Boson Correlation Energies from Reduced Hamiltonian Interpolation

David A. Mazziotti and Dudley R. Herschbach
Phys. Rev. Lett. 83, 5185 – Published 20 December 1999
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Abstract

The ground-state energies of interacting bosons are computed beyond the mean-field approximation by a new method which we call reduced Hamiltonian interpolation (RHI). In this interpolation the N-particle Hamiltonian is represented through a sequence of p-particle expanded and reduced Hamiltonians that give upper and lower bounds on the true energy. A synthesis of ideas from N-representability and dimensional interpolation, the RHI interpolates over the number p of quasiparticles (equivalent to spatial dimension) to calculate the N-particle energy as the mean of close upper and lower bounds. Application to bosons with harmonic interactions yields more than 99% of the correlation energy.

  • Received 12 August 1999

DOI:https://doi.org/10.1103/PhysRevLett.83.5185

©1999 American Physical Society

Authors & Affiliations

David A. Mazziotti1,2 and Dudley R. Herschbach2

  • 1Department of Chemistry, Duke University, Durham, North Carolina 27708-0346
  • 2Department of Chemistry, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138

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Vol. 83, Iss. 25 — 20 December 1999

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