##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section C. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section C, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
catena-poly[[aquapyridinecadmium(II)]μ₃-{4,4'-[(2,4,6-trimethyl-
1,3-phenylene)bis(methylene)]dibenzoato}]
;
_chemical_name_common     ?
_chemical_formula_moiety     'C30 H29 Cd N O5'
_chemical_formula_sum     'C30 H29 Cd N O5'
_chemical_formula_iupac     '[Cd (C25 H22 O4) (C5 H5 N) (H2 O)]'
_chemical_formula_weight     595.94
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'C 2/c'
_space_group_name_Hall     '-C 2yc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y, -z+1/2'
    'x+1/2, y+1/2, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y, z-1/2'
    '-x+1/2, -y+1/2, -z'
    'x+1/2, -y+1/2, z-1/2'
_cell_length_a     40.058(4)
_cell_length_b     5.9102(5)
_cell_length_c     24.142(2)
_cell_angle_alpha     90.00
_cell_angle_beta     111.7230(10)
_cell_angle_gamma     90.00
_cell_volume     5309.8(8)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     4106
_cell_measurement_theta_min     4.538
_cell_measurement_theta_max     53.618
_cell_measurement_temperature     298(2)
_exptl_crystal_description     block
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.10
_exptl_crystal_size_mid     0.10
_exptl_crystal_size_min     0.08
_exptl_crystal_density_diffrn     1.491
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     2432
_exptl_absorpt_coefficient_mu     0.863
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2005)'
_exptl_absorpt_correction_T_min     0.9187
_exptl_absorpt_correction_T_max     0.9342
_exptl_special_details     ?
_diffrn_ambient_temperature     298(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART APEXII CCD area-detector'
_diffrn_measurement_method     'ω and φ'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     14990
_diffrn_reflns_av_R_equivalents     0.0308
_diffrn_reflns_av_sigmaI/netI     0.0433
_diffrn_reflns_theta_min     1.74
_diffrn_reflns_theta_max     27.53
_diffrn_reflns_theta_full     27.53
_diffrn_measured_fraction_theta_max     0.983
_diffrn_measured_fraction_theta_full     0.983
_diffrn_reflns_limit_h_min     -50
_diffrn_reflns_limit_h_max     51
_diffrn_reflns_limit_k_min     -7
_diffrn_reflns_limit_k_max     7
_diffrn_reflns_limit_l_min     -31
_diffrn_reflns_limit_l_max     19
_diffrn_standards_number     ?
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
Refinement of F² against ALL reflections.  The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based on F,
with F set to zero for negative F². The threshold expression of F² >
2sigma(F²) is used only for calculating R-factors(gt) etc. and is not
relevant to the choice of reflections for refinement.  R-factors based on F²
are statistically about twice as large as those based on F, and R-factors based
on ALL data will be even larger.
;
_reflns_number_total     6029
_reflns_number_gt     4415
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0535
_refine_ls_R_factor_gt     0.0313
_refine_ls_wR_factor_gt     0.0637
_refine_ls_wR_factor_ref     0.0711
_refine_ls_goodness_of_fit_ref     1.000
_refine_ls_restrained_S_all     1.000
_refine_ls_number_reflns     6029
_refine_ls_number_parameters     337
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.0287P)²+1.6485P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.003
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.483
_refine_diff_density_min     -0.290
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cd' 'Cd' -0.8075 1.2024
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2005)'
_computing_cell_refinement     'APEX2 (Bruker, 2005)'
_computing_data_reduction     'SAINT (Bruker, 2005)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics     'DIAMOND (Brandenburg, 2008)'
_computing_publication_material     'publCIF (Westrip, 2010)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_symmetry_multiplicity
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Cd Cd1 0.712203(5) 0.41631(3) 1.028794(8) 0.03501(7) Uani d . 1 1 . .
    C C1 0.71592(6) 0.2840(5) 0.90723(11) 0.0394(6) Uani d . 1 1 . .
    C C2 0.68222(6) 0.3377(4) 0.85560(10) 0.0350(6) Uani d . 1 1 . .
    C C3 0.66517(7) 0.5452(5) 0.85087(11) 0.0433(7) Uani d . 1 1 . .
    H H3 0.6738 0.6502 0.8816 0.052 Uiso calc R 1 1 . .
    C C4 0.63537(7) 0.5963(5) 0.80056(12) 0.0462(7) Uani d . 1 1 . .
    H H4 0.6239 0.7350 0.7981 0.055 Uiso calc R 1 1 . .
    C C5 0.62239(7) 0.4438(5) 0.75390(11) 0.0407(6) Uani d . 1 1 . .
    C C6 0.63862(7) 0.2353(5) 0.76003(12) 0.0490(7) Uani d . 1 1 . .
    H H6 0.6295 0.1279 0.7300 0.059 Uiso calc R 1 1 . .
    C C7 0.66839(7) 0.1832(5) 0.81039(12) 0.0463(7) Uani d . 1 1 . .
    H H7 0.6791 0.0417 0.8136 0.056 Uiso calc R 1 1 . .
    C C8 0.59218(8) 0.5106(5) 0.69607(13) 0.0549(8) Uani d . 1 1 . .
    H H8A 0.5749 0.6018 0.7056 0.066 Uiso calc R 1 1 . .
    H H8B 0.6021 0.6037 0.6728 0.066 Uiso calc R 1 1 . .
    C C9 0.57273(7) 0.3103(5) 0.65829(11) 0.0445(7) Uani d . 1 1 . .
    C C10 0.58113(7) 0.2381(6) 0.61010(12) 0.0499(7) Uani d . 1 1 . .
    C C11 0.56298(8) 0.0547(6) 0.57769(12) 0.0576(8) Uani d . 1 1 . .
    H H11 0.5688 0.0053 0.5458 0.069 Uiso calc R 1 1 . .
    C C12 0.53656(8) -0.0595(5) 0.59015(12) 0.0512(7) Uani d . 1 1 . .
    C C13 0.52838(7) 0.0098(5) 0.63866(12) 0.0467(7) Uani d . 1 1 . .
    C C14 0.54686(7) 0.1937(5) 0.67331(12) 0.0453(7) Uani d . 1 1 . .
    C C15 0.53877(8) 0.2679(6) 0.72702(13) 0.0680(9) Uani d . 1 1 . .
    H H15A 0.5414 0.1413 0.7532 0.102 Uiso calc R 1 1 . .
    H H15B 0.5146 0.3241 0.7142 0.102 Uiso calc R 1 1 . .
    H H15C 0.5552 0.3853 0.7478 0.102 Uiso calc R 1 1 . .
    C C16 0.60921(9) 0.3562(7) 0.59200(16) 0.0812(12) Uani d . 1 1 . .
    H H16A 0.6011 0.5060 0.5781 0.122 Uiso calc R 1 1 . .
    H H16B 0.6128 0.2721 0.5607 0.122 Uiso calc R 1 1 . .
    H H16C 0.6314 0.3650 0.6257 0.122 Uiso calc R 1 1 . .
    C C17 0.51738(9) -0.2554(6) 0.55088(15) 0.0763(11) Uani d . 1 1 . .
    H H17A 0.5230 -0.3930 0.5736 0.114 Uiso calc R 1 1 . .
    H H17B 0.5251 -0.2673 0.5177 0.114 Uiso calc R 1 1 . .
    H H17C 0.4919 -0.2300 0.5364 0.114 Uiso calc R 1 1 . .
    C C18 0.49866(7) -0.1080(5) 0.65219(14) 0.0576(8) Uani d . 1 1 . .
    H H18A 0.5044 -0.1028 0.6949 0.069 Uiso calc R 1 1 . .
    H H18B 0.4981 -0.2658 0.6409 0.069 Uiso calc R 1 1 . .
    C C19 0.46135(7) -0.0082(5) 0.62091(12) 0.0439(7) Uani d . 1 1 . .
    C C20 0.43140(7) -0.1317(5) 0.61823(14) 0.0527(8) Uani d . 1 1 . .
    H H20 0.4344 -0.2732 0.6363 0.063 Uiso calc R 1 1 . .
    C C21 0.39694(7) -0.0480(5) 0.58901(13) 0.0512(7) Uani d . 1 1 . .
    H H21 0.3772 -0.1354 0.5867 0.061 Uiso calc R 1 1 . .
    C C22 0.39184(6) 0.1647(4) 0.56331(11) 0.0372(6) Uani d . 1 1 . .
    C C23 0.42143(7) 0.2881(5) 0.56611(12) 0.0470(7) Uani d . 1 1 . .
    H H23 0.4184 0.4312 0.5489 0.056 Uiso calc R 1 1 . .
    C C24 0.45580(7) 0.2023(5) 0.59427(13) 0.0520(8) Uani d . 1 1 . .
    H H24 0.4755 0.2881 0.5952 0.062 Uiso calc R 1 1 . .
    C C25 0.35503(7) 0.2602(5) 0.53201(11) 0.0388(6) Uani d . 1 1 . .
    C C26 0.71673(10) 0.5108(7) 1.16252(15) 0.0721(10) Uani d . 1 1 . .
    H H26 0.7287 0.6354 1.1552 0.087 Uiso calc R 1 1 . .
    C C27 0.71442(11) 0.4934(8) 1.21776(17) 0.0815(11) Uani d . 1 1 . .
    H H27 0.7241 0.6047 1.2465 0.098 Uiso calc R 1 1 . .
    C C28 0.69805(13) 0.3143(9) 1.22914(19) 0.0921(13) Uani d . 1 1 . .
    H H28 0.6968 0.2951 1.2666 0.111 Uiso calc R 1 1 . .
    C C29 0.68310(14) 0.1588(8) 1.1853(2) 0.1049(15) Uani d . 1 1 . .
    H H29 0.6709 0.0343 1.1920 0.126 Uiso calc R 1 1 . .
    C C30 0.68627(11) 0.1886(6) 1.13040(17) 0.0766(11) Uani d . 1 1 . .
    H H30 0.6761 0.0818 1.1006 0.092 Uiso calc R 1 1 . .
    N N1 0.70310(7) 0.3622(4) 1.11923(11) 0.0536(6) Uani d . 1 1 . .
    O O1 0.72884(5) 0.4313(3) 0.94771(8) 0.0491(5) Uani d . 1 1 . .
    O O1W 0.71470(5) 0.7930(3) 1.04106(8) 0.0523(5) Uani d . 1 1 . .
    H H1WA 0.7335 0.8425 1.0367 0.063 Uiso d R 1 1 . .
    H H1WB 0.6962 0.8524 1.0150 0.063 Uiso d R 1 1 . .
    O O2 0.73032(5) 0.0959(4) 0.90692(8) 0.0566(6) Uani d . 1 1 . .
    O O3 0.35118(5) 0.4644(3) 0.51865(9) 0.0511(5) Uani d . 1 1 . .
    O O4 0.32799(5) 0.1295(3) 0.51925(9) 0.0490(5) Uani d . 1 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Cd1 O1W . 2.2431(19) y
    Cd1 O2 7_657 2.2516(18) y
    Cd1 O1 . 2.2913(18) y
    Cd1 O4 2_656 2.3302(18) y
    Cd1 N1 . 2.365(2) y
    Cd1 O3 2_656 2.3846(18) y
    C1 O2 . 1.254(3) ?
    C1 O1 . 1.267(3) ?
    C1 C2 . 1.494(3) ?
    C2 C7 . 1.373(3) ?
    C2 C3 . 1.387(4) ?
    C3 C4 . 1.385(4) ?
    C3 H3 . 0.9300 ?
    C4 C5 . 1.385(4) ?
    C4 H4 . 0.9300 ?
    C5 C6 . 1.376(4) ?
    C5 C8 . 1.523(3) ?
    C6 C7 . 1.386(3) ?
    C6 H6 . 0.9300 ?
    C7 H7 . 0.9300 ?
    C8 C9 . 1.521(4) ?
    C8 H8A . 0.9700 ?
    C8 H8B . 0.9700 ?
    C9 C10 . 1.393(4) ?
    C9 C14 . 1.400(4) ?
    C10 C11 . 1.377(4) ?
    C10 C16 . 1.519(4) ?
    C11 C12 . 1.379(4) ?
    C11 H11 . 0.9300 ?
    C12 C13 . 1.390(4) ?
    C12 C17 . 1.513(4) ?
    C13 C14 . 1.403(4) ?
    C13 C18 . 1.516(4) ?
    C14 C15 . 1.513(4) ?
    C15 H15A . 0.9600 ?
    C15 H15B . 0.9600 ?
    C15 H15C . 0.9600 ?
    C16 H16A . 0.9600 ?
    C16 H16B . 0.9600 ?
    C16 H16C . 0.9600 ?
    C17 H17A . 0.9600 ?
    C17 H17B . 0.9600 ?
    C17 H17C . 0.9600 ?
    C18 C19 . 1.522(4) ?
    C18 H18A . 0.9700 ?
    C18 H18B . 0.9700 ?
    C19 C24 . 1.380(4) ?
    C19 C20 . 1.385(4) ?
    C20 C21 . 1.388(4) ?
    C20 H20 . 0.9300 ?
    C21 C22 . 1.383(4) ?
    C21 H21 . 0.9300 ?
    C22 C23 . 1.372(3) ?
    C22 C25 . 1.496(3) ?
    C23 C24 . 1.386(4) ?
    C23 H23 . 0.9300 ?
    C24 H24 . 0.9300 ?
    C25 O3 . 1.244(3) ?
    C25 O4 . 1.272(3) ?
    C25 Cd1 2_656 2.708(3) ?
    C26 N1 . 1.319(4) ?
    C26 C27 . 1.375(5) ?
    C26 H26 . 0.9300 ?
    C27 C28 . 1.326(6) ?
    C27 H27 . 0.9300 ?
    C28 C29 . 1.362(6) ?
    C28 H28 . 0.9300 ?
    C29 C30 . 1.388(5) ?
    C29 H29 . 0.9300 ?
    C30 N1 . 1.309(4) ?
    C30 H30 . 0.9300 ?
    O1W H1WA . 0.8501 ?
    O1W H1WB . 0.8498 ?
    O2 Cd1 7_657 2.2516(18) ?
    O3 Cd1 2_656 2.3846(18) ?
    O4 Cd1 2_656 2.3302(17) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1W Cd1 O2 . 7_657 87.51(7) y
    O1W Cd1 O1 . . 93.53(7) y
    O2 Cd1 O1 7_657 . 92.50(7) y
    O1W Cd1 O4 . 2_656 140.95(6) y
    O2 Cd1 O4 7_657 2_656 131.43(7) y
    O1 Cd1 O4 . 2_656 88.21(7) y
    O1W Cd1 N1 . . 91.54(8) y
    O2 Cd1 N1 7_657 . 80.04(8) y
    O1 Cd1 N1 . . 170.79(8) y
    O4 Cd1 N1 2_656 . 92.69(8) y
    O1W Cd1 O3 . 2_656 86.14(6) y
    O2 Cd1 O3 7_657 2_656 165.98(7) y
    O1 Cd1 O3 . 2_656 100.35(7) y
    O4 Cd1 O3 2_656 2_656 55.31(6) y
    N1 Cd1 O3 . 2_656 87.65(8) y
    O2 C1 O1 . . 123.8(2) ?
    O2 C1 C2 . . 117.3(2) ?
    O1 C1 C2 . . 118.9(3) ?
    C7 C2 C3 . . 118.7(2) ?
    C7 C2 C1 . . 119.8(2) ?
    C3 C2 C1 . . 121.4(2) ?
    C4 C3 C2 . . 120.2(3) ?
    C4 C3 H3 . . 119.9 ?
    C2 C3 H3 . . 119.9 ?
    C3 C4 C5 . . 120.9(3) ?
    C3 C4 H4 . . 119.6 ?
    C5 C4 H4 . . 119.6 ?
    C6 C5 C4 . . 118.4(2) ?
    C6 C5 C8 . . 121.0(3) ?
    C4 C5 C8 . . 120.6(2) ?
    C5 C6 C7 . . 120.8(3) ?
    C5 C6 H6 . . 119.6 ?
    C7 C6 H6 . . 119.6 ?
    C2 C7 C6 . . 120.8(3) ?
    C2 C7 H7 . . 119.6 ?
    C6 C7 H7 . . 119.6 ?
    C9 C8 C5 . . 113.9(2) ?
    C9 C8 H8A . . 108.8 ?
    C5 C8 H8A . . 108.8 ?
    C9 C8 H8B . . 108.8 ?
    C5 C8 H8B . . 108.8 ?
    H8A C8 H8B . . 107.7 ?
    C10 C9 C14 . . 119.8(3) ?
    C10 C9 C8 . . 120.7(3) ?
    C14 C9 C8 . . 119.5(3) ?
    C11 C10 C9 . . 118.4(3) ?
    C11 C10 C16 . . 119.3(3) ?
    C9 C10 C16 . . 122.2(3) ?
    C10 C11 C12 . . 123.2(3) ?
    C10 C11 H11 . . 118.4 ?
    C12 C11 H11 . . 118.4 ?
    C11 C12 C13 . . 118.6(3) ?
    C11 C12 C17 . . 119.4(3) ?
    C13 C12 C17 . . 122.0(3) ?
    C12 C13 C14 . . 119.6(3) ?
    C12 C13 C18 . . 119.7(3) ?
    C14 C13 C18 . . 120.7(3) ?
    C9 C14 C13 . . 120.3(3) ?
    C9 C14 C15 . . 119.6(3) ?
    C13 C14 C15 . . 120.1(3) ?
    C14 C15 H15A . . 109.5 ?
    C14 C15 H15B . . 109.5 ?
    H15A C15 H15B . . 109.5 ?
    C14 C15 H15C . . 109.5 ?
    H15A C15 H15C . . 109.5 ?
    H15B C15 H15C . . 109.5 ?
    C10 C16 H16A . . 109.5 ?
    C10 C16 H16B . . 109.5 ?
    H16A C16 H16B . . 109.5 ?
    C10 C16 H16C . . 109.5 ?
    H16A C16 H16C . . 109.5 ?
    H16B C16 H16C . . 109.5 ?
    C12 C17 H17A . . 109.5 ?
    C12 C17 H17B . . 109.5 ?
    H17A C17 H17B . . 109.5 ?
    C12 C17 H17C . . 109.5 ?
    H17A C17 H17C . . 109.5 ?
    H17B C17 H17C . . 109.5 ?
    C13 C18 C19 . . 114.9(2) ?
    C13 C18 H18A . . 108.5 ?
    C19 C18 H18A . . 108.5 ?
    C13 C18 H18B . . 108.5 ?
    C19 C18 H18B . . 108.5 ?
    H18A C18 H18B . . 107.5 ?
    C24 C19 C20 . . 117.8(2) ?
    C24 C19 C18 . . 122.6(2) ?
    C20 C19 C18 . . 119.6(2) ?
    C19 C20 C21 . . 121.1(3) ?
    C19 C20 H20 . . 119.4 ?
    C21 C20 H20 . . 119.4 ?
    C22 C21 C20 . . 120.4(3) ?
    C22 C21 H21 . . 119.8 ?
    C20 C21 H21 . . 119.8 ?
    C23 C22 C21 . . 118.7(2) ?
    C23 C22 C25 . . 119.8(2) ?
    C21 C22 C25 . . 121.6(2) ?
    C22 C23 C24 . . 120.8(3) ?
    C22 C23 H23 . . 119.6 ?
    C24 C23 H23 . . 119.6 ?
    C19 C24 C23 . . 121.2(3) ?
    C19 C24 H24 . . 119.4 ?
    C23 C24 H24 . . 119.4 ?
    O3 C25 O4 . . 120.9(2) ?
    O3 C25 C22 . . 120.1(2) ?
    O4 C25 C22 . . 119.0(2) ?
    O3 C25 Cd1 . 2_656 61.70(13) ?
    O4 C25 Cd1 . 2_656 59.26(13) ?
    C22 C25 Cd1 . 2_656 177.11(18) ?
    N1 C26 C27 . . 124.2(4) ?
    N1 C26 H26 . . 117.9 ?
    C27 C26 H26 . . 117.9 ?
    C28 C27 C26 . . 118.5(4) ?
    C28 C27 H27 . . 120.8 ?
    C26 C27 H27 . . 120.8 ?
    C27 C28 C29 . . 119.1(4) ?
    C27 C28 H28 . . 120.5 ?
    C29 C28 H28 . . 120.5 ?
    C28 C29 C30 . . 119.2(4) ?
    C28 C29 H29 . . 120.4 ?
    C30 C29 H29 . . 120.4 ?
    N1 C30 C29 . . 122.1(4) ?
    N1 C30 H30 . . 118.9 ?
    C29 C30 H30 . . 118.9 ?
    C30 N1 C26 . . 116.9(3) ?
    C30 N1 Cd1 . . 124.3(2) ?
    C26 N1 Cd1 . . 118.8(2) ?
    C1 O1 Cd1 . . 117.87(16) ?
    Cd1 O1W H1WA . . 108.9 ?
    Cd1 O1W H1WB . . 109.2 ?
    H1WA O1W H1WB . . 109.5 ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    O1W H1WA O1 7_667 0.85 1.95 2.719(2) 150.7
    O1W H1WB O4 2_666 0.85 1.93 2.675(2) 146.2
data_global
_journal_date_recd_electronic     2012-06-21
_journal_date_accepted     2012-10-28
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2012
_journal_volume     68
_journal_issue     12
_journal_page_first     m333
_journal_page_last     m335
_journal_paper_category     FM
_journal_paper_doi     10.1107/S0108270112044587
_journal_coeditor_code     EM3052
_publ_contact_author_name     'Weiyong Ying'
_publ_contact_author_address
;
Engineering Research Center of Large Scale Reactor Engineering and Technology
Ministry of Education
State Key Laboratory of Chemical Engineering
East China University of Science and Technology
Shanghai 200237
People's Republic of China
;
_publ_contact_author_email     wying@ecust.edu.cn
_publ_contact_author_fax     ?
_publ_contact_author_phone     ?
_publ_section_title
;
Biphase synthesis of a one-dimensional coordination polymer based on a dinuclear
CdII secondary building unit and a novel semi-rigid dicarboxylate
;
loop_
    _publ_author_name
    _publ_author_address
    'Xiaolai Zhang'
;
Engineering Research Center of Large Scale Reactor Engineering and Technology
Ministry of Education
State Key Laboratory of Chemical Engineering
East China University of Science and Technology
Shanghai 200237
People's Republic of China
;
    'Weiyong Ying'
;
Engineering Research Center of Large Scale Reactor Engineering and Technology
Ministry of Education
State Key Laboratory of Chemical Engineering
East China University of Science and Technology
Shanghai 200237
People's Republic of China
;
