Anti-Aging in Ultrastable Metallic Glasses

Martin Lüttich, Valentina M. Giordano, Sylvie Le Floch, Eloi Pineda, Federico Zontone, Yuansu Luo, Konrad Samwer, and Beatrice Ruta
Phys. Rev. Lett. 120, 135504 – Published 30 March 2018
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Abstract

As ultrastable metallic glasses (UMGs) are promising candidates to solve the stability issues of conventional metallic glasses, their study is of exceptional interest. By means of x-ray photon correlation spectroscopy, we have investigated the stability of UMGs at the atomic level. We find a clear signature of ultrastability at the atomic level that results in slower relaxation dynamics of UMGs with respect to conventional (rapidly quenched) metallic glasses, and in a peculiar acceleration of the dynamics by near Tg annealing. This surprising phenomenon, called here anti-aging, can be understood in the framework of the potential energy landscape. For all samples, the structural relaxation process can be described with a highly compressed shape of the density fluctuations, unaffected by thermal treatments and regardless of the ultrastability of the glass.

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  • Received 27 July 2017
  • Revised 22 February 2018

DOI:https://doi.org/10.1103/PhysRevLett.120.135504

© 2018 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter, Materials & Applied Physics

Authors & Affiliations

Martin Lüttich1,2,*, Valentina M. Giordano3, Sylvie Le Floch3, Eloi Pineda4, Federico Zontone2, Yuansu Luo1, Konrad Samwer1, and Beatrice Ruta3,2,†

  • 1I. Physikalisches Institut, Universität Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany
  • 2ESRF—The European Synchrotron, CS 40220, 38043 Grenoble Cedex 9, France
  • 3Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière, F-69622 Villeurbanne, France
  • 4Department of Physics, Universitat Politècnica de Catalunya-BarcelonaTech, Esteve Terradas 8, Castelldefels 08860, Spain

  • *mluetti1@gwdg.de
  • beatrice.ruta@univ-lyon1.fr

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Issue

Vol. 120, Iss. 13 — 30 March 2018

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