##############################################################################
###                                                                        ###
###           Full Paper (Acta Crystallographica Section C)                ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section C. It conforms to the editorial and technical    #
# requirements of Notes for Authors for Section C, and has been peer         #
# reviewed under the auspices of the IUCr Commission on Journals.            #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_name_common     ?
_chemical_formula_moiety     'Cs3 CoCl5 '
_chemical_formula_sum     'Cl5 Co Cs3'
_chemical_formula_weight     634.91
_chemical_melting_point     ?
_symmetry_cell_setting     Tetragonal
_symmetry_space_group_name_H-M     I4/mcm
_symmetry_space_group_name_Hall     '-I 4 2c'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, z'
    '-y, x, z'
    'y, -x, z'
    '-x, y, -z+1/2'
    'x, -y, -z+1/2'
    'y, x, -z+1/2'
    '-y, -x, -z+1/2'
    'x+1/2, y+1/2, z+1/2'
    '-x+1/2, -y+1/2, z+1/2'
    '-y+1/2, x+1/2, z+1/2'
    'y+1/2, -x+1/2, z+1/2'
    '-x+1/2, y+1/2, -z+1'
    'x+1/2, -y+1/2, -z+1'
    'y+1/2, x+1/2, -z+1'
    '-y+1/2, -x+1/2, -z+1'
    '-x, -y, -z'
    'x, y, -z'
    'y, -x, -z'
    '-y, x, -z'
    'x, -y, z-1/2'
    '-x, y, z-1/2'
    '-y, -x, z-1/2'
    'y, x, z-1/2'
    '-x+1/2, -y+1/2, -z+1/2'
    'x+1/2, y+1/2, -z+1/2'
    'y+1/2, -x+1/2, -z+1/2'
    '-y+1/2, x+1/2, -z+1/2'
    'x+1/2, -y+1/2, z'
    '-x+1/2, y+1/2, z'
    '-y+1/2, -x+1/2, z'
    'y+1/2, x+1/2, z'
_cell_length_a     9.0793(3)
_cell_length_b     9.0793(3)
_cell_length_c     14.4862(8)
_cell_angle_alpha     90.0
_cell_angle_beta     90.0
_cell_angle_gamma     90.0
_cell_volume     1194.15(9)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     32
_cell_measurement_theta_min     29.67
_cell_measurement_theta_max     35.25
_cell_measurement_temperature     10(2)
_exptl_crystal_description     Prism
_exptl_crystal_colour     'Dark blue'
_exptl_crystal_size_max      .32
_exptl_crystal_size_mid      .28
_exptl_crystal_size_min      .28
_exptl_crystal_density_diffrn     3.532
_exptl_crystal_density_meas     'not measured'
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1108
_exptl_absorpt_coefficient_mu     11.503
_exptl_absorpt_correction_type     Gaussian
_exptl_absorpt_process_details
                            'XTAL 3.7 (Hall, du Boulay & Olthof-Hazekamp, 2000)'
_exptl_absorpt_correction_T_min      .1200
_exptl_absorpt_correction_T_max      .1410
_exptl_special_details
;
 The correction for the absorption by the beryllium thermal shields was
 performed by PROFIT (Streltsov & Zavodnik, 1989) program.
;
_diffrn_ambient_temperature     10(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength      .71073
_diffrn_radiation_source     'normal-focus sealed tube'
_diffrn_radiation_monochromator     none
_diffrn_measurement_device_type     'Huber 512 goniometer'
_diffrn_measurement_method     'ω-2θ scan'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     23863
_diffrn_reflns_av_R_equivalents      .0261
_diffrn_reflns_av_sigmaI/netI      .0086
_diffrn_reflns_theta_min     2.81
_diffrn_reflns_theta_max     50.13
_diffrn_reflns_theta_full     50.13
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full     1.000
_diffrn_reflns_limit_h_min     -19
_diffrn_reflns_limit_h_max     19
_diffrn_reflns_limit_k_min     -19
_diffrn_reflns_limit_k_max     19
_diffrn_reflns_limit_l_min     -31
_diffrn_reflns_limit_l_max     31
_diffrn_standards_number     3
_diffrn_standards_interval_count     100
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     1
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     1708
_reflns_number_gt     1706
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all      .0206
_refine_ls_R_factor_gt      .0206
_refine_ls_wR_factor_ref      .0448
_refine_ls_goodness_of_fit_ref     1.442
_refine_ls_restrained_S_all     1.442
_refine_ls_number_reflns     1708
_refine_ls_number_parameters     18
_refine_ls_number_restraints     0
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
       'calc w = 1/[σ²(Fo²)+(0.0092P)²+6.8514P] where P=(Fo²+2Fc²)/3'
_refine_ls_shift/su_max      .002
_refine_ls_shift/su_mean      .000
_refine_diff_density_max     3.409
_refine_diff_density_min     -1.524
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 1997)'
_refine_ls_extinction_coef      .0118(2)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'Cl' 'Cl'  .1484  .1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Co' 'Co'  .3494  .9721
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cs' 'Cs'  -.3680 2.1192
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'local diffractometer control software'
_computing_cell_refinement     'local diffractometer control software'
_computing_data_reduction     'PROFIT (Streltsov & Zavodnik, 1989)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1990)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'SHELXTL (Bruker, 1997)'
_computing_publication_material     'SHELXTL'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Co  .0000  .5000  .2500  .00387(6) Uani d S 1 . . Co
    Cs1  .0000  .0000  .2500  .00418(3) Uani d S 1 . . Cs
    Cs2  .662190(10) 1.162190(10)  .0000  .00356(3) Uani d S 1 . . Cs
    Cl1  .0000  .0000  .0000  .00598(10) Uani d S 1 . . Cl
    Cl2  .14216(3)  .64216(3)  .15710(3)  .00616(6) Uani d S 1 . . Cl
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Co Cl2 2_565 2.2679(4) ?
    Co Cl2 28 2.2679(4) ?
    Co Cl2 27_455 2.2679(4) ?
    Co Cl2 . 2.2679(4) ?
    Co Cs2 9_445 4.17763(18) ?
    Co Cs2 19_465 4.17763(19) ?
    Co Cs2 3_655 4.17763(19) ?
    Co Cs2 25_565 4.17763(19) ?
    Cs1 Cl1 5 3.6215(2) ?
    Cs1 Cl1 . 3.6215(2) ?
    Cs1 Cl2 4_455 3.7460(3) ?
    Cs1 Cl2 27_455 3.7460(3) ?
    Cs1 Cl2 28_545 3.7460(3) ?
    Cs1 Cl2 3_655 3.7460(3) ?
    Cs1 Cl2 25 3.7460(3) ?
    Cs1 Cl2 1_545 3.7460(3) ?
    Cs1 Cl2 26_445 3.7460(3) ?
    Cs1 Cl2 2_565 3.7460(3) ?
    Cs1 Cs2 3_645 4.96901(17) ?
    Cs1 Cs2 11_645 4.96901(17) ?
    Cs2 Cl2 2_675 3.3896(4) ?
    Cs2 Cl2 17_675 3.3896(4) ?
    Cs2 Cl1 1_665 3.40227(12) ?
    Cs2 Cl1 13_564 3.40227(13) ?
    Cs2 Cl2 19_565 3.5844(4) ?
    Cs2 Cl2 20_665 3.5844(4) ?
    Cs2 Cl2 4_565 3.5844(4) ?
    Cs2 Cl2 3_665 3.5844(4) ?
    Cs2 Cs2 17_675 4.1651(3) ?
    Cs2 Co 9_554 4.17763(18) ?
    Cs2 Co 25_565 4.17763(18) ?
    Cs2 Cs2 19_575 4.81154(17) ?
    Cl1 Cs2 19_465 3.40227(12) ?
    Cl1 Cs2 3_645 3.40227(12) ?
    Cl1 Cs2 17_665 3.40227(12) ?
    Cl1 Cs2 1_445 3.40227(12) ?
    Cl1 Cs1 17 3.6215(2) ?
    Cl2 Cs2 17_675 3.3896(4) ?
    Cl2 Cs2 3_655 3.5844(4) ?
    Cl2 Cs2 19_465 3.5844(4) ?
    Cl2 Cs1 1_565 3.7460(3) ?
    Cl2 Cs1 25 3.7460(3) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    Cl2 Co Cl2 2_565 28 110.619(11) ?
    Cl2 Co Cl2 2_565 27_455 110.619(11) ?
    Cl2 Co Cl2 28 27_455 107.20(2) ?
    Cl2 Co Cl2 2_565 . 107.20(2) ?
    Cl2 Co Cl2 28 . 110.619(11) ?
    Cl2 Co Cl2 27_455 . 110.619(11) ?
    Cl2 Co Cs2 2_565 9_445 156.301(11) ?
    Cl2 Co Cs2 28 9_445 59.040(9) ?
    Cl2 Co Cs2 27_455 9_445 59.040(9) ?
    Cl2 Co Cs2 . 9_445 96.500(12) ?
    Cl2 Co Cs2 2_565 19_465 59.040(9) ?
    Cl2 Co Cs2 28 19_465 156.301(11) ?
    Cl2 Co Cs2 27_455 19_465 96.500(12) ?
    Cl2 Co Cs2 . 19_465 59.040(9) ?
    Cs2 Co Cs2 9_445 19_465 138.721(3) ?
    Cl2 Co Cs2 2_565 3_655 59.040(9) ?
    Cl2 Co Cs2 28 3_655 96.500(12) ?
    Cl2 Co Cs2 27_455 3_655 156.301(11) ?
    Cl2 Co Cs2 . 3_655 59.040(9) ?
    Cs2 Co Cs2 9_445 3_655 138.721(3) ?
    Cs2 Co Cs2 19_465 3_655 59.801(5) ?
    Cl2 Co Cs2 2_565 25_565 96.500(12) ?
    Cl2 Co Cs2 28 25_565 59.040(9) ?
    Cl2 Co Cs2 27_455 25_565 59.040(9) ?
    Cl2 Co Cs2 . 25_565 156.301(11) ?
    Cs2 Co Cs2 9_445 25_565 59.801(5) ?
    Cs2 Co Cs2 19_465 25_565 138.721(3) ?
    Cs2 Co Cs2 3_655 25_565 138.721(3) ?
    Cl1 Cs1 Cl1 5 . 180.0 ?
    Cl1 Cs1 Cl2 5 4_455 111.055(6) ?
    Cl1 Cs1 Cl2 . 4_455 68.945(6) ?
    Cl1 Cs1 Cl2 5 27_455 68.945(6) ?
    Cl1 Cs1 Cl2 . 27_455 111.055(6) ?
    Cl2 Cs1 Cl2 4_455 27_455 136.615(12) ?
    Cl1 Cs1 Cl2 5 28_545 68.945(6) ?
    Cl1 Cs1 Cl2 . 28_545 111.055(6) ?
    Cl2 Cs1 Cl2 4_455 28_545 62.056(12) ?
    Cl2 Cs1 Cl2 27_455 28_545 137.889(12) ?
    Cl1 Cs1 Cl2 5 3_655 111.055(6) ?
    Cl1 Cs1 Cl2 . 3_655 68.945(6) ?
    Cl2 Cs1 Cl2 4_455 3_655 137.889(12) ?
    Cl2 Cs1 Cl2 27_455 3_655 62.056(12) ?
    Cl2 Cs1 Cl2 28_545 3_655 136.615(12) ?
    Cl1 Cs1 Cl2 5 25 68.945(6) ?
    Cl1 Cs1 Cl2 . 25 111.055(6) ?
    Cl2 Cs1 Cl2 4_455 25 139.689(12) ?
    Cl2 Cs1 Cl2 27_455 25 82.584(4) ?
    Cl2 Cs1 Cl2 28_545 25 82.584(4) ?
    Cl2 Cs1 Cl2 3_655 25 59.708(13) ?
    Cl1 Cs1 Cl2 5 1_545 111.055(6) ?
    Cl1 Cs1 Cl2 . 1_545 68.945(6) ?
    Cl2 Cs1 Cl2 4_455 1_545 82.584(4) ?
    Cl2 Cs1 Cl2 27_455 1_545 139.689(12) ?
    Cl2 Cs1 Cl2 28_545 1_545 59.708(13) ?
    Cl2 Cs1 Cl2 3_655 1_545 82.584(4) ?
    Cl2 Cs1 Cl2 25 1_545 62.056(12) ?
    Cl1 Cs1 Cl2 5 26_445 68.945(6) ?
    Cl1 Cs1 Cl2 . 26_445 111.055(6) ?
    Cl2 Cs1 Cl2 4_455 26_445 59.708(13) ?
    Cl2 Cs1 Cl2 27_455 26_445 82.584(4) ?
    Cl2 Cs1 Cl2 28_545 26_445 82.584(4) ?
    Cl2 Cs1 Cl2 3_655 26_445 139.689(12) ?
    Cl2 Cs1 Cl2 25 26_445 137.889(12) ?
    Cl2 Cs1 Cl2 1_545 26_445 136.615(12) ?
    Cl1 Cs1 Cl2 5 2_565 111.055(6) ?
    Cl1 Cs1 Cl2 . 2_565 68.945(6) ?
    Cl2 Cs1 Cl2 4_455 2_565 82.584(4) ?
    Cl2 Cs1 Cl2 27_455 2_565 59.708(13) ?
    Cl2 Cs1 Cl2 28_545 2_565 139.689(12) ?
    Cl2 Cs1 Cl2 3_655 2_565 82.584(4) ?
    Cl2 Cs1 Cl2 25 2_565 136.615(12) ?
    Cl2 Cs1 Cl2 1_545 2_565 137.889(12) ?
    Cl2 Cs1 Cl2 26_445 2_565 62.056(12) ?
    Cl1 Cs1 Cs2 5 3_645 136.788(2) ?
    Cl1 Cs1 Cs2 . 3_645 43.212(2) ?
    Cl2 Cs1 Cs2 4_455 3_645 42.984(7) ?
    Cl2 Cs1 Cs2 27_455 3_645 154.065(6) ?
    Cl2 Cs1 Cs2 28_545 3_645 67.939(7) ?
    Cl2 Cs1 Cs2 3_655 3_645 101.997(6) ?
    Cl2 Cs1 Cs2 25 3_645 107.830(6) ?
    Cl2 Cs1 Cs2 1_545 3_645 45.968(6) ?
    Cl2 Cs1 Cs2 26_445 3_645 102.562(7) ?
    Cl2 Cs1 Cs2 2_565 3_645 99.868(7) ?
    Cl1 Cs1 Cs2 5 11_645 43.212(2) ?
    Cl1 Cs1 Cs2 . 11_645 136.788(2) ?
    Cl2 Cs1 Cs2 4_455 11_645 154.065(6) ?
    Cl2 Cs1 Cs2 27_455 11_645 42.984(7) ?
    Cl2 Cs1 Cs2 28_545 11_645 101.997(6) ?
    Cl2 Cs1 Cs2 3_655 11_645 67.939(7) ?
    Cl2 Cs1 Cs2 25 11_645 45.968(6) ?
    Cl2 Cs1 Cs2 1_545 11_645 107.830(6) ?
    Cl2 Cs1 Cs2 26_445 11_645 99.868(7) ?
    Cl2 Cs1 Cs2 2_565 11_645 102.562(7) ?
    Cs2 Cs1 Cs2 3_645 11_645 153.770(3) ?
    Cl2 Cs2 Cl2 2_675 17_675 84.347(16) ?
    Cl2 Cs2 Cl1 2_675 1_665 75.783(3) ?
    Cl2 Cs2 Cl1 17_675 1_665 75.783(3) ?
    Cl2 Cs2 Cl1 2_675 13_564 75.783(3) ?
    Cl2 Cs2 Cl1 17_675 13_564 75.783(3) ?
    Cl1 Cs2 Cl1 1_665 13_564 141.293(4) ?
    Cl2 Cs2 Cl2 2_675 19_565 148.964(6) ?
    Cl2 Cs2 Cl2 17_675 19_565 90.248(11) ?
    Cl1 Cs2 Cl2 1_665 19_565 73.265(6) ?
    Cl1 Cs2 Cl2 13_564 19_565 132.301(7) ?
    Cl2 Cs2 Cl2 2_675 20_665 148.964(6) ?
    Cl2 Cs2 Cl2 17_675 20_665 90.248(11) ?
    Cl1 Cs2 Cl2 1_665 20_665 132.301(7) ?
    Cl1 Cs2 Cl2 13_564 20_665 73.265(6) ?
    Cl2 Cs2 Cl2 19_565 20_665 61.229(13) ?
    Cl2 Cs2 Cl2 2_675 4_565 90.248(11) ?
    Cl2 Cs2 Cl2 17_675 4_565 148.964(6) ?
    Cl1 Cs2 Cl2 1_665 4_565 73.265(6) ?
    Cl1 Cs2 Cl2 13_564 4_565 132.301(7) ?
    Cl2 Cs2 Cl2 19_565 4_565 78.825(12) ?
    Cl2 Cs2 Cl2 20_665 4_565 108.958(9) ?
    Cl2 Cs2 Cl2 2_675 3_665 90.248(11) ?
    Cl2 Cs2 Cl2 17_675 3_665 148.964(6) ?
    Cl1 Cs2 Cl2 1_665 3_665 132.301(7) ?
    Cl1 Cs2 Cl2 13_564 3_665 73.265(6) ?
    Cl2 Cs2 Cl2 19_565 3_665 108.958(9) ?
    Cl2 Cs2 Cl2 20_665 3_665 78.825(12) ?
    Cl2 Cs2 Cl2 4_565 3_665 61.229(13) ?
    Cl2 Cs2 Cs2 2_675 17_675 137.826(8) ?
    Cl2 Cs2 Cs2 17_675 17_675 137.827(8) ?
    Cl1 Cs2 Cs2 1_665 17_675 109.353(2) ?
    Cl1 Cs2 Cs2 13_564 17_675 109.353(2) ?
    Cl2 Cs2 Cs2 19_565 17_675 54.479(5) ?
    Cl2 Cs2 Cs2 20_665 17_675 54.479(5) ?
    Cl2 Cs2 Cs2 4_565 17_675 54.479(5) ?
    Cl2 Cs2 Cs2 3_665 17_675 54.479(5) ?
    Cl2 Cs2 Co 2_675 9_554 162.074(8) ?
    Cl2 Cs2 Co 17_675 9_554 77.727(8) ?
    Cl1 Cs2 Co 1_665 9_554 99.5090(10)
                                     ?
    Cl1 Cs2 Co 13_564 9_554 99.5090(10)
                                      ?
    Cl2 Cs2 Co 19_565 9_554 32.859(7) ?
    Cl2 Cs2 Co 20_665 9_554 32.859(7) ?
    Cl2 Cs2 Co 4_565 9_554 105.115(6) ?
    Cl2 Cs2 Co 3_665 9_554 105.115(6) ?
    Cs2 Cs2 Co 17_675 9_554 60.099(2) ?
    Cl2 Cs2 Co 2_675 25_565 77.727(8) ?
    Cl2 Cs2 Co 17_675 25_565 162.074(8) ?
    Cl1 Cs2 Co 1_665 25_565 99.5090(10)
                                      ?
    Cl1 Cs2 Co 13_564 25_565 99.5090(10)
                                       ?
    Cl2 Cs2 Co 19_565 25_565 105.115(6) ?
    Cl2 Cs2 Co 20_665 25_565 105.115(7) ?
    Cl2 Cs2 Co 4_565 25_565 32.859(7) ?
    Cl2 Cs2 Co 3_665 25_565 32.859(7) ?
    Cs2 Cs2 Co 17_675 25_565 60.099(2) ?
    Co Cs2 Co 9_554 25_565 120.199(4) ?
    Cl2 Cs2 Cs2 2_675 19_575 48.079(7) ?
    Cl2 Cs2 Cs2 17_675 19_575 48.079(7) ?
    Cl1 Cs2 Cs2 1_665 19_575 45.0 ?
    Cl1 Cs2 Cs2 13_564 19_575 96.293(4) ?
    Cl2 Cs2 Cs2 19_565 19_575 107.658(5) ?
    Cl2 Cs2 Cs2 20_665 19_575 138.089(6) ?
    Cl2 Cs2 Cs2 4_565 19_575 107.658(5) ?
    Cl2 Cs2 Cs2 3_665 19_575 138.088(6) ?
    Cs2 Cs2 Cs2 17_675 19_575 154.353(2) ?
    Co Cs2 Cs2 9_554 19_575 116.704(2) ?
    Co Cs2 Cs2 25_565 19_575 116.704(2) ?
    Cs2 Cl1 Cs2 19_465 3_645 180.0000(10)
                                        ?
    Cs2 Cl1 Cs2 19_465 17_665 90.0 ?
    Cs2 Cl1 Cs2 3_645 17_665 90.0 ?
    Cs2 Cl1 Cs2 19_465 1_445 90.0 ?
    Cs2 Cl1 Cs2 3_645 1_445 90.0 ?
    Cs2 Cl1 Cs2 17_665 1_445 180.0000(10)
                                        ?
    Cs2 Cl1 Cs1 19_465 . 90.0 ?
    Cs2 Cl1 Cs1 3_645 . 90.0 ?
    Cs2 Cl1 Cs1 17_665 . 90.0 ?
    Cs2 Cl1 Cs1 1_445 . 90.0 ?
    Cs2 Cl1 Cs1 19_465 17 90.0 ?
    Cs2 Cl1 Cs1 3_645 17 90.0 ?
    Cs2 Cl1 Cs1 17_665 17 90.0 ?
    Cs2 Cl1 Cs1 1_445 17 90.0 ?
    Cs1 Cl1 Cs1 . 17 180.0 ?
    Co Cl2 Cs2 . 17_675 174.227(19) ?
    Co Cl2 Cs2 . 3_655 88.101(12) ?
    Cs2 Cl2 Cs2 17_675 3_655 87.201(9) ?
    Co Cl2 Cs2 . 19_465 88.101(12) ?
    Cs2 Cl2 Cs2 17_675 19_465 87.201(9) ?
    Cs2 Cl2 Cs2 3_655 19_465 71.042(9) ?
    Co Cl2 Cs1 . 1_565 94.836(9) ?
    Cs2 Cl2 Cs1 17_675 1_565 88.124(8) ?
    Cs2 Cl2 Cs1 3_655 1_565 85.323(3) ?
    Cs2 Cl2 Cs1 19_465 1_565 156.092(10) ?
    Co Cl2 Cs1 . 25 94.836(9) ?
    Cs2 Cl2 Cs1 17_675 25 88.124(8) ?
    Cs2 Cl2 Cs1 3_655 25 156.092(10) ?
    Cs2 Cl2 Cs1 19_465 25 85.323(3) ?
    Cs1 Cl2 Cs1 1_565 25 117.944(12) ?
data_publ
_journal_date_recd_electronic     2000-05-30
_journal_date_accepted     2000-10-13
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2001
_journal_volume     57
_journal_issue      2
_journal_page_first     139
_journal_page_last     140
_journal_paper_category     FI
_publ_contact_author_name     'Prof. B.N. Figgis'
_publ_contact_author_address
;
Chemistry Department
University of Western Australia
Nedlands, W.A. 6907
Australia
;
_publ_contact_author_email     bnf@crystal.uwa.edu.au
_publ_contact_author_fax     '618-9380-1005'
_publ_contact_author_phone     '618-9380-3157'
_publ_section_title
;
 Cs₃CoCl₅ at 10 K
;
loop_
    _publ_author_name
    _publ_author_address
    'Figgis, Brian N.'
;
Chemistry Department
University of Western Australia
Nedlands, W.A. 6907
Australia
;
    'Sobolev, Alexandre N.'
;
Chemistry Department
University of Western Australia
Nedlands, W.A. 6907
Australia
;
_publ_section_synopsis
;
The crystal structure of Cs₃CoCl₅ has been determined at 10 K
with high precision.
;
