##############################################################################
###                                                                        ###
###           Full Paper (Acta Crystallographica Section C)                ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section C. It conforms to the editorial and technical    #
# requirements of Notes for Authors for Section C, and has been peer         #
# reviewed under the auspices of the IUCr Commission on Journals.            #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
Tetraphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III)
acetone solvate
;
_chemical_name_common     ?
_chemical_formula_moiety     'C24 H20 P + , C6 Au S10 - , C3 H6 O'
_chemical_formula_sum     'C33 H26 Au O P S10'
_chemical_formula_iupac     '(C24 H20 P) [Au (C3 S5)2] , C3 H6 O'
_chemical_formula_weight     987.07
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P2/c'
_symmetry_space_group_name_Hall     '-P 2yc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y, -z+1/2'
    '-x, -y, -z'
    'x, -y, z-1/2'
_cell_length_a     24.4198(7)
_cell_length_b     7.4511(2)
_cell_length_c     23.1654(6)
_cell_angle_alpha     90.00
_cell_angle_beta     115.7720(10)
_cell_angle_gamma     90.00
_cell_volume     3795.78(18)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     6858
_cell_measurement_theta_min     2.50
_cell_measurement_theta_max     27.48
_cell_measurement_temperature     296(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     brown
_exptl_crystal_size_max     0.24
_exptl_crystal_size_mid     0.23
_exptl_crystal_size_min     0.15
_exptl_crystal_density_diffrn     1.727
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1944
_exptl_absorpt_coefficient_mu     4.495
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(APEX2; Bruker, 2005)'
_exptl_absorpt_correction_T_min     0.379
_exptl_absorpt_correction_T_max     0.508
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     296(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     33785
_diffrn_reflns_av_R_equivalents     0.0241
_diffrn_reflns_av_sigmaI/netI     0.0231
_diffrn_reflns_theta_min     0.93
_diffrn_reflns_theta_max     27.51
_diffrn_reflns_theta_full     27.51
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -31
_diffrn_reflns_limit_h_max     27
_diffrn_reflns_limit_k_min     -9
_diffrn_reflns_limit_k_max     8
_diffrn_reflns_limit_l_min     -30
_diffrn_reflns_limit_l_max     30
_diffrn_standards_number     0
_diffrn_standards_interval_count     .
_diffrn_standards_interval_time     .
_diffrn_standards_decay_%     ?
_reflns_number_total     8724
_reflns_number_gt     7545
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0304
_refine_ls_R_factor_gt     0.0226
_refine_ls_wR_factor_gt     0.0496
_refine_ls_wR_factor_ref     0.0536
_refine_ls_goodness_of_fit_ref     1.026
_refine_ls_restrained_S_all     1.056
_refine_ls_number_reflns     8724
_refine_ls_number_parameters     419
_refine_ls_number_restraints     14
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.0246P)²+1.8915P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.004
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.623
_refine_diff_density_min     -0.438
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 1997)'
_refine_ls_extinction_coef     0.00015(3)
_refine_ls_extinction_expression
                                  'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2005)'
_computing_cell_refinement     'APEX2 (Bruker, 2005)'
_computing_data_reduction     'APEX2 (Bruker, 2005)'
_computing_structure_solution     'SIR97 (Altomare et al.,  1999)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'SHELXTL (Bruker, 1997)'
_computing_publication_material     'WinGX (Farrugia, 1999)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au1 0.743045(4) 0.072091(14) 0.744125(4) 0.03323(4) Uani d . 1 . .
    C C1 0.61106(18) 0.5443(5) 0.54607(16) 0.0647(10) Uani d . 1 . .
    C C2 0.67440(12) 0.3955(4) 0.65743(13) 0.0381(6) Uani d . 1 . .
    C C3 0.67318(12) 0.2724(4) 0.61440(12) 0.0408(6) Uani d . 1 . .
    C C4 0.81844(13) -0.1314(4) 0.87232(13) 0.0436(7) Uani d . 1 . .
    C C5 0.81351(13) -0.2546(4) 0.82822(13) 0.0420(7) Uani d . 1 . .
    C C6 0.8809(2) -0.4073(5) 0.93658(17) 0.0773(13) Uani d . 1 . .
    C C7 0.50051(12) 0.1656(4) 0.68865(12) 0.0371(6) Uani d . 1 . .
    C C8 0.45587(15) 0.0332(4) 0.66528(15) 0.0501(8) Uani d . 1 . .
    H H8 0.4262 0.0264 0.6802 0.060 Uiso calc R 1 . .
    C C9 0.45560(16) -0.0872(4) 0.62025(15) 0.0557(8) Uani d . 1 . .
    H H9 0.4256 -0.1749 0.6046 0.067 Uiso calc R 1 . .
    C C10 0.49958(16) -0.0784(4) 0.59830(15) 0.0531(8) Uani d . 1 . .
    H H10 0.4991 -0.1597 0.5676 0.064 Uiso calc R 1 . .
    C C11 0.54409(15) 0.0500(5) 0.62151(16) 0.0545(8) Uani d . 1 . .
    H H11 0.5740 0.0545 0.6068 0.065 Uiso calc R 1 . .
    C C12 0.54496(13) 0.1734(4) 0.66678(14) 0.0453(7) Uani d . 1 . .
    H H12 0.5752 0.2606 0.6823 0.054 Uiso calc R 1 . .
    C C13 0.56529(12) 0.4570(4) 0.78121(13) 0.0377(6) Uani d . 1 . .
    C C14 0.60901(14) 0.4460(4) 0.84412(14) 0.0519(8) Uani d . 1 . .
    H H14 0.6069 0.3566 0.8711 0.062 Uiso calc R 1 . .
    C C15 0.65604(16) 0.5705(5) 0.86636(17) 0.0647(10) Uani d . 1 . .
    H H15 0.6853 0.5649 0.9087 0.078 Uiso calc R 1 . .
    C C16 0.65990(15) 0.7007(5) 0.82693(17) 0.0580(9) Uani d . 1 . .
    H H16 0.6921 0.7818 0.8423 0.070 Uiso calc R 1 . .
    C C17 0.61632(14) 0.7126(4) 0.76451(16) 0.0513(8) Uani d . 1 . .
    H H17 0.6190 0.8020 0.7378 0.062 Uiso calc R 1 . .
    C C18 0.56901(14) 0.5928(4) 0.74156(14) 0.0457(7) Uani d . 1 . .
    H H18 0.5394 0.6020 0.6995 0.055 Uiso calc R 1 . .
    C C19 0.93779(12) 0.5504(4) 0.70427(13) 0.0393(6) Uani d . 1 . .
    C C20 0.88291(14) 0.5617(5) 0.70767(17) 0.0561(9) Uani d . 1 . .
    H H20 0.8765 0.6514 0.7320 0.067 Uiso calc R 1 . .
    C C21 0.83756(17) 0.4391(6) 0.6748(2) 0.0745(12) Uani d . 1 . .
    H H21 0.8006 0.4461 0.6772 0.089 Uiso calc R 1 . .
    C C22 0.84676(17) 0.3076(5) 0.63892(18) 0.0700(11) Uani d . 1 . .
    H H22 0.8160 0.2254 0.6171 0.084 Uiso calc R 1 . .
    C C23 0.90077(16) 0.2956(5) 0.63477(16) 0.0587(9) Uani d . 1 . .
    H H23 0.9065 0.2067 0.6097 0.070 Uiso calc R 1 . .
    C C24 0.94674(15) 0.4154(4) 0.66771(15) 0.0510(8) Uani d . 1 . .
    H H24 0.9838 0.4062 0.6656 0.061 Uiso calc R 1 . .
    C C25 0.98150(12) 0.8390(4) 0.80145(12) 0.0384(6) Uani d . 1 . .
    C C26 0.93880(14) 0.9737(4) 0.77422(15) 0.0513(8) Uani d . 1 . .
    H H26 0.9198 0.9876 0.7299 0.062 Uiso calc R 1 . .
    C C27 0.92444(16) 1.0866(5) 0.81239(18) 0.0595(9) Uani d . 1 . .
    H H27 0.8955 1.1762 0.7938 0.071 Uiso calc R 1 . .
    C C28 0.95230(19) 1.0684(5) 0.87763(19) 0.0657(10) Uani d . 1 . .
    H H28 0.9421 1.1448 0.9032 0.079 Uiso calc R 1 . .
    C C29 0.9952(2) 0.9371(6) 0.90531(18) 0.0738(12) Uani d . 1 . .
    H H29 1.0145 0.9256 0.9497 0.089 Uiso calc R 1 . .
    C C30 1.00990(16) 0.8216(5) 0.86709(15) 0.0572(9) Uani d . 1 . .
    H H30 1.0389 0.7325 0.8859 0.069 Uiso calc R 1 . .
    P P1 0.5000 0.31188(14) 0.7500 0.0353(2) Uani d S 1 . .
    P P2 1.0000 0.69624(14) 0.7500 0.0360(2) Uani d S 1 . .
    S S1 0.56884(7) 0.6801(2) 0.48764(5) 0.1163(6) Uani d U 1 . .
    S S2 0.63706(4) 0.59766(11) 0.62603(4) 0.0564(2) Uani d . 1 . .
    S S3 0.63422(4) 0.33387(14) 0.53405(4) 0.0623(2) Uani d . 1 . .
    S S4 0.70838(4) 0.36335(10) 0.74012(3) 0.04252(17) Uani d . 1 . .
    S S5 0.70504(4) 0.05928(10) 0.63341(3) 0.04545(17) Uani d . 1 . .
    S S6 0.78624(4) 0.08266(10) 0.85538(3) 0.04876(19) Uani d . 1 . .
    S S7 0.77268(4) -0.22242(10) 0.74579(3) 0.04580(17) Uani d . 1 . .
    S S8 0.86143(5) -0.19546(14) 0.95187(4) 0.0709(3) Uani d . 1 . .
    S S9 0.84996(5) -0.45844(12) 0.85599(4) 0.0633(3) Uani d . 1 . .
    S S10 0.92384(9) -0.5475(2) 0.99244(6) 0.1455(8) Uani d U 1 . .
    O O1 0.8261(3) 0.0873(8) 1.0601(4) 0.218(3) Uani d . 1 . .
    C C31 0.7672(6) 0.3303(12) 1.0190(5) 0.369(11) Uani d D 1 . .
    H H31A 0.7706 0.3740 1.0594 0.553 Uiso calc R 1 . .
    H H31B 0.7271 0.3549 0.9862 0.553 Uiso calc R 1 . .
    H H31C 0.7968 0.3892 1.0086 0.553 Uiso calc R 1 . .
    C C32 0.7782(4) 0.1340(11) 1.0232(3) 0.160(4) Uani d D 1 . .
    C C33 0.7244(4) 0.0304(16) 0.9827(4) 0.274(8) Uani d D 1 . .
    H H33A 0.7335 -0.0954 0.9892 0.410 Uiso calc R 1 . .
    H H33B 0.7126 0.0599 0.9385 0.410 Uiso calc R 1 . .
    H H33C 0.6917 0.0586 0.9936 0.410 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au1 S7 . 2.3057(8) y
    Au1 S4 . 2.3166(7) y
    Au1 S5 . 2.3191(7) y
    Au1 S6 . 2.3233(7) y
    C1 S1 . 1.645(3) y
    C1 S2 . 1.723(4) y
    C1 S3 . 1.730(4) y
    C2 C3 . 1.345(4) y
    C2 S4 . 1.742(3) y
    C2 S2 . 1.747(3) y
    C3 S5 . 1.739(3) y
    C3 S3 . 1.743(3) y
    C4 C5 . 1.340(4) y
    C4 S8 . 1.745(3) y
    C4 S6 . 1.746(3) y
    C5 S9 . 1.736(3) y
    C5 S7 . 1.744(3) y
    C6 S10 . 1.639(4) y
    C6 S9 . 1.725(4) y
    C6 S8 . 1.729(4) y
    C7 C12 . 1.384(4) ?
    C7 C8 . 1.393(4) ?
    C7 P1 . 1.795(3) ?
    C8 C9 . 1.374(4) ?
    C8 H8 . 0.9300 ?
    C9 C10 . 1.375(5) ?
    C9 H9 . 0.9300 ?
    C10 C11 . 1.370(5) ?
    C10 H10 . 0.9300 ?
    C11 C12 . 1.388(4) ?
    C11 H11 . 0.9300 ?
    C12 H12 . 0.9300 ?
    C13 C14 . 1.385(4) ?
    C13 C18 . 1.396(4) ?
    C13 P1 . 1.797(3) ?
    C14 C15 . 1.389(4) ?
    C14 H14 . 0.9300 ?
    C15 C16 . 1.364(5) ?
    C15 H15 . 0.9300 ?
    C16 C17 . 1.376(5) ?
    C16 H16 . 0.9300 ?
    C17 C18 . 1.371(4) ?
    C17 H17 . 0.9300 ?
    C18 H18 . 0.9300 ?
    C19 C20 . 1.379(4) ?
    C19 C24 . 1.392(4) ?
    C19 P2 . 1.792(3) ?
    C20 C21 . 1.381(5) ?
    C20 H20 . 0.9300 ?
    C21 C22 . 1.366(5) ?
    C21 H21 . 0.9300 ?
    C22 C23 . 1.366(5) ?
    C22 H22 . 0.9300 ?
    C23 C24 . 1.376(4) ?
    C23 H23 . 0.9300 ?
    C24 H24 . 0.9300 ?
    C25 C30 . 1.376(4) ?
    C25 C26 . 1.386(4) ?
    C25 P2 . 1.796(3) ?
    C26 C27 . 1.372(4) ?
    C26 H26 . 0.9300 ?
    C27 C28 . 1.368(5) ?
    C27 H27 . 0.9300 ?
    C28 C29 . 1.372(5) ?
    C28 H28 . 0.9300 ?
    C29 C30 . 1.389(5) ?
    C29 H29 . 0.9300 ?
    C30 H30 . 0.9300 ?
    P1 C7 2_656 1.795(3) ?
    P1 C13 2_656 1.797(3) ?
    P2 C19 2_756 1.792(3) ?
    P2 C25 2_756 1.796(3) ?
    O1 C32 . 1.162(8) ?
    C31 C32 . 1.483(8) ?
    C31 H31A . 0.9600 ?
    C31 H31B . 0.9600 ?
    C31 H31C . 0.9600 ?
    C32 C33 . 1.460(8) ?
    C33 H33A . 0.9600 ?
    C33 H33B . 0.9600 ?
    C33 H33C . 0.9600 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    S7 Au1 S4 . . 177.20(3) y
    S7 Au1 S5 . . 87.20(3) y
    S4 Au1 S5 . . 91.76(3) y
    S7 Au1 S6 . . 91.48(3) y
    S4 Au1 S6 . . 89.68(3) y
    S5 Au1 S6 . . 176.97(3) y
    S1 C1 S2 . . 123.3(2) ?
    S1 C1 S3 . . 123.8(2) ?
    S2 C1 S3 . . 112.88(18) ?
    C3 C2 S4 . . 124.6(2) ?
    C3 C2 S2 . . 116.1(2) ?
    S4 C2 S2 . . 119.30(16) ?
    C2 C3 S5 . . 124.9(2) ?
    C2 C3 S3 . . 116.0(2) ?
    S5 C3 S3 . . 119.13(17) ?
    C5 C4 S8 . . 115.5(2) ?
    C5 C4 S6 . . 124.9(2) ?
    S8 C4 S6 . . 119.53(18) ?
    C4 C5 S9 . . 117.1(2) ?
    C4 C5 S7 . . 124.0(2) ?
    S9 C5 S7 . . 118.88(17) ?
    S10 C6 S9 . . 122.9(2) ?
    S10 C6 S8 . . 124.0(2) ?
    S9 C6 S8 . . 113.16(19) ?
    C12 C7 C8 . . 119.5(3) ?
    C12 C7 P1 . . 122.7(2) ?
    C8 C7 P1 . . 117.6(2) ?
    C9 C8 C7 . . 120.1(3) ?
    C9 C8 H8 . . 119.9 ?
    C7 C8 H8 . . 119.9 ?
    C8 C9 C10 . . 120.2(3) ?
    C8 C9 H9 . . 119.9 ?
    C10 C9 H9 . . 119.9 ?
    C11 C10 C9 . . 120.1(3) ?
    C11 C10 H10 . . 119.9 ?
    C9 C10 H10 . . 119.9 ?
    C10 C11 C12 . . 120.5(3) ?
    C10 C11 H11 . . 119.7 ?
    C12 C11 H11 . . 119.7 ?
    C7 C12 C11 . . 119.5(3) ?
    C7 C12 H12 . . 120.3 ?
    C11 C12 H12 . . 120.3 ?
    C14 C13 C18 . . 119.6(3) ?
    C14 C13 P1 . . 122.1(2) ?
    C18 C13 P1 . . 118.1(2) ?
    C13 C14 C15 . . 119.1(3) ?
    C13 C14 H14 . . 120.5 ?
    C15 C14 H14 . . 120.5 ?
    C16 C15 C14 . . 120.9(3) ?
    C16 C15 H15 . . 119.6 ?
    C14 C15 H15 . . 119.6 ?
    C15 C16 C17 . . 120.2(3) ?
    C15 C16 H16 . . 119.9 ?
    C17 C16 H16 . . 119.9 ?
    C18 C17 C16 . . 120.1(3) ?
    C18 C17 H17 . . 119.9 ?
    C16 C17 H17 . . 119.9 ?
    C17 C18 C13 . . 120.1(3) ?
    C17 C18 H18 . . 119.9 ?
    C13 C18 H18 . . 119.9 ?
    C20 C19 C24 . . 119.5(3) ?
    C20 C19 P2 . . 121.6(2) ?
    C24 C19 P2 . . 118.7(2) ?
    C19 C20 C21 . . 119.7(3) ?
    C19 C20 H20 . . 120.2 ?
    C21 C20 H20 . . 120.2 ?
    C22 C21 C20 . . 120.3(3) ?
    C22 C21 H21 . . 119.8 ?
    C20 C21 H21 . . 119.8 ?
    C21 C22 C23 . . 120.6(3) ?
    C21 C22 H22 . . 119.7 ?
    C23 C22 H22 . . 119.7 ?
    C22 C23 C24 . . 119.9(3) ?
    C22 C23 H23 . . 120.1 ?
    C24 C23 H23 . . 120.1 ?
    C23 C24 C19 . . 120.0(3) ?
    C23 C24 H24 . . 120.0 ?
    C19 C24 H24 . . 120.0 ?
    C30 C25 C26 . . 119.3(3) ?
    C30 C25 P2 . . 121.8(2) ?
    C26 C25 P2 . . 118.9(2) ?
    C27 C26 C25 . . 120.2(3) ?
    C27 C26 H26 . . 119.9 ?
    C25 C26 H26 . . 119.9 ?
    C28 C27 C26 . . 120.5(3) ?
    C28 C27 H27 . . 119.8 ?
    C26 C27 H27 . . 119.8 ?
    C27 C28 C29 . . 119.9(3) ?
    C27 C28 H28 . . 120.0 ?
    C29 C28 H28 . . 120.0 ?
    C28 C29 C30 . . 120.0(3) ?
    C28 C29 H29 . . 120.0 ?
    C30 C29 H29 . . 120.0 ?
    C25 C30 C29 . . 120.0(3) ?
    C25 C30 H30 . . 120.0 ?
    C29 C30 H30 . . 120.0 ?
    C7 P1 C7 . 2_656 105.24(18) ?
    C7 P1 C13 . . 111.92(12) ?
    C7 P1 C13 2_656 . 110.91(12) ?
    C7 P1 C13 . 2_656 110.91(12) ?
    C7 P1 C13 2_656 2_656 111.92(12) ?
    C13 P1 C13 . 2_656 106.06(18) ?
    C19 P2 C19 . 2_756 105.36(19) ?
    C19 P2 C25 . . 110.98(13) ?
    C19 P2 C25 2_756 . 111.10(12) ?
    C19 P2 C25 . 2_756 111.10(12) ?
    C19 P2 C25 2_756 2_756 110.98(13) ?
    C25 P2 C25 . 2_756 107.36(19) ?
    C1 S2 C2 . . 97.48(15) ?
    C1 S3 C3 . . 97.53(15) ?
    C2 S4 Au1 . . 99.44(10) ?
    C3 S5 Au1 . . 99.35(9) ?
    C4 S6 Au1 . . 99.27(10) ?
    C5 S7 Au1 . . 100.09(10) ?
    C6 S8 C4 . . 97.25(16) ?
    C6 S9 C5 . . 96.93(16) ?
    C32 C31 H31A . . 109.5 ?
    C32 C31 H31B . . 109.5 ?
    H31A C31 H31B . . 109.5 ?
    C32 C31 H31C . . 109.5 ?
    H31A C31 H31C . . 109.5 ?
    H31B C31 H31C . . 109.5 ?
    O1 C32 C33 . . 130.7(9) ?
    O1 C32 C31 . . 116.1(10) ?
    C33 C32 C31 . . 113.1(9) ?
    C32 C33 H33A . . 109.5 ?
    C32 C33 H33B . . 109.5 ?
    H33A C33 H33B . . 109.5 ?
    C32 C33 H33C . . 109.5 ?
    H33A C33 H33C . . 109.5 ?
    H33B C33 H33C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    S4 C2 C3 S5 . . . . 0.2(4) ?
    S2 C2 C3 S5 . . . . -178.12(17) ?
    S4 C2 C3 S3 . . . . 178.02(16) ?
    S2 C2 C3 S3 . . . . -0.3(3) ?
    S8 C4 C5 S9 . . . . 0.1(4) ?
    S6 C4 C5 S9 . . . . 179.40(18) ?
    S8 C4 C5 S7 . . . . 179.68(17) ?
    S6 C4 C5 S7 . . . . -1.0(4) ?
    C12 C7 C8 C9 . . . . -0.8(5) ?
    P1 C7 C8 C9 . . . . -177.3(3) ?
    C7 C8 C9 C10 . . . . 0.4(5) ?
    C8 C9 C10 C11 . . . . 0.4(5) ?
    C9 C10 C11 C12 . . . . -0.7(5) ?
    C8 C7 C12 C11 . . . . 0.5(4) ?
    P1 C7 C12 C11 . . . . 176.8(2) ?
    C10 C11 C12 C7 . . . . 0.2(5) ?
    C18 C13 C14 C15 . . . . -0.4(5) ?
    P1 C13 C14 C15 . . . . -175.5(3) ?
    C13 C14 C15 C16 . . . . -0.8(5) ?
    C14 C15 C16 C17 . . . . 1.2(5) ?
    C15 C16 C17 C18 . . . . -0.4(5) ?
    C16 C17 C18 C13 . . . . -0.8(5) ?
    C14 C13 C18 C17 . . . . 1.2(4) ?
    P1 C13 C18 C17 . . . . 176.5(2) ?
    C24 C19 C20 C21 . . . . 0.0(5) ?
    P2 C19 C20 C21 . . . . -175.8(3) ?
    C19 C20 C21 C22 . . . . -0.3(6) ?
    C20 C21 C22 C23 . . . . -0.2(7) ?
    C21 C22 C23 C24 . . . . 0.9(6) ?
    C22 C23 C24 C19 . . . . -1.1(5) ?
    C20 C19 C24 C23 . . . . 0.7(5) ?
    P2 C19 C24 C23 . . . . 176.6(3) ?
    C30 C25 C26 C27 . . . . -1.0(5) ?
    P2 C25 C26 C27 . . . . -179.0(3) ?
    C25 C26 C27 C28 . . . . 0.4(5) ?
    C26 C27 C28 C29 . . . . 0.4(6) ?
    C27 C28 C29 C30 . . . . -0.7(6) ?
    C26 C25 C30 C29 . . . . 0.7(5) ?
    P2 C25 C30 C29 . . . . 178.6(3) ?
    C28 C29 C30 C25 . . . . 0.2(6) ?
    C12 C7 P1 C7 . . . 2_656 -123.6(3) ?
    C8 C7 P1 C7 . . . 2_656 52.7(2) ?
    C12 C7 P1 C13 . . . . -3.1(3) ?
    C8 C7 P1 C13 . . . . 173.3(2) ?
    C12 C7 P1 C13 . . . 2_656 115.2(2) ?
    C8 C7 P1 C13 . . . 2_656 -68.5(3) ?
    C14 C13 P1 C7 . . . . -115.0(3) ?
    C18 C13 P1 C7 . . . . 69.9(3) ?
    C14 C13 P1 C7 . . . 2_656 2.3(3) ?
    C18 C13 P1 C7 . . . 2_656 -172.9(2) ?
    C14 C13 P1 C13 . . . 2_656 124.0(3) ?
    C18 C13 P1 C13 . . . 2_656 -51.2(2) ?
    C20 C19 P2 C19 . . . 2_756 124.0(3) ?
    C24 C19 P2 C19 . . . 2_756 -51.8(2) ?
    C20 C19 P2 C25 . . . . 3.7(3) ?
    C24 C19 P2 C25 . . . . -172.2(2) ?
    C20 C19 P2 C25 . . . 2_756 -115.7(3) ?
    C24 C19 P2 C25 . . . 2_756 68.5(3) ?
    C30 C25 P2 C19 . . . . 112.1(3) ?
    C26 C25 P2 C19 . . . . -70.0(3) ?
    C30 C25 P2 C19 . . . 2_756 -4.8(3) ?
    C26 C25 P2 C19 . . . 2_756 173.1(2) ?
    C30 C25 P2 C25 . . . 2_756 -126.3(3) ?
    C26 C25 P2 C25 . . . 2_756 51.6(2) ?
    S1 C1 S2 C2 . . . . 178.1(3) ?
    S3 C1 S2 C2 . . . . -2.0(3) ?
    C3 C2 S2 C1 . . . . 1.4(3) ?
    S4 C2 S2 C1 . . . . -177.0(2) ?
    S1 C1 S3 C3 . . . . -178.2(3) ?
    S2 C1 S3 C3 . . . . 1.9(3) ?
    C2 C3 S3 C1 . . . . -1.0(3) ?
    S5 C3 S3 C1 . . . . 177.0(2) ?
    C3 C2 S4 Au1 . . . . -0.6(3) ?
    S2 C2 S4 Au1 . . . . 177.61(15) ?
    S5 Au1 S4 C2 . . . . 0.63(10) ?
    S6 Au1 S4 C2 . . . . 177.97(10) ?
    C2 C3 S5 Au1 . . . . 0.4(3) ?
    S3 C3 S5 Au1 . . . . -177.39(15) ?
    S7 Au1 S5 C3 . . . . 176.82(10) ?
    S4 Au1 S5 C3 . . . . -0.58(10) ?
    C5 C4 S6 Au1 . . . . -2.3(3) ?
    S8 C4 S6 Au1 . . . . 176.91(16) ?
    S7 Au1 S6 C4 . . . . 3.42(11) ?
    S4 Au1 S6 C4 . . . . -179.13(11) ?
    C4 C5 S7 Au1 . . . . 3.8(3) ?
    S9 C5 S7 Au1 . . . . -176.69(15) ?
    S5 Au1 S7 C5 . . . . 173.48(11) ?
    S6 Au1 S7 C5 . . . . -3.80(11) ?
    S10 C6 S8 C4 . . . . 179.1(3) ?
    S9 C6 S8 C4 . . . . -1.5(3) ?
    C5 C4 S8 C6 . . . . 0.8(3) ?
    S6 C4 S8 C6 . . . . -178.5(2) ?
    S10 C6 S9 C5 . . . . -179.1(3) ?
    S8 C6 S9 C5 . . . . 1.5(3) ?
    C4 C5 S9 C6 . . . . -1.0(3) ?
    S7 C5 S9 C6 . . . . 179.4(2) ?
data_II
_audit_creation_method     SHELXL97
_chemical_name_systematic
;
ethyltriphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C20 H20 P + , C6 Au S10 -'
_chemical_formula_sum     'C26 H20 Au P S10'
_chemical_formula_iupac     '(C20 H20 P) [Au (C3 S5)2]'
_chemical_formula_weight     880.96
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/n'
_symmetry_space_group_name_Hall     '-P 2yn'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     17.3058(2)
_cell_length_b     9.93060(10)
_cell_length_c     19.0668(2)
_cell_angle_alpha     90.00
_cell_angle_beta     103.9590(10)
_cell_angle_gamma     90.00
_cell_volume     3179.99(6)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     7323
_cell_measurement_theta_min     2.20
_cell_measurement_theta_max     25.12
_cell_measurement_temperature     296(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     brown
_exptl_crystal_size_max     0.24
_exptl_crystal_size_mid     0.17
_exptl_crystal_size_min     0.13
_exptl_crystal_density_diffrn     1.840
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1720
_exptl_absorpt_coefficient_mu     5.351
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(APEX2; Bruker, 2005)'
_exptl_absorpt_correction_T_min     0.3612
_exptl_absorpt_correction_T_max     0.5363
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     296(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker APEXII CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     22548
_diffrn_reflns_av_R_equivalents     0.0269
_diffrn_reflns_av_sigmaI/netI     0.0329
_diffrn_reflns_theta_min     1.43
_diffrn_reflns_theta_max     27.52
_diffrn_reflns_theta_full     27.52
_diffrn_measured_fraction_theta_max     0.998
_diffrn_measured_fraction_theta_full     0.998
_diffrn_reflns_limit_h_min     -22
_diffrn_reflns_limit_h_max     22
_diffrn_reflns_limit_k_min     -12
_diffrn_reflns_limit_k_max     12
_diffrn_reflns_limit_l_min     -24
_diffrn_reflns_limit_l_max     20
_diffrn_standards_number     0
_diffrn_standards_interval_count     .
_diffrn_standards_interval_time     .
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     7292
_reflns_number_gt     5381
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0484
_refine_ls_R_factor_gt     0.0270
_refine_ls_wR_factor_gt     0.0506
_refine_ls_wR_factor_ref     0.0565
_refine_ls_goodness_of_fit_ref     1.008
_refine_ls_restrained_S_all     1.008
_refine_ls_number_reflns     7292
_refine_ls_number_parameters     344
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.0231P)²+0.4583P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.004
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.803
_refine_diff_density_min     -0.272
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Au' 'Au' -2.0133 8.8022
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2005)'
_computing_cell_refinement     'APEX2 (Bruker, 2005)'
_computing_data_reduction     'APEX2 (Bruker, 2005)'
_computing_structure_solution     'SIR97 (Altomare et al.,  1999)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'SHELXTL (Bruker, 1997)'
_computing_publication_material     'WinGX (Farrugia, 1999)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Au Au1 0.516859(7) 0.169589(14) 0.569909(7) 0.05201(5) Uani d . 1 . .
    C C1 0.23676(19) 0.3873(4) 0.61700(18) 0.0583(9) Uani d . 1 . .
    C C2 0.35561(18) 0.2309(4) 0.60940(18) 0.0547(8) Uani d . 1 . .
    C C3 0.36701(18) 0.3427(3) 0.57426(18) 0.0515(8) Uani d . 1 . .
    C C4 0.66656(18) -0.0074(4) 0.57120(18) 0.0569(8) Uani d . 1 . .
    C C5 0.68057(18) 0.1036(4) 0.53625(17) 0.0541(8) Uani d . 1 . .
    C C6 0.80389(19) -0.0540(4) 0.54034(18) 0.0613(9) Uani d . 1 . .
    C C7 0.4048(2) 0.5503(4) 0.8277(2) 0.0688(10) Uani d . 1 . .
    H H7 0.3937 0.6375 0.8401 0.083 Uiso calc R 1 . .
    C C8 0.3622(3) 0.4440(5) 0.8459(2) 0.0871(13) Uani d . 1 . .
    H H8 0.3221 0.4599 0.8697 0.104 Uiso calc R 1 . .
    C C9 0.3786(3) 0.3175(5) 0.8290(3) 0.0901(14) Uani d . 1 . .
    H H9 0.3502 0.2461 0.8421 0.108 Uiso calc R 1 . .
    C C10 0.4361(3) 0.2923(4) 0.7932(3) 0.0865(13) Uani d . 1 . .
    H H10 0.4466 0.2041 0.7819 0.104 Uiso calc R 1 . .
    C C11 0.4796(2) 0.3982(4) 0.7733(2) 0.0733(11) Uani d . 1 . .
    H H11 0.5185 0.3813 0.7483 0.088 Uiso calc R 1 . .
    C C12 0.46378(18) 0.5292(3) 0.79147(17) 0.0516(8) Uani d . 1 . .
    C C13 0.6044(2) 0.5624(5) 0.6776(2) 0.0933(15) Uani d . 1 . .
    H H13 0.5569 0.5377 0.6457 0.112 Uiso calc R 1 . .
    C C14 0.6763(3) 0.5319(5) 0.6614(3) 0.1048(16) Uani d . 1 . .
    H H14 0.6767 0.4853 0.6192 0.126 Uiso calc R 1 . .
    C C15 0.7455(3) 0.5691(5) 0.7062(3) 0.0973(16) Uani d . 1 . .
    H H15 0.7934 0.5466 0.6953 0.117 Uiso calc R 1 . .
    C C16 0.7458(2) 0.6404(5) 0.7686(2) 0.0889(14) Uani d . 1 . .
    H H16 0.7937 0.6687 0.7986 0.107 Uiso calc R 1 . .
    C C17 0.6746(2) 0.6695(4) 0.7859(2) 0.0690(11) Uani d . 1 . .
    H H17 0.6745 0.7163 0.8281 0.083 Uiso calc R 1 . .
    C C18 0.60295(19) 0.6286(4) 0.74024(19) 0.0594(9) Uani d . 1 . .
    C C19 0.54222(19) 0.9288(4) 0.8148(2) 0.0635(10) Uani d . 1 . .
    H H19 0.5340 0.9546 0.7667 0.076 Uiso calc R 1 . .
    C C20 0.5651(2) 1.0231(4) 0.8687(3) 0.0740(11) Uani d . 1 . .
    H H20 0.5731 1.1121 0.8571 0.089 Uiso calc R 1 . .
    C C21 0.5759(2) 0.9858(5) 0.9391(3) 0.0785(12) Uani d . 1 . .
    H H21 0.5910 1.0500 0.9753 0.094 Uiso calc R 1 . .
    C C22 0.5650(2) 0.8558(5) 0.9574(2) 0.0789(12) Uani d . 1 . .
    H H22 0.5721 0.8317 1.0057 0.095 Uiso calc R 1 . .
    C C23 0.5431(2) 0.7593(4) 0.9034(2) 0.0638(9) Uani d . 1 . .
    H H23 0.5365 0.6701 0.9155 0.077 Uiso calc R 1 . .
    C C24 0.53134(17) 0.7957(3) 0.83187(18) 0.0516(8) Uani d . 1 . .
    C C25 0.44500(18) 0.7354(4) 0.68109(17) 0.0571(9) Uani d . 1 . .
    H H25A 0.4691 0.8148 0.6657 0.068 Uiso calc R 1 . .
    H H25B 0.4404 0.6682 0.6434 0.068 Uiso calc R 1 . .
    C C26 0.36185(19) 0.7719(4) 0.6877(2) 0.0678(10) Uani d . 1 . .
    H H26A 0.3357 0.6927 0.6994 0.102 Uiso calc R 1 . .
    H H26B 0.3319 0.8082 0.6426 0.102 Uiso calc R 1 . .
    H H26C 0.3653 0.8378 0.7251 0.102 Uiso calc R 1 . .
    P P1 0.51085(5) 0.67177(9) 0.76198(5) 0.0494(2) Uani d . 1 . .
    S S1 0.15650(6) 0.45163(12) 0.63482(6) 0.0814(3) Uani d . 1 . .
    S S2 0.27188(5) 0.22832(10) 0.64467(5) 0.0638(2) Uani d . 1 . .
    S S3 0.29482(5) 0.46755(10) 0.56763(5) 0.0659(3) Uani d . 1 . .
    S S4 0.41871(5) 0.09184(10) 0.62318(6) 0.0659(3) Uani d . 1 . .
    S S5 0.44766(5) 0.36954(10) 0.53575(6) 0.0660(3) Uani d . 1 . .
    S S6 0.58309(5) -0.03155(10) 0.60555(5) 0.0669(3) Uani d . 1 . .
    S S7 0.61831(5) 0.24389(10) 0.51903(5) 0.0610(2) Uani d . 1 . .
    S S8 0.73882(6) -0.13432(11) 0.58270(6) 0.0723(3) Uani d . 1 . .
    S S9 0.76890(5) 0.10384(11) 0.50763(5) 0.0627(2) Uani d . 1 . .
    S S10 0.88848(6) -0.11736(13) 0.53239(7) 0.0858(3) Uani d . 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Au1 S4 . 2.3119(8) y
    Au1 S6 . 2.3215(10) y
    Au1 S7 . 2.3215(8) y
    Au1 S5 . 2.3291(10) y
    C1 S1 . 1.637(3) y
    C1 S3 . 1.728(3) y
    C1 S2 . 1.728(4) y
    C2 C3 . 1.336(5) y
    C2 S2 . 1.739(3) y
    C2 S4 . 1.740(4) y
    C3 S3 . 1.743(3) y
    C3 S5 . 1.747(3) y
    C4 C5 . 1.340(5) y
    C4 S6 . 1.741(3) y
    C4 S8 . 1.751(3) y
    C5 S9 . 1.743(3) y
    C5 S7 . 1.743(4) y
    C6 S10 . 1.634(3) y
    C6 S8 . 1.731(4) y
    C6 S9 . 1.741(4) y
    C7 C8 . 1.379(5) ?
    C7 C12 . 1.379(4) ?
    C7 H7 . 0.9300 ?
    C8 C9 . 1.344(6) ?
    C8 H8 . 0.9300 ?
    C9 C10 . 1.359(6) ?
    C9 H9 . 0.9300 ?
    C10 C11 . 1.398(6) ?
    C10 H10 . 0.9300 ?
    C11 C12 . 1.390(5) ?
    C11 H11 . 0.9300 ?
    C12 P1 . 1.791(3) ?
    C13 C18 . 1.369(5) ?
    C13 C14 . 1.386(5) ?
    C13 H13 . 0.9300 ?
    C14 C15 . 1.343(6) ?
    C14 H14 . 0.9300 ?
    C15 C16 . 1.383(6) ?
    C15 H15 . 0.9300 ?
    C16 C17 . 1.380(5) ?
    C16 H16 . 0.9300 ?
    C17 C18 . 1.393(5) ?
    C17 H17 . 0.9300 ?
    C18 P1 . 1.793(3) ?
    C19 C20 . 1.376(5) ?
    C19 C24 . 1.385(5) ?
    C19 H19 . 0.9300 ?
    C20 C21 . 1.362(6) ?
    C20 H20 . 0.9300 ?
    C21 C22 . 1.362(6) ?
    C21 H21 . 0.9300 ?
    C22 C23 . 1.391(5) ?
    C22 H22 . 0.9300 ?
    C23 C24 . 1.377(5) ?
    C23 H23 . 0.9300 ?
    C24 P1 . 1.785(3) ?
    C25 C26 . 1.518(4) ?
    C25 P1 . 1.797(3) ?
    C25 H25A . 0.9700 ?
    C25 H25B . 0.9700 ?
    C26 H26A . 0.9600 ?
    C26 H26B . 0.9600 ?
    C26 H26C . 0.9600 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    S4 Au1 S6 . . 86.97(3) y
    S4 Au1 S7 . . 178.22(3) y
    S6 Au1 S7 . . 91.49(3) y
    S4 Au1 S5 . . 91.43(3) y
    S6 Au1 S5 . . 178.40(3) y
    S7 Au1 S5 . . 90.11(3) y
    S1 C1 S3 . . 124.6(2) ?
    S1 C1 S2 . . 123.1(2) ?
    S3 C1 S2 . . 112.30(19) ?
    C3 C2 S2 . . 116.3(3) ?
    C3 C2 S4 . . 124.9(2) ?
    S2 C2 S4 . . 118.8(2) ?
    C2 C3 S3 . . 116.0(2) ?
    C2 C3 S5 . . 124.5(3) ?
    S3 C3 S5 . . 119.51(19) ?
    C5 C4 S6 . . 124.5(3) ?
    C5 C4 S8 . . 116.4(2) ?
    S6 C4 S8 . . 119.1(2) ?
    C4 C5 S9 . . 115.8(3) ?
    C4 C5 S7 . . 125.0(2) ?
    S9 C5 S7 . . 119.3(2) ?
    S10 C6 S8 . . 124.3(2) ?
    S10 C6 S9 . . 123.8(2) ?
    S8 C6 S9 . . 111.89(19) ?
    C8 C7 C12 . . 121.0(4) ?
    C8 C7 H7 . . 119.5 ?
    C12 C7 H7 . . 119.5 ?
    C9 C8 C7 . . 119.9(4) ?
    C9 C8 H8 . . 120.0 ?
    C7 C8 H8 . . 120.0 ?
    C8 C9 C10 . . 121.0(4) ?
    C8 C9 H9 . . 119.5 ?
    C10 C9 H9 . . 119.5 ?
    C9 C10 C11 . . 120.3(4) ?
    C9 C10 H10 . . 119.8 ?
    C11 C10 H10 . . 119.8 ?
    C12 C11 C10 . . 119.0(4) ?
    C12 C11 H11 . . 120.5 ?
    C10 C11 H11 . . 120.5 ?
    C7 C12 C11 . . 118.7(3) ?
    C7 C12 P1 . . 119.0(3) ?
    C11 C12 P1 . . 122.0(3) ?
    C18 C13 C14 . . 120.4(4) ?
    C18 C13 H13 . . 119.8 ?
    C14 C13 H13 . . 119.8 ?
    C15 C14 C13 . . 120.5(4) ?
    C15 C14 H14 . . 119.7 ?
    C13 C14 H14 . . 119.7 ?
    C14 C15 C16 . . 120.4(4) ?
    C14 C15 H15 . . 119.8 ?
    C16 C15 H15 . . 119.8 ?
    C17 C16 C15 . . 119.6(4) ?
    C17 C16 H16 . . 120.2 ?
    C15 C16 H16 . . 120.2 ?
    C16 C17 C18 . . 120.0(4) ?
    C16 C17 H17 . . 120.0 ?
    C18 C17 H17 . . 120.0 ?
    C13 C18 C17 . . 119.0(3) ?
    C13 C18 P1 . . 121.4(3) ?
    C17 C18 P1 . . 119.5(3) ?
    C20 C19 C24 . . 120.3(4) ?
    C20 C19 H19 . . 119.8 ?
    C24 C19 H19 . . 119.8 ?
    C21 C20 C19 . . 119.9(4) ?
    C21 C20 H20 . . 120.1 ?
    C19 C20 H20 . . 120.1 ?
    C22 C21 C20 . . 121.1(4) ?
    C22 C21 H21 . . 119.5 ?
    C20 C21 H21 . . 119.5 ?
    C21 C22 C23 . . 119.5(4) ?
    C21 C22 H22 . . 120.2 ?
    C23 C22 H22 . . 120.2 ?
    C24 C23 C22 . . 120.1(4) ?
    C24 C23 H23 . . 119.9 ?
    C22 C23 H23 . . 119.9 ?
    C23 C24 C19 . . 119.1(3) ?
    C23 C24 P1 . . 120.9(3) ?
    C19 C24 P1 . . 119.8(3) ?
    C26 C25 P1 . . 115.5(2) ?
    C26 C25 H25A . . 108.4 ?
    P1 C25 H25A . . 108.4 ?
    C26 C25 H25B . . 108.4 ?
    P1 C25 H25B . . 108.4 ?
    H25A C25 H25B . . 107.5 ?
    C25 C26 H26A . . 109.5 ?
    C25 C26 H26B . . 109.5 ?
    H26A C26 H26B . . 109.5 ?
    C25 C26 H26C . . 109.5 ?
    H26A C26 H26C . . 109.5 ?
    H26B C26 H26C . . 109.5 ?
    C24 P1 C12 . . 109.53(16) ?
    C24 P1 C18 . . 108.04(16) ?
    C12 P1 C18 . . 112.37(16) ?
    C24 P1 C25 . . 111.65(17) ?
    C12 P1 C25 . . 107.78(15) ?
    C18 P1 C25 . . 107.51(16) ?
    C1 S2 C2 . . 97.65(17) ?
    C1 S3 C3 . . 97.67(17) ?
    C2 S4 Au1 . . 99.75(11) ?
    C3 S5 Au1 . . 99.30(12) ?
    C4 S6 Au1 . . 99.63(13) ?
    C5 S7 Au1 . . 99.36(11) ?
    C6 S8 C4 . . 97.78(17) ?
    C6 S9 C5 . . 98.17(17) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    S2 C2 C3 S3 . . . . -1.3(4) ?
    S4 C2 C3 S3 . . . . 179.9(2) ?
    S2 C2 C3 S5 . . . . 178.82(19) ?
    S4 C2 C3 S5 . . . . 0.0(5) ?
    S6 C4 C5 S9 . . . . 179.55(19) ?
    S8 C4 C5 S9 . . . . 0.0(4) ?
    S6 C4 C5 S7 . . . . 0.2(5) ?
    S8 C4 C5 S7 . . . . -179.30(19) ?
    C12 C7 C8 C9 . . . . 0.9(7) ?
    C7 C8 C9 C10 . . . . -1.0(8) ?
    C8 C9 C10 C11 . . . . 0.1(7) ?
    C9 C10 C11 C12 . . . . 0.8(6) ?
    C8 C7 C12 C11 . . . . 0.1(6) ?
    C8 C7 C12 P1 . . . . 174.3(3) ?
    C10 C11 C12 C7 . . . . -0.9(5) ?
    C10 C11 C12 P1 . . . . -174.9(3) ?
    C18 C13 C14 C15 . . . . -1.3(8) ?
    C13 C14 C15 C16 . . . . -1.1(9) ?
    C14 C15 C16 C17 . . . . 2.2(8) ?
    C15 C16 C17 C18 . . . . -0.9(6) ?
    C14 C13 C18 C17 . . . . 2.5(7) ?
    C14 C13 C18 P1 . . . . 179.0(4) ?
    C16 C17 C18 C13 . . . . -1.4(6) ?
    C16 C17 C18 P1 . . . . -178.0(3) ?
    C24 C19 C20 C21 . . . . -1.0(5) ?
    C19 C20 C21 C22 . . . . 0.4(6) ?
    C20 C21 C22 C23 . . . . 0.6(6) ?
    C21 C22 C23 C24 . . . . -1.1(6) ?
    C22 C23 C24 C19 . . . . 0.6(5) ?
    C22 C23 C24 P1 . . . . 175.1(3) ?
    C20 C19 C24 C23 . . . . 0.5(5) ?
    C20 C19 C24 P1 . . . . -174.1(3) ?
    C23 C24 P1 C12 . . . . 27.1(3) ?
    C19 C24 P1 C12 . . . . -158.4(2) ?
    C23 C24 P1 C18 . . . . -95.6(3) ?
    C19 C24 P1 C18 . . . . 78.9(3) ?
    C23 C24 P1 C25 . . . . 146.4(3) ?
    C19 C24 P1 C25 . . . . -39.1(3) ?
    C7 C12 P1 C24 . . . . 43.0(3) ?
    C11 C12 P1 C24 . . . . -143.0(3) ?
    C7 C12 P1 C18 . . . . 163.1(3) ?
    C11 C12 P1 C18 . . . . -22.9(3) ?
    C7 C12 P1 C25 . . . . -78.7(3) ?
    C11 C12 P1 C25 . . . . 95.4(3) ?
    C13 C18 P1 C24 . . . . -163.6(4) ?
    C17 C18 P1 C24 . . . . 12.8(4) ?
    C13 C18 P1 C12 . . . . 75.4(4) ?
    C17 C18 P1 C12 . . . . -108.1(3) ?
    C13 C18 P1 C25 . . . . -43.0(4) ?
    C17 C18 P1 C25 . . . . 133.4(3) ?
    C26 C25 P1 C24 . . . . -64.3(3) ?
    C26 C25 P1 C12 . . . . 56.0(3) ?
    C26 C25 P1 C18 . . . . 177.3(3) ?
    S1 C1 S2 C2 . . . . -179.0(2) ?
    S3 C1 S2 C2 . . . . 2.1(2) ?
    C3 C2 S2 C1 . . . . -0.5(3) ?
    S4 C2 S2 C1 . . . . 178.4(2) ?
    S1 C1 S3 C3 . . . . 178.4(2) ?
    S2 C1 S3 C3 . . . . -2.7(2) ?
    C2 C3 S3 C1 . . . . 2.4(3) ?
    S5 C3 S3 C1 . . . . -177.7(2) ?
    C3 C2 S4 Au1 . . . . 2.2(3) ?
    S2 C2 S4 Au1 . . . . -176.63(17) ?
    S6 Au1 S4 C2 . . . . 177.37(12) ?
    S5 Au1 S4 C2 . . . . -2.56(12) ?
    C2 C3 S5 Au1 . . . . -2.1(3) ?
    S3 C3 S5 Au1 . . . . 177.98(17) ?
    S4 Au1 S5 C3 . . . . 2.54(12) ?
    S7 Au1 S5 C3 . . . . -176.55(12) ?
    C5 C4 S6 Au1 . . . . 1.0(3) ?
    S8 C4 S6 Au1 . . . . -179.47(17) ?
    S4 Au1 S6 C4 . . . . 179.56(12) ?
    S7 Au1 S6 C4 . . . . -1.35(12) ?
    C4 C5 S7 Au1 . . . . -1.3(3) ?
    S9 C5 S7 Au1 . . . . 179.37(17) ?
    S6 Au1 S7 C5 . . . . 1.41(12) ?
    S5 Au1 S7 C5 . . . . -178.68(12) ?
    S10 C6 S8 C4 . . . . 179.0(2) ?
    S9 C6 S8 C4 . . . . -0.6(2) ?
    C5 C4 S8 C6 . . . . 0.3(3) ?
    S6 C4 S8 C6 . . . . -179.2(2) ?
    S10 C6 S9 C5 . . . . -178.9(2) ?
    S8 C6 S9 C5 . . . . 0.6(2) ?
    C4 C5 S9 C6 . . . . -0.4(3) ?
    S7 C5 S9 C6 . . . . 179.0(2) ?
data_global
_journal_date_recd_electronic     2007-09-21
_journal_date_accepted     2007-11-19
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2008
_journal_volume     64
_journal_issue      1
_journal_page_first     m46
_journal_page_last     m49
_journal_paper_category     FM
_journal_coeditor_code     SK3168
_publ_contact_author_name     'Dr Xin-Qiang Wang'
_publ_contact_author_address
;
State Key Laboratory of Crystal Materials
Institute of Crystal Materials
Shandong University
Jinan 250100
People's Republic of China
;
_publ_contact_author_email     xqwang@sdu.edu.cn
_publ_contact_author_fax     ' '
_publ_contact_author_phone     '086 0531 88364986'
_publ_section_title
;
Tetraphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III)
acetone solvate and ethyltriphenylphosphonium
bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III)
;
loop_
    _publ_author_name
    _publ_author_address
    'Wang, Xin-Qiang'
;
State Key Laboratory of Crystal Materials
Institute of Crystal Materials
Shandong University
Jinan 250100
People's Republic of China
;
    'Yu, Wen-Tao'
;
State Key Laboratory of Crystal Materials
Institute of Crystal Materials
Shandong University
Jinan 250100
People's Republic of China
;
    'Xu, Dong'
;
State Key Laboratory of Crystal Materials
Institute of Crystal Materials
Shandong University
Jinan 250100
People's Republic of China
;
    'Fan, Jian-Dong'
;
State Key Laboratory of Crystal Materials
Institute of Crystal Materials
Shandong University
Jinan 250100
People's Republic of China
;
    'Zhang, Guang-Hui'
;
State Key Laboratory of Crystal Materials
Institute of Crystal Materials
Shandong University
Jinan 250100
People's Republic of China
;
    'Ren, Quan'
;
Department of Optics
School of Information Science and Engineering
Shandong University
Jinan 250100
People's Republic of China
;
