##############################################################################
###                                                                        ###
###           Full Paper (Acta Crystallographica Section C)                ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section C. It conforms to the editorial and technical    #
# requirements of Notes for Authors for Section C, and has been peer         #
# reviewed under the auspices of the IUCr Commission on Journals.            #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
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##############################################################################
data_global
_audit_creation_method     'by CrystalStructure 3.6.0'
_journal_date_recd_electronic     2006-10-13
_journal_date_accepted     2006-11-26
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2007
_journal_volume     63
_journal_issue      1
_journal_page_first     m22
_journal_page_last     m26
_journal_paper_category     FM
_journal_coeditor_code     RB3021
_publ_contact_author_name     'Mamiko Odoko'
_publ_contact_author_address
;
Faculty of Pharmaceutical Sciences
Kinki University
Kowakae 3-4-1
Higashiosaka
Osaka 577-8502
Japan
;
_publ_contact_author_email     odoko@phar.kindai.ac.jp
_publ_contact_author_fax     '00-81-6-6730-1394'
_publ_contact_author_phone     '00-81-6-6730-5880-3864'
_publ_section_title
;\
catena-Poly[[bis(μ₂-4-methylbenzoato-κ²O:O')\
disilver(I)(Ag---Ag)]-μ₂-di-2-pyridylamine-κ²N²:N^2'^]
and
catena-poly[[(di-2-pyridylamine-κN²)(μ₂-4-nitrobenzoato-\
κ²O:O')disilver(I)(Ag---Ag)]-μ₃-4-nitrobenzoato-\
κ³O:O':O']
;
loop_
    _publ_author_name
    _publ_author_address
    'Odoko, Mamiko'
;
Faculty of Pharmaceutical Sciences
Kinki University
Kowakae 3-4-1
Higashiosaka
Osaka 577-8502
Japan
;
    'Ise, Tomoyasu'
;
Faculty of Pharmaceutical Sciences
Kinki University
Kowakae 3-4-1
Higashiosaka
Osaka 577-8502
Japan
;
    'Okabe, Nobuo'
;
Faculty of Pharmaceutical Sciences
Kinki University
Kowakae 3-4-1
Higashiosaka
Osaka 577-8502
Japan
;
data_I
_chemical_name_systematic
;
catena-Poly[[bis(μ₂-4-methylbenzoato-κ²O:O')disilver(I)(Ag---Ag)]-
μ₂-di-2-pyridylamine-κ²N²:N^2'^]
;
_chemical_formula_moiety     'C26 H23 Ag2 N3 O4'
_chemical_formula_sum     'C26 H23 Ag2 N3 O4'
_chemical_formula_iupac     '[Ag2 (C8 H7 O2)2 (C10 H9 N3)]'
_chemical_formula_weight     657.21
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'C 2/c'
_symmetry_space_group_name_Hall     '-C 2yc'
loop_
    _symmetry_equiv_pos_site_id
    _symmetry_equiv_pos_as_xyz
    1 +X,+Y,+Z
    2 -X,+Y,1/2-Z
    3 -X,-Y,-Z
    4 +X,-Y,1/2+Z
    5 1/2+X,1/2+Y,+Z
    6 1/2-X,1/2+Y,1/2-Z
    7 1/2-X,1/2-Y,-Z
    8 1/2+X,1/2-Y,1/2+Z
_cell_length_a     24.76(2)
_cell_length_b     8.590(10)
_cell_length_c     11.550(10)
_cell_angle_alpha     90
_cell_angle_beta     107.11(3)
_cell_angle_gamma     90
_cell_volume     2348(4)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     7596
_cell_measurement_theta_min     3.3
_cell_measurement_theta_max     27.5
_cell_measurement_temperature     296.1
_exptl_crystal_description     platelet
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.20
_exptl_crystal_size_mid     0.10
_exptl_crystal_size_min     0.03
_exptl_crystal_density_diffrn     1.859
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1304.00
_exptl_absorpt_coefficient_mu     1.707
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(ABSCOR; Higashi, 1995)'
_exptl_absorpt_correction_T_min     0.639
_exptl_absorpt_correction_T_max     0.949
_diffrn_radiation_type     'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_measurement_device_type     'Rigaku R-AXIS RAPID'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     10.00
_diffrn_reflns_number     11540
_diffrn_reflns_av_R_equivalents     0.048
_diffrn_reflns_theta_max     27.48
_diffrn_reflns_theta_full     27.48
_diffrn_measured_fraction_theta_max     0.9969
_diffrn_measured_fraction_theta_full     0.9969
_diffrn_reflns_limit_h_min     -32
_diffrn_reflns_limit_h_max     31
_diffrn_reflns_limit_k_min     -11
_diffrn_reflns_limit_k_max     11
_diffrn_reflns_limit_l_min     -14
_diffrn_reflns_limit_l_max     14
_diffrn_standards_number     0
_refine_special_details
;
     Refinement using all reflections. The weighted
     R-factor (wR) and goodness of fit (S) are based on F².
     R-factor (gt) are based on F. The threshold expression of
     F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_reflns_number_total     2679
_reflns_number_gt     1585
_reflns_threshold_expression     F²>2σ(F²)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_R_factor_gt     0.0306
_refine_ls_wR_factor_ref     0.0578
_refine_ls_goodness_of_fit_ref     0.802
_refine_ls_number_reflns     2679
_refine_ls_number_parameters     160
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
               'calc w = 1/[σ²(Fo²)+(0.0282P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_shift/su_max     0.001
_refine_diff_density_max     0.542
_refine_diff_density_min     -0.790
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.003 0.002
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
    'H' 'H' 0.000 0.000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
    'O' 'O' 0.011 0.006
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
    'N' 'N' 0.006 0.003
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
    'Ag' 'Ag' -0.897 1.101
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
_computing_data_collection     'RAPID-AUTO (Rigaku, 1998)'
_computing_cell_refinement     'RAPID-AUTO'
_computing_data_reduction
;
CrystalStructure (Rigaku/MSC, 2005) and CRYSTALS (Betteridge et
al.,  2003)
;
_computing_structure_solution     'SIR97 (Altomare et al.,  1999)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics
                              'ORTEP-3 (Farrugia, 1997) and PLATON (Spek, 2003)'
_computing_publication_material     'CrystalStructure'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag1 0.518213(11) 0.64184(3) 0.96130(2) 0.04886(10) Uani d . 1 . .
    O O1 0.44762(9) 0.6062(3) 0.79853(19) 0.0485(7) Uani d . 1 . .
    O O2 0.41382(9) 0.4011(3) 0.8695(2) 0.0596(8) Uani d . 1 . .
    N N1 0.54997(10) 0.9039(3) 0.9499(2) 0.0301(6) Uani d . 1 . .
    N N2 0.5000 0.9312(4) 0.7500 0.0333(8) Uani d S 1 . .
    H H22 0.5000 0.8311 0.7500 0.040 Uiso calc SR 1 . .
    C C1 0.58397(12) 0.9606(4) 1.0539(3) 0.0350(8) Uani d . 1 . .
    H H1 0.5954 0.8936 1.1198 0.042 Uiso calc R 1 . .
    C C2 0.60309(12) 1.1115(4) 1.0692(3) 0.0385(8) Uani d . 1 . .
    H H2 0.6253 1.1473 1.1440 0.046 Uiso calc R 1 . .
    C C3 0.58802(12) 1.2083(4) 0.9688(3) 0.0366(8) Uani d . 1 . .
    H H3 0.6009 1.3106 0.9751 0.044 Uiso calc R 1 . .
    C C4 0.55416(12) 1.1535(4) 0.8603(3) 0.0332(7) Uani d . 1 . .
    H H4 0.5445 1.2168 0.7919 0.040 Uiso calc R 1 . .
    C C5 0.53449(11) 1.0006(4) 0.8544(2) 0.0291(7) Uani d . 1 . .
    C C6 0.41071(12) 0.5059(4) 0.7938(3) 0.0332(7) Uani d . 1 . .
    C C7 0.35821(12) 0.5123(4) 0.6887(3) 0.0362(8) Uani d . 1 . .
    C C8 0.35269(14) 0.6147(4) 0.5951(3) 0.0529(11) Uani d . 1 . .
    H H8 0.3817 0.6846 0.5982 0.063 Uiso calc R 1 . .
    C C9 0.30546(16) 0.6164(5) 0.4972(3) 0.0680(13) Uani d . 1 . .
    H H9 0.3036 0.6871 0.4352 0.082 Uiso calc R 1 . .
    C C10 0.26115(14) 0.5189(5) 0.4871(3) 0.0561(10) Uani d . 1 . .
    C C11 0.26599(15) 0.4167(6) 0.5823(3) 0.0818(16) Uani d . 1 . .
    H H11 0.2363 0.3493 0.5802 0.098 Uiso calc R 1 . .
    C C12 0.31385(15) 0.4131(5) 0.6799(3) 0.0742(15) Uani d . 1 . .
    H H12 0.3162 0.3415 0.7415 0.089 Uiso calc R 1 . .
    C C13 0.20958(15) 0.5182(6) 0.3768(3) 0.0842(15) Uani d . 1 . .
    H H13A 0.2028 0.6216 0.3441 0.126 Uiso calc R 1 . .
    H H13B 0.1773 0.4835 0.3996 0.126 Uiso calc R 1 . .
    H H13C 0.2159 0.4493 0.3167 0.126 Uiso calc R 1 . .
_geom_special_details
;
  All esds (except the esd in the dihedral angle between two l.s. planes)
  are estimated using the full covariance matrix.  The cell esds are taken
  into account individually in the estimation of esds in distances, angles
  and torsion angles; correlations between esds in cell parameters are only
  used when they are defined by crystal symmetry.  An approximate (isotropic)
  treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 O1 . 2.179(3) ?
    Ag1 O2 5_667 2.203(3) ?
    Ag1 N1 . 2.401(4) ?
    Ag1 Ag1 5_667 2.833(3) ?
    O1 C6 . 1.245(4) ?
    O2 C6 . 1.242(4) ?
    O2 Ag1 5_667 2.203(3) ?
    N1 C1 . 1.339(4) ?
    N1 C5 . 1.344(4) ?
    N2 C5 . 1.390(3) ?
    N2 C5 2_656 1.390(3) ?
    N2 H22 . 0.8600 ?
    C1 C2 . 1.374(5) ?
    C1 H1 . 0.9300 ?
    C2 C3 . 1.386(4) ?
    C2 H2 . 0.9300 ?
    C3 C4 . 1.371(4) ?
    C3 H3 . 0.9300 ?
    C4 C5 . 1.396(4) ?
    C4 H4 . 0.9300 ?
    C6 C7 . 1.496(4) ?
    C7 C8 . 1.369(4) ?
    C7 C12 . 1.370(5) ?
    C8 C9 . 1.367(5) ?
    C8 H8 . 0.9300 ?
    C9 C10 . 1.358(5) ?
    C9 H9 . 0.9300 ?
    C10 C11 . 1.385(5) ?
    C10 C13 . 1.515(5) ?
    C11 C12 . 1.375(5) ?
    C11 H11 . 0.9300 ?
    C12 H12 . 0.9300 ?
    C13 H13A . 0.9600 ?
    C13 H13B . 0.9600 ?
    C13 H13C . 0.9600 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Ag1 O2 . 5_667 162.05(9) ?
    O1 Ag1 N1 . . 106.07(9) ?
    O2 Ag1 N1 5_667 . 91.64(9) ?
    O1 Ag1 Ag1 . 5_667 84.41(8) ?
    O2 Ag1 Ag1 5_667 5_667 78.87(7) ?
    N1 Ag1 Ag1 . 5_667 164.49(6) ?
    C6 O1 Ag1 . . 121.8(2) ?
    C6 O2 Ag1 . 5_667 128.3(2) ?
    C1 N1 C5 . . 117.6(3) ?
    C1 N1 Ag1 . . 114.9(2) ?
    C5 N1 Ag1 . . 127.3(2) ?
    C5 N2 C5 . 2_656 129.2(4) ?
    C5 N2 H22 . . 115.4 ?
    C5 N2 H22 2_656 . 115.4 ?
    N1 C1 C2 . . 124.1(3) ?
    N1 C1 H1 . . 117.9 ?
    C2 C1 H1 . . 117.9 ?
    C1 C2 C3 . . 117.5(3) ?
    C1 C2 H2 . . 121.3 ?
    C3 C2 H2 . . 121.3 ?
    C4 C3 C2 . . 120.0(3) ?
    C4 C3 H3 . . 120.0 ?
    C2 C3 H3 . . 120.0 ?
    C3 C4 C5 . . 118.6(3) ?
    C3 C4 H4 . . 120.7 ?
    C5 C4 H4 . . 120.7 ?
    N1 C5 N2 . . 113.7(3) ?
    N1 C5 C4 . . 122.0(3) ?
    N2 C5 C4 . . 124.2(3) ?
    O2 C6 O1 . . 125.3(3) ?
    O2 C6 C7 . . 117.2(3) ?
    O1 C6 C7 . . 117.5(3) ?
    C8 C7 C12 . . 116.7(3) ?
    C8 C7 C6 . . 121.7(3) ?
    C12 C7 C6 . . 121.6(3) ?
    C9 C8 C7 . . 121.5(3) ?
    C9 C8 H8 . . 119.3 ?
    C7 C8 H8 . . 119.3 ?
    C10 C9 C8 . . 122.5(3) ?
    C10 C9 H9 . . 118.7 ?
    C8 C9 H9 . . 118.7 ?
    C9 C10 C11 . . 116.3(3) ?
    C9 C10 C13 . . 122.3(3) ?
    C11 C10 C13 . . 121.3(3) ?
    C12 C11 C10 . . 121.2(3) ?
    C12 C11 H11 . . 119.4 ?
    C10 C11 H11 . . 119.4 ?
    C7 C12 C11 . . 121.7(3) ?
    C7 C12 H12 . . 119.2 ?
    C11 C12 H12 . . 119.2 ?
    C10 C13 H13A . . 109.5 ?
    C10 C13 H13B . . 109.5 ?
    H13A C13 H13B . . 109.5 ?
    C10 C13 H13C . . 109.5 ?
    H13A C13 H13C . . 109.5 ?
    H13B C13 H13C . . 109.5 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O2 Ag1 O1 C6 5_667 . . . 33.3(4) ?
    N1 Ag1 O1 C6 . . . . -156.4(2) ?
    Ag1 Ag1 O1 C6 5_667 . . . 12.0(2) ?
    O1 Ag1 N1 C1 . . . . 164.85(19) ?
    O2 Ag1 N1 C1 5_667 . . . -18.1(2) ?
    Ag1 Ag1 N1 C1 5_667 . . . 33.6(4) ?
    O1 Ag1 N1 C5 . . . . -10.5(2) ?
    O2 Ag1 N1 C5 5_667 . . . 166.6(2) ?
    Ag1 Ag1 N1 C5 5_667 . . . -141.71(19) ?
    C5 N1 C1 C2 . . . . 1.2(4) ?
    Ag1 N1 C1 C2 . . . . -174.6(2) ?
    N1 C1 C2 C3 . . . . -2.9(5) ?
    C1 C2 C3 C4 . . . . 1.5(5) ?
    C2 C3 C4 C5 . . . . 1.4(4) ?
    C1 N1 C5 N2 . . . . 179.0(2) ?
    Ag1 N1 C5 N2 . . . . -5.8(3) ?
    C1 N1 C5 C4 . . . . 2.1(4) ?
    Ag1 N1 C5 C4 . . . . 177.26(19) ?
    C5 N2 C5 N1 2_656 . . . 162.7(2) ?
    C5 N2 C5 C4 2_656 . . . -20.4(2) ?
    C3 C4 C5 N1 . . . . -3.3(4) ?
    C3 C4 C5 N2 . . . . -179.9(2) ?
    Ag1 O2 C6 O1 5_667 . . . 2.3(5) ?
    Ag1 O2 C6 C7 5_667 . . . -177.42(19) ?
    Ag1 O1 C6 O2 . . . . -12.1(5) ?
    Ag1 O1 C6 C7 . . . . 167.69(18) ?
    O2 C6 C7 C8 . . . . -174.3(3) ?
    O1 C6 C7 C8 . . . . 5.9(5) ?
    O2 C6 C7 C12 . . . . 4.0(5) ?
    O1 C6 C7 C12 . . . . -175.8(3) ?
    C12 C7 C8 C9 . . . . -0.7(6) ?
    C6 C7 C8 C9 . . . . 177.7(3) ?
    C7 C8 C9 C10 . . . . 0.7(7) ?
    C8 C9 C10 C11 . . . . 0.4(7) ?
    C8 C9 C10 C13 . . . . -178.2(4) ?
    C9 C10 C11 C12 . . . . -1.4(7) ?
    C13 C10 C11 C12 . . . . 177.2(4) ?
    C8 C7 C12 C11 . . . . -0.4(6) ?
    C6 C7 C12 C11 . . . . -178.8(4) ?
    C10 C11 C12 C7 . . . . 1.5(7) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N2 H22 O1 . 0.86 2.48 3.197(5) 141.1 yes
data_II
_chemical_name_systematic
;
catena-poly[[(di-2-pyridylamine-\kN²)(μ₂-4-nitrobenzoato-
κ²O:O')disilver(I)(Ag---Ag)]-μ₃-4-nitrobenzoato-κ³O:O':O']
;
_chemical_formula_moiety     'C24 H17 Ag2 N5 O8'
_chemical_formula_sum     'C24 H17 Ag2 N5 O8'
_chemical_formula_iupac     '[Ag2 (C7 H4 N O4)2 (C10 H9 N3)]'
_chemical_formula_weight     719.17
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_site_id
    _symmetry_equiv_pos_as_xyz
    1 +X,+Y,+Z
    2 -X,-Y,-Z
_cell_length_a     7.259(8)
_cell_length_b     11.070(10)
_cell_length_c     15.38(2)
_cell_angle_alpha     82.66(5)
_cell_angle_beta     84.84(4)
_cell_angle_gamma     72.01(4)
_cell_volume     1164(2)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     9330
_cell_measurement_theta_min     3.0
_cell_measurement_theta_max     27.5
_cell_measurement_temperature     296.1
_exptl_crystal_description     platelet
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.40
_exptl_crystal_size_mid     0.20
_exptl_crystal_size_min     0.03
_exptl_crystal_density_diffrn     2.051
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     708.00
_exptl_absorpt_coefficient_mu     1.746
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(ABSCOR; Higashi, 1995)'
_exptl_absorpt_correction_T_min     0.582
_exptl_absorpt_correction_T_max     0.957
_diffrn_radiation_type     'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_measurement_device_type     'Rigaku R-AXIS RAPID'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     10.00
_diffrn_reflns_number     11341
_diffrn_reflns_av_R_equivalents     0.024
_diffrn_reflns_theta_max     27.48
_diffrn_reflns_theta_full     27.48
_diffrn_measured_fraction_theta_max     0.9877
_diffrn_measured_fraction_theta_full     0.9877
_diffrn_reflns_limit_h_min     -9
_diffrn_reflns_limit_h_max     9
_diffrn_reflns_limit_k_min     -14
_diffrn_reflns_limit_k_max     14
_diffrn_reflns_limit_l_min     -19
_diffrn_reflns_limit_l_max     19
_diffrn_standards_number     0
_refine_special_details
;
     Refinement using all reflections. The weighted
     R-factor (wR) and goodness of fit (S) are based on F².
     R-factor (gt) are based on F. The threshold expression of
     F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_reflns_number_total     5281
_reflns_number_gt     4093
_reflns_threshold_expression     F²>2σ(F²)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_R_factor_gt     0.0327
_refine_ls_wR_factor_ref     0.0882
_refine_ls_goodness_of_fit_ref     1.009
_refine_ls_number_reflns     5281
_refine_ls_number_parameters     351
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
               'calc w = 1/[σ²(Fo²)+(0.0469P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_shift/su_max     0.001
_refine_diff_density_max     1.063
_refine_diff_density_min     -0.792
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.003 0.002
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
    'H' 'H' 0.000 0.000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
    'N' 'N' 0.006 0.003
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
    'Ag' 'Ag' -0.897 1.101
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
    'O' 'O' 0.011 0.006
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
_computing_data_collection     'RAPID-AUTO (Rigaku, 1998)'
_computing_cell_refinement     'RAPID-AUTO'
_computing_data_reduction
;
CrystalStructure (Rigaku/MSC, 2005) and CRYSTALS (Betteridge et
al.,  2003)
;
_computing_structure_solution     'SIR97 (Altomare et al.,  1999)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics
                              'ORTEP-3 (Farrugia, 1997) and PLATON (Spek, 2003)'
_computing_publication_material     'CrystalStructure'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag1 0.89741(3) 0.13823(3) 0.554037(15) 0.05584(10) Uani d . 1 . .
    Ag Ag2 1.29267(3) -0.01184(2) 0.571841(14) 0.05205(10) Uani d . 1 . .
    O O1 0.9050(3) 0.0677(2) 0.69404(13) 0.0540(6) Uani d . 1 . .
    O O2 1.1912(3) -0.0817(2) 0.70066(13) 0.0490(5) Uani d . 1 . .
    O O3 0.9345(4) -0.2598(3) 1.13020(16) 0.0863(9) Uani d . 1 . .
    O O4 0.6844(3) -0.0964(2) 1.12742(15) 0.0676(7) Uani d . 1 . .
    O O5 1.3265(3) 0.08205(19) 0.43793(12) 0.0427(5) Uani d . 1 . .
    O O6 1.0217(3) 0.2092(2) 0.43068(13) 0.0493(5) Uani d . 1 . .
    O O7 1.2401(5) 0.4777(3) 0.02400(18) 0.1043(11) Uani d . 1 . .
    O O8 1.4476(5) 0.3001(3) 0.00161(17) 0.0917(10) Uani d . 1 . .
    N N1 0.5595(3) 0.2341(2) 0.55414(16) 0.0407(5) Uani d . 1 . .
    N N2 0.5637(3) 0.3535(2) 0.42195(15) 0.0426(6) Uani d . 1 . .
    H H22 0.6831 0.3072 0.4194 0.051 Uiso calc R 1 . .
    N N3 0.3472(3) 0.5375(2) 0.35207(15) 0.0433(6) Uani d . 1 . .
    N N4 0.8296(4) -0.1641(2) 1.09215(16) 0.0472(6) Uani d . 1 . .
    N N5 1.3312(4) 0.3697(3) 0.04937(17) 0.0574(7) Uani d . 1 . .
    C C1 0.4695(4) 0.2001(3) 0.62935(19) 0.0441(7) Uani d . 1 . .
    H H1 0.5413 0.1356 0.6687 0.053 Uiso calc R 1 . .
    C C2 0.2773(4) 0.2561(3) 0.65051(19) 0.0475(7) Uani d . 1 . .
    H H2 0.2181 0.2296 0.7024 0.057 Uiso calc R 1 . .
    C C3 0.1754(4) 0.3527(3) 0.5923(2) 0.0525(8) Uani d . 1 . .
    H H3 0.0444 0.3927 0.6047 0.063 Uiso calc R 1 . .
    C C4 0.2648(4) 0.3914(3) 0.51573(18) 0.0459(7) Uani d . 1 . .
    H H4 0.1969 0.4582 0.4767 0.055 Uiso calc R 1 . .
    C C5 0.4599(4) 0.3274(3) 0.49845(17) 0.0359(6) Uani d . 1 . .
    C C6 0.3089(5) 0.6192(3) 0.2792(2) 0.0499(7) Uani d . 1 . .
    H H6 0.1960 0.6878 0.2804 0.060 Uiso calc R 1 . .
    C C7 0.4238(5) 0.6094(3) 0.20266(19) 0.0508(7) Uani d . 1 . .
    H H7 0.3899 0.6692 0.1540 0.061 Uiso calc R 1 . .
    C C8 0.5900(5) 0.5084(3) 0.2009(2) 0.0523(8) Uani d . 1 . .
    H H8 0.6720 0.4983 0.1505 0.063 Uiso calc R 1 . .
    C C9 0.6341(4) 0.4227(3) 0.27350(19) 0.0478(7) Uani d . 1 . .
    H H9 0.7456 0.3530 0.2731 0.057 Uiso calc R 1 . .
    C C10 0.5095(4) 0.4410(3) 0.34868(17) 0.0370(6) Uani d . 1 . .
    C C11 1.0307(4) -0.0220(3) 0.73313(17) 0.0353(6) Uani d . 1 . .
    C C12 0.9801(3) -0.0591(2) 0.82785(16) 0.0333(5) Uani d . 1 . .
    C C13 1.0915(4) -0.1698(3) 0.87320(17) 0.0389(6) Uani d . 1 . .
    H H13 1.2011 -0.2211 0.8451 0.047 Uiso calc R 1 . .
    C C14 1.0430(4) -0.2057(3) 0.95956(18) 0.0414(6) Uani d . 1 . .
    H H14 1.1178 -0.2807 0.9895 0.050 Uiso calc R 1 . .
    C C15 0.8808(4) -0.1273(3) 1.00021(16) 0.0364(6) Uani d . 1 . .
    C C16 0.7681(4) -0.0156(3) 0.95759(18) 0.0391(6) Uani d . 1 . .
    H H16 0.6607 0.0366 0.9865 0.047 Uiso calc R 1 . .
    C C17 0.8176(4) 0.0174(3) 0.87074(18) 0.0395(6) Uani d . 1 . .
    H H17 0.7412 0.0918 0.8408 0.047 Uiso calc R 1 . .
    C C18 1.1931(4) 0.1674(3) 0.40032(17) 0.0364(6) Uani d . 1 . .
    C C19 1.2366(4) 0.2240(2) 0.30983(16) 0.0345(6) Uani d . 1 . .
    C C20 1.1290(4) 0.3465(3) 0.27887(18) 0.0416(6) Uani d . 1 . .
    H H20 1.0358 0.3957 0.3161 0.050 Uiso calc R 1 . .
    C C21 1.1584(4) 0.3964(3) 0.19341(19) 0.0448(7) Uani d . 1 . .
    H H21 1.0860 0.4784 0.1725 0.054 Uiso calc R 1 . .
    C C22 1.2983(4) 0.3209(3) 0.14011(17) 0.0392(6) Uani d . 1 . .
    C C23 1.4094(4) 0.1991(3) 0.16914(18) 0.0393(6) Uani d . 1 . .
    H H23 1.5028 0.1502 0.1318 0.047 Uiso calc R 1 . .
    C C24 1.3787(4) 0.1519(3) 0.25430(17) 0.0376(6) Uani d . 1 . .
    H H24 1.4538 0.0706 0.2752 0.045 Uiso calc R 1 . .
_geom_special_details
;
  All esds (except the esd in the dihedral angle between two l.s. planes)
  are estimated using the full covariance matrix.  The cell esds are taken
  into account individually in the estimation of esds in distances, angles
  and torsion angles; correlations between esds in cell parameters are only
  used when they are defined by crystal symmetry.  An approximate (isotropic)
  treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 O6 . 2.187(3) yes
    Ag1 O1 . 2.194(3) yes
    Ag1 N1 . 2.353(3) yes
    Ag1 Ag2 . 2.855(3) yes
    Ag1 Ag2 2_756 3.158(2) yes
    Ag2 O2 . 2.183(3) yes
    Ag2 O5 . 2.214(3) yes
    Ag2 O5 2_856 2.626(4) yes
    O1 C11 . 1.252(3) ?
    O2 C11 . 1.244(3) ?
    O3 N4 . 1.212(4) ?
    O4 N4 . 1.217(3) ?
    O5 C18 . 1.249(3) ?
    O6 C18 . 1.256(3) ?
    O7 N5 . 1.207(4) ?
    O8 N5 . 1.216(3) ?
    N1 C5 . 1.322(4) ?
    N1 C1 . 1.346(4) ?
    N2 C5 . 1.387(4) ?
    N2 C10 . 1.389(4) ?
    N2 H22 . 0.8600 ?
    N3 C10 . 1.326(4) ?
    N3 C6 . 1.339(4) ?
    N4 C15 . 1.468(4) ?
    N5 C22 . 1.457(4) ?
    C1 C2 . 1.368(4) ?
    C1 H1 . 0.9300 ?
    C2 C3 . 1.370(5) ?
    C2 H2 . 0.9300 ?
    C3 C4 . 1.378(4) ?
    C3 H3 . 0.9300 ?
    C4 C5 . 1.392(4) ?
    C4 H4 . 0.9300 ?
    C6 C7 . 1.376(4) ?
    C6 H6 . 0.9300 ?
    C7 C8 . 1.370(5) ?
    C7 H7 . 0.9300 ?
    C8 C9 . 1.362(4) ?
    C8 H8 . 0.9300 ?
    C9 C10 . 1.398(4) ?
    C9 H9 . 0.9300 ?
    C11 C12 . 1.507(4) ?
    C12 C13 . 1.384(4) ?
    C12 C17 . 1.389(4) ?
    C13 C14 . 1.383(4) ?
    C13 H13 . 0.9300 ?
    C14 C15 . 1.381(4) ?
    C14 H14 . 0.9300 ?
    C15 C16 . 1.375(4) ?
    C16 C17 . 1.385(4) ?
    C16 H16 . 0.9300 ?
    C17 H17 . 0.9300 ?
    C18 C19 . 1.500(4) ?
    C19 C20 . 1.386(4) ?
    C19 C24 . 1.392(4) ?
    C20 C21 . 1.384(4) ?
    C20 H20 . 0.9300 ?
    C21 C22 . 1.379(4) ?
    C21 H21 . 0.9300 ?
    C22 C23 . 1.381(4) ?
    C23 C24 . 1.372(4) ?
    C23 H23 . 0.9300 ?
    C24 H24 . 0.9300 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O6 Ag1 O1 . . 153.23(9) yes
    O6 Ag1 N1 . . 107.18(10) yes
    O1 Ag1 N1 . . 95.94(9) yes
    O6 Ag1 Ag2 . . 81.16(9) yes
    O1 Ag1 Ag2 . . 77.11(7) yes
    N1 Ag1 Ag2 . . 170.57(6) yes
    O6 Ag1 Ag2 . 2_756 83.11(10) yes
    O1 Ag1 Ag2 . 2_756 118.55(9) yes
    N1 Ag1 Ag2 . 2_756 68.95(9) yes
    Ag2 Ag1 Ag2 . 2_756 108.55(7) yes
    O2 Ag2 O5 . . 167.26(8) yes
    O2 Ag2 Ag1 . . 84.96(8) yes
    O5 Ag2 Ag1 . . 82.33(8) yes
    O2 Ag2 Ag1 . 2_756 101.48(10) yes
    O5 Ag2 Ag1 . 2_756 73.65(10) yes
    Ag1 Ag2 Ag1 . 2_756 71.45(7) yes
    O2 Ag2 O5 . 2_856 109.31(9) yes
    O5 Ag2 O5 . 2_856 83.30(9) yes
    Ag1 Ag2 O5 . 2_856 161.49(5) yes
    C11 O1 Ag1 . . 129.04(18) ?
    C11 O2 Ag2 . . 119.62(19) ?
    C18 O5 Ag2 . . 123.78(18) ?
    C18 O6 Ag1 . . 126.5(2) ?
    C5 N1 C1 . . 119.0(2) ?
    C5 N1 Ag1 . . 128.15(19) ?
    C1 N1 Ag1 . . 111.83(19) ?
    C5 N2 C10 . . 131.6(2) ?
    C5 N2 H22 . . 114.2 ?
    C10 N2 H22 . . 114.2 ?
    C10 N3 C6 . . 116.3(2) ?
    O3 N4 O4 . . 122.6(3) ?
    O3 N4 C15 . . 118.8(2) ?
    O4 N4 C15 . . 118.5(3) ?
    O7 N5 O8 . . 122.3(3) ?
    O7 N5 C22 . . 118.7(3) ?
    O8 N5 C22 . . 119.0(3) ?
    N1 C1 C2 . . 123.0(3) ?
    N1 C1 H1 . . 118.5 ?
    C2 C1 H1 . . 118.5 ?
    C1 C2 C3 . . 117.5(3) ?
    C1 C2 H2 . . 121.2 ?
    C3 C2 H2 . . 121.2 ?
    C2 C3 C4 . . 120.7(3) ?
    C2 C3 H3 . . 119.6 ?
    C4 C3 H3 . . 119.6 ?
    C3 C4 C5 . . 118.0(3) ?
    C3 C4 H4 . . 121.0 ?
    C5 C4 H4 . . 121.0 ?
    N1 C5 N2 . . 114.8(2) ?
    N1 C5 C4 . . 121.7(3) ?
    N2 C5 C4 . . 123.5(3) ?
    N3 C6 C7 . . 125.0(3) ?
    N3 C6 H6 . . 117.5 ?
    C7 C6 H6 . . 117.5 ?
    C8 C7 C6 . . 117.5(3) ?
    C8 C7 H7 . . 121.3 ?
    C6 C7 H7 . . 121.3 ?
    C9 C8 C7 . . 119.4(3) ?
    C9 C8 H8 . . 120.3 ?
    C7 C8 H8 . . 120.3 ?
    C8 C9 C10 . . 119.1(3) ?
    C8 C9 H9 . . 120.4 ?
    C10 C9 H9 . . 120.4 ?
    N3 C10 N2 . . 120.3(2) ?
    N3 C10 C9 . . 122.7(3) ?
    N2 C10 C9 . . 117.0(2) ?
    O2 C11 O1 . . 125.8(3) ?
    O2 C11 C12 . . 118.2(3) ?
    O1 C11 C12 . . 116.1(2) ?
    C13 C12 C17 . . 118.9(3) ?
    C13 C12 C11 . . 121.1(2) ?
    C17 C12 C11 . . 120.0(3) ?
    C14 C13 C12 . . 121.3(2) ?
    C14 C13 H13 . . 119.4 ?
    C12 C13 H13 . . 119.4 ?
    C15 C14 C13 . . 118.3(3) ?
    C15 C14 H14 . . 120.8 ?
    C13 C14 H14 . . 120.8 ?
    C16 C15 C14 . . 122.0(3) ?
    C16 C15 N4 . . 119.4(2) ?
    C14 C15 N4 . . 118.6(3) ?
    C15 C16 C17 . . 118.7(2) ?
    C15 C16 H16 . . 120.7 ?
    C17 C16 H16 . . 120.7 ?
    C16 C17 C12 . . 120.8(3) ?
    C16 C17 H17 . . 119.6 ?
    C12 C17 H17 . . 119.6 ?
    O5 C18 O6 . . 125.8(3) ?
    O5 C18 C19 . . 118.3(2) ?
    O6 C18 C19 . . 115.9(3) ?
    C20 C19 C24 . . 119.1(3) ?
    C20 C19 C18 . . 120.4(2) ?
    C24 C19 C18 . . 120.4(3) ?
    C21 C20 C19 . . 120.9(2) ?
    C21 C20 H20 . . 119.5 ?
    C19 C20 H20 . . 119.5 ?
    C22 C21 C20 . . 118.0(3) ?
    C22 C21 H21 . . 121.0 ?
    C20 C21 H21 . . 121.0 ?
    C21 C22 C23 . . 122.5(3) ?
    C21 C22 N5 . . 119.5(3) ?
    C23 C22 N5 . . 118.0(2) ?
    C24 C23 C22 . . 118.5(2) ?
    C24 C23 H23 . . 120.8 ?
    C22 C23 H23 . . 120.8 ?
    C23 C24 C19 . . 120.9(3) ?
    C23 C24 H24 . . 119.6 ?
    C19 C24 H24 . . 119.6 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O6 Ag1 Ag2 O2 . . . . 176.48(8) ?
    O1 Ag1 Ag2 O2 . . . . 12.22(9) ?
    Ag2 Ag1 Ag2 O2 2_756 . . . -103.90(10) ?
    O6 Ag1 Ag2 O5 . . . . -4.36(8) ?
    O1 Ag1 Ag2 O5 . . . . -168.62(8) ?
    Ag2 Ag1 Ag2 O5 2_756 . . . 75.26(10) ?
    O6 Ag1 Ag2 Ag1 . . . 2_756 -79.62(11) ?
    O1 Ag1 Ag2 Ag1 . . . 2_756 116.12(10) ?
    Ag2 Ag1 Ag2 Ag1 2_756 . . 2_756 0.0 ?
    O6 Ag1 O1 C11 . . . . -52.7(4) ?
    N1 Ag1 O1 C11 . . . . 157.3(3) ?
    Ag2 Ag1 O1 C11 . . . . -16.2(2) ?
    Ag2 Ag1 O1 C11 2_756 . . . 88.1(3) ?
    O5 Ag2 O2 C11 . . . . -20.2(5) ?
    Ag1 Ag2 O2 C11 . . . . -16.5(2) ?
    Ag1 Ag2 O2 C11 2_756 . . . -86.3(2) ?
    O2 Ag2 O5 C18 . . . . 9.2(5) ?
    Ag1 Ag2 O5 C18 . . . . 5.4(2) ?
    Ag1 Ag2 O5 C18 2_756 . . . 78.2(2) ?
    O1 Ag1 O6 C18 . . . . 42.3(3) ?
    N1 Ag1 O6 C18 . . . . -169.1(2) ?
    Ag2 Ag1 O6 C18 . . . . 6.4(2) ?
    Ag2 Ag1 O6 C18 2_756 . . . -103.7(2) ?
    O6 Ag1 N1 C5 . . . . -9.4(3) ?
    O1 Ag1 N1 C5 . . . . 157.0(2) ?
    Ag2 Ag1 N1 C5 2_756 . . . -84.7(2) ?
    O6 Ag1 N1 C1 . . . . -177.63(19) ?
    O1 Ag1 N1 C1 . . . . -11.3(2) ?
    Ag2 Ag1 N1 C1 2_756 . . . 107.1(2) ?
    C5 N1 C1 C2 . . . . 1.4(4) ?
    Ag1 N1 C1 C2 . . . . 170.8(2) ?
    N1 C1 C2 C3 . . . . -1.3(5) ?
    C1 C2 C3 C4 . . . . -0.1(5) ?
    C2 C3 C4 C5 . . . . 1.4(5) ?
    C1 N1 C5 N2 . . . . -178.5(2) ?
    Ag1 N1 C5 N2 . . . . 13.9(4) ?
    C1 N1 C5 C4 . . . . 0.1(4) ?
    Ag1 N1 C5 C4 . . . . -167.45(19) ?
    C10 N2 C5 N1 . . . . 178.6(3) ?
    C10 N2 C5 C4 . . . . 0.0(5) ?
    C3 C4 C5 N1 . . . . -1.4(4) ?
    C3 C4 C5 N2 . . . . 177.0(3) ?
    C10 N3 C6 C7 . . . . 0.3(5) ?
    N3 C6 C7 C8 . . . . 0.0(5) ?
    C6 C7 C8 C9 . . . . 0.2(5) ?
    C7 C8 C9 C10 . . . . -0.8(5) ?
    C6 N3 C10 N2 . . . . 178.2(3) ?
    C6 N3 C10 C9 . . . . -0.9(4) ?
    C5 N2 C10 N3 . . . . 16.2(5) ?
    C5 N2 C10 C9 . . . . -164.7(3) ?
    C8 C9 C10 N3 . . . . 1.1(5) ?
    C8 C9 C10 N2 . . . . -178.0(3) ?
    Ag2 O2 C11 O1 . . . . 10.3(4) ?
    Ag2 O2 C11 C12 . . . . -169.59(17) ?
    Ag1 O1 C11 O2 . . . . 8.5(4) ?
    Ag1 O1 C11 C12 . . . . -171.60(17) ?
    O2 C11 C12 C13 . . . . -11.4(4) ?
    O1 C11 C12 C13 . . . . 168.8(3) ?
    O2 C11 C12 C17 . . . . 169.6(3) ?
    O1 C11 C12 C17 . . . . -10.3(4) ?
    C17 C12 C13 C14 . . . . 0.6(4) ?
    C11 C12 C13 C14 . . . . -178.5(2) ?
    C12 C13 C14 C15 . . . . -0.7(4) ?
    C13 C14 C15 C16 . . . . -0.2(4) ?
    C13 C14 C15 N4 . . . . -179.4(2) ?
    O3 N4 C15 C16 . . . . -176.9(3) ?
    O4 N4 C15 C16 . . . . 2.3(4) ?
    O3 N4 C15 C14 . . . . 2.3(4) ?
    O4 N4 C15 C14 . . . . -178.5(3) ?
    C14 C15 C16 C17 . . . . 1.2(4) ?
    N4 C15 C16 C17 . . . . -179.7(2) ?
    C15 C16 C17 C12 . . . . -1.3(4) ?
    C13 C12 C17 C16 . . . . 0.4(4) ?
    C11 C12 C17 C16 . . . . 179.5(2) ?
    Ag2 O5 C18 O6 . . . . -2.4(4) ?
    Ag2 O5 C18 C19 . . . . 179.29(16) ?
    Ag1 O6 C18 O5 . . . . -4.4(4) ?
    Ag1 O6 C18 C19 . . . . 173.95(17) ?
    O5 C18 C19 C20 . . . . -154.6(3) ?
    O6 C18 C19 C20 . . . . 27.0(4) ?
    O5 C18 C19 C24 . . . . 28.8(4) ?
    O6 C18 C19 C24 . . . . -149.7(3) ?
    C24 C19 C20 C21 . . . . 1.4(4) ?
    C18 C19 C20 C21 . . . . -175.4(3) ?
    C19 C20 C21 C22 . . . . -0.2(4) ?
    C20 C21 C22 C23 . . . . -0.5(4) ?
    C20 C21 C22 N5 . . . . 179.1(3) ?
    O7 N5 C22 C21 . . . . 3.0(5) ?
    O8 N5 C22 C21 . . . . -176.2(3) ?
    O7 N5 C22 C23 . . . . -177.4(3) ?
    O8 N5 C22 C23 . . . . 3.4(4) ?
    C21 C22 C23 C24 . . . . 0.0(4) ?
    N5 C22 C23 C24 . . . . -179.6(3) ?
    C22 C23 C24 C19 . . . . 1.2(4) ?
    C20 C19 C24 C23 . . . . -1.8(4) ?
    C18 C19 C24 C23 . . . . 174.9(2) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    N2 H22 O6 . 0.86 2.37 3.220(5) 168.3 yes
    C6 H6 O1 2_666 0.93 2.65 3.394(5) 137.7 yes
    C7 H7 O8 2_765 0.93 2.60 3.316(5) 134.0 yes
    C14 H14 O7 1_546 0.93 2.55 3.404(6) 153.6 yes
    C23 H23 O4 1_654 0.93 2.65 3.372(5) 135.4 yes
