_crystal_size_mid      .30
_exptl_crystal_size_min      .30
_exptl_crystal_density_diffrn     2.100
_exptl_crystal_density_meas     'not measured'
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     2667
_exptl_absorpt_coefficient_mu     8.191
_exptl_absorpt_correction_type     'multi-scan (SADABS; Sheldrick, 1997)'
_exptl_absorpt_correction_T_min      .026
_exptl_absorpt_correction_T_max      .086
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     173(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength      .71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device     'Siemens SMART Area Detector'
_diffrn_measurement_method     'ω rotation with narrow frame'
_diffrn_detector_area_resol_mean     60
_diffrn_reflns_number     28033
_diffrn_reflns_av_R_equivalents      .0501
_diffrn_reflns_av_sigmaI/netI      .0747
_diffrn_reflns_theta_min     1.58
_diffrn_reflns_theta_max     27.51
_diffrn_reflns_theta_full     ?
_diffrn_measured_fraction_theta_max     ?
_diffrn_reflns_limit_h_min     -16
_diffrn_reflns_limit_h_max     16
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     21
_diffrn_reflns_limit_l_min     -15
_diffrn_reflns_limit_l_max     26
_diffrn_standards_number     ?
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     none
_reflns_number_total     10124
_reflns_number_gt     7391
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all      .0703
_refine_ls_R_factor_gt      .0486
_refine_ls_wR_factor_all      .1184
_refine_ls_wR_factor_ref      .1126
_refine_ls_goodness_of_fit_all     1.031
_refine_ls_goodness_of_fit_ref     1.154
_refine_ls_restrained_S_all     1.045
_refine_ls_restrained_S_obs     1.172
_refine_ls_number_reflns     10124
_refine_ls_number_parameters     430
_refine_ls_number_restraints     8
_refine_ls_hydrogen_treatment     'H atoms: see text'
_refine_ls_weighting_scheme
        'calc w = 1/[\s^2^(Fo^2^)+(0.0570P)^2^] where P=(Max{Fo^2^,0}+2Fc^2^)/3'
_refine_ls_shift/su_max      -.002
_refine_ls_shift/su_mean      .000
_refine_diff_density_max     1.441
_refine_diff_density_min     -1.102
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     none
_refine_ls_abs_structure_details     'Flack (1983)'
_refine_ls_abs_structure_Flack      .486(10)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C'  .0033  .0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H'  .0000  .0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'B' 'B'  .0013  .0007
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O'  .0106  .0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P'  .1023  .0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl'  .1484  .1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Br' 'Br'  -.2901 2.4595
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Rh' 'Rh' -1.1178  .9187
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Siemens, 1995a)'
_computing_cell_refinement     'SAINT (Siemens, 1995a)'
_computing_data_reduction     'SAINT'
_computing_structure_solution     'SHELXTL (Siemens, 1995b)'
_computing_structure_refinement     'SHELXTL'
_computing_molecular_graphics     'SHELXTL'
_computing_publication_material     'SHELXTL'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_thermal_displace_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_group
    _atom_site_type_symbol
    Rh1  .12299(4)  .68363(3)  .20445(3)  .02169(13) Uani d PD 1 1 Rh
    Cl10  .1299(9)  .7901(9)  .2912(8)  .044(4) Uani d PD  .740(10)
                                                                  1 Cl
    Br10  .1530(13)  .7914(8)  .2899(7)  .026(2) Uani d PD  .260(10)
                                                                   2 Br
    H1  .1060  .6048  .1354  .050 Uiso d . 1 . H
    P1  -.0034(2)  .63206(14)  .27492(13)  .0408(6) Uani d . 1 . P
    P2  .2436(2)  .58707(14)  .23955(13)  .0379(6) Uani d . 1 . P
    P3  .25129(14)  .75992(13)  .15273(12)  .0303(5) Uani d . 1 . P
    P4  -.00308(15)  .74355(13)  .14093(11)  .0289(5) Uani d . 1 . P
    Br1  .13374(6) 1.02967(5)  .50410(5)  .0396(2) Uani d . 1 . Br
    Br2  .01471(8)  .89700(7)  .40725(6)  .0636(3) Uani d . 1 . Br
    Br3  -.23684(9)  .88166(6)  .41526(7)  .0692(4) Uani d . 1 . Br
    Br4  -.36971(6) 1.01277(5)  .50684(5)  .0440(2) Uani d . 1 . Br
    Br5  -.10621(8) 1.22497(7)  .82408(5)  .0543(3) Uani d . 1 . Br
    Br6  -.11777(9) 1.42797(7)  .83927(6)  .0647(3) Uani d . 1 . Br
    Br7  -.12498(10) 1.54016(6)  .70702(7)  .0779(4) Uani d . 1 . Br
    Br8  -.11962(7) 1.45053(5)  .56376(5)  .0479(2) Uani d . 1 . Br
    B1  -.1232(7) 1.1722(5)  .6064(5)  .036(2) Uani d . 1 . B
    O1  -.2122(4) 1.1256(3)  .5815(3)  .0344(14) Uani d . 1 . O
    O2  -.0333(4) 1.1293(3)  .5824(3)  .0333(14) Uani d . 1 . O
    O3  -.1262(4) 1.2580(3)  .5847(3)  .0328(12) Uani d . 1 . O
    O4  -.1236(4) 1.1783(3)  .6780(3)  .0336(12) Uani d . 1 . O
    C11  -.0755(7)  .5433(6)  .2535(6)  .062(3) Uani d . 1 . C
    H11A  -.0290(10)  .4966(11)  .250(3)    .092 Uiso calc R 1 . H
    H11B  -.110(5)    .5525(18)  .2122(18)  .092 Uiso calc R 1 . H
    H11C  -.127(4)    .532(3)    .2870(18)  .092 Uiso calc R 1 . H
    C12  .0424(8)  .6099(7)  .3558(5)  .063(3) Uani d . 1 . C
    H12A  .085(5)    .655(2)    .3712(14)  .094 Uiso calc R 1 . H
    H12B  .084(5)    .560(2)    .3551(8)  .094 Uiso calc R 1 . H
    H12C  -.0164(8)  .603(4)    .3848(9)  .094 Uiso calc R 1 . H
    C13  -.0986(6)  .7054(6)  .2990(5)  .054(3) Uani d . 1 . C
    H13A  -.0645(7)  .7556(16)  .313(3)    .081 Uiso calc R 1 . H
    H13B  -.140(3)    .6831(17)  .335(2)    .081 Uiso calc R 1 . H
    H13C  -.144(3)    .718(3)    .2624(11)  .081 Uiso calc R 1 . H
    C21  .3176(8)  .6019(8)  .3126(6)  .076(4) Uani d . 1 . C
    H21A  .2714(11)  .617(5)    .3480(11)  .114 Uiso calc R 1 . H
    H21B  .368(4)    .645(4)    .3058(14)  .114 Uiso calc R 1 . H
    H21C  .353(5)    .5512(17)  .324(2)    .114 Uiso calc R 1 . H
    C22  .1910(7)  .4844(5)  .2519(6)  .062(3) Uani d . 1 . C
    H22A  .162(5)    .4642(18)  .2113(10)  .094 Uiso calc R 1 . H
    H22B  .137(4)    .4865(9)  .285(3)    .094 Uiso calc R 1 . H
    H22C  .2459(14)  .4478(12)  .266(3)    .094 Uiso calc R 1 . H
    C23  .3438(6)  .5600(5)  .1816(6)  .053(3) Uani d . 1 . C
    H23A  .3136(11)  .555(4)    .1385(8)  .079 Uiso calc R 1 . H
    H23B  .375(4)    .508(2)    .1940(18)  .079 Uiso calc R 1 . H
    H23C  .397(3)    .603(2)    .181(2)    .079 Uiso calc R 1 . H
    C31  .2181(7)  .8677(5)  .1389(5)  .047(3) Uani d . 1 . C
    H31A  .192(4)    .8915(11)  .1789(9)  .070 Uiso calc R 1 . H
    H31B  .165(4)    .8713(5)  .105(2)    .070 Uiso calc R 1 . H
    H31C  .2795(13)  .8975(9)  .125(3)    .070 Uiso calc R 1 . H
    C32  .3028(7)  .7288(5)  .0746(5)  .052(3) Uani d . 1 . C
    H32A  .2506(18)  .737(4)    .0412(7)  .078 Uiso calc R 1 . H
    H32B  .322(5)    .6710(12)  .0762(10)  .078 Uiso calc R 1 . H
    H32C  .364(3)    .762(3)    .0644(15)  .078 Uiso calc R 1 . H
    C33  .3680(6)  .7726(5)  .2035(5)  .049(2) Uani d . 1 . C
    H33A  .399(3)    .7192(6)  .211(3)    .074 Uiso calc R 1 . H
    H33B  .3488(9)  .798(4)    .2447(13)  .074 Uiso calc R 1 . H
    H33C  .417(2)    .808(3)    .1811(14)  .074 Uiso calc R 1 . H
    C41  -.0512(6)  .8427(5)  .1658(5)  .042(2) Uani d . 1 . C
    H41A  -.014(3)    .8856(5)  .143(2)    .063 Uiso calc R 1 . H
    H41B  -.041(4)    .8495(15)  .2123(7)  .063 Uiso calc R 1 . H
    H41C  -.1247(12)  .8464(14)  .156(3)    .063 Uiso calc R 1 . H
    C42  .0297(7)  .7576(6)  .0554(4)  .049(2) Uani d . 1 . C
    H42A  .090(3)    .793(3)    .0518(5)  .074 Uiso calc R 1 . H
    H42B  -.0286(18)  .782(3)    .0328(7)  .074 Uiso calc R 1 . H
    H42C  .045(4)    .7046(7)  .0359(8)  .074 Uiso calc R 1 . H
    C43  -.1166(6)  .6842(6)  .1275(5)  .050(2) Uani d . 1 . C
    H43A  -.150(3)    .673(3)    .1689(5)  .076 Uiso calc R 1 . H
    H43B  -.0980(9)  .6328(18)  .106(3)    .076 Uiso calc R 1 . H
    H43C  -.164(2)    .7147(17)  .100(3)    .076 Uiso calc R 1 . H
    C51  -.1730(6) 1.0665(5)  .5446(4)  .029(2) Uani d . 1 . C
    C52  -.0655(6) 1.0706(4)  .5429(4)  .024(2) Uani d . 1 . C
    C53  -.0109(5) 1.0200(4)  .5034(4)  .027(2) Uani d . 1 . C
    C54  -.0638(7)  .9618(5)  .4652(5)  .038(2) Uani d . 1 . C
    C55  -.1663(7)  .9603(5)  .4652(4)  .034(2) Uani d . 1 . C
    C56  -.2253(5) 1.0116(4)  .5057(4)  .028(2) Uani d . 1 . C
    C61  -.1236(6) 1.3046(5)  .6373(4)  .029(2) Uani d . 1 . C
    C62  -.1230(5) 1.2581(4)  .6915(3)  .027(2) Uani d . 1 . C
    C63  -.1169(6) 1.2951(5)  .7522(4)  .037(2) Uani d . 1 . C
    C64  -.1163(7) 1.3795(5)  .7569(5)  .043(2) Uani d . 1 . C
    C65  -.1209(6) 1.4254(4)  .7012(5)  .035(2) Uani d . 1 . C
    C66  -.1219(6) 1.3906(5)  .6393(4)  .036(2) Uani d . 1 . C
    C91  -.1108(7)  .6297(5)  .4883(5)  .049(2) Uiso d PD  .559(10) 1 C
    H91A  -.1236(7)  .5711(5)  .4962(5)  .059 Uiso calc PR  .559(10) 1 H
    H91B  -.0978(7)  .6389(5)  .4418(5)  .059 Uiso calc PR  .559(10) 1 H
    Cl2  -.2113(14)  .6908(13)  .5172(14)  .365(9) Uiso d PD  .559(10) 1 Cl
    Cl3  -.0149(12)  .6658(13)  .5344(10)  .293(7) Uiso d PD  .559(10) 1 Cl
    C91A  -.1108(7)  .6297(5)  .4883(5)  .049(2) Uiso d PD  .441(10) 2 C
    H91C  -.0540(15)  .6265(17)  .4566(15)  .059 Uiso calc PR  .441(10) 2 H
    H91D  -.1197(15)  .5769(17)  .5107(15)  .059 Uiso calc PR  .441(10) 2 H
    Cl2A  -.2208(15)  .6662(17)  .4566(15)  .365(9) Uiso d PD  .441(10) 2 Cl
    Cl3A  -.099(2)    .7163(12)  .5438(10)  .293(7) Uiso d PD  .441(10) 2 Cl
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles, correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Rh1 P4 . 2.322(2) y
    Rh1 P2 . 2.345(2) y
    Rh1 P3 . 2.346(2) y
    Rh1 P1 . 2.357(2) y
    Rh1 Cl10 . 2.507(14) y
    Rh1 Br10 . 2.531(12) y
    P1 C11 . 1.787(10) ?
    P1 C13 . 1.798(9) ?
    P1 C12 . 1.817(11) ?
    P2 C21 . 1.811(11) ?
    P2 C23 . 1.828(9) ?
    P2 C22 . 1.835(9) ?
    P3 C32 . 1.826(10) ?
    P3 C31 . 1.841(8) ?
    P3 C33 . 1.859(9) ?
    P4 C43 . 1.792(8) ?
    P4 C41 . 1.817(8) ?
    P4 C42 . 1.838(10) ?
    Br1 C53 . 1.889(7) y
    Br2 C54 . 1.903(9) y
    Br3 C55 . 1.891(8) y
    Br4 C56 . 1.879(7) y
    Br5 C63 . 1.887(8) y
    Br6 C64 . 1.883(9) y
    Br7 C65 . 1.886(7) y
    Br8 C66 . 1.848(9) y
    B1 O2 . 1.453(11) y
    B1 O3 . 1.478(10) y
    B1 O1 . 1.482(10) y
    B1 O4 . 1.486(11) y
    O1 C51 . 1.335(9) y
    O2 C52 . 1.330(9) y
    O3 C61 . 1.333(8) y
    O4 C62 . 1.339(8) y
    C51 C56 . 1.388(11) ?
    C51 C52 . 1.401(10) ?
    C52 C53 . 1.365(10) ?
    C53 C54 . 1.418(11) ?
    C54 C55 . 1.333(11) ?
    C55 C56 . 1.415(11) ?
    C61 C62 . 1.357(10) ?
    C61 C66 . 1.412(11) ?
    C62 C63 . 1.399(10) ?
    C63 C64 . 1.387(11) ?
    C64 C65 . 1.380(13) ?
    C65 C66 . 1.404(11) ?
    C91 Cl3 . 1.680(9) ?
    C91 Cl2 . 1.752(9) ?
    C91A Cl2A . 1.685(10) ?
    C91A Cl3A . 1.833(10) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    P4 Rh1 P2 . . 159.16(9) y
    P4 Rh1 P3 . . 91.04(8) y
    P2 Rh1 P3 . . 91.45(8) y
    P4 Rh1 P1 . . 90.57(8) y
    P2 Rh1 P1 . . 91.88(8) y
    P3 Rh1 P1 . . 166.27(9) y
    P4 Rh1 Cl10 . . 97.9(4) n
    P2 Rh1 Cl10 . . 102.9(4) n
    P3 Rh1 Cl10 . . 86.0(3) n
    P1 Rh1 Cl10 . . 80.3(3) n
    C11 P1 C13 . . 104.6(4) y
    C11 P1 C12 . . 103.8(6) y
    C13 P1 C12 . . 96.0(5) y
    C11 P1 Rh1 . . 120.3(4) ?
    C13 P1 Rh1 . . 114.4(3) ?
    C12 P1 Rh1 . . 114.5(3) ?
    C21 P2 C23 . . 101.7(5) y
    C21 P2 C22 . . 101.8(6) y
    C23 P2 C22 . . 97.8(5) y
    C21 P2 Rh1 . . 121.6(4) ?
    C23 P2 Rh1 . . 115.9(4) ?
    C22 P2 Rh1 . . 114.4(3) ?
    C32 P3 C31 . . 102.5(5) y
    C32 P3 C33 . . 103.5(5) y
    C31 P3 C33 . . 99.9(4) y
    C32 P3 Rh1 . . 121.2(3) ?
    C31 P3 Rh1 . . 114.6(3) ?
    C33 P3 Rh1 . . 112.5(3) ?
    C43 P4 C41 . . 104.2(4) y
    C43 P4 C42 . . 96.3(5) y
    C41 P4 C42 . . 104.0(5) y
    C43 P4 Rh1 . . 116.2(3) ?
    C41 P4 Rh1 . . 117.5(3) ?
    C42 P4 Rh1 . . 115.9(3) ?
    O2 B1 O3 . . 112.2(7) y
    O2 B1 O1 . . 105.1(6) y
    O3 B1 O1 . . 111.3(8) y
    O2 B1 O4 . . 112.3(8) y
    O3 B1 O4 . . 103.9(6) y
    O1 B1 O4 . . 112.4(7) y
    C51 O1 B1 . . 105.9(6) ?
    C52 O2 B1 . . 107.9(6) ?
    C61 O3 B1 . . 107.2(6) ?
    C62 O4 B1 . . 106.0(6) ?
    O1 C51 C56 . . 128.0(7) ?
    O1 C51 C52 . . 111.2(7) ?
    C56 C51 C52 . . 120.5(8) ?
    O2 C52 C53 . . 130.2(7) ?
    O2 C52 C51 . . 109.5(7) ?
    C53 C52 C51 . . 120.3(8) ?
    C52 C53 C54 . . 119.4(7) ?
    C52 C53 Br1 . . 117.5(6) ?
    C54 C53 Br1 . . 123.0(6) ?
    C55 C54 C53 . . 119.9(8) ?
    C55 C54 Br2 . . 121.8(7) ?
    C53 C54 Br2 . . 117.9(6) ?
    C54 C55 C56 . . 122.1(8) ?
    C54 C55 Br3 . . 119.9(7) ?
    C56 C55 Br3 . . 117.8(6) ?
    C51 C56 C55 . . 117.6(7) ?
    C51 C56 Br4 . . 118.5(6) ?
    C55 C56 Br4 . . 123.9(6) ?
    O3 C61 C62 . . 110.8(6) ?
    O3 C61 C66 . . 126.6(7) ?
    C62 C61 C66 . . 122.5(7) ?
    O4 C62 C61 . . 112.1(6) ?
    O4 C62 C63 . . 127.8(7) ?
    C61 C62 C63 . . 120.1(7) ?
    C64 C63 C62 . . 119.7(8) ?
    C64 C63 Br5 . . 123.5(7) ?
    C62 C63 Br5 . . 116.7(6) ?
    C65 C64 C63 . . 119.1(8) ?
    C65 C64 Br6 . . 121.8(6) ?
    C63 C64 Br6 . . 119.0(8) ?
    C64 C65 C66 . . 122.9(7) ?
    C64 C65 Br7 . . 119.5(6) ?
    C66 C65 Br7 . . 117.6(7) ?
    C65 C66 C61 . . 115.6(8) ?
    C65 C66 Br8 . . 123.9(6) ?
    C61 C66 Br8 . . 120.5(6) ?
    Cl3 C91 Cl2 . . 99.2(8) ?
    Cl2A C91A Cl3A . . 92.4(9) ?
    C53 Br1 Br8 . 4_576 156.0(3) y
    C53 Br1 Br6 . 3_546 84.9(2) y
    C55 Br3 Br5 . 2_474 168.3(3) y
    C56 Br4 Br8 . 4_476 153.6(3) y
    C63 Br5 Br3 . 2_475 137.1(3) y
    C64 Br6 Br1 . 3_556 176.5(3) y
    C66 Br8 Br1 . 4_476 111.9(2) y
    C66 Br8 Br4 . 4_576 116.4(2) y
data_global
_journal_date_recd_electronic     1999-08-27
_journal_date_accepted     1999-10-21
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2000
_journal_volume     56
_journal_issue      1
_journal_page_first     50
_journal_page_last     52
_journal_paper_category     FM
_publ_contact_author_name     'Dr. M.J. Quayle'
_publ_contact_author_address
;
Colloids, Crystals and Interfaces Group,
Department of Chemical Engineering,
UMIST,
P.O. Box 88,
Manchester M60 1QD.
;
_publ_contact_author_email     michael.j.quayle@umist.ac.uk
_publ_contact_author_fax     '0161 200 4399'
_publ_contact_author_phone     '0161 200 4362'
_publ_section_title
;
Compositional disorder in
trans-[RhCl~0.74~Br~0.26~H(C₃H₉P)₄](C₁₂BBr₈O₄).CH₂Cl₂
;
loop_
    _publ_author_name
    _publ_author_address
    'Norman, Nicholas C.'
;  School of Chemistry
 University of Bristol
 Cantock's Close
 BS8 1TS. Bristol, UK
;
    'Orpen, A. Guy'
;  School of Chemistry
 University of Bristol
 Cantock's Close
 BS8 1TS. Bristol, UK
;
    'Quayle, Michael J.'
;  School of Chemistry
 University of Bristol
 Cantock's Close
 BS8 1TS. Bristol, UK
;
    'Robins, Edward G.'
;  School of Chemistry
 University of Bristol
 Cantock's Close
 BS8 1TS. Bristol, UK
;
