##############################################################################
###                                                                        ###
###           Full Paper (Acta Crystallographica Section C)                ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section C. It conforms to the editorial and technical    #
# requirements of Notes for Authors for Section C, and has been peer         #
# reviewed under the auspices of the IUCr Commission on Journals.            #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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data_global
_audit_creation_method     'SHELXL97'
_journal_date_recd_electronic     2007-02-05
_journal_date_accepted     2007-05-07
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2007
_journal_volume     63
_journal_issue      7
_journal_page_first     m323
_journal_page_last     m326
_journal_paper_category     FM
_journal_coeditor_code     GA3042
_publ_contact_author_name     'Dr Alan S. Goldman'
_publ_contact_author_address
;
Department of Chemistry and Chemical Biology
Rutgers State University of New Jersey
610 Taylor Road
Piscataway
NJ 08854
USA
;
_publ_contact_author_email     alan.goldman@rutgers.edu
_publ_contact_author_fax     '732-445-5312'
_publ_contact_author_phone     '732-445-5232'
_publ_section_title
;
A mixed-valence chloride-bridged (pincer)IrIII--(diene)IrI complex
;
loop_
    _publ_author_name
    _publ_author_address
    'Pelczar, Elizabeth M.'
;
Department of Chemistry and Chemical Biology
Rutgers, The State University of New Jersey
610 Taylor Road
Piscataway
NJ 08854
USA
;
    'Emge, Thomas J.'
;
Department of Chemistry and Chemical Biology
Rutgers, The State University of New Jersey
610 Taylor Road
Piscataway
NJ 08854
USA
;
    'Goldman, Alan S.'
;
Department of Chemistry and Chemical Biology
Rutgers, The State University of New Jersey
610 Taylor Road
Piscataway
NJ 08854
USA
;
data_I
_chemical_name_systematic
;
[2,6-bis(di-tert-butylphosphino)phenyl-1κ³P,C¹,P']di-μ-chlorido-
1:2κ⁴Cl:Cl-(2η⁴-cycloocta-2,5-diene)diiridium(I,III) hexane hemisolvate
;
_chemical_name_common
;
κ³-(tBuPCPIrH)-(μ₂Cl)₂-η⁴-Ir(COD)
;
_chemical_formula_moiety     'C32 H56 Cl2 Ir2 P2 , 0.5C6 H14'
_chemical_formula_sum     'C35 H63 Cl2 Ir2 P2'
_chemical_formula_iupac     '[Ir2 (C8 H12) (C24 H44 P2) Cl2] , 0.5C6 H14'
_chemical_formula_weight     1001.09
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/c'
_symmetry_space_group_name_Hall     '-P 2ybc'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     14.8424(7)
_cell_length_b     11.6735(5)
_cell_length_c     22.0589(10)
_cell_angle_alpha     90.00
_cell_angle_beta     99.4160(10)
_cell_angle_gamma     90.00
_cell_volume     3770.5(3)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     8331
_cell_measurement_theta_min     2.56
_cell_measurement_theta_max     30.58
_cell_measurement_temperature     100(2)
_exptl_crystal_description     lath
_exptl_crystal_colour     orange
_exptl_crystal_size_max     0.19
_exptl_crystal_size_mid     0.12
_exptl_crystal_size_min     0.08
_exptl_crystal_density_diffrn     1.764
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1964
_exptl_absorpt_coefficient_mu     7.301
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS in SAINT-Plus; Bruker, 2003)'
_exptl_absorpt_correction_T_min     0.361
_exptl_absorpt_correction_T_max     0.558
_exptl_special_details
;
All solvents were purchased as anhydrous from Aldrich and degassed before use.
NMR spectra were recorded on a Varian 400-MHz NMR spectrometer; ¹H NMR
signals are referenced to the residual proton peaks of the deuterated solvent
and ³¹P{¹H} NMR signals are referenced to PMe₃ dissolved in
p-xylene-d₁₀, in a capillary.
³¹P{¹H} (400 MHz, toluene-d₈, δ, p.p.m.): 54.89 (d, J = 13 Hz);
¹H (400 MHz, toluene-d₈, δ, p.p.m.): 3.95 (d, J = 17 Hz, 4H, COD),
3.29 (dt, JH---H = 17 Hz, JP---H = 3 Hz, 2H, CH₂), 2.86 (dt, JH---H =
15 Hz, JP---H = 4 Hz, 2H, CH₂), 1.73 (t, J = 6 Hz, 18H, tBu),
1.22 (t, J = 6 Hz, 18H, tBu), -25.73 (t, J = 16 Hz, 1H, Ir---H).
;
_diffrn_ambient_temperature     100(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART CCD area-detector'
_diffrn_measurement_method     'φ and ω'
_diffrn_reflns_number     42778
_diffrn_reflns_av_R_equivalents     0.0332
_diffrn_reflns_av_sigmaI/netI     0.0316
_diffrn_reflns_theta_min     1.87
_diffrn_reflns_theta_max     30.61
_diffrn_reflns_theta_full     30.61
_diffrn_measured_fraction_theta_max     0.990
_diffrn_measured_fraction_theta_full     0.990
_diffrn_reflns_limit_h_min     -21
_diffrn_reflns_limit_h_max     21
_diffrn_reflns_limit_k_min     -16
_diffrn_reflns_limit_k_max     16
_diffrn_reflns_limit_l_min     -31
_diffrn_reflns_limit_l_max     31
_diffrn_standards_number     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     11498
_reflns_number_gt     10259
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0317
_refine_ls_R_factor_gt     0.0263
_refine_ls_wR_factor_gt     0.0603
_refine_ls_wR_factor_ref     0.0622
_refine_ls_goodness_of_fit_ref     1.003
_refine_ls_restrained_S_all     1.003
_refine_ls_number_reflns     11498
_refine_ls_number_parameters     383
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
            'calc w = 1/[σ²(Fo²)+(0.03P)²+7.5P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.003
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     2.040
_refine_diff_density_min     -1.027
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ir' 'Ir' -1.4442 7.9887
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 2005)'
_computing_cell_refinement     'SMART'
_computing_data_reduction     'SAINT-Plus (Bruker,2003)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'SHELXTL (Bruker, 2003)'
_computing_publication_material     'SHELXTL'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ir Ir1 0.680138(8) 0.126447(9) 0.159875(5) 0.00922(3) Uani d . 1 . .
    H H1 0.6890 0.0307 0.1101 0.020 Uiso d . 1 . .
    Ir Ir2 0.838754(8) 0.322798(10) 0.254009(6) 0.01107(3) Uani d . 1 . .
    P P1 0.66778(5) 0.23654(7) 0.07101(4) 0.01129(14) Uani d . 1 . .
    P P2 0.65536(5) -0.02464(7) 0.22407(4) 0.01062(14) Uani d . 1 . .
    Cl Cl1 0.84815(5) 0.15376(6) 0.19479(4) 0.01398(14) Uani d . 1 . .
    Cl Cl2 0.67694(5) 0.28732(6) 0.24043(3) 0.01297(13) Uani d . 1 . .
    C C1 0.5440(2) 0.1114(3) 0.13518(15) 0.0125(6) Uani d . 1 . .
    C C2 0.4993(2) 0.1449(3) 0.07595(15) 0.0132(6) Uani d . 1 . .
    C C3 0.4046(2) 0.1378(3) 0.06018(15) 0.0163(6) Uani d . 1 . .
    H H3 0.3756 0.1640 0.0210 0.020 Uiso calc R 1 . .
    C C4 0.3521(2) 0.0926(3) 0.10132(16) 0.0168(6) Uani d . 1 . .
    H H4 0.2875 0.0896 0.0909 0.020 Uiso calc R 1 . .
    C C5 0.3954(2) 0.0518(3) 0.15791(15) 0.0150(6) Uani d . 1 . .
    H H5 0.3602 0.0178 0.1854 0.018 Uiso calc R 1 . .
    C C6 0.4896(2) 0.0604(3) 0.17462(15) 0.0133(6) Uani d . 1 . .
    C C7 0.5583(2) 0.1817(3) 0.02973(15) 0.0147(6) Uani d . 1 . .
    H H7A 0.5268 0.2422 0.0028 0.018 Uiso calc R 1 . .
    H H7B 0.5693 0.1157 0.0037 0.018 Uiso calc R 1 . .
    C C8 0.5373(2) 0.0084(3) 0.23435(15) 0.0140(6) Uani d . 1 . .
    H H8A 0.5055 -0.0623 0.2439 0.017 Uiso calc R 1 . .
    H H8B 0.5373 0.0632 0.2686 0.017 Uiso calc R 1 . .
    C C9 0.7517(2) 0.2027(3) 0.01761(15) 0.0152(6) Uani d . 1 . .
    C C10 0.7097(3) 0.2189(3) -0.05021(16) 0.0220(7) Uani d . 1 . .
    H H10A 0.7575 0.2114 -0.0758 0.033 Uiso calc R 1 . .
    H H10B 0.6820 0.2952 -0.0560 0.033 Uiso calc R 1 . .
    H H10C 0.6627 0.1605 -0.0621 0.033 Uiso calc R 1 . .
    C C11 0.8374(2) 0.2786(3) 0.03346(18) 0.0223(7) Uani d . 1 . .
    H H11A 0.8852 0.2506 0.0114 0.033 Uiso calc R 1 . .
    H H11B 0.8595 0.2755 0.0778 0.033 Uiso calc R 1 . .
    H H11C 0.8220 0.3579 0.0213 0.033 Uiso calc R 1 . .
    C C12 0.7828(2) 0.0779(3) 0.02649(16) 0.0194(7) Uani d . 1 . .
    H H12A 0.7294 0.0273 0.0187 0.029 Uiso calc R 1 . .
    H H12B 0.8142 0.0669 0.0687 0.029 Uiso calc R 1 . .
    H H12C 0.8245 0.0596 -0.0023 0.029 Uiso calc R 1 . .
    C C13 0.6481(2) 0.3965(3) 0.07266(15) 0.0155(6) Uani d . 1 . .
    C C14 0.6308(3) 0.4552(3) 0.00934(16) 0.0206(7) Uani d . 1 . .
    H H14A 0.6124 0.5349 0.0141 0.031 Uiso calc R 1 . .
    H H14B 0.5820 0.4146 -0.0176 0.031 Uiso calc R 1 . .
    H H14C 0.6868 0.4533 -0.0088 0.031 Uiso calc R 1 . .
    C C15 0.7286(2) 0.4570(3) 0.11265(16) 0.0185(7) Uani d . 1 . .
    H H15A 0.7104 0.5347 0.1223 0.028 Uiso calc R 1 . .
    H H15B 0.7804 0.4610 0.0903 0.028 Uiso calc R 1 . .
    H H15C 0.7465 0.4139 0.1509 0.028 Uiso calc R 1 . .
    C C16 0.5621(2) 0.4128(3) 0.10254(16) 0.0192(7) Uani d . 1 . .
    H H16A 0.5708 0.3747 0.1427 0.029 Uiso calc R 1 . .
    H H16B 0.5092 0.3793 0.0760 0.029 Uiso calc R 1 . .
    H H16C 0.5515 0.4948 0.1080 0.029 Uiso calc R 1 . .
    C C17 0.6489(2) -0.1668(3) 0.18208(15) 0.0150(6) Uani d . 1 . .
    C C18 0.6285(3) -0.2683(3) 0.22221(16) 0.0203(7) Uani d . 1 . .
    H H18A 0.6215 -0.3383 0.1974 0.030 Uiso calc R 1 . .
    H H18B 0.5719 -0.2533 0.2384 0.030 Uiso calc R 1 . .
    H H18C 0.6791 -0.2778 0.2565 0.030 Uiso calc R 1 . .
    C C19 0.7398(2) -0.1883(3) 0.15836(16) 0.0185(7) Uani d . 1 . .
    H H19A 0.7367 -0.2617 0.1366 0.028 Uiso calc R 1 . .
    H H19B 0.7901 -0.1903 0.1932 0.028 Uiso calc R 1 . .
    H H19C 0.7504 -0.1265 0.1303 0.028 Uiso calc R 1 . .
    C C20 0.5725(3) -0.1644(3) 0.12607(16) 0.0194(7) Uani d . 1 . .
    H H20A 0.5829 -0.1008 0.0991 0.029 Uiso calc R 1 . .
    H H20B 0.5135 -0.1541 0.1398 0.029 Uiso calc R 1 . .
    H H20C 0.5722 -0.2368 0.1035 0.029 Uiso calc R 1 . .
    C C21 0.7184(2) -0.0469(3) 0.30485(14) 0.0147(6) Uani d . 1 . .
    C C22 0.6597(3) -0.1087(3) 0.34640(16) 0.0191(7) Uani d . 1 . .
    H H22A 0.6953 -0.1182 0.3876 0.029 Uiso calc R 1 . .
    H H22B 0.6416 -0.1841 0.3290 0.029 Uiso calc R 1 . .
    H H22C 0.6051 -0.0631 0.3489 0.029 Uiso calc R 1 . .
    C C23 0.8089(2) -0.1112(3) 0.30518(17) 0.0205(7) Uani d . 1 . .
    H H23A 0.8430 -0.0753 0.2758 0.031 Uiso calc R 1 . .
    H H23B 0.7961 -0.1913 0.2935 0.031 Uiso calc R 1 . .
    H H23C 0.8452 -0.1080 0.3464 0.031 Uiso calc R 1 . .
    C C24 0.7421(2) 0.0709(3) 0.33318(15) 0.0190(7) Uani d . 1 . .
    H H24A 0.7695 0.0619 0.3764 0.029 Uiso calc R 1 . .
    H H24B 0.6865 0.1171 0.3303 0.029 Uiso calc R 1 . .
    H H24C 0.7856 0.1092 0.3110 0.029 Uiso calc R 1 . .
    C C25 0.9804(2) 0.3312(3) 0.28602(16) 0.0163(6) Uani d . 1 . .
    H H25 1.0085 0.2634 0.2809 0.020 Uiso d . 1 . .
    C C26 0.9592(2) 0.3831(3) 0.22771(16) 0.0156(6) Uani d . 1 . .
    H H26 0.9702 0.3361 0.1952 0.020 Uiso d . 1 . .
    C C27 0.9541(2) 0.5107(3) 0.21596(16) 0.0161(6) Uani d . 1 . .
    H H27A 0.9253 0.5246 0.1729 0.019 Uiso calc R 1 . .
    H H27B 1.0168 0.5424 0.2215 0.019 Uiso calc R 1 . .
    C C28 0.8996(2) 0.5730(3) 0.25895(17) 0.0182(6) Uani d . 1 . .
    H H28A 0.9413 0.5965 0.2966 0.022 Uiso calc R 1 . .
    H H28B 0.8721 0.6431 0.2385 0.022 Uiso calc R 1 . .
    C C29 0.8246(2) 0.4972(3) 0.27637(16) 0.0151(6) Uani d . 1 . .
    H H29 0.7639 0.5201 0.2588 0.020 Uiso d . 1 . .
    C C30 0.8350(2) 0.4293(3) 0.33026(16) 0.0160(6) Uani d . 1 . .
    H H30 0.7849 0.4100 0.3435 0.020 Uiso d . 1 . .
    C C31 0.9225(2) 0.4216(3) 0.37679(16) 0.0204(7) Uani d . 1 . .
    H H31A 0.9166 0.3591 0.4062 0.024 Uiso calc R 1 . .
    H H31B 0.9315 0.4942 0.4002 0.024 Uiso calc R 1 . .
    C C32 1.0064(2) 0.3990(3) 0.34575(16) 0.0186(7) Uani d . 1 . .
    H H32A 1.0341 0.4729 0.3367 0.022 Uiso calc R 1 . .
    H H32B 1.0525 0.3554 0.3742 0.022 Uiso calc R 1 . .
    C C33 0.9658(4) 0.5435(6) -0.0152(2) 0.071(2) Uani d . 1 . .
    H H33A 0.9108 0.5023 -0.0356 0.085 Uiso calc R 1 . .
    H H33B 0.9925 0.5838 -0.0475 0.085 Uiso calc R 1 . .
    C C34 0.9364(5) 0.6329(7) 0.0284(3) 0.080(3) Uani d . 1 . .
    H H34A 0.9917 0.6718 0.0501 0.096 Uiso calc R 1 . .
    H H34B 0.9072 0.5929 0.0597 0.096 Uiso calc R 1 . .
    C C35 0.8698(6) 0.7245(9) -0.0031(3) 0.105(3) Uani d . 1 . .
    H H35A 0.8974 0.7637 -0.0348 0.157 Uiso calc R 1 . .
    H H35B 0.8568 0.7802 0.0276 0.157 Uiso calc R 1 . .
    H H35C 0.8127 0.6876 -0.0221 0.157 Uiso calc R 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ir1 C1 . 2.012(3) y
    Ir1 P1 . 2.3260(10)
                      y
    Ir1 P2 . 2.3280(10)
                      y
    Ir1 Cl1 . 2.5070(10)
                       y
    Ir1 Cl2 . 2.5910(10)
                       y
    Ir1 H1 . 1.59 y
    Ir2 C26 . 2.090(3) y
    Ir2 C30 . 2.100(3) y
    Ir2 C25 . 2.108(3) y
    Ir2 C29 . 2.113(3) y
    Ir2 Cl1 . 2.3830(10)
                       y
    Ir2 Cl2 . 2.4070(10)
                       y
    P1 C7 . 1.843(3) ?
    P1 C9 . 1.891(3) ?
    P1 C13 . 1.891(3) ?
    P2 C8 . 1.845(3) ?
    P2 C21 . 1.891(3) ?
    P2 C17 . 1.896(3) ?
    C1 C6 . 1.412(4) ?
    C1 C2 . 1.420(4) ?
    C2 C3 . 1.394(5) ?
    C2 C7 . 1.511(4) ?
    C3 C4 . 1.393(5) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.391(5) ?
    C4 H4 . 0.9500 ?
    C5 C6 . 1.390(4) ?
    C5 H5 . 0.9500 ?
    C6 C8 . 1.516(4) ?
    C7 H7A . 0.9900 ?
    C7 H7B . 0.9900 ?
    C8 H8A . 0.9900 ?
    C8 H8B . 0.9900 ?
    C9 C12 . 1.531(5) ?
    C9 C10 . 1.536(5) ?
    C9 C11 . 1.542(5) ?
    C10 H10A . 0.9800 ?
    C10 H10B . 0.9800 ?
    C10 H10C . 0.9800 ?
    C11 H11A . 0.9800 ?
    C11 H11B . 0.9800 ?
    C11 H11C . 0.9800 ?
    C12 H12A . 0.9800 ?
    C12 H12B . 0.9800 ?
    C12 H12C . 0.9800 ?
    C13 C15 . 1.537(5) ?
    C13 C14 . 1.539(5) ?
    C13 C16 . 1.542(5) ?
    C14 H14A . 0.9800 ?
    C14 H14B . 0.9800 ?
    C14 H14C . 0.9800 ?
    C15 H15A . 0.9800 ?
    C15 H15B . 0.9800 ?
    C15 H15C . 0.9800 ?
    C16 H16A . 0.9800 ?
    C16 H16B . 0.9800 ?
    C16 H16C . 0.9800 ?
    C17 C20 . 1.535(5) ?
    C17 C18 . 1.538(5) ?
    C17 C19 . 1.546(5) ?
    C18 H18A . 0.9800 ?
    C18 H18B . 0.9800 ?
    C18 H18C . 0.9800 ?
    C19 H19A . 0.9800 ?
    C19 H19B . 0.9800 ?
    C19 H19C . 0.9800 ?
    C20 H20A . 0.9800 ?
    C20 H20B . 0.9800 ?
    C20 H20C . 0.9800 ?
    C21 C24 . 1.528(5) ?
    C21 C23 . 1.537(5) ?
    C21 C22 . 1.543(5) ?
    C22 H22A . 0.9800 ?
    C22 H22B . 0.9800 ?
    C22 H22C . 0.9800 ?
    C23 H23A . 0.9800 ?
    C23 H23B . 0.9800 ?
    C23 H23C . 0.9800 ?
    C24 H24A . 0.9800 ?
    C24 H24B . 0.9800 ?
    C24 H24C . 0.9800 ?
    C25 C26 . 1.410(5) ?
    C25 C32 . 1.531(5) ?
    C25 H25 . 0.910 ?
    C26 C27 . 1.512(5) ?
    C26 H26 . 0.938 ?
    C27 C28 . 1.528(5) ?
    C27 H27A . 0.9900 ?
    C27 H27B . 0.9900 ?
    C28 C29 . 1.520(4) ?
    C28 H28A . 0.9900 ?
    C28 H28B . 0.9900 ?
    C29 C30 . 1.416(5) ?
    C29 H29 . 0.959 ?
    C30 C31 . 1.520(5) ?
    C30 H30 . 0.871 ?
    C31 C32 . 1.540(5) ?
    C31 H31A . 0.9900 ?
    C31 H31B . 0.9900 ?
    C32 H32A . 0.9900 ?
    C32 H32B . 0.9900 ?
    C33 C33 3_765 1.514(14) ?
    C33 C34 . 1.529(11) ?
    C33 H33A . 0.9900 ?
    C33 H33B . 0.9900 ?
    C34 C35 . 1.543(12) ?
    C34 H34A . 0.9900 ?
    C34 H34B . 0.9900 ?
    C35 H35A . 0.9800 ?
    C35 H35B . 0.9800 ?
    C35 H35C . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C1 Ir1 P1 . . 83.27(9) y
    C1 Ir1 P2 . . 81.21(9) y
    P1 Ir1 P2 . . 158.83(3) y
    C1 Ir1 Cl1 . . 176.79(9) y
    P1 Ir1 Cl1 . . 97.23(3) y
    P2 Ir1 Cl1 . . 99.07(3) y
    C1 Ir1 Cl2 . . 96.80(9) y
    P1 Ir1 Cl2 . . 99.77(3) y
    P2 Ir1 Cl2 . . 96.29(3) y
    Cl1 Ir1 Cl2 . . 79.98(2) y
    C1 Ir1 H1 . . 87 y
    P1 Ir1 H1 . . 79 y
    P2 Ir1 H1 . . 86 y
    Cl1 Ir1 H1 . . 96 y
    Cl2 Ir1 H1 . . 176 y
    C26 Ir2 C30 . . 99.14(13) ?
    C26 Ir2 C25 . . 39.25(13) ?
    C30 Ir2 C25 . . 81.93(13) ?
    C26 Ir2 C29 . . 82.09(12) ?
    C30 Ir2 C29 . . 39.27(13) ?
    C25 Ir2 C29 . . 90.49(12) ?
    C26 Ir2 Cl1 . . 89.84(9) ?
    C30 Ir2 Cl1 . . 160.23(9) ?
    C25 Ir2 Cl1 . . 94.45(9) ?
    C29 Ir2 Cl1 . . 160.48(9) ?
    C26 Ir2 Cl2 . . 154.80(10) ?
    C30 Ir2 Cl2 . . 92.58(9) ?
    C25 Ir2 Cl2 . . 165.92(10) ?
    C29 Ir2 Cl2 . . 93.42(9) ?
    Cl1 Ir2 Cl2 . . 86.33(3) y
    C7 P1 C9 . . 103.74(15) ?
    C7 P1 C13 . . 103.07(15) ?
    C9 P1 C13 . . 109.73(15) ?
    C7 P1 Ir1 . . 99.55(10) ?
    C9 P1 Ir1 . . 116.13(11) ?
    C13 P1 Ir1 . . 121.36(11) ?
    C8 P2 C21 . . 104.29(14) ?
    C8 P2 C17 . . 105.67(15) ?
    C21 P2 C17 . . 108.52(15) ?
    C8 P2 Ir1 . . 99.45(10) ?
    C21 P2 Ir1 . . 125.06(11) ?
    C17 P2 Ir1 . . 111.51(10) ?
    Ir2 Cl1 Ir1 . . 97.43(3) ?
    Ir2 Cl2 Ir1 . . 94.60(2) ?
    C6 C1 C2 . . 117.0(3) ?
    C6 C1 Ir1 . . 121.3(2) ?
    C2 C1 Ir1 . . 121.5(2) ?
    C3 C2 C1 . . 120.9(3) ?
    C3 C2 C7 . . 121.4(3) ?
    C1 C2 C7 . . 117.6(3) ?
    C4 C3 C2 . . 120.6(3) ?
    C4 C3 H3 . . 119.7 ?
    C2 C3 H3 . . 119.7 ?
    C5 C4 C3 . . 119.3(3) ?
    C5 C4 H4 . . 120.4 ?
    C3 C4 H4 . . 120.4 ?
    C6 C5 C4 . . 120.7(3) ?
    C6 C5 H5 . . 119.7 ?
    C4 C5 H5 . . 119.7 ?
    C5 C6 C1 . . 121.2(3) ?
    C5 C6 C8 . . 120.5(3) ?
    C1 C6 C8 . . 118.1(3) ?
    C2 C7 P1 . . 109.1(2) ?
    C2 C7 H7A . . 109.9 ?
    P1 C7 H7A . . 109.9 ?
    C2 C7 H7B . . 109.9 ?
    P1 C7 H7B . . 109.9 ?
    H7A C7 H7B . . 108.3 ?
    C6 C8 P2 . . 107.1(2) ?
    C6 C8 H8A . . 110.3 ?
    P2 C8 H8A . . 110.3 ?
    C6 C8 H8B . . 110.3 ?
    P2 C8 H8B . . 110.3 ?
    H8A C8 H8B . . 108.5 ?
    C12 C9 C10 . . 107.9(3) ?
    C12 C9 C11 . . 107.3(3) ?
    C10 C9 C11 . . 109.8(3) ?
    C12 C9 P1 . . 109.5(2) ?
    C10 C9 P1 . . 112.2(2) ?
    C11 C9 P1 . . 110.0(2) ?
    C9 C10 H10A . . 109.5 ?
    C9 C10 H10B . . 109.5 ?
    H10A C10 H10B . . 109.5 ?
    C9 C10 H10C . . 109.5 ?
    H10A C10 H10C . . 109.5 ?
    H10B C10 H10C . . 109.5 ?
    C9 C11 H11A . . 109.5 ?
    C9 C11 H11B . . 109.5 ?
    H11A C11 H11B . . 109.5 ?
    C9 C11 H11C . . 109.5 ?
    H11A C11 H11C . . 109.5 ?
    H11B C11 H11C . . 109.5 ?
    C9 C12 H12A . . 109.5 ?
    C9 C12 H12B . . 109.5 ?
    H12A C12 H12B . . 109.5 ?
    C9 C12 H12C . . 109.5 ?
    H12A C12 H12C . . 109.5 ?
    H12B C12 H12C . . 109.5 ?
    C15 C13 C14 . . 108.4(3) ?
    C15 C13 C16 . . 108.6(3) ?
    C14 C13 C16 . . 107.8(3) ?
    C15 C13 P1 . . 110.9(2) ?
    C14 C13 P1 . . 115.2(2) ?
    C16 C13 P1 . . 105.8(2) ?
    C13 C14 H14A . . 109.5 ?
    C13 C14 H14B . . 109.5 ?
    H14A C14 H14B . . 109.5 ?
    C13 C14 H14C . . 109.5 ?
    H14A C14 H14C . . 109.5 ?
    H14B C14 H14C . . 109.5 ?
    C13 C15 H15A . . 109.5 ?
    C13 C15 H15B . . 109.5 ?
    H15A C15 H15B . . 109.5 ?
    C13 C15 H15C . . 109.5 ?
    H15A C15 H15C . . 109.5 ?
    H15B C15 H15C . . 109.5 ?
    C13 C16 H16A . . 109.5 ?
    C13 C16 H16B . . 109.5 ?
    H16A C16 H16B . . 109.5 ?
    C13 C16 H16C . . 109.5 ?
    H16A C16 H16C . . 109.5 ?
    H16B C16 H16C . . 109.5 ?
    C20 C17 C18 . . 106.8(3) ?
    C20 C17 C19 . . 107.6(3) ?
    C18 C17 C19 . . 109.6(3) ?
    C20 C17 P2 . . 110.4(2) ?
    C18 C17 P2 . . 113.1(2) ?
    C19 C17 P2 . . 109.3(2) ?
    C17 C18 H18A . . 109.5 ?
    C17 C18 H18B . . 109.5 ?
    H18A C18 H18B . . 109.5 ?
    C17 C18 H18C . . 109.5 ?
    H18A C18 H18C . . 109.5 ?
    H18B C18 H18C . . 109.5 ?
    C17 C19 H19A . . 109.5 ?
    C17 C19 H19B . . 109.5 ?
    H19A C19 H19B . . 109.5 ?
    C17 C19 H19C . . 109.5 ?
    H19A C19 H19C . . 109.5 ?
    H19B C19 H19C . . 109.5 ?
    C17 C20 H20A . . 109.5 ?
    C17 C20 H20B . . 109.5 ?
    H20A C20 H20B . . 109.5 ?
    C17 C20 H20C . . 109.5 ?
    H20A C20 H20C . . 109.5 ?
    H20B C20 H20C . . 109.5 ?
    C24 C21 C23 . . 107.2(3) ?
    C24 C21 C22 . . 107.0(3) ?
    C23 C21 C22 . . 110.3(3) ?
    C24 C21 P2 . . 107.9(2) ?
    C23 C21 P2 . . 111.7(2) ?
    C22 C21 P2 . . 112.6(2) ?
    C21 C22 H22A . . 109.5 ?
    C21 C22 H22B . . 109.5 ?
    H22A C22 H22B . . 109.5 ?
    C21 C22 H22C . . 109.5 ?
    H22A C22 H22C . . 109.5 ?
    H22B C22 H22C . . 109.5 ?
    C21 C23 H23A . . 109.5 ?
    C21 C23 H23B . . 109.5 ?
    H23A C23 H23B . . 109.5 ?
    C21 C23 H23C . . 109.5 ?
    H23A C23 H23C . . 109.5 ?
    H23B C23 H23C . . 109.5 ?
    C21 C24 H24A . . 109.5 ?
    C21 C24 H24B . . 109.5 ?
    H24A C24 H24B . . 109.5 ?
    C21 C24 H24C . . 109.5 ?
    H24A C24 H24C . . 109.5 ?
    H24B C24 H24C . . 109.5 ?
    C26 C25 C32 . . 123.4(3) ?
    C26 C25 Ir2 . . 69.71(19) ?
    C32 C25 Ir2 . . 114.2(2) ?
    C26 C25 H25 . . 107 ?
    C32 C25 H25 . . 120 ?
    Ir2 C25 H25 . . 111 ?
    C25 C26 C27 . . 125.2(3) ?
    C25 C26 Ir2 . . 71.04(19) ?
    C27 C26 Ir2 . . 111.0(2) ?
    C25 C26 H26 . . 113 ?
    C27 C26 H26 . . 117 ?
    Ir2 C26 H26 . . 106 ?
    C26 C27 C28 . . 112.4(3) ?
    C26 C27 H27A . . 109.1 ?
    C28 C27 H27A . . 109.1 ?
    C26 C27 H27B . . 109.1 ?
    C28 C27 H27B . . 109.1 ?
    H27A C27 H27B . . 107.9 ?
    C29 C28 C27 . . 111.3(3) ?
    C29 C28 H28A . . 109.4 ?
    C27 C28 H28A . . 109.4 ?
    C29 C28 H28B . . 109.4 ?
    C27 C28 H28B . . 109.4 ?
    H28A C28 H28B . . 108.0 ?
    C30 C29 C28 . . 123.7(3) ?
    C30 C29 Ir2 . . 69.85(18) ?
    C28 C29 Ir2 . . 113.4(2) ?
    C30 C29 H29 . . 117 ?
    C28 C29 H29 . . 114 ?
    Ir2 C29 H29 . . 107 ?
    C29 C30 C31 . . 124.3(3) ?
    C29 C30 Ir2 . . 70.88(19) ?
    C31 C30 Ir2 . . 112.0(2) ?
    C29 C30 H30 . . 116 ?
    C31 C30 H30 . . 116 ?
    Ir2 C30 H30 . . 104 ?
    C30 C31 C32 . . 112.0(3) ?
    C30 C31 H31A . . 109.2 ?
    C32 C31 H31A . . 109.2 ?
    C30 C31 H31B . . 109.2 ?
    C32 C31 H31B . . 109.2 ?
    H31A C31 H31B . . 107.9 ?
    C25 C32 C31 . . 111.3(3) ?
    C25 C32 H32A . . 109.4 ?
    C31 C32 H32A . . 109.4 ?
    C25 C32 H32B . . 109.4 ?
    C31 C32 H32B . . 109.4 ?
    H32A C32 H32B . . 108.0 ?
    C33 C33 C34 3_765 . 114.8(6) ?
    C33 C33 H33A 3_765 . 108.6 ?
    C34 C33 H33A . . 108.6 ?
    C33 C33 H33B 3_765 . 108.6 ?
    C34 C33 H33B . . 108.6 ?
    H33A C33 H33B . . 107.5 ?
    C33 C34 C35 . . 114.7(5) ?
    C33 C34 H34A . . 108.6 ?
    C35 C34 H34A . . 108.6 ?
    C33 C34 H34B . . 108.6 ?
    C35 C34 H34B . . 108.6 ?
    H34A C34 H34B . . 107.6 ?
    C34 C35 H35A . . 109.5 ?
    C34 C35 H35B . . 109.5 ?
    H35A C35 H35B . . 109.5 ?
    C34 C35 H35C . . 109.5 ?
    H35A C35 H35C . . 109.5 ?
    H35B C35 H35C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C1 Ir1 P1 C7 . . . . -21.72(14) ?
    P2 Ir1 P1 C7 . . . . 21.31(14) ?
    Cl1 Ir1 P1 C7 . . . . 161.47(11) ?
    Cl2 Ir1 P1 C7 . . . . -117.50(11) ?
    C1 Ir1 P1 C9 . . . . -132.26(15) ?
    P2 Ir1 P1 C9 . . . . -89.23(14) ?
    Cl1 Ir1 P1 C9 . . . . 50.94(12) ?
    Cl2 Ir1 P1 C9 . . . . 131.96(12) ?
    C1 Ir1 P1 C13 . . . . 90.06(15) ?
    P2 Ir1 P1 C13 . . . . 133.09(14) ?
    Cl1 Ir1 P1 C13 . . . . -86.74(13) ?
    Cl2 Ir1 P1 C13 . . . . -5.72(13) ?
    C1 Ir1 P2 C8 . . . . -28.64(14) ?
    P1 Ir1 P2 C8 . . . . -71.93(13) ?
    Cl1 Ir1 P2 C8 . . . . 148.12(11) ?
    Cl2 Ir1 P2 C8 . . . . 67.31(11) ?
    C1 Ir1 P2 C21 . . . . -143.63(16) ?
    P1 Ir1 P2 C21 . . . . 173.07(13) ?
    Cl1 Ir1 P2 C21 . . . . 33.13(13) ?
    Cl2 Ir1 P2 C21 . . . . -47.69(13) ?
    C1 Ir1 P2 C17 . . . . 82.46(15) ?
    P1 Ir1 P2 C17 . . . . 39.16(15) ?
    Cl1 Ir1 P2 C17 . . . . -100.78(12) ?
    Cl2 Ir1 P2 C17 . . . . 178.40(12) ?
    C26 Ir2 Cl1 Ir1 . . . . -144.88(10) ?
    C30 Ir2 Cl1 Ir1 . . . . 97.6(3) ?
    C25 Ir2 Cl1 Ir1 . . . . 176.11(10) ?
    C29 Ir2 Cl1 Ir1 . . . . -79.7(3) ?
    Cl2 Ir2 Cl1 Ir1 . . . . 10.20(3) ?
    P1 Ir1 Cl1 Ir2 . . . . 89.10(3) ?
    P2 Ir1 Cl1 Ir2 . . . . -104.44(3) ?
    Cl2 Ir1 Cl1 Ir2 . . . . -9.60(3) ?
    C26 Ir2 Cl2 Ir1 . . . . 72.0(2) ?
    C30 Ir2 Cl2 Ir1 . . . . -170.05(9) ?
    C25 Ir2 Cl2 Ir1 . . . . -103.5(4) ?
    C29 Ir2 Cl2 Ir1 . . . . 150.63(9) ?
    Cl1 Ir2 Cl2 Ir1 . . . . -9.82(3) ?
    C1 Ir1 Cl2 Ir2 . . . . -170.55(9) ?
    P1 Ir1 Cl2 Ir2 . . . . -86.25(3) ?
    P2 Ir1 Cl2 Ir2 . . . . 107.59(3) ?
    Cl1 Ir1 Cl2 Ir2 . . . . 9.45(2) ?
    P1 Ir1 C1 C6 . . . . -171.6(3) ?
    P2 Ir1 C1 C6 . . . . 22.8(2) ?
    Cl2 Ir1 C1 C6 . . . . -72.5(2) ?
    P1 Ir1 C1 C2 . . . . 12.5(2) ?
    P2 Ir1 C1 C2 . . . . -153.1(3) ?
    Cl2 Ir1 C1 C2 . . . . 111.6(2) ?
    C6 C1 C2 C3 . . . . 6.2(4) ?
    Ir1 C1 C2 C3 . . . . -177.7(2) ?
    C6 C1 C2 C7 . . . . -170.3(3) ?
    Ir1 C1 C2 C7 . . . . 5.7(4) ?
    C1 C2 C3 C4 . . . . -3.0(5) ?
    C7 C2 C3 C4 . . . . 173.4(3) ?
    C2 C3 C4 C5 . . . . -1.6(5) ?
    C3 C4 C5 C6 . . . . 2.8(5) ?
    C4 C5 C6 C1 . . . . 0.6(5) ?
    C4 C5 C6 C8 . . . . -175.7(3) ?
    C2 C1 C6 C5 . . . . -5.0(4) ?
    Ir1 C1 C6 C5 . . . . 178.9(2) ?
    C2 C1 C6 C8 . . . . 171.4(3) ?
    Ir1 C1 C6 C8 . . . . -4.7(4) ?
    C3 C2 C7 P1 . . . . 157.5(3) ?
    C1 C2 C7 P1 . . . . -26.0(4) ?
    C9 P1 C7 C2 . . . . 150.2(2) ?
    C13 P1 C7 C2 . . . . -95.3(2) ?
    Ir1 P1 C7 C2 . . . . 30.2(2) ?
    C5 C6 C8 P2 . . . . 153.6(3) ?
    C1 C6 C8 P2 . . . . -22.8(3) ?
    C21 P2 C8 C6 . . . . 164.0(2) ?
    C17 P2 C8 C6 . . . . -81.7(2) ?
    Ir1 P2 C8 C6 . . . . 33.9(2) ?
    C7 P1 C9 C12 . . . . -82.2(3) ?
    C13 P1 C9 C12 . . . . 168.2(2) ?
    Ir1 P1 C9 C12 . . . . 25.9(3) ?
    C7 P1 C9 C10 . . . . 37.6(3) ?
    C13 P1 C9 C10 . . . . -72.0(3) ?
    Ir1 P1 C9 C10 . . . . 145.6(2) ?
    C7 P1 C9 C11 . . . . 160.1(2) ?
    C13 P1 C9 C11 . . . . 50.5(3) ?
    Ir1 P1 C9 C11 . . . . -91.9(2) ?
    C7 P1 C13 C15 . . . . 172.9(2) ?
    C9 P1 C13 C15 . . . . -77.1(3) ?
    Ir1 P1 C13 C15 . . . . 63.0(3) ?
    C7 P1 C13 C14 . . . . -63.5(3) ?
    C9 P1 C13 C14 . . . . 46.5(3) ?
    Ir1 P1 C13 C14 . . . . -173.5(2) ?
    C7 P1 C13 C16 . . . . 55.4(2) ?
    C9 P1 C13 C16 . . . . 165.4(2) ?
    Ir1 P1 C13 C16 . . . . -54.5(2) ?
    C8 P2 C17 C20 . . . . 49.1(3) ?
    C21 P2 C17 C20 . . . . 160.4(2) ?
    Ir1 P2 C17 C20 . . . . -58.0(2) ?
    C8 P2 C17 C18 . . . . -70.5(3) ?
    C21 P2 C17 C18 . . . . 40.9(3) ?
    Ir1 P2 C17 C18 . . . . -177.6(2) ?
    C8 P2 C17 C19 . . . . 167.2(2) ?
    C21 P2 C17 C19 . . . . -81.4(2) ?
    Ir1 P2 C17 C19 . . . . 60.1(2) ?
    C8 P2 C21 C24 . . . . -80.4(2) ?
    C17 P2 C21 C24 . . . . 167.4(2) ?
    Ir1 P2 C21 C24 . . . . 32.3(3) ?
    C8 P2 C21 C23 . . . . 162.1(2) ?
    C17 P2 C21 C23 . . . . 49.9(3) ?
    Ir1 P2 C21 C23 . . . . -85.2(2) ?
    C8 P2 C21 C22 . . . . 37.5(3) ?
    C17 P2 C21 C22 . . . . -74.8(3) ?
    Ir1 P2 C21 C22 . . . . 150.15(19) ?
    C30 Ir2 C25 C26 . . . . -115.3(2) ?
    C29 Ir2 C25 C26 . . . . -76.8(2) ?
    Cl1 Ir2 C25 C26 . . . . 84.27(18) ?
    Cl2 Ir2 C25 C26 . . . . 176.9(3) ?
    C26 Ir2 C25 C32 . . . . 118.5(3) ?
    C30 Ir2 C25 C32 . . . . 3.2(2) ?
    C29 Ir2 C25 C32 . . . . 41.7(2) ?
    Cl1 Ir2 C25 C32 . . . . -157.2(2) ?
    Cl2 Ir2 C25 C32 . . . . -64.6(5) ?
    C32 C25 C26 C27 . . . . -3.5(5) ?
    Ir2 C25 C26 C27 . . . . 102.8(3) ?
    C32 C25 C26 Ir2 . . . . -106.2(3) ?
    C30 Ir2 C26 C25 . . . . 65.1(2) ?
    C29 Ir2 C26 C25 . . . . 100.6(2) ?
    Cl1 Ir2 C26 C25 . . . . -97.25(18) ?
    Cl2 Ir2 C26 C25 . . . . -178.25(16) ?
    C30 Ir2 C26 C27 . . . . -56.4(3) ?
    C25 Ir2 C26 C27 . . . . -121.4(3) ?
    C29 Ir2 C26 C27 . . . . -20.9(2) ?
    Cl1 Ir2 C26 C27 . . . . 141.3(2) ?
    Cl2 Ir2 C26 C27 . . . . 60.3(3) ?
    C25 C26 C27 C28 . . . . -46.6(4) ?
    Ir2 C26 C27 C28 . . . . 34.5(3) ?
    C26 C27 C28 C29 . . . . -31.2(4) ?
    C27 C28 C29 C30 . . . . 94.2(4) ?
    C27 C28 C29 Ir2 . . . . 13.6(4) ?
    C26 Ir2 C29 C30 . . . . -115.0(2) ?
    C25 Ir2 C29 C30 . . . . -76.6(2) ?
    Cl1 Ir2 C29 C30 . . . . 178.6(2) ?
    Cl2 Ir2 C29 C30 . . . . 89.89(18) ?
    C26 Ir2 C29 C28 . . . . 4.0(2) ?
    C30 Ir2 C29 C28 . . . . 119.0(3) ?
    C25 Ir2 C29 C28 . . . . 42.4(3) ?
    Cl1 Ir2 C29 C28 . . . . -62.4(4) ?
    Cl2 Ir2 C29 C28 . . . . -151.1(2) ?
    C28 C29 C30 C31 . . . . -1.3(5) ?
    Ir2 C29 C30 C31 . . . . 104.1(3) ?
    C28 C29 C30 Ir2 . . . . -105.3(3) ?
    C26 Ir2 C30 C29 . . . . 65.4(2) ?
    C25 Ir2 C30 C29 . . . . 100.8(2) ?
    Cl1 Ir2 C30 C29 . . . . -178.6(2) ?
    Cl2 Ir2 C30 C29 . . . . -92.26(18) ?
    C26 Ir2 C30 C31 . . . . -54.9(3) ?
    C25 Ir2 C30 C31 . . . . -19.5(2) ?
    C29 Ir2 C30 C31 . . . . -120.2(3) ?
    Cl1 Ir2 C30 C31 . . . . 61.2(4) ?
    Cl2 Ir2 C30 C31 . . . . 147.5(2) ?
    C29 C30 C31 C32 . . . . -49.0(5) ?
    Ir2 C30 C31 C32 . . . . 32.3(4) ?
    C26 C25 C32 C31 . . . . 94.2(4) ?
    Ir2 C25 C32 C31 . . . . 13.3(4) ?
    C30 C31 C32 C25 . . . . -29.3(4) ?
    C33 C33 C34 C35 3_765 . . . 177.6(6) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C12 H12B Cl1 . 0.98 2.93 3.785(4) 147.1
    C15 H15C Cl2 . 0.98 2.80 3.628(4) 143.1
    C16 H16A Cl2 . 0.98 2.66 3.551(4) 151.6
    C24 H24B Cl2 . 0.98 2.79 3.295(3) 112.5
    C24 H24C Cl1 . 0.98 2.91 3.782(3) 148.5
    C24 H24B Cl2 . 0.98 2.79 3.295(3) 112.5
    C26 H26 Cl1 . 0.94 2.79 3.165(3) 104.7
    C27 H27B Cl1 2_755 0.99 2.81 3.659(3) 143.9
    C30 H30 Cl2 . 0.87 2.93 3.264(3) 104.7
    C32 H32A Cl1 2_755 0.99 2.90 3.865(3) 166.0
